Document QXpLo033ejqLYnx5MxEM0Mdb5

3 GLP10-01-02 Interim Report 01: Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected in March/April 2010 Study Title 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program Data Requirement EPA TSCA Good Laboratory Practice Standards 40 CFR Part 792 Study Director Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Phone: 610-701-3761 Principle Analytical Investigator Cleston C. Lange, Ph.D. 3M Environmental Laboratory Interim Report Completion Date Date of signing Performing Laboratory 3M Environmental Health and Safety Operations Environmental Laboratory 3M Center, Bldg 260-05-N-17 St. Paul, MN 55144 Project Identification GLP-10-01-02-01 Total Number of Pages 539 Study: GLP10-02-01 Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 This page has been reserved for specific country requirements. 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/Aprll 2010 GLP Compliance Statement Report Title: GLP10-01-02 Interim Report 01. Analysis of Decatur Site Soils for PFOS, PFHS and PFBS, Collected in March/April 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-01: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This analytical phase was conducted in compliance with Toxic Substances Control Act (TSCA) Good Laboratory Practice (GLP) Standards, 40 CFR 792, with the exceptions listed below: Exceptions to GLP compliance: Test, control and reference substances were not all characterized under GLPs. As these are real-life environmental samples, there was no dosing and no specific test Date 3M Study: GLP10-01-02 Interim Report 01 Page 3 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Q uality A ssurance Statement Report Title: GLP10-01-02 Interim Report 01. Analysis of Decatur Site Soils for PFOS, PFHS and PFBS, Collected in March/April 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This report and the accompanying data were audited by the 3M Environmental Laboratory Quality Assurance Unit (QAU), as indicated below. The findings were reported to the principal investigator (P.I.), laboratory management and study director. Inspection Dates March 3,2010 March 25,2010 June 14-18,2010 Phase Protocol In-phase Report and Data P .l. March 3,2010 March 31, 2010 June 18,2010 D ate Reported to Study D irector M anagem ent March 3, 2010 March 31, 2010 June 18, 2010 Study D irector March 3,2010 March 31,2010 June 18,2010 -_ QAU Representative '3-1 o Date 3M Study: GLP10-01-02 Interim Report 01 Page 4 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table of Contents GLP Compliance Statement...............................................................................................................3 Quality Assurance Statement.............................................................................................................4 1 Study Information......................................................................................................................... 7 2 Summary....................................................................................................................................... 8 3 Introduction..................................................................................................................................10 4 Test, Control and Reference Substances.................................................................................. 10 5 Test System................................................................................................................................ 12 6 Method Summary........................................................................................................................12 6.1 Methods.......................................................................................................................... 12 6.2 Sample Collection............................................................................................................12 6.3 Sample Preparation......................................................................................................... 12 6.4 Percent Soil Moisture Determination...............................................................................13 6.5 LC/MS/MS Analysis........................................................................................................14 7 Analytical Results ........................................................................................................................15 7.1 Calibration ....................................................................................................................... 15 7.2 Limits of Quantitation (LOQs) ......................................................................................... 17 7.3 Continuing Calibration .....................................................................................................17 7.4 Blanks.............................................................................................................................. 17 7.5 Laboratory Control Spikes (LCSs)...................................................................................17 7.6 Laboratory Matrix Spikes (LMSs)....................................................................................19 7.7 Percent Soil Moisture Determinations.............................................................................19 7.8 Individual Sample Results............................................................................................... 21 8 Conclusion .................................................................................................................................. 28 9 Data/Sample Retention .............................................................................................................. 28 3M Study: GLP10-01-02 Interim Report 01 Page 5 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 10 List of Attachments.................................................................................................................... 28 11 Signatures.................................................................................................................................. 29 List of Tables Table 1. Summarized Results (Decatur FSIA Soils, March/April 2010).............................................8 Table 2. LMS Recoveries (Decatur FSIA Soils, March/April 2010)................................................... 9 Table 4. Instrument Information......................................................................................................... 14 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053).................................................14 Table 6. Mass Transitions..................................................................................................................15 Table 7. PFOS Calibration Summary............................................................................................... 16 Table 8. PFHS Calibration Summary................................................................................................ 16 Table 9. PFBS Calibration Summary ................................................................................................ 16 Table 10. LCS Results (PFOS).........................................................................................................18 Table 11. LCS Results (PFHS).........................................................................................................18 Table 12. LCS Results (PFBS)..........................................................................................................18 Table 13. Percent Moisture Results for Decatur FSIA Soils (March/April 2010)..............................20 Table 14. Individual PFOS Results for Decatur FSIA Soils (March/April 2010)...............................21 Table 15. Individual PFHS Results for Decatur FSIA Soils (March/April 2010)............................... 23 Table 16. Individual PFBS Results for Decatur FSIA Soils (March/April 2010)............................... 25 3M Study: GLP10-01-02 Interim Report 01 Page 6 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 1 Study Information Sponsor 3M Company Sponsor Representative Gary A. Hohenstein Environmental Manager Special Projects, EHS Operations Bldg 224-5W-03 St. Paul, MN 55144 Phone: (651) 737-3570 gahohenstein@mmm.com Study Director Jaisimha Kesari, P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Study Analytical Testing Facility 3M EHS Operations Environmental Laboratory Building 260-5N-17 St. Paul, MN 55144 Study Personnel (3M Environmental Laboratory) William K. Reagen, Ph.D., Laboratory Manager Cleston C. Lange, Ph.D., Principal Analytical Investigator Gabriel P. McMurtry, Laboratory Technician (Pace Analytical, Professional Services) Kevin J. Eich, Laboratory Technician (Quality Associates, Professional Services) Study Dates Study Initiation: March 24, 2010 Interim Analytical Initiation: April 15, 2010 Interim Analytical Completion: May 14, 2010 Interim Report Completion: July 13, 2010 Location of Archives All original raw data and analytical reports have been archived at the 3M Environmental Laboratory according to 40 CFR Part 792. The test substance and analytical reference standard reserve samples are archived at the 3M Environmental Laboratory according to 40 CFR Part 79 3M Study: GLP10-01-02 Interim Report 01 Page 7 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 2 Summary Twenty-nine Decatur, AL former sludge incorporation area (FSIA) field soils, and two soil trip blanks, were analyzed for PFOS, PFHS and PFBS. Triplicate samples of each were extracted for LC/MS/MS analysis, with the third replicate serving as a laboratory matrix spike (LMS) sample. The percent moisture of each soil was determined, and the average concentrations of PFOS, PFHS and PFBS reported on a dry weight basis in Table 1. The PFOS concentrations ranged from 4.74 ng/g to 18,900 ng/g. The PFHS and PFBS concentrations were lower than PFOS in all samples, and ranged from below the lower limit of quantitation (BLQ) to a high of 4.26 ng/g for PFBS and 86.8 ng/g for PFHS. The relative percent difference (RPD) for duplicate results was less than 50%, except seven results as noted. The LMS recoveries reported in Table 2 were within 100+30%, with two exceptions as noted. The trip blanks were BLQ for all analytes, indicating sample integrity was maintained during shipping and collection. Two aqueous equipment rinseate samples were analyzed in a separate water analysis, and were less than 0.0255 ng/mL PFBS, less than 0.0258 ng/mL PFHS and less than 0.510 ng/mL PFOS, as reported in GLP10-01-02 interim report 02. Table 1. Summarized Results (Decatur FSIA Soils, March/April 2010) Sample ID Average Concentration (ng/g; dry/ weight) PFOS PFHS PFBS DAL DF05 SS SS06 0 0000 35.8 0.161 0.187 DAL DF05 SS SS06 0 0010 48.4 BLQ BLQ DAL DF05 SS SS06 1 0010 42.1 BLQ BLQ DAL DF05 SS SS07 0 0000 49.4 0.357 BLQ DAL DF05 SS SS07 0 0010 4.74 [a, b] 0.467[a] BLQ DAL DF05 SS SS08 0 0000 101 0.156 BLQ DAL DF05 SS SS08 0 0010 59.8 BLQ BLQ DAL DF05 SS SS09 0 0000 410 0.283 BLQ DAL DF05 SS SS09 0 0010 88.4 0.164 [c] BLQ DAL DF05 SS SS10 0 0000 1080 [b] 2.16 [a] BLQ DAL DF05 SS SS10 0 0010 237 1.27 BLQ DAL DF8C SS SS01 0 0000 159 0.681 0.156 DAL DF8C SS SS01 0 0010 356 1.39 0.222 DAL DF8C SS SS02 0 0000 121 0.563 BLQ DAL DF8C SS SS02 0 0010 91.8 0.345 BLQ DAL DF8C SS SS03 0 0000 874 11.2 2.17 DAL DF8C SS SS03 0 0010 1550 10.4 1.33 DAL DF8C SS SS03 1 0010 1530 10.5 1.38 DAL DF8C SS SS04 0 0000 242 0.290 [c] BLQ DAL DF8C SS SS04 0 0010 302 0.333 BLQ DAL DF8C SS SS05 0 0000 276 1.48 0.198 DAL DF8C SS SS05 0 0010 508 27.1 6.62 DAL DF11 SS SS05 0 0000 1500 [a] 10.0 0.919 DAL DF11 SS SS05 0 0010 1140 [a] 3.21 [a] 0.227 DAL DF11 SS SS05 1 0010 1360 2.98 0.185 DAL DF11 SS SS06 0 0000 1050 4.62 0.326 DAL DF11 SS SS06 0 0010 659 [b] 2.01 0.139 DAL DF11 SS SS07 0 0000 18900 86.8 4.26 [a] DAL DF11 SS SS07 0 0010 4960 1.95 BLQ Soil Trip Blank 1 BLQ BLQ BLQ Soil Trip Blank 3 BLQ BLQ BLQ [a] R P D w a s g re a te r tha n 50% [b] LM S re co ve ry w a s ou tsid e o f 100 + 30 % , but w ith in 100 + 50% [c] R esult re p o rte d fro m one va lu e w h e n d u p lica te re su lt w a s B LQ , sin g le real va lu e use d to ca lcu la te LM S re covery. B LQ ; L C /M S /M S an a lyte re sp o n se w a s be lo w th e low lim it o f q u a n tita tio n (le ss th a n the no m in a l 0 .2 0 0 ng sta n d a rd ). 3M Study: GLP10-01-02 Interim Report 01 Page 8 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 2. LMS Recoveries (Decatur FSIA Soils, March/April 2010) Sample ID PFOS LMS Analyte Recoveries (%) PFHS PFBS DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0010 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0010 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0010 Soil Trip Blank 1 101% 125% 94.7% 101% 139% [a] 120% 78.2% 96.9% 121% 63.1% 84.1% 76.3% 84.7% 92.9% 113% 88.6% 86.1% 91.7% 88.1% 81.0% 68.3% 81.5% 88.4% 82.2% 78.5% 74.5% 133% [a] 88.9% 69.6% 100% 102% 114% 107% 95.4% 83.5% 104% 112% 117% 101% 91.2% 93.7% 94.5% 90.6% 107% 104% 94.4% 101% 100% 98.0% 92.6% 100% 101% 114% 81.7% 86.1% 74.1% 99.7% 83.9% 102% 99.4% 106% 114% 105% 107% 102% 112% 101% 111% 97.2% 104% 108% 99.3% 105% 115% 103% 101% 104% 105% 106% 105% 107% 103% 109% 91.6% 107% 92.2% 99.6% 96.4% 112% 102% Soil Trip Blank 3 98.8% 98.5% 95.6% F o rtific a tio n s w e re a t le v e ls c o m p a ra b le to th e e n d o g e n o u s a n a ly te le v e l in s o il s a m p le s (i.e. fo rtifie d b e tw e e n 0 .5 and 10 -tim es the e n d o g e n o u s analyte con centration ) [a] LM S re co ve ry w a s ou tsid e o f norm al a cce p ta n ce crite ria o f 100 + 30% , but re ported w h e n w ithin 100 + 50% 3M Study: GLP10-01-02 Interim Report 01 Page 9 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 3 Introduction This study was conducted to further characterize fluorochemicals concentrations in areas undergoing capping at the 3M facility located in Decatur, Alabama. This analytical study was conducted to measure PFOS, PFHS and PFBS in soils from former sludge incorporation area (FSIA) fields #5, #8 and #11 and collected at the Decatur site. Soils were collected by Weston Solutions, Inc. personnel and sent to the 3M Environmental Laboratory for quantitative analysis in March/April 2010. Travel blanks (trip blanks), sample bottles containing a control soil, accompanied the empty sample bottles to the site and then accompanied the soil samples back to the laboratory, and were also analyzed as a measure of any sample contamination during field collections and sample shipping. Two aqueous equipment rinseate samples were also collected during soil collections and were sent with the soil shipment to evaluate whether soil collection equipment was thoroughly cleaned between samplings so as to avoid cross-contamination. The aqueous equipment rinseate samples were analyzed with groundwater samples for study GLP10-01-02 and reported in interim report 02. This interim report describes the sample shipping, receipt, extraction and quantitative liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) analysis procedures conducted for determination of PFOS, PFHS and PFBS concentrations in the FSIA soils and associated travel blanks as study GLP10-01-02 (project GLP10-01-02-01). Additional results include the evaluation of analytical precision and accuracy of the results, as well as determination of soil percent moisture for reporting concentration results on a dry soil weight basis. 4 Test, Control and Reference Substances This study does not have a test or control substance in the classic sense of a GLP study because this study was purely analytical in nature. The analytical reference substances are listed in Table 3. Table 3. Reference Substances R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description PFOS (linear) PFOS (linear + branched) PFHS (linear) n-Perfluorooctane-1Sulfonate Potassium Salt n-Cg F1 7 SO3 K Reference Standard for Calibration and LCSs 2795-39-3 Wellington Laboratories 10/18/13 -20C LPFOSKBM06 TCR08-0001-1/1 Crystalline Perfluorooctane Sulfonate Potassium Salt C8 F1 7 SO3 K Reference Standard for LMSs 2795-39-3 3M 12/14/16 -20C 171 TCR-696 W hite Powder n-Perfluorohexane-1-sulfonate Sodium Salt n-C6 F1 3 SO3 Na Reference Standard for Calibration and LCSs 3871-99-6 Wellington Laboratories 4/2/13 -20C LPFHxSAM08 TCR08-0018-1/1 Crystalline 3M Study: GLP10-01-02 Interim Report 01 Page 10 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 3. Reference Substances Purity R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity 98% PFHS (linear + branched) n-Perfluorohexane-1sulfonate Potassium Salt n-Cg F13 SO3 K Reference Standard for LMSs 3871-99-6 3M 2/12/17 -20C NB 120067-69 TCR-083 W hite Powder 98.6% [1,2,3,4,5,6,7,8-13C8 ]PFOS [1 3 C8 ]-Perfluorooctane-1Sulfonate Sodium Salt 1 3 C8 F1 7 SO 3 Na Internal Standard for PFOS 2795-39-3 Wellington Laboratories 6/17/12 -20 C M8PFOS0609 TCR09-0051-3/15 Methanol solution, sealed ampule >98% 86.4% PFBS (predominantly linear) Perfluorobutane-1-sulfonate Potassium Salt n-C4 Fg SC>3 K Reference Standard for All PFBS 29420-49-3 3M 1/10/17 -20C 101 TCR-121 W hite Powder 96.7% [1 8 O2 ]-PFHS [1 8 O2 ]-Perfluorohexane-1Sulfonate Sodium Salt C6 F1 3 S1 8 O 2 1 6 O Na Internal Standard for PFHS 3871-99-6 W ellington Laboratories 7/24/11 -20C MPFHxS0706 T C R -1 2 1 7 M ethanol solution, sealed a m p u le >98% >98% [1,2,3,4-1 3 C4 ]-PFOS [1,2,3,4-1 3 C4 ]P e rflu o ro o c ta n e -1 -S u lfo n a te Sodium Salt 1 3 C4 1 2 C4 F1 7 SO3 Na S u rro g a te 2795-39-3 W ellington Laboratories 9/9/2012 -20C MPFOS0808 T C R 0 9 -0 0 5 1 -6 /1 5 Methanol solution, sealed ampule >98% [1 8 O 2 ]-PFBS [1 8 O2 ]-Perfluorobutane-1Sulfonate A m m onium Salt c 4f 9s 18o 216o n h 4 Internal Standard for PFBS 29420-49-3 RTI International 9/23/10 -20C 11546-107-2 T C R -1 0 0 4 Methanol solution, sealed am p u le >99% 3M Study: GLP10-01-02 Interim Report 01 Page 11 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 5 Test System There was not a test system for this study in the classic sense of a GLP study. This study was conducted for analysis of FSIA soils collected from the Decatur, AL site in March/April 2010. Samples for this study are "real world" environmental samples composed of soil. 6 Method Summary 6.1 Methods Soil extraction and quantitative LC/MS/MS analyses were performed using validated method ETS-8-053.0. Initially, a range finding (screening) analysis was conducted on 09-April-2010 to estimate the concentrations of PFOS, PFHS and PFBS in the soils. Those screening results were used for establishing the proper fortification concentrations of LMSs during the definitive analyses. The definitive LC/MS/MS analyses for reporting PFOS, PFHS and PFBS results herein were performed on 21-April2010, 26-April-2010 and 11-May-2010. 6.2 Sample Collection On March 25, 2010, thirty-one empty 250-mL HDPE NalgeneTM sample bottles and three travel blanks (trip blanks) containing approximately 5 to10 grams of a control soil in each, were sent from the 3M Environmental Laboratory to Weston Solutions, Inc. field personnel for collection of FSIA soils from the 3M Decatur, AL facility. Following soil sample collections, the filled sample bottles and two of the travel blanks were returned back to the laboratory for PFOS, PFHS and PFBS analysis. One travel blank was accidentally not returned from the field and is omitted from this report. The soil samples were appropriately shipped in accordance with USDA/APHIS soil permit number P330-09-00125 and received at the laboratory on 01-April-2010. Samples were stored refrigerated until they could be logged into the laboratory's electronic laboratory information management system (LIMS). Sample's logging into LIMS was delayed due to questions regarding the missing trip blank and also due to some additional field-applied labels on the trip blanks which were unexpected at the lab, the questions were addressed and sample's successfully logged in on 05-April-2010. Sample ID nomenclature follows the form DAL DFxx SS SSxx x 00xx where the first string defines Decatur Alabama (DAL) project area, the second string defines sampling area (i.e., DF05 = Field 5), the third string defines the sample media (i.e. SS = soil sample), the fourth string defines specific sampling location, the fifth string defines the sample type (0 = primary sample, 1 = field duplicate, RB = equipment rinseate blank) and the last string defines the sampling depth interval (i.e., 0000 = 0 to 0.5 ft depth and 0010 = 1 to 1.5 ft depth). 6.3 Sample Preparation Once the soil samples were received at the laboratory, they were stored refrigerated until extraction could be performed. Each soil extraction involved removal of a 1 cubic centimeter (1 cc; 1 mL) soil aliquot (typically ~ 1 gram) from each sample bottle using a fixed volume 1 cc spoon, followed by accurate weight determination of the aliquot on a 5-place balance. Then, a known quantity of internal standard (IS; nominal 3.0 ng for each) and surrogate (nominal 3.0 ng) were added to each soil aliquot. 3M Study: GLP10-01-02 Interim Report 01 Page 12 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 For LMS preparations, an additional known quantity of PFOS (linear + branched), PFHS (linear + branched) and PFBS were also added. After fortifications were complete, the soil aliquots were each extracted by addition of 8 mL of a 4:1 acetonitrile:water solution followed by sonication for 1 to 2 hours and then centrifugation to remove solids. The supernatant from each was transferred to an autovial for analysis. An accurately measured volume of each supernatant was analyzed by LC/MS/MS. For this study, a screening analysis of individually prepared extracts for each soil was initially performed to approximate the concentrations of PFOS, PFHS and PFBS in them. Preparation of samples for the screening analysis was performed on 08-April-2010, and the extracts were analyzed on 09-April-2010. The screening results were used to determine the appropriate laboratory matrix spike (LMS) concentrations for the definitive analysis. After the screening analysis was completed, triplicate aliquots of each soil were taken from the bulk samples and extracted for definitive analysis. The third aliquot of each was prepared as a LMS and was fortified with a known quantity of PFOS (linear + branched), PFHS (linear +branched) and PFBS prior to extraction. Fortifications were performed at a level that was appropriate to the endogenous analyte level in the soils (0.5- to 10-times the endogenous analyte level), and based on results determined during the screening analysis. For those samples with PFOS levels above the range of the curve, a separate set of LMSs were prepared for PFOS only, in order to minimize interferences in quantifying PFBS and PFHS in those same samples. Sample preparations for the definitive analyses were performed as two batches, one prepared on 15-April-2010 and the second on 07-May-2010. The first batch was analyzed as analytical runs S100421a and S100426a (diluted samples for PFOS) on 21April-2010 and 26-April-2010, and the second batch ran as J100511a on 11-May-2010. The 11-May2010 analysis was performed as a re-extraction and analysis (re-assay) for select sample results that did not meet the quality control criteria during their earlier analyses. Those re-assay results were reported for those select samples and are identified by footnotes as being re-assay results in Table 14, Table 15 and Table 16. Samples requiring dilution to give a PFOS response within the calibration curve response range were diluted with extracts of method blanks in order to maintain the appropriate IS concentrations in the final extracts. Based on the results from screening analysis, select samples and LMSs were diluted 50-fold and 500-fold to attain PFOS concentrations within the range of the calibration curve. The result from the least diluted sample that was within the range of the curve was reported for each. Laboratory control spike (LCS) samples were prepared with each sample extraction batch, prepared at three levels (3.0, 30 and 300 ng fortifications) and each level prepared in triplicate. One extra set of 300 ng LCSs were prepared and diluted similar to samples to evaluate dilution accuracy. The LCSs were prepared using control soil TCR-842 and were fortified with PFOS (linear), PFHS (linear) and PFBS. A set of calibration standards were prepared by spiking known quantities of PFOS (linear), PFHS (linear) and PFBS, and surrogate (13C4-PFOS) into 1-cubic centimeter (1 cc; equivalent to 1 mL) aliquots of 3M Environmental Laboratory matrix soil TCR-842. The nominal mass of 1 cc of control soil TCR842 is 1.0 gram (dry). Therefore, the range of calibration standards was nominal concentrations 0.200 ng/cc to 500 ng/cc (equivalent to 0.200 ng/mL to 500 ng/mL). When adjusted for the nominal mass of standard soil TCR-842, the nominal calibration standard range was 0.200 ng/g to 500 ng/g. 6.4 Percent Soil Moisture Determination The percent moisture of soils, used to calculate the dry weight of the wet soils weighed during sample preparations for analysis, was determined by gravimetric analysis. Dry weights were determined for separate weighings than the weighings for extract preparations. To determine the percent moisture, duplicate aliquots of each soil sample were removed and the accurate "wet" weight determined for each. Then the aliquots were dried at > 100C until no further mass loss occurred from water evaporation, at which time the accurate dried weights were determined. The difference in mass, attributed to water evaporation, was used to calculate the percent moisture in the original soil. The averaged percent moisture result for each was then used to calculate the soil PFOS, PFHS and PFBS 3M Study: GLP10-01-02 Interim Report 01 Page 13 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 concentrations on a dry weight basis. 6.5 LC/MS/MS Analysis The analysis of soil extracts for PFOS, PFHS and PFBS was performed by liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) as described in method ETS-8053.0. The relative percent difference (RPD) of duplicate sample results was used as a measure of analytical precision. The determined recovery of fortified PFOS (linear + branched), PFHS (linear + branched) and PFBS from LMS samples was used as a measure of analytical accuracy. Recovery of the surrogate (13C4-PFOS) is included within this report in Table 14, and is also part of an on-going method validation aspect in which surrogate recovery is being evaluated in real environmental samples. Details of the specific instrument parameters, the liquid chromatography gradient program, and the specific mass transitions analyzed are detailed in the raw data, and are briefly described below in Table 4, Table 5 and Table 6. Screening analysis was performed as analytical run s100409c on 09-April-2010 and is not reported herein, but the raw data is included in Attachment A. The definitive results reported herein were acquired as analytical runs S100421a, S100426a (diluted samples for PFOS results) and J100511a (re assay results). Table 4. Instrument Information Instrument Name A n a lytica l M ethod ID Liquid C hrom atograph Pre-sam pler column Analytical guard column Analytical column Injection Volum e Mass Spectrom eter Ion S ource P o la rity Software ETS-Stan E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 u) O asis HLB (3 x 20 mm, 5 u); 30C Betasil-C 18 (2.1 x 100 mm, 5 u); 30C 25 uL API 4000 Turbolon Spray N e g a tiv e A nalyst 1.4.2 ETS-Jonas E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 u) O asis HLB (3 x 20 mm, 5 u); 30C Betasil-C 18 (2.1 x 100 mm, 5 u); 30C 25 uL API 5000 TurboIon Spray N e g a tiv e A nalyst 1.4.2 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053) Step Num ber Total Time [m in] 1 0.0 2 3.0 3 3.5 4 17.0 5 17.5 6 19.5 7 20.0 Flow Rate [m L/m in] 0.400 0.400 0.400 0.400 0.400 0.400 0.400 Percent A [2 mm Aqueous A m m onium Acetate] 97.0 97.0 70.0 40.0 10.0 10.0 97.0 Percent B [ M ethanol] 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3M Study: GLP10-01-02 Interim Report 01 Page 14 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 8 23.0 0.400 97.0 Table 6. Mass Transitions A n a ly te Mass Transitions M onitored PFBS 299>99, 299>80 18O 2-P F B S (IS ) 303>84 PFHS 399>99, 399>80 18O 2-P F H S (IS ) 403>84 PFOS 499>130, 499>99, 499>80 13C 8- P F O S (IS ) 507>80 13C 4- P F O S ( S u r r o g a te ) 503>80 N ote: M ultiple m ass transitions are sum m ed to give the instrum ent response fo r that analyte. 3.0 7 Analytical Results All results are rounded to three significant figures according to EPA rounding rules. Because of rounding, values may vary slightly from those found in the raw data. Laboratory matrix spikes (LMS) meeting the method acceptance criteria of 100 30%, demonstrate that the method was appropriate. The spiked concentrations were adequate for the given matrix and their respective quantitative ranges of PFOS, PFHS and PFBS measured in the FSIA soils. A few results with matrix spikes within 100 + 50%, but outside of 100+ 30% were reported and footnoted in the data tables. 7.1 Calibration A set of calibration standards were prepared by spiking varying known quantities of PFOS (linear), PFHS (linear), PFBS and surrogate (13C4-PFOS), and a fixed quantity of stable isotope labeled internal standards, into one cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmental Laboratory control soil TCR-842 (nominal soil mass of 1.0 g/mL). A total of twelve (12) calibration standards were prepared as a set. The standards ranged from nominal concentration 0.200 ng/mL to 500 ng/mL (0.200 ng/g to 500 ng/g). Following analysis of calibration standards, the nominal concentration of each standard was plotted against the measured analyte /IS peak area ratio. A quadratic equation with 1/x weighting was used to fit the data. Calibration curves were not forced through zero. Determining the standard concentration using the resultant calibration curve and comparing to the known concentration confirmed accuracy of each curve point to within the acceptance criteria of 100 30% (+ 35% at the LLOQ). The correlation coefficient (r) was greater than 0.999 for all calibration curves, and the coefficient of determination (r2) was greater than 0.990. Calibration results for PFOS, PFHS and PFBS are summarized in Table 7, Table 8 and Table 9, respectively. Because soil weights can vary significantly for a 1 cc (1 mL) field sample, depending on soil type and moisture content, the instrument response was calibrated for the known concentrations of target analytes based on the mass quantity of each added to a 1 cc soil ( 1 mL) calibration standard prior to extraction (e.g. calibrated in this study for a range of 0.200 ng/mL to 200 ng/mL PFOS, PFHS and PFBS). Because a 1cc aliquot of control soil TCR-842 weighs nominally 1.0 gram (dry weight) and has less than 5% moisture content, the nominal concentration range of the calibration was essentially 0.200 ng/g to 500 ng/g. However, because the FSIA soil aliquots typically weigh more than 1.0 gram and contain significant moisture, the determined concentrations during the analysis on a ng/mL basis from the calibration curve were adjusted for the accurate determined weight and percent moisture so they could be reported on a ng/g (dry weight) basis. 3M Study: GLP10-01-02 Interim Report 01 Page 15 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 7. PFOS Calibration Summary Analytical Run A ctu a l S100421a S100426a J100511a A ve ra g e Std. D eviation RSD(% ) Avg. Recovery (%) n STD 1 0 .2 0 0 0.193 excluded 0.200 0.198 N/A N /A STD 2 0 .5 0 0 0.513 0.482 0.487 0.496 0.017 3.4% 98.8% 2 99.1% 3 STD 3 0 .7 5 0 0.792 0.675 -/821 0.739 0.083 11.2% 98.5% 3 STD 4 1.00 0.921 0.978 0.984 0.971 0.035 3.6% 97.1% 3 STD 5 2 .5 0 2.60 2.65 2.51 2.57 0.071 2.8% 103% 3 PFOS (ng/mL) STD STD STD 6 78 5 .0 0 10.0 25.0 5.15 9.88 24.9 5.31 10.3 26.1 5.08 10.0 25.8 5.14 0.12 2.3% 10.0 0.22 2.2% 25.5 0.62 2.5% 103% 3 100% 3 102% 3 STD 9 5 0 .0 49.5 49.2 51.2 50.0 1.1 2.2% 100% 3 STD 10 100 97.0 96.2 104 99.3 4.3 4.3% 99% 3 STD 11 200 205 203 190 200 8.1 4.1% 99.8% 3 STD 12 500 499 499 505 501 3.5 0.69% 100% 3 r NA 0.9999 0.9998 0.9996 0.9998 0.00015 0.015% N/A 3 Table 8. PFHS Calibration Summary Analytical Run A ctu a l S100421a S100426a J100511a A ve ra g e Std. D eviation R S D (%) Avg. Recovery (%) n STD 1 0 .2 0 0 0.202 0.203 0.172 0.194 0.018 9.1% STD 2 0 .5 0 0 0.497 0.506 0.477 0.495 0.015 3.0% 97.1% 3 99.0% 3 STD 3 0 .7 5 0 0.763 0.751 0.721 0.746 0.022 2.9% 99.5% 3 STD 4 1.00 0.939 0.952 1.02 0.978 0.044 4.4% 97.8% 3 STD 5 2 .5 0 2.62 2.66 2.74 2.63 0.061 2.3% 105% 3 PFHS (ng/mL) STD STD STD 6 78 5 .0 0 10.0 25.0 4.85 10.1 25.3 5.01 9.79 24.5 5.32 10.1 25.7 5.05 0.24 4.7% 10.0 0.18 1.8% 25.1 0.61 2.4% STD 9 5 0 .0 49.2 49.5 48.8 49.4 0.35 0.71% 101% 3 100% 3 101% 3 98.8% 3 STD 10 100 98.8 96.6 106 100.4 4.9 4.9% 100% 3 STD 11 200 202 206 189 199 8.9 4.5% 99.6% 3 STD 12 500 498 497 505 500 4.4 0.87% 100% 3 r NA 1.0000 0.9998 0.9993 0.9997 0.00036 0.036% N/A 3 Table 9. PFBS Calibration Summary Analytical Run A ctu a l S100421a S100426a J100511a A ve ra g e Std. D eviation R S D (%) Avg. Recovery (%) n STD 1 0 .2 0 0 0.209 0.218 0.156 0.196 0.034 17% STD 2 0 .5 0 0 0.503 0.479 0.487 0.492 0.012 2.5% STD 3 0 .7 5 0 0.740 0.739 0.733 0.741 0.0038 0.51% STD 4 1.00 0.958 0.939 1.01 0.977 0.037 3.8% 97.9% 3 98.5% 3 98.7% 3 97.7% 3 STD 5 2 .5 0 2.52 2.59 2.66 2.57 0.070 2.7% PFBS (ng/mL) STD STD STD 678 5 .0 0 10.0 2 5 .0 4.85 9.95 25.0 4.82 9.71 25.5 5.32 10.3 26.4 5.00 0.28 5.6% 10.0 0.30 3.0% 25.5 0.71 2.8% STD 9 5 0 .0 50.5 50.6 52.2 50.8 1.0 1.9% 103% 3 100% 3 99.9% 3 102% 3 102% 3 STD 10 100 97.6 09/7 98.5 98.7 0.55 0.6% 98.7% 3 STD 11 200 201 199 192 198 4.7 2.4% 99.0% 3 STD 12 500 498 498 504 500 3.5 0.69% r NA 1.0000 1.0000 0.9996 0.9999 0.00023 0.023% 100% 3 N/A 3 3M Study: GLP10-01-02 Interim Report 01 Page 16 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 7.2 Limits of Quantitation (LOQs) The lower limit of quantitation (LLOQ) is the lowest non-zero calibration standard in the curve that met linearity and accuracy requirements (100 + 35%) and for which the area counts were at least 2X that of the average response determined from the method blanks. The LLOQ for this study was the nominal 0.200 ng/g standard for PFBS, PFHS and PFOS, except in run S100426a where the LLOQ for PFOS was raised to 0.500 ng/g. Each sample that gave an analyte response less than the response of the LLOQ calibration standard was reported as BLQ (below the limit of quantitation). The upper limit of quantitation (ULOQ) was nominal concentration 500 ng/g, and samples with endogenous analyte levels at greater than the ULOQ were appropriately diluted to achieve analyte results within the curve range. PFOS was the only analyte requiring dilution for this analysis. 7.3 Continuing Calibration During the course of each analysis, continuing calibration verifications (CCVs) was performed by injection of a mid-level calibration standard to confirm that the instrument response and the initial calibration curve were still in control. All CCVs flanking reported data met the method criteria of 100% 30% (+ 35% at LLOQ). 7.4 Blanks Four types of blanks were analyzed during this analysis, and included the following: three method blanks were prepared with blank matrix soil TCR-842 and were spiked with IS, three method blanks without IS were prepared, two travel blanks prepared from aliquots of the travel blanks that accompanied the sample shipment, and several solvent blanks containing extraction solvent. The different blanks results are reviewed to evaluate potential contamination during shipment and sampling, to evaluate method performance parameters such as injector carry over and also to establish the LLOQ. In addition to the aforementioned blanks, two aqueous equipment rinseate `blank' samples were received with the soils, and were analyzed by a sensitive water analysis LC/MS/MS method. The results for those rinseate sample analyses showed they were less than 0.0255 ng/mL PFBS, less than 0.0258 ng/mL PFHS and less than 0.510 ng/mL PFOS as reported in GLP10-01-02 interim report 02. 7.5 Laboratory Control Spikes (LCSs) Laboratory control spikes were prepared by spiking know quantities of PFOS (linear), PFHS (linear) and PFBS into 1 cc aliquots of soil TCR-842, fortified with nominal 3.0 ng, 30 ng and 300 ng, each level prepared in triplicate. An additional triplicate set of 300 ng LCS was prepared and then diluted 50-fold as a measure of dilution accuracy for the extraction batch on 15-April-2010, but was not included for the extraction batch on 07-May-2010. The results of the LCS analyses and calculation of analyte measurement accuracies (percent recovery) for PFOS, PFHS and PFBS are shown in Table 10, Table 11 and Table 12, respectively. The LCS recoveries were calculated using the following equation: LCS Recovery = -(-D--e-t-e--r-m--i-n-e--d--C--o--n-c--e-n-t-r-a--t-io--n--o--f--L--C--S-)- *, 100% Spike Concentration 3M Study: GLP10-01-02 Interim Report 01 Page 17 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 10. LCS Results (PFOS) Sample ID Actual Conc. (ng/g) LCS 1 (run s100421a/26a) LCS 2 (run s100421a/26a) LCS 3 (run s100421a/26a) LCS 1 (run j100511a) LCS 2 (run j100511a) LCS 3 (run j100511a) Average Standard Deviation Relative Std. Dev. Average LCS Recovery 3.0 ng LCS 3.00 2.98 2.96 3.15 3.40 3.41 3.42 3.22 0.22 6.8% 107% Measured PFOS (ng) 30 ng LCS 300 ng LCS 30.0 30.2 30.1 30.5 33.0 33.1 33.1 31.7 1.5 4.9% 106% 300 329 319 326 354 384 379 349 28 8.1% 116% 300 ng LCS (50 fold dilution) 300 300 300 294 LCS not included LCS not included LCS not included 298 3.5 1.2% 99.3% Table 11. LCS Results (PFHS) Sample ID Actual Conc. (ng/g) LCS 1 (run s100421a/26a) LCS 2 (run s100421a/26a) LCS 3 (run s100421a/26a) LCS 1 (run j100511a) LCS 2 (run j100511a) LCS 3 (run j100511a) Average Standard Deviation Relative Std. Dev. Average LCS Recovery 3.0 ng LCS 3.03 3.21 3.17 3.05 3.30 3.29 3.28 3.22 0.096 3.0% 106% Measured PFHS (ng) 30 ng LCS 300 ng LCS 30.3 31.0 31.3 30.9 31.1 32.0 31.8 31.4 0.45 1.4% 103% 303 317 321 324 334 341 347 331 12 3.6% 109% 300 ng LCS (50 fold dilution) 303 307 312 311 LCS not included LCS not included LCS not included 310 2.6 0.85% 102% Table 12. LCS Results (PFBS) Sample ID 3.0 ng LCS Actual Conc. (ng/g) LCS 1 (run s100421a/26a) LCS 2 (run s100421a/26a) LCS 3 (run s100421a/26a) LCS 1 (run j100511a) LCS 2 (run j100511a) LCS 3 (run j100511a) Average Standard Deviation Relative Std. Dev. Average LCS Recovery 2.99 3.17 3.05 3.08 3.20 3.12 3.03 3.11 0.067 2.2% 104% Measured PFBS (ng) 30 ng LCS 300 ng LCS 29.9 30.2 31.6 29.0 30.7 30.9 30.2 30.4 0.87 2.9% 102% 299 288 287 290 284 298 291 290 4.8 1.6% 96.9% 300 ng LCS (50 fold dilution) 299 297 303 306 LCS not included LCS not included LCS not included 302 4.6 1.52% 101% 3M Study: GLP10-01-02 Interim Report 01 Page 18 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 7.6 Laboratory Matrix Spikes (LMSs) Laboratory matrix spikes (LMSs) were generated by adding a known quantity of PFOS (linear + branched), PFHS (linear + branched) and PFBS to an aliquot of soil collected from the field, and then preparing the sample the same as non-spiked samples. For this study, LMSs were spiked at levels that were appropriate for the endogenous analyte levels in the soils, determined from screening analysis. The LMS method acceptance criteria of 100 30% was met for all reported results, with few exceptions as noted in results tables, and all met protocol defined reportability criteria of 100 + 50%. The LMS recovery results are summarized in Table 2, and individual sample results for PFOS, PFHS and PFBS are shown in Table 14, Table 15 and Table 16, respectively. The PFOS, PFHS and PFBS recovery calculations for LMSs used the following equation: TLM,, ,,S ,,Recovery = -(-D--e-t-e-r-m---i-n-e--d--C--o--n-c-e--n-t-r-a--t-io--n--o--f--L--M--S------D--e--te--r-m--i-n--e-d--C---o-n--c-e-n--t-r-a-t-i-o-n---o-f--F--i-e-l-d--S--a-m--p--le) *.,100%. Spike Concentration 7.7 Percent Soil Moisture Determinations The percent moisture was determined in duplicate for each soil sample. A sample aliquot of each is accurately weighed to determine the "wet" weight. Then the aliquot is dried at > 100C until no further loss in mass occurs (due to water evaporation), and then the dry weight is accurately determined. The average percent moisture and RPD of the duplicate determinations for each soil is reported in Table 13. The percent moisture was calculated by the following equation: ,,Percent ,,M,oi.sture = -(--Orig- -in--a-l--S-o--i-l-W---e--t-M---a-s--s-----D--r-i-e--d--S-o--i-l-M---a-s-s-)- _* 100% Original Soil Wet Mass 3M Study: GLP10-01-02 Interim Report 01 Page 19 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 13. Percent Moisture Results for Decatur FSIA Soils (March/April 2010) Sample ID DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0010 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0010 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0010 Soil Trip Blank 1 Soil Trip Blank 3 Average Percent Moisture (%; w/w) 13.7 16.5 16.4 16.2 20.3 15.4 17.0 16.0 18.3 14.5 19.1 14.7 17.3 15.1 18.5 14.0 13.1 13.1 17.5 18.5 17.5 19.4 14.0 14.2 13.2 12.8 16.5 15.7 13.6 3.55 3.54 Relative Percent Difference (%) 4.9 2.8 0.45 4.4 0.94 1.5 2.7 6.2 1.2 3.9 1.7 2.5 0.82 0.23 1.4 0.66 0.43 1.7 0.59 3.0 6.4 1.7 3.2 13 3.1 5.0 3.4 5.7 4.9 6.0 3.5 3M Study: GLP10-01-02 Interim Report 01 Page 20 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 7.8 Individual Sample Results Table 14. Individual PFOS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-001 G LP 10-01-01-01-001 Dup G LP 10-01-01-01-001 LMS G LP 10-01-01-01-002 G LP 10-01-01-01-002 Dup G LP 10-01-01-01-002 LMS G LP 10-01-01-01-003 G LP 10-01-01-01-003 Dup G LP 10-01-01-01-003 LMS G LP 10-01-01-01-004 G LP 10-01-01-01-004 Dup G LP 10-01-01-01-004 LMS G LP 10-01-01-01-005 G LP 10-01-01-01-005 Dup G LP 10-01-01-01-005 LMS G LP 10-01-01-01-007 G LP 10-01-01-01-007 Dup G LP 10-01-01-01-007 LMS G LP 10-01-01-01-008 G LP 10-01-01-01-008 Dup G LP 10-01-01-01-008 LMS G LP 10-01-01-01-009 G LP 10-01-01-01-009 Dup G LP 10-01-01-01-009 LMS G LP 10-01-01-01-010 G LP 10-01-01-01-010 Dup G LP 10-01-01-01-010 LMS G LP 10-01-01-01-011 G LP 10-01-01-01-011 Dup G LP 10-01-01-01-011 LMS G LP 10-01-01-01-012 G LP 10-01-01-01-012 Dup G LP 10-01-01-01-012 LMS G LP 10-01-01-01-013 G LP 10-01-01-01-013 Dup G LP 10-01-01-01-013 LMS G LP 10-01-01-01-014 G LP 10-01-01-01-014 Dup G LP 10-01-01-01-014 LMS G LP 10-01-01-01-015 G LP 10-01-01-01-015 Dup G LP 10-01-01-01-015 LMS G LP 10-01-01-01-016 G LP 10-01-01-01-016 Dup S a m p le D e scrip tio n DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 S u rro g a te (13C 4 PFOS) R e co ve ry [d] 99.3% 103% 95.7% 98.0% 87.0% 98.0% 103% 97.0% 106% 112% 96.7% 95.3% 110% 103% 103% 102% 105% 106% 100% 100% 106% 97.3% 99.7% 98.3% 97.7% 102% 92.3% 97.0% 106% 119% [e] 108% 109% 102% 105% 100% 104% 106% 97.7% 105% 101% 102% 105% 104% 98.7% A c tu a l LMS S p ik e Conc. (ng/g; dry w e ig h t) N/A 61.7 N/A 65.2 N/A 79.6 N/A 100 N/A 4.7 N/A 106 N/A 70.0 N/A 1034 N/A 83.6 N/A 994 N/A 1039 N/A 609 N/A 715 N/A 751 N/A M easured PFOS C o n c e n tra tio n (ng/g; dry w e ig h t) 34.1 37.5 97.9 52.6 44.2 130 40.4 43.8 117 50.4 48.4 151 3.24 6.24 11.1 94.0 108 228 59.0 60.6 115 419 401 1410 105 71.4 190 823 1330 1700 227 247 1110 148 170 623 375 338 962 122 119 818 93.2 90.4 RPD / LMS R e covery [a] 10% 101% 17% 125% 8.1% 94.7% 4.0% 101% 63.3% 139% 14.0% 120% 2.8% 78.2% 4.4% 96.9% 38% 121% 47% 63.1% 8.2% 84.1% 13% 76.3% 10% 84.7% 1.8% 92.9% 3.0% Average PFOS Concentration (ng/g; dry wt.) 35.8 N/A 48.4 N/A 42.1 N/A 49.4 N/A 4.74 [b,c,f] N/A 101 [c] N/A 59.8 N/A 410 N/A 88.4 N/A 1080 N/A 237 N/A 159 N/A 356 N/A 121 N/A 91.8 3M Study: GLP10-01-02 Interim Report 01 Page 21 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 14. Individual PFOS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-016 LMS G LP 10-01-01-01-017 G LP 10-01-01-01-017 Dup G LP 10-01-01-01-017 LMS G LP 10-01-01-01-018 G LP 10-01-01-01-018 Dup G LP 10-01-01-01-018 LMS G LP 10-01-01-01-019 G LP 10-01-01-01-019 Dup G LP 10-01-01-01-019 LMS G LP 10-01-01-01-020 G LP 10-01-01-01-020 Dup G LP 10-01-01-01-020 LMS G LP 10-01-01-01-021 G LP 10-01-01-01-021 Dup G LP 10-01-01-01-021 LMS G LP 10-01-01-01-022 G LP 10-01-01-01-022 Dup G LP 10-01-01-01-022 LMS G LP 10-01-01-01-023 G LP 10-01-01-01-023 Dup G LP 10-01-01-01-023 LMS G LP 10-01-01-01-024 G LP 10-01-01-01-024 Dup G LP 10-01-01-01-024 LMS G LP 10-01-01-01-025 G LP 10-01-01-01-025 Dup G LP 10-01-01-01-025 LMS G LP 10-01-01-01-026 G LP 10-01-01-01-026 Dup G LP 10-01-01-01-026 LMS G LP 10-01-01-01-027 G LP 10-01-01-01-027 Dup G LP 10-01-01-01-027 LMS G LP 10-01-01-01-028 G LP 10-01-01-01-028 Dup G LP 10-01-01-01-028 LMS G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 [c] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 D up [c] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 LM S [c] G LP 10-01-01-01-030 G LP 10-01-01-01-030 Dup G LP 10-01-01-01-030 LMS G LP 10-01-01-01-033 G LP 10-01-01-01-033 Dup G LP 10-01-01-01-033 LMS S a m p le D e scrip tio n DAL DF8C SS SS02 0 0010 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 DAL DF11 SS S S05 0 0000 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 DAL DF11 SS S S07 0 0000 DAL DF11 SS S S07 0 0000 DAL DF11 SS S S07 0 0000 DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 S oil T rip B la n k 1 S oil T rip B la n k 1 S oil T rip B la n k 1 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 101% 109% 109% 159% [e] 113% 107% 139% [e] 110% 103% 145% [e] 96.3% 97.3% 107% 99.7% 96.7% 103% 98.0% 96.0% 107% 102% 104% 145% [e] 96.0% 101% 104% 99.3% 106% 147% [e] 102% 114% 146% [e] 112% 110% 148% [e] 99.3% 106% 147% [e] ND [e] ND [e] ND [e] 133% [e] 134% [e] 179% [e] 97.7% 106% 98.7% A c tu a l LMS S p ik e Conc. (ng/g; dry w e ig h t) 126 N/A 6341 N/A 7641 N/A 9758 N/A 902 N/A 687 N/A 755 N/A 8021 N/A 7163 N/A 6800 N/A 8075 N/A 7119 N/A 621 N /A 27497 N/A 7580 N/A 0.946 M easured PFOS C o n c e n tra tio n (ng/g; dry w e ig h t) 234 844 905 6490 1580 1530 8130 1650 1410 10500 237 248 1037 286 318 859 281 271 792 512 504 7050 1890 1110 7840 746 1530 6730 1270 1450 7700 1050 1060 6360 658 660 1490 17700 20100 43300 4620 5300 10200 BLQ BLQ 0.949 RPD / LMS R e covery [a] Average PFOS Concentration (ng/g; dry wt.) 113% 7.0% 88.6% 3.2% 86.1% 16% 91.7% 4.6% 88.1% 11% 81.0% 3.6% 68.3% 1.6% 81.5% 52% 88.4% 69% 82.2% 12.6% 78.5% 1.5% 74.5% 0.30% 133% 13% 88.9% 14% 6 N /A 100% N/A 874 N/A 1550 N/A 1530 N/A 242 N/A 302 N/A 276 N/A 508 N/A 1500 [b] N/A 1140 [b] N/A 1360 N/A 1050 N/A 659 [f] N/A 18900 [c] N/A 4960 N/A BLQ N/A 3M Study: GLP10-01-02 Interim Report 01 Page 22 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 14. Individual PFOS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID S a m p le D e scrip tio n S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] A c tu a l LMS S p ik e Conc. (ng/g; dry w e ig h t) M easured PFOS C o n c e n tra tio n (ng/g; dry w e ig h t) RPD / LMS R e covery [a] Average PFOS Concentration (ng/g; dry wt.) G LP 10-01-01-01-034 G LP 10-01-01-01-034 Dup S oil T rip B la n k 3 S oil T rip B la n k 3 98.0% BLQ N/A N/A BLQ 93.0% BLQ G LP 10-01-01-01-034 LMS S oil T rip B la n k 3 103% 0.970 0.959 98.8% N/A [a] LM S s p repared using P F O S (lin e a r + branche d isom e rs), but q u a n tifie d o ff o f a P FO S (lin e a r isom e r) calibration . [b] R P D w a s g re a te r tha n 50% . [c] T he va lu e re ported w a s d e te rm in e d from a re-assay. [d ]S u rro g a te re c o v e ry d e te rm in e d fo r s a m p le s fo r tifie d w ith 2 .9 9 n g o f C 4-P F O S a n d q u a n tifie d fro m a C 4-P F O S c a lib r a tio n c u r v e . [e] S u rro g a te re co ve ry a p p e a re d a ffe cte d by high P FO S c o n ce n tra tio n w h ich re q u ire d d ilu tio n o f th e sa m p le and d ilu te d the su rro g a te . [f] LM S re co ve ry w a s o u tsid e o f m e th o d crite ria o f 100 + 30% , but w ith in p ro to co l re p o rtin g c rite ria o f 100 + 50% . ND; not d e te rm in e d b e ca u se d ilu tio n o f th e sa m p le g a ve a B LQ re su lt fo r the su rro g a te . Table 15. Individual PFHS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-001 G LP 10-01-01-01-001 Dup G LP 10-01-01-01-001 LMS G LP 10-01-01-01-002 G LP 10-01-01-01-002 Dup G LP 10-01-01-01-002 LMS G LP 10-01-01-01-003 G LP 10-01-01-01-003 Dup G LP 10-01-01-01-003 LMS G LP 10-01-01-01-004 G LP 10-01-01-01-004 Dup G LP 10-01-01-01-004 LMS G LP 10-01-01-01-005 G LP 10-01-01-01-005 Dup G LP 10-01-01-01-005 LMS G LP 10-01-01-01-007 G LP 10-01-01-01-007 Dup G LP 10-01-01-01-007 LMS G LP 10-01-01-01-008 G LP 10-01-01-01-008 Dup G LP 10-01-01-01-008 LMS G LP 10-01-01-01-009 G LP 10-01-01-01-009 Dup G LP 10-01-01-01-009 LMS G LP 10-01-01-01-010 G LP 10-01-01-01-010 Dup G LP 10-01-01-01-010 LMS G LP 10-01-01-01-011 G LP 10-01-01-01-011 Dup S am p le D escrip tion DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 99.3% 103% 95.7% 98.0% 87.0% 98.0% 103% 97.0% 106% 112% 96.7% 95.3% 103% 91.3% 102% 96.0% 96.0% 106% 100% 100% 106% 97.3% 99.7% 98.3% 97.7% 102% 92.3% 97.0% 106% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) N /A 0.613 N /A 0.648 N /A 0.791 N /A 0.995 N /A 1.15 N /A 0.621 N /A 0.696 N /A 1.03 N /A 0.831 N /A M easured PFHS C o n c e n tra tio n (n g/g; dry w e ig h t) 0.143 0.179 0.787 BLQ BLQ 0.740 BLQ BLQ 0.847 0.342 0.373 1.31 0.694 0.240 1.42 0.159 0.152 0.803 BLQ BLQ 0.780 0.302 0.264 1.48 0.164 BLQ 0.999 1.48 2.85 RPD / LM S R ecovery [a ] A vera ge P FH S C o n c e n tra tio n (n g/g; d ry w t.) 22% 102% N /A 114% NA 107% 8.5% 95.4% 97% 83.5% 4.4% 104% N /A 112% 14% 117% N /A 101% 63% 0.161 N /A BLQ N /A BLQ N /A 0.357 N /A 0.467 [b] N /A 0.156 N /A BLQ N /A 0.283 N /A 0.164 [c] N /A 2.16 [b] 3M Study: GLP10-01-02 Interim Report 01 Page 23 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 15. Individual PFHS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-011 LMS G LP 10-01-01-01-012 G LP 10-01-01-01-012 Dup G LP 10-01-01-01-012 LMS G LP 10-01-01-01-013 G LP 10-01-01-01-013 Dup G LP 10-01-01-01-013 LMS G LP 10-01-01-01-014 G LP 10-01-01-01-014 Dup G LP 10-01-01-01-014 LMS G LP 10-01-01-01-015 G LP 10-01-01-01-015 Dup G LP 10-01-01-01-015 LMS G LP 10-01-01-01-016 G LP 10-01-01-01-016 Dup G LP 10-01-01-01-016 LMS G LP 10-01-01-01-017 G LP 10-01-01-01-017 Dup G LP 10-01-01-01-017 LMS G LP 10-01-01-01-018 G LP 10-01-01-01-018 Dup G LP 10-01-01-01-018 LMS G LP 10-01-01-01-019 G LP 10-01-01-01-019 Dup G LP 10-01-01-01-019 LMS G LP 10-01-01-01-020 G LP 10-01-01-01-020 Dup G LP 10-01-01-01-020 LMS G LP 10-01-01-01-021 G LP 10-01-01-01-021 Dup G LP 10-01-01-01-021 LMS G LP 10-01-01-01-022 G LP 10-01-01-01-022 Dup G LP 10-01-01-01-022 LMS G LP 10-01-01-01-023 G LP 10-01-01-01-023 Dup G LP 10-01-01-01-023 LMS G LP 10-01-01-01-024 G LP 10-01-01-01-024 Dup G LP 10-01-01-01-024 LMS G LP 10-01-01-01-025 G LP 10-01-01-01-025 Dup G LP 10-01-01-01-025 LMS G LP 10-01-01-01-026 G LP 10-01-01-01-026 Dup G LP 10-01-01-01-026 LMS G LP 10-01-01-01-027 S am p le D escrip tion DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS06 0 0000 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 119% [e] 108% 109% 102% 105% 100% 104% 106% 97.7% 105% 101% 102% 105% 104% 98.7% 101% 109% 109% 159% [e] 113% 107% 139% [e] 110% 103% 145% [e] 96.3% 97.3% 107% 99.7% 96.7% 103% 98.0% 96.0% 107% 102% 104% 145% [e] 96.0% 101% 104% 99.3% 106% 147% [e] 102% 114% 146% [e] 112% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) 9.88 N /A 10.3 N /A 0.605 N /A 7.11 N /A 0.746 N /A 1.25 N /A 63.0 N /A 75.9 N /A 97.0 N /A 0.897 N /A 0.683 N /A 7.50 N /A 79.7 N /A 6.98 N /A 6.76 N /A 8.03 N /A M easured PFHS C o n c e n tra tio n (n g/g; dry w e ig h t) 11.2 1.11 1.44 10.9 0.633 0.728 1.25 1.41 1.36 7.82 0.610 0.516 1.36 0.326 0.364 1.64 11.5 10.9 70.7 10.4 10.4 87.5 10.6 10.4 108 BLQ 0.290 1.17 0.334 0.332 0.966 1.57 1.39 8.94 26.9 27.2 108 10.1 9.80 17.9 2.40 4.03 8.74 2.87 3.09 9.89 4.50 RPD / LM S R ecovery [a ] A vera ge P FH S C o n c e n tra tio n (n g/g; d ry w t.) 91.2% 26% 93.7% 14% 94.5% 3.6% 90.6% 17% 107% 11% 104% 5.0% 94.4% 0.28% 101% 1.7% 100% N /A 98.0% 0.53% 92.6% 12% 100% 1.1% 101% 3.5% 114% 51% 81.7% 7.2% 86.1% 5.1% N /A 1.27 N /A 0.681 N /A 1.39 N /A 0.563 N /A 0.345 N /A 11.2 N /A 10.4 N /A 10.5 N /A 0.290 [a] N /A 0.333 N /A 1.48 N /A 27.1 N /A 10.0 [f] N /A 3.21 [b] N /A 2.98 N /A 4.62 3M Study: GLP10-01-02 Interim Report 01 Page 24 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 15. Individual PFHS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-027 Dup G LP 10-01-01-01-027 LMS G LP 10-01-01-01-028 G LP 10-01-01-01-028 Dup G LP 10-01-01-01-028 LMS G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 [c] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 D up [c] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 LM S [c] G LP 10-01-01-01-030 G LP 10-01-01-01-030 Dup G LP 10-01-01-01-030 LMS G LP 10-01-01-01-033 G LP 10-01-01-01-033 Dup S am p le D escrip tion DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 S oil T rip B la n k 1 S oil T rip B lank 1 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 110% 148% [e] 104% 106% 119% 370% [e] 643% [e] 1010% [e] 133% [e] 134% [e] 179% [e] 97.7% 106% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) 7.08 N /A 6.17 N /A 83.5 N /A 7.53 N /A M easured PFHS C o n c e n tra tio n (n g/g; dry w e ig h t) 4.73 9.86 1.92 2.10 8.16 78.7 95.0 157 1.89 2.01 9.66 BLQ BLQ RPD / LM S R ecovery [a ] A vera ge P FH S C o n c e n tra tio n (n g/g; d ry w t.) 74.1% 8.7% 99.7% 19% 83.9% 6.2% 102% N /A N /A 2.01 N /A 86.8 N /A 1.95 N /A BLQ G LP 10-01-01-01-033 LMS S oil T rip B la n k 1 98.7% 0.940 0.934 99.4% N /A G LP 10-01-01-01-034 G LP 10-01-01-01-034 Dup S oil T rip B la n k 3 S oil T rip B lank 3 98.0% BLQ N /A N /A BLQ 93.0% BLQ G LP 10-01-01-01-034 LMS S oil T rip B la n k 3 103% 0.964 0.950 98.5% N /A [a] L M S s p re p a re d using P F H S (lin e a r + b ra n ch e d isom e rs), but q u a n tifie d o ff o f a P F H S (lin e a r iso m e r) ca lib ra tio n . [b] R P D w a s g re a te r th a n 50% . [c] V a lu e re p o rte d fro m on e result, the d u p lic a te re su lt w a s BLQ . [d ]S u rr o g a te re c o v e ry d e te rm in e d fo r s a m p le s fo rtifie d w ith 2 .9 9 n g o f 13C 4-P F O S a n d q u a n tifie d fro m a 13C 4-P F O S c a lib r a tio n c u rv e . [e] S u rro g a te re co ve ry a p p e a re d a ffe cte d by high P F O S co n c e n tra tio n , w h ic h re q u ire d d ilu tio n o f th e sa m p le and th u s d ilu tio n o f th e s u rro g a te . [f] T h e v a lu e r e p o rte d w a s d e te rm in e d fro m a re -a s s a y .______________________________________________________________________________________________ Table 16. Individual PFBS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-001 G LP 10-01-01-01-001 Dup G LP 10-01-01-01-001 LMS G LP 10-01-01-01-002 G LP 10-01-01-01-002 Dup G LP 10-01-01-01-002 LMS G LP 10-01-01-01-003 G LP 10-01-01-01-003 Dup G LP 10-01-01-01-003 LMS G LP 10-01-01-01-004 G LP 10-01-01-01-004 Dup G LP 10-01-01-01-004 LMS G LP 10-01-01-01-005 G LP 10-01-01-01-005 Dup G LP 10-01-01-01-005 LMS S am p le D escrip tion DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 99.3% 103% 95.7% 98.0% 87.0% 98.0% 103% 97.0% 106% 112% 96.7% 95.3% 103% 91.3% 102% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) N /A 0.614 N /A 0.649 N /A 0.792 N /A 0.996 N /A 1.15 M easured PFBS C o n c e n tra tio n (n g/g; dry w e ig h t) 0.169 0.205 0.836 BLQ BLQ 0.740 BLQ BLQ 0.831 BLQ BLQ 1.07 BLQ BLQ 1.17 RPD / LM S R ecovery [a ] A vera ge PFBS C o n c e n tra tio n (n g/g; d ry w t.) 20% 106% N /A 114% N /A 105% N /A 107% N /A 102% 0.187 N /A BLQ N /A BLQ N /A BLQ N /A BLQ N /A 3M Study: GLP10-01-02 Interim Report 01 Page 25 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 16. Individual PFBS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-007 G LP 10-01-01-01-007 Dup G LP 10-01-01-01-007 LMS G LP 10-01-01-01-008 G LP 10-01-01-01-008 Dup G LP 10-01-01-01-008 LMS G LP 10-01-01-01-009 G LP 10-01-01-01-009 Dup G LP 10-01-01-01-009 LMS G LP 10-01-01-01-010 G LP 10-01-01-01-010 Dup G LP 10-01-01-01-010 LMS G LP 10-01-01-01-011 G LP 10-01-01-01-011 Dup G LP 10-01-01-01-011 LMS G LP 10-01-01-01-012 G LP 10-01-01-01-012 Dup G LP 10-01-01-01-012 LMS G LP 10-01-01-01-013 G LP 10-01-01-01-013 Dup G LP 10-01-01-01-013 LMS G LP 10-01-01-01-014 G LP 10-01-01-01-014 Dup G LP 10-01-01-01-014 LMS G LP 10-01-01-01-015 G LP 10-01-01-01-015 Dup G LP 10-01-01-01-015 LMS G LP 10-01-01-01-016 G LP 10-01-01-01-016 Dup G LP 10-01-01-01-016 LMS G LP 10-01-01-01-017 G LP 10-01-01-01-017 Dup G LP 10-01-01-01-017 LMS G LP 10-01-01-01-018 G LP 10-01-01-01-018 Dup G LP 10-01-01-01-018 LMS G LP 10-01-01-01-019 G LP 10-01-01-01-019 Dup G LP 10-01-01-01-019 LMS G LP 10-01-01-01-020 G LP 10-01-01-01-020 Dup G LP 10-01-01-01-020 LMS G LP 10-01-01-01-021 G LP 10-01-01-01-021 Dup G LP 10-01-01-01-021 LMS G LP 10-01-01-01-022 G LP 10-01-01-01-022 Dup S am p le D escrip tion DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 96.0% 96.0% 106% 100% 100% 106% 97.3% 99.7% 98.3% 97.7% 102% 92.3% 97.0% 106% 119% [e] 108% 109% 102% 105% 100% 104% 106% 97.7% 105% 101% 102% 105% 104% 98.7% 101% 109% 109% 159% [e] 113% 107% 139% [e] 110% 103% 145% [e] 96.3% 97.3% 107% 99.7% 96.7% 103% 98.0% 96.0% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) N /A 0.622 N /A 0.696 N /A 1.03 N /A 0.832 N /A 0.989 N /A 1.03 N /A 0.606 N /A 0.711 N /A 0.747 N /A 1.25 N /A 6.31 N /A 7.60 N /A 9.71 N /A 0.898 N /A 0.683 N /A M easured PFBS C o n c e n tra tio n (n g/g; dry w e ig h t) BLOQ BLOQ 0.696 BLQ BLQ 0.700 BLQ BLQ 1.14 BLQ BLQ 0.809 BLQ BLQ 1.03 BLQ BLQ 1.12 0.147 0.165 0.758 0.221 0.223 0.969 BLQ BLQ 0.859 BLQ BLQ 1.29 2.22 2.11 8.53 1.30 1.36 9.21 1.34 1.41 11.6 BLQ BLQ 0.951 BLQ BLQ 0.717 0.221 0.175 RPD / LM S R ecovery [a ] A vera ge PFBS C o n c e n tra tio n (n g/g; d ry w t.) N /A 112% NA 101% N /A 111% N /A 97.2% N /A 104% N /A 108% 12% 99.3% 1.2% 105% N /A 115% N /A 103% 5.0% 101% 4.3% 104% 4.8% 105% N /A 106% N /A 105% 24% BLQ N /A BLQ N /A BLQ N /A BLQ N /A BLQ N /A BLQ N /A 0.156 N /A 0.222 N /A BLQ N /A BLQ N /A 2.17 N /A 1.33 N /A 1.38 N /A BLQ N /A BLQ N /A 0.198 3M Study: GLP10-01-02 Interim Report 01 Page 26 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Table 16. Individual PFBS Results for Decatur FSIA Soils (March/April 2010) L IM S S a m p le ID G LP 10-01-01-01-022 LMS G LP 10-01-01-01-023 G LP 10-01-01-01-023 Dup S am p le D escrip tion DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 S u rro g a te (1 3 C4 PFOS) R e co ve ry [d] 107% 102% 104% A ctu a l LM S S p ik e C onc. (n g/g; dry w e ig h t) 0.751 N /A M easured PFBS C o n c e n tra tio n (n g/g; dry w e ig h t) 1.00 6.58 6.65 RPD / LM S R ecovery [a ] A vera ge PFBS C o n c e n tra tio n (n g/g; d ry w t.) 107% 1.0% N /A 6.62 G LP 10-01-01-01-023 LMS G LP 10-01-01-01-024 G LP 10-01-01-01-024 Dup DAL DF8C SS SS05 0 0010 DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 145% [e] 96.0% 101% 7.98 N /A 14.8 0.924 0.915 103% 1.0% N /A 0.919 G LP 10-01-01-01-024 LMS G LP 10-01-01-01-025 G LP 10-01-01-01-025 Dup DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 104% 99.3% 106% 0.698 N /A 1.68 0.178 0.276 109% 43% N /A 0.227 G LP 10-01-01-01-025 LMS G LP 10-01-01-01-026 G LP 10-01-01-01-026 Dup DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 147% [e] 102% 114% 0.677 N /A 0.847 0.182 0.187 91.6% 2.9% N /A 0.185 G LP 10-01-01-01-026 LMS G LP 10-01-01-01-027 G LP 10-01-01-01-027 Dup DAL DF11 SS SS05 1 0010 DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 146% [e] 112% 110% 0.803 N /A 1.05 0.376 0.277 107% 30% N /A 0.326 G LP 10-01-01-01-027 LMS G LP 10-01-01-01-028 G LP 10-01-01-01-028 Dup DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 148% [e] 104% 106% 0.708 N /A 0.979 0.127 0.151 92.2% 17% N /A 0.139 G LP 10-01-01-01-028 LMS G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 [c] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 D up [c] DAL DF11 SS SS06 0 0010 DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 119% 370% [e] 643% [e] 0.617 N /A 0.754 2.57 5.95 99.6% 79% N /A 4.26 [b] G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 LM S [c] G LP 10-01-01-01-030 G LP 10-01-01-01-030 Dup DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 1010% [e] 133% [e] 134% [e] 8.36 N /A 12.3 BLQ BLQ 96.4% N /A N /A BLQ G LP 10-01-01-01-030 LMS G LP 10-01-01-01-033 G LP 10-01-01-01-033 Dup DAL DF11 SS SS07 0 0010 S oil T rip B la n k 1 S oil T rip B lank 1 179% [e] 97.7% 106% 0.754 N /A 0.845 BLQ BLQ 112% N /A N /A BLQ G LP 10-01-01-01-033 LMS S oil T rip B la n k 1 98.7% 0.941 0.959 102% G LP 10-01-01-01-034 G LP 10-01-01-01-034 Dup S oil T rip B la n k 3 S oil T rip B lank 3 98.0% 93.0% N /A BLQ BLQ N /A G LP 10-01-01-01-034 LMS S oil T rip B la n k 3 103% 0.965 0.923 95.6% [a] L M S s p re p a re d using P F H S (lin e a r + b ra n ch e d isom e rs), but q u a n tifie d o ff o f a P F H S (lin e a r iso m e r) ca lib ra tio n . [b] R P D w a s g re a te r th a n 50% . [c] V a lu e re p o rte d fro m on e result, the d u p lic a te re su lt w a s BLQ . [d ]S u rr o g a te re c o v e ry d e te rm in e d fo r s a m p le s fo rtifie d w ith 2 .9 9 n g o f 13C 4-P F O S a n d q u a n tifie d fro m a 13C 4-P F O S c a lib r a tio n c u rv e . [e j T h e v a lu e re p o rte d w a s d e te rm in e d fro m a re -a s s a y .__________________________________________________________________________________ N /A BLQ N /A 3M Study: GLP10-01-02 Interim Report 01 Page 27 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 8 Conclusion Quantitative analysis for PFOS, PFHS and FPBS in the FSIA soils collected from fields #5, #8 and #11 at the 3M Decatur, AL site was successfully completed following 3M Environmental Laboratory method ETS-8-053.0. The average PFOS, PFHS and PFBS concentration results are summarized in Table 1 and the LMS recoveries are summarized in Table 2. The PFOS, PFHS and PFBS results for the individual sample replicates that were successfully extracted and analyzed with acceptable results are shown in Table 14, Table 15 and Table 16, respectively. The overall results showed that PFOS was the dominant analyte in each of the samples and in several instances exceeded the ULOQ (nominal concentration 500 ng/g). Dilutions of those samples were required to accurately determine PFOS in them, and in some instances required up to 500-fold dilution. The PFOS concentrations ranged over four orders of magnitude. The PFHS and PFBS concentrations were lower in concentration than PFOS in all samples, and did not exceed 100 ng/g for PFHS and did not exceed 10 ng/g for PFBS. In many instances the PFBS results were BLQ. 9 Data/Sample Retention All samples and associated project data (hardcopy and electronic) will be archived according to 3M Environmental Laboratory standard operating procedures. 10 List of Attachments Attachment A: Raw Data Chromatograms, Preparation Forms and Correspondence. 3M Study: GLP10-01-02 Interim Report 01 Page 28 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 11 Signatures Report Approval: Cleston C. Lange, Ph.D., Principal Analytical Investigator ^ h s .Z O / Date William K. Reagen, Ph.D., 3M Environmental Laboratory Management Date 3M Study: GLP10-01-02 Interim Report 01 Page 29 of 539 Study: GLP10-01-02, Interim Report: 01 Analysis for PFOS, PFHS and PFBS in Decatur Site Soils Collected March/April 2010 Attachment A Raw Data, Chromatograms (Partial Set), Preparation Forms and Correspondence 3M Study: GLP10-01-02 Interim Report 01 Page 30 of 539 PFBS S a m p le ID S a m p le D e scrip tio n LCS-100415-01 3 ng LCS in TCR-842 LCS-100415-02 3 ng LCS in TCR-842 LCS-100415-03 3 ng LCS in TCR-842 LCS-100415-04 30 ng LCS in TCR-842 L C S-100415-05 30 ng LCS in TCR-842 LCS-100415-06 30 na LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 LCS-100415-08 300 ng LCS in TCR-842 LCS-100415-09 300 na LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 DF50 LCS-100415-08 300 ng LCS in TCR-842 DF50 LCS-100415-09 300 na LCS in TCR-842 DF50 LLOQ sl0 0 4 2 la = 0 .l9 9 ng/mL s!00426a=0.199 ng/mL B L O Q = L L O Q /w e ig h t PFHS S a m p le ID S a m p le D escrip tio n LCS-100415-01 3 ng LCS in TCR-842 LCS-100415-02 3 ng LCS in TCR-842 LCS-100415-03 3 n a LCS in TCR-842 LCS-100415-04 30 ng LCS in TCR-842 LCS-100415-05 30 ng LCS in TCR-842 LCS-100415-06 30 na LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 LCS-100415-08 300 ng LCS in TCR-842 LCS-100415-09 300 na LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 DF50 LCS-100415-08 300 ng LCS in TCR-842 DF50 LCS-100415-09 300 na LCS in TCR-842 DF50 LLOQ sl00421a=0.200 ng/mL sl00426a=0.200 ng/mL B L O Q = L L O Q /w e ig h t PFOS S a m p le ID S a m p le D escrip tio n LCS-100415-01 LCS-100415-02 LCS-100415-03 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 na LCS in TCR-842 LCS-100415-04 30 ng LCS in TCR-842 LCS-100415-05 LCS-100415-06 30 ng LCS in TCR-842 30 na LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 LCS-100415-08 LCS-100415-09 LCS-100415-07 300 ng LCS in TCR-842 300 na LCS in TCR-842 300 ng LCS in TCR-842 DF50 LCS-100415-08 300 ng LCS in TCR-842 DF50 LCS-100415-09 300 na LCS in TCR-842 DF50 LLOQ sl00421a=0.200 ng/mL sl00426a=0.500 ng/mL B L O Q = L L O Q /w e ig h t w e ig h t (g) 1.0886 1.0643 1.0627 1.0896 1.1277 1.0657 1.0618 1.0885 1.0782 1.0618 1.0885 1.0782 in stru m en t v a lu e (n g /m L ) 3.17 3.05 3.08 30.2 31.6 29.0 288 287 290 5.94 6.06 6.11 R esu lts T ab le sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb s!00421a.rdb sl00421a.rdb sl00426a.rdb sl00426a.rdb s!00426a.rdb D ilu tio n F a c to r 1 1 l 1 1 1 1 1 1 50 50 50 fin al co n c e n tra tio n fn a /m L ) 3.17 3.05 3.08 30.2 31.6 29.0 288 287 290 297 303 306 endogenous (n g /g ) BLOQ BLOQ BLOQ BLOQ BLOQ BLOO BLOQ BLOQ BLOO BLOQ BLOQ BLOQ sp ike co n c e n tra tio n (n a /m L ) 2.99 2,99 2,99 29.9 29.9 29.9 299 299 299 299 299 299 P ercent R ecovery 115% 109% 109% 110% 119% 103.4% 102.3% 104.5% 104.6% 105.5% 110% 110% A verage P e rc e n t R ecovery R elative P e rc e n t D iffe re n c e 111% 2 .0 1 % 111% 4.3% 103.8% 0.5% 109% 1.45% w e ig h t (g) 1.0886 1.0643 1.0627 1.0896 1.1277 1.0657 1.0618 1.0885 1.0782 1.0618 1.0885 1.0782 in stru m en t v a lu e (n g /m L ) 3.21 3.17 3.05 31.0 31.3 30.9 317 321 324 6.14 6.24 6,21 R esu lts T ab le sl00421a.rdb s 10042 la.rdb s!0042la.rdb s 10042 la.rdb sl00421a.rdb s!00421a.rdb s!00421a.rdb s 10042 la.rdb s 10042 la.rdb si00426a.rdb s!00426a.rdb s!00426a.rdb D ilu tio n F acto r 1 1 1 1 1 1 1 1 1 50 50 50 fin al co n c e n tra tio n (n g /g ) 3.21 3.17 3.05 31.0 31.3 30,9 317 321 324 307 312 311 endogenous (n g /g ) BLOQ BLOQ BLOQ BLOQ BLOQ BLOO BLOQ BLOQ BLOQ BLOQ BLOQ BLOQ sp ike co n c e n tra tio n (n g /m L ) 3.03 3.03 3.03 30.3 30.3 30.3 303 303 303 303 303 303 P e rc e n t R ecovery 115% m% 107% 111% 116% 109% 111% 115% 115% 108% 112% 110% A verage P e rc e n t R ecovery R elative P ercent D ifferen ce 111% 2.6% 112% 0.7% 114% 1.10% 110% 0 .8 3 % w e ig h t (g) 1.0886 1.0643 1.0627 1.0896 1.1277 1.0657 1.0618 1.0885 1.0782 1.0618 1.0885 1,0782 in stru m en t v a lu e (n g /m L ) 2.98 2.96 3.15 30.2 30.1 30.5 329 319 326 6.00 6.00 5.88 R esu lts T ab le s 10042 la.rdb sl00421a.rdb s!00421a.rdb s!00421a.rdb sl00421a.rdb s 10042 la.rdb sl00421a.rdb s!00421a.rdb sl00421a.rdb s!00426a.rdb sl00426a.rdb sl00426a.rdb D ilu tio n F a c to r 1 l 1 1 l l 1 50 50 50 fin al co n c e n tra tio n in a la ) 2.98 2.96 3.15 30.2 30.1 30.5 329 319 326 300 300 294 endogenous (n g /g ) BLOQ BLOQ BLOO BLOQ BLOQ BLOQ BLOQ BLOQ BLOO BLOQ BLOQ BLOO sp ike co n c e n tra tio n (n a/m L ) 3.00 3.00 3.00 30.0 30.0 30.0 300 300 300 300 300 300 P e rc e n t R ecovery 108.1% 105.0% 112% 110% 113% 108% 116% 116% 117% 106% 109% 105.7% A v e ra g e P e rc e n t R ecovery R elative P ercent D iffe re n c e 108% 3.4% 110% 0.7% 116% 1.6% 106.9% 1.2% 3M Study: GLP10-01-02 Interim Report 01 Page 31 of 539 Sampl* OmCriptSen GLPI04-01-01-001 GLPIOOI-Ot-Ol-OOl Dup GLPIO-Ol-Ol-Ol-OOl LMS GLPIO-OU 01003 GLPtMU 01002D^> CLPldOU 01002 LMS GLPIO-OU 01003 G lilM H 0)003 Dt? GLP10-0U -01-003LMS GLPlO-OI-f GLPIO-OU GLPIO-Ol-C GLP10-0U 01-003 GLPIO-OI-C 01-005 Dup GLPIO-OI-C 01003 LMS GLPIO-OI-C 01007 GLPIO-Ol-C 01007 Dup GLPIMU 01007 LMS CLP10-01< -01-001 OLPIO-Ol-C -Ol-OOICXp OLPIO-Ol-C OIQOt LMS GLP10-0U 01009 GLPIO-OI-C 01-009Dup OLPIO-Ol-C 01-009LMS GLPIO-OI-C 01010 GLPIO-OU -OlOlODup OLPIOOI-C -OlOIOLMS GLPIO-Ol-C -OlOtl GLPIO-Ol-C -Ol-OtlDup GLPIO-OI-C 01-011 IMS GLPIO-Ol-C 01012 GLPIO-OI-C 01012 Dup GLPIO-OI-C 01012 IMS GLPIO-Ol-C 01013 GLPIO-OI-C 01013 Dup GLPIO-OI-C 01013 LMS GLPIOOI-C 01014 GLPIO-Ol-C -Ol-OMDup GLPIO-OI-C Ol 014 LMS GLPUM31-C OIOIJ GLPIO-Ol-C 0)015 Dup GLPIO-OI-C 01013 LMS GLPIO-OI-C 01013 GLPIO-OI-C 0)016 Di? GLPIO-OI-C 01016 LMS GLPIO-OI-C 0)017 GLPIO-OI-C OI-017DI9 010)1GLPIO-Ol-C 010)7 LMS GLPIO-OI-C GLPIOOI-O OlOllDup OLPKLOI-C 010)8 LMS GLPIO-OI-C 01019 GLPIO-OI-C 01019 D^ GLPIOOI-O 01019LMS GLPIO-Ol-C GLPIOOIO GLPIO-OI-C GLPIOOI-O 01021 GLPIOOI-O 01021 Dup GLPIOOIO 01021 LMS 01022Di*GLPIOOIO 01022 GLPIOOIO GLPIOOIO 0)022 LMS GLPIOOIO 01023 GLPIOOIO 01023 Dup GLPIOOIO 01023 LMS GLPIOOIO 01-024 OLPIOOI-O 01024 Dup GLPIOOI-O 01024 LMS GLPIO-OI-C 01025 GLPIO-OI-C 01025 Dup QLPIO-Ol-C 01025 LMS GLPIO-OI-C 01026 GLPIO-OI-C 01026 Dup OLPIOOI-C 01026 LMS GLPIOOIO 01027 GLPIOOIO 01027 Dup GLPIOOIO 01027 LMS GLPIOOIO GLPIOOIO GLPIOOIO GLPIOOIO 01029 GLPIOOIO 01029 Dup GLPIOOIO 01029 LMS OLPIOOIO 01030 OLPIOOIO 01030 Dup OLPIOOIO 01030 LMS OLPIOOIO 01033 GLPIO-OU 01033 Dup GLPIO-OU 01033 LMS GLPIOOIO!Ol 034 GLPI(M)lO101O34Dup GLP10010I01034LMS BLOCHXOQNmghl ILDF05 SS SS060 0000 DALDP05 SS SS060 0000 3P05SSSS060 0000 DALDF05 SS SS060 0010 DALDF05 SS SS060 0010 DALDF05 SS SS060 0010 ' DALDF05 SS 3506 I 0010 DALDF05 SS SS0610010 _ DALDF05 SSSS06I0Q10 DALDFOSSS SS0700000 " DALDF05 SS 5S0700010 DALDF05SS 5507 0 0010 lLDF05SS 5507 0 0010 DALDF05 SS SSOI 0 0000 _ DAL DFOSSSSS08 00000 ~ DAL DF05SSSS08OOOtO DAL DF05SSSS0800010 _ DALDF05SSSSM00010 ~ DAL DF05SSSS090OOOO DAL DFOSSSSS090OOOO _ DAL DFOSSSSS090OOOO DAL DFOSSSSS0900010 DAL DFOSSSSS0900010 DAL DFOSSSSS0900010 " DAL DFOSSSSS1000000 DAL DF05 SSSS1000000 DALDF05SSSS10 00000 " DAL DFOSSSSSIOOOOIO DAL DFOSSSSSIOOOOIO DAL DFOSSSSSIOOOOIO " DALDFICSS SS0100000 DAL DFSCSS5501 00000 _ DALDF6CSS5S01 00000 " DALDF8CSSS501 00010 DAL DF8CSSSS0100010 DALDFICSS 5501 00010 " DAL DF8CSSSS0200000 DAL DFIC S355020OOOO DAL DFIC SSS50200000 " DAL DFIC SSSS0200010 DAL DFIC SSS30200010 __ DAL DFIC SSSS020Q010 ~ DAL DFIC SSSS030 OOOO DAL DFIC SSSS0300000 DAL DFIC SSSS0300000 " DAL DFIC SSSS03OOOIO DAL DFIC SSSS030 0010 DAL DFIC SSSS030 0010 " DAL DFIC SSSS03 10010 DALDFIC SSSS03 I 0010 DALDFIC SSSS03 10010 " DALDFIC SSSSM0 OOOO DALDFIC SSSSM0 OOOO DALDFIC SSSSM0 OOOO " DALDFICSS SSMOOOIO DALDFIC SSSSM0 0010 _ DALDFIC SSSSM0 0010 " DALDFIC SSSSOS0OOOO DALDFICSS SSOS00000 DALDFIC S3SSOSOOOOO " DALDFIC SSSSOSOOOIO DALDFIC SSS50S00010 DALDFIC SSSSOSOOOIO " DALDFI1 SSSSOS0OOOO DALDF11 SSSSOSOOOOO DALDF11 SSSSOSOOOOO " DAL DF11SSSSOSOOOIO DALDF11SS SSOSOOOIO DALDF11 SSSSOSOOOIO " DALDF11 SSSSOSI 0010 DALDF1I SSSSOSI 0010 DALDF) I SSSSOS10010 " DALDFIl SSSS0600000 DALDFII SSSS0600000 DALDFIl SSS30600000 " DALDFIl SSSS0600010 DALDFIl SSSS06000I0 _ DALDFII SSSS06OOOIO " DALDFII SSSS0700000 DALDFII SSSS0700000 DALDFIl SSSS070000Q " DALDFII SSSS07000IO DALDFIl SSSS0100010 DALDFIl SSSS0700010 Soil Trip Blank 3 Soil Trip Blank3 ril Trip Blank 3 Raanalyiii Rouka (Analytical RupjlOOSlla) GLP10-01-01-01-024 GLP10-01-01-01-024 CKJP GLPlO-OI-Ol-OI-024 LMS DALDFIl SS SSOSOOOOO DALDFIl SS SSOSOOOOO 3M Study: GLP10-01-02 Interim Report 01 0.199 0.199 0997 0.199 0.199 0963 10042 IOM 1004 <1004 <1004 <1004 1004 <1004 <1004 1004 J0O4__ J004__ J0O4_ Page 32 of 539 BLOOLLOO/wnsht IGLP10-OI-O1-OI-O24 jDALDFI1S3 SS05 00000 GLPKM141-0|.024Dib IDALDFI 1SS 3505 0 0000 GLPHWH-0I-OI-O24LMS DAL DFII SS SS0500000 3M Study: GLP10-01-02 Interim Report 01 134 1100511 15 1 l100311-rib~[ U4 10051la tdb | : below) Page 33 of 539 OLPIO-Ol-O OLPI 0-01-0 OLPIMI-O OLFI04I-0 OLFIO-OI-O o u io -o u OLFIO-OI-O OLFIO-OI-O OLFIO-OI-O OLFIO-OI-O OLPI041-0 OLPI0-01-0 OLPI 0-01-0 GLPIO-Ol-O OLF10-0I4 OLPI0-01 OLPI0-01-0 OLPI0-01-0 OLPI041-0 QLP10-0! OLPI0-01-0 OLPI0-01-0 OLPI0-01-0 OLPI0-01-0 OLPI001-0 OLPI0-01-0 OLPI0-01OLPI0-01-0 OLFIO-OI-O OLPI0-01-0 OLPI 04)1-01 OLPIO-Ol-O) p u l 0-01-01 Sample Daacflpttea DF05 S3SSOti 0 0000 DFOSSSSS0600000 DALDF05 S3SSOO0000 DALDFOS SSSSOOOOOIO DALDFOS SS330600010 DALDF05 S3SS06000 DAL DFOSS3 S30201 DAL DFOSS3 SS070I DALDFOSS3SS070 1 DAL DFOSS3 SS0700010 SSSSOl 0 1 DALDF0533 SSOS00000 DALDFOi sassoso0000 DAL DFOSSSSS02OOOIO DALDFOS33 330800010 DALDFOS S3SSOIOOOIO DAL DFOSSSSSO01 DAL DFOSSSSSO00000 S3SSOOOOOOO DAL DFOSSSSSO00010 DAL DFOSSSSSO00010 DALDFOS SSSS00< DAL DFOSSSSS100OOOO DAL DFOSSSSSIO00000 DAL DFOSSSS31000000 DAL DFOSSSSSIOOPPIO DF3CS3SSOl O' AL DF1CSSSS0100C DAL DF3CSSSS0I0 DALDF3CSSSS0I 00010 DAL DRCSSSSOIOOOIO DALDFSCSSSSOl OPPIO PAL0F1C SSSS0200010 DAL DF1C S3SSOS00010 DALDF1CS3SSOl 10010 OLPI0-014 OLPI0-014 OLPI0411-0 OLPI0-01-0 OLPI0-01-0 OLPIO-Ol-O OLPIO-Ol-O OLPIO-Ol-O OLPIO-Ol-O OLPI0-01-0 OLPI0-01-0 OLPI0-01-01 OLPI001-0 OLPI001-0 qtJL0lr01 OLPI0-010 OLPI001-0 OLEIOOIOI OLPIOOIO 2tllOLPI04)10 OLPIOOIO OLPIOOIO OLPIOOIO BLOQ*LLOQAtthl DAL DF11 SSSSOSI 0010 ALDF11 S3SSOSI 0010 DALDF11 S3 SSOSI DF11 SS33060 OOOO DAL DF11SSS3060 OOOO DALDF11 S3 SS060 000Q DAL DF11SSSS060 0010 DALDFlt SSSSOOOOOIO DALDF1I S3SS06OPPIO DAL DF11 S333070 OOOO 1SSSS0700000 DAL DFII S33S070 OOOO DAL DFI 1S3SS070 0010 DAL DFI 1S3SS0700010 DALDFI 1SSSS07OPPIO TripBleak 1 Soil Tr^ Bbak ) Soil Try Bleak S Inrtrumerit (ngfinl) Remiti TaMt I0042lerdb I00421trdb 100421t rdb 100421t nib 100421t-rdb 100421t,nib 100421t rdb I0042ltrdb I00421trdb I0042ltrdb 100421t.rdb 100421t rdb 100421t-rdh 10042Urdb 10042ltrdb 100421trdb 10042ltrdb 10042ltrdb I00421t-rdb 100421t-rdb 100421 100421t-rdb 100421. 10042li 10042lt-rdb 10042lt.rdb 100421t.rrfli 100421t r 100421t r 10<M2t*t 10042L 100421t-rdb 10Q42Uidh 10O42lenfb 100421t rdb 10Q421i 10042UR) 10O42U 10Q42U 0042lt-nft> 00421t rdb 1004211 I00421udb 10042Itrdb 100421t rdb 0O421*rdb 1004211 rdb 100421t rdb I0042lt-rr9> 1004211 1004211 I0042l*rdb 100421t-rdb I00421irdb 100421t.rdb I0042ltrdb 100421t rdb 10042Itrdb 10O42ltrdb I00421t.rdh 100421*rdb 10042l*rdb 100421t rdb I00421*rdb 100421trdb 100421trdb 10042lt.rdb 100421t rdb I00421rdb 3M Study: GLP10-01-02 Interim Report 01 NR. LM3tpim left vat act ^ |n y it r too bi(b (not 0 $lo IOlentetadogtaott) NR. LM3rttaht imtcc^ubla ruorat nlu* but OtafarLMSneofav outiideof100JOH. but wshei 100SOH ISSO ISSO reporttala*,bat fltf farRPD 50H 1SOO report value.btrt Or*farRPD> SOH 1140 1260 10S0 n o t rato* bur B far LMSrtcattrvamide of100 JOH. bar with* 100 SOH NR. LMSretake uateotpttbW needlo retetlyit $0.000 4960 .boi Oat far LMSrtcofweatndtof 100 SOH.but biti 100 SOH .but Oh Sir RPD> SOH I .00ef/f Page 34 o f 539 S am p le ID S am p le D escription GLP10-01-01-01-001 DAL DF05 SS SS06 0 0000 GLP10*01-0 101-001 Dup DAL DF05 SS SS06 0 0000 GLP 10-01-01 -01 -001 LMS DALDF05 SSSS06 0 0000 GLP 10-01-01-01-002 DAL DF05 SS SS06 0 0010 GLP10-01-01 -01 -002 Dup DAL DF05 SS SS06 0 0010 GLP10-01-01-01-002 LMS DAL DF05 SS SS06 0 0010 GLP10-01-01-01-003 DAL DF05 SS SS06 1 0010 GLP 10-01-01-01-003 Dup DAL DF05 SS SS06 1 0010 GLP 10-01 -01 -01-003 LMS DALDF05 SS SS06 1 0010 GLP 10-01-01-01-004 DAL DF05 SS SS07 0 0000 GLP 10-01-01-01 -004 Dup DAL DF05 SS SS07 0 0000 GLP10-01 -01 -01-004 LMS DAL DF05 SS SS07 0 0000 GLP 10-01-01-01-005 DAL DF05 SS SS07 0 0010 GLP 10-01 -01-01-005 Dup DAL DF05 SS SS07 0 0010 GLP 10-01-01-01-005 LMS DAL DF05 SS SS07 0 0010 GLP 10-01-01-01-007 DAL DF05 SS SS08 0 0000 GLP 10-01-01-01-007 Dup DAL DF05 SS SS08 0 0000 GLP 10-01 -01 -01-007 LMS DAL DF05 SS SS08 0 0000 GLP 10-01-01-01-008 DAL DF05 SS SS08 0 0010 GLP10-01-01-01-008 Dup DAL DF05 SS SS08 0 0010 GLP 10-01-01-01-008 LMS DAL DF05 SS SS08 0 0010 GLP 10-01 -01-01-009 DAL DF05 SS SS09 0 0000 GLP 10-01 -01-01 -009 Dup DAL DF05 SS SS09 0 0000 GLP 10-01-01-01 -009 LMS DAL DF05 SS SS09 0 0000 GLP 10-01-01-01-010 DAL DF05 SS SS09 0 0010 GLPlO-Ol-Ol-Ol-OlO Dup DAL DF05 SS SS09 0 0010 GLPlO-01-01-01-010 LMS DALDF05 SS SS09 0 0010 GLPIO-Ol-Ol-Ol-Ol 1 DALDF05 SS SS10 0 0000 GLP 10-01-01-01-011 Dup DALDF05 SS SS10 0 0000 GLP 10-01-01-01-011 LMS DAL DF05 SS SS10 0 0000 GLP 10-01-01-01-012 DAL DF05 SS SS10 0 0010 GLP 10-01-01-01-012 Dup DAL DF05 SS SS1000010 GLP 10-01-01-01-012 LMS DAL DF05 SSSS10 0 0010 GLP 10-01-01-01-013 DAL DF8C SS SS01 0 0000 GLP10-01-01-01-013 Dup DAL DF8CSSSS0I 0 0000 GLP 10-01-01-01-013 LMS DAL DF8C SS SS01 0 0000 GLP 10-01-01-01-014 DAL DF8CSSSS01 0 0010 GLP 10-01-01-01-014 Dup DAL DF8C SS SS01 0 0010 GLP10-01-01-01-014 LMS DAL DF8C SS SS01 0 0010 GLP 10-01-01-01-015 DAL DF8C SS SS02 0 0000 GLP10-01-01-01-015 Dup DAL DF8C SS SS02 0 0000 GLP 10-01-01-01-015 LMS DAL DF8C SS SS02 0 0000 GLP 10-01-01-01-016 DAL DF8C SS SS02 0 0010 GLP10-01-01-01-016 Dup DAL DF8C SS SS02 0 0010 GLP10-01-01-01-016 LMS DAL DF8C SS SS02 0 0010 GLP 10-01-01-01-017 DAL DF8C SS SS03 0 0000 GLP10-01-01-01-017 Dup DAL DF8C SS SS03 0 0000 GLP10-01-01-01-017 LMS DAL DF8C SS SS03 0 0000 GLP 10-01-01-01-018 DAL DF8C SS SS03 0 0010 GLP 10-01-01-01-018 Dup DAL DF8C SS SS03 0 0010 GLP10-01-01-01-018 LMS DAL DF8C SS SS03 0 0010 GLP 10-01-01-01-019 DAL DF8C SS SS03 1 0010 GLP10-01-01-01-019 Dup DAL DF8C SS SS03 1 0010 GLP10-01-01-01-019 LMS DAL DF8C SS SS03 1 0010 GLP 10-01-01-01-020 DAL DF8C SS SS04 0 0000 GLP 10-01-01-01-020 Dup DAL DF8C SS SS04 0 0000 GLP 10-01-01-01-020 LMS DAL DF8C SS SS04 0 0000 GLP 10-01-01-01-021 DAL DF8C SS SS04 0 0010 GLP 10*01-01-01-021 Dup DAL DF8C SS SS04 0 0010 GLP 10-01-01-01-021 LMS DAL DF8C SS SS04 0 0010 GLP 10-01-01-01-022 DAL DF8C SS SS05 0 0000 GLP 10-01 -01 -01 -022 Dup DAL DF8C SS SS05 0 0000 GLP 10-01-01 -01 -022 LMS DAL DF8C SS SS05 0 0000 GLP 10-01-01-01-023 DAL DF8C SS SS05 0 0010 GLP 10-01-01-01-023 Dup DAL DF8C SS SS05 0 0010 GLP10-01-01-01 -023 LMS DAL DF8C SS SS05 0 0010 GLP10-01-01-01 -024 DAL DF11 SS SS05 0 0000 GLP 10-01-01-01-024 Dup DAL DF11 SS SS05 0 0000 GLP 10-01-01-01-024 LMS DAL DF11 SS SS05 0 0000 GLP 10-01-01-01-025 DAL DF11 SS SS05 0 0010 GLP 10-01-01-01-025 Dup DAL D F ll SS SS05 0 0010 GLP 10-01-01-01 -025 LMS DAL D F ll SS SS05 0 0010 GLP 10-01-01-01 -026 DAL D F ll SS SS05 1 0010 GLP 10-01-01-01-026 Dup DAL D F ll SS SS05 1 0010 GLP 10-01-01-01-026 LMS DAL D F ll SS SS05 1 0010 GLP 10-01 -01 -01-027 DAL D F ll SS SS06 0 0000 GLP10-01-01-01-027 Dup DAL D F ll SS SS06 0 0000 GLP 10-01 -01 -01 -027 LMS DAL D F ll SS SS06 0 0000 GLP 10-01 -01 -01 -028 DAL D F ll SS SS06 0 0010 GLP 10-01-01-01 -028 Dup DAL D F ll SS SS06 0 0010 GLP 10-01 -01 -0 1-028 LMS DAL D F ll SS SS06 0 0010 GLP 10-01-01-01 -029 DAL DF11 SS SS07 0 0000 GLP 10-01-01-01-029 Dup DAL D F ll SS SS07 0 0000 GLP 10-01-01-01 -029 LMS DAL DF11 SS SS07 0 0000 GLP 10-01 -01 -0 1-030 DAL DFU SS SS07 0 0010 GLP 10-01-01-01 -030 Dup DAL D F ll SS SS07 0 0010 GLP 10-01-01-01 -030 LMS DAL D F ll SS SS07 0 0010 GLP 10-01-01-01 -033 Soil Trip Blank l GLP 10-01 -01-01-033 Dup Soil Trip Blank 1 GLP 10-01-01-01 -033 LMS Soil Trip Blank l GLP 10-01-01-01 -034 Soil Trip Blank 3 GLP 10-01 -01 -01-034 Dup Soil Trip Blank 3 GLP 10-01 -01 -01 -034 LMS Soil Trip Blank 3 BLOQ=LLOQ/weight w eight (9) 1.9650 1.6981 1,8718 1.8628 1.8337 1.8281 1,8000 1,7175 1.4970 1.2318 1.1116 1.1882 1.1131 1.2355 1.0833 1.9483 1.9822 1.8844 1.6034 1.6661 1.7140 1.2599 1.2863 1.1470 1.6385 1.4065 1.4571 1.5271 1,1321 1.1709 1.1801 0.9966 1.1851 1.7547 1.6576 1.9182 1.6942 1.6684 1.6845 1.7736 1.9036 1.5627 1.0448 0.9780 0.9699 1.4815 1.5682 1.8270 1.4471 1.4871 1.4995 1.2515 1.3724 1.1744 1.3256 1.3835 1.3379 1.4547 1.4181 1.7787 1.5340 1.3891 1.6003 1.5147 1.5388 1.5402 1.4952 1.3211 1.6172 1.7416 1.6289 1.7067 1.5825 1.4943 1.4205 1.5721 1.7218 1.6041 1.9205 2.0055 1.9234 1.5987 1.4491 1.4063 1.5521 1.4415 1.5209 1.0883 1.0960 1.0921 1.1055 1.0831 1.0642 Instrum ent v a lu e in a/m L l 2.98 3.09 2.87 2.94 2.61 2.94 3.10 2.91 3.17 3.36 2.90 2.86 3,08 2.74 3.06 2.88 2.88 3.18 3.01 3.01 3.19 2.92 2.99 2.95 2.93 3.05 2.77 2.91 3.17 3.56 3.25 3.26 3.05 3.16 3.00 3.13 3.18 2.93 3.16 3,04 3,06 3.14 3.12 2.96 3.03 3.26 3.27 4.77 3.40 3.21 4.17 3.30 3.09 4.34 2.89 2,92 3.21 2.99 2.90 3.10 2.94 2.88 3.22 3.06 3.11 4.36 3.24 3.01 5.06 2,98 3.17 4.41 3.07 3.43 4.38 3.36 3.29 4.44 3.13 3.18 3.56 11.1 19.3 30.3 3.98 4.03 5.36 2.93 3.19 2.96 2.94 2,79 3.10 R esu lts Table sl00421a.rdb s 100421 a.rdb s100421 a.rdb sl0042la.rdb s 10042 la. rdb sl00421a.rdb si 0042 la. rdb s!0042ia.rdb si 0042 la.rdb sl00421a.rdb Sl00421a.rdb si 0042 la.rdb sl00421a.rdb s!00421a.rdb sl00421ardb sl00421a.rdb s)00421a.rdb s!00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb si 0042 la.rdb slOG421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb si 0042 la.rdb sl00421a.rdb sl00421a.rdb sl0042!a.rdb si 0042 la. rdb sl00421a.rdb si 0042 la. rdb sl00421a.rdb si 0042 la. rdb sl00421a.rdb si 0042 la.rdb s)0042)a.rdb si 0042 la.rdb s)00421a.rdb si 0042 la.rdb s!00421a.rdb sl00421a.rdb s!00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb si 0042 la.rdb sl00421a.rdb sl00421a.rdb si 0042 la.rdb sl0042la.rdb sl00421a.rdb sI00421a.rdb sl00421a.rdb sl00421a.rdb sl00421a.rdb sl0042!a.rdb sl0042la.rdb sl00421a.rdb sl00421a.rdb s!00421a.rdb sl00421a,rdb sl00421a.rdb si 0042 la.rdb sl00421a.rdb s!00421a.rdb s!00421a.rdb si 0042 la.rdb sl00421a.rdb si 0042 la.rdb s!00421a.rdb sl00421a.rdb sl00421a.rdb si 0042 la.rdb s)00421a.rdb si 0042 la.rdb sl00421a.rdb si 0042 la.rdb sl00421a.rdb s!00421a.rdb sl00421a,rdb sl00421a.rdb si 0042 la. rdb sl00421a.rdb sl00421ardb D ilution F a c to r 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l 1 l I 1 1 1 1 l 1 1 1 1 1 1 l 1 1 1 1 1 1 1 1 1 1 1 1 l 1 l 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l 1 1 1 1 1 1 l 1 1 1 1 1 fin a l co ncentration in a la ) 1.52 1.82 . 1.53 1.58 1.42 1.61 1.72 1.69 2.12 2.73 2.61 2.41 2.77 2.22 2.82 1.48 1.45 1.69 1.88 1.81 1.86 2.32 2.32 2.57 1.79 2.17 1.90 1.91 2.80 3.04 2.75 3.27 2.57 1.80 1.81 1.63 1.88 1.76 1.88 1.71 1.61 2.01 2.99 3.03 3.12 2.20 2.09 2.61 2.35 2.16 2.78 2.64 2.25 3.70 2.18 2.11 2.40 2.06 2.04 1.74 1.92 2.07 2,01 2.02 2.02 2.83 2.17 2.28 3.13 1.71 1.95 2.58 1.94 2.30 3.08 2.14 1.91 2.77 1.63 1.59 1.85 6.94 13.3 21.5 2.56 2.80 3.52 2.69 2.91 2.71 2.66 2.58 2.91 s p ik e c o n c e n tra tio n in a/m L l 3.00 3.00 3.00 3.00 3.00 3,00 3.00 3.00 3.00 3.00 3.00 3.00 3,00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3,00 3.00 3.00 3.00 3,00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3,00 3.00 3.00 3.00 3.00 3.00 Percent R ecovery 99.3% 103% 95,7% 98.0% 87.0% 98.0% 103% 97.0% 106% 112% 96,7% 95,3% 103% 91.3% 102% 96.0% 96.0% 106% 100% 100% 106% 97.3% 99.7% 98.3% 97.7% 102% 92.3% 97.0% 106% 119% 108% 109% 102% 105% 100% 104% 106% 97.7% 105% 101% 102% 105% 104% 98.7% 101% 109% 109% 159% 113% 107% 139% 110% 103% 145% 96.3% 97.3% 107% 99.7% 96.7% 103% 98.0% 96.0% 107% 102% 104% 145% 108% 100% 169% 99.3% 106% 147% 102% 114% 146% 112% 110% 148% 104% 106% 119% 370% 643% 1010% 133% 134% 179% 97.7% 106% 98.7% 98.0% 93.0% 103% 3M Study: GLP10-01-02 Interim Report 01 Page 35 of 539 Project or Study D escrip tio n : LIMS Number: Affected Data: Note To File Decatur Soil Sam pling GLP10-01-01 / GLP10-01-02 None On 3/24/10 a bottle order for soil sampling was prepared as follows: Three soil trip blank in 250 mL Nalgene bottles, closed and sealed with tape, and labeled as Trip Blank 1, Trip Blank 2 and Trip Blank 3. Trip Blank 1 contains 24.6646g o f 09 005-31, Trip Blank 2 contains 26.7657g o f 09 005-31, Trip Blank 3 contains 25.2420g o f 09 005-31, (09 005-31 is an aliquot ofTCR842). The trip blanks were weighed on balance 908 on 3/24/10. Two 1 L bottles containing Milli-Q Gradient water (TN I0-0084) forrinseate samples. 31 empty 250 mL Nalgene bottles (for collecting soil and rinseate samples). initial~ 0ate 3M Study: GLP10-01-02 Interim Report 01 Page 36 of 539 Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Form 3 8 7 7 8 - A - P W O S h ip p in g A d d re s s : 3M C en ter B id g . 2 6 G -5 N -1 7 St. Paul, MN 55144 T e le p h o n e : S a m p le R e c e iv in g : ($ 5 1 ) 7 3 6 -6 5 5 9 A tte rria te : (6 5 1 )7 3 3 -9 8 7 3 FA X : (6 5 1 ) 73 3 -5 9 8 2 P roject ID /P roje ct N a m e Te m plate # P roject Lead U a `E D ept. # (m ain) S cH 1 / L O ? /n P U s k b r Final R epo rt D ue D ate Internal D ue D ate C lass/Job /P roject # 3 0s toa - X9 C ontact Nam e Com pany 'T a i jU L S A d { M a ilin g A d d re ss C ity, S tate, Z ip N o e * C E S - t o j O J A - ! l O E S T C h e g -t E K - j T e ie p h o n e # t b ~ 7 P - 3 r? > t PA //O C FAX# S p e c ia l in s tru c tio n s a n d /o r S p e c ific R e g u la to ry R e q u ire m e n ts : )( m e t h o d ,.lim it o f d e t e c t io n , r e p o r t in g u n its , e t c . D ate A vailable D ate D ue C ontract Lab Preservatives: 15183 0*4 i n 3M Env. Lab Project# _____ For Internal Use Only S 4 i/s - h o ... 6 lP /o ~ o i~ a t ~ o i Analysis Requested: C o m p le te b e lo w . A tta c h a n y a s s o c ia te d In fo rm a tio n . Total Number of Containers to O Z X V oCNO X V) u O > 9Co z w 9 6 p" T z * * " f " r R <3 9 Ite m # C lie n t S am p le Ide ntificatio n 3M LIM S# D ate S am p le d Tim e S am pled M a trix/ M edia E n ter th e n u m b er o f co n tain ers o f each S31. o al D FoS S3 O OOO O f 3 /S ///C a l S o S X1 S S 2. D al D F g SS O O O iO OO f ijiO o J S S ] S' I 3. D a l FT S S $$o> I o o X O 0 0 3 3 M c a l Sb _ ^ 4. V a l f o r s s s s o l o o o o a o l < 3 (2 .0 5. B a l 8.6. D A L 7. Da l :B a l 9. .CFS SS SSoO 0 0*0} O f r SS s s o l X . v o t a OOS b CFOS' SS s - s c R o o o o O O 1 C Fot^ SS S 3 o B O O O c o r O FS 3 3 S S O 7 0 o o o o OJ m / / f ST 3 % i]ic > O ? S O 3 /3 r/m 3 /3 -& ifaf/ro /e 3 // z S QL~10. C F O S ' S S S S c A O O O i O O t M k / / 3,& w 3 rr i ( i i 1 i c O' 3? C ollected by (print): oo 'S3 Item # o /-/C > 7/ y J ^ /< - . ed by/A ffiliation 3 - L a J /C T im e /Y 3 o D ate C ollecto r's signature: S hipped V ia: -X1{E n te r a n in th e b o x b e lo w to in d ic a te re q u e s t) Tim e iS ~ D a te fo S am p le C o n d itio n U p o n R eceipt: Tem perature: O th e r A sso ciated C o C s 'C A cceptable C O ther: p b ^ e c e iv e d on Ice C o p ie s to: C om m ents:. --------- Exacreo ______Initial__ ~ * iio M 5f a f / k z s . Date i *M StudyLP10-01-02 Pase -- in te rim Report 01 O rd in al Accom panying Sam ples Last P age - O riginator S ee Reverso Side for instructions Page 37 of 539 Environmental Laboratory Form 3 8 7 7 8 A -P W O S h ip p in g A d d re s s : 3 M C en ter B ldg. 2 S -5 N -1 7 S t P au l. M N 5 5 1 4 4 T e le p h o n e : S a m p le R e c e iv in g : (5 5 1 ) 7 3 6 *6 5 5 9 A lte rn a te : (6 5 1 ) 73 3 -9 8 7 3 F A X : (6 5 1 ) 7 3 3 -5 9 8 2 Chain of Custody /Request for Laboratory Analytical F $ !~ AP ro je c t ID /P ro je c t N a m e ______ S f i s L . S~AfiOpL.t^Ch T e m p la te # Final R eport D ue D ate P ro je ct Lead 5 < C /S } Internal D ue D ate D ept. # (m ain) C lass/Job /P roject # 15184 OH lO 3M Env. Lab Project # For Internal Use Only < > s 4 /s / o ^ r c F f ^ / - - iP tO O t - O i - O l tn C o n ta c t N a m e ^ , h f B S t R l 3 to * *~ O CL & C om pany J ^T p X > M ailing A ddress C ity, S tate, Zip T elephone # t o 'lo i $ o ^ T ; a /J ? 3 '7 C I S p e c ia l In s tru c tio n s a n d /o r S p e c ific R e g u la to ry R e q u ire m e n ts : (m e th o d , lim it o f d e te c tio n , rep o rtin g u n its, e tc .) I J C L , FAX # D ate A vailable D ate Due C ontract Lab P re s e rv a tiv e s : A n a ly s is R e q u e s te d : C o m p le te b e lo w . A tta c h a n y a s s o c ia te d in fo rm a tio n . T o ta l N u m b e r o f C o n ta in e rs T t r ...... " A -- ____ ............... - A Ite m # C lient S am p le Identification 1. AL D F o S ' S 3 S S I > 0 0 2 0 S s2. n / ) / n F k A T < 3 l a O iO L3. m O F 8 c. S S S S C I Q fS O O 4. A L f B C . s s S S O f OO l O 5. A L C F C r S S S S C 2 . o 6. D A L F B C * S S S ' S ' Z O c o t a X>A7. L F S C S S S S c 3 O O 0 O 8. n 4 L O F C S Z S S C 2 0 O / 9. D A c c m c s s s s o 3 i n o i O 10. n A L F 8 C s SSoH a oooo> > C o lle c te d b y (p rin t): TS O Item # to U3 / - / o 'S JOcrCa J iL J jjte ljftq u ii^ )^ b y /A ffilia tio n S am p le C ond ition U pon R eceipt: Tem perature: O th e r A sso ciated C o C s : 'C A ccepta ble O O ther: ^ R e c e iv e d o n Ice / C o p ie s to: 0 00 0z X w O (0 ri X 0) c w 9. > ZS 3M LIM S # O l fZ . A3 o fA O iT O L 011 O ff Of f 2 D ate S a m p le d T im e S am pled M a trix/ M edia E n te r th e n u m b er o f c o n ta in e rs of ach i/z h /fO t'.S /fl O S 5 Xj /J c ffO / 3 A t > S $ m / c / 3 ' S '3/ 3 W / / S Jo W A / 2 0 s M /o /< 2 .S Silfio f r s r hjo /S '3 < S S' 5T 5 sr x; C o llecto r's signa ture : 1 1 f 1 / ( { I 1 % ? 6L f (E n te r a n X in th e b o x b e lo w to in d fc a le .r o u e s tl T im e /? 3 0 D ate 2m S hippe d V ia: ^ ^ R e c e i v e d b y /A friia tio rT 3 ^ /A T im e l$ ~ D ate C om m ents: x3ct Copy t i t o r i s TTT + 3- Date Pa8e s tu d y j^ L P io -0 1 -0 2 B - ^ I n t e r im R e p o rt 01 O riginal - Accom panying Sam ples Last P age O riginator S ee R everse Side for instructions Page 38 of 539 Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Form 3 8 7 7 3 - A - P W O S h ip p in g A d d ress: 3 M C en ter B ld g . 2 6 -5 N -1 7 S L P au l, M N 5 5 1 4 4 T e le p h o n e : S a m p le R e c e iv in g : {8 5 1 ) 7 3 6 -6 5 5 9 A lte rn a te : {651) 7 3 3 -9 8 7 3 F A X : (6 5 1 ) 733-5 9 8 2 P ro je ct IP /P roject N am e / & _____ < > 1 , S A m ^ U T em plate # P ro je ct Lead L)A&fL S c H .l L_ Final R e p o rt D ue D ate Internal D ue D ate D ept. # (m ain) C la s s /J o b /P ro je c t it i a 3 S t - auo ne. C ontact N am e C om pany M ailing A ddress C ity. S tate , Z ip 33 K E 5 a A f ~ _____________ , / e T FAX# D ate A vailable D ate D ue C ontract Lab S p e c ia l In s tru c tio n s a n d /o r S p e c ific R e g u la to ry R e q u ire m e n ts : (m e th o d , lim it o f d e te c tio n , re p o rtin g u n its , e tc .) Preservatives: 15185 0 4 ( O _______ 3M Env. Lab Project # _____ For Internal Use Only Q L f iO '^O CrLpjO- l - Q ! - O i Analysis Requested: C o m p le te b e lo w . A tta c h a n y a s s o c ia te d In fo rm a tio n . Total Number of Containers OXZPS' Ow XVN>- O(9 OCO z ..Qwc> O Item # Client Sample Identification 3M Date Time LIMS# Sampled Sampled 1. D L n F C 5 5 5 5 o 4 O O l O Z / S / 30 / / < / $ 5 2. f L F 8 C . 5 5 S o S ' o O O o < 2 > 2 Z i h l f i o 0 7 / 5 3. D A L p F & O 5 5 S S T n o / O ih ii/o o ? zf> 4. A U D F i l 5 5 5 S O 5 ~ & O O o 3h/3ry/ o / 0 / 5. n / l L f l l 5 5 5 S < 5 o o o l O l * " 3 /d f/r > /> 2 6. D A L D R / < 5 S S & - 0 0 ( 0 7, A L . D F t l 5 5 5 5 0 ^ 0 . 0 0 0 0 Z f * % 3 c J iO /O 2X5 0 * 7 . 3 /z /t 0 ? 3 0 8. D A L D F f i 5<s S S o 0 o o l O <P 2-^ 'S /.Z A o 9. D A L D F l l 5 5 S S o 7 > o o Z 1 3 / M 10. 1>4L. D R / / 5 5 -0 7 0 O 0 / 3 i/d /f t % 5 0 Matrix/ Media ofE n te r t h e n u m b e r c o n ta in e r s o f e a c h 5" / 5* t r S S' I s 5 TI S \ X Tk r r Z. f cH 2 . . (E n te r a n 'X* in d ie b o x b e lo w to in d ic a te r e u e s ,; >o oto Ite m # 3 o /-/ > *5 c 1JUZ3 fj& tfnft(jist)gd b y/A ffilia tio n S a m p le C ondition U pon R eceip t: ** L A c c e p ta b le O O ther. T im e /? 3 o D ate S hipped V ia: f ---- C om m ents: .c o p y T im e D ate V /t/zo i r v *' Tem perature: O th e r A sso ciated C o C s : 'C (R e c e iv e d on Ice f C o p ie s to: Page J 3 m S tydy^^LP 10-01' 02 -^rnterim Report 01 O rig n al - Accom panying Sam ples Last P age - O riginator S ee R everse Side for Instructions Page 39 of 539 Report Results to: VOCs Other Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Form 3 8778 * A - P W O S h ip p in g A d d re s s : 3 M C en ter S tdg. 2 6 0 -5 N -1 7 S t. P au l, M N 5 5 1 4 4 T e le p h o n e : S a m p le R e c e iv in g : (6 5 1 ) 7 3 6 -6 5 5 9 A lte rn a te : (6 5 1 ) 733*9873 FA X : (6 5 1 ) 7 33-5882 P roject ID /P roje ct N am e T em plate # P ro je ct Lead {/J-A OL D ept. # (m ain) Contact Name Z fk t JS'E.SAAI Company )EST2>sO S ^LuTTe a J S -/aJ O Mailing Address f~ S l A SToiU S A M Pi-i-Ogb "C-HLi 4 - Final R e p o rt D ue D ate Interna! D ue D ate C lass/Job /P roject # Date Available Date Due City, State, Zip Telephone# / OO 3 ! FAX# S p e c ia l In s tru c tio n s a n d /o r S p e c ific R e g u la to ry R e q u ire m e n ts : (m e th o d , Rm it o f d e fe c tio n , ro p d rttn g u n its , o tc .) m OT <2- Contract Lab Preservatives: - In ^ D a te zsl <on N Z C 2 15186 OH i O 3M Env. Lab Project # For internal Use Only 5 # //s/ 6-i-P /-oi-o i - o t Analysis Requested: C o m p le te b e lo w . A tta c h a n y a s s o c ia te d In fo rm a tio n . 72 { / /t 5 L P > Item # Client Sample Identification 1. T)a l n r u 5 5 5 s * o 7 2A P A L F l i SS S S J 3 3. SL P A u k 3- 4. S e i t J im A fLoi 3 5. 6. 7. coi o oo/ o 3M .LIMS# Date Time Sampled Sampled l ) 3/sc-liO oZsV* 0 3 t-: 'j& P J 03 V Matrix/ Media w -- E n ter th e num ber, o f c o n tain ers o f each X X i f (E n ter an X in tho b o x b elo w to In d icaie req u es!) 8. 9. 10. C ollected by (print): $ Be Ite m .# 3 o / - 2. o* c JZ o ish e d b y/A ffiliatio n T im e /? 1 ? Q C ollecto r's signa ture : D ate S hipped Via: 3// x* z,. 7 *. // c C Tim e /< f O a te m i S am p le C ondition U pon R eceipt: Tem perature: O th e rA s s o c ia te d C oC s: `C A cceptable O O ther 'S ' R e c e iv e d o n Ic e C o p ie s to: M S tudyG LP 10-01-02 Pa9s -- in te rim rt 01 O riginai - Accom panying sam ples Last Page - O riginator C o m m e n ttsa: TT t"L- T. C- ,'pi B U l JL TJ U x t * c/ 15 *5 5547 3 O t O . S h ie ld DA*-fl\ s s Ss o l 3 0 6 f n o i feee-eoe, 4z Tr-'p * 0 1 O i. C-C, HU * b/ SA t/b/t S ee R everse S ide for Instructions Page 40 o f 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Lims # N/A GLP10-01-01-01 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 1 2 3 4 3MSampleIDs G LP 10-01-01-01-001 G LP 10-01-01-01-002 G LP 10-01-01-01-003 G L P 1 0 -0 1 -0 1 -01 -0 0 4 Out:storageID Init/date In:storageID Init/date Out:storageID 1,0 -o \________ f.-'ill `-/.ZC, 10 L0&O V CCmt-i-Zi-it' _____ i__________ Init./date ln:storageID Init/date Comments/lnit/date y y y y 5 G LP 10-01-01-01-005 y 6 G LP 10-01-01-01-006 y 7 G LP 10-01-01-01-007 y 8 G LP 10-01-01-01-008 9 G LP 10-01-01-01-009 y / 10 G LP 10-01-01-01-010 / 11 G L P 1 0 -0 1 -0 1 -0 1 -0 1 1 / 12 G LP 10-01 -01-01 -01 2 / 13 G LP 10-01-01-01-013 14 G LP 10-01-01-01-014 A yy 15 G L P 1 0-01 -0 1 -0 1 -0 1 5 \y/ 16 G LP 10-01-01-01-016 17 G LP 10-01-01-01-017 vy fy 18 G LP 10 -01-01-01-018 19 G LP 10-01-01-01-019 1 2 0 G L P 1 0-01 -01 -01 -0 2 0 y 21 G LP 10-01-01-01-021 22 G LP 10-01-01-01-022 / / 2 3 G LP 10-01-01-01-023 / 2 4 G LP 10-01-01-01-024 2 5 G LP 10-01-01-01-025 y>/ 2 6 G L P 1 0-01 -01-01 -0 2 6 2 7 G LP 10-01-01-01-027 / / 2 8 G LP 10-01 -0 1 -0 1 -0 2 8 / 2 9 G LP 10-01-01-01-029 3 0 G L P 1 0-01 -01 -0 1 -0 3 0 - L . ______ \\y ____ ./ / n^ y ______________ 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Page 41 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S a m p le s e t ID # Lim s # N /A G LP 10-01-01-01 S a m p le D e scrip tio n : D e c a tu r S oils Exact Copy of Original tr~ \ H- Initial Date INTERNAL CHAIN OF CUSTODY 3M Sample IDs Out: storage ID Init./date 31 G L P 1 0 - 0 1 - 0 1 - 0 1 - 0 3 1 ______ u ? ( ^ 6 ) \ _________ P r i H - l L - i Q 3 2 ____ G L P 1 0 - 0 1 - 0 1 - 0 1 - 0 3 3 3 3 G L P 1 0 -0 1 -0 1 -01 -0 3 4 34. ' ` 35 36 37 . ' , - ' 38- . ' -- Comments/lnit./date 4 0 -, 41! 42 . 43 44 45 46 47 48 49 50 ; 51 52 53J 54 55 56 5 7 . 58 59 60 ill. il* > iillp iP ___ __r1_ ` _*s,, __________________________ " __________ L l 1 1 __ ` ___________ __________ ; L :_____ ' I v ! tr& , c m e - - m * V v- -% r' sw - _i __________ i" 'S.* r-tfz .. ___ _____________ : -jr^aI- ' _____________ I ir I '" 1 7 7 ....5 "V*- W * n - .i....... _________ ___________ _____*_____v_____-_ ,-*-*<4* m m so , r- a t * - . . ' -_________ " ------^ A- # ___________________________ ____________________ ' ~ | ________ . . - ------ -- * 4 * ,_______ _ . i*,**~iF ><"* t " .t _______. . . .. ................................... .. . . V. - =*> / . .- ________________I -.7f . .. ____________________________ ' - - - `_______________- lawMWBWwaw'aM**qregi > y ^__________ ; 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 Page 42 of 539 GLP10-01-01-01 Sample ID 1 GLP10-01-01-01-001 GLP10-01-01-01-001 Dup GLP10-01-01-01-002 GLP10-01-01-01-002 Dup GLP10-01-01-01-003 GLP10-01-01-01-003 Dup GLP10-01-01-01-004 GLP10-01-01-01-004 Dup GLP10-01-01-01-005 GLP10-01-01-01-005 Dup GLP10-01-01-01-007 GLP 10-01-01-01-007 Dup GLP 10-01-01-01-008 GLP10-01-01-01-008 Dup GLP 10-01-01-01-009 GLP 10-01-01-01-009 Dup GLP 10-01-01-01-010 GLP 10-01-01-01-010 Dup GLP10-01-01-01-011 GLP10-01-01-01-011 Dup GLP 10-01-01-01-012 GLP10-01-01-01-012 Dup GLP10-01-01-01-013 GLP10-01-01-01-013 Dup GLP10-01-01-01-014 GLP10-01-01-01-014 Dup GLP10-01-01-01-015 GLP 10-01-01-01-015 Dup GLP10-01-01-01-016 GLP10-01-01-01-016 Dup GLP10-01-01-01-017 GLP10-01-01-01-017 Dup GLP10-01-01-01-018 GLP10-01-01-01-018 Dup GLP 10-01-01-01-019 GLP10-01-01-01-019 Dup GLP10-01-01-01-020 GLP10-01-01-01-020 Dup GLP 10-01-01-01-021 GLP10-01-01-01-021 Dup GLP10-01-01-01-022 GLP10-01-01-01-022 Dup GLP10-01-01-01-023 GLP10-01-01-01-023 Dup GLP10-01-01-01-024 GLP10-01-01-01-024 Dup Sample Description 2 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 Sample Duplicate DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 Sampie Duplicate DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 Sample Duplicate DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 Sample Duplicate DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 Sample Duplicate DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 Sample Duplicate DAL DF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 Sample Duplicate DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 Sample Duplicate DALDF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 Sample Duplicate DAL DF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 Sample Duplicate DALDF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 Sample Duplicate DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 Sample Duplicate DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 Sample Duplicate DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 Sample Duplicate DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 Sample Duplicate DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 Sample Duplicate DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 Sample Duplicate DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 Sample Duplicate DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 Sample Duplicate DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 Sample Duplicate DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 Sample Duplicate DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 Sample Duplicate DAL DF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 Sample Duplicate ExactCopy ofOriginal t-/-'2 il'~ l 0 Initial ' Date % Moisture Determination W eight of Weighing Dish (g) Initial W eight (soil + Dish) (g) 1st Determination W eight (soil + Dish) (g) Difference (9) 2nd Determination W eight (soil + D is h )(g ) Difference (g) % Moisture * Average % M o is tu re RPD (% M o is tu re ) 3 1.3233 1.3073 1.3090 1.3082 1.3207 1.3255 1.3288 1.3136 1.3077 1.3204 1.3262 1.3305 1.3249 1.3315 1.3232 1.3111 1.3154 1.3243 1.3039 1.3245 1.3251 1.3138 1.3228 1.3041 1.3008 1.3287 1.3347 1.3289 1.3124 1.2946 1.3189 1.3262 1.3325 1.3249 1.3213 1.3431 1.3339 1.3278 1.3219 1.3203 1.3223 1.3327 1.3384 1.3356 1.3359 1.3278 4 6.5238 8.4162 8.5893 7.9816 7.3894 8.2415 5.0333 5.9816 8.2438 5.5818 6.7685 6.8007 5.2097 6.1919 5.2823 5.8106 6.4169 6.7995 4.7704 8.1594 5.4669 5.6930 7.9845 9.0748 5.8073 4.8300 7.3196 6.3198 5.6896 5.6909 7.4169 6.8851 5.9493 6.1519 6.1636 5.8985 5.8814 7.7600 7.7249 5.0276 6.0485 5.8621 6.7542 6.3628 5.4991 6.8744 66 7 8 11 12 13 t* 1. *W ' f. 1 . * - - <v ; *. ? ^ ' ... M fe W M ' rjM h -y , jfji. 4-, - ^4 ` * * & \~ J 5 tK K Tm m m a m *. * . gS&t: Li*; / . : -A S c - i . w m s m m ^ `.s s m e s s a m i Us&BSSM m tm g ffig m m m m m m tm J2F; r- r. a ' s -.v r V ' . ' 'g m m 'y m V* . * * & * # & * * & a m * e. `ts .-m c 's ^>ssfr^te ' -.issm .^ak - ~ * i -A .A* TtQi If* * 7 V ' - M & f l M f e im m s s M A S S I S I - ' W * Cc a i IH H H a i 5 <31" '-'tfCH m m m m . H H M i r'jfc - . - 4 l. - i * " - *-.* . > im m s m I M B B H N i m as& m T.`. :n?*r m r ,** v. . ...... im m m m 4. r IWMBWOWIWMtsSS MJB&Mi K- t&fc* , 1 S W B M B mmmwmmmmmammm - w r s ? 'W fe v . m . M i --*? \v -.: . ''5' .... . A i.V i * r^ S l l & fi " ^ ITTwim'a-M.r^uiiiuSurriK'.^'v * * * - *"* .. = .... ht vj9Kv iciiA t itfC mmmm amsmm K3KKS wmimms ^ M r - r *: i j *-----; ms-imc.' . IpUWiMlSna . . . liS lilllli - fcfHBNKMHBMMFBiwarwdMwHHrpflfiwaitiMs3rasf5if*t m m m m Ksm m m wm m m if f iK "t jcat a 'as?; i M . ,, 4 - * ' 1 ^ 8MM . % 1 4 E M M * m m s^ - yr-W * * . Wif ^ tfSAcNG* *\ M; =- . - >! 'r.JC 'hCSii L . S ii' -'-KF./ i- ' ' '-V T -./a -r-/ * 0 -- a r f l' ' i f I ' j 'f..- S& & ,`SfSSBa 4'SRS. JS *i<' - -JV am i mmmm; '.Jgi-1 ;' TRjP.' 1 = mmsms il -Viii'.te . 7**'L* ;-ts :> i msmam seanem mmmm lin ifn ia m ii-r ^ : m s s mmwsmm 1*'V i * v&e a * O 'infer, (LU*f A t ^4 . . * V- Kit'^jWMILaaRBCEgEmSiM'mty+sftki~Ri- ftfr-i.n mmsmsm 'S'*::--. r.->. *" T "V mmmm ... . <4 s&y: S-iF. r.- : ' -?A- - r . . :J S -4 . -' 'tammsm i * * * \ ** 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Page 43 of 539 GLP10-01-01-01 % Moisture Determination Sample ID 1 GLP10-01-01-01-025 GLP10-01-01-01-025 Dup GLP10-01-01-01-026 GLP10-01-01-01-026 Dup GLP10-01-01-01-027 GLP10-01-01-01-027 Dup GLP 10-01-01-01-028 GLP 10-01-01-01-028 Dup GLP10-01-01-01-029 GLP 10-01-01-01-029 Dup GLP 10-01-01-01-030 GLP10-01-01-01-030 Dup GLP10-01-01-01-033 GLP10-01-01-01-033 Dup GLP 10-01-01-01-034 GLP10-01-01-01-034 Dup Sample Description 2 DALDF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 Sample Duplicate DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 Sample Duplicate DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 Sample Duplicate DAL DF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 Sample Duplicate DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 Sample Duplicate DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 Sample Duplicate Soil Trip Blank 1 Soil Trip Blank 1 Sample Duplicate Soil Trip Blank 3 Soil Trip Blank 3 Sample Duplicate Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2nd Determination Weight (soil + Dish) (g) Difference (9) % Moisture * Average % Moisture RPD (% Moisture) 3 1.3190 1.3307 1.3311 1.3204 1.3213 1.3232 1.3321 1.3229 1.3228 1.3251 1.3218 1.3328 1.3250 1.3232 1.3252 1.3268 4 6.9871 6.5778 7.7974 6.3979 8.7240 6.5806 4.6574 6.1503 8.3048 6.3063 6.8379 6.9418 2.6846 2.9212 2.6645 2.5294 5 6 7 8 11 12 13 - ' k-4'* * .-'t % <* MMM SSSSSIlil if* . . M H I gjggPgggjgi " V; .. ' ' ' ' saw:?' ; SBBHl - *!* ' ` f *8b!^"h8?V<&S f . li S B S j __________ WBvBHi'*'sip V fW V * m m am m i H i m *>sr-- .a mmmmm ' V - ' M l i i r i Y 4, ^ V / jH E M H w m m m s.R's.iV'? i''':r sli"-i `* - iiia i O K S '''*? ! 5i a S f t S V ' . . * i r j * * - ,v s * ? *r t e Ssa & fc M v - * i iifci ^ - -.,^5 " - """i SMu> "t'S r *` iS ? **' " Column 3: Balance ID: 900 Initial/Date: 6 p r*1 I* Column 4: Balance ID: 900 Temp of Oven (' C): 99.8 Oven Time/Date In: 4/26/2010 3:30 PM Initial/Date: H- 6 - '/ D Oven ID: OV-1 Probe ID: Probe #1, RTD #14 Column 5: N/A Column 7: N/A S? CopyofOriginal MU--- -- --^ SS- 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 Page 44 of 539 GLP10-01-01-01 Sample ID Sample Description 1 GLP10-01-01-01-001 GLP10-01-01-01-001 Dup GLP10-01-01-01-002 GLP10-01-01-01-002 Dup GLP10-01 -01-01 -003 GLP10-01-01-01-003 Dup GLP10-01-01-01-004 GLP10-01-01-01-004 Dup GLP10-01-01-01-005 GLP10-01-01-01-005 Dup GLP10-01-01-01-007 GLP10-01-01-01-007 Dup GLP10-01-01-01-008 GLP10-01-01-01-008 Dup GLP10-01-01-01-009 GLP10-01-01-01-009 Dup GLP10-01-01-01-010 GLP10-01-01-01-010 Dup GLP10-01-01-01-011 GLP10-01-01-01-011 Dup GLP10-01-01-01-012 GLP10-01-01-01-012 Dup GLP 10-01-01-01-013 GLP10-01-01-01-013 Dup GLP10-01-01-01-014 GLP10-01-01-01-014 Dup GLP10-01-01-01-015 GLP 10-01-01-01-015 Dup GLP10-01-01-01-016 GLP10-01-01-01-016 Dup GLP10-01-01-01-017 GLP10-01-01-01-017 Dup GLP10-01-01-01-018 GLP10-01-01-01-018 Dup GLP 10-01-01-01-019 GLP10-01-01-01-019 Dup GLP10-01-01-01-020 GLP10-01-01-01-020 Dup GLP10-01-01-01-021 GLP10-01-01-01-021 Dup GLP10-01 -01 -01-022 GLP10-01-01-01-022 Dup GLP 10-01-01-01-023 GLP 10-01-01-01-023 Dup GLP 10-01-01-01-024 GLP10-01-01-01-024 Dup 2 DAL DF05 SS SS06 0 0000 DAL DF05 SS SS06 0 0000 Sample Duplicate DAL DF05 SS SS06 0 0010 DAL DF05 SS SS06 0 0010 Sample Duplicate DAL DF05 SS SS06 1 0010 DAL DF05 SS SS06 1 0010 Sample Duplicate DAL DF05 SS SS07 0 0000 DAL DF05 SS SS07 0 0000 Sample Duplicate DAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 Sample Duplicate DAL DF05 SS SS08 0 0000 DAL DF05 SS SS08 0 0000 Sample Duplicate DALDF05 SS SS08 0 0010 DAL DF05 SS SS08 0 0010 Sample Duplicate DAL DF05 SS SS09 0 0000 DAL DF05 SS SS09 0 0000 Sample Duplicate DAL DF05 SS SS09 0 0010 DAL DF05 SS SS09 0 0010 Sample Duplicate DALDF05 SS SS10 0 0000 DAL DF05 SS SS10 0 0000 Sample Duplicate DAL DF05 SS SS10 0 0010 DAL DF05 SS SS10 0 0010 Sample Duplicate DAL DF8C SS SS01 0 0000 DAL DF8C SS SS01 0 0000 Sample Duplicate DAL DF8C SS SS01 0 0010 DAL DF8C SS SS01 0 0010 Sample Duplicate DAL DF8C SS SS02 0 0000 DAL DF8C SS SS02 0 0000 Sample Duplicate DAL DF8C SS SS02 0 0010 DAL DF8C SS SS02 0 0010 Sample Duplicate DAL DF8C SS SS03 0 0000 DAL DF8C SS SS03 0 0000 Sample Duplicate DAL DF8C SS SS03 0 0010 DAL DF8C SS SS03 0 0010 Sample Duplicate DAL DF8C SS SS03 1 0010 DAL DF8C SS SS03 1 0010 Sample Duplicate DAL DF8C SS SS04 0 0000 DAL DF8C SS SS04 0 0000 Sample Duplicate DAL DF8C SS SS04 0 0010 DAL DF8C SS SS04 0 0010 Sample Duplicate DAL DF8C SS SS05 0 0000 DAL DF8C SS SS05 0 0000 Sample Duplicate DAL DF8C SS SS05 0 0010 DAL DF8C SS SS05 0 0010 Sample Duplicate DALDF11 SSSS05 0 0000 DAL DF11 SS SS05 0 0000 Sample Duplicate ExactCopy ofOriginal V~ & initial ' Date % Moisture Determination Weight of Weighing Dish (g) Initial W eight (soil + Dish) (g) 1st Determination W eight (soil + Dish)(g) Difference (g) 2nd Determination Weight (soil + Dish) (g) Difference Average % (g) % Moisture * Moisture 3 1.3233 1.3073 1.3090 1.3082 1.3207 1.3255 1.3288 1.3136 1.3077 1.3204 1.3262 1.3305 1.3249 1.3315 1.3232 1.3111 1.3154 1.3243 1.3039 1.3245 1.3251 1.3138 1.3228 1.3041 1.3008 1.3287 1.3347 1.3289 1.3124 1.2946 1.3189 1.3262 1.3325 1.3249 1.3213 1.3431 1.3339 1.3278 1.3219 1.3203 1.3223 1.3327 1.3384 1.3356 1.3359 1.3278 4 6.5238 8.4162 8.5893 7.9816 7.3894 8.2415 5.0333 5.9816 8.2438 5.5818 6.7685 6.8007 5.2097 6.1919 5.2823 5.8106 6.4169 6.7995 4.7704 8.1594 5.4669 5.6930 7.9845 9.0748 5.8073 4.8300 7.3196 6.3198 5.6896 5.6909 7.4169 6.8851 5.9493 6.1519 6.1636 5.8985 5.8814 7.7600 7.7249 5.0276 6.0485 5.8621 6.7542 6.3628 5.4991 6.8744 6 5.7928 7.4659 7.3762 6.8998 6.4004 7.1096 4.4187 5.2415 6.8365 4.7236 5.9261 5.9666 4.5618 5.3591 4.6320 5.1158 5.4944 5.7954 4.2603 7.1945 4.6722 4.8660 6.9957 7.9500 5.0337 4.2224 6.4177 5.5647 4.8881 4.8760 6.5663 6.1054 5.3465 5.5257 5.5258 5.3070 5.0915 6.6364 6.5279 4.3544 5.2488 5.0457 5.7184 5.3828 4.9281 6.0882 6 0.7310 0.9503 1.2131 1.0818 0.9890 1.1319 0.6146 0.7401 1.4073 0.8582 0.8424 0.8341 0.6479 0.8328 0.6503 0.6948 0.9225 1.0041 0.5101 0.9649 0.7947 0.8270 0.9888 1.1248 0.7736 0.6076 0.9019 0.7551 0.8015 0.8149 0.8506 0.7797 0.6028 0.6262 0.6378 0.5915 0.7899 1.1236 1.1970 0.6732 0.7997 0.8164 1.0358 0.9800 0.5710 0.7862 7 5.7918 7.4631 7.3729 6.8979 6.3976 7.1061 4.4182 5.2400 6.8302 4.7214 5.9239 5.9640 4.5600 5.3564 4.6297 5.1132 5.4901 5.7924 4.2592 7.1903 4.6701 4.8646 6.9936 7.9472 5.0306 4.2216 6.4157 5.5643 4.8869 4.8736 6.5644 6.1028 5.3447 5.5225 5.5244 5.3073 5.0885 6.6318 6.5237 4.3526 5.2465 5.0427 5.7138 5.3801 4.9248 6.0843 8 0.0010 0.0028 0.0033 0.0019 0.0028 0.0035 0.0005 0.0015 0.0063 0.0022 0.0022 0.0026 0.0018 0.0027 0.0023 0.0026 0.0043 0.0030 0.0011 0.0042 0.0021 0.0014 0.0021 0.0028 0.0031 0.0008 0.0020 0.0004 0.0012 0.0024 0.0019 0.0026 0.0018 0.0032 0.0014 -0.0003 0.0030 0.0046 0.0042 0.0018 0.0023 0.0030 0.0046 0.0027 0.0033 0.0039 11 14.08 13.41 16.71 16.24 16.34 16.42 16.60 15.89 20.38 20.19 15.52 15.30 16.72 17.19 16.48 15.50 18.17 18.39 14.75 14.18 19.24 18.92 14.87 14.51 17.24 17.38 15.10 15.14 18.34 18.59 13.98 14.07 13.10 13.04 13.20 12.98 17.44 17.54 18.76 18.21 16.97 18.09 19.21 19.55 13.79 14.24 12 13.74 16.47 16.38 16.25 20.29 15.41 16.96 15.99 18.28 14.46 19.08 14.69 17.31 15.12 18.46 14.03 13.07 13.09 17.49 18.48 17.53 19.38 14.02 RPD {% M o is ture) 13 4.86 2.85 0.45 4.42 0.94 1.45 2.75 6.15 1.24 3.93 1.68 2.48 0.82 0.23 1.37 0.66 0.43 1.70 0.59 2.99 6.40 1.74 3.21 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Page 45 of 539 GLP10-01-01-01 % Moisture Determination Sample ID Sample Description 1 GLP10-01-01-01-025 GLP10-01-01-01-025 Dup GLP10-01-01-01-026 GLP10-01-01-01-026 Dup GLP10-01-01-01-027 GLP 10-01-01-01-027 Dup GLP10-01-01-01-028 GLP10-01-01-01-028 Dup GLP10-01-01-01-029 GLP10-01-01-01-029 Dup GLP 10-01-01-01-030 GLP 10-01-01-01-030 Dup GLP10-01-01-01-033 GLP10-01-01-01-033 Dup GLP10-01-01-01-034 GLP10-01-01-01-034 Dup 2 DAL DF11 SS SS05 0 0010 DAL DF11 SS SS05 0 0010 Sample Duplicate DAL DF11 SS SS05 1 0010 DAL DF11 SS SS05 1 0010 Sample Duplicate DAL DF11 SS SS06 0 0000 DAL DF11 SS SS06 0 0000 Sample Duplicate DALDF11 SS SS06 0 0010 DAL DF11 SS SS06 0 0010 Sample Duplicate DALDF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 Sample Duplicate DAL DF11 SS SS07 0 0010 DAL DF11 SS SS07 0 0010 Sample Duplicate Soil Trip Blank 1 Soil Trip Blank 1 Sample Duplicate Soil Trip Blank 3 Soil Trip Blank 3 Sample Duplicate W eight of Weighing Dish (g) Initial W eight (soil + Dish) (g) 1st Determination W eight (soil 4 D is h )(g ) Difference (9) 2nd Determination W eight (soil + D ish )(g ) Difference Average % (g) % M oisture * Moisture 3 1.3190 1.3307 1.3311 1.3204 1.3213 1.3232 1.3321 1.3229 1.3228 1.3251 1.3218 1.3328 1.3250 1.3232 1.3252 1.3268 4 6.9871 6.5778 7.7974 6.3979 8.7240 6.5806 4.6574 6.1503 8.3048 6.3063 6.8379 6.9418 2.6846 2.9212 2.6645 2.5294 5 6.1319 5.8863 6.9624 5.7197 7.8033 5.8933 4.1173 5.3391 7.1786 5.5463 6.0711 6.1999 2.6380 2.8693 2.6176 2.4895 6 0.8552 0.6915 0.8350 0.6782 0.9207 0.6873 0.5401 0.8112 1.1262 0.7600 0.7668 0.7419 0.0466 0.0519 0.0469 0.0399 7 6.1294 5.8838 6.9596 5.7190 7.8014 5.8915 4.1165 5.3378 7.1749 5.5448 6.0693 6.1976 2.6349 2.8662 2.6163 2.4876 8 0.0025 0.0025 0.0028 0.0007 0.0019 0.0018 0.0008 0.0013 0.0037 0.0015 0.0018 0.0023 0.0031 0.0031 0.0013 0.0019 11 15.13 13.23 12.96 13.37 12.46 13.11 16.27 16.83 16.18 15.29 13.93 13.27 3.66 3.44 3.60 3.48 12 14.18 13.16 12.79 16.55 15.74 13.60 3.55 3.54 RPD (% Moisture) 13 13.44 3.15 5.04 3.41 5.69 4.90 6.02 3.48 Column 3: Balance ID: 900 Initial/Date: Column 4: Balance ID: 900 Temp of Oven ('C): 99.8 Oven Time/Date In: 4/26/2010 3:30 PM Initial/Date: Oven ID: OV-1 Probe ID: Probe #1, RTD #14 Column 5: Temp of Oven ('C): 103.2 Oven Time/Date Out: 4/27/2010 10:00 AM Oven Time/Date In: 4/27/2010 11:15AM Balance ID: 908 Initial/Date: Qj>tv{ *1 * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven fC ): 112.0 Oven Time/Date Out: 4/27/2010 1:15 PM Oven Time/Date In: N/A Balance ID: 908 Initial/Date: Qs-' r ^ r / C) 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 ExactCopy o: ... Gfry Initial V- z j f ' t c Date Page 46 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Lims # N/A GLP10-01-01 ExactCopyofOriginal Initial Date Sample Description: Soil INTERNAL CHAIN OF CUSTODY # 3M Sample IDs 1 GLP10-01-01-01-001 DAL DF05 SS SS06 0 0000 2 GLP10-01-01-01-002 DAL DF05 SS SS06 0 0010 3 GLP10-01-01-01-003 DAL DF05 SS SS06 1 0010 4 GLP10-01-01-01-004 DAL DF05 SS SS07 0 0000 5 GLP10-01-01-01-005 DAL DF05 SS SS07 0 0010 6 GLP10-01-01-01-007 DAL DF05 SS SS08 0 0000 7 GLP10-01-01-01-008 DAL DF05 SS SS08 0 0010 3 GLP10-01 -01 -01 -009 DAL DF05 SS SS09 0 0000 9 GLP10-01-01-01-010 DAL DF05 SS SS09 0 0010 10 GLP10-01-01-01-011 DAL DF05 SS SS10 0 0000 11 GLP10-01-01-01-012 DAL DF05 SS SS10 0 0010 12 GLP10-01-01-01-013 DAL DF8C SS SS01 0 0000 13 GLP10-01-01-01-014 DAL DF8C SS SS01 0 0010 14 GLP10-01-01-01-015 DAL DF8C SS SS02 0 0000 15 GLP10-01 -01-01 -016 DAL DF8C SS SS02 0 0010 16 GLP10-01-01-01-017 DAL DF8C SS SS03 0 0000 17 GLP10-01-01-01-018 DAL DF8C SS SS03 0 0010 18 GLP10-01 -01-01 -019 DAL DF8C SS SS03 1 0010 19 GLP10-01-01 -01-020 DAL DF8C SS SS04 0 0000 20 GLP10-01-01 -01-021 DAL DF8C SS SS04 0 0010 Out: From WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 WR01 Init./date H S -/ \!/ In: storage ID ______ Init./date 6 'W \ Q -IT -IO Comments Init./date / / / / / / J2v/ a i Z _____ 7y /\S [ / / / / / / / / \ L ____ / 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Page 47 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID# Lims # N/A GLP10-01-01 Sample Description: Soil INTERNAL CHAIN OF CUSTODY # 3M Sample IDs Out: From Init./date In: storage ID Init./date Comments init./date 21 GLP10-01-01-01-022 DAL DF8C SS SS05 0 0000 WR01 !> H oK //-A '-ZQ 22 GLP10-01-01-01-023 DAL DF8C SS SS05 0 0010 23 GLP10-01-01-01-024 DAL DF11 SS SS05 0 0000 24 GLP10-01-01-01-025 DAL DF11 SS SS05 0 0010 25 GLP10-01-01-01-026 DAL DF11 SS SS05 1 0010 26 GLP10-01-01-01-027 DAL DF11 SS SS06 0 0000 WR01 WR01 WR01 WR01 WR01 |I I\ \ / / / . / f X |/ 27 GLP10-01-01-01-028 DAL DF11 SS SS06 0 0010 WR01 K 7^ 28 GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 WR01 / 29 GLP10-01-01-01-030 DAL DF11 SS SS07 0 0010 WR01 / 30 GLP10-01-01-01-033 Soil Trip Blank 1 WR01 X 31 GLP10-01-01-01-034 Soil Trip Blank 3 WR01 v / ^ _____ A^ ____ / ---------------- - e ------ .* '-i ------- ---------------- . .>X -- ^ ------ -- :-- T " ---------------------- ------------- - : r ; , 'V ^ - r r - ^ 7 . _______ -- ------------ ...... -----------------^ ^ ................... ............... .. mm ^ ------=?- __-----------------c T m * : . 'll 1mW. rTh'fc~^i.fici, Trr~- HA- $S*S^1i&&S,TSi2iusFsrraS5m B*yS*ift iXH,--,t--__* T-TTrjfr ____________________ ____________ --------- --------- ------------ -- :------- ' ' ----- - :--------- :--------------- - r------ -- i r , V " ,35 ------- ; f ' '* j L -----------t ---------------' b-i ----------- ----- -- ------------------ -- ---------------- 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 Page 48 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Lims # N/A GLP10-01-01-01 Sample Description: Decatur Soils # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 INTERNAL CHAIN OF CUSTODY 3MSampleIDs Out: storageID G LP 10-01-01-01-001 LJf t O 1 G L P 1 0 -0 1-01-01-002 \ G LP 10-01-01-01-003 G L P 1 0 -0 1-01-01-004 G LP 10-01-01-01-005 G LP 10-01-01-01-006 G L P 1 0-01 -01-01 -0 0 7 G LP 10-01-01-01-008 _______________ G LP 10-01-01-01-009 G LP 10-01-01-01-010 G L P 1 0-01 -01-01 -01 1 G L P 1 0-01-01-01-012 G L P 1 0-01 -01 -01 -0 1 3 G LP 10-01-01-01-014 G LP 10-01-01-01-015 G L P 1 0-01 -0 1 -0 1 -0 1 6 G LP 10-01-01-01-017 G LP 10-01-01-01-018 G LP 10-01-01-01-019 G L P 1 0-01-01-01-020 G LP 10-01-01-01-021 G LP 10-01-01-01-022 G LP 10-01-01-01-023 G LP 10-01-01-01-024 G LP 10-01-01-01-025 G LP 10 -01-01-01-026 G L P 1 0-01 -01-01 -0 27 G LP 10-01-01-01-028 G L P 1 0-01-01-01-029 G L P 1 0-01 -0 1 -0 1 -0 3 0 _______\ ' ' Init./date In: storageID Init./date Out: storageID Init./date In: storageID Init/date `/-s/'IQ 1 P n i - f ' i o ____ V / y yy / / */ / / / / / _____________ z ____________ / y / *y y. a I. y$r Comments/lnit/date / / y y / 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Page 49 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Urns # N/A GLP10-01-01-01 Sample Description: Decatur Soils ^ CopyofOriginal y- D a te INTERNAL CHAIN OF CUSTODY # 3M Sam ple IDs Out: storage ID Init./date In: storage ID Init./date Out: storage ID Init./date In: Storage ID Init./date C om m ents/lnit/date 31 G L P 1 0 -0 1 -0 1 -0 1 -0 3 1 32 G L P 1 0 -0 1-0 1-0 1-033 34 35 36 37 38 . N - - ' * v " vs - ',, . /W 4 ^ '/< 5 C f ^ `.W - / --_____i _p__--_____ -------- V -= v ' * . v: ' y y y : ; \ ------------------ ... . S- L \s *, .: . < : . ^y 39 40 42 !?";: 43 44 45? 46 47 48":""*:: 49 Y '' ' 'ft *. I; v \ . . 'VO. ' .. . ' ' . : >? * * v. ` ^ '4 .'- : ... V * - Y - : . . . . . i X' . .. V." .., ' : *f . : .. *- so > 51 52 53 : 54 55 ' 56 57 : 58 59 . 's *. Y~ ' <* Y ' . ` * . V. . :v : . I- . . * '*t* *" . " * ' 4 '* - ' 4 "* . * . ' . . I l S a l i * 1 **- > ^ ^ ...Y'-' . * i- V ,,/ i ** . 60. 15 ,, ",, * Y - - \* _ jl 'S ^ -- rT - jfT O . < .- .. . ,*4 ' S | _ - v'v *&X \ * ' - ' '' 45^,^', % *5* ** k* ' 4 '4, " . v. , ' . . j"' K "* s * -- . .. 4 J5 . ` >y 4 . . s * " .. > , -* v 1 -- . i _____ -- 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 Page 50 of 539 G LP 10-01-01-01 G LP 10-01-02-01 E T S -8 -0 5 3 Samples Extracted 08-Apr-2010 Prescreening S a m p le ID 1 E C -1 0 0 4 0 8 -0 1 E C -1 0 0 4 0 8 -0 2 E C -1 0 0 4 0 8 -0 3 E C -1 0 0 4 0 8 -0 4 E C -1 0 0 4 0 8 -0 5 E C -1 0 0 4 0 8 -0 6 E C -1 0 0 4 0 8 -0 7 E C -1 0 0 4 0 8 -0 8 E C -1 0 0 4 0 8 -0 9 E C -1 0 0 4 0 8 -1 0 E C -1 0 0 4 0 8 -1 1 M B --1 0 0 408-01 M B --1 0 0 4 0 8 -0 2 M B --1 0 0 4 0 8 -0 3 M B --1 0 0 4 0 8 -0 4 M B -1 0 0 4 0 8 -0 5 M B -1 0 0 4 0 8 -0 6 L C S -1 0 0 4 08-01 L C S -1 0 0 4 0 8 -0 2 L C S -1 0 0 4 0 8 -0 3 L C S -1 0 0 4 0 8 -0 4 L C S -1 0 0 4 0 8 -0 5 L C S -1 0 0 4 0 8 -0 6 G L P 1 0 -0 1 -0 1 -0 1 -0 0 1 G L P 1 0 -0 1 -0 1 -01-002 G L P 1 0 -0 1 -01 -01 -0 0 3 G L P 1 0 -0 1 -0 1 -0 1 -0 0 4 G L P 1 0 -0 1 -01 -01 -0 0 5 G L P 1 0 -0 1 -0 1 -0 1 -0 0 7 G L P 1 0 -0 1 -01 -01 -0 0 8 G L P 1 0 -0 1 -01 -01 -0 0 9 G L P 1 0 -0 1 -0 1 -0 1 -0 1 0 G L P 1 0 -0 1 -0 1 -0 1 -0 1 1 G L P 1 0 -0 1 -0 1 -0 1 -0 1 2 G L P 1 0 -0 1 -0 1 -0 1 -0 1 3 G L P 1 0 -0 1 -0 1 -0 1 -0 1 4 G L P 1 0 -0 1 -0 1 -0 1 -0 1 5 G L P 1 0 -0 1 -0 1 -0 1 -0 1 6 G L P 1 0 -0 1 -01 -01 -0 1 7 G L P 1 0 -0 1 -0 1 -0 1 -0 1 8 G L P 10 -0 1 -0 1 -0 1 -0 1 9 G L P 1 0 -0 1 -01 -01 -0 2 0 G L P 1 0 -0 1 -0 1 -0 1 -0 2 1 G L P 1 0 -0 1 -0 1 -0 1 -0 2 2 G L P 1 0 -0 1 -0 1 -0 1 -0 2 3 S a m p le D e s c rip tio n 2 0 .2 n q E x tra c te d C u rv e P o in t 0 .5 n q E x tra c te d C u rv e P o in t 0 .7 5 nq E xtra c te d C u rv e P o in t 1 nq E xtra c te d C u rv e P o in t 2 .5 nq E xtra c te d C u rv e P o in t 5 n q E xtra c te d C u rv e P o in t 1 0 n o E xtra c te d C u rv e P o in t 2 5 n q E xtra c te d C u rv e P o in t 5 0 n o E x tra c te d C u rv e P o in t 1 0 0 n q E xtra c te d C u rv e P o in t 2 0 0 n q E xtra c te d C u rv e P o in t M e th o d B la n k 1 w /o IS M e th o d B la n k 2 w /o IS M e th o d B la n k 3 w /o IS M e th o d B la n k 4 w / IS M e th o d B la n k 5 w / IS M e th o d B la n k 6 w / IS 3 n q L C S in T C R -8 4 2 3 nq L C S in T C R -8 4 2 3 n q L C S in T C R -8 4 2 3 0 n q L C S in T C R - 8 4 2 . 3 0 n q L C S in T C R - 8 4 2 3 0 n q L C S in T C R - 8 4 2 DAL D F05 SS SS06 0 0000 DAL D F05 SS SS 06 0 0010 DAL D F05 SS SS 06 1 0010 DAL D F05 SS SS07 0 0000 DAL D F05 SS SS07 0 0010 DAL D F05 SS SS 08 0 0000 DAL D F05 SS SS08 0 0010 DAL D F05 SS SS 09 0 0000 DAL D F05 SS SS 09 0 0010 DAL D F05 SS SS10 0 0000 DAL D F05 SS SS10 0 0010 DAL D F 8C SS S S01 0 0 0 0 0 D A L D F 8C SS S S01 0 0 0 1 0 DAL D F 8C SS S S 02 0 0 0 0 0 D A L D F 8C SS S S 02 0 0 0 1 0 D A L D F 8C SS S S 0 3 0 0 0 0 0 D A L D F 8C SS S S 03 0 0 0 1 0 D A L D F 8C S S S S 0 3 1 0 0 1 0 D A L D F 8C SS S S 04 0 0 0 0 0 DAL D F 8C SS S S 04 0 0 0 1 0 DAL D F 8C SS S S 0 5 0 0 0 0 0 DAL D F 8C SS S S 0 5 0 0 0 1 0 S o il M a x trix ID S o il W e ig h t U s e d (g ) S p ik e ID S p ik e V o lu m e (u L ) In te rn a l S ta n d a rd ID In te rn a l S ta n d a rd V o lu m e (u L ) S u rro g a te S p ik e ID S u rro g a te S p ik e V o lu m e (u L ) Add 8 mL E x tra c tio n S o lv e n t S o n ic a te 1 hr C e n trifu g e C o m m e n ts 3 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 10 0 0 1 -1 5 2 ` ** T . v ' -r k~ # . 4 1.0 112 1 .0 4 0 9 1 .0 3 8 6 1 .1 0 7 8 1 .0 9 2 9 1 .0 6 4 8 1 .0 7 5 0 1 .0 8 0 2 1 .0 9 3 7 1 .0 4 3 0 1 .1 0 2 9 1 .0 8 9 6 1 .1 3 4 9 1 .0 9 2 9 1.0 6 5 1 1.1 0 3 1 1.0 3 2 1 1 .0 7 1 1 1 .0 9 0 5 0 .9 9 1 9 1 .0 4 2 4 1 .0 9 4 3 1 .0 6 7 6 1 .7 5 0 9 2 .0 0 5 6 2 .0 1 4 9 1 .5 3 1 9 1 .6 1 5 5 1 .8 1 1 4 1 .8 4 7 5 1 .2 2 5 9 1 .4 1 5 0 1 .2 2 3 2 1 .4 3 1 8 1 .9 2 6 5 1 .5 8 0 6 1 .5 4 9 5 1 .3 2 4 4 1 .5 4 7 9 1 .5 6 9 9 1 .6 5 8 7 1 .5 1 4 4 1 .8 7 7 7 1 .5 7 4 9 1 .9 6 7 3 ' * * i` 5 10 00 1 -1 5 1 10 00 1 -1 5 1 10 00 1 -1 5 1 10 00 1 -1 5 1 10 0 0 1 -1 5 0 10 0 0 1 -1 5 0 10 0 0 1 -1 5 0 10 0 0 1 -1 4 9 10 0 0 1 -1 4 9 10 0 0 1 -1 4 9 10 0 0 1 -1 4 9 * r` ; 10 0 0 1 -1 4 8 10 0 0 1 -1 4 8 10 0 0 1 -1 4 8 10 0 0 1 -1 4 7 10 0 0 1 -1 4 7 10 0 0 1 -1 4 7 vV* * -- ' J * \` ,' K 6 20 50 75 100 25 50 100 25 50 100 200 >. -t > 30 30 30 30 30 30 - * x,, s' ?* < C ' t * ~* , ` < * 2 * .--is,., - ,, ' ' ,s - 7 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 0 9 0 0 4 -1 1 5 09 0 0 4 -1 1 5 09 0 0 4 -1 1 5 09 0 0 4 -1 1 5 09 0 0 4 -1 1 5 09 0 0 4 -1 1 5 8 9 10 3 0 1 0 0 0 1 -1 4 6 20 30 1 0 0 0 1 -1 4 6 50 30 10 0 0 1 -1 4 6 75 30 10 0 0 1 -1 4 6 100 30 10 0 0 1 -1 4 5 25 30 10 0 0 1 -1 4 5 50 30 10 0 0 1 -1 4 5 100 30 0 9 0 0 4 -1 1 4 25 30 0 9 0 0 4 -1 1 4 50 3 0 0 9 0 0 4 -1 1 4 100 30 0 9 0 0 4 -1 1 4 200 - . \\y \ s r-'r. . 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 1 0 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 3 0 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 1 0 0 0 1 -1 4 5 30 3 0 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 30 10 0 0 1 -1 4 5 30 11 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM ' GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 12 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 13 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 14 / 1O K / Nv iSi y _________ t e / r o __________ ' v K _____________ 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 2 Exact Copy of Original O ff* -Sr-f* initial " Date Page 51 of 539 G L P 1 0 -0 1 -01-01 G L P 10-01-02-01 E T S -8 -0 5 3 Samples Extracted 08-Apr-2010 P res cre e n in g S a m p le ID S a m p le D e s c rip tio n G L P 1 0 -0 1 -01 -0 1 -0 2 4 G L P 1 0 -0 1 -01 -0 1 -0 2 5 G L P 1 0 -0 1 -0 1 -0 1 -0 2 6 G L P 1 0 -0 1 -01 -0 1 -0 2 7 G L P 1 0 -0 1 -0 1 -0 1 -0 2 8 G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 G L P 1 0 -0 1 -01 -0 1 -0 3 0 G L P 1 0 -0 1 -01 -0 1 -0 3 3 G L P 1 0 -0 1 -0 1 -0 1 -0 3 4 2 DAL DF11 SS S S 05 0 0000 DAL DF11 SS S S 05 0 0010 DAL DF11 SS S S 051 0010 DAL D F11 SS SS06 0 0000 DAL D F11 SS SS06 0 0010 DAL D F11 SS SS07 0 0000 DAL D F11 SS SS07 0 0010 S o il T rip B la n k 1 S o il T rip B la n k 3 C ol 3 & 4: QP rf B a la n c e ID : 9 0 0 B C o l 5 & 6 : >f r f y - f - / 0 P ip e tte ID : 1 0 9 3 4 6 7 S o il M a x trix ID S o il W e ig h t U s e d (g ) S p ik e ID S p ik e V o lu m e <uL) In te rn a l S ta n d a rd ID In te rn a l S ta n d a rd V o lu m e (u L ) S u rro g a te S p ik e ID S u rro g a te S p ik e V o lu m e (u L ) Add 8 mL E x tra c tio n S o lv e n t S o n ic a te 1 hr C e n trifu g e C o m m e n ts 34 5 67 8 9 10 1 1 12 13 14 1 .5 1 5 0 % 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 1 .9 1 5 9 1 .5 6 2 7 * '' * 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 ` 4 ' v * 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 GPM GPM GPM GPM GPM GPM GPM GPM GPM / / / > 1 .5 5 6 7 - ,i ` 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 GPM GPM GPM ,A /\ 1 .8 8 7 8 ? 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 GPM GPM GPM f j y (L 1 .7 7 3 5 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 GPM GPM GPM 1 .7 2 2 4 1 .1 1 8 1 1 .1 0 5 6 -~ 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 0 9 0 0 4 -1 1 5 3 0 10 0 0 1 -1 4 5 30 0 9 0 0 4 -1 1 5 30 10 0 0 1 -1 4 5 30 GPM GPM GPM GPM GPM GPM GPM GPM GPM y / y LPr\ C o l 7 & 8 : b* * 7 P ip e tte ID : 1 0 9 3 4 6 7 C ol 9 & 10: P ip e tte ID : 1 0 9 3 4 6 7 16 Col 11: //-S '"/ O E x tra c tio n S o lv e n t ID : 0 9 0 0 4 - 1 1 6 Col 12: y - '" /l5 S o n ic a to r ID : Q E J 1 0 0 5 9 5 0 0 3 C ol 13: C e n trifu g e ID : 0 2 1 1 8 8 -5 5 1 0 m in @ 3 0 0 0 R P M Col 14: ^ 4 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 2 * Date Page 52 of 539 Extract Dilutions GLP10-01-02-01 SamlpeIO Samlpe Description Dateof Originai Extraction iDluted? Yes/No iDluted?* Yes/No iDluted?* Yes/No iDluted?* Yes/No iDluted?* Yes/No 1 G LP 10-01 01-01-009 G L P 10-01 -0 1 -0 1 -0 0 9 Dup G L P 10-01-01-01 -0 0 9 LM S G LP 10-01-01-01-011 G L P 1 0 -0 1 -01 -0 1 -0 1 1 Dup G L P 1 0 -0 1 -01 -0 1 -0 1 1 LM S G L P 1 0 -0 1 -01 -0 1 -0 1 2 G L P 10-01-0 1 -01-012 Dup G L P 10 -0 1 -01-01-012 LM S G L P 10-01-01-01-013 G L P 10 -0 1 -01-01-013 Dup G L P 10 -0 1 -01-01-013 LM S G L P 10-01-01-01-014 G L P 10 -0 1 -01-01-014 Dup G L P 10-01-0 1 -01-014 LM S G L P 1 0-01 -0 1 -0 1 -0 1 5 G L P 10 -0 1 -01-01-015 Dup G L P 10 -0 1 -01-01-015 LM S G L P 10-01-01-01-020 G L P 10-01-0 1 -01-020 Dup G L P 10 -0 1 -01-01-020 LM S G L P 10-01 -01 -01 -021 G L P 1 0 -0 1 -01 -0 1 -0 2 1 Dup G L P 1 0 -0 1 -0 1 -0 1 -021 LM S G L P 10-01 -01 -01 -0 2 2 G L P 10-01 -01 -01 -0 2 2 Dup G L P 10-01-0 1 -01-022 LM S G L P 10-01-01-01-028 G LP 10-01 -0 1 -0 1 -0 2 8 Dup G L P 10-01-0 1 -01-028 LM S G L P 10-01-01-01-017 G L P 1 0 -01-01-01-017 Dup G L P 1 0 -01-01-01-017 LM S G L P 10 -0 1 -0 1 -01-018 G L P 1 0 -01-01-01-018 Dup G LP 10-01-0 1 -0 1 -0 1 8 LM S G LP 10 -0 1 -01-01-019 G L P 1 0 -01-01-01-019 Dup G L P 1 0 -01-01-01-019 LM S 2 DAL DF05 SS SS09 0 0000 D A L D F 0 5 S S S S 0 9 0 0 0 0 0 S a m p le D uplicate D A L D F 0 5 S S S S 0 9 0 0 0 0 0 L ab M atrix Spike DAL DF05 SS SS10 0 0000 D A L D F 0 5 S S S S 1 0 0 0 0 0 0 S a m p le D uplicate D A L D F 0 5 S S S S 10 0 0 0 0 0 L ab M atrix Spike DAL D F05 SS SS 10 0 0010 D A L D F 0 5 S S S S 1 0 0 0 0 1 0 S a m p le D uplicate D A L D F 0 5 S S S S 1 0 0 0 0 1 0 L ab M atrix Spike D A L D F 8C S S S S 0 1 0 0 0 0 0 D A L D F 6C S S S S 0 1 0 0 0 0 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L D F 8C S S S S 0 1 0 0 0 1 0 D A L D F 8C S S S S 0 1 0 0 0 1 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 1 0 0 0 1 0 L a b M a trix S p ik e D A L D F 8C S S S S 0 2 0 0 0 0 0 D A L D F 8C S S S S 0 2 0 0 0 0 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 2 0 0 0 0 0 L a b M a trix S p ik e D A L D F 8C S S S S 0 4 0 0 0 0 0 D A L D F 8C S S S S 0 4 0 0 0 0 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 4 0 0 0 0 0 L a b M a trix S p ik e D A L D F 8C S S S S 0 4 0 0 0 1 0 D A L D F 8C S S S S 0 4 0 0 0 1 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 4 0 0 0 1 0 L a b M a trix S p ik e D A L D F 8C S S S S 0 5 0 0 0 0 0 D A L D F 6C S S S S 0 5 0 0 0 0 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 5 0 0 0 0 0 L a b M a trix S p ik e DAL DF11 SS S S06 0 0010 D A L D F 11 S S S S 0 6 0 0 0 1 0 S a m p le D uplicate D A L D F 11 S S S S 0 6 0 0 0 1 0 L ab M atrix Spike D A L D F 8C S S S S 0 3 0 0 0 0 0 D A L D F 8C S S S S 0 3 0 0 0 0 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 3 0 0 0 0 0 Lab M atrix Spike D A L D F 8C S S S S 0 3 0 0 0 1 0 D A L D F 8C S S S S 0 3 0 0 0 1 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 3 0 0 0 1 0 L a b M a tr ix S p ik e DAL D F 8C S S S S 03 1 0010 D A L D F 8C S S S S 0 3 1 0 0 1 0 S a m p le D u p lic a te D A L D F 8C S S S S 0 3 1 0 0 1 0 L a b M a trix S p ik e 3 4/26/2010 4 /26 /20 10 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4 Yes Yes s 'S Yes **!. Yes Yes Yes Yes Yes s Yes Yes Yes i*S Yes Yes Yes Yes Yes Yes Yes i. Yes | vlS | B M I ^ M i | r.o P | j ,- v .... 5 1 1-- Nj I 1F - 'N o ^ ' \ an san e; Nm * wm * M H l i l H H f W M M M t& m s s s & Ne m m m am m am m m m m m w w m m no ; , r> N 0 ' ,{ > *%>No Asl m m m m gm m K M 1K W M H S W W ** * M N oY ' l M M B B P W B IIM M \,, H H IS ` i/ No j * * * iim m m o w m m m m M S * * m asm ssm m m m m w sm N V. No ' , aM V W m m m m m m m rn m g m m mmmm llt f S f lili na m ssaunm H igi^N o Ne 1-- i N o llillilll w m m ai W M x&W M B , W M s a m m m - m M m m m > .. ,, S^No K .* ia u N 5 fc .x T i. IlN o if|g ||f| W fi lB M i Yes Yes N Yes Yes Yes Yes Yes Nw Yes Yes I N N, * W t ll8 ll ` = w m m m B. *. ' " ------------------ , Nq ,, - ' m m m m rn m mmmmmm wm w il wm m m m m T) " t ,,N o ~ M rH o*m , * * P ip e tte : E p p e n d o r f______________ M o d e l: R e s e a r c h ________ I.D .: 1 0 9 3 4 6 7 Int/Date ^ Cj 3M Study: GLP10-01-02 Interim Report 01 * * P ip e tte : E p p e n d o r f_____________ M o d e l: R e s e a r c h ________ I.D .: 2 6 5 8 9 3 lnt/Date_ 6 / > r ~ 7 V - 7 0 > V O Page 1 of 3 Page 53 of 539 Extract Dilutions GLP10-01-02-01 S a m p le ID S am p le D es c rip tio n D ate o f O rig in a l E xtra c tio n D ilu te d ? Y e s /N o D ilu te d ? * Y e s /N o D ilu ted ? * Y e s /N o D ilu te d ? * Y e s /N o D ilu te d ? ' Y e s /N o 1 G LP 10-01-01-01-023 G LP 10 -0 1 -01-01-023 Dup G L P 10 -0 1 -01-01-023 LM S G LP 10-01-01-01-024 G LP 10-01-01-01 -0 2 4 Dup G L P 10-01-01-01 -0 2 4 LM S G LP 10-01-01-01-025 G L P 10-01-01-01-025 Dup G LP 10-0 1 -0 1 -0 1 -0 2 5 LM S G LP 10-01-01-01 -026 G LP 10-01-01-01 -0 2 6 Dup G LP 10-01-01-01 -0 2 6 LM S G LP 10-0 1 -0 1 -0 1 -0 2 7 G L P 10-01-01-01 -0 2 7 D up G L P 10-01-01-01 -0 2 7 LM S G LP 10-01-01-01-029 G LP 10-01-01-01 -0 2 9 D up G L P 10-01-01-01 -0 2 9 LM S G L P 10-01-01-01-030 G LP 10-01-01-01 -0 3 0 D up G L P 1 0 -01-01-01-030 LM S L C S -100415-07 L C S -100415-08 L C S -100415-09 G L P 1 0 -0 1 -0 1 -0 1 -0 1 7 Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 1 7 D u p Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 1 7 L M S Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 1 8 D i!.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 1 8 D u p D il.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 1 8 L M S Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 1 9 Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 1 9 D u p D il.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 1 9 L M S D il.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 2 3 D il.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 2 3 D u p Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 2 3 L M S Dil.xSO G L P 1 0 -0 1 -0 1 -0 1 -0 2 4 Dil.xSO G L P 10-0 1 -0 1 -0 1 -0 2 4 D u p D il.x50 G L P 1 0 -0 1 -0 1 -0 1 -0 2 4 L M S Dil.xSO Cot 4: V o lum e o f sam ple added*:___ gC V o lum e o f D iluent Added**: 98 D iluent ID M B-100415-08 l'ft S pDilution Factor, Int/Dato I I I I f wsem. 2 DAL DF8C SS SS05 0 0010 D A L D F 8 C S S S S 0 5 0 0 0 1 0 S am p le D uplicate D A L D F 8 C S S S S 0 5 0 0 0 1 0 Lab M atrix Spike DAL DF11 SS S S05 0 0000 D A L D F 1 1 S S S S 0 5 0 0 0 0 0 S a m p le D uplicate D A L D F 1 1 S S S S 0 5 0 0 0 0 0 Lab M atrix Spike DAL DF11 SS S S05 0 0010 D A L D F 1 1 S S S S 0 5 0 0 0 1 0 S a m p le D uplicate D A L D F 1 1 S S S S 0 5 0 0 0 1 0 L ab M atrix Spike DALDF11 S S S S 05 1 0010 D A L D F 1 1 S S S S 0 5 1 0 0 1 0 S a m p le D uplicate D A L D F 1 1 S S S S 0 5 1 0 0 1 0 Lab M atrix Spike DALDF11 SS SS06 0 0000 D A L D F 1 1 S S S S 0 6 0 0 0 0 0 S a m p le D uplicate D A L D F 1 1 S S S S 0 6 0 0 0 0 0 L ab M atrix Spike DALDF11 SS SS07 0 0000 D A L D F 1 1 S S S S 0 7 0 0 0 0 0 S a m p le D uplicate D A L D F 1 1 S S S S 0 7 0 0 0 0 0 L ab M atrix Spike DAL DF11 SS SS07 0 0010 D A L D F 1 1 S S S S 0 7 0 0 0 1 0 S am p le D uplicate D A L D F 1 1 S S S S 0 7 0 0 0 1 0 L ab M atrix Spike 3 0 0 n q L C S in T C R -8 4 2 3 0 0 n q L C S in T C R -8 4 2 3 0 0 nq L C S in T C R -8 4 2 D A L D F 8 C S S S S 0 3 0 0 0 0 0 D il.x50 D A L D F 8 C S S S S 0 3 0 0 0 0 0 S am p le D uplicate D il.x50 D A L D F 8 C S S S S 0 3 0 0 0 0 0 L a b M a trix S p ik e Dil.xSO D A L D F 8 C S S S S 0 3 0 0 0 1 0 Dil.xSO D A L D F 8 C S S S S 0 3 0 0 0 1 0 S a m p le D u p lic a te Dil.xSO D A L D F 8 C S S S S 0 3 0 0 0 1 0 L a b M a trix S p ik e Dil.xSO D A L D F 8 C S S S S 0 3 1 0 0 1 0 Dil.xSO D A L D F 8 C S S S S 0 3 1 0 0 1 0 S a m p le D u p lic a te Dil.xSO D A L D F 8 C S S S S 0 3 1 0 0 1 0 Lab M atrix S p ike D il.x50 D A L D F 8 C S S S S 0 5 0 0 0 1 0 Dil.xSO D A L D F 8 C S S S S 0 5 0 0 0 1 0 S a m p le D u p lic a te Dil.xSO D A L D F 8 C S S S S 0 5 0 0 0 1 0 Lab M atrix S p ike D il.x50 D A L D F 1 1 S S S S 0 5 0 0 0 0 0 Dil.xSO D A L D F 1 1 S S S S 0 5 0 0 0 0 0 S a m p le D u p lic a te Dil.xSO D A L D F 1 1 S S S S 0 5 0 0 0 0 0 Lab M atrix S p ike D il.x50 3 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 4/26/2010 45678 .Yes '^ N O m No**" ` Yes \ s * * & N o . ..Yes '> Yes ) No N ' * NO V " > W M m m M m s iim m m Yes w m m M M m m m m m ** Yes V. N o <1 'n $ r- .Yes - - N o 4 V Ni Yes Ho l ' . - S - V S N . - m M P M M P H Yes m m m m m m w a r n m u m Yes a B U N s i H l l l Yes ** No N- *. Mc. ..Yes N. .No > t\ No,, Yes **** H#*>: --m a c - > * *Yes p * * * w* mmmsstmammm t S | N I * | ' "3Yes * No & jN o * M ^^i^SSSSM "* a .Yes No' .N o,. No Yes Yes * M SB N > - v s kMhm. mm>&NNsom%;mtfii mmmMHoWMmm Yes Yes ** No a WKmmM . H B M iP iss .'"'`No `'o N o * . * No '> noYes 1 ^Nov . . N O Yes Yes mmgmtimm/mM ` ,NNo.. -- - il?. w m M m m m im wmmmmmmmm M WYes 1 * 1 '^ N o ' ' H Yes Nv No . lllllllll, Yes a fe -. N ~ *N o iy j / ^ Yes P ****** . . M. wmmmmm mYes * * a . * i N S m p M p liN S H I mKmsmmmmm Yes *. No* j ', Yes -muo. M 'A ' N oi No ' - , 4 M P *** Yes . . . t N o - r * . No' , Yes .. (N o mm W BmSmm T O ' NO w ' Yes m m m m M W i N o#**. mmm wmmmm Yes s h e n -; N o " '4<*< mmaYes m N o Yes |N o t W m tiB ^m m N N o -^ ^ . Yes |N 5 " P * * B N 3 P P P I H M IN i^ ^ a n Yes wmm N- m m M: Yes N* s ppp Col 5: Volum e of sam ple Volum e o f D iluent Added**:. 900 UL_ D iluent ID M B -10 04 15 -0 9 D ilution Factor:__ 10____ CM * 'i C> IllsVbtiCTe'ofeamPleiad^tl i ... * P ip e tte : E p p e n d o r f____________ M o d e l: R e s e a r c h ________ I.D .: 1 0 9 3 4 6 7 Int/Date C. /-Q ~ /c> * * P ip e tte : E p p e n d o r f____________ M o d e l: R e s e a r c h ________ I.D .: 2 6 5 8 9 3 Int/Date ( /**+ + C/~ Z ^ / S 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 3 Page 54 of 539 E x tract D ilutions CO o CO r c ccnn o ccno CD G L P 10-01-02-01 GIP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e s c rip tio n S o il M a xtrix S o li W e ig h t ID U s e d (g) S p ik e ID 1 EC -100415-01 E C -100415-02 E C -100415-03 EC -100415-04 EC -100415-05 E C -100415-06 E C -100415-07 E C -100415-08 EC -100415-09 EC -100415-10 EC -100415-11 EC -100415-12 M B--100415-01 M B --1 0 0 4 1 5 -0 2 M B --1 0 0 4 1 5 -0 3 M B --1 0 0 4 1 5 -0 4 M B --1 0 0 4 1 5 -0 5 M B --1 0 0 4 1 5 -0 6 L C S -1 0 0 4 1 5 -0 1 LC S -100415-02 L C S -1 0 0 4 1 5 -0 3 L C S -100415-04 L C S -100415-05 LC S -100415-06 LC S -100415-07 LC S -100415-08 L C S -1 0 0 4 1 5 -0 9 G L P 10-01-01-01-033 G L P 10-01 -01 -01 -0 33 D up G LP 10-01 -01 -01 -0 33 LM S G LP 10-01-01-01-034 G LP 10-01 -01 -01 -0 34 D ud G LP 10-01 -01 -0 1-03 4 LM S G LP 10-01-01-01-001 G LP 10-01-01-01-001 D ud G LP 10-01-01-01-001 LM S G LP 10-01-01-01-002 G LP 10-01-01-01-002 D ud G LP10-01-01-01-002 LMS G LP 10-01-01-01-003 G LP 10-01-01-01-003 D ud G LP 10-01-01-01-003 LM S G LP 10-01-01-01-004 G LP 10-01-01-01-004 D ud G LP 10-01-01-01-004 LM S G LP 10-01-01-01-005 G LP 10-01-01-01-005 D ud G LP 10-01-01-01-005 LM S G LP 10-01-01-01-007 G LP 10-01 -01 -01 -0 07 D ud G LP 10-01-01-01-007 LM S G LP10-01-01-01-008 G LP 10-01-01-01-008 D ud G LP 10-01-01-01-008 LM S G LP 10-01-01-01-010 G LP 10-01-01-01-010 D ud G LP10-01-01-01-010 LMS G LP 10-01-01-01-016 G LP10-01-01-01-016D U D G LP 10-01-01-01-016 LM S G LP 10-01-01-01-009 G LP 10-01-01-01-009 D ud G LP 10-01-01-01-009 LM S G LP10-01-01-01-011 G LP10-01-01-01-011 D ud G LP10-01-01-01-011 LMS G LP 10-01-01-01-012 G LP10-01-01-01-012 D ud G LP 10-01-01-01-012 LM S G LP 10-01-01-01-013 G LP10-01-01-01-013 D ud G LP 10-01-01-01-013 LM S G LP 10-01-01-01-014 G LP 10-01-01-01-014 D ud G LP 10-01-01-01-014 LM S G LP 10-01-01-01-015 G LP 10-01-01-01-015 Duo G LP 10-01-01-01-015 LM S G LP 10-01-01-01-020 G LP 10-01-01-01-020 D ud G LP 10-01-01-01-020 LMS G LP 10-01-01-01-021 G LP 10-01-01-01-021 D ud G LP10-01-01-01-021 LM S G LP 10-01-01-01-022 G LP 10-01-01-01-022 D ud G LP 10-01-01-01-022 LM S G LP 10-01-01-01-028 G LP 10-01-01-01-028 D ud G LP 10-01-01-01-028 LM S G LP 10-01-01-01-017 G LP 10-01-01-01-017 D ud G LP 10-01-01-01-017 LM S G LP 10-01-01-01-018 G LP 10-01-01-01-018 D ud G LP 10-01-01-01-018 LM S 2 0.2 na E xtracted C u rve P oint 0.5 no E xtracted C u rve P oint 0.75 na E xtracted C urve P oint 1 na E xtra cted C urve P oint 2.5 no E xtra cted C u rve P oint 5 na E xtra cted C urve Point 10 na E xtracted C urve P oint 25 no E xtra cted C urve P oint 50 no E xtracted C u rve P oint 100 na E xtracted C u rve P oint 20 0 no E xtracted C u rve P oint 50 0 na E xtracted C u rve P oint M eth od B la nk 1 w /o IS M eth o d B la nk 2 w /o IS M eth o d B la nk 3 w /o IS M eth od B la nk 4 w / IS M eth od B la nk 5 w / IS M e th o d B la n k 6 w / IS 3 no LC S in T C R -8 42 3 na LC S in T C R -8 42 3 na LC S in T C R -8 42 30 na LC S in T C R -8 42 30 na LC S in T C R -8 42 30 na LC S in T C R -8 42 30 0 na LC S in TC R -842 30 0 na LC S in TC R -842 30 0 no LC S in TC R -842 S o il TriD B la n k 1 S o il TriD B la n k 1 S a m p le D up lica te S oil T rio B la nk 1 La b M atrix Soike Soil T rio B la nk 3 S o il TriD B la n k 3 S a m p le D up lica te S oil T rio B la nk 3 La b M atrix Soike DAL DF05 SS SS06 0 0000 D A L D F 05 S S S S 06 0 0 0 0 0 S a m o le D up lica te D A L D F 05 S S S S 06 0 0000 Lab M atrix Soike DAL DF05 SS SS06 0 0010 D A L D F05 S S S S 06 0 0 0 1 0 S a m o le OuDlicate D A L D F 05 S S S S 06 0 0 0 10 La b M atrix Soike DAL DF05 SS SS06 1 0010 D A L D F 05 S S S S 06 1 0 0 1 0 S a m o le D uo lica te D A L D F05 S S S S 06 1 0 0 10 La b M atrix Soike DAL DF05 SS SS07 0 0000 D A L D F 05 S S S S 07 0 0 0 0 0 S a m o le D uD licate D A L D F 05 S S S S 07 0 0 0 00 La b M atrix Soike DAL DF05 SS SS07 0 0010 D A L D F 0 5 S S S S 07 0 0 0 1 0 S a m p le D uD licate D A L D F 05 S S S S 07 0 0 0 10 La b M atrix Soike DAL DF05 SS SS08 0 0000 D A L D F05 S S S S 0 8 0 0 0 0 0 S a m o le D up lica te D A L D F 05 S S S S 08 0 0 0 00 La b M atrix Spike DAL DF05 SS SS08 0 0010 D A L D F 05 S S S S 0 8 0 0 0 1 0 S a m o le D up lica te D A L D F 05 SS S S 08 0 0 0 10 Lab M atrix S oike DAL DF05 SS SS09 0 0010 D A L D F05 S S S S 0 9 0 0 0 1 0 S a m o le D up lica te D A L D F 05 SS S S 09 0 0010 Lab M atrix S oike DAL DF8C SS SS02 0 0010 D A L D F 8 C S S S S 02 0 0 0 1 0 S a m p le D up lica te D A L D F 8C S S S S 02 0 00 10 La b M atrix Soike DAL DF05 SS SS09 0 0000 D A L D F 05 S S S S 0 9 0 0 0 0 0 S a m o le D uo lica te D A L D F 05 S S S S 0 9 0 0 0 0 0 Lab M atrix SDike DAL DF05 SS SS10 0 0000 D A L D F 05 S S S S 1 0 0 0 0 0 0 S a m p le D up lica te D A L D F 05 SS S S 10 0 0000 La b M atrix Soike DAL D F05S S SS10 0 0010 D A L D F 05 S S S S 1 0 0 0 0 1 0 S a m o le D uo lica te D A L D F 05 SS S S 10 0 0 0 10 Lab M atrix Soike DAL DF8C SS SS01 0 0000 D A L D F 8 C S S SS 01 0 0 0 0 0 S a m p le D up lica te D A L D F 8C S S SS01 0 00 00 La b M atrix Soike DAL DF8C SS SS01 0 0010 D A L D F 8 C S S SS 01 0 0 0 1 0 S a m o le D up lica te D A L D F 8C S S SS01 0 00 10 Lab M atrix Soike DAL DF8C SS SS02 0 0000 D A L D F 8 C S S S S 02 0 0 0 0 0 S a m o ie D uo lica te D A L D F 8C SS S S 02 0 0 0 00 Lab M atrix Spike DAL DF8C SS SS04 0 0000 D A L D F 8C S S S S 04 0 00 00 S a m o le D up lica te D AL D F8C S S SS 04 0 0000 Lab M atrix Spike DAL DF8C SS SS04 0 0010 D A L D F 8C S S S S 04 0 0 0 1 0 S a m p le D uo lica te D A L D F 8C S S S S 04 0 0 0 10 La b M atrix Spike DAL DF8C SS SS05 0 0000 D A L D F 8 C S S S S 05 0 0 0 0 0 S a m p le D up lica te D A L D F 8C S S S S 05 0 0 0 00 La b M atrix Soike DAL DF11 S S S S 0 6 0 0 0 1 0 D A L D F11 S S S S 0 6 0 0 0 1 0 S a m p le D uo lica te D A L D F 1 1 SS S S 06 0 0 0 10 La b M atrix Spike DAL DF8C SS SS03 0 0000 D A L D F 8 C S S S S 03 0 0 0 0 0 S a m o le D up lica te D A L D F 8C S S S S 03 0 0 0 00 La b M atrix Soike DAL DF8C SS SS03 0 0010 D A L D F 8 C S S S S 03 0 0 0 1 0 S a m p le D up lica te D A L D F 8C S S S S 03 0 0 0 10 La b M atrix Soike 3 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10001-152 '* V' u ; . ... >: - ' , t x ..........; S- , iX'f, ,'i ......................... 4 1.0875 1.1064 1.0895 1.0745 1.0530 1.0814 1.0701 1.0410 1.0569 1.0549 1.0867 1.0897 1.0976 1.0940 1.1337 1.0546 1.0928 1.0917 1.0886 1.0643 1.0627 1.0896 1.1277 1.0657 1.0618 1.0885 1.0782 1.0883 1.0960 1.0921 1.1055 1.0831 1.0642 1.9650 1.6981 1.8718 1.8628 1.8337 1.8281 1.8000 1.7175 1.4970 1.2318 1.1116 1.1882 1.1131 1.2355 1.0833 1.9483 1.9822 1.8844 1.6034 1.6661 1.7140 1.6385 1.4065 1.4571 1.0448 0 .9 7 8 0 0 .9 6 9 9 1.2599 1.2863 1.1470 1.5271 1.1321 1.1709 1.1801 0 .9 9 6 6 1.1851 1.7547 1.6576 1.9182 1.6942 1.6684 1.6845 1.7736 1.9036 1.5627 1.3256 1.3835 1.3379 1.4547 1.4181 1.7787 1.5340 1.3891 1.6003 1.9205 2.0055 1.9234 1.4815 1.5682 1.8270 1.4471 1.4871 1.4995 5 10 001-151 10 001-151 10 001-151 10 001-151 10 001-150 10 001-150 10 001-150 10 001-149 10001-149 10001-149 09 004-118 09 004-118 10 001-148 10001-148 10 001-148 10001-147 10 001-147 10 001-147 09 004-117 09 004-117 09 004-117 S p ike V o lum e <uL> In te rn a l S tandard ID In tern al S tandard V o lu m e (u L ) S urrogate S p ik e ID S u rro ga te S p ike V o lum e <UL) PFB S S pike ID PFBS S pike V o lum e <uL) 6 7 8 9 10 11 12 20 09 004-128 30 10 001-146 20 . 50 09 004-128 30 10 001-146 50 s a H H ii u t t o r . 75 0 9 0 0 4 -1 2 8 3 0 10 0 0 1 -1 4 6 7 5 % *4s Y * r 'i * & ' 100 09 004-128 30 10 001-146 100 25 0 9 0 0 4 -1 2 8 3 0 10 0 0 1 -1 9 6 2 5 t ? * c 3 F w & r-`3 S B S S S -? .'". 50 09 004-128 30 10 001-196 50 , 1 Vs 100 09 004-128 30 10 001-196 100 ' T '.< ' ? 0 -v 25 09 004-128 30 09 004-125 25 50 09 004-128 30 09 004-125 50 100 09 004-128 30 09 004-125 100 ItS F ? 20 09 004-128 30 09 004-125 200 \.u - m - 50 09 004-128 30 09 004-125 500 . ni- % R v , 1 v 'i. .t, i i ' t. r *$ 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 30 09 004-128 30 10 001-196 30 * ' '* < -, ' ' ft.'-" ' : v- H 30 09 004-128 30 10001-196 30 3 0 0 9 004-128 3 0 10 0 0 1 -1 9 6 3 0 30 09 004-128 30 10 001-196 30 30 09 004-128 30 10 001-196 30 30 09 004-128 30 10 001-196 30 ` .r , C . " - 30 09 004-128 30 10 001-196 30 30 09 004-128 30 10 001-196 30 30 09 004-128 30 10001-196 30 * *;-A 1 * ' 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10001-196 30 08 008-124-5 100 09 004-128 30 10001-196 30 . ... - ' . 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10001-196 30 08 008-124-5 100 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 00 1-1 96 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 00 1-1 96 30 08 008-124-5 100 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-4 100 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-4 100 3M Study: GLP10-01-02 Interim Report 01 Page 1 o f 4 6A * Page 56 of 539 GLP10-01-02-01 TS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e s c rip tio n S o il M axtrix S o il W e ig h t ID U sed (g) S p ik e ID 1 G L P 10-01-01-01-019 G LP10-01-01-01-019 Dup G LP 10-01 -01 -01 -0 1 9 LM S G LP 10-01-01-01-023 G LP 10-01-01-01-023 Dup G LP 10-01-01-01-023 LM S G LP 10-01-01-01-024 G LP 10-01-01-01-024 Dup G LP 10-01-01-01-024 LM S G LP 10-01-01-01-025 G LP 10-01-01-01-025 Dup G LP 10-01-01-01-025 LM S G LP 10-01-01-01-026 G LP 10-01-01-01-026 Duo G LP 10-01-01 -01 -0 26 LM S G LP 10-01-01-01-027 G LP 10-01-01-01-027 Duo G LP 10-01-01-01-027 LM S G LP 10-01-01-01-029 G LP 10-01-01-01-029 Dup G LP 10-01-01-01-029 LM S G LP 10-01-01-01-030 G LP 10-01-01-01-030 D ud G LP 10-01-01-01-030 LM S M B - 100415-07 M B - 100415-08 M B --1 0 0 4 1 5 -0 9 M B --1 0 0 4 1 5 -1 0 M B --1 0 04 15 -11 2 DAL DF8C SS SS03 1 0010 D A L D F 8 C S S S S 03 1 0 0 1 0 S a m p le D up lica te D A L D F 8C SS S S 03 1 0 0 10 La b M atrix Spike DAL DF8C SS SS05 0 0010 D A L D F 8 C S S S S 05 0 0 0 1 0 S a m p le D up lica te D A L D F 8C S S S S 05 0 0 0 10 La b M atrix Spike DAL D F 11 SS SS05 0 0000 D A L D F11 SS S S 05 0 00 00 S a m p le D up lica te D A L D F11 SS S S 05 0 0000 Lab M atrix Spike DAL D F11 SS SS05 0 0010 D A L D F 1 1 S S S S 05 0 00 10 S a m p le D up lica te D A L D F11 S S S S 05 0 0010 Lab M atrix Spike DAL D F11 SS SS05 1 0010 D A L D F 1 1 S S S S 05 1 0 0 1 0 S a m p le D up lica te D A L D F 1 1 S S S S 05 1 0010 Lab M atrix Spike DAL DF11 SS SS06 0 0000 D A L D F 1 1 S S S S 06 0 0 0 0 0 S a m p le D up lica te D A L D F11 S S S S 06 0 00 00 La b M atrix Spike D AL DF11 SS SS07 0 0000 D A L D F11 S S S S 07 0 0 0 0 0 S a m p le D up lica te D A L DF11 SS SS07 0 0000 Lab M atrix S pike D A L O F 11 S S S S 0 7 0 0 0 1 0 D A L D F 1 1 S S S S 07 0 0 0 1 0 S a m p le D up lica te D A L D F 11 S S S S 0 7 0 0 0 1 0 L a b M a trix S p ik e M eth od B la nk 5a w / IS fo r D ilutions M eth od B la nk 5q w / IS fo r D ilu tion s M eth od B la n k 5a w / IS fo r D ilu tion s M eth od B la n k 5 a w / IS fo r D ilu tion s M eth od 8 la n k 5a w / IS fo r D ilu tion s 3 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 4 1.2515 1.3724 1.1744 1.5147 1.5388 1.5402 1.4952 1.3211 1.6172 1.7416 1.6269 1.7067 1.5825 1.4943 1.4205 1.5721 1.7218 1.6041 1.5987 1.4491 1.4063 1.5521 1.4415 1.5209 5 .0 2 5 7 4 .9 6 5 9 5 .1 3 0 2 5.0913 5.0688 C ol 3 & 4: /J lA B alance ID : 90 0 Col 5 & 6: C $ C 1 P ipette ID: 1093467 / 5 S p ike V o lum e (u L ) In tern al S tandard ID In te rn a l S tandard V o lum e (u L ) S u rro ga te S p ik e ID S u rro ga te S p ike V o lu m e <uL) PFB S S pike ID PFBS S pike V o lum e (uL) 6 7 6 9 1 0 11 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-4 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-4 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-126 30 10 001-196 30 08 008-124-5 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 0 9 0 0 4 -1 2 8 3 0 f 0 0 0 f- 1 9 6 3 0 0d 008-124-4 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 09 004-128 30 10 001-196 30 08 008-124-5 09 004-128 150 10001-196 150 09 004-128 150 10 001-196 150 09 004-128 150 10001-196 150 09 004-128 150 10 001-196 150 09 004-128 150 10 001-196 150 C ol 7 & 8: C o l 11 & 12: Q f r i . P ipette ID: 1093467 Pipette ID : 1093467 265893 (for volum es ove r 100 uL) c o i 9 & io : 6 (> r* i t j- ic -- ) o P ipette ID: 1093467 265893 (for volum es o ve r 100 uL) -M r t * 12 100 100 100 100 100 100 to o 100 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 4 Page 57 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e s c rip tio n L-PFH xS S p ik e ID L-PFH xS S p ike V o lum e (u L ) L-PFO S S p ik e ID L-PFO S S p ike V o lum e <uL) E xtra ctio n S o lve n t V o lu m e (m L) S o nica te 1 h r 1 EC -100415-01 EC -100415-02 E C -1 0 0 4 1 5 -0 3 E C -1 0 0 4 1 5 -0 4 E C -1 0 0 4 1 5 -0 5 EC -100415-06 E C -1 0 0 4 1 5 -0 7 E C -100415-08 EC -100415-09 EC -100415-10 EC -100415-11 EC -100415-12 M B -100415-01 M B - 100415-02 M B -100415-03 M B -100415-04 M B -100415-05 M B - 100415-06 L C S -1 0 0 4 1 5 -0 1 LC S -100415-02 LC S -100415-03 LC S -100415-04 LC S -100415-05 LC S -100415-06 LC S -100415-07 LCS -100415-08 LCS -100415-09 G L P 10-01-01-01-033 G L P 10-01-01-01-033 D ud G LP 10-01-01-01-033 LM S G LP10-01-01-01-034 G LP 10-01-01-01-034 Dup G LP 10-01-01-01-034 LM S G LP10-01-01-01-001 G L P 10-01-01-01-001 DuD G LP 10-01-01-01-001 LM S G LP 10-01-01-01-002 G LP 10-01-01-01-002 D ud G LP10-01-01-01-002 LM S G LP 10-01-01-01-003 G LP 10-01-01-01-003 D ud G LP 10-01 -01-01-003 LM S G LP 10-01-01-01-004 G LP10-01-01-01-004 D ud G LP 10-01-01-01-004 LM S G LP 10-01-01-01-005 G LP 10-01-01-01-005 DuD G LP 10-01-01-01-005 LM S G LP 10-01-01-01-007 G LP 10-01-01-01-007 DuD G LP10-01-01-01-007 LMS G LP 10-01-01-01-008 G LP 10-01-01-01-008 DuD G LP 10-01-01-01-008 LM S G LP 10-01-01-01-010 G LP10-01-01-01-010 Dud G LP 10-01-01-01-010 LM S G LP 10-01-01-01-016 G LP10-01-01-01-016 Dup G LP 10-01-01-01-016 LM S G L P 10-01 -01-01-009 G LP 10-01-01-01-009 D ud G LP 10-01-01-01-009 LM S G LP10-01-01-01-011 G LP 10-01-01-01-011 D ud G LP10-01-01-01-011 LM S G LP 10-01-01-01-012 G LP 10-01-01-01-012 D ud G LP10-01-01-01-012 LM S G LP10-01-01-01-013 G LP 10-01-01-01-013 D ud G LP 10-01-01-01-013 LM S G LP 10-01-01-01-014 G LP 10-01-01-01-014 D ud G LP 10-01-01-01-014 LM S G LP 10-01-01-01-015 G LP10-01-01-01-015 Dup G LP 10-01-01-01-015 LM S G LP 10-01-01-01-020 G LP 10 -01-01-01-020 D ud G LP 10-01-01-01-020 LM S G LP 10-01-01-01-021 G LP10-01-01-01-021 D ud G LP 10-01-01-01-021 LM S G LP 10-01-01-01*022 G LP 10-01-01-01-022 D ud G LP10-01-01-01-022 LMS G LP 10-01-01-01-028 G LP 10-01-01-01-028 DuD G LP 10-01-01-01-028 LM S G LP 10-01-01-01-017 G L P 10-01-01-01-017 DuD G LP10-01-01-01-017 LMS G LP 10-01-01-01-018 G LP 10-01-01-01-018 D ud G LP 10-01-01-01-018 LM S 2 0.2 na E xtracted C urve P oint 0.5 no E xtracted C urve P oint 0.75 no E xtracted C urve Point 1 nq E xtra cted C urve P oint 2.5 nq E xtra cted C urve P oint 5 nq E xtra cted C urve P oint 10 nq E xtra cted C u rve P oint 25 nq E xtra cted C u rve P oint 50 no E xtra cted C urve P oint 10 0 n q E x tra c te d C u r v e P oint 20 0 nq E xtracted C urve Point 50 0 nq E xtracted C urve Point M eth od B la nk 1 w /o IS M ethod B la nk 2 w /o IS M ethod B lank 3 w /o IS M eth o d B la nk 4 w / IS M eth o d B la n k 5 w / IS M eth od B la nk 6 w / IS 3 nq LC S in TC R -842 3 nq LC S in TC R -8 42 3 nq LC S in T C R -8 42 3 0 nq L C S in TC R -8 42 30 nq LC S in T C R -8 42 30 nq LC S in T C R -8 42 300 nq LC S in T C R -8 42 300 nq LC S in T C R -8 42 300 nq L C S in T C R -8 42 Soil T rio B lank 1 S o il TriD B la n k 1 S a m le D u o lica te S o il TriD B la n k 1 L a b M a trix S o ike Soil T rip B lank 3 S o il TriD B la n k 3 S a m le D u o lica te S o il TriD B la n k 3 L a b M a trix S o ike DAL DF05 SS SS06 0 0000 D A L D F 05 SS S S 0 6 0 0 0 0 0 S a m p le D up lica te D A L D F 05 SS S S 0 6 0 0 0 0 0 La b M atrix SDike DAL DF05 SS SS06 0 0010 D A L D F 05 SS S S 0 6 0 0 0 1 0 Sam D le D uplicate D A L D F 05 SS S S 06 0 0 0 10 Lab M atrix Soike DAL DF05 SS SS06 1 0010 D A L D F 05 SS S S 0 6 1 0 0 1 0 S a m le D uo lica te D A L D F 05 SS S S 06 1 0 0 10 La b M atrix Soike DAL DF05 SS SS07 0 0000 D A L D F 05 SS S S 07 0 00 00 S a m le D uD licate D A L D F 05 SS S S 07 0 0000 Lab M atrix Soike DAL DF05 SS SS07 0 0010 D A L D F 05 S S S S 07 0 0 0 1 0 Sam D le D uo lica te D A L D F 05 S S S S 07 0 0 0 1 0 Lab M atrix SDike DAL DF05 SS SS08 0 0000 D A L D F 05 S S S S 08 0 0 0 0 0 Sam D le D uo lica te D A L D F 05 S S S S 08 0 00 00 La b M atrix Soike DAL DF05 SS SS08 0 0010 D A L D F 05 SS S S 0 8 0 0 0 1 0 S a m le D uo lica te D A L D F 05 SS S S 08 0 00 10 Lab M atrix Soike DAL DF05 SS SS09 0 0010 D A L D F 05 SS S S 09 0 0 0 1 0 S a m le D up lica te D A L D F 05 SS S S 09 0 00 10 Lab M atrix Soike DAL DF8C SS SS02 0 0010 D A L D F 8 C S S S S 02 0 0 0 1 0 S a m le D up lica le D A L D F 8 C S S S S 02 0 0 0 1 0 La b M atrix SDike DAL DF05 SS SS09 0 0000 D A L D F 05 S S S S 0 9 0 0 0 0 0 S a m le D up lica te D A L D F 05 SS S S 0 9 0 0 0 0 0 Lab M atrix SDike DAL DF05 SS SS10 0 0000 D A L D F 05 S S S S 10 0 0 0 0 0 S a m le D up lica te D A L D F 05 S S S S 10 0 0 0 0 0 La b M atrix SDike DAL DF05 SS SS10 0 0010 D A L D F 05 SS S S 1 0 0 0 0 1 0 Sam D le D uo lica te D A L D F 05 SS S S 1 0 0 0 0 1 0 La b M atrix SDike DAL DF8C SS SS01 0 0000 D A L D F 8 C S S SS01 0 0 0 0 0 S a m le D up lica te D A L D F 8 C S S SS 01 0 0 0 0 0 La b M atrix SDike DAL DF8C SS SS01 0 0010 D A L D F 8 C S S SS 01 0 0 0 1 0 Sam D le D uplicate D A L D F 8 C S S SS 01 0 0 0 1 0 La b M atrix SDike DAL DF8C SS SS02 0 0000 D A L D F 8 C S S S S 02 0 0 0 0 0 Sam D le D uolicate D A L D F 8 C S S S S 02 0 0 0 0 0 La b M atrix SDike DAL DF8C SS SS04 0 0000 D A L D F 8C S S S S 04 0 00 00 S a m le D uo lica te D A L D F8C SS S S 04 0 0000 Lab M atrix Soike DAL DF8C SS SS04 0 0010 D A L D F 8C S S S S 04 0 0 0 1 0 Sam D le D up lica te D A L D F8C S S S S 04 0 0 0 10 Lab M atrix Soike DAL DF8C SS SS05 0 0000 D A L D F 8 C S S S S 05 0 0 0 0 0 S a m le D uo lica te D A L D F 8C S S S S 05 0 0 0 00 La b M atrix Soike DAL D F11 SS SS06 0 0010 D A L D F11 SS S S 0 6 0 00 10 Sam D le D uplicate D A L D F11 SS S S 06 0 0 0 10 La b M atrix Soike DAL DF8C SS SS03 0 0000 D A L D F 8 C S S S S 03 0 0 0 0 0 Sam D le D uo lica te D A L D F 8 C SS S S 03 0 0 0 0 0 La b M atrix SDike DAL DF8C SS SS03 0 0010 D A L D F 8 C SS S S 03 0 0 0 1 0 Sam D le D up lica te D A L D F 8C SS S S 03 0 0 0 10 La b M atrix Spike 13 14 .1 : '' 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-4 100 08 008-125-4 100 08 008-125-5 100 08 008-125-4 100 08 008-125-5 100 08 008-125-5 100 08 008-125-5 100 08 008-125-4 100 08 008-125-4 100 08 008-125-3 100 08 008-125-3 100 15 08 008-126-5 08 008-126-5 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-3 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-2 08 008-126-1 08 008-126-1 16 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 17 8 8 8 8 8 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 8 8 8 6 8 6 6 6 8 6 6 6 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 6 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 6 8 6 18 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM C e n trifu g e 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM C om m ents 20 ------- ri t i ---------------------- 3M Study: GLP10-01-02 Interim Report 01 Page 3 of 4 Page 58 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e s c rip tio n L-PFH xS S p ik e ID L-PFH xS S p ike V o lum e <uL) L-PFO S S p ik e ID L-PFO S S p ike V o lum e (u L ) E xtra ctio n S o lve n t V o lu m e (m L) S o n ica te 1 hr C e n trifu g e C om m ents 1 G LP 10-01-01-01-019 G LP10-01-01-01-019 Duo G LP10-01-01-01-019 LM S G LP 10-01-01-01-023 G LP 10-01-01-01-023 Dup G UP10-01-01-01 -023 LM S G LP 10-01-01-01-024 G LP 10-01-01-01-024 Dup G L P 10-01-01-01-024 LM S G LP 10-01-01-01-025 G LP 10-01-01-01-025 Dup G LP 10-01-01-01-025 LM S G LP 10-01-01-01-026 G LP 10-01-01-01-026 Dup G LP 10-01-01-01-026 LM S G LP 10-01-01-01-027 G L P 10-01-01-01-027 Dup G LP 10-01-01-01-027 LM S G LP 10-01-01-01-029 G LP 10-01-01-01-029 Dup G LP 10-01-01-01-029 LM S G LP 10-01-01-01-030 G LP 10-01-01-01-030 Dup G LP 10-01-01-01-030 LM S M B --1 0 0 4 1 5 -0 7 M B -100415-08 M B - 100415-09 M B --1 0 0 4 1 5 -1 0 M B --10 04 15 -11 2 DAL DF8C SS SS03 1 0010 D A L D F 8 C SS S S 03 1 0 0 1 0 S a m p le D up lica te D A L D F 8C S S S S 03 1 0 0 10 La b M atrix Spike DAL DF8C SS SS05 0 0010 D A L D F 8 C S S S S 05 0 0 0 1 0 S a m p le D up lica te D A L D F 8C SS S S 05 0 0 0 10 La b M atrix S pike DAL DF11 SS SS05 0 0000 D A L D F11 SS S S 05 0 0 0 0 0 S a m p le D uplicate D A L D F 1 1 SS S S 05 0 0000 La b M atrix Spike DAL D F11 SS SS05 0 0010 D A L D F 1 1 SS S S 05 0 0 0 1 0 S a m p le D uplicate D A L D F11 S S S S 05 0 0 0 10 La b M atrix Spike DAL D F11 SS SS05 1 0010 D A L D F11 SS S S 05 1 0 0 1 0 S a m p le D uplicate D A L D F 1 1 SS S S 05 1 00 10 La b M atrix Spike DAL DF11 SS SS06 0 0000 D A L DF11 SS S S 0 6 0 0 0 0 0 S a m p le D up lica te D A L D F 11 S S S S 0 6 0 0 0 0 0 L a b M a trix S p ik e DAL DF11 SS SS07 0 0000 D A L D F 1 1 SS S S 07 0 0 0 0 0 S a m p le D uplicate D A L D F 1 1 SS S S 07 0 00 00 La b M atrix Spike DAL DF11 SS SS07 0 0010 D A L DF11 SS S S 07 0 0 0 1 0 S a m p le D up lica te D A L D F 1 1 SS S S 07 0 00 10 La b M atrix Spike M eth od B la n k 5o w / IS fo r D ilutions M eth od B la nk 5a w / IS fo r D ilu tion s M eth od B la nk 5a w / IS fo r D ilutions M eth od B la nk 5a w / IS fo r D ilutions M eth od B la n k 5a w / IS fo r D ilutions 13 08 008-125-3 08 008-125-3 08 008-125-4 08 008-125-4 08 008-125-4 08 008-125-4 08 008-125-3 08 008-125-4 14 100 100 100 100 100 100 100 100 C ol 13 & 14: P /* Pipette ID : 1093467 C ol 15 & 16: P ipette ID: 1093467 15 16 08 008-126-1 100 08 008-126-1 100 08 008-126-1 100 17 8 8 8 8 6 8 6 6 6 6 18 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 08 008-126-1 100 08 008-126-1 100 6 6 8 6 8 8 8 GPM GPM GPM GPM GPM GPM GPM 08 008-126-1 100 08 008-126-1 100 08 008-126-1 100 8 8 8 8 8 8 8 40 40 40 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 40 GPM 40 GPM \ 'f Col 17: / C~Io E xtra ction Solvent ID: 0 9 004-116 ^^ cons: G -fr* S o nica torlD : QEJ100595003 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 20 / / / / / n/ 4Ai(7 (V T A/ K/ -- ( V ----------------------- / fiiII/ { { / / f/ } C ol 19: C en trifug e ID: 02 1188-55 769613 (for 50m L tubes) 10 m in @ 3 0 0 0 R PM -- /$ 3M Study: GLP10-01-02 Interim Report 01 Page 4 of 4 Page 59 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e scrip tio n S o il M axtrix S o il W eigh t ID U s e d (g ) S p ik e ID S p ike V o lu m e (uL) In tern al S tandard ID In te rn a l S tandard V o lum e (uL) S u rro ga te S p ik e ID S urrogate S p ike V o lum e (uL) PFBS S p ik e ID PFBS S p ike V o lu m e (u L ) I EC -100415-01 EC -100415-02 EC -100415-03 E C -1 0 0 4 1 5 -0 4 EC -100415-05 E C -1 0 0 4 1 5 -0 6 E C -100415-07 E C -1 0 0 4 1 5 -0 8 E C -1 0 0 4 1 5 -0 9 E C -1 0 0 4 1 5 -1 0 EC -100415-11 E C -1 0 0 4 1 5 -1 2 M B --10 04 15 -01 M B -100415-02 M B --1 0 0 4 1 5 -0 3 M B --100415-04 M B --100415-05 M B --1 0 0 4 1 5 -0 6 LC S-100415-01 LC S -100415-02 LC S -100415-03 LC S -100415-04 LC S -100415-05 LC S -100415-06 LC S -100415-07 LC S -100415-08 LC S -100415-09 G LP10-01-01-01-033 G LP10-01-01-01-033 D ud G LP10-01-01-01 -033 LM S G LP 10-01-01-01-034 G LP10-01-01-01 -034 D ud G LP 10-01-01-01-034 LM S G L P 1 0-01 -01 -01 -001 G LP 10-01-01-01-001 D ud G L P 1 0-01 -01 -01 -001 LM S G L P 1 0-01 -01 -01 -002 G L P 1 0-01 -01 -01 -002 D ud G L P 1 0-01 -01 -01 -002 LM S G L P 1 0-01 -01 -01 -003 G LP 10-01-01-01-003 D ud G L P 1 0-01 -01 -01 -003 LM S G LP10-01-01-01-004 G LP 10-01-01-01-004 D ud G LP 10-01-01-01-004 LM S G LP10-01-01-01-005 G LP10-01-01-01-005 D ud G LP10-01-01-01-005 LM S G LP10-01-01-01-007 G LP 10-01-01-01-007 D ud G LP10-01-01 -01-007 LM S G LP10-01-01-01-008 G LP10-01 -01 -01-008 D ud G L P 10-01 -01 -01 -008 LM S G LP 10-01-01-01-010 G L P 10-01 -01 -01 -010 D ud G LP 10-01-01-01-010 LM S G L P 10-01 -01 -01 -016 G L P 10-0 1-01-01-016 D ud G LP 10-01-01-01-016 LM S G LP10-01-01-01-009 G LP10-01-01-01-009 D ud G L P 10-01 -01 -01 -009 LM S G L P 10-01 -01 -01 -011 G L P 10-01 -01 -01 -011 D ud G LP 10-01-01-01-011 LM S G L P 10-01 -01 -01 -012 G LP10-01-01-01-012 D ud G LP10-01-01-01-012 LM S G LP10-01-01-01-013 G LP10-01-01-01-013 D ud G LP10-01-01-01-013 LM S G LP10-01-01-01-014 G LP10-01-01-01-014 D ud G LP10-01-01-01-014 LM S G LP10-01-01-01-015 G LP 10-01-01-01-015 D ud G L P 10-01 -01 -01 -015 LM S G L P 10-01 -01 -01 -020 G L P 10-01 -01-01 -02 0 D ud G LP 10-01-01-01-020 LM S G L P 10-01-01-01-021 G LP10-01-01-01-021 D ud G LP10-01-01-01-021 LM S G LP10-01-01-01-022 G LP10-01-01-01-022 D ud G LP10-01-01-01-022 LM S G LP 10-01-01-01-028 G L P 10-01-01-01 -028 D ud G L P 10-01 -01 -01 -028 LM S G L P 10-01 -01 -01 -017 G L P 10-01-01-01-017 D ud G LP10-01-01-01-017 LM S G LP10-01 -01-01 -018 G LP10-01-01-01-018 D ud G LP10-01-01-01-018 LM S 2 0.2 na E xtracted C urve P oint 0.5 nq E xtracted C urve Point 0.75 no E xtracted C urve Point 1 na E xtracted C u rve P oint 2.5 nq E xtracted C urve Point 5 na E xtracted C urve Point 10 na E xtracted C urve Point 25 na E xtracted C urve Point 50 na E xtracted C urve P oint 100 na E xtracted C urve Point 20 0 na E xtracted C urve Point 500 na E xtracted C urve Point M ethod B lank 1 w /o IS M ethod B lank 2 w /o IS M ethod B lank 3 w /o IS M e th o d B la n k 4 w / IS M ethod B lank 5 w/ IS M ethod B lank 6 w / IS 3 na LC S in TC R -842 3 na LC S in TC R -842 3 na LC S in TC R -842 30 na LC S in TC R -842 30 na LC S in TC R -842 30 na LC S in TC R -842 300 na LC S in T C R -842 300 na LC S in TC R -8 42 300 na LC S in T C R -842 Soil T rio B lank 1 S o il T rip B la nk 1 S a m p le D up lica te S oil T rip B lank 1 Lab M atrix Spike S oil T rip B lank 3 S o il T rip B la nk 3 S a m p le D up lica te S o il TriD B la n k 3 L a b M a trix SDike DAL DF05 SS SS06 0 0000 O A L D F05 S S S S 06 0 0 0 00 S a m p le D up lica te D A L D F05 S S S S 06 0 00 00 Lab M a trix SDike DAL DF05 SS SS06 0 0010 D A L D F 05 S S S S 06 0 00 10 Sam D le D uplicate D A L D F 0 5 S S S S 06 0 0 0 1 0 L a b M a trix SDike DAL DF05 SS SS06 1 0010 D A L D F 05 S S S S 06 1 00 10 S a m p le D up lica te D A L D F 05 S S S S 06 1 00 10 Lab M a trix SDike DAL DF05 SS SS07 0 0000 D A L D F 05 S S S S 07 0 00 00 Sam D le D up lica te D A L D F 05 S S S S 07 0 00 00 La b M a trix SDike DAL DF05 SS SS07 0 0010 D A L D F 05 S S S S 07 0 0010 Sam D le D uD licate D A L D F 05 S S S S 07 0 0010 Lab M a trix SDike DAL DF05 SS SS08 0 0000 D A L D F05 S S S S 08 0 00 00 S a m cle D uD licate D A L D F05 S S S S 08 0 00 00 La b M a trix SDike D AL DF05 SS SS08 0 0010 D A L D F05 S S S S 08 0 00 10 S a m p le D up lica te D A L D F05 S S S S 08 0 00 10 La b M atrix SDike DAL DF05 SS SS09 0 0010 D A L D F05 S S S S 09 0 00 10 S a m p le D up lica te D A L D F05 SS S S 09 0 0010 La b M atrix Spike DAL DF8C SS SS02 0 0010 D A L D FSC S S S S 02 0 00 10 S a m p le D uplicate D A L D F8C S S S S 02 0 0010 Lab M atrix Spike DAL DF05 SS SS09 0 0000 D A L D F 05 S S S S 09 0 00 00 Sam D le D up lica te D A L D F05 SS S S 09 0 0000 Lab M atrix Spike DAL DF05 SS SS10 0 0000 D A L D F 05 S S S S 10 0 00 00 S a m p le D up lica te D A L D F05 S S S S 10 0 0000 Lab M atrix Spike DAL DF05 SS SS10 0 0010 D A L D F 05 S S S S 10 0 00 10 S a m p le D uD licate D AL D F05 S S S S 10 0 0010 Lab M atrix Spike DAL OF8C SS SS01 0 0000 D A L D F 8C SS SS01 0 00 00 Sam D le D uD licate D A L D F8C SS SS01 0 0000 La b M atrix Spike DAL DF8C SS SS01 0 0010 D A L D F 8C S S SS01 0 0010 S a m p le D up lica te D A L D F 8C S S SS01 0 0010 Lab M a trix SDike D AL DF8C SS SS02 0 0000 D A L D F 8C S S S S 02 0 00 00 Sam D le DuDlicate D A L DFSC SS S S 02 0 0000 La b M atrix S pike DAL DF8C SS SS04 0 0000 D A L D F 8C S S S S 04 0 00 00 Sam D le D up lica te D A L D F 8C S S S S 04 0 00 00 La b M a trix SDike DAL DF8C SS SS04 0 0010 D A L D F8C S S S S 04 0 00 10 S a m p le D up lica te D A L D F8C S S S S 04 0 00 10 La b M a trix SDike DAL DF8C SS SS05 0 0000 D A L D F8C S S S S 05 0 00 00 S a m p le D up lica te D A L D F8C S S S S 05 0 0000 Lab M atrix Spike DALDF11 SS SS06 0 0010 D A L DF11 S S S S 06 0 00 10 Sam D le D up lica te D A L D F11 S S S S 06 0 00 10 La b M a trix SDike DAL DFSC SS SS03 0 0000 D A L D FSC S S S S 03 0 0000 Sam D le D uD licate D A L D FSC SS S S 03 0 0000 Lab M atrix Spike DAL DFSC SS SS03 0 0010 D A L D F 8C S S S S 03 0 00 10 S a m p le D uplicate D A L D F8C SS S S 03 0 0010 La b M atrix Spike 3 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 mmmmm mmmmmm mmmmm S B *** ................... : mmmmmm mmmmm ^m m m m m m mmmmm U -- ________ : W* im m m m m m ** 8 * !* t* * * i S S ** * < w p "'//, :z 5, -A 4 1 0875 1 1064 1 0895 1 0745 1 0530 1 0814 1 0701 1 0410 1 0569 1 0549 1 0867 1 0897 1 0976 1 0940 1 1337 1 0546 1 0928 1 0917 1 0886 1 0643 1 0627 1 0896 1 1277 1 0657 1 0618 1 0885 1 0762 1 0883 1 0960 1.0921 1 1055 1 0831 1 0642 1 9650 1 6981 1 8718 1 8628 1 8337 1 6281 1 8000 1 7175 1.4970 1 2318 1 1116 1 1882 1 1131 1 2355 1 0833 1 9483 1 9822 1 8844 1 6034 1 6661 1 7140 1 6385 1 4065 1 4571 1 0448 0 9780 0 9699 1 2599 1 2863 1 1470 1.5271 1 1321 1 1709 1 1801 0 9966 1 1851 1 7547 1 6576 1 9162 1 6942 1 6684 1 6845 1 7736 1 9036 1 5627 1 3256 1 3835 1 3379 1 4547 1 4181 1 7787 1 5340 1 3891 1 6003 1 9205 2 0055 1 9234 1 4615 1 5682 1 8270 1 4471 1 4871 1.4995 5 6 7 8 9 10 11 12 T* * ' . ; s 'r ' M K N M ****1 1 B IB * * mmmmmmmmm. m m m % M m ,l- mmmmmmmm li* -C .. \ '' 7 .7 MW m m m m m m m m a w m m m m mmmmmm m m m m s, \ W ^. I a ** i p i 4H H N M N m H K 1 * ** * * * * * i V % Z f ' 4*- > ' * fx V 4L. 4 * $t$Si f c s ' e e t - X " x f m -h m* M M M M M W K W M M * * * * . * ? -. ila f r< 3 ana Immmmm iiiita :a ' - SV > M M a u m N t m m m m m w a rn m m M m m m s s rn .......... mmmmm m m m m m 1 mmmmmmmmm mmmmm w m u m m m m m iB 8 ifi* s * B f m m m m m t s w * . S IS *** .. .. m m m m m m m m m m rn m e m m m m m m :...... r s r - - w s m m m m m m sm m & xA sm m iM m m m H m m m m m iM K M ffl m W m m M M m sm m m m sM m w ks i i i i i i *, '* % . * am . H M nnaM am . -- S S mmmm * mmmmm .... K \m m s m m ..........r . . ' mmmmmmmmm m m m m m m m ) . w ssm m rn rn iK m m m . a * * l i t . .. . ... . is * -W W * * e * *. * m m m m m m m im m K m m m m m m m * * H M H ..* m m ....... mm . . . - . U & tc , M M i* pH S S W a rn te ) ' .iW 1 Uv < O \ T iW M w m m m m m m m 'm m m m m H , a _______ i l i * r iS * * # tp K * iM . MM . M . ^ 8 8 * * ! * (* * mmmmm mmmmm mmmmm h m m . . . mmmm V '- W "" -T , , } ______ . s a x iiir w m '0 * * ./ W r* * '. m m m m . -*- W S r> M M N M M M W i w m m m m i m m . m m m sm w m m m * ik s mmmmmm im m s rn s a m m m m m m m m m m S S S S m p IW H if lM a iiiM * * -"* * 1 .. mmmm . W s* ' 4- - J fM mmmmmmm mmmm mmmm. '/m n - H M * ,,* fc ii tti-f H M H f iS iB B m m um W M M .i l P w a c g a w & m m m W r} wm m m mmmmm -y t * H" * ' vy '*i '- mm m m * m tm s m wmmmwmmmm m m m m m m m m m w m m m m m m m m m sm m m m ^m m m -w m '' rn s m m m m m bm m m m m m m m m m m m m w m sm m m m m m m m m m tM n * * I h h m h i w * . s M B B a i m m m m mmmmmm * w s * ia mmmmmm m m m m m & W m m m m m m m wKm m M m m m m i? m m ' - y TM -;"..... !** mmmm ** r *% c- .. - * * * '' ita V tii) - ;- W mmmzmm ' Z" ^ i? . St * m m sun. 4' mmmmm .. ._ 'S . m m m m m m m m m wm m m m m m m m m "" >K m M m m a M m m m , )s b b s * * * * * * * * * S* *- > ^ *** r i. v * y` c j m * - i V 'is t,' * . ' , *t m m m m m M BM m m M m m m m m m m m m m m m _ / v t- $ i w m m tm 4 4%$%* .; JV ,. . '* - 4 ,, \ . , S it'* ' 4/ i m m m m " ' fr i ' m m m m m . ' - m M m m m K B M 'M m m m /M m m M m m m m m m ssm . m m m m m m u m m s x -< * & ' J -ff 1 h - a r*V 'S " * ,* ' V* - ' 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 4 ^ y -p a g e /6 0 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 S a m p le ID S a m p le D e scrip tio n S o il M axtrix S o il W e ig h t ID U s e d (g) S p ik e ID S p ike V o lum e (uL) In te rn a l S tandard ID In te rn a l S tandard V o lum e (u L ) S u rro ga te S p ik e ID S u rro ga te S p ike V o lum e (uL) PFBS S p ik e ID PFBS S p ike V o lum e (uL) 1 G LP 10-01-01-01-019 G L P 10-01-01-01-019 D ud G LP10-01-01-01-019 LM S G L P 10-01 -01 -01 -023 G LP10-01-01-01-023 D ud G LP 10-01 -01 -01 -023 LM S G LP10-01-01-01-024 G LP10-01-01-01-024 D ud G LP10-01-01-01-024 LM S G LP 10-01-01-01-025 G LP 10-01-01-01-025 D ud G LP10-01-01-01-025 LM S G LP 10-01-01-01-026 G LP 10-01-01-01-026 D ud G LP 10-01-01-01-026 LM S G LP 10-01-01-01-027 G LP 10-01-01-01-027 D ud G LP 10-01-01-01-027 LM S G LP 10-01-01-01-029 G LP 10-01-01-01-029 D ud G LP 10-01-01-01-029 LM S G LP 10-01-01-01-030 G LP 10-01-01-01-030 D ud G L P 10-01 -01 -0 1-03 0 LM S M B --1 0 0 4 1 5 -0 7 M B--100415-08 M B --1 0 0 4 1 5 -0 9 M B-100415-10 M B --10 04 15 -11 2 DAL DF8C SS SS03 1 0010 D A L D F 8C S S S S 03 1 00 10 Sam D le D uplicate D A L D F8C SS S S 03 1 0010 Lab M atrix Spike DAL DF8C SS SS05 0 0010 D A L D F 8C S S S S 05 0 0010 S a m le D uD licate D A L D F8C SS S S 05 0 0010 Lab M atrix Spike DAL DF11 SS SS05 0 0000 D A L DF11 SS S S 05 0 00 00 S a m le D uolicate D A L DF11 S S S S 0 5 0 0 0 0 0 La b M a trix SDike DALDF11 SS SS05 0 0010 D A L D F 1 1 SS S S 05 0 0010 S a m le D uolicate D A L DF11 S S S S 05 0 0010 Lab M a trix SDike D AL DF11 SS SS05 1 0010 D A L DF11 S S S S 05 1 0010 S a m le D uplicate D A L DF11 SS S S 05 1 0010 Lab M atrix Soike DAL DF11 SS SS06 0 0000 D A L DF11 S S S S 06 0 0000 S a m p le D up lica te D A L DF11 SS S S 06 0 0000 Lab M atrix Soike DAL DF11 SS SS07 0 0000 D A L DF11 S S S S 07 0 00 00 S a m p le D up lica te D A L DF11 SS SS07 0 0000 Lab M atrix S cike D AL DF11 SS SS07 0 0010 D A L DF11 S S S S 07 0 00 10 S a m p le D uplicate D A L D F 11 SS S S 07 0 0010 La b M atrix S pike M ethod B la nk Sa w / IS fo r D ilu tion s M ethod B la n k 5a w/ IS fo r D ilu tion s M ethod B la n k 5a w/ IS fo r D ilu tion s M ethod B la n k 5a w / IS fo r D ilu tion s M ethod B la n k 5a w / IS fo r D ilu tion s 3 r# n w m m sM M m m m m It m m * * S ii ! 10 001-152 10 001-152 10 001-152 10 001-152 10 001-152 4 1.2515 1.3724 1.1744 1.5147 1.5388 1.5402 1.4952 1.3211 1.6172 1.7416 1.6289 1.7067 1.5825 1.4943 1.4205 1.5721 1.7218 1.6041 1.5987 1.4491 1.4063 1.5521 1.4415 1.5209 5.0257 4.9659 5.1302 5.0913 5.0688 5 6 7 8 9 10 11 12 m m m m m sm m m m ,,A v m sm m m w ssssem '! '* 1 ' ilB IS iS : - * # * u m js m u B iiiiiliiiiS mmmmm HM v> - mmmm . . . . mmmmm mmmm `-c *<. * I W W i ^ W % . ,, 'i , . iiiM a a M WMTOJ8an. W H. - mmmmm. m m m m A ?*, ' a s w ir *** MMMg mmmm ' - mmmmmmmmm mmmm * j&r. mmmm .. m m m m m w bbum mmmm M H** Stfc* . . W M * :WmmM. H H W B R ** * mmssm?!: wmasmm , mmmmm %m iiM liflli .. . mmmm H H . m. . . mmm -. I * MMMMMM ISMS'- V m s* um m m m *... : Sk, H M * * mmmmm V **-' ' ' r Col 3 & : g w B alance ID: 900 C o l 7 & 8: jO ' C o l 11 & 12: j O A /t Col 5 & 6: fJ fif C ol 9 & 10: y O 3M Study: GLP10-01-02 Interim Report 01 Page 2 of 4 Page 61 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 15-Apr-2010 3M Study: GLP10-01-02 Interim Report 01 Page 3 of 4 Page 62 of 539 GLP10-01-02-01 ETS-8-053 Samples Extracted Starting 1S-Apr-2010 S a m p le ID S a m p le D e scrip tio n L-P F H xS S p ik e ID L-PFH xS S p ike V o lum e (uL) L-PFO S S p ik e ID L-PFO S S p ike V o lum e (u L ) E xtra ctio n S o lve n t V o lu m e (m L) S o n ica te 1 h r C e n trifu g e C om m ents 1 G LP10-01-01-01-019 G LP10-01-01-01-019 Dup G LP10-01-01-01-019LM S G LP10-01-01-01-023 G LP 10-01-01-01-023 D ud G LP10-01-01-01-023 LM S G LP10-01-01-01-024 G LP 10-01-01-01-024 D ud G LP10-01-01-01-024 LM S G LP 10-01-01-01-025 G LP10-01-01-01-025 Dup G LP10-01-01-01-025 LM S G LP10-01-01-01-026 G LP10-01-01-01-026 D ud 2 D AL DF8C SS SS03 1 0010 D A L D F8C S S S S 03 1 0010 S a m le D uo lica te D A L D F8C SS S S 03 1 0010 Lab M atrix Soike D AL DF8C SS SS05 0 0010 D A L D F8C S S S S 05 0 0010 Sam D le D up lica te D A L D F8C S S SS0S 0 00 10 Lab M atrix SDike DAL DF11 SS SS05 0 0000 D A L DF11 S S S S 05 0 00 00 S a m le DuDlicate D A L D F 1 1 S S S S 05 0 00 00 Lab M a trix SDike D ALDF11 S S S S 05 0 0010 D A L DF11 S S S S 05 0 0010 S a m le D uo lica te D A L DF11 SS S S 05 0 0010 Lab M atrix Soike DAL DF11 SS SS05 1 0010 D A L DF11 S S S S 05 1 0010 S a m le D uo lica te 13 14 G LP 10-01 -01 -01 -027 G LP 10-01 -01 -01 -027 Dup G LP 10-01 -01 -01 -027 LM S G LP 10-01 -01 -01 -029 G LP 10-01 -01 -01 -02 9 D ud GLP10-01-01-01-029 LM S G LP10-01-01-01-030 G LP 10-01-01 -01 -03 0 D ud G LP10-01-01 -01-030 LM S M B ~100415-07 M B-100415-08 M B-100415-09 M B-100415-10 M B-100415-11 DAL DF11 SS SS06 0 0000 D A L D F 1 1 S S S S 06 0 00 00 Sam D le D uplicate D A L D F 1 1 S S S S 06 0 00 00 La b M atrix SDike D AL DF11 SS SS07 0 0000 D A L DF11 S S S S 07 0 00 00 Sam D le D uolicate D A L DF11 S S S S 07 0 00 0 0 L a b M a trix SDike D AL DF11 SS SS07 0 0010 D A L DF11 S S S S 07 0 00 10 Sam D le D uolicate D A L DF11 S S S S 07 0 0010 La b M atrix Soike M ethod B la nk 5a w / IS fo r D ilu tion s M ethod B la nk 5a w / IS fo r D ilu tion s M ethod B la nk 5a w / IS fo r D ilu tion s M ethod B la nk 5a w/ IS fo r D ilu tion s M ethod B la nk 5a w/ IS fo r D ilu tion s C ol 13 & 14: j ) 4 15 16 17 > , '% s iiiit ' S * S B i "" f T T lili C O M ?: 18 19 il* * 20 mmmmmmm -- * * 1 w nM M KM M * mmmmm w S B im w S S iil &- - mmmmmmmi Laaassa^ ^ tiH ia m H M mmmmmmm H M . . m' m gm m m d m m m m m tm sm : s w H im iis s h m Col19: AJ/yH- C ol 15 & 16: co'1 y O //Y 3M Study: GLP10-01-02 Interim Report 01 Page 4 of 4 Page 63 of 539 GLP10-01 -02-01 ETS-8-053 Sample ID Sample Description EC-100507-01 EC-100507-02 EC-100507-03 EC-100507-04 EC-100507-05 EC-100507-06 EC-100507-07 EC-100507-08 EC-100507-09 EC-100507-10 EC-100507-11 EC-100507-12 MB-100507-01 MB-100507-02 MB-100507-03 MB-100507-04 MB--100507-05 MB-100507-06 ICS-100507-01 LCS-100507-02 LCS-100507-03 LCS-100507-04 LCS-100507-05 LCS-100507-06 LCS-100507-07 LCS-100507-08 LCS-100507-09 GLP10-01-01-01-005 GLP10-01-01-01-005 Dud GLP10-01-01-01-005 LMS GLP1CMH-01-01-007 GLP10-01-01-01-007 Dud GLP10-01-01-01 -007 LMS GLP10-01-01-01-024 GLP10-01-01-01-024 Dud GLP10-01-01-01-024 LMS GLP10-01-01-01-029 GLP10-01-01-01-029 Dud GLP1DO1-01-01-029 LMS MB-1005G7-07 2 0.2 no Extracted Curve Point 0.5 no Extracted Curve Point 0.75 no Extracted Curve Point 1 no Extracted Curve Point 2.5 no Extracted Curve Point 5 no Extracted Curve Point 10 no Extracted Curve Point 25 no Extracted Curve Point 50 no Extracted Curve Point 100 no Extracted Curve Point 200 no Extracted Curve Point 500 no Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS /Method Blank 4 w/ IS Method Blank 5 w IS Method Blank 6 w/ IS 3 nq LCS in TCR-842 3 no LCS in TCR-842 3 ng LCS in TCR-842 30 no LCS in TCR-842 30 ng LCS in TCR-842 30 no LCS in TCR-842 300 no LCS in TCR-842 300 ng LCS in TCR-842 300 no LCS in TCR-842 OAL DF05 SS SS07 0 0010 DAL DF05 SS SS07 0 0010 Samole Duplicate DAL DF05 SS SS07 0 00101 ah Matrix Spike DAL DFOS SS SS08 0 0000 DAL DF05 SS SS08 0 0000 Sample Duplicate DAL DF05 SS SS08 0 0000 Lab Matrix Spike DALOF11 SS SS05 0 0000 DAL DF11 SS SS05 0 0000 Sample Duplicate DAL DF11 SS SS05 0 0000 Lab Matrix Spike DAL DF11 SS SS07 0 0000 DAL DF11 SS SS07 0 0000 Sample Duplicate DAL DF11 SS SS07 0 0000 Lab Matrix Spike Method Blank 5a w/ IS for Dilutions Col 3 & 4: B a la n c e I.D .: l/D :_ k U _ _ 9 0 0 ________ 5 -7 ^ 7 Col S & 6: l/ D : L ^M Soli Maxtrlx Soli Weight ID Used (g) Spike ID Spike Volume <uL) Internal Internal Standard Standard ID Volume (uL) Surrogate Spike 10 Surrogate Spike Volume <uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume <uL> L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume <mL) Sonicate 1 hr Centrifuge Comments 3 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 10003-2 _10003-2 mmmmm ' 'rmmmm 10003-2 4 1.0707 0.9804 0.8910 1.0328 1.1632 1.0040 1.0399 1.0913 1.0355 1.0485 1.16i: 1.1135 1.1705 1.0905 1.1295 1.0872 1.1623 1.1080 1.1046 1.1043 1.0715* 1.0765 1.1231 1.0791 1.1084 1.151 1.0155 .162 .521 .3671 1.9244 .3996 .396 .535 .7926 1.6503 2.1348 2.0275 2.1493 5.1835 5 10001-151 10001-151 10 001-151 10001-151 10001-150 10001-150 10 001-150 10001-149 10 001-149 10 001-149 4...........- 10001-148 10001-148 10 001-148 10 001-147 * '*10 001-147 14 09 004-117 * 67 20 09 004-126 50 09 004-126 75 09 004-128 100 09 004-126 25 09 004-128 50 09 004-126 100 09 004-128 25 09 004-128 50 09 004-128 100 09 004-128 20 50 - 4 aa w\ 09 004-128 09 004-128 . 09 004-128 09 004-178 - 09 004-128 -30 09 004-128 09 004-128 V 09 004-128 09 004-178 09 004-128 09 004-128 09 004-128 PSsSPSi 0-9.004--1i2>6 / 0..^9.''.0vX0..4.--.17i.t8.a 09 004-128 19004-128 19004-128 >9004-128 19004-128 , ' -8 10 11 12 13 14 1S 16 30 10 001-146 20 -30 10 001-146 50 30 10 001-146 *30 10 001-146 100 30 10 001-196 fr, 6 30 10 001-196 50 - -30 10001-196 100 "30 09 004-125 25 - 'K 30 09 004-125 30 09 004-125 30 im00K99m000I0m44M--11m2255.mtmmm.m.-mmmmmmmmmmmmtmmtmammmm-' 10001-196 30 - M*.' . _ 'mmmm__- 11 i 1111 lliiSli lilllll . i -10 001-196 .. V. ,10001-196 -.1 10 001-196 10 001-196 s 30 10 001-196 wwmmm*-iV rw. i . 5- .J O %, --*** -- .30 10 001-196 30 10 001-196 10 001-196 30 10 001-196 30 V. -30 10 001-196 ' -. '1J JU 1 j 10 001-196 mm ' __ 08 008-126-5 - A**\ 10 001-196 30 08 008-126-3 . 10 001-196 1. 30 10 001-196 30 100 08 006-125-4 100 30 10 001-196 30 30 10001-196 30 30 10 001-196 30 ty`i 08 008-126-1 500 150 17 8 8 8 8 6 6 8 6 6 6 8 6 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8a 8 8 8 40 16 19 20 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes <\t/l/lJi*\n Yes Yes Yes Yes 1Yes Yes ------ -- Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes /Yes Yes Yes Yes Yes Yes Col 7 & 8: P ip ette I . D . : E p p en d o rf P ip e tte M o d el: R e s e a rc h P ip e tte S /N : hH<?2<3T1~)______________ l/D: K T f i . 6 - // ? - /t > Col 11 & 12: l/D: b - i Q ' t # Col 1 3 & 14: l/D: k 3 i ' l f f ' l O Col 9 & 10: P ip ette I . D . : E p p en d o rf P ip e tte M o d el: R e s e a rc h ^ O i O - l - )P ip e tte S /N : _______________ Col 15 & 16: l/D: K - 3 E V (/ l/D: K 3 T F - h ~ i O - / Q C alib ratio n c u rv e w a s sp iked usin g g a s tight syrin g es. Col 17: E x tra c tio n S o lv e n t \.:.l O l/D: U T fc . $ - 0 - / 0 ^ ) Col 18: > S o n ic a t o r I . D . : i tC S o n icato r S /N : Q E J 1 0 0 5 9 5 0 0 3 l/D: Col 19: C en trifu g e I.D .M j V H ? R P M S etting: 3 0 0 0 T im e (m in): 1 0 l/D: T fc t5 Q S p . k d c v ' k 5 c > 4 ,5ln+ ly r .Y t jt - b -> 0 -,0 /)// oirnphi \Jce\cf m \ie $ A le<^r\ /$ jz> lvrr\?^<2A>7-2- p l '^ r ^ Vj . $rl& -/0 ^ ?\c ( > C ^ ^ r cU r R+ S -iO -l o , s /e-T-y. 6 -^ -^ 3M Study: GLP10-01-02 Interim Report 01 Pags 1 of Page 64 of 539 SampleID Samlpe Description Dateof Original Extraction iDluted? Yes/No iDluted?* Yes/No iDluted?* Yes/No iDluted?* Yes/No iDluted?* Yes/No GLP10-01-02-01 ETS-8-053 1 2 34 56 G L P 1 0 -0 1 -0 1 -0 1 -0 2 9 D A L D F 11 S S S S 0 7 0 0 0 0 0 5/10/2010 Yes Yes No G L P 10 -0 1 -0 1 -0 1 -0 2 9 Dup D A L D F 11 S S S S 0 7 0 0 0 0 0 S a m p le D u p licate 5/10/2010 Yes Yes No G L P 10 -0 1 -0 1 -0 1 -0 2 9 LM S D A L D F 1 1 S S S S 0 7 0 0 0 0 0 L a b M atrix S p ik e 5/10/2010 Yes Yes No * If e x tr a c t t o b e d ilu te d is a d ilu tio n fro m a n o th e r p re v io u s d ilu tio n , e n te r th e c o lu m n n u m b e r o f p re v io u s d ilu tio n a n d th e fin a l d ilu tio n fa c to r in th e s p a c e p ro v id e d . Col 4: Volume of sample added: 100 uL Volume of Diluent Added: S mL (final volume)__ Diluent ID MB-100510-07___________ Dilution Factor:__5Q____ lnt/Date_ S -y o -/o 7 No No No 8 No No No 3M Study: GLP10-01-02 Interim Report 01 Page 65 of 539 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Ums # N/A GLP10-01-02 Sample Description: Soil INTERNAL CHAIN OF CUSTODY 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 1 Page 66 o f 539 G L P 1 0-01-0 2 -0 1 ETS-8-053 S a m p le ID S a m p le D e s c rip tio n D ate o f O rig in a l E x tra c tio n D ilu te d ? Y e s /N o D ilu te d ? * Y e s /N o D ilu te d ? * Y e s /N o D ilu te d ? * Y e s /N o D ilu te d ? * Y e s /N o 1 2 34 5 6 7 G L P 10 -01-01-01-029 DAL DF11 SS S S07 0 0000 5/10/2010 Yes Yes No No G L P 1 0-01 -01 -01 -0 2 9 D up D A L D F 1 1 S S S S 0 7 0 0 0 0 0 S a m p le D u p licate 5/10/2010 Yes Yes No No G L P 1 0-01 -01 -01 -0 2 9 IM S D A L D F 1 1 S S S S 0 7 0 0 0 0 0 L ab M atrix S p ike 5/10/2010 Yes Yes No No * If e x tra c t to b e d ilu te d is a d ilu tio n fro m a n o th e r p re v io u s dilu tio n , e n te r th e c o lu m n n u m b e r o f p re v io u s d ilu tio n a n d th e fin a l d ilu tio n fa c to r in th e s p a c e p ro v id e d . Col 4: Col 5: Volume of sample added: 100 uL Volume of sample added:___100 uL___ irne of sarr Volume of Diluent Added: 5 mL (final volume)__ Diluent ID MB-100415-10___________ Dilution Factor:__50 lnt/Date_ Volume of Diluent Added:_____ 900 uL_ Diluent ID MB-100415-10 Dilution Factor: Int/Date. 500 $ - i Z '> C ? i jm e of Diluent Added:^. Diluent'lDj___ .Dilution Fat m am 8 No No No mm p e p ili 'Col 8* WWm .Volume of sample e W\A*Am^m >of Douent iliiHHMMNNHHI --Volume of sample added ' ' "____________ Volume'of Diluent Added ? '* *________ , M BI 3M Study: GLP10-01-02 Interim Report 01 Page 67 of 539 Description: Date Prepared: Prepared By: Storage Location: Expiration Date: r q \ v C/A~P /- 7 ~ j o _________________ Uf n ___________________ _________________ I Z ) Q ____________ MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Exac t Copy o f Original Page No. 116 Initial D a te Solvent: 3M Trace #: Source: Expiration Date: Description jA cxAo L- Standard ID # 09 004-116 Component Standard ID# Cone, or Purity Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration THlo-Qd-fC, iOrtL- -- -- 2fi/0 j^iol'OoJo - y-zo-iH HOO^L- - -- &>V0 s' 3M Study: GLP10-01-02 Interim Report 01 Final Volume Approximate 5Z)0 /~}L- Concentration of the mix .4*^1; Reviewed by: _ Signature, 5 - / 6 "/Q Date Page 68 of 539 Description: 3 3 r l - y : Date Prepared: H'lH'ld Prepared By: Storage Location: Expiration Date: A-^~H) /o~~f-~lO MULTI-COMPONENT PREPARATION LOG Exac t Copy o f Original K3P- S - n - i initial O a ts Book No. Page No. 09 004 128 Solvent: A<^N____________ 3M Trace #: TKloCi - cxA?~ TlSource: + T ____________ Expiration Date: L/''i<o~lLj_________ Description 1 iA S 'fF o A Standard ID# 09 004-128 Component Standard ID# Cone, or Purity Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration lo co1" HI /o ooi - f l . TV7-5 l-7'l \ 12 . 5 z./ -- -- O i IO 2. -- <-- o < o i l Z )o oc?! ' / V3 7-* / o -- -- 6 , )oo io c o i - IHH H u 2-1 V ---- . /O rf --------- I P * Avi H1 ' 3M Study: GLP10-01-02 Interim Report 01 Final Volume /o ^ U Approximate Concentration of the mix 3 ` Reviewed by:. 4 Signature, Date Page 69 of 539 Exac t Copy o f Original JrTS vp Initial D a ta Date: j- M ' )Q Analyst: 6 P**1 SINGLE COMPONENT PREPARATION LOG Description: S ^ r ^ c .^ .^ . M .y ^ -------------------------------------------- Book No. Page No. 10 001 196 Stock Number: Y OC^/-)2A> Weight or Volume Used: JQ & ^.L - Concentration or Purity: Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Nrnberg A -C H T H 'i - ^ - y / z . Final Volume:_____ ) t> w Storage Location:______ A s ^ H ) Final Concentration: Q . / s t s j _ Expiration Date: / - l - l b 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: S ig n a tu re , ^ Date Page 70 of 539 Description: ^ -'B S Date Prepared: B a r t Copy of Original initial D a te Storage Location: A-S~h-0 Expiration Date: 3 c MULTI-LEVEL PREPARATION LOG Book No. 08 008 Page No. 124 Solvent: ^4 ->n/ 3M Trace #: -ns/.o`i-o & 'i - Description PFS5 PFSS Pf=2s Standard ID # Description 08 008-124-1 08 008-124-2 08 008-124-3 08 008-124-4 08 008-124-5 08 008-124-6 08 008-124-7 08 008--12-8 I ~Z- 3 y / Component Standards ID # (6 O ' 1c/( Cone S'OSO .'s U l Expiration Date <j-3 ' / o Std 1 Std 2 -- Amount of Component Standard Added Std 3 -- Std 4 _-- Std 5 -- Std 6 / Stcjr7 Std 8 OS' c C g - iZ H ' I . i `f-J b v o { S o a f - M i - S o M ) ^ n L ?-JfcW0 Final Volume ___i ^ ) __ -- -- to jO O O ^ tL -- to io O jU -0 -- -- /0 0 0 .*aL 1 iO -- /O ^oiLt V 7* Final Concentration (p kC \),,\) t t f . l 9 .9 t 0^9] /O i ' i ' t 1 a>, o 771 Description Standard ID # 08 008-124 08 008-124 08 008-124 08 008-124 08 008-124 08 008-124 08 008-124-9 10 11 12 13 14 15 . Description Component Standards ID# Cone Expiration Date Std 9 Std 10 Amount of Component StandatAdtfecT Std 11 Std 13 Std 14 Std 15 Std 16 . .A M' ' 3M Study: GLP10-01-02 Interim Report 01 FingLVdlume"" Concentration R e v ie w e d by: S ig n a tu re , D ate Page 71 of 539 Description: f y - \Ay S Date Prepared: H-iy-jo Exact Copy of Original Initial 5 -)% '/& Oats Storage Location: ____A < ? & MULTI-LEVEL PREPARATION LOG Book No. 08 008 Page No. 125 Solvent: ACt-X__________________ Description A - Pf& S L'fFU xS Standard ID # 08 008-125-1 08 008-125-2 08 008-125-3 08 008-125-4 08 008-125-5 08 008-125-6 08 008-125-7 08 008-1^5-8 Description t 3H ir Component Standards ID # Cone />cx>l'l i1 Vico ^ oSooF-izf- 1 Expiration Date -/t) Std 1 Std 2 -- -- jOoO^-L. Amount of Component Standard Added / Std 3 -- Std 4 -- --- Std 5 ---- Std 6 Std 7 vu Fr/ \ D Std 8 osa%' ns-3> o - 1 i o g > -- --- jooo^t-- I4S.L- / Final Volume (r^iL) Final Concentration )& to IO to / o % ?o o.J?0 o .o ffo 0,60 JJq / Standard ID # 08 008-125 08 008-125 08 008-125 08 008-125 08 008-125 0 8 0 0 & J * < ' "08008-125 08 008-125-9 10 11 12 13 1 4 __ - -- " 1 5 16 Description Description Component Standards ID# Cone Expiration Date 1 t> Std 9 Amount of ComjjDfrentStandard Added Std 10 S lC P tT Std 12 O Std 13 Std 14 Std 15 Std 16 tO ^ 3M Study: GLP10-01-02 Interim Report 01 ^^-H' tnaivolum e ^ Final Concentration Reviewed by: Signature, ______ S- t % Date Page 72 of 539 Description: Date Prepared: Prepared By: H-H-lo &pr^ Bract Copy of Original vede < o 'i% '/o initial Oats Storage Location: Expiration Date: ________ *7- 30*10 MULTI-LEVEL PREPARATION LOG Book No. 08 008 Page No. 126 Solvent: /4-Cbi 3M Trace #: t~Nc> ? - ^ 70 - V /y Description L. L'P F**' u - p p *<> Standard ID # 08 008-126-1 08 008-126-2 08 008-126-3 08 008-126-4 08 008-126-5 08 008-126-6 08 008-126-7 08 008-12f6 Description Component Standards ID# Cone H iH o Expiration Date 9-3:o- / / Std 1 2-*35" 2^ Std 2 -- 3H jA Amount of Component Standard Added f ^ ) / / Std 3 -- Std 4 .-- - Std 5 Std 6 Std 7 / Std 8 OgCoS- Z6- n . i o8ocg'/U '3> o . W \ Final Volume ( ^ ) Final Concentration --- -- )t> 9<U lo o o -- H> . 9.% 00 -- l 0x9% -- o o o / oo /A IO / / o.ooJJC / Standard ID # 08 008-126 08 008-126 08 008-126 08 008-126 08 008-126 08 008-126 08jtoei2608 008-126-9 10 : 11 . 12 13 14 15 / 16 Description Description Component Standards / ID# Cone Expiration Date Std 9 Std 10 Amount of Component StajjdertifAdded Std 11 ^ s t e r r ^ Std 13 Std 14 Std 15 Std 16 *. -A ^tftaT^oiume""^ .-- ' ":inal Concentration 3M Study: GLP10-01-02 Interim Report 01 Reviewed by n / - Signature, s Date Page 73 of 539 SINGLE COMPONENT PREPARATION LOG Date: Analyst: J/gc; l - pfoa WDescription: Book No. Page No. 10 001 108 Stock Number:_ W eight or Volume Used: T a o 7 - Q w l ~ '// Or)!iHcj Aao-fo & Balance ID: Concentration or Purity: m% . Other Correction Factors: l a ___ a. iw O . l j h ,Corrected Weight: k j J rwoi-om-^iSolvent and TN-A Number: Final Volume: Storage Location: A71) Final Concentration: WO Expiration Date: \~ io -in Exact CopyofOriginal ~ 6 ? rx r-ir-i initial ' Date 3M Study: GLP10-01-02 Interim Report 01 Page 74 of 539 Date: Analyst: SINGLE COMPONENT PREPARATION LOG 0 __________ m ___ Description: L - P P o 1? Book No. Page No. 10 001 110 Stock Number:_ Tcm-oooi- '/, Weight or Volume Used: OMU & Concentration or Purity:_ Balance ID: 311 Other Correction Factors: Q Cj 'J Corrected Weighty OM O 1 Final Volume: k *v L Storage Location: b S JQ . Final Concentration: Expiration Date: % ^L Exact Copy of Original S '- ) t - / Initial Date 3M Study: GLP10-01-02 Interim Report 01 Page 75 of 539 Date: ' O ' I Q SINGLE COMPONENT PREPARATION LOG Analyst:________3 / 2 ^ ___________ Book No. Page No. 10 001 111 Description^ L - P F / U Stock Number:_ I C f l f r f - O O l V - ' / i Weight or Volume Used: .O if Concentration or Purity: | UCorrected Weight:_____ 0 - 0 Q Balance ID: Vl Other Correction Factors: Q .IH 'Solvent and TN-A Number: A t 33 TV0^-0010'% , Final Volume: L Storage Location: 4 s i) Final Concentration: Vito *4 h -* C - . Expiration Date: 0 Exact Copy of Original - fr"1 S '- / / - / ri Initial ' Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, tiU /O Date Page 76 of 539 H Date: '~ (0 SINGLE COMPONENT PREPARATION LOG - Analyst: St.tj.Description: PFH5 ( E C F ) Book No. 10 001 Page No. 107 o Stock Number: T a i - Weight or Volume Used: 0 . to V c , -------------------------- ---------------------- Balance ID: \n Concentration or Purity: 11U Other Correction Factors: O .V t Corrected Weight: 0.0%7 c Solvent and TN-A Number: A C M T v o \ - c x m - I.lb Final Volume: Storage Location: A s 7n Final Concentration: v io Expiration Date: ^ -p -IO Exact Copy of Originai Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: ^- r y O h Signature. A4 //0 Date Page 77 of 539 Date: ^ " ^ 0 " 10 SINGLE COMPONENT PREPARATION LOG Analyst:__________ y j ^ - 5 PF05Descripitoionn: Book No. Page No. 10 001 105 T i l l - io%Stock Number: W eight or Volume Used: Concentration or Purity:_ % .H % Corrected Weight: O .Q W lc Balance ID: Other Correction Factors: A Gj'i'j 'A I f f Solvent and TN-A A * j ) n~, , ~r r 10, Number: n C A / \kJ(i0l0 " / IJ s Final Volume: i_ Storage Location:_ A S 7 (I Final Concentration: *vL Expiration Date: ' M 'u ' ( Exact Copy of Original c m _____ 5~-/r-y o Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed Signature, k I/o Date Page 78 of 539 Ho -/oDate: SINGLE COMPONENT PREPARATION LOG Analyst:__ PFP? s WDescription^ Book No. Page No. 10 001 104 Stock Number: ( c A - l>i Weight or Volume Used: O . m i cJ, Concentration or Purity: Corrected Weight: 0, H I , 3 Final Volume: Storage Location: Balance ID: Vl Other Correction Factors: CHsry A C / J WSolvent and TN-A Number: T o r oFinal Concentration: Expiration Date: \-)0 -lo ExactCopyof Original Initit Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed Signature, //Q Date Page 79 of 539 Date: i - W ~ 1 0 Analyst: vks SINGLE COMPONENT PREPARATION LOG Description: PFQA (CF) Book No. Page No. 10 001 99 i a t- u iStock Number: Weight or Volume Used: 0 . 1066a J Concentration or Purity: inBalance ID: Other Correction Factors: 0-%y CorrectedWeigh,: - C T O a A d / / W h C P fo ~ % Final Volume: Storage Location: A rm Final Concentration: Expiration Date: f ^o-kJfjtE Exact Copy of Original f a -?_______ g Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed Signature, vU k ? / Date Page 80 of 539 Date: Analyst: 6 Prn SINGLE COMPONENT PREPARATION LOG Description: TCfL. ~~ Z_ Book No. 10 001 Page No. 152 Stock Number: T c -fi-- Weight or Volume Used: / 1'2-S '> 3 ^ _____________ Balance ID: Concentration or Purity: Corrected Weight: . Other Correction Factors: Solvent and TN-A Number: ~pQ Final Volume: Storage Location: Final Concentration: Expiration Date: /O -T -/0 Exact CopyofOriginal f r r i_________ Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by:_ Signature. Z > /L > Date Page 81 of 539 ate: lh 1 ' ^ Analyst: C fr-Q Description: u SINGLE COMPONENT PREPARATION LOG Book No. 10 001 Page No. 151 -I Stock Number: ^ Q O \ -- I T O Weight or Volume Used:____ / ooc> Concentration or Purity: O- )rA L Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: TN0*1-00 cf Final Volume:_______ J ^L-- Storage Location:_____ ~T~C> Final Concentration: O <O Expiration Date: ZO ' ! Exact Copy of Original 3~- i ~ I Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, Date Page 82 of 539 Date: Analyst: GfPr' SINGLE COMPONENT PREPARATION LOG Description: / . /n e e . / ' H ' y Book No. Page No. 10 001 150 Stock Number: i O o f ~ f t i ' f Weight or Volume Used: /ooo Concentration or Purity: ' L~ Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: T7\)6 <j ~ o o f O ' ~ / ' Z _ Final Volume: / Storage Location: o Final Concentration: / Expiration Date: Exact Copy of Original . S -lf-L o Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: ' / S ig n a tu re , ^ T h /o Date Page 83 of 539 Date: Analyst: G (V T Description: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 001 149 Stock Number: 0 ? o o H - l ) # Weight or Volume Used: Jooo L, Concentration or Purity:______ L-- Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: /z / 77V O f ~ ?0 Final Volume: /o Storage Location: ^ 5 -7 -0 Final Concentration: ! L-. Expiration Date: & ExactCopy ofOriginal CPm s ^ /S r-i 6 In itia l Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed b y : . Signature, Date Page 84 of 539 Date: H - ' T - '' I Analyst: 0 P'""1 Description: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 001 148 Stock Number: to oo) Weight or Volume Used: /oo Concentration or Purity: ) )r* I-- Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: y 4 - C N . -, T K l 0 * 7 -CO^O' / r Z - )Final Volume:_________ L Storage Location:_______ / 4 Final Concentration:____ L~ Expiration Date: ~ I^ Ewct CopyofOriginal . s*ir-io Initial 3M Study: GLP10-01-02 Interim Report 01 Reviewed by Signature, H -IT h /0 Date Page 85 of 539 Date: H - 7 - ' lb Analyst: 6 SINGLE COMPONENT PREPARATION LOG Description: C - \ -- . /-- Book No. Page No. 10 001 147 Stock Number: o ? POH- 11 ~-f~ Weight or Volume Used: /oQO L~ Concentration or Purity: ! } /V } L-- Corrected Weight- Balance ID: Other Correction Factors: Solvent and TN-A Number: T M l-O j ' z.. )0Final Volume:______ ! Storage Location: 5~ Final Concentration:______ Expiration Date: et ' ~ / o Exact Copy of Original Initial ' 5 itT 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, q -Z > /p Date Page 86 of 539 Date. Analyst: 4 &Cr*\ Description:______ SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 001 146 Stock Number: /o QO\ ^ ttys'______ W eight or Volume Used: OOO ua,L- Concentration or Purity: * l juqI^i L Corrected Weight: Balance ID: ' Other Correction Factors: Solvent and TN-A Number: /4 - c h J T N o')- o /tx. Final Volume: ]& Storage Location: Final Concentration: e , Oj Expiration Date: )0- 1 Copy of Original nftiai Date 3M S tudy: G L P 10 -01 -02 In te rim R e p o rt 01 Reviewed by: S ig n a tu re , Date Page 87 o f 539 D ate:___________ Analyst: G f 3^ Description: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 001 145 Stock Number: 0 e? Qq H- 11 W eight or Volume Used: /ooo .aa L Concentration or Purity:______ / L~ Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: /4 -O J , T 7v/Q ? ~ Q ? C )'' Final Volume. m L~ Storage Location:_______ A ^ " f Final Concentration: Q ,, Expiration Date: jo - 7 ~ / 0 **xac*Copy of Original Aim s-Jt-i In itia l " D iti" 3M Study: GLP10-01-02 Interim Report 01 Reviewed z Signature, I-21-/0 Date Page 88 of 539 Date: Analyst: C-fV-4 Description: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 001 144 S' P FrS Stock Number: - OoS~! - 6 / / 5 " Weight or Volume Used: . e -n bine. Concentration or Purlty:_ Corrected Weight: Balance ID: ^too Other Correction Factors: O, <A 5 'X Solvent and TN-A Number: Final Volume: // X /~ iX Storage Location: A 5 ~ ? t> Flnal Concentration: Expiration Date: i ~b't Bct CopyofOriginal r-- in itia l ->D*UatOe 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, b 2 > / Date Page 89 of 539 Date: Analyst: 10 6-<V*7 SINGLE COMPONENT PREPARATION LOG Description: T i f f P F ^ ^ 4 Book No. 10 001 Page No. 143 Stock Number: "T (^ ^ O cl - OP & ~ f- ~ 5/^' Weight or Volume Used: Concentration or Purity: g. />, |g_ M <jf )/*> L-- Corrected Weight: M jm L-- ' Balance ID: cl o Other Correction Factors: 0.?9ff Solvent and TN-A Number: Final Volume: I, 2 - m L Storage Location: /4 5~'7'(3 Final Concentration: H "f jm l -- Expiration Date: i o ' ~ ~ h ' l O Exact Copy ofOriginal Initial ' Date" 3M Study: GLP10-01-02 Interim Report 01 Reviewed by Signature, Date Page 90 of 539 Date: H ' T ~ \ SINGLE COMPONENT PREPARATION LOG Analyst: G - P r t _______________ Book No. 10 001 Page No. 142 Description:_ r l P F H - S Stock Number: ~T0 (2 * - 12-I Weight or Volume Used: S k l l i r c Concentration or Purity: Corrected Weight: '77- 3 Balance ID: `j O O Other Correction Factors: 0 *? V / Solvent and TN-A Number: -- Final Volume: J. Z- r~ t 1-- Storage Location. /4 Bract Copy ofOriginal Initial Date 3M Study: GLP10-01-02 Interim Report 01 Final Concentration: V T -.S J /-- Expiration Date: /O " 7"7 0 Reviewed by: S ig n a tu re , ^ / Date Page 91 of 539 Date: H - I - I O Analyst: & P n Description: IS' SINGLE COMPONENT PREPARATION LOG PF 3 S Book No. Page No. 10 001 141 Stock Number: )o "X 'C -jL .- -f-O Q .,% C r/V n Weight or Volume Used: n. * * f> * ) r . Concentration or Purity: 4^ ji. r r . = Corrected Weight: f i'Z . )rv\L- Balance ID: ` ' Other Correction . Factors: 0 ` Solvent and TN-A Number: Final Volume: / , "2- ^ /_ Storage Location: Final Concentration: S '!* 2- Expiration Date: I O ~ O Copy of Original if- to Initial : Date" 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: H 'V y /o Date . Page 92 of 539 Date: H ' 7 -/0 SINGLE COMPONENT PREPARATION LOG Analyst: -/VT_______________ Description:_ y i ______________ Book No. Page No. 10 001 140 Stock Number: "TC H o ^ - p o y - C , ~~ W ~ Weight or Volume _ Used: a n + i r<s- ^>u. l-e* Concentration or Purity: 5 fl Corrected Weight: ^ 7 *^ i/.-- Balance ID: t f o Other Correction Factors: O . S " > Solvent and TN-A Number: '' Final Volume:_______/ 2- ________________ Final Concentration: AStorage Location: Expiration Date: IO - ? - / Exact Copyof Original - S '- t f ' .W-.. Initial ' Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: S ig n a tu re . Date Page 93 of 539 m m i Date: i Analyst: Qr P P ^ m Description: SINGLE COMPONENT PREPARATION LOG Book No. 10 001 Page No. 139 H Stock Number: N 1 Weight or Volume Used: I^ L L Balance ID: ^ o m R 1 w* 1l i Concentration or Purity: SO Corrected Weight: ? jA C j/sn L . Final Volume: Other Correction Factors: O * 7 Solvent and TN-A Number: Final Concentration: 4 c/ ,, f j j j i Storage Location: Expiration Date: / < ? - ? ' I n m i C r f >b \ Initial S '- it ~ / Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by:_ Signature, M - Z 7 -/ > Date Page 94 of 539 D ate: A n a lyst: S -1 -/0 K3E SINGLE COMPONENT PREPARATION LOG D e s c rip tio n : % 0 ' 7 ? A r' \a J cA 6, Book No. 10 003 Page No. ___ 1 Stock Number: ~T N O ~ Q \ Q 1 Weight or Volume . Used:_______ l D O m L Concentration or Purity: 4 Corrected Weight: Final Volume: 5oo Storage Location: /S 7 o Balance ID: Other Correction Factors: Solvent and TN-A ., Number: f \ oe ) t V i\ ,4 r .W TMio -oo^ y% Final Concentration: Yj? ZC? A V iA .- jp '"' Expiration Date:_ \ Q ~ \ 2 - \ Q Exact CopyofOriginal f* m i'if-i initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, Date Page 95 of 539 Date: 6 - ~ - / 0 Analyst: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 003 2 Description: ~ t R Stock Number: W eight or Volume Ci I U sed:_________ I I 0 / p | ________ n s 'i Balance ID :____________ / Concentration or Purity: Corrected W eight: Other Correction Factors: Solvent and TN-A Number: Final Volume: Storage Location: Final Concentration: Expiration Date: / / -1 -J O Exact Copy of Original 6**^ r - ) ~ i > Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed Date Page 96 of 539 Description: Date Prepared: Prepared By: Storage Location: Expiration Date: >)C H-T'IO___________ O m ______ ,________ AS~bO____________ / 0 " T ~ ( d __________ MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Page No. 114 Solvent: /4c-e.V o <O i4-n fc- 3M Trace #: TJMOJ-qq ? - 1e/ )? Source: Expiration Date: _____________ 2A-lLj ________ Description rtflro A H P r S Standard ID # 09 004-114 Component Standard Cone, or ID # Purity Expiration Date Weight or Volume Balance ID Corrected Weight Final Concentration jorwi' /o-T-IO 2 x c . w-/- -- IO &-oo\-iH (g rfrty-j-io HJ.XjlKj!A l o - b ' i o tio. -- o.WZ -- /. o o oA s '. s Final Volume Approximate )D rr%L~ Concentration of the mix / h~lA Exact Copy of Original Cfr*\ y - t f - i o ' Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, c(- 2 1 - / 0 Date Page 97 of 539 MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Page No. 115 Description: IT S Date Prepared: H - I 'I O Prepared By: Q P ^ _____ Storage Location: y4-X~7-c> Expiration Date: id Solvent: /Ac. >-b/-i l_ 3M Trace #: s o f o - ' ^ 2- Source: B+'-i___________ Expiration Date: c/ ' 2A ~ ______ i Description ~ CFES J&V' - PF Standard ID # 09 004-115 Component Standard ID# /o col - H \ Cone, or gi.z-----{X-M--P---uS--r-I-i-rt-ty1L--i)-- Expiration Date IO - Weight or Volume Corrected Weight Balance ID Final Concentration ( mc^ I ^ L ) l2-r S -- -- . 1 l c i ' / V Z . n . 3 z\ jsL -- -- 0 ,0 ^ 3 n s -p f o a ' r i p f *s )o ool - )H3 Io c l -'lclLf n . s z-o -^ u \ a 2.1 M F -- -- V O --- -- o . IO ---------- rL rtxf ,^ 4 A -- Final Volume Approximate I m U Concentration of the mix > 1 Exact Copy of Original /fr n Initial S' l Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, t'h Z l'/O Date Page 98 of 539 1 I I Description: D a te P r e p a r e d : ____ ' / - 7 - t g ----------. P r e p a r e d By: -------- ,AS to r a g e L o c a t io n : , E x p ira tio n D a te : S~ -- !-- MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Page No. 117 Solvent: ^.<-*Arc.rti\n __ 3M Trace #: tno'x-cx^ ~~-- (tz. Source: ^ 4-J___________ Expiration Date: Q-2& 3M Study: GLP10-01-02 .Interim Report 01 Page 99 of 539 f, t , D escrip tion: D ate Prepared:. P repared By S torage L o c a tio n E xpiratio n D a te H ' T ' Z l ------------ -go -\0 MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Page No. 118 S o lve n t: 14--^ 1- 3M Trace #: -n N o ? - S o u r c e : ^ + - T ______________ E x p ir a t io n D a te : H - ' l d ~ H _________ Exact Copy of Original 6f r i T ~ l fi-l Initiai Date 3M Study: GLP10-01-02 .Interim Report 01 S ig n a tu re , Page 100 of 539 Description: 3 (a PCvc^ Ae. (T\H Date Prepared: H~l 2>Q__________ Prepared By:_______ K T f i _____________ Storage Location: ^<>10 Expiration Date:______ C?~~)~/Q__________ MULTI-COMPONENT PREPARATION LOG Book No. 09 004 Page No. 125 Solvent: f\ce.\t)n 4 a lc 3M Trace #:*T M P ^ I Source:________ ~ _________ Expiration Date: I er>2> Description fS\ ?pOf) tfPPoS Standard ID # 09 004-125 Component Standard Cone, or ID # Purity Ln ) Expiration Date )o Weight or Volume Balance ID Corrected Weight W /X -- -- Final Concentration frr> L \ % IOoO)-lH0 H i t W-1-l 21%L -- -- )xO ^ V ^ i fJ xT1 .-'" U V / s' F nal Volume Appro ximate Concentrati an of the mix 1 Exact Copy of Original Ae r - it-it Initial Date 3M Study: GLP10-01-02 Interim Report 01 Reviewed by: Signature, Y - T-r-i c Date Page 101 of 539 Date: ID j \ j 0\ alyst: G-PW SINGLE COMPONENT PREPARATION LOG Description: A \ ^ o \ o f "TC-0- SZH2. Book No. 09 005 Page No. 31 Stock Number:____ A/eight or Volume Used: Concentration or Purity: tfe-c > Corrected Weight: Balance ID: ^ I & Other Correction Factors: Solvent and TN-A Number: Final Volume: Storage Location: / \ 5 \ & Final Concentration: t l e c~ k Expiration Date: H j >j l 0 Exact Copy of Original Affc ' 5 Jt-i Initiai ' Date 3M Study: GLP10-01-02 Interim Report 01 Page 102 of 539 DATA REVIEW SUMMARY FORM Date: 4/28/2010 Data Analyst: KJE Study #: GLP10-01-02 Description: Decatur Soil Analysis Batch: sl00421a Results Table: sl00421a.rdb Instrument: Stan V I660305 Method(s): ETS-8-53.0 Analyte: PFBS Comments/Justifications: 1 Acceptable Linear Range: 0.199 ng/mL to 498 ng/mL Internal Standard: 1802 PFBS LOQ: 0.199 ng/mL Analyte: PFHS Comments/Justifications: None Acceptable Linear Range: 0.200 ng/mL to 499 ng/mL Internal Standard: 1 8 0 2 PFHS LOO: 0.200 ng/mL Analyte: PFOS_____________________________ Comments/Justifications: 1,2____________________ Acceptable Linear Range: 0.200 ng/mL to 500 ng/mL Internal Standard: M8PFOS_______________ LOQ: 0.200 ng/mL________________________ Data Review Sign-Off Analyst Review and Acceptance of Manual Integrations Name/Date: /( ? Technical and Manual Integration Review Name / Date: jT-iy-io Comments / Justifications: Values above the ULOQ were not reported. The least diluted sample_____ within the calibration range was used._______________________________ 1 Method Blank 5 was determined to be an outlier at 95% confidence using _____the Grubbs test. It was not used in the method blank determinations.______ 2 Due to high levels of PFOS in some samples, there are some solvent_____ blanks that are high due to carryover. However, of the samples bracketed by high PFOS solvent blanks, the ratio of the solvent blank level to to level of PFOS in the sample is less than 0.3% and therefore should not affect the final analytical result. Also, most samples bracketed by high solvent blanks were rerun as dilutions later. Since the method only requires______ the use of method blanks for the calibration curve this did not affect the calibration curve._______________________________________________ Analyte: M4PFOS Comments/Justifications: None__________________ Acceptable Linear Range: 0.200 ng/mL to 500 ng/mL Internal Standard: M8PFOS_______________ LOQ: 0.200 ng/mL_______________________ 0 Analyte: N/A Comments/Justifications: N/A Acceptable Linear Range: N/A Internal Standard: N/A LOQ: N/A____________ 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 1 Page 103 of 539 Stan V1660305 *3M Environmental Lab 0 rfc i W ' lA Results Name: sl00421a.rdb Sample Nam Sample ID 1 s100421a001 09004-129 solvent blank 2 100421a002 09004-129 solvent blank 3 100421a003 EC-100415-09 50 ng Warm up standard 4 s100421a004 EC-100415-09 50 ng Warm up standard 5 s100421a005 EC-100415-09 50 ng W arm up standard 6 100421a006 09004-129 solvent blank 7 100421a007 09004-129 solvent blank 8 s100421a008 09004-129 solvent blank 9 100421a009 09004-129 solvent blank 10 s100421a010 09004-129 solvent blank 11 s100421a011 EC-100415-01 0.2 ng Extracted Curve Point 12 1004213012 EC-100415-02 0.5 ng Extracted Curve P ant 13 s100421a013 EC-10041503 0.75 ng Extracted Curve Point 14 100421a014 EC-100415-04 1 ng Extracted Curve Point 15 100421a015 EC-100415-05 2.5 ng Extracted Curve Point 16 100421a016 EC-10041506 5 ng Extracted Curve Point 17 100421a017 EC-100415-07 10 ng Extracted Curve Point 18 100421a018 EC-100415-08 25 ng Extracted Curve Point 19 s100421a019 EC-10041509 50 ng Extracted Curve Point 20 100421a020 EC-100415-10 100 ng Extracted Cun Point 21 100421a021 EC-100415-11 200 ng Extracted Curve Point ' 22 1004213022 EC-100415-12 500 ng Extracted Curve Point 23 s100421a023 09004-129 solvent blank 24 1004213024 09004-129 solvent blank 25 100421a02S 09004-129 solvent blank 26 1004213026 09004-129 solvent blank 27 100421a027 MB--100415-01 Method Blank 1 w/o IS 28 1004213028 MB--1 0 0 4 1 5 0 2 Method Blank 2 w/o is 29 8l00421a029 MB--10041503 Method Blank 3 w/o IS 30 s100421a030 MB--100415-04 Method Blank 4 w/ IS 31 100421a031 MB--10041505 Method Blank 5 vtf IS 32 B1004213032 MB--10041506 Method Blank 6 w/ IS 33 100421a033 LCS-100415-01 3 ng LCS in TCR-842 34 100421a034 LCS-10041502 3 ng LCS in TCR-842 35 100421a035 LCS-100415-03 3 ng LCS in TCR-842 36 100421a036 LCS-100415-04 30 ng LCS in TCR-842 37 100421a37 LCS-16641505 30 fig LCS in TC&842 38 1004213038 LCS-10041506 30 ng LCS in TCR-842 39 6l00421a039 LCS-100415-07 300 ng LCS in TCR-842 40 s100421a040 LCS-100415-08 300 rg LCS in TCR-842 41 100421a041 LCS-100415-09 300 ng LCS in TCR-842 42 1004213042 09004-129 solvent blank 43 8l00421a043 EC-10041505 2.5 ng Extracted Cun Point 44 1004213044 09004-129 solvent blank 45 100421a045 GLP10-01-01-01-033 Soil Trip Blank 1 46 100421a046 GLP10-01-01-01-033 Dup Soil Trip Blank 1 Sample Duplicate 47 1004213047 GLP10-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike 48 100421a048 GLP10-01-01-01-034 Soil Trip Blank 3 49 100421a049 GLP10-01-01-01-034 Dup Soil Trip Blank 3 Sample Duplicate 50 1004213050 GLP10-01-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike 51 100421a051 GLP 10-01-01-01-001 DAL DF05 SS SS06 0 0000 52 100421a052 GLP10-01-01-01-001 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate 53 100421a053 GLP10-01-01-01-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike 54 100421a054 GLP10-01-01-01-002 DAL DF05 SS SS06 0 0010 55 1004213055 GLP10-01-01-01-002 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate 56 s100421a056 GLP1001-01-01-002 LMS DAL DF05 SS SS06 0 0010 Lab Matrix Spike 57 1004213057 GLP10-01-01-01-003 DAL DF05SS SS06 1 0010 58 100421a056 GLP10-01-01-01-003 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate 59 1004213059 G LP1001-01-01-003 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 60 1004213060 09004-129 solvent blank 61 100421a061 EC-100415-06 5 ng Extracted Curve Point 62 100421a062 09004-129 solvent blank 63 100421a063 G LP10-01-01-01-004 DAL DF05 SS SS07 0 0000 64 1004213064 G LP10-01-01-01-004 Dup DAL DF05 SS SS07 0 0000 Sample Duplicate 65 10423065 G LP10-01-01-01-004 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike 66 1004213066 G LP10-01-01-01-005 DAL DFOS SS SS07 0 0010 67 1004213067 GLP10-01-01-01-005 Dup DAL DFOS SS SS07 0 0010 Sample Duplicate Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte Retention Tim e (min) Analyte P eal Area (counts) M4PFOS Double Blank 0.00 M4PFOS Double Blank JO 00 M4PFS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank ; 0.00 M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFS 'M4PFS M4PFOS M4PFOS Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank E ,0.200 I0.500 K 0.750 E 1.00 E 2.50 E 5.00 K 10.0 E 25.0 E ' 50.0 E 100. E 200. E 500. 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Double Blank 0.00 M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFS Unknown N/A . M4PFS Unknown N/A M4PFOS Unknown N/A M4PFS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A , , M4PFOS Double Blank 0.00 . M4PFOS Quality Control E 2.50 M4PFOS Double Blank j 0.00 M4PFOS Unknown i N/A M4PFOS Unknown i N/A M4PFOS Unknown /A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown : N/A M4PFOS Unknown : N/A M4PFOS Unknown : N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Double Blank 0.00 M4PFOS M4PFOS Quality Control Double Blank E 5.00 0.00 M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A M4PFOS Unknown N/A 12.91 12.67 12.85 12.81 12.83 12.83 12.77 12.76 12.79 12.84 2.79 12.80 12.78 12.75 12.75 12.77 12.76 12.76 12.76 12.76 12.74 12.73 12.78 12.76 12.81 12.85 12.86 12.95 12.81 12.74 12.74 12.72 12.74 12.75 12.74 12.75 2.75 12.73 12.77 12.75 12.77 12.71 12.74 12.77 12.76 12.74 12.76 12.75 12.76 12.75 12.76 12.78 12.77 12.76 12.76 12.77 12.78 12.78 12.78 12.90 12.77 0.000 12.78 12.80 12.77 12.77 12.78 93 34 982818 973066 985301 58 31 46 10 20 4966 11353 16027 19329 49901 98762 200723 488980 943648 1883396 3470102 6549208 1146 300 106 41 58 31 46 61156 62258 S7843 55999 60565 58677 59413 60175 60772 54983 56555 55961 82 49323 22 59764 63465 S9578 60667 58354 60724 59627 60310 53547 55735 55637 50729 62385 60299 S7983 46 98007 0 62593 57541 52819 62613 55539 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 85 34 62123 56233 63089 58 58 58 60 22 62466 60528 56756 62157 57773 60655 61821 62470 61076 59549 51872 42543 22 34 0 34 103 119 65 61524 62137 60715 63418 62777 62225 63573 63546 61825 57450 59556 57754 130 60767 22 61371 59944 60574 62111 63019 59134 60203 58820 56185 57207 64003 51964 60732 62407 55109 34 61248 44 56242 59756 55708 61337 61107 IS IS Concentration Retention Calculated Concentration Accuracy (ng/mL) Time (m in) (ng/mL) (%> N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A ] 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A N/A N/A N/A N/A N/A N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3,00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3 .0 0 ' 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 - 3.00 3.00 3.00 12.63 12.97 12.84 12.81 12.81 12.64 12.71 12.94 13.00 12.66 12.79 12.76 12.77 12.75 12.76 12.77 12.76 12.78 12.76 12.74 12.75 12.72 13.02 12.68 0.000 12.61 12.74 12.77 12.79 12.73 12.74 12.72 12.73 12.74 12.72 12.75 12.75 12.77 12.73 12.74 12.75 12.78 12.76 12.61 12.77 12.75 12.75 12.75 12.76 12.78 12.75 12.76 12.74 12.76 12.80 12.77 12.76 12.74 12.76 12.94 12.77 12.71 12.76 12.77 12.77 12.78 12.79 , N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.200 '0.530 0.820 0.908 2 .6 0 4.94 9.89 23.9 47.4 97.6 209. 497. N/A N/A N/A N/A N/A N/A N/A 3.00 3.02 2.87 2 .6 6 2.91 2.64 2.81 2.65 2.96 2.68 2.86 2.92 N/A 2.44 N/A '2 3 3.19 2.96 2.94 2 .7 9 3.10 2.96 3.09 2 .8 7 2.94 2.61 2.94 3.10 2.91 3.17 N/A 4.85 N/A 3.36 2 .9 0 2 .6 6 3.08 2.74 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. 106. 109. 90.8 104. 98.7 98.9 95.8 94.8 97.6 105. 99.4 N/A N/A N/A N/A N/A N/A N/A N/A N/ N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 97.5 N/ N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 97.0 N/A N/A N/A N/A N/A N/A Record Modified File Name 100421 a.wiff 100421 a.wiff 100421 a.wiff n 100421a.wiff 100421 a.wiff 100421 a.wiff n s100421a.wiff 100421 a.wiff ____ ,s100421a.wiff 100421 a.wiff E 8l0O421a.wiff s100421a.wiff 100421a.wiff 100421a.wiff E s100421a.wtff 100421a.wiff E 100421a.wiff 100421a-.wiff 100421a.wiff s100421a.wiff 100421a.wiff E s100421a.wiff n 100421 a.wiff *100421 a.wiff n 100421 a.wiff 100421 a.wiff 100421 a.wiff 100421a.wiff 100421 a.wiff E 100421 a.wiff s100421a.wiff s10O421a.wiff 100421a w ff E 100421a.wiff s100421a.wiff s10042la.wiff 100421a.wiff E a100421a.wiff a 100421a.wiff E 100421 a.wiff nE 100421 a.wiff 100421 a.wiff n 100421 a.wiff 100421 a.wiff K 100421 a.wiff s10042la.wiff 100421a.wiff n s10042la.wiff n 100421a,wiff 100421a.wiff n 100421a.wiff 100421a.wiff 100421 a.wiff n 100421a.wiff 100421 a.wiff 100421 a.wiff 100421 a.wiff 10042la.wiff E 100421a,wiff 100421a.wiff 8100421a.wiff n 6l00421a.wiff 100421a.wiff 100421 a.wiff 100421 a.wiff 100421 a.wiff 100421 a.wiff Printing Printing lin te rim ^ R p ft^^ ' 2010 Page 1 of 14 Page 104 of 539 Stan V1660305 *3M Environmental Lab Sam ple Nam Sample ID 68 s100421a068 69 s100421a069 70 s100421a070 71 s 100421a071 72 s100421a072 73 s100421a073 74 s100421a074 75 s100421a07S 76 " s100421a076 77 s100421a077 78 s 1004213078 79 s100421a079 60 8100421a080 61 8100421a081 82 8100421a082 83 8100421a083 84 s100421a084 85 s100421a08S 66 s100421a086 87 s 004213087 88 si421a88 89 s100421a089 90 s100421a090 91 s100421a091 92 &100421a092 93 s100421a093 94 8100421a094 95 8100421a095 96 s100421a96 97 Is100421a097 96 8100421a098 99 8100421a099 100 s100421a100 101 s 100421 a101 102 8100421a102 103 s100421a103 104 8100421a104 1 " s 1004213105 106 8100421a106 107 s100421a107 108 s100421a108 109 s100421a109 110 s100421a110 111 s100421a111 112 s100421a112 113 s100421a113 114 8l00421a114 115 s100421a115 116 s100421a116 117 s100421a117 118 8100421a118 119 s100421a119 120 s100421a120 121 s100421a121 122 8100421a122 123 s100421a123 124 s100421a124 125 s100421a125 126 s100421ai26 127 s100421a127 126 s100421a128 129 s10O421a129 130 s100421a130 131 81004218131 132 s100421a132 133 s100421a133 134 s100421al34 GLP10-01-01-01-005 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike GLP10-01-01-01-007 DAL DF05 SS SS08 0 0000 GLP10-01-01-01-007 Dup DAL DF05 SS SS08 0 0000 Sample Duplicate GLP10-01-01-01-007 LMS DAL DF05 SS SS08 0 0000 Lab Matrix Spike G IP 1 0 0 1 -01-01-008 DAL DF05 SS SS06 0 0010 Ql_jbi c M j - j 1-01-008 Dup DAL DF5 SS SS08 0 0010 Sample Duplicate G U ^ iO ^ i-01-01-008 LMS DAL DF5 SS SS8 1 Lab Matrix Spike GLP10-01-01-01-010 DAL DF05 SS SS09 0 0010 GLP10-01-01-01-010 Dup DAL DF05 SS SS09 0 0010 Sampl Duplicate GLP10-01-01-01-010 LMS DAL DFOS SS SS09 0 0010 Lab Matrix Spike 09004-129 solvent blank EC-100415-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-016 DAL DF8C SS SS02 0 0010 GLP10-01-01-01-016 Dup DAL DF8C SS SS02 0 0010 Sample Duplicate GLP1001-01-01-016 LMS DAL DF8C SS SSQ2 0 0010 Lab Matrix Spike GLP10-01-01-01-009 DAL DF05 SS SS09 0 0000 GLP10-01-01-01-009 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate GLP10-01-01-01-009 LMS DAL DF05 SS SS09 0 0000 Lab Matrix Spike GLP10-01-01-01-011 DAL DF05 SS SS10 0 0000 GLP10-01-01-01-011 Dup DAL DF05 SS SS10 0 0000 Sample Duplicate GLP10-01-01-01-011 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike GLP10-01-01-01-012 DAL DF05 SS SS10 0 0010 GLP10-01-01-01-012 Dup DAL DFOS SS SS10 0 0010 Sample Duplicate GLP10-01-01-01-012 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike GLP10-01-01 -01-013 DAL DF8C SS SS01 0 0000 GLP1001-01-01-013 Dup DAL DF8C SS SS01 0 0000 Sample Duplicate GLP10-01-01-01-013 LMS DAL DF8C SS SS01 0 0000 L a b ka 09004-129 solvent biank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-014 DAL DF8C SS SS01 0 0010 GLP10-01-01-01-014 Dup DAL DF8C SS SS01 0 0010 Sample Dupficate GLP10-01-01-01-014 LMS DAL DF8C SS SS01 0 0010 Lab Matrix Spike GLP10-01-01-01-015 DAL DF6C SS SS02 0 0000 GLP10-01-01-01-015 Dup DAL DF6C SS SS02 0 0000 Sample Dupficate GLP 1001401^014)15 LMS DAL DF8C SS SS02 0000 Gib Matrix Spike GLP10-01-01-01-020 DAL DF8C SS SS04 0 0000 GLP10-01-01-01-020 Dup DAL DF8C SS SS04 0 0000 Sample Dupficate GLP10-01-01-01-020 LMS O A LD F 8C S S SS04* 0 0000 Lab Matrix Spike GLP10-01-01-01-021 DAL DF8C SS SS04 0 0010 GLP10-01-01-01-021 Dup DAL DF8C SS SS04 0 0010 Sample Dupficate o p e e SS SS4 0 X 1 Lab Matrix Spike GLP10-01-01-01-022 DAL DF8C SS SS05 0 0000 GLP10-01-01-01-022 Dup CAL DF8C SS SS05 0 0000 Sample Dupficate GLP10-01-01-01-022 LMS DAL DF8C SS SS05 0 0000 Lab Matrix Spike 09004-129 solvent blank EC-100415-06 5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-028 DAL DF11 SS SS06 0 0010 GLP10-01-01-01-028 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate GLP10-01-01-01-028 LMS DALDF11 SS SS06 0 0010 Lab Matrix Spike GLP10-01-01-01-017 CAL DF6C SS SS03 0 0000 GLP10-01-01-01-017 Dup DAL DF6C SS SS03 0 0000 Sample Dupficate GLP10-01-01-01-017 LMS DAL DF8C SS SS03 0 0000 Lab Matrix Spike GLP10-01-01-01-018 DAL DF8C SS SS03 0 0010 GLP1D-01-01-01-018 Dup DAL DF8C SS SS03 0 0010 Sample Dupficate GLP10-01-01-01-018 LMS DAL DF8C SS SS03 0 0010 Lab Matrix Spike GLP10-01-01-01-019 DAL DF8C SS SS03 1 0010 GLP10-01-01-01-019 Dup DAL DF8C SS SS03 1 0010 Sample Dupficate GLP10-01-01-01-019 LMS DAL DF8C SS SS03 1 0010 Lab Matrix Spike "GLP1001-01-01-023 DAL DF8C SS SS05 0 0010 GLP10-01-01-01-023 Dup CAL DF8C SS SS05 0 0010 Sample Duplicate GLP1-0^0T-014323 LMS D LD F8C SS SS05 010 Lab Matrix Spike 09004-129 solvent biank EC-100415-07 10 ng Extracted Curve Point 09004-129 advent blank Printing l|M 8 td d V 1<& L P l0 -0 :'1L-0226 ' 2010 Printing ^ m F G>ftPo0M Results Name: sl00421a.rdb Analyte Pea Name ( Sam ple Type M4PFOS M4PFOS M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFS `M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFS M4PFOS M4PFOS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank QuaSty Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Use Record Analyte Concentration (n g /m L ) Analyte R e te n tio n Timo (min) Analyte Peal Area (counts IS Peak Nan* IS Peak Arai (counts) IS Concentration (n g /m L ) IS Retention Tima (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy <%) Record Modified File Name N/A N/A N/A N/A N/A N/A N/A N/A N/A IN/A :0.00 E 10.0 0 00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 2.50 jO.OO N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 10.0 0.00 12.77 12.78 12.77 12.78 12.79 12.81 12.79 12.79 12.79 12.79 12.94 12.80 12.72 12.81 12.84 12.80 12.80 12.82 12.79 12.63 13.04 12.77 12.60 12.79 12.60 12.79 12.79 12.64 12.76 12.60 12.73 12.81 12.82 12.78 12.82 12.78 12.79 12.79 12.79 12.79 12.81 12.79 12.79 12.60 12.83 12.80 0.000 12.61 0.000 12.78 12.79 12.79 12.61 12.79 12.78 12.81 12.79 12.77 12.80 12.80 12.78 12.78 12.65 12.79 0.000 12.78 12.60 57510 55370 57794 52804 55067 SS474 - 55149 60015 61230 55453 22 199556 34 60546 59510 53311 484 IS 50368 36745 37934 37673 35616 57405 58421 34465 53172 53015 37636 34 52572 22 45816 47259 37447 55889 55349 36882 53621 52306 37274 54784 53584 35374 48302 50466 35856 0 96739 0 39516 37684 31234 40580 38576 24368 34706 31957 20895 34211 33497 21504 42954 42591 21531 0 186484 22 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M6PFOS M6PFOS M8PFOS M6PFOS M6PFOS M6PFOS M8PFOS ^MSPFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M6PFOS 56627 57694 60467 50094 55205 55576 52204 61763 60441 60370 46 58013 31 58548 60630 53004 49988 50817 37567 39244 35865 30228 53365 54083 34040 50687 53212 36313 46 59800 34 43490 48517 35705 55483 54452 35452 55922 54056 35023 55253 55618 34410 49577 52762 33577 0 59116 0 36066 35947 26515 37521 35616 15490 30827 30018 15179 31285 32729 15001 42325 41345 14963 0 57817 0 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3X N/A 3 .X N/A 12.76 12.77 12.80 12.78 12.78 12.77 1 2 .X 12.77 12.79 12.81 12.76 12.83 12.95 12.83 12.79 12.81 12.79 12.83 12.83 12.79 13.10 12.78 12.79 12.79 12.X 12.82 12.78 12.80 12.84 12.81 12.64 1 2 .X 12.62 12.63 12.82 12.62 1 2 .X 12.78 12.79 12.78 12.62 12.80 12.79 12.81 12.78 12.75 O.OX 1 2 .X O .O X 1 2 .X 1 2 .X 12.79 1 2 .X 12.78 12.75 12.79 12.80 12.78 1 2 .X 1 2 .X 12.77 12.76 12.79 12.82 0.000 1 2 .X O.OX 3 .X 2 .X 2 .X 3.16 301 3.01 3.19 2.93 3 05 2.77 N/A 10.5 N/A 3.12 2 .X 3.03 2.92 2 .X 2 .X 2.91 3.17 3 .X 3.25 3.26 3 .X 3.16 3 .X 3.13 N/A 2.64 N/A 3.18 2.93 3.16 3.04 3.06 3.14 2 .X 2.92 3.21 2 .X 290 3 10 2.94 2 .X 3.22 N/A S .X N/A 3.13 3.18 3 .X 326 3.27 4.77 3.40 3.21 4.17 3 .X 3 .X 4.34 3 .X 3.11 4 .X N/A 9.82 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 106. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 101. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A X .2 N/A E K K n R E E n E E n E n K E rE ___ K E E E E E n E n E E E E E E n E E E E E E 8100421 a.wiff s100421 a.wiff 8100421 a.wiff s 1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a ,w iIT siX421a.w iff s 1 0 0 4 2 1 a ,w iff si00421a.wiff s 1 0 0 4 2 1 a .w iff 6 l0 0 4 2 1 a .w iff s 1 0 0 4 2 1 a .w iff 8100421a.wiff 81004 2 1 a .w ill s100421a.wi(T 81004 2 1 a ,w iff 81004 2 1 a .w iff 8100421a.wiff s 1 0 0 4 2 1 a .w iff 8100421a.wiff 8100421 a.wiff 8100421a.wiff 8100421 a.wiff 8100421a.wiff 8100421a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421a wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 6l00421a.wiff s100 4 2 1 a .w iff s 1 0 0 4 2 1 a .w iff s 1 0 0 4 2 1 a .w iff 81004 2 1 a ,w iff 6 l0 0 4 2 1 a .w iff 81004 2 1 a .w iff s 1 0 0 4 2 1 a .w iff s100421awiff 81004 2 1 a .w iff 8100421 a.wiff s0421a.wiT 8100421a.wiff S100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff s 1 0 0 4 2 1 a .w iff s 1 0 0 4 2 1 a ,w iff 81004 2 1 a .w iff s 1 0 0 4 2 1 a .w iff s1 00 4 2 1 a .w iff 8100421 a.wiff s 1 0 0 4 2 1 a .w iff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8 l0 0 4 2 1 a .w iff s 1 0 0 4 2 1 a .w iff 81004 2 1 a .w iff s i0 0 4 2 l a.wiff Page 2 of 14 Page 105 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Sam ple Name Sam ple ID 135 s100421a13S 136 s100421a136 137 s100421a137 138 s100421a136 139 s100421a139 140 s100421a140 141 s100421a141 142 s100421a142 143 s100421a143 144 s100421a144 145 s 1 X 4 2 1 a i 45 146 s100421a146 147 a100421a147 148 s100421a148 149 s100421a149 150 a100421a150 151 s100421a151 5 2 s100421a152 153 s100421a153 154 s100421a154 155 s100421a1S5 156 s100421a156 157 a100421a157 156 s100421a1S8 159 s100421a159 160 ^ s100421a160 161 s100421a161 162 s100421a162 163 s100421a163 164 s100421a164 6 5 J s100421a165 166 s100421a166 167 s100421a167 168 s100421a168 169 s100421a169 170 n 8l00421a170 171 s100421a171 172 s100421a172 173 s100421a173 174 s100421a174 175 s100421a175 176 s100421a176 177 8l00421a177 178 s100421a178 179 s100421a179 160 s100421a180 161 s100421a161 182 s100421a162 183 s100421a163 184 s100421a184 185 8l00421a18S 166 s100421a186 187 81004213187 186 s100421a188 189 s100421a189 190 s100421a190 191 s100421a191 192 s100421a192 193 8l00421a193 194 s100421a194 195 8l00421a195 196 s100421a196 197 s100421a197 198 s100421a196 199 s100421a199 200 s100421a200 201 s100421a201 GLP10-01-01-01-024 DAL DF11 SS SS05 0 0000 GLP10-01-01-01-024 Dup DAL DF11 SS SSOS 0 0000 Sample Duplicate GLP10-01-01-01-024 LMS DAL DF11 SS SSOS 0 0000 Lab Matrix Spike GLP10-01-01-01-02S DAL DF11 SS SSOS 0 0010 GLP10-01-01-01-025 Dup DAL DF11 SS SS05 0 0010 Sample Duplicate GLP10-01-01-01-025 LMS DAL DF11 SS SS05 0 0010 Lab Matrix Spike GLP10-01-01-01-026 DAL DF11 SS SS05 1 0010 G LP1001-01-01-026 Dup DAL DF11 SS SS05 1 0010 Sample Duplicate GLP10-01-01-01-026 LMS DAL DF11 SS SS05 1 0010 Lab Matrix Spike 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-027 DAL DF11 SS SS06 0 0000 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sample Duplicate GLP10-01-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 GLP10-01-01-01-029 Dup DAL DF11 SS SS07 0 0000 Sample Duplicate GLP1001-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike GLP10-01-01-01-030 DAL DF11 SS SS07 0 0010 GLP1001-01-01-030 Dup DAL DF11 SS SS07 0 0010 Sample Duplicate GLP10-01-01-01-030 LMS DAL DF11 SS SS07 0 0010 Lab Matrix Spike 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-10041S-06 5 ng Extracted Curve Point 09004-129 solvent blank M B -1 00415-07 M ethod Blank 5g w/ IS for Diutions MB--100415-06 Method Blank 5g w/ IS for Dilutions MB--100415-09 M ethod Blank 5g w/ IS for Dilutions MB--100415-10 Method Blank Sg w/ IS for Dilutions M B -1 00415-11 Method Blank Sg w/ IS for Dilutions LCS-100415-07 Dil.x50 300 ng LCS in IC R-842 Dil.xSO LCS-100415-08 Dil.x50 300 ng LCS in TCR-642 Dil.x50 LCS-100415-09 Dil.xSO 300 ng LCS in TCR-842 Dil.xSO GLP10-01-01-01-009 LMS Dil.xSO DAL DF05 SS SS09 0 0000 Lab Matrix Spike Dii.x50 GLP10-01-01-01-011 Dil.x50 DAL DF05 SS SS10 0 0000 Dil.x50 GLP10-01-01-01-011 Dup DiLxSO CAL DF05 SS SS10 0 0000 Sample Duplicate Dil.x50 GLP 10-01-01 -Oi-Oi 1 LMS Dil.x50 DAL DF05 SS SS10 0 0000 Lab Matrix Spike Dil.xSO 09004-129 solvent blank EC-100415-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-012 LMS Dil.xSO DAL DF05 SS SS10 0 0010 Lab Matrix Spike Dil.xSO GLP10-01-01-01-013 LMS DiLxSO DAL DF8C SS SS01 0 0000 Lab Matrix Spike Dil.xSO GLP 10-01-01-01-014 Dil.xSO DAL DF6C SS SS01 0 0010 Dil.xSO GLP10-01-01-01-014 Dup Dil.xSO DAL DF8C SS SS01 0 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-014 LMS Dil.x50 DAL DF8C SS SS01 0 0010 Lab Matrix Spike Dil.x50 GLP1001-01-01-015 LMS Dil.xSO DAL DF8C SS SS02 0 0000 Lab Matrix Spike Dil.x50 GLP10-01-01-01-020 LMS Dil.xSO DAL DF8C SS SS04 0 0000 Lab Matrix Spike Dil.xSO 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-021 LMS Oil.xSO DAL OF8C SS SS04 0 0010 Lab Matrix Spike Dil.xSO GLP10-01-01-01-022 LMS Dl.xS0 DAL DF8C SS SS05 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-028 Dil.xSO DAL DF11 SS SS06 0 0010 Dil.x50 GLP10-01-01-01-028 Dup Dil.x50 DAL DF11 SS SS06 0 0010 Sample Duplicate Dil.xSO GLP10-01-01-01-028 LMS DiLxSO DALDF11 SS SS06 0 0010 Lab Matrix Spike Dil.xSO GLP10-01-01-01-017 Dil.x50 DAL DF8C SS SS03 0 0000 DiLxSO GLP10-01-01-01-017 Dup DiLxSO DAL DF8C SS SS03 0 0000 Sample Duplicate DlxSO GLP10-01-01-01-017 LMS Dil.xSO DAL DF8C SS SS03 0 0000 Lab Matrix Spike Di!.x50 GLP 10-01-01-01-018 Di.xSO DAL DF6C SS SS03 0 01 Dil.xSO GLP10-01-01-01-018 Dup Ol.xSO DAL DF8C SS SS03 0 0010 Sample Duplicate DiLxSO GLP10-01-01-01-018 LMS Dil.xSO DAL DF8C SS SS03 0 0010 Lab Matrix Spike Dil.x50 09004-129 solvent blank EC-100415-06 S ng Extracted Curve Point 09004-129 solvent blank Analyte Pea Name ' Sam ple Type M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Use Record A n a ly te Concentration (ng/m L) A n a ly te R e te n tio n Tim e (m in) Analyte Peal A rea (counts! IS Peak Narra IS Peak Area (counts) C IS oncentration (ng/m L) IS R e te n tio n Tim e (m in) C alculated C o n c e n tra tio n (ng/m L) A ccu ra cy <%) Record M odified File Name N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 .O 0.00 E 2. SO 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 0 .0 0 0.00 0.00 E 5.00 0.00 N/A N/A N/ N/A !N/A iN/A N /A !N/A N/A N/A N/A N/A O.OO E 10.0 0.00 |N/A iN/A IN /A IN /A IN /A iN/A jN/A 0.00 E 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 K 5.00 0.00 12.79 12.76 12.79 12.80 12.81 12.78 12.76 12.76 12.80 0.000 12.68 13.01 12.79 12.78 12.78 12.83 12.79 12.62 12.59 12.61 12.82 12.78 12.60 12.87 12.70 0.000 12.62 12.87 1 2 .es 12.63 12.85 12.63 12.83 12.62 12.84 12.81 12.83 12.65 12.84 12.85 12.60 12.96 12.92 12.68 12.83 12.86 12.85 12.87 12.87 12.87 12.93 12.89 0.000 12.87 12.87 12.65 12.84 12.91 *"12.87 12.87 12.89 12.87 12.69 12.69 12.88 12.88 0.000 31336 35492 23846 37056 31612 21414 33185 33821 20724 0 34 34 50801 10 38133 34580 23290 23767 24171 26738 23773 24804 23540 34 10 0 98661 34 63168 60869 62273 61856 63518 57312 62159 62221 61041 62266 57435 61460 34 46 22 63888 63529 63770 62299 62021 60515 63547 70 51273 0 64183 63075 62860 61168 63561 63961 59517 56739 59676 62219 56167 10 95602 0 M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M -- OS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS " M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 29143 35536 14280 37486 30056 14691 32568 29774 14311 22 56 22 60954 45 34277 31676 15683 6534 3825 2698 16089 18638 13333 46 34 34 61775 22 66119 60512 60530 56565 62470 59891 64349 61614 G4323 61039 60246 59894 46 22 22 62670 64646 64067 64776 62831 61765 61647 22 61173 22 64718 66326 60364 63188 60992 63905 63261 55753 59033 61768 57426 70 59144 22 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A N/A N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 300 3.00 N/A /A N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3.00 3 .X 3 .X 3 .X N/A 3 .X N/A 12.79 12.78 12.77 12.79 12.77 12.72 12.79 12.80 12.75 12.81 12.69 12.86 12.79 12.65 1 2 .X 12.X 12.79 12.X 12.79 12.84 12.80 12.83 12.79 12.82 12.95 12.77 12.83 12.92 12.84 12.84 12.X 12.84 12.X 12.84 12.84 12.82 12.60 12.X 12.62 12.84 12.77 12.X 13.01 12.65 12.X " 12.X 12.87 ^2.87 12.89 12.85 12.84 12.X 12.97 12.87 12.X 12.X 12.87 12.69 12.87 12.87 12.87 12.X 12.86 12.87 12.72 12.87 12.93 3.24 3.01 5 .X 2 .X 3.17 4.41 3.07 3.43 4 .X N/A N/A N/A 2 .X N/A 3 .X 3.29 4.44 11.1 19.3 X .3 3 98 4.03 5 .X N/A N/A N/A 4.84 N/A 2 .X 3 .X 3.10 3 .X 3.07 2 .X 2.91 3.04 2 .X 3.08 2.87 3 .X N/A 6.41 N/A 3.07 2 .X 3 .X 2 .X 2.97 2 .X 3.11 N/A 2.52 N/A 2 .X 2 .X 3.14 2.92 3.14 3.02 2.63 3.07 3 .X 3.04 2 .X N/A 4 .X N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1X. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A X .8 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 64.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A 101. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A X .O N/A R E E R R R E E E n o E E R R R E E E 1E "1 n E E n R E n IE n E n n E E E E E E s100421a.wiff 8100421a.w ill 81 00 42 1a . w ifi 8100421a.wiff s100421a.wiff S100421 a.wiff s1 0 0 4 2 1 a .w iff s100421a.wiff s1 0 0 4 2 1 a .w iff &100421a.wiff s1 0 0 4 2 1 a .w iff s100421a.wiff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff a100421a.wiff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s100421a.wiff s1 0 0 4 2 1 a .w iff s1 0 0 4 2 1 a .w iff s100421a.wiff s1 0 0 4 2 1 a .w iff 6100421a.wiff s100421a.wiff s100421a.wiff s100421a.wiff S100421 a.wiff s100421a wiff 81 00 42 1a . w iff s100421a.wiff s100421a.wiff s100421a.wiff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff 6100421a.vriIT S100421 a.wiff s1 00 4 2 1 a .w iff 8100421a.wiff s100421a.wiff 8100421a.wiff s1 00 4 2 1 a .w iff 8100421a.wiff 8100421a.wiff 6100421a.wiff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s1 00 4 2 1 a .w iff s100421a.wiff 6100421a.wiff Printing D Printing ^ a ^^ M 0?" ' ' 2010 Page 3 of 14 Page 106 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb S am ple Name Sam ple ID 202 s100421a202 203 s100421a203 204 8100421a204 20S e100421a20S 26- 18100421a206 207 s100421a207 208 e100421a208 209 8100421a209 210 s100421a210 211 8l00421a211 212 s100421a212 213 s100421a213 1214 s100421a214 215 1 s100421a215 216 s100421a216 217 8100421a217 218 s100421a216 219 8100421a219 2 2 0 "1 8100421 a220 221 s100421a221 222 8100421a222 223 s100421a223 224 s100421a224 225 8100421225 226 8100421 226 227 81004218227 228 81004218226 229 8100421a229 23 s100421a230 231 8100421a231 232 8100421a232 233 81004218001 234 8100421a002 235 S00421 a003 236 8100421a004 237 8100421a005 238 81004213006 239 8100421a007 240 8100421a008 241 8100421a009 242 6l00421a010 243 s100421a011 244 Bl421a12 245 s100421a013 246 s100421a014 247 s100421a015 248 s100421a016 249 81004213017 250 s100421a018 251 s100421a019 252 8100421a020 253 s100421a021 254 8100421a022 255 8100421a023 256 8100421a024 257 8100421a025 258 6100421a026 259 8100421a027 260 8100421a028 261 8100421a029 262 8100421a030 263 8100421a031 264 8100421a032 265 8100421a033 266 8100421a034 267 s100421a035 268 s100421a036 GLP1001-01 -01-019 Dil.xSO DAL DF8C SS SS03 1 0010 Dil.x50 GLP104)1-01^01^019 Dup Dil.xSO DAL DFSC SS SS3 1 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-019 LMS Dil.xSO DAL DF8C SS SS03 1 0010 Lab Matrix Spike Dil.x50 GLP10-01-01-01-023 Dil.x50 DAL DF8C SS SS05 0 0010 Dil.x50 GLP10-01-01-01-023 Dup Dil.xSO DAL DFSC SS SS05 0 0010 Sample Duplicate Dil.xSO GLP10 -0 1 -0 1 -0 1 -023 LMS DiLxSO DAL DF8C SS SS05 0 0010 Lab Matrix Spike Dil.x50 GLP10-01-01-01-024 Dil.xSO DAL DF11 SS SS05 0 0000 Dil.xSO GLP10-01-01-01-024 Dup Dil.xSO DAL DF11 SS SS05 0 0000 Sample Duplicate Dil.xSO GLP10-01-01-01-024 LMS Dil.xSO DAL DF11 SS SS05 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-025 Dil.xSO DAL DF11 SS SS05 0 0010 Dil.xSO GLP10-01-01-01-025 Dup Dil.xSO DAL DF11 SS SS05 0 0010 Sample Duplicate DiLxSO GLP10-01-01-01-025 LMS Dil.xSO DAL DF11 SS SS05 0 0010 Lab Matrix Spike Dil.x50 09004-129 solvent blank EC-10041S-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-026 Dil.xSO DAL DF11 SS SS05 1 0010 Dii x50 GLP10-01-01-01-026 Dup DiLxSO DAL DF11 SS SS05 1 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-026 LMS Dil.xSO DAL DF11 SS SSOS 1 0010 Lab Matrix Spike DiLxSO GLP10-01-01-01-027 Dil.xSO DAL DF11 SS SS06 0 0000 DiLxSO GLP10-01-01-01-027 Dup DiLxSO DAL DF11 SS SS06 0 0000 Sample Duplicate DiLxSO GLP10-01-01-01-027 LMS Dil.x50 DAL DF11 SS SS06 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-029 DiLxSO DAL DF11 SS SS07 0 0000 Dil.xSO GLP10-01-01-01-029 Dup DiLxSO DAL DF11 SS SS07 0 0000 Sample Duplicate DiLxSO G LP10-01-01-01-029 LMS Dil.xSO DAL DF11 SS SS07 0 0000 Lab Matrix Spike Dii.x50 p jj xg OAL DF11 SS SS7 O DI.xS GLP10-01-01-01-030 Dup Dil.x50 DAL DF11 SS SS07 0 0010 Sample Duplicate Dil.x50 G LP10-01-01-01-030 LMS Dil.x50 DAL DF11 SS SS07 0 0010 Lab Matrix Spike DiLxSO 09004-129 solvent blank EC-100415-05 2.S ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-09 50 ng Warm up standard EC-10041S-09 50 ng Warm up standard EC-100415-09 50 ng Warm up standard 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-10415O1 0.2 ng Extracted Curve Point EC-1041SO2 .5 ng Extracted Cune Point EC-10041503 0.75 ng Extracted Curve Point EC-100415-04 1 ng Extracted Cune Point EC-100415-05 2.5 ng Extracted Curve Point EC-10041S06 5 ng Extracted Curve Point EC-10041507 10 ng Extracted Cune Point EC-10041508 25 ng Extracted Curve Point EC-100415-09 SO ng Extracted Cune Point EC-100415-10 100 ng Extracted Curve Point EC-100415-11 200 ng Extracted Cune Point EC-100415-12 500 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank MB--100415-01 Method Blank 1 w/o IS M B-10041S 02 Method Blank 2 w/o IS MB--100415-03 Method Blank 3 w/o IS MB--1004154)4 Method Blank 4 w f IS MB-10041S-5 Method Blank 5 w / IS MB-10041S-06 Method Blank 6 w / IS LCS-100415-01 3 ng LCS in TCR-642 LCS-141502 3 ng LCS in TCR642 LCS-100415-03 3 ng LCS in TCR-642 LCS-100415-04 30 ng LCS in TCR-642 Analyte Peak ,, . to m a I s * m l>to T " M4PFOS M4PFOS M4PFS M4PFOS M4PFOS M4PFS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS M4PFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS >FBS PFBS PFBS PFBS PFBS PFBS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Biank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Use Record A n a ly te C o n ce n tra tio n (ng/m L) -- Analyte R e te n tio n Time (m in) Analyte Peal A rea (counts) IS Peak Nam e IS P e a k Area (counts) IS C o n ce n tra tio n (ng/m L) IS R e te n tio n Time (m in) C a lc u la te d C o n ce n tra tio n (ng/m L) A ccu ra cy (%) Record M o d ifie d File Name E j j ; E E E E R E E E E E E LE E N/A N/A N/A N/A N/A N/A N/A N/A N/A M/A N/A |N /A 000 10.0 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 2.50 0.00 0.00 0.00 0.00 .0 0.00 [0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.498 0.747 0.996 2.49 4.98 9.96 24 9 49.8 99.6 199. 498. 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A N/A N/A N/A N/A N/A N/A 12.90 12.89 12.89 12.87 12.87 12.87 12.85 12.87 12.86 12.87 12.66 12.87 12.85 12.86 12.99 12.85 12.84 12.78 12.82 12.81 12.81 12.81 12.79 12.80 12.79 12.82 12.79 0.000 12.79 12.92 13.04 7.697 7.959 7.808 7.788 7.788 7.669 7.606 7.929 7.707 7.788 7.778 7.758 7.737 7.737 7.717 7.717 7.748 7.748 7.748 7.737 7.727 7.727 7.798 7.959 7.737 7.667 7.697 7.758 7.667 7.768 7.818 7.7S8 7.727 7.737 7.717 7.737 61172 61185 55546 61995 59945 56442 63791 63313 55257 61790 57428 57694 34 195167 22 60345 62798 59317 63619 59915 58371 52513 52864 47S65 60626 60629 56338 0 51023 56 22 12296 563 8593635 8518311 8650467 1093 1363 1213 2057 495 40605 86786 127927 168343 431904 639039 1690154 4356061 8716511 16531962 29956260 58165154 6124 284 614 819 3268 2626 2952 5607 99339 5972 532234 531722 522959 5313721 M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS "M8PFOS M8PFOS M8PFOS M8PFOS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1 8 0 2 PFBS 1802 PFBS 1602 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 58752 60843 54467 62475 61639 60228 59033 63162 56451 61662 59354 58499 46 57778 0 60638 56303 58013 60112 63157 59802 51332 46739 46963 61288 61189 57126 56 65354 22 46 237 143 458830 451515 457601 58 188 70 34 94 44552 436497 435226 446093 443869 4S1287 444744 459717 4S9622 459742 421292 373877 128 0 0 46 80 0 20 437450 437844 448055 435S92 452052 440924 464638 3.00 3 .X 3,00 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X tv'A 3 .X N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 3 .X 3.06 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3.06 3 .X N/A N/A N/A N/A N/A N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 12.88 12.87 12.91 1 2 .X 1 2 .X 12.X 12.87 12.X 12.87 12.X 12.X 12.X 12.X 12.87 0.000 12.83 12.81 12.77 12.82 12.X 12.81 12.79 12.79 12.60 12.79 12.78 12.78 12.61 12.X 12.77 12.84 7.697 7.737 7.798 7.798 7 .7 X 7 .X 7 7 .9 X 7.737 7.667 7.768 7.768 7.717 7.717 7.748 7.758 7.727 7.717 7.758 7.737 7.737 7.737 7.737 7.707 O.OX O.OX 7.949 7.959 .X 7 .7 X 7.737 7.727 7.717 7.727 7.737 7.727 7.717 3.14 3.03 3.07 2.99 2.93 2.82 3.26 3.02 2 .X 3.02 2.91 2.97 N/A 10.3 N/A 2 99 3.25 3 .X 3.20 2 .X 2.94 3 .X 3.27 2.93 2 .X 2.99 2.97 N/A 2.34 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A .29 0.503 0.740 0.958 2.52 4.8S 9 .X 25.0 50.5 97.6 201. 4X. N/A N/A N/A N/A N/A N/A N/A 0 .X 3 X 0.564 0.00469 3.17 3.05 3 .X 30.2 N/A n s100421a.wiff N/A E 8100421a,wiff N/A g is100421a.wiff N/A E s100421a.wri! N/A E s100421a.wiff RN/A s100421a.wiff RN/A s100421a.wiff N/A E s100421a.wiff N/A s100421a.wi1T N/A n 8100421a.wiff N/A n s100421a.wiff N/A E s100421a.wiff N/A 103. n s100421a.wiff s1 00 4 2 1 a .w iff N/A 8100421a.wiff N/A ~ ' K s 1 0 0 4 2 1 a .w iff N/A 8100421a,wiff EN/A s100421a.wiff N/A E 8100421a,wiff N/A 8100421a.wiff N/A E s100421a.wiff RN/A 8100421a.wiff N/A E s100421a.wiff N/A E 8100421a,wiff N/A s100421a.wiff N/A 8100421a.wiff N/A n e100421a.wiff N/A s100421a,wiff 93.7 8100421a,wiff N/A s100421a.wiff N/A 8100421a.wiff N/A s100421a.wiff N/A 8100421a.wiff N/A 8100421a.wiff N/A n 8100421 a.wiff N/A E 8100421 a.wiff N/A n 8100421a.wiff N/A n 8100421a.wiff N/A 8100421 a.wiff N/A 8100421 a.wiff N/A 105. H 8100421 a.wiff 8100421 a.wiff . 8100421 a.wiff 99.0 R 8100421 a.wiff X .2 101. 97.3 X .9 100. 101. X .O E 8100421 a.wiff E 8100421 a.wiff E e100421a.wiff n 8100421 a.wiff 8100421 a.wiff E 6l00421a.wiff e1004 2 1 a .w iff n101. E 8100421a.wiff X . 9 s100421a.wiff N/A n 8100421a.wiff N/A 8l00421a.wiff N/A 8100421a.wiff N/A 8l00421a.wiff N/A 8100421a.wiff N/A 8100421a.wiff N/A N/A *N/A N/A N/A E 8100421a.wiff 8100421 a.wiff 8100421 a.wiff n 8100421 a.wiff 8100421 a.wiff N/A r i 8100421 a.wiff N/A 8100421 a.wiff N/A 6100421 a.wiff Printing >>3M St2tV1G :P1M0t-0226 ' 2010 Printing T ^ m2! poLPo0M Page 4 of 14 Page 107 of 539 Stan V1660305 *3M Environmental Lab S am ple Name S am ple 10 269 s100421a037 LCS-100415-05 30 ng LCS in TCR-842 270 s100421a038 LCS-100415-06 30 ng LCS in TCR-642 27. 8100421a039 LCS-1D0415-07 300 ng LCS in TCR-642 272 8100421a040 LCS-100415-08 300 ng LCS in TCR-842 273 Is100421a041 LCS-100415-09 300 r ^ LCS in TCR-842 274 8100421a042 09004-129 solvent blank 275 8100421a043 EC-100415-05 2.5 ng Extracted Cune Point 276 8100421a044 09004-129 solvent blank 277 8100421a045 GLP1CW1-01-01-033 Soil Trip Blank 1 278 8100421a046 GLP10-01-01-01-033 Oup Soil Trip Blank 1 Sample Duplicate 279 ;&100421a047 GLP10-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike 280 8100421a046 GLP10-01-01-01-034 Soil Trip Blank 3 281 s100421a049 GLP10-01-01-01-034 Dup Soil Trip Blank 3 Sample DupBcate 282 s100421a050 GLP1001-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike 283 ' s10421a51 GLP1001 O l 01-001 DAL DF05 SS SS06 0 0000 284 s100421a052 G L P 1 0 0 1 0 1 0 1 0 0 1 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate 285 8l00421a053 GLP10O1O101-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike 286 s100421a054 i GLP 10-01-01-01-002 DAL OF05 SS SS06 0 0010 287 s100421a055 GLP10 0 1 0 1 0 1 0 0 2 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate 288 s100421a056 GLP10 0 1 0 1 0 1 0 0 2 LMS DAL DF05 SS SS06 0 0010 Lab Matrix Spike 289 s100421a057 G L P 1 0 0 1 0 1 0 1 0 0 3 DAL DF05 SS SS06 1 0010 290 s100421a058 GLP10 0 1 0 1 0 1 0 0 3 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate 291 s100421a0S9 GLP10O10 1 0 1 0 0 3 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 292 ;8100421a060 09004-129 solvent blank 293 s100421a061 EC-100415-06 5 ng Extracted Curve Point 294 8l00421a062 09004-129 solvent blank 295 is100421a063 G LP10010 1 0 1 0 0 4 DAL DF05SS SS07 0 0000 296 8100421a064 G L P 1 0 0 1 0 1 0 1 0 0 4 Dup DAL DFS SS SS7 0 0000 Sample Duplicate 297 s100421a065 GLP10O10 1 0 1 0 0 4 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike 298 8100421a066 GLP10O10 1 0 1 0 0 5 DAL DF05 SS SS07 0 0010 299 8100421a067 GLP10O10 1 0 1 0 0 5 Dup DAL DF05 SS SS07 0 0010 Sample Duplicate 300 8100421a068 " IGLP1 0 0 1 0101-00 5 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike 301 8100421a069 G L P 1 0 0 1 0 1 0 1 0 0 7 DAL DF05 SS SS08 0 0000 302 8100421a070 G L P 1 0 0 1 0 1 0 1 0 0 7 Dup DAL DF05 SS SS08 0 0000 Sample Duplicate 303 8l00421a071 G L P 1 0 0 1 0 1 0 1 0 0 7 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike 304 8100421a072 G LP1 0 0 1 0 1 0 1 0 0 8 DAL DF05 SS SS08 0 0010 305 s100421a073 G LP1 0 0 1 0 1 0 1 0 0 8 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate 306 s100421a074 G LPO O O VO O e LMS DAL DF5 SS SS8 1 Lab Matrix Spike 307 s100421a075 GLP10O1O10 1 0 1 0 DAL DF05 SS SS09 0 0010 308 e100421a076 G L P 1 0 0 1 0 1 1 0 1 0 Dup DAL DF05 SS SS09 0 0010 Sample Duplicate 309 s100421a077 G L P 1 0 0 1 0 1 0 1 0 1 0 LMS DAL DF05 SS SS09 0 0010 Lab Matrix Spike 310 8100421a078 09004-129 solvent blank 311 s100421a079 E 0 1 0 0 4 1 5 0 7 10 ng Extracted Curve Point 312 8l00421a080 09004-129 solvent blank 313 8100421a081 GLP10-01-01-01-016 DAL DF8C SS SSQ2 0 0010 314 8100421a082 GLP10-0101-01-016 Dup DAL DF6C SS SS02 0 0010 Sample Duplicate 315 8100421a083 GLP1-lO l O l -016 LMS DAL DF8C SS SSQ2 1 2b Matrix Spike 316 n s100421a084 GLP10O101-01-009 DAL DF05 SS SS09 0 0000 317 8100421a08S GLP10 0 1 0 1 0 1 0 0 9 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate 318 1 8100421a086 G LP1 0 0 1 0 1 0 1 0 0 9 LMS DAL DF05 SS SS09 0 0000 Lab Matrix Spike 319 8100421a087 GLP1001-01-01-011 DAL DF05SS SS10 0 0000 320 8100421a088 G L P 1 0 0 1 0 1 0 1 0 1 1 Dup DAL DF05 SS SS10 0 0000 Sample Duplicate 321 8100421a089 GLP100101-01-011 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike 322 8100421a090 GLP1001-01-01-012 DAL DF05 SS SS10 0 0010 323 8100421a091 GLP10-01 -01-01-012 Dup DAL DF05 SS SS10 0 0010 Sample Duplicate 324 s100421a092 325 j 8l00421a093 GLP10-01-01-01-012 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike GLP10-01-01-01-013 DAL DF8C SS SS01 0 0000 326 s100421a094 GLP10-01-01-01-013 Dup DAL DF8C SS SS01 0 0000 Sample Duplicate 327 s100421a095 GLP10-01-01-01-013 LMS DAL DF8C SS SS01 0 0000 Lab Matrix Spike 328 s100421a096 09004-129 solvent blank 329 s100421a097 EC-100415-05 2.5 ng Extracted Curve Point 330 s100421a098 09004-129 solvent blank 331 8100421a099 GLP10-01 -01-01-014 DAL DF8C SS SS01 0 0010 332 s100421a100 GLP10-01-01-01-014 Dup DAL DF6C SS SS01 0 0010 Sample Duplicate 333 s100421a101 GLP10-01-01-01-014 LMS DAL DF6C SS SS01 0 0010 Lab Matrix Spike 334 s100421a102 GLP10-01-01-01-015 DAL DF8C SS SS02 0 0000 335 8l00421a103 GLP1001-01-01-015 Dup DAL DF6C SS SS02 0 0000 Sample Duplicate Printing 3Me3tLlftyaG L P lb lb 1 '0?26 ' 2010 Printing ^ M H r r jf lP P b 0 Results Name: sl00421a.rdb Analyte Pea Name ( Sam ple Type Use Record Analyte C o n ce n tra tio n (ng/m L) Analyte R e te n tio n Tim e (m in) Analyte Peal A rea (counts) IS Peak Nanw I8 Peak Arei (counts) IS C o n ce n tra tio n (ng/m L) IS R e te n tio n Tim e (m in) C alculated C o n ce n tra tio n (ng/m L) A ccu ra cy (%) Record M odified File Name PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Unknown Unknown Unknown Unknown Unknown Double Blank i Quality Control E Double Blank i Unknown ; Unknown Unknown Unknown Unknown Unknown : Unknown 1 Unknown i Unknown j Unknown Unknown Unknown Unknown Unknown i Unknown ; Double Blank ; Quality Control E Double Blank j Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank jQuality Control E Double Blank ! Unknown j Unknown Unknown ; i Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank E Unknown Unknown Unknown Unknown Unknown N/A N/A N/A N/A N/A 0.00 2.49 0.00 N/A N/A N/A N/A N/A N/A N/A N/A r_N/A N/A N/A N/A N/A N/A 0.00 4.98 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 9.96 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 2 .4 9 0.00 N/A N/A N/A N/A N/A 7.737 7.727 7.727 7.727 7.737 7.778 7.717 7.657 7.758 7.697 7.717 7.687 7.748 7.737 7.758 7.748 j 7.758 7.748 7.748 7.768 7.737 7.768 7.768 7.677 7.737 7.717 7.798 7.737 7.758 7.758 7.869 7.748 7.737 7.778 7.758 7.768 7.758 7.768 7.778 7.768 7.778 7.636 7.778 7.919 7.788 7.758 7.758 7.826 7.748 7.768 7.798 7.808 7.760 7.778 7.737 7.748 7.778 7.737 I7.778 7.717 7.778 7.788 7.806 7.778 7.758 7.748 7.737 5313936 5190777 42494261 42251703 42207990 6311 441781 285 8627 7306 170792 5372 6358 166581 55519 56100 226105 26157 25645 168613 27564 27794 176545 259 858030 10 11379 11563 179985 10464 11213 171784 34532 28037 187367 10379 11063 173107 15683 12865 181559 2108 1684557 241 10143 8562 174984 18964 19044 168702 20259 '22508 175271 21804 20930 181950 41234 42423 197414 297 433504 509 56751 56180 216871 25695 27094 1802' PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1 8 0 2 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 8 2 PFBS 1602 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1602 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1 8 0 2 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 444401 473132 431073 430524 42S634 58 436730 0 427849 i 444172 429733 435930 444758 446261 459838 443275 1430207 436088 484530 426860 452398 455641 436294 81 449390 22 433451 451924 434226 440931 450811 432772 441751 480244 430252 430163 417696 441155 478520 452510 476745 62 441047 0 456445 454424 436290 461653 451707 439139 451434 452473 431795 435270 441695 432016 431044 420113 406428 46 431802 92 438616 435562 412271 414127 431878 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.6 3.06 3.06 N/A 3.06 N/A 3.06 "3 0 6 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06. 7.717 7.737 7.748 7.707 7.727 7.798 7.717 0.000 7.737 7.727 7.737 7.758 7.748 7.727 7.768 7.748 7.748 7.748 7.758 7.758 7.758 7.748 7.768 7.919 7.758 7.828 7.748 7.758 7.748 7.758 7.758 7.748 7.737 7.768 7.758 7.748 7.768 7.758 7.768 7.758 7.768 7.697 7.758 0.000 7.788 7.778 7.778 7.768 7.788 7.768 7.758 7.838 7.748 7.788 7.768 7.758 7.7S8 7.758 7.758 7.889 7.778 7.717 7.758 7.7S8 7.758 7.748 7.768 31.6 29.0 288. 287. 290. N/A 2.62 N/A 0.0226 0.0131 1.01 0.00227 0.00742 0.947 0 286 0.30 1.35 0.127 0.109 1.13 0.129 0.130 1.04 N/ 4.98 N/A 0.0387 0.0370 1.06 0.0321 0.0351 1.01 0.175 0.123 1.11 0.0332 0.0393 0.997 0.0569 0.0444 0.963 N/A 10.0 N/A 0.0282 0.0193 1.02 0.0775 0.0804 1.10 0.087S 0.100 1.03 0.101 0.0940 1.07 0.220 0.234 1.24 N/A 2.60 N/A 0.309 0.308 1.35 0.132 0.134 N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.9 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 104. N/A N/A N/A N/A N/A N/A s100421a.wiff s100421a.wiff s100421a.wiff n s100421a.wifi s100421a.wiff 6100421a.wiff s100421 a.wiff K 6100421a.wiff E 8100421a.wiff E 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff ....... ....... 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff n 8100421 a.wiff n 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff E 6100421 a.wiff s10042a.wiff 8100421 a.wiff E 8100421 a.wiff s100421a.wiff E 8100421 a.wiff s100421a.wiff 8100421 a.wiff E S10421 a.wiff 8100421 a.wiff n s100421a.wiff s100421a.wiff s100421a.wiff 8100421a.wiff E s100421a.wiff 8100421a,wiff s100421a.wiff nE 8100421a.wiff 8100421a. w iff 8100421 a.wiff 8100421a.wiff 8100421a.wiff s 100421 a.wiff 8100421 a.wiff 8 0 0 4 2 a.wiff nE 8100421 a.wiff 8100421 a.wiff nE 8100421 a.wiff 8100421 a.wiff s100421a.wiff E 8100421a,wiff E 8100421 a.wiff s100421a.wiff n 8100421a.wiff 8100421a.wiff 8l00421a.wiff 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff Page 5 of 14 Page 108 of 539 Stan V1660305 *3M Environmental Lab Sample Name Sample IO 336 s100421a104 337 s100421a105 338 siO421a16 339 s100421a107 340 s100421a108 341 8l00421a109 342 8l00421a110 343 8 l0 0 4 2 a 344 8l0O421a112 345 s10O421a113 346 s100421a114 '347 s100421a11S 348 8l0O421a116 349 s100421a117 360 ^ s100421a118 351 ^ 8l00421a119 352 1 e100421a120 353" 1 s100421a121 354 8l00421a122 355 s100421a123 356 e100421a124 357 s100421a12S 358 ^ 8l00421a126 359 s100421a127 360 6 l0 0 4 2 a 2 8 361 s100421a129 362 ^ s100421a130 363 s100421a131 364 s100421a132 365 s100421a133 366 s100421a134 367 s100421a135 368 s100421a136 369 8l00421a137 370 6l00421a138 '371 Hs100421a139 372 s100421a140 373 s100421a141 374 s100421a142 375 s100421a143 376-- s100421a144 377 8l00421a145 378 s100421a146 `379 s100421a147 380 s100421a148 381 |s100421a149 382 s100421a150 383 s10O421a151 384 s10O421a152 385 s10O421a153 386 s10O421a154 387 8l00421a1SS 388 8l0O421a156 389 s100421a157 390 s10O421a158 391 s10O421a1S9 392 8l00421a160 393 8l00421a161 394 s100421a162 395 e100421a163 396 s100421a164 397 s100421a165 398 Bl00421a166 399 s100421a167 400 6l00421a168 401 s100421a169 402 s100421a170 GLP10-01-01-01-015 LMS DAL DF8C SS SSQ2 0 0000 Lab Matrix Spike GLP10-01-01-01-020 DAL DF8C SS SS04 0 0000 GLP10-01-01-01-020 Dup DAL DF8C SS SS04 0 0000 Sample Dupficate GLP10-01-01-01-020 LMS DAL DF8C SS SS04 0 0000 Lab Matrix Spike GLP10-01-01-01-021 DAL DF8C SS SS04 0 0010 GLP 1Oi-i 4)14721 Dtip DAL DF8C S S SS04 0010 Sample Duplicate GLP 10O1 -01-01-021 LMS DAL DF8C SS SS04 0 10 Lab Matrix Spike GLP 1001 -014)14722 DAL DF8C SS SS05 0 00 GLP1001-01-01-022 Dup DAL DF8C SS SS05 0 0000 Sample Duplicate GLP10-0101-01-022 LMS DAL DF8C SS SS05 0 0000 Lab Matrix Spike 09004-129 solvent blank EC-10041506 5 ng Extracted Curve Point 09004-129 solvent blank GLP10O10 1 0 1 0 2 8 DAL DF11 SS SS06 0 0010 GLP10O10 1 0 1 0 2 8 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate GLP10O10 1 0 1 0 2 8 LMS DAL DF11 SS SS06 0 0010 Lab Matrix Spike GLP10O10 1 0 1 0 1 7 DAL DF8C SS SS03 0 0000 G L P 1 0 0 1 0 1 0 1 0 1 7 Dup DAL DF8C SS SS03 0 0000 Sample Duplicate GLP10O10 1 0 1 0 1 7 LMS DAL DF8C SS SS03 0 0000 Lab Matrix Spike GLP10O10 1 0 1 0 1 8 DAL DF8C SS SS03 0 0010 GLP10O10 1 0 1 0 1 8 Dup DAL DF8C SS SS03 0 0010 Sample Dupficate GLP10O10 1 0 1 0 1 8 LMS DAL DF8C SS SS03 0 0010 Lab Matrix Spike G L P 1 0 0 1 0 1 0 1 0 1 9 DAL DF8C SS SS03 1 0010 GLP10O1O10 1 0 1 9 Dup DAL DF8C SS SS03 1 0010 Sample Dupficate GLP10O10 1 0 1 0 1 9 LMS DAL DF8C SS SS03 1 0010 Lab Matrix Spike GLP10O1O10 1 0 2 3 DAL DF8C SS SS05 0 0010 GLP10O1O10 1 0 2 3 Dup DAL DF8C SS SS05 0 0010 Sample Dupficate G iJ*1 0 0 1 0 1 0 1 0 2 3 LMS DAL DF8C SS SS05 6 0010 Lab Matrix Spike 09004-129 solvent biank EC-10041507 10 ng Extracted Curve Point 09004-129 solvent blank G L P 1 0 0 1 0 1 0 1 0 2 4 DAL DF11 SS SS05 0 0000 GLP10 0 1 0 1 0 1 0 2 4 Dup DAL DF11 SS SS05 0 0000 Sample Duplicate G LP1 0 0 1 0 1 0 1 -0 2 4 LMS DAL DF11 SS SS05 0 0000 Lab Matrix Spike GLP10 0 1 0 1 0 1 0 2 5 DALDF11 SS SS05 0 0010 GLP10O1O10 1 0 2 5 Dup DAL DF11 SS SS05 0 0010 Sample Duplicate G LP1 0 0 1 0 1 0 1 0 2 5 LMS DAL DF11 SS SS05 0 0010 Lab Matrix Spike GLP 1 0 6 1 0 1 0 1 0 2 6 DAL DF11 SS SS05 1 0010 GLP1 0 0 1 0 1 0 1 0 2 6 Dup DAL DF11 SS SS05 1 0010 S ampie Duplicate G LP1 0 0 1 0 1 0 1 0 2 6 LMS DAL DF11 SS SS05 1 001 Lab Matrix Spke 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Cune Point 09004-129 solvent blank G L P 10010101 -0 27 DAL DF11 SS SS06 0 0000 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sample Duplicate G LP1001-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 GLP 10-01-01-01-029 Dup DAL DF11 SS SS07 0 0000 Sample Duplicate GLP10-01-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike GLP10-01-01-01-030 DAL DF11 SS SS07 0 0010 GLP10-01-01-01-030 Dup DAL DF11 SS SS07 0 0010 Sampie Duplicate GLP10-01-01-01-030 LMS DAL DF11 SS SS07 0 0010 Lab Matrix Spike 09004-129 solven i biank 09004-129 solvent biank 09004-129 solvent biank EC-100415-06 5 ng Extracted Cune Point 09004-129 solvent biank MB--100415-07 Method Biank 5g w / IS for Dilutions MB--100415-08 Method Blank 5g w / IS for Dilutions MB--100415-09 Method Blank 5g w / IS for Dilutions MB-100415-10 Method Blank Sg w / IS for Dilutions MB--100415-11 Method Blank Sg w / IS for Dilutions LCS-10041S-07 Dil.xSO 300 ng LCS in TCR-842 Dil.xSO LCS-100415-08 Dil.xSO 300 ng LCS in TCR-842 Di!.x50 LCS-100415-09 Dil.xSO 300 ng LCS in TCR-842 Dil.xSO Printing Printing G L P 1 0 -0 0 ? 26 ' 2010 poftPoO-0 Results Name: sl00421a.rdb . ...... .......... ...... r ............................. Analyte Peak . ,_ (m e S*"ple Type I Use Record A n a ly te C o n c e n tra tio n (n g /m L ) PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Double Blank 0 .0 0 PFBS PFBS Quality Control Double Blank E 4.98 0 .0 0 PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Double Blank 0.00 PFBS PFBS Quality Control Double Blank E 9.96 0 .0 0 PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS H Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Double Blank 0.00 PFBS Double Biank 0.00 PFBS Double Blank jO.OO PFBS PFBS Quality Control Double Blank E 2.49 0.00 PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS Unknown N/A PFBS PFBS PFBS Double Blank Double Blank Double Blank j [ 0.00 0 .0 0 0 .0 0 PFBS PFBS Quality Control E Double Blank ) 4.98 0.00 PFBS Unknown i N/A PFBS Unknown N/A PFBS Unknown N/ PFBS Unknown ] N/A PFBS Unknown { N/A PFBS Unknown ] N/A PFBS Unknown I N/A PFBS Unknown j N/A Analyte R e te n tio n U rne (min) Analyte Peal Area (counts 7.778 7.737 7.748 7.758 7.798 7.768 7.758 7.778 7.788 7.768 7.586 7.778 7.909 7.748 7.768 7.768 7.768 7.748 7.748 7.768 7.768 7.778 7.768 7.788 7.768 7.758 7.768 7.768 7.869 7.758 0.000 7.737 7.758 7.758 7.778 7.758 7.727 7.727 7.768 7.737 7.727 7.778 7.737 7.748 7.778 7.748 7.758 7.768 7.768 7.768 7.758 7.788 7.788 7.788 7.788 7.778 7.778 7.758 7.748 7.828 7.778 7.808 7.758 7.778 7.778 7.768 7.768 1185457 12109 l 7476 176426 23495 11062 177619 50629 37786 " 1220188 79 827160 496 42545 47460 205440 492563 483401 2143309 272312 299550 1929586 247183 289127 1893031 1322886 1354870 2930123 733 1624230 0 299089 171321 311882 50499 72435 212071 46613 44669 212805 975 728 2673 422562 3554 91969 72182 224171 594211 1213202 2398684 26645 22216 184676 3452 4380 483 810092 578 4281 4019 10420 3629 4500 1021905 1036494 1041064 1 8 0 2 PFBS 1802 PFBS 1602 PFBS' 1802 PFBS 1 6 0 2 PFBS 1 6 0 2 PFBS 1802 PFBS 1 8 0 2 PFBS 1 8 0 2 PFBS 1602 PFBS 1 8 0 2 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS ^1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1 8 0 2 PFBS 1 6 0 2 PFBS 1 6 0 2 PFBS 1 8 0 2 PFBS 1602 PFBS 1802 PFBS 1 6 0 2 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 4134S8 476173 458906 429266 444926 469633 435398 427585 429581 425701 57 427940 56 477570 440709 432391 450873 439253 420718 426388 437368 423279 433221 4479,'G 419147 430469 429439 419466 58 424654 34 448790 440825 438765 447299 4SS745 436105 435079 428964 423186 46 22 0 427605 70 441569 424005 419630 446297 437012 430038 437442 444789 423357 46 22 94 424670 46 449793 428611 428716 420369 432661 433893 445054 442937 IS IS Concentratien Retention Calculated C o n c e n tra tio n Accuracy (ng/m L) Tim e (m in) (ng/m L) (% ) 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/ 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A N/A N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A N/A N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 7.748 7.788 7.768 7.776 7.778 7.768 7.778 7.758 7.778 7.748 7.659 7.768 7.919 7.758 7.758 7.778 7.737 7.748 7.768 7.788 7.768 7.758 7.768 7.778 7.748 7.737 7.768 7.778 7.919 7.748 7.969 7.758 7.768 7.748 7.758 7.737 7.748 7.748 7.748 7.768 7.758 7.909 0.000 7.748 7.939 7.758 7.737 7.748 7.748 7.758 7.768 7.768 7.758 7.758 7.806 7.899 7.578 7.768 7.798 7.748 7.768 7.768 7.778 7.788 7.758 7.768 7.788 1.14 N/A .366 N/A 0.0697 N/A 1 0 5 N/A 0.108 N/A 0.037 N/A .4 N/A 0 280 N/A 0.200 ' N/A 1.32 N/A N/A N/A 5.04 101. N/A N/A 0.203 N/A 0.252 N/A 1.21 N/A 2.83 N/A 2.85 N/A 13.4 N/A 1.64 N/A 1.76 N/A 12.0 N/A 1.46 N/A 1.68 N/A 11.8 N/A 6.04 N/A 6.25 N/A 18 4 N/A N/A N/A 10.0 101. N/A N/A 1.72 N/A *0.988 N/A 1.83 N/A 0.266 N/A 0.386 N/A 1.24 N/A 0.250 N/A 0.243 N/A 1.29 N/A N/A N/A N/A N/A N/A N/A 2.56 103. N/A N/A 0.515 N/A 0.416 N/A 1.37 N/A 3.46 N/A 7.26 N/A 14.6 N/A 0.129 N/A 0.101 1.11 N/A N/A N/A N/A N/A N/A N/A N/A 4.97 99.8 N/A N/A < 0 N/A < 0 N/A 0.0336 N/A < 0 N/A < 0 N/A 6.15 N/A 6.08 N/A 6.14 N/A Record M o d if ie d File Name s100421a.wi1f 6100421a.w ill e100421a.wiff n s100421a w iff 8100421 a.wiIf 8100421 a.wiff [ ; 8100421 a.wiff 8l00421a.wiff 8100421a.wiff E 8100421 a.wiff o 8100421a.wiff 8100421a.wiff 8l00421a.wiff s100421a w iff 8100421 a.wiff E 8100421a.wiff 8l00421a.wiff E 8100421a.wiff E s100421a.wiff E 8100421 a.wiff E 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff 6100421 a.wiff n 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff E _8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff n 8100421 a.wiff E s100421a.wiff n 8100421a,wiff D 6l00421a.wiff E 8100421a.wiff n 8100421a.wiff n s100421a.wiff 8100421a.wiff K 8100421a.wiff 8100421a.wiff s100421a.wiff 8100421a.wiff E 8100421a.wiff s100421a.wiff E 8100421a.wiff n 8100421 a.wiff n 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff n s10O421a.wiff n 8100421 a.wiff s100421a.wiff E 8100421a.wiff s100421a.wiff 8100421a.wiff E s100421a.wiff E 8100421a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff Page 6 of 14 Page 109 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Sam ple Name Sample ID 403 ~ 81004218171 404 ^ e100421a172 405 81004218173 406 s100421al74 407 s100421a175 408 s100421a176 409 s 0 0 4 2 a 7 7 410 s100421a176 411 s100421a179 412 s100421a180 413 s100421a181 414 s100421a182 415 s100421a183 416 1s100421a184 417 s100421a18S 416 s100421a186 419 s100421a187 420 8l00421a188 421 s100421a169 422 e100421a190 423 s100421a191 424 s100421a192 42S s100421a193 426 s100421a194 427 s421a195 426 e100421a196 429 a100421a197 430 s100421a198 431 b 100421a199 432 8100421a200 433 8100421a201 434 8100421a202 435 s100421a203 436 8100421a204 437 8100421a205 438 8100421a206 439 8100421a207 440 8100421a208 441 8100421a209 442 8100421a210 443 8100421a211 444 8100421a212 445 8100421a213 446 8100421a214 447 8100421a21S 446 s100421a216 449 s100421a217 450 s100421a218 451 s100421a219 452 s100421a220 453 s100421a221 454 s100421a222 455 s100421a223 456 s100421a224 457 8100421a22S 456 8100421a226 459 s100421a227 460 8100421a228 461 8100421a229 462 8100421a230 463 81004213231 464 8100421a232 465 8100421a001 468 61004218002 467 8100421a003 468 81004218004 469 8100421a005 GLP10-01-01-01-009 LMS Dl.xSO DAL DF05 SS SS09 0 0000 Lab Matrix Spike Dil.xSO GLP10-01-01-01-011 Dil.xSO DAL DF05 SS SS10 0 0000 Dil.xSO GLP10-01-01-01-011 Dup Dil.xSO DAL DF05 SS SS10 0 0000 Sample DupGcate Dil.xSO GLP10-01-01 -01-011 LMS O l.x50 DAL DFOS SS SS10 0 0000 Lab Matrix Spike Dil.xSO 09004-129 solvent blank cPi04V54>7 10 rig Extracted Cun-' i - m 09004-129 solvent blank GLP10-01-01-01-012 LMS Dil.xSO DAL DF05 SS SS10 0 0010 Lab Matrix Spike Dil.x50 GLP1Q-01-01-01-013 LMS Dil.xS DAL DF6C SS SS01 0 0000 Lab Matrix Spike Dil.xSO GLP10-01-01-01-014 Dil.xSO DAL DF8C SS SS01 0 0010 Dil.xSO GLP10-01-01-01-014 Dup Dil.x50 DAL DF6C SS SS01 0 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-014 LMS Dil.xSO CAL DF8C SS SS01 0 0010 Lab Matrix Spike D l.x50 GLP10-01-01-01-015 LMS Dil.xSO DAL DF8C SS SS02 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-020 LMS Dil.xSO DAL DF6C SS SS04 0 0000 Lab Matrix Spike Dil.xSO 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Cune Point 09004-129 solvent blank GLP10-01-01-01-021 LMS DiLxSO DAL DF6C SS SS04 0 0010 Lab Matrix Spike Di!.x50 GLP10-01-01-01-022 LMS Dil.x50 DAL DF8C SS SSOS 0 0000 Lab Matrix Spike DiLxSO GLP1001-01-01-028 Dil.x50 DAL DF11 SS SS06 0 0010 DiLxSO GLP10-01-01-01-028 Dup Dil.xSO DAL DF11 SS SS06 0 0010 Sample Duplicate DiLxSO GLP1001-01-01-028 LMS DiLxSO DAL DF11 SS SS06 0 0010 Lab Matrix Spike DiLxSO GLP10-01 -01-01-017 DiLxSO DAL DF8C SS SS03 0 0000 DiLxSO GLP10-01-01-01-017 Dup Dil.xSO DAL DF6C SS SS03 0 0000 Sample Duplicate DiLxSO GLP10-01-01-01-017 LMS Dil.x50 DAL DF6C SS SS03 0 0000 Lab Matrix Spike DiLxSO GLP 10-01-01-01-018 DiLxSO DAL DF8C SS SS03 0 0010 DiLxSO GLP10-01 -01-01-018 Dup Dil.xSO DAL DF8C SS SS03 0 0010 Sample Dupficate DiLxSO GLP10-01-01-01-018 LMS Dil.xSO DAL DF8C SS SS03 0 0010 Lab Matrix Spike Di).x50 09004-129 solvent blank EC-100415-06 S ng Extracted Cune Point 09004-129 solvent blank G LP 100101-01-019 DiLxSO DAL DF8C SS SS03 1 0010 DI.X50 GLP10O101-01-019 Dup Dil.xSO DAL DF8C SS SS03 1 0010 Sample Duplicate DiLxSO GLP10-01-01-01-019 LMS DiLxSO DAL DF8C SS SS03 1 0010 Lab Matrix Spike DiLxSO GLP10O101-01-023 DiLxSO DAL DF8C SS SS05 0 0010 Dil.xSO GLP10-01-01-01-023 Dup Dil.xSO DAL DFSC SS SS05 0 0010 Sample Duplicate DiLxSO GLP10-01-01-01-023 LMS Dil.xSO DAL DF8C SS SS05 0 0010 Lab Matrix Spike Dil.x50 GLP10-01-01-01-024 Dil.x50 DAL DF11 SS SSOS 0 0000 Dl.xSO GLP10-01-01-01-024 Dup Dil.xSO DAL DF11 SS SS05 0 0000 Sample Duplicate Dil.xSO GLP10-01-01-01-024 LMS Dil.xSO DAL DF11 SS SS05 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-025 DiLxSO DAL DF11 SS SS05 0 0010 DiLxSO GLP10-01-01-01-025 Dup Dil.x50 DAL DF11 SS SS05 0 0010 Sample Duplicate DiLxSO GLP10-01-01-01-025 LMS Dl.xSO DAL DF11 SS SS05 0 0010 Lab Matrix Spike DiLxSO 09004-129 solvent blank EC-100415-07 10 ng Extracted Cune Point 09004-129 solvent blank GLP10-01-01-01-026 DiLxSO DAL DF11 SS SSOS 1 0010 DiLxSO GLP10-01-01-01-026 Dup DiLxSO DAL DF11 SS SS05 1 0010 Sample DupGcate Dil.x50 GLP10-01-01-01-026 LMS Dil.x50 DAL DF11 SS SSOS 1 0010 Lab Matrix Spike DiLxSO GLP10-01-01-01-027 Dil.xSO DAL DF11 SS SS06 0 0000 DiLxSO GLP1 CM>14)1-01-027 Dup Dii.xSO DAL DP11 SS SS6 Sample DupGcate Dii.xSO GLP1001-01-01-027 LMS Dil.x50 DAL DF11 SS SS06 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-029 Dil.xSO DAL DF11 SS SS07 0 0000 DiLxSO GLP10-01-01-01-029 Dup Dl.xSO DAL DF11 SS SS07 0 0000 Sample DupGcate Di!.x50 GLP10-01-01-01-029 LMS Dil.xSO DAL DF11 SS SS07 0 0000 Lab Matrix Spike DiLxSO GLP10-01-01-01-030 DiLxSO DAL DF11 SS SS07 0 0010 Dil.xSO GLP1001-01-01-030 Dup Dil.xSO DAL DF11 SS SS07 0 0010 Sample DupGcate DiLxSO GLP10O10 1 0 1 0 3 0 LMS DiLxSO DAL DF11 SS SS07 0 0010 Lab Matrix Spike Dil.x50 09004-129 solvent blank EC-10041 SOS 2.5 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-10041S-09 SO ng Warm up standard EC-10041509 50 ng Warm up standard EC-100415-09 SO ng Warm up standard Analyte Peak .^ t o m . ! 8 n ,P1 ' VP Use Record A n a ly te C o n c e n tra tio n (n g /m L ) Analyte R e te n tio n Time (min) Analyte Peal Area (counts! IS Peak Nanx IS P eak Are (counts) IS Concentration (ng/m L) IS Calculated Retention Concentration Tim e (min) (ng/m L) Accuracy (%) PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS Unknown Unknown Unknown Unknown | Double Blank j Quality Control E Double Blank ! Unknown j Unknown } Unknown Unknown Unknown Unknown j Unknown j Double Blank j Quality Control Double Blank E Unknown Unknown ; Unknown : Unknown Unknown Unknown Unknown : Unknown i Unknown i Unknown I Unknown j Double Blank \ Quality Control E Double Blank j Unknown Unknown Unknown Unknown i Unknown ; Unknown : Unknown Unknown ; Unknown ; Unknown i Unknown \ Unknown I Double Blank I Quality Control Double Blank R Unknown Unknown Unknown ] Unknown \ Unknown j Unknown j Unknown Unknown Unknown Unknown Unknown i Unknown Double Blank j f QuaBty Control E Double Blank ; Double Blank ; Double Blank < Double Blank Double Blank Double Blank Double Blank i ! i j N/A N/A jN/A N/A 0.00 9.96 0.00 N/A N/A N/A N/A N/A N/A N/A 0.00 2 .4 9 000 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 4.98 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 9.96 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 2.49 0.00 0.0 0.00 0.00 0.00 0.00 0.00 7.838 7.798 7.768 7.758 7.990 7.980 7.647 7.778 7.748 7.638 7.838 7.838 7.768 7.778 7.869 7.798 7.657 7.806 7.778 7.889 7.818 7.818 7.788 7.808 7.798 7.771 7.778 7.806 0.000 7.788 7.929 7.788 7.628 7.608 7.608 7.798 7.798 7.798 7.879 7.768 7.758 7.758 7.788 7.616 7.778 7.879 7.798 7.797 7.707 . 7.778 7.7S8 7.727 7.818 7.768 7.727 7.798 7.768 7.768 7.959 7.748 7.919 0.000 10.06 9.947 10.13 10.10 10.11 9SS7 3668 2092 6128 122 524 453 8092 6405 4719 6112 6S51 8213 8628 900 410928 182 7489 7430 6210 6242 9028 11822 13603 41179 10456 9494 38574 0 816045 263 9753 9250 37240 28038 29199 56451 11109 7598 11769 5279 609S 6099 636 1631117 321 63S3 5766 9447 5290 5349 6971 15169 29508 43649 4052 4219 9004 198 426684 32S 0 1648 642 6201622 60896S5 6112542 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS F82PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1602 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1602 PFBS 1802 PFBS 1802 PFBS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 429970 440452 434654 440902 68 10 34 447629 438433 443685 443149 431158 439607 449861 81 429794 S3 447103 441909 428758 438085 429860 430949 434813 427S47 433131 430459 432471 20 426675 440915 424202 42S742 437370 433007 440849 432899 431634 426236 445752 431200 439985 0 421182 34 432699 449431 443887 435985 437SS 442968 437425 440529 442158 44633S 441432 444306 34 4287S9 34 22 20 34 194435 189546 194574 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 ^ 3.06 3.06 306 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 3.06 N/A 3.06 N/A N/A N/A N/A N/A N/A N/A 7.778 7.778 7.778 7.778 7.778 7.697 7.606 7.778 7.778 7.788 7.798 7.788 7.798 7.788 7.848 7.788 7.838 7.788 7.788 7.798 7.788 7.788 7.778 7.788 7.808 7.788 7.808 7.808 7.778 7.798 0.000 7.786 7.808 7.818 7.798 7.788 7.798 7.788 7.788 7.788 7.788 7.788 7 .//6 0.000 7.778 7.687 7.788 7.758 7.737 7.748 7.748 7.737 7.737 7.737 7.748 7.748 7.748 7.748 7.929 7.748 7.768 7.667 9.906 9.896 10.13 10.10 10.09 0.0282 <0 < 0 0.0183 N/A 150. N/A 0.0173 0.00825 <0 0.00611 0.0219 0.0169 0.0202 N/A 2.47 N/A 0.0138 0.0140 0.00792 0.00730 0.0250 0.0418 0.0519 0.222 0.0332 0.0277 0.203 N/A 4 .9 9 N/A 0.0279 0.0271 0.199 0.138 0.147 0.305 0.0372 0.0161 0.0423 0.00101 0.00700 0.0182 N/A 10.1 N/A 0.00844 0.00359 0.0257 0.00177 0.00201 0.0230 0.0609 0.14S 0.230 <0 <0 0.0231 N/A 2.58 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1500. N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.4 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A N/A N/A N/A N/A N/A N/A N/ N/A N/A N/A N/A N/A N/A 104. N/A N/A N/A N/A N/A N/A N/A Record M o d if ie d File Name R ;e100421a.wriT 8100421 a.wiff R js100421a.wiff n s100421 a.wiff s100421a.w ill 8100421 a.wiff n 8100421 a.wiff & s100421a.wiff 8100421 a.wtff s100421a.wiff e100421a.wiff E 8100421a.wtff E 8l00421a.wtff R s100421a.wtff s100421a.wiff s100421a.wiff s100421a.wiff s100421a.wiff s100421a.wiff R Bl00421a.wiff e100421a.wiff s100421a.wiff s100421a.wiff E s100421a.wiff 8100421a.wiff R 8100421a.wiff ,8l00421a.wiff 8100421a wiff " 8100421 a.wiff 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff n 8100421a.wtff s100421a.wiff a s100421a.wiff E 8l00421a.wiff R s100421a.wiff E s100421a.wtff E 8100421a wiff s100421a.wiff s100421a.wiff E s100421a.wiff s100421 aw iff E 8100421 a.wiff R 8100421 a.wiff R 8100421 a.wiff 8100421 a.wiff n 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff E s100421a.wiff E s100421a.wiff 8l00421a.wiff n s100421a.wiff R 8100421a,wiff s100421a.wiff s100421a.wiff 6100421a.wiff s100421a.wiff 8100421 a.wiff 8100421 a.wiff 6100421 a.wiff R 8100421 a.wiff s100421a.wiff Printing 13M e5tudynGt>P10W 0226 ' 2010 Printing Tfnterfm^pdrt 0 l PM Pa9e 7 of 14 Page 110 of 539 Stan V1660305 *3M Environmental Lab Sample Name Sample 10 470 100421a006 471 s100421a007 472 8100421a008 473 ^ 61004218009 474 8100421a010 475 81004218011 476 S10421812 477 18100421&013 478 161004218014 479 81004218015 480 8100421a016 481 61004218017 482 8100421a018 483 81004218019 484 8100421a020 485 8100421a021 486 8100421a022 487 81004218023 488 8100421a024 489 81004218025 490 81004218026 491 81004218027 492 n 81004218026 493 6100421a029 494 s100421a030 495 8100421a031 496 81004218032 497 8100421a033 498 8100421a034 499 81004218035 500 8100421a036 501 81004218037 502 81004218036 503 8100421a039 504 81004218040 505 81004218041 506 8100421a042 507 8100421a043 508 8100421a044 509 8100421a045 510 8100421a046 511 8100421a047 512 8100421a048 513 s100421a049 514 81004218050 515 8l00421a0S1 516 Bl00421a052 517 s100421a053 518 ^s100421a054 519 s100421a055 520 s100421a056 521 61004218057 522 8l00421a058 523 81004218059 524 s100421a060 525 s100421a061 526 s100421a062 1527 81004218063 528 s100421a64 529 81004218065 530 81004218066 531 s100421a067 532 8100421a068 533 8100421a069 534 81004218070 535 8100421a071 536 81004218072 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-01 0.2 ng Extracted Curve Point EC-10641&O2 6.5 ng Extracted Curve Point EC-100415-03 0.75 ng Extracted Curve Point EC-100415-04 1 ng Extracted Curve Point EC-100415-05 2.5 ng Extracted Curve Point EC-100415-06 5 ng Extracted Curve Point EC-100415-07 10 ng Extracted Curve Point EC-100415-08 25 ng Extracted Cun Point EC-100415-09 50 ng Extracted Cun Point EC-100415-10 100 ng Extracted Cun Point EC-100415-11 200 ng Extracted Cun Point EC-100415-12 500 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank MB--100415-01 Method Blank 1 w/o IS MB--100415-02 Method Blank 2 w/o IS MB--100415-03 Method Blank 3 w/o IS MB--100415-04 Method Blank 4 w /lS MB--10041S-05 Method Blank 5 w / IS MB--100415-06 Method Blank 6 w / IS LCS- 4SO 3 hg LCS in TCR642 LCS-100415-02 3 ng LCS in TCR-642 LCS-100415-03 3 ng LCS in TCR-842 LCS-100415-04 30 rtg LCS in TCR-842 LCS-100415-05 30 ng LCS in TCR-842 LCS-100415-06 30 ng LCS in TCR-842 LCS-100415-07 300 i q LCS in TCR-642 LCS-10041S-08 300 LCS in TCR-642 LCS-100415-09 300 ng LCS in TCR-842 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-033 Soil Trip Blank 1 GLP10-01-01-01-033 Dup Soil Trip Blank 1 Sample Duplicate GLP10-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike GLP10-01-01-01-034 Soil Trip Blank 3 GLP10-01-01-01-034 Dup Soil Trip Blank 3 Sample Duplicate GLP10-01-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike GLP10-01-01-01-001 DAL DF05 SS SS06 0 0000 GLP10-01-01-01-001 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate GLP1001-01-01-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike GLP10-01-01-01-002 DAL DF05 SS SS06 0 0010 GLP10-01-01-01-002 Dup DAL DF05 SS SS06 0 0010 S am pie Duplicate GLP10-01-01-01-002 LMS DAL DF05 SS SS06 0 0010 Lab Matrix Spike GLP10-01-01-01-003 DAL DF05 SS SS06 1 0010 GLP10-01-01-01-003 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate GLP10-01-01-01-003 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 09004-129 solvent blank EC-100415-06 5 ng Extracted Curve Point 09004-129 solvent blank GLP1001-01-01-004 DAL DFOS SS SS07 0 0000 GLP1001-01-01-004 Dup DAL DFOS SS SS07 0 0000 Sample Duplicate GLP10-01-01-01-004 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike GLP10 0 1 0 1 0 1 -0 0 5 DAL DFOS SS SS07 0 0010 GLP10-01-01-01-005 Dup DAL DF05 SS SS07 0 0010 Sample Duplicate GLP1 0 0 1 0 1 0 1 -0 0 5 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike GLP10 0 1 0 1 0 1 0 0 7 DAL DF05 SS SS08 0 0000 G L P 1 0 0 1 0 1 0 1 0 0 7 Dup DAL DFOS SS SS08 0 0000 Sample Duplicate GLP10 0 1 0 1 0 1 0 0 7 LMS DAL DF05 SS SS08 0 0000 Lab Matrix Spike GLP1 0 0 1 0 1 0 1 -0 0 8 DAL DFOS SS SS08 0 0010 Printing D3MSttf0y1`&LP10HT'P-0226 ' 2010 P rin tin g . Results Name: sl00421a.rdb Analyte Pea Name Sample Type Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte R e te n tio n Tim e (min) Analyte Peat Area (counts; IS Peak Nairn IS P eak Area (counts) IS Concentration (ng/m L) IS Retendn lim e (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy <%) PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS" PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown E E E E E E E E E E E E r .. E E 0.00 0.00 iO.OO 0.00 0.00 0.200 0.499 0.749 0.998 2 .5 0 4 .9 9 9.98 25.0 49.9 99.8 200. 499. 0.00 0.00 0.00 0.00 0.00 0.00 IO.OO N/A .. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 4 .9 9 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 10.09 10.16 10.13 10.04 10.21 10.09 10.06 10.08 10.05 10.03 10.06 10.06 10.07 10.05 10.04 10.05 10.04 10.01 10.08 9.937 10.03 10.06 9.997 9.987 10.07 10.09 10.02 10.06 10 06 10.03 10.05 10.06 10.05 10.05 10.05 10.04 10.12 10.05 10.04 10.08 10.06 10.04 10.11 10.09 10.06 10.07 10.08 10.06 10.08 10.11 10.10 10.06 10.11 10.06 10.06 10.08 10.05 10.09 10.08 10.07 10.07 10.07 10.07 10.07 10.13 10.09 10.09 1575 209 738 653 174 25609 59654 92643 114393 313799 612385 1213449 3082293 6080763 11931254 21865686 44086040 7366 2163 419 472 615 681 677 4495 9726 3288 363286 392513 379895 3867707 3879290 3614294 34280568 34788106 34469334 4135 314206 7349 4052 3631 118319 4211 3510 121000 31342 32862 147496 22720 19527 133421 17713 20326 131207 902 607925 420 43057 43674 161302 74997 29494 147618 31667 34663 149962 15474 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 182 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 21 46 0 0 91 189637 183424 186253 187179 184646 195221 185656 189901 193694 192192 177986 159902 58 0 0 0 63 34 44 179571 190206 166732 164570 191310 192226 194831 193412 192698 184417 184759 181476 34 193348 62 165846 192546 184815 167245 185632 190790 194565 189515 178355 184392 209665 181770 192591 200019 190685 81 185964 0 165141 190979 190602 166294 168550 184981 183487 204760 179969 183891 N/A N/A N/A N/A N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 N/A N/A N/A N/A N/A N/A N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.96 2.98 2.98 2.98 2.98 2.96 2.98 2.98 2.93 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 10.05 10.02 0.000 0.000 9.977 10.06 10.06 10.05 10.04 10.06 10.04 10.08 10.08 10.06 10.02 10.04 10.02 10.18 0.000 0.000 0.000 10.09 10.20 9.906 10.06 10.04 10.04 10.05 10.05 10.05 10.05 10.04 10.04 10.06 10.06 10.06 10.03 10.05 10.06 10.05 10.06 10.05 10.04 10.07 10.06 10.09 10.08 10.06 10.08 10.05 1.09 10.09 10.08 10.10 10.17 10.07 0.000 10.06 10.08 10.09 10.06 10.10 10.08 10.06 10.10 10.09 10.11 N/A N/A N/A N/A N/A 0.202 0.497 0.763 0.939 2.62 4.85 10.1 25.3 49.2 96.6 202. 498. N/A N/A N/A N/A N/A N/A N/A 0.0323 0.0727 0.0209 3 21 3.17 3.05 31.0 31.3 30.9 317. 321. 324. N/A 2.51 N/A 0.0274 0.0228 0.984 0.0284 0.0229 0.975 0.243 0.262 1.27 0.184 0.136 1.13 0.136 O".151 1.06 N/A 5.06 N/A 0.353 0.347 1.30 0.616 0.236 1.23 0.262 0.2S5 1.28 0.124 N/A N/A N/A N/A N/A 101. 99.5 102. 94.1 105. 97.2 101. 101. 98.7 99.0 101. 99.9 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 101. N/A N/A N/A N/A N/A N/ N/A N/A N/A N/A N/A Record Modified File Name 8100421a.wiff 8100421 a.wiff s100421a.wiir s100421a.wiff 8100421 a.wiff 8100421a.wiff 8100421 a.wiff 8100421a.wiff n s100421a.wiff n 8100421 a.witf n 8100421a.wiff s100421a.wiff n s100421a.wiff n s100421a.wrif s100421a.wiff s100421a.wiff R 8l00421a.wiff s100421a.wiff E s10042ta,wfff 8CC42a.wiff 8100421a.wiff n s100421a.wtff n s100421a.wiff n s100421a.wiff 8100421a.vwff e10O421a.wiff 8100421a.wiff T 8100421a wiff E s100421a.wiff E 8100421a.wiff E s100421a.wiff K s100421a.wiff E s100421a.wiff K 8100421a.wiff R 8100421a.wiff E 8100421a.wiff 8100421a.wiff 8100421 a.wiff 8100421 a.wiff 8100421a.wiff E 8100421a.wiff 8100421a.wiff E 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E S100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E S100421 a.wiff 8100421 a.wiff E 8100421 a.wiff R s100421a.wiff R 8100421 a.wiff E s100421a.wiff 8l00421a.wiff 8100421a,wiff E 8100421a.wiff E s100421a.wiff R 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff R 8100421a.wiff E 6100421 a.wiff R 8100421 a.wiff E 8100421 a.wiff Pa3e 8 of 14 Page 111 of 539 Stan V1660305 *3M Environmental Lab Sample Name Sample ID 537 s100421a073 538 s i 00421a074 539 s100421a075 54" 1 s100421a076 541 s100421a077 542 81004213078 543 8100421a079 544 18100421a080 545 8100421a081 546 8100421a082 547 8100421a083 548 8100421a084 549 ^8100421a085 550 8100421a086 551 8100421a087 552 8100421a88 553 8100421a089 554 8100421a090 555 s100421a091 566 8100421a092 557 8100421a093 558 8100421a094 559 8100421 a095 560 8100421a096 56 8100421a097 8100421a098 563 8100421a099 * * 8l00421a100 565 H8l00421a101 568 s100421a102 567 8l00421a103 568 8l00421a104 569 s100421a105 570 8l00421a106 571 s100421a107 572 8l00421a106 573 8l00421a109 574 8l00421a110 57S 8l00421a111 576 ^ s100421a112 577 s100421a113 578 s100421a114 579 s 1 0 0 4 2 1 a il5 580 H s100421a116 561 1s100421a117 582 s100421a118 583 s100421a119 584 8l00421a120 585 s100421a121 586 s100421a122 587 s100421a123 588 s100421a124 589 8l00421a12S 590 s100421a126 591 s100421a127 592 s100421a128 593 s100421a129 594 s100421a130 595 s100421a131 596 s100421a132 597 ^ s100421a133 596 s100421a134 599 s100421a135 600 81004213136 601 s 100421a137 602 s10O421a138 603 s10O421a139 GLP10-01-01-01-008 Dup DAL DF05 SS SS08 0 0010 Sample Duplicate GLP10-01-01-01-008 LMS DAL DF05SS SS08 0 0010 Lab Matrix Spike GLP1001-01-01-010 DAL DF05 SS SS09 0 0010 GLP1001-01-01-010 Dup DAL DF05 SS SS09 0 0010 Sample Duplicate GLP1001-01-01-010 LMS DAL DF05 SS SS09 0 0010 Lab Matrix Spike 09004-129 solvent blank EC-10041507 10 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-016 DAL DF8C SS SS02 0 0010 GLP10 0 1 0 1 0 1 0 1 6 Dup DAL DF8C SS SS02 0 0010 Sample Duplicate G L P 1 0 0 1 0 1 0 1 0 1 6 LMS DAL DF8C SS SS02 0 0010 Lab Matrix Spike GLP10-01-01-01-009 DAL DF05 SS SS09 0 0000 GLP10-010101-009 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate GLP1 0 0 1 0 1 0 1 0 0 9 LMS DAL DF05 SS SS09 0 0000 Lab Matrix Spike GLP100101-01-011 DAL DF05SS SS10 0 0000 G L P 1 0 0 1 0 1 0 1 0 1 1 Dup DAL DF05 SS SS10 0 0000 Sample Duplicate G L P 1 0 0 1 0 1 0 1 0 1 1 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike GLP10 0 1 0 1 0 1 0 1 2 DAL DF05 SS SS10 0 0010 GLP10 0 1 0 1 0 1 0 1 2 Dup DAL DFOS SS SS10 0 0010 Sample Duplicate GLP10O10 1 0 1 0 1 2 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike GLP10O10 1 0 1 0 1 3 DAL DF6C SS SS1 0 0000 GLP10 0 1 -0 1 0 1 0 1 3 Dup DAL DF8C SS SS1 0000 Sample DupCcate GLP10 0 1 0 1 0 1 0 1 3 LMS DAL DF8C SS SS01 0 0000 Lab Matrix Spike 09004-129 solvent blank C^10415O5 2.5 ng Extracted Curve Point 09004-129 solvent blank G L P 1 0 0 1 0 1 0 1 0 1 4 DAL DF6C SS SS01 0 0010 GLP10O10 1 0 1 0 1 4 Dup DAL DF8C SS SS01 0 0010 Sample DupGcate GLP10O10 1 0 1 0 1 4 LMS DAL DF8C SS SS01 0 0010 Lab Matrix Spike GLP10O10 1 0 1 0 1 5 DAL DF6C SS SS02 0 0000 GLP10O10 1 0 1 0 1 5 Dup DAL DF8C SS SS02 0 0000 Sample DupBcate GLP10O10 1 0 1 0 1 5 LMS DAL DF8C SS SS02 0 0000 Lab Matrix Spike GLP 10 O O JQ-02 DAL DF8C SS SS4 6000 GLP 10 O O O O 2 0 Dup DAL DF8C SS SS4 0000 Sample Duplicate GLP10O10 1 0 1 0 2 0 LMS DAL DF8C SS SS04 0 0000 Lab Matrix Spike GLP10O10 1 0 1 0 2 1 DAL DF8C SS SS04 0 0010 GLP10O10 1 0 1 0 2 1 Dup DAL DF8C SS SS04 0 0010 Sample DupCcate GLP10O10 1 0 1 0 2 1 LMS DAL DF8C SS SS04 0 0010 Lab Matrix Spike GLP10O10 1 0 1 0 2 2 DAL DF8C SS SSOS 0 0000 GLP10O10 1 0 1 0 2 2 Dup DAL DF8C SS SS05 0 0000 Sample DupCcate GLP10O10 1 0 1 0 2 2 LMS DAL DF8C SS SS05 0 0000 Lab Matrix Spike 09004-129 solvent blank EC-100415-06 5 ng Extracted Cun Point 09004-129 solvent blank GLP10O10 1 0 1 0 2 8 DAL DF11 SS SS06 0 0010 G L P 1 0 0 1 0 1 0 1 0 2 8 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate G L P 1 0 0 1 0 1 0 1 0 2 6 LMS DAL DF11 SS SS06 0 0010 Lab Matrix Spike G L P 1 0 0 1 0 1 0 1 0 1 7 DAL DF8C SS SS03 0 0000 G L P 1 0 0 1 0 1 0 1 0 1 7 Dup DAL DF8C SS SS03 0 0000 Sample DupCcate G L P 1 0 0 1 0 1 0 1 0 1 7 LMS DAL DF8C SS SS03 0 0000 Lab Matrix Spike G L P 1 0 0 1 0 1 0 1 0 1 8 DAL DF8C SS SS03 0 0010 G L P 1 0 0 1 0 1 0 1 0 1 8 Dup DAL DF8C SS SS03 0 0010 Sample Duplicate GLP10-01-01-01-018 LMS DAL DF8C SS SS03 0 0010 Lab Matrix Spike GLP10-1-01-01-019 DAL DF8C SS SS03 1 0010 GLP10-01-01-01-019 Dup DAL DF8C SS SS03 1 0010 Sample DupCcate GLP10-01-01-01-019 LMS DAL DF8C SS SS3 1 0010 U b Matrix Spike GLP10-01-01-01-023 DAL DF6C SS SS05 0 0010 GLP10-01-01-01-023 Dup DAL DF8C SS SS05 0 0010 Sample Duplicate GLP10-01-01-01-023 LMS DAL DF8C SS SSOS 0 0010 Lab Matrix Spike 09004-129 solvent blank EC-100415-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP1001 -01-01-024 DAL DF11 SS SS05 0 0000 GLP10-01-01-01-024 Dup DAL DF11 SS SS05 0 0000 Sample Duplicate GLP10-01-01-01-024 LMS DAL DF11 SS SS05 0 0000 Lab Matrix Spike GLP10-01-01-01-025 DAL DF11 SS SS05 0 0010 GLP1001-01-01-025 Dup DAL DF11 SS SS05 0 0010 Sample Duplicate Results Name: sl0042la.rdb Analyte Pea Name Sample Type Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte Retention Tim e (min) Analyte Peal Area (counts IS Peak Manx 18 P eak Are (counts) IS C o n c e n tra tio n (ng/m L) IS Retention Tim e (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy (%) PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS ^ pfhs PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Unknown Unknown Unknown Unknown Unknown Double Blank Qua&ty Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown ; i : K E E E N/A N/A N/A N/A N/A 0.00 9.98 0.00 N/A N/A N/A N/A N/A N/A KI/A :n /a jN /A N/A N/A N/A N/A !N/A IN/A 000 2.50 0.00 N/A N/A N/A iN/A i N/A iN/A iN /A iN/A jN/A N/A jN/A jN/A jN/A iN/A iN/A 10.00 4 .9 9 0.00 N/A N/A N/A N/A jN/A IN/A N/A jN/A N/A N/A N/A N/A N/A N/A N/A 0 .0 0 9.96 0.00 N/A N/A N/A N/A N/A 10.09 10.09 10. 10.08 10.09 10.08 10.11 10.15 10.14 10.10 10.09 10.13 10.12 10.11 O . 10.66 10.09 10.12 10.06 10.11 10.12 10.10 10.10 10.11 O . 10.06 10.10 10.12 10.11 10.10 10.10 10.12 10.14 10.13 10.09 10.14 10.07 10.10 10.11 10.12 10.10 10.04 0.12 10.17 10.12 10.12 10.11 10.11 10.10 10.10 10.13 10.11 10.12 10.11 10.10 10.11 10.10 10.11 10.09 10.06 10.09 10.24 10.10 10.10 10.10 10.10 10.10 14756 132926 29716 19515 155122 2988 1221755 264 35938 35522 155377 39800 36119 172074 244023 339380 1303241 128086 146757 1225492 113765 123150 237692 1460 307052 1552 239989 226698 1248963 110519 101140 207370 24437 42276 1SS396 48982 51132 166169 234671 186601 1371861 398 S99540 1424 408469 439753 1536686 1770814 1794194 12288722 1564626 1608787 12262936 1372562 1477142 12018401 3849394 3812522 13975014 2295 1169210 452 2289445 10567S1 1812477 439119 682648 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1S2PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 180259 ~183920 203570 201416 200940 22 188624 70 195139 185230 183755 188813 191904 185686 194877 190149 160325 T86S22 194697 181172 164455 163104 178662 58 ' 162161 10 166991 165734 177024 "164754 166389 176415 207621 193785 165132 168299 202771 182672 183004 183354 180648 0 192923 70 204672 193507 181696 166666 169356 176260 165333 185111 172414 165633 164475 174237 162494 176120 167875 34 181709 0 189185 185998 187569 188656 187750 2.98 2.96 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.98 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.98 2.98 2.98 2.96 2.98 298 298 2.98 N/A 298 N/A 2.98 2.98 2.98 2.98 2.98 10.10 10.10 10.12 10.09 0.09 10.10 10.12 9.977 10.11 10.10 10.09 10.11 10.11 (10.14 10.12 10.66 10.11 10.11 10.10 10.12 10.11 10.12 10.13 10.23 10.12 10.09 10.12 10.09 10.11 10.11 10.12 10.10 10.11 hb.09 10.11 10.13 10.12 10.13 10.12 10.10 10.10 .0 10.12 10.09 10.11 10.10 10.11 10.12 10.09 10.09 10.12 0 .1 10.11 10.10 10.11 10.12 10.11 10.12 10.10 10.26 10.10 0.000 10.09 10.09 10.12 10.10 10.11 0.120 1.11 .219 0.143 1.19 N/A 10.0 N/A 0.276 0.290 1.30 0.320 0.285 1.43 1.93 2.76 11.2 1.06 1.16 10.5 0.948 1.03 2.05 N/A 2 .6 0 N/A 1.98 1.88 10.9 0.919 0.633 1.81 0.176 0.331 1.29 0.396 0.384 1.40 1.96 1.59 11.8 N/A 4.61 N/A 3.06 3.51 13.1 14.6 14.7 111. 13.1 13.5 114. 11.5 12.4 110. 32.9 33.8 134. N/A 9.97 N/A 18.8 8.60 15.0 3 59 5.63 N/A N/A ^ N/ N/A N/A N/A O . N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 104. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 96.3 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.9 N/A N/A N/A N/A N/A N/A Record Modified R ie Name E 6100421a.wit! E 6100421a.wiff E 6100421a.wiff E s100421a.wiff R 8100421a.wiff E 8100421a.wiff 8100421a.wiff 8100421a.wiff E 8100421a.wiff K 8100421 a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421a.wiff E 8100421a.wiff E . 8100421 a.wiff E 8100421a.wiff R 8100421a.wiff R 8100421a.wiff E 8100421a.wiff E _j 8100421 a.wiff E _j8100421 a.wiff E ,8100421a.wiff E 8100421a.wiff 8100421 a.wiff 8100421 a.wiff R 8100421a.wiff E 8100421 a.wiff R 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff R 8100421 a.wiff E s100421a.wiff E s100421a.wiff E s100421a.wiff E 8100421a.wiff E s100421a.wiff E 8100421a.wiff s100421a.wiff 8100421a.wiff n 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff R 8100421 a.wiff R 8100421 a.wiff E 8100421a.wiff E s 100421 a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff R 8100421 a.wiff R 8100421 a.wiff E 8100421 a.wiff E 6l00421a.wiff R 8100421a.wiff E 8100421a.wiff 8100421a.wiff E s100421a.wiff E 8100421a.wiff E 6100421a.wiff R 8100421a.wiff E 8100421 a.wiff Printing 13^ ^ tudyn^ ^ P l0 -0 1 -&226' 21 Printing Tjftterim faeport ftlTM Page 9 of 14 Page 112 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!0042la.rdb 1 Sam ple Name Sample ID 604 s100421a140 605 s100421a141 606 s100421a142 607 s100421a143 608 s100421a144 609 e100421a145 610' s100421a146 611 s100421a147 612 s100421a148 613 s100421a149 614 s100421a150 615 s100421a151 616 s100421a152 617 s100421a153 618 s100421a154 619 s100421a155 620 8l0O421a156 621 s100421a157 622 s100421a158 623 s100421a1S9 624 si00421a160 625 s100421a161 626 s100421a162 627 8l0O421a163 628 s100421a164 629 s100421a165 630 a100421a166 631 s10O421a167 632 s100421a168 633 s100421a169 634 s100421a170 635 s100421a171 636 s100421a172 637 8100421a173 638 81004218174 639 8100421a175 640 81004213176 641 s100421a177 642 s100421a178 643 1si00421a179 644 s100421a180 645 s100421a181 646 s100421a182 647 s100421a183 648 s100421a184 649 s100421a185 650 s100421a186 651 s100421a187 652 s100421a188 653 s100421a189 654 s100421a190 655 s100421a191 656 '' s100421a192 657 " 18l00421a193 658 s100421a194 659 s100421a195 660 s100421a196 661 s100421a197 662 s100421a198 663 s100421a199 664 s100421a200 665 s100421a201 666 s100421a202 667 s100421a203 668 s100421a204 669 s100421a205 670 s100421a206 GLP10-01-01-01-025 LMS DAL DF11 SS SS0S 0 0010 Lab Matrix Spike DAL DF1 SS SS05 1 0010 ]GLP10-01-01-01-026 Dup DAL DF11 SSSS0S 1 0010 Sample Duplicate GLP10-01-01-01-026 LMS DAL DF11 SS SS05 1 0010 Lab Matrix Spike 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP10-01-01-01-027 DAL DF11 SS SS06 0 0000 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sample Duplicate GLP10-01-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike G LP1601-01-01-029 DAL DF11 SS SS07 0 0000 GLP10-01-01-01-029 Dup DALDP11 SS SS07 0 0000 Sample Duplicate G LP10-01-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike G LP10-01-01-01-030 DAL DF11 SS SS07 0 0010 GLP10-01-01-01-030 Dup DAL DF11 SS SS07 0 0010 Sample Duplicate G LP10-01-01-01-030 LMS DAL DF11 SS SS07 0 0010 Lab Matrix Spike 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-10041S-06 5 ng Extracted Curve Point 09004-129 solvent blank M B -1 00415-07 Method Blank 5g w / IS for Dilutions MB--100415-08 Method Blank 5g w / IS for Dilutions MB--100415-09 Method Blank Sg w / IS for Dilutions M B-10041S-10 Method Blank 5g w / IS for Dilutions MB--100415-11 Method Blank 5 g w /IS for Dilutions LCS-100415-07 Dil.x50 300 ng LCS in TCR-842 Dii.xSO LCS-100415-08 Dii.xSO 300 ng LCS in TCR-842 Dii.xSO LCS-100415-09 Dil.x50 300 ng LCS in TCR-842 Dii.xSO GLP10-0101-01-009 LMS Dii.xSO DAL DF05 SS SS09 0 0000 Lab Matrix Spike Dii.xSO G L P 1 0 0 1 0 1 0 1 0 1 1 Dii.xSO DAL DF05 SS SS10 0 0000 Dii.xSO G L P 1 0 0 1 0 1 0 1 0 1 1 Dup D ilxSO D AL OFOSSS SS10 0 0000 Sample Duplicate Dii.xSO G L P 1 0 0 1 0 1 0 1 0 1 1 LMS Dii.xSO DAL DFOS SS SS10 0 0000 Lab Matrix Spike Dii.xSO 09004-129 solvent blank EC-10041547 10 ng Extracted C une Point 09004-129 solvent blank GLP10-01-01-01-012 LMS Dii.xSO OAL DF05 SS SS10 0 0010 Lab Matrix Spike Dii.xSO GLP10-01-01-01-013 LMS Dii.xSO CAL DF8C SS SS01 0 0000 Lab Matrix Spike Dl.xS0 GLP10-01-01-01-014 Dii.xSO DAL DF8C SS SS01 0 0010 Dil.x50 GLP10-01-01-01-014 Dup OiLxSO DAL DF8C SS SS01 0 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-014 LMS Dii.xSO DAL DF8C SS SS01 0 0010 Lab Matrix Spike Dil.x$0 GLP10-01-01-01-015 LMS Dii.xSO DAL DF8C SS SS02 0 0000 Lab Matrix Spike Dii.xSO GLP10-01-01-01-020 LMS Dii.xSO DAL DF8C SS SS04 0 0000 Lab Matrix Spike Dil.x50 09004-129 sohent blank EC-100415-05 2.5 ng Extracted Cune Point 09004-129 sohent blank GLP10-01-01-01-021 LMS Dil.x50 DAL DF8C SS SS04 0 0010 Lab Matrix Spike Dii.xSO GLP10-01-01-01-022 LMS DiJ.x50 DAL DP6C SS SS05 0 0000 Lab Matrix Spike Dil.x50 GLP10-01-01-01-028 0 1 x 5 0 DAL D f 11 SS SS06 0 0010 Ol.xSO GLP10-01-01-01-028 Dup O l.x50 DAL DF11 SS SS06 0 0010 Sample Duplicate Dii.xSO GLP1001-01-01-028 LMS O l.x50 DAL DF11 SS SS06 0 0010 Lab Matrix Spike Dil.x50 GLP10-01-01-01-017 O l.x50 DAL DF8C SS SS03 0 0000 Ol.xSO GLP1001-01-01-017 Dup O l.x50 DAL DF8C SS SS03 0 0000 Sample Duplicate O l.x50 GLP10-01 -01-01-017 LMS Ol.xSO DAL DF8C SS SS03 0 0000 Lab Matrix Spike Ol.xSO GLP10-01-01-01-018 0 1 x 5 0 DAL DF8C SS SS03 0 0010 Ol.x50 GLP10-01 -01-01-018 Dup Ol.xSO DAL DFSC SS SS03 0 0010 Sample Duplicate Ol.xSO GLP10-01-01-01-018 LMS O l.x50 DAL DF8C SS SS03 0 0010 Lab Matrix Spike O l.x50 09004-129 solvent blank EC-100415-06 5 ng Extracted Cune Point 09004-129 solvent blank GLP10-01-01-01-019 OI.X50 DAL DF8C SS SS03 1 0010 Ol.xSO GLP10-01-01-01-019 Dup O l.x50 DAL DF8C SS SS03 1 0010 Sample Duplicate Ol.xSO GLP10-01-01-01-019 LMS Ol.xSO DAL DF8C SS SS03 1 0010 Lab Matrix Spike Ol.xSO GLP10-01-01-01-023 O l.x50 DAL DF8C SS SSOS 0 0010 Ol.xSO GLP10-01-01-01-023 Dup Ol.xSO DAL DF8C SS SS05 0 0010 Sample Duplicate O l.x50 Analyte Pea Name ----------------- 1 Sample Type Use Record A n a ly te C o n c e n tra tio n (ng/mL) Analyte Retention Tim e (min) Analyte P eal Area (counts! IS Peak Narm IS P e a k Are (counts) IS C o n cen tra tie n (ng/mL) IS Retention Tim e (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy <%> PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quafity Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quafity Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown N/A N/A N/A N/A 0.00 6. 0.00 E 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 0 .0 0 0 .0 0 0 .0 0 E 4.99 0 .0 0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0 .0 0 E 9.98 0 .0 0 N/A N/A N/A N/A N/A N/A N/A 0.00 E 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 4.99 0.00 N/A N/A N/A N/A N/A 10.10 10.08 10.11 10.11 10.11 0 .3 10.03 10.11 10.13 10.11 10.09 10.10 10.09 10.11 10.11 10.12 10.11 10.11 10.05 10.13 10.1S 10.12 10.14 10.18 10.14 10.15 10.10 10.11 10.14 10.13 10.13 10.11 10.14 10.13 10.15 10.08 10.21 10.10 10.11 10.13 10.13 10.14 10.13 10.18 10.18 10.16 10.14 10.32 10.17 10.15 10.13 10.17 10.18 10.15 10.17 10.15 10.17 10.20 10.16 10.20 10.18 10.17 10.16 10.16 10.17 10.17 10.16 1504872 478960 484660 1449672 896 1279 777 308421 937 741702 873973 1655947 11364421 119138S6 16959767 306078 295650 1418643 913 1711 743 588601 1672 4190 4657 3501 3770 4708 748327 741717 746094 6392 8249 8210 26266 933 327 70 28138 7727 7134 7561 26157 7179 6735 54 307483 207 7310 26223 10796 10458 31486 35224 37678 236486 32380 32761 243293 142 586130 213 30076 29222 229239 69995 75340 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFRs 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 182474 187594 i 186685 184378 10 22 34 182238 64 186063 190391 186878 170742 163979 167043 186563 162295 172784 34 0 48 163393 34 189277 181429 181706 184271 168652 194216 160654 165228 184028 165936 187261 161061 10 22 34 188539 93608 184470 169289 189132 189064 187624 34 180554 10 184928 183974 190902 185535 191430 189520 189482 190402 184111 189691 179400 46 162306 34 163848 191096 182629 169433 186811 2.98 2.98 2.98 2.98 N/A N/A N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2 98 2.98 2.98 2.98 N/A N/A N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.96 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 N/A 2.96 N/A 2.98 2.98 2.98 2.98 2.98 10.09 10.10 10.10 10.10 10.10 10.26 10.17 10.13 9.896 10.10 10.11 10.12 10.10 10.12 10.11 10.11 10.12 10.11 10.16 0.000 10.24 10.13 10.11 10.12 10.12 10.13 10.12 10.12 10.10 10.12 10.15 10.10 10.13 10.14 10.13 10.20 10.09 10.14 10.14 10.13 10.15 10.12 10.16 10.14 10.14 10.19 10.15 10.32 10.15 10.16 10.14 10.14 10.15 10.15 10.17 10.15 10.16 10.17 10.18 10.29 10.17 10.04 10.16 10.17 10.18 10.15 10.16 12.8 395 4.01 12.2 N/A N/A N/A 2.61 N/A 6.17 7.11 13.8 106. 116. 186. 2.53 2.50 12.7 N/A N/A N/A 4.96 N/A 0.0279 0.0333 0.0234 0.02S3 0.0322 5.96 6.36 6.23 0.0474 0.0623 0.0614 0.235 N/A 23.4 N/A 0.224 0.0554 0.0534 0.0554 0.208 0.0524 0.0491 N/A 2.63 N/A 0.0548 0.231 0.0811 0.0808 0.248 0.281 0.301 1.92 0.266 0.261 2.09 N/A 4.97 N/A 0.247 0.230 1.94 0.565 0.617 N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.5 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 234 N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.7 N/A N/A N/A N/A N/A N/A Record Modified File Name E s100421a.wiff [: 8100421a.wiff E s100421a.wiff E s100421a.wiff E 8100421a.wiff E 8100421a.wiff 8100421a.wiff 8100421a.w ill E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff 8100421a.wiff n 8100421a.wiff 8100421a.wiff 8100421a.wiff n 8100421a.wiff 8100421a.wiff 8100421a.wiff 8100421a.wiff 8100421a.wiff 8100421 a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff n 8100421a.wiff 8100421 a.wiff E 8100421 a.wiff n s 100421 a.wiff 8100421 a.wiff E 8100421a.wiff 8100421 a.wiff s100421 a.wiff 8100421 a.wiff S10O421 a.wiff E 8100421 a.wiff s100421a.wiff n S100421a.wiff n s100421a,wiff s100421a.wiff n s100421a.wiff s100421a.wiff 8100421a.wiff E 8100421a.wiff 8100421a.wiff 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E s100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff a 8100421a.wiff 8100421a.wiff 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E s10O421a.wiff E s100421a.wiff Printing Printing G W Interim R eporrO T 2" 2010 Page 10 of 14 Page 113 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Sample Name Sample ID 671 s100421a207 672 s100421a208 673 81X421 a209 674 1 8100421a210 675 8100421a211 676 s100421a212 677 8100421a213 678 8100421a214 679 8100421a215 680 8100421a216 681 8100421a217 682 8100421a218 683 8100421a219 684 8100421a220 685 8100421a221 686 8100421a222 687 8100421a223 688 6100421a224 689 8100421a225 690 8100421a226 691 61004213227 692 8100421a228 693 8100421a229 694 8100421a230 695 81004213231 696 8100421a232 697 81004213001 698 s100421a002 699 8421a3 700 81004213004 701 s100421a005 702 s100421a006 703 8l00421a007 704 rs0421a008 705 8100421a009 706 ^ 81004213010 707 80421a61 708 8100421a012 709 8100421a013 710 81004213014 711 8100421a015 712 s100421a016 713 s 1004213017 714 8100421a018 715 81004213019 716 81004213020 717 81004213021 718 81004213022 719 81004213023 720 81004218024 721 8100421a025 722 8100421a026 723 8100421a027 724 8100421a028 725 8100421a029 726 8100421a030 727 s100421a031 728 s100421a032 729 s100421a033 730 s100421a034 731 s100421a035 732 s100421a036 733 s100421a037 734 8100421a038 735 s 00421a039 736 81004213040 737 8100421a041 GLP10-01-01-01*023 LMS Dil.xSO DAL DF8C SS SS05 0 0010 Lab Matrix Spike Dil.xSO GLP10-01-01-01-024 Dil.xSO DAL DF11 SS SS05 0 0000 D il.x X GLP10-01-01-01-024 Dup Dil.xSO DAL DF11 SS SS05 0 0000 Sample Duplicate Dil.x50 GLP10-01-01-01-024 LMS Dil.xSO DAL DF11 SS SS05 0 0000 Lab Matrix Spike Dil.x50 GLP10-01-01-01-025 Dil.xSO DAL DF11 SS SS05 0 0010 Dil.xS0 GLPlboT-OT-Oi-025 Dtiip Dil.xSO DAL D F li SS SS05 0 0010 Sample Dupficate Dii.xSO G L P iC i-b i-b i-0 2 5 IM S Oii.xSO DAL DF11 SS SS05 6 0010 Lab Matrix Spike Dii.xSO 09004-129 solvent blank EC-100415-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP1001-01-01-026 Dil.xSO DAL DF11 SS SS05 1 0010 Dil.xSO G LP10-01-01-01-026 Dup Dil.x50 DAL DF11 SS SS05 1 0010 Sample Dupficate Dil.xSO G LP10-01-01-01-026 LMS Dil.xSO DAL DF11 SS SS05 1 0010 Lab Matrix Spike Oii.xSO GLP10-01-01-01-027 Dil.xSO DAL DF11 SS SS06 0 0000 Dil.x50 GLP10-01-01-01-027 Dup D il.x X DAL DF11 SS SS06 0 0000 Sample Duplicate Dil.xSO GLP1CL01-01-01-027 LMS Dil.x50 DAL DF11 SS SS06 0 0000 Lab Matrix Spike Dii.xSO GLP10-01-01-01-029 Dil.xSO DAL DF11 SS SS07 0 0000 Dil.x50 G LP10-01-01-01-029 Dup Dil.xSO DAL DF11 SS SS07 0 0000 Sample Duplicate Di!.x50 GLP10-01-01-01-029 LMS Dil.xSO DALDF11 SS SS07 0 0000 Lab Matrix Spike Dil.xSO GLP10-01-01-01-030 Dil.xSO DAL DF11 SS SS07 0 0010 Dil.x50 G L P 1 0 0 1 0 1 0 1 0 3 0 Dup Dil.x50 DAL DF11 SS SS07 0 0010 Sample Duplicate Dii.xSO GLP100101-01-030 LMS Dil.xSO DAL DF11 SS SS07 0 0010 Lab Matrix Spike Dil.xSO 09004-129 solvent blank EC-10041S-05 2.5 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-10041S-09 SO ng Warm up standard EC-100415-09 50 ng Warm up standard EC-100415-09 SO ng Warm up standard 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank EC-100415-01 0.2 ng Extracted Curve Point EC-100415-02 O.S ng Extracted Curve Point EC-100415-03 0.75 ng Extracted Curve Point EC-100415-04 1 ng Extracted Curve Point EC-100415-05 2.5 ng Extracted Curve Point EC-100415-06 S ng Extracted Curve Point EC-100415-07 10 ng Extracted Curve P a n t EC-100415-08 25 ng Extracted Curve Point EC-100415-09 50 ng Extracted Curve Point EC-10041S-10 100 ng Extracted Curve Point EC-100415-11 200 ng Extracted Curve Point EC-10041S-12 500 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank 09004-129 solvent blank MB--100415-01 Method Blank 1 w/o IS MB--100415-02 Method Blank 2 w/o IS MB--100415-03 Method Blank 3 w/o IS MB--100415-04 Method Blank 4 w / IS MB--100415-05 Method Blank 5 w / IS MB--100415-06 Method Blank 6 w / IS LCS-10041S-01 3 ng LCS in TCR-S42 LCS-100415-02 3 ng LCS in TCR-642 LCS-100415-03 3 ng LCS in TCR-842 LCS-100415-04 30 ng LCS in TCR-842 LCS-100415-05 30 ng LCS in TCR-842 LCS-100415-06 30 ng LCS in TCR-842 LCS-100415-07 300 ng LCS in TCR-842 LCS-100415-06 300 r ^ LCS in TCR-842 LCS-10041509 300 ng LCS in TCR-842 Analyte Peak ,, ._ Marne S , m 1* PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Unknown . Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte R e te n tio n Tim e (min) Analyte Peal Area (counts. IS Peak Narm IS Peak An (counts) IS C o n c e n tra tio n (n g /m L ) IS Calculated Retention Concentration Tim e (min) (ng/m L) Accuracy <*) Record Modified R ie Name jN /A N/A jN /A jN /A jN /A N/A N/A 0.00 E 9 98 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0 .0 0 E 2.50 0.00 0 .0 0 0 .0 0 10.00 0 .0 0 0 .0 0 0 .0 0 0 .0 0 0 .0 0 0 .0 0 0 .0 0 0 .0 0 [ 0.200 E 0.500 E 0.750 E 1.00 2.50 E 5.00 E 10.0 E 25.0 E 50.0 E 100. E 200. E 500. 0 .0 0 0 .0 0 000 0 .0 0 0 .0 0 0 .0 0 0 .0 0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 10.15 272226 10.14 46119 10.13 25363 10.14 42128 10.13 13544 10.14 15676 10.16 31S3S 10.16 162 10.14 1169049 10.11 165 10.13 13453 10.10 12784 10.05 29493 10.08 20379 10.09 20931 10.07 31992 10.07 222335 10.09 243073 10.07 366893 10.12 8988 10.05 7830 10.06 27572 10.06 284 10.09 306439 10.06 175 10.11 157 12.6S 39014 12.71 929 12.86 2427053 12.82 2441782 12.62 2438214 12.66 1464 12.63 970 12.76 520 12.78 858 12.75 207 12.83 14063 12.78 28972 12.77 39750 12.77 49843 12.76 123242 12.76 251650 12.78 488344 12.77 1236151 12.76 2393644 12.76 4S62103 12.75 6351946 12.74 16468251 12.75 3356 12.85 775 1 2 :7 7 ............ 954 12.75 226 12.77 5074 12.63 4463 12.79 5715 12.72 7870 12.78 120334 12.76 4991 12.77 154089 12.77 152006 12.73 159732 12.75 1525702 12.75 1516356 12.74 1495593 12.75 14778754 12.75 14663233 12.76 14706350 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1602 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS 1802 PFHS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M6PFOS M6PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 180028 165323 183362 183421 164261 182276 186303 0 163728 34 178217 190694 189317 183223 184742 182533 184493 185461 185794 185146 190466 186715 10 164575 0 34 65 34 62123 58233 63089 58 56 58 80 22 62466 60528 56756 62157 57773 606SS 61621 62470 61076 59549 51872 42543 22 34 0 34 103 119 65 61524 62137 60715 63416 62777 62225 63573 63546 61825 57450 59556 57754 2.98 2.98 2.98 2.98 2.98 2.96 2.96 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.96 2.96 2.96 2.98 2.98 2.98 2.96 2.98 N/A 2.98 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Too 3.00 3.00 3.00 . 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A N/A N/A ' n/a N/A N/A N/A 3.00 3.00 Too 3.00 3.00 3.00 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 10.15 10.16 10.16 10.16 10.15 10.15 10.14 O.OX 10.15 10.20 10.12 1 0 .X 1 0 .X 10.11 1 0 .X 1 0 .X 10.10 1 0 .X 10.07 1 0 .X 1 0 .X 10.07 10.16 10.07 O .O X 9.896 12.63 12.97 12.84 12.81 12.81 12.64 12.71 12.94 1 3 .X 1 2 .X 12.79 12.76 12.77 12.75 12.76 12.77 12.76 12.78 12.76 12.74 12.75 12.72 13.02 12.X O.OX 12.61 12.74 12.77 12.79 12.73 12.74 12.72 12.73 12.74 12.72 12.75 12.75 12.77 12.73 12.74 12.75 2.33 0.379 0 .2 X 0.349 0.107 0.127 0.255 N/A 9.66 N/A 0.110 0 .X 7 3 0.235 0 .1 X 0 .1 X 0.265 1 .X 2.02 3 .X 0 0687 0 .X 7 2 0.220 N/A 2 .X N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.193 0.513 0.792 0.921 2 .X 5.15 9 .X 24.9 49.5 97.0 205. 499. N/A N/A N/A N/A N/A N/A N/A O .X X 2.35 0.0122 2.96 2 .X 3.15 30.2 30.1 30.5 329. 319. 326. N/A N/A N/A N/A N/A N/A N/A N/A X .8 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A jN /A X3 103. 106. 92.1 104. 103. X .8 X .6 X .9 97.0 102. X .7 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/ N/A N/A N/A N/A N/A E E E E E E E n n E E E E E E E E E n n n E n E E E n E E n E E _ E n E E E E E E E E E E E E E E E s 100421a.witT s 100421 a.wiff 8100421a.wiff 8100421 a.wiff 8100421 a.wiff s1 00 4 2 1 a .w iff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wi1f 8100421 a.wiff S100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff s10O421a.wiff 8100421a.wiff 8l00421a.wiff 8100421a.wiff 6l00421a.wiff 8l00421a.wiff 8l00421a.wiff 8100421a.wiff 8100421a.wiff 8100421a.wiff 8100421a.wiff 81 00421a. w iff 81 00421a. w iff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff s 100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff 8100421 a.wiff s1 00 4 2 1 a .w iff 8100421a.wiff s1 00 4 2 1 a .w iff 8100421a.wiff 8100421a.wiff 8l00421a.wiff 8100421a.wiff 8100421a.wiff 610 04 21 a. w iff 610 04 21 a. w iff 810 04 21 a. w iff 81 00421a.w iff 8100421 a.wiff 8100421 a.wiff 81 00421a.w iff 8100421 a.wiff 8100421 a.wiff e100421a.wiff 8100421a.wiff s1 0 0 4 2 1 a .w iff 8100421a.wiff Printing D3MStUBV"G L P l0 H 0 f-0 2 6 ' 2010 Printing T^enm ReftoLPoO- Pa9e 11 of 14 Page 114 of 539 Stan V1660305 *3M Environmental Lab Sam ple Name " Sample ID 738 s100421a042 739 s100421a043 740 100421a044 741 s 1004213045 742 8100421a046 743 8100421a047 744 8100421a048 745 81004213049 746 81004213050 747 81004213051 748 842130S2 749 81004213053 750 8100421a054 751 s100421a055 752 81004213056 753 S421357 754 81004213058 755 81004213059 756 s100421a060 757 81004213061 758 8100421a062 759 81004213063 760 81004213064 761 81004213065 762 81004213066 763 81004213067 764 8100421a068 765 rs 1004218069 766 81004213070 767 81004213071 768 81004213072 769 81004213073 770 s100421a074 771 8100421a075 772 8100421a076 773 $100421a077 774 8100421a078 775 8100421a079 776 8100421a080 777 8100421a081 778 s100421a082 779 8100421a083 780 8l00421a084 781 hs100421a085 782 8100421a086 783 8100421a087 784 8100421a088 785 8100421a069 786 8100421a090 787 8100421a091 788 8100421a092 789 81004213093 790 8100421a094 791 8100421a095 792 8100421a096 793 8100421a097 794 s100421a096 795 8l00421a099 796 s100421a100 797 s100421a101 798 8l00421a102 799 s100421a103 800 s100421a104 801 s100421a105 802 s100421a106 803 s100421a107 804 s100421a108 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP1001-01-01-033 Soil Trip Blank 1 GLP1001-01-01-033 Dup Soil Trip Blank 1 Sample Duplicate GLP10-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike GLP10-01-01-01-034 Soil Trip Blank 3 GLP1001-01-01-034 Dup Soil Trip Blank 3 Sample Dupficate GLP10-01-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike GLP1001-01-01-001 DAL DF05 SS SS06 0 0000 GLP1001-01-01-001 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate GLP1001-01-01-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike GLP1001-01-01-002 DAL DF05 SS SS06 0 0010 GLP10-01-01-01-002 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate GLP1 O O i^o i-01-002 LMS DAL DP05 SS SS06 0 0010 Lab Matrix Spike GLP 1b-01 4J1-0 ll0 0 3 DAL DF05 SS SS06 1 0010 G LP IO O i-01-01-003 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate GLP10-01-01-01-003 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 09004-129 solvent blank EC-100415-06 5 ng Extracted Cun Point 09004-129 solvent blank GLP10-01-01-01-004 DAL DF05 SS SS07 0 0000 GLP10-01-01-01-004 Dup DAL DF05 SS SS07 0 0000 Sample Duplicate GLP10-01-01-01-004 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike GLP10-01-01-01-005 DAL DF05 SS SS07 0 0010 GLP10-01-01-01-005 Dup DAL DF05 SS SS07 0 0010 Sample Duplicate GLP10-01-01-01-005 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike GLP1001-01-01-007 DAL DF05 SS SS08 0 0000 GLP1001 -01-01-007 Dup DAL DP05 SS SS08 0 0000 Sample Duplicate GLP10-01-01-01-007 LMS DAL DFOS SS SSOS 0 0000 Lab Matrix Spike GLP1001-01-01-008 DAL DF05 SS SS08 0 0010 GLP 1001-01-01-008 Dup DAL DFOS SS SS08 0 0010 Sample Duplicate GLP1001-01-01-008 LMS DAL DFOS SS SS08 0 0010 Lab Matrix Spike G LP1001-01-01-010 DAL DF05 SS SS09 0 0010 GLP1001 -01-01-010 Dup DAL DF05 SS SS09 0 0010 Sample Duplicate GLP10-01-01-01-010 LMS DAL DF05 SS SS09 0 0010 Lab Matrix Spike 09004-129 solvent blank EC-10041507 10 ng Extracted Cun Point 09004-129 solvent blank GLP1001-01-01-016 DAL OFSC SS SS02 0 0010 GLP10-01-01-01-016 Dup DAL DF8C SS SS02 0 0010 Sample Duplicate GLj>10O1 ^ 1 ^ 1 -0 1 6 LMS DAL DF8C SS SS02 0 0010 Lab Matrix Spike GLP 16-01-01-01-009 DAL DF05 SS SS09 6 0000 GLP 10-01-01-01-009 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate GLP10-01 -01-01-009 LMS DAL DFOS SS SS09 0 0000 Lab Matrix Spike GLP10O1 -01-01-011 DAL DFOS SS SS10 0 0000 GLP 1 M T 0 T 0 1 * 1 "i b lip DAL DF05 SS SS10 6 6666 Sample Duplicate GLP1001-01-01-011 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike GLP1001-01-01-012 DAL DFOS SS SS10 0 0010 G L P 1 0 0 1 0 1 0 1 0 1 2 Dup DAL DF05 SS SS10 0 0010 Sample Duplicate G L P 1 0 0 1 0 1 0 1 0 1 2 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike GLP10O1O10 1 0 1 3 DAL DF8C SS SS01 0 0000 G L P 1 0 0 1 0 1 0 1 0 1 3 Dup DAL DF8C SS SS01 0 0000 Sample Duplicate GLP10O1O10 1 0 1 3 LMS DAL DF8C SS SS01 0 0000 Lab Matrix Spike 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Cun Point 09004-129 solvent blank G L P 1 0 0 1 0 1 0 1 0 1 4 DAL DF8C SS SS01 0 0010 G L P 1 0 0 1 0 1 0 1 0 1 4 Dup DAL DF8C SS SS01 0 0010 Sample Duplicate G L P 1 0 0 1 0 1 0 1 0 1 4 LMS DAL DF6C SS SS01 0 0010 Lab Matrix Spike G L P 1 0 0 1 0 1 0 1 0 1 5 DAL DF8C SS SSQ2 0 0000 GLP10-01-01 -01-015 Dup DAL DF8C SS SS02 0 0000 Sample Duplicate GLP1001-01-01-01S LMS DAL DF8C SS SS02 0 0000 Lab Matrix Spike GLP10-01-01-01-020 DAL DF8C SS SS04 0 0000 G LP10-01-01-01-020 Dup DAL DF8C SS SS04 0 0000 Sample DupEcate G LP10-01-01-01-020 LMS DAL DF8C SS SS04 0 0000 Lab Matrix Spike GLP10-01-01-01-021 DAL DF6C SS SS04 0 0010 Printing pn n t i n g T|nferim2R e p 6 rt% ^ ' 2010 Results Name: sl00421a.rdb Analyte Pea Name Sam ple Type PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS' PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Use Record A n a ly te Concentration (n g /m L ) Analyte R e te n tio n Tim e (min) Analyte Peal Area (counts! IS Peak Namr IS P eak Area (counts) IS C o n c e n tra tio n (n g /m L ) IS R e te n tio n Time (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy (%) 0.00 E 2.50 0.00 N/A N/A N/A N/A N/A N/A ;N/A ;N/A N /A iN/A iN/A N/A |n /a IN/A jhl/A 10.00 E 5.00 0.00 j N/A \U /A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 10.0 0.00 N/A N/A N/A I n/a I N/A i N/A IN/A IN/A N/A IN/A IN/A IN/A IN/A N/A N/A 0 .0 0 E 2.50 0 .0 0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A ' 12.73 12.78 12.73 12.77 12.77 12.76 12.77 12.77 12.78 12.78 12.79 12.77 12.77 12.79 12.78 12.78 12.78 12.78 12.78 12.78 12.65 12.78 12.78 12.77 12.78 12.79 12.78 12.79 12.60 12.79 12.79 12.79 12.81 12.80 12.60 12.60 12.62 12.83 12.88 1 2 .8 2 12.63 12.62 12.62 12.81 12.62 12.62 13.08 12.78 12.79 12.82 12.81 12.82 12.81 12.80 12.80 12.60 12.82 12.82 12.81 12.81 12.81 12.80 12.81 12.62 12.80 12.81 12.62 3502 126347 1271 4733 6724 52378 5869 5204 50405 2753977 2562688 7011557 3700261 3426294 6096342 2923135 3105957 6398796 1833 250781 142 2316837 2137447 6597643 264026 294521 4821343 5429694 6212362 10603964 3425267 3684986 6705136 6865431 3924733 10694188 2288 478724 217 3677739 3459004 7709562 17216236 17137425 38927020 35467845 40154466 44453002 9106377 8464014 32237427 8842207 10003069 33475538 9034 12S944 2139 21853195 21170082 41061321 7984267 r82S1349 33000537 11339944 111994549 35261160 14629410 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFS M8PFS M6PFOS M8PFOS M8PFS ^M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 130 60767 22 61371 59944 60574 62111 63019 59134 60203 56820 56165 57207 64003 51964 60732 62407 55109 34 61248 44 56242 59758 55708 61337 61107 56627 57694 60467 50094 55205 55578 52204 61763 60441 60370 46 58013 31 56548 60630 53004 49988 50817 37567 39244 35865 30228 53365 54083 34040 50687 53212 36313 46 59800 34 43490 48517 35705 55483 54452 35452 55922 54056 35023 55253 N/A 12.76 3.00 12.76 N/A 12.61 3.00 12.77 3.00 12.7S 3.00 12.75 3.00 12.75 3.00 12.76 3 .0 0 12.78 3.00 12.75 3.00 1276 3.00 12.74 3.00 12.76 3.00 1 2 .X 3.00 12.77 3 0 0 12.76 3.00 12.74 3.00 12.76 N/A 12.94 3.00 12.77 N/A 12.71 3.00 12.76 3.00 12.77 3.00 12.77 3.00 12.78 3.00 12.79 3.00 12.76 3.00 12.77 3.00 1 2 .X 3.00 12.78 3.00 12.78 3.00 12.77 3.00 1 2 .X 3 .0 0 12.77 3 .0 0 12.79 3.00 12.81 N/A 12.76 3.00 1 2 .X N/A 12.95 3.00 1 2 .X 3.00 12.79 3 0 0 12.81 ............. ... 12.79 3.00 12.83 3.00 1 2 .X 3 X 12.79 3 . X 13.10 3 . X 12.78 3 . X 12.79 3 . X 12.79 3 .X 12.X 3 . X 12.62 3 . X 12.78 3 .X 12.X N/A 12.84 3 . X 12.61 N/A 12.64 3 .X 12.X 3 . X 12.82 3 .X 12.X 3 . X 12.82 3 . X 12.82 3 .X 12.X 3 . X 12.78 3 . X 12.79 3 . X 12.78 3 .X 12.X N/A 2 .X N/A 0.00579 0 .0 5 X 1 .X 0.0277 0.0127 0.984 57.8 55.0 156. 81.6 67.7 196. X .6 62.9 147. N/A 5 .X N/A 52.0 45.1 150. 5.34 5.99 108. 119. 130. 270. 78.5 X .9 163. 141. 82.1 226. N/A 10.3 N/A 79.4 72.1 185. 443. 433. 13X. 12X. 1510. 2020. 217. 199. 12X. 222. 240. 12X. N/A 2.57 N/A 652. 564. 15X. 1X. 193. 1240. 2S9. 2X. 13X. 339. N/A 101. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 103. N/A N/ N/A N/A N/A rN/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Record Modified File Name E 8100421a.wiff 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421a.wiff E s1421a.wiff E 8100421 a.wilt E 8100421 a.wiff E 8100421a.wiff 8100421a.wiff 8100421 a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421a.wiff E e100421a.wiff E s100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421a.wiff E s100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff n 8100421 a.wiff 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E s1421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 81X421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E &100421a.wiff E 8100421 a.wiff E 8l00421a.wiff 8100421a.wiff 8100421a,wiff E s10O421a.wiff E 8100421a,wiff E s100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421a.wiff E 8100421 a.wiff Page 12 of 14 ' Page 115 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb ............................. .....-- ....-- ...................... Sample Name ..................... ......... ............. -- ........... .....-- ..... ....... Sample ID Analyte Peak _ , _ K m . i Sam pl" ^ 805 s100421a109 GLP10-01-01-01-021 Dup CAL DF8C SS SS04 0 0010 Sample Dupficate PFOS 606 842aT'''- '''' GLP10-01-01-01-021LMS DAL DF8C SS SS04 0 0010 Lab Matrix Spike" .... P F O S - ..... 807 s l 0 4 2 1 a l...... GLP10 ^ l ^ l ^ 1 C&~L DF8C SS SS 05 0 0000.................. ............................. ........ ............... PFOS 608 s100421a112 GLP10 -0 1 -0 1 -0 1 -0 2 2 Dup DAL DF8C SS SS05 0 0000 Sample Duplicate PFOS 609 s100421a113 GLP10-01-01-01-022 LMS DAL DF8C SS SS05 0 0000 Lab Matrix Spike PFOS 810 s1421a114 09004-129 solvent blank PFOS 611 a100421a115 EC-100415-06 5 ng Extracted Curve Point PFOS 812 s100421a116 09004-129 solvent blank PFOS 813 s100421a117 GLP10-01-01-01-028 DAL DF11 SS SS06 0 0010 PFOS 814 s100421a116 GLP10-01-01-01-026 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate PFOS 815 s1421a19 GLP16-014>1-01-028 LMS DAL DF 11 SS SS06 0 0010 Lab Matrix Spike PFOS 816 s100421a120 GLP10-01-01-01-017 DAL DF8C SS SS03 0 0000 PFOS 817 s100421a121 GLP10-01-01-01-017 Dup DAL DF8C SS SS03 0 0000 Sample Dupficate PFOS 818 s100421a122 GLP10-01-01-01-017 LMS DAL DF6C SS SS03 0 0000 Lab Matrix Spike PFOS 819 s100421a123 GLP10-01-01 -01-018 DAL DF8C SS SS03 0 0010 PFOS 820 s100421a124 GLP1OQ1 -01-01 -016 Dup DAL DF8C SS SS03 0 0010 Sample Dupficate PFOS 821 s100421a125 GLP10-01-01-01 -016 LMS DAL DF6C SS SS03 0 0010 Lab Matrix Spike PFOS 822 s10O421a126 GLP10-01-01-01-019 DAL DF8C SS SS03 1 0010 PFOS 823 s10O421a127 GLP10-01-01-01-019 Dup DAL DF8C SS SS03 1 0010 Sample Duplicate PFOS 824 s100421a126 GLP10-01-01 -01-019 LMS DAL DF6C SS SS03 1 0010 Lab Matrix Spike PFOS 825 s100421a129 GLP1001-01-01-023 DAL DF8C SS SS05 0 0010 PFOS 826 s100421a130 GLR10-01-01-01-023 Dup DAL DF8C SS SS05 0 0010 Sample Dupficate PFOS 827 s100421a131 GLP10-01-01-01-023 LMS DAL DF8C SS SS05 0 0010 Lab Matrix Spike PFOS 828 s100421a132 09004-129 solvent blank PFOS 829 s10O421a133 EC-100415-07 10 ng Extracted Curve Point PFOS 830 8l00421a134 09004-129 solvent blank PFOS 831 s100421a135 GLP10-01-01-01-024 DAL DF11 SS SS05 0 0000 PFOS 832 s10O421a136 fc L P I 0 ^ 1 0 1 0 1 -0 2 4 Dup DAL DF11 SS SS05 6 0000 Sample Duplicate PFOS 833 s10O421a137 GLP10-01-01-01-024 LMS DALDF11 SS SS05 0 0000 Lab Matrix Spike PFOS 834 s100421a138 GLP10-01-01-01-025 DAL DF11 SS SS05 0 0010 PFOS 835 s10O421a139 GLP10-01-01-01-025 Dup DAL DF11 SS SS05 0 0010 Sample Duplicate PFOS 836 s100421a140 GLP10-01-01-01-025 LMS DAL DF11 SS SS05 0 0010 Lab Matrix Spike PFOS 837 8l0O421a141 GLP10-01-01-01-026 DAL DP11 SS SSOS 1 0010 PFOS 838 s10O421a142 GLP10-01-01-01-026 Dup DALDF11 SS SSOS 1 0010 Sample Duplicate PFOS 839 s10O421a143 GLP10-01-01-01-026 LMS DAL DF11 SS SSOS 1 0010 Lab Matrix Spike PFOS 840 s 100421a144 09004-129 solvent blank PFOS 841 s10O421a145 09004-129 solvent blank PFOS 842 s100421a146 09004-129 solvent blank PFOS 843 s10O421a147 EC-100415-05 2.5 ng Extracted Curve Point PFOS 644 s100421a148 09004-129 solvent blank PFOS 845 s100421a149 GLP1001-01-01-027 DAL DP11 SS SS06 0 0000 PFOS 846 s100421a150 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sample Duplicate PFOS 847 8100421a151 GLP10-01-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike PFOS 848 8100421a152 GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 PFOS 849 s100421a1S3 GLP10-01-01-01-029 Dup DALDF11 SS SS07 0 0000 Sample Duplicate PFOS 850 8l00421a154 GLP10-01-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike PFOS 651 8l00421a15S GLP10-01-01-01-030 DAL DF11 SS SS07 0 0010 PFOS 852 S10421a1S6 GLP10-01-01-01-030 Dup DAL D M 1 SS SS07 0 0010 Sample Duplicate PFOS 653 s100421a157 GLP1001-01-01-030 LMS DAL D M 1 SS SS07 0 0010 Lab Matrix Spike PFOS 654 s100421a1S8 09004-129 solvent blank PFOS 855 81004218159 09004-129 solvent blank PFOS 856 s100421a160 09004-129 solvent blank PFOS 857 s100421a161 EC-100415-06 5 ng Extracted Curve Point PFOS 858 s100421a162 09004-129 solvent blank PFOS 659 s100421a163 MB--100415-07 Method Blank 5g w / IS for Dilutions PFOS 860 s100421a164 M B-10041S-08 Method Blank 5g w1 1S for Dilutions PFOS 661 s100421a165 MB-100415-09 Method Blank 5g w / IS for Dilutions PFOS 662 s100421a166 MB--100415-10 Method Blank Sg w/ IS for Dilutions PFOS 663 81004213167 MB--100415-11 Method Blank 5g w / IS for Dilutions PFOS 664 s100421a168 LCS-100415-07 Dil.xSO 300 ng LCS in TCR-842 Dil.xSO PFOS 665 s100421a169 LCS-100415-08 Dil.xSO 300 ng LCS in TCR-642 Dil.xSO PFOS 866 s100421a170 LCS-100415-09 Dil.xSO 300 ng LCS in TCP-842 Dil.xSO PFOS 867 s1X421a171 GLP10-01-01-01-009 LMS Dil.xSO DAL DF05 SS SS09 0 0000 Lab Matrix Spike Di!.x50 PFOS 868 s100421a172 GLP10-01-01-01-011 Dil.xSO DAL DF05 SS SS10 0 0000 Dil.xSO PFOS 869 8100421a173 GLP 1 0 0 1 O l -01-011 Dup Dil.xSO DAL DF05 SS SS10 0 0000 Sample Duplicate Dti.xSO PFOS 870 s100421a174 GLP10-01-01-01-011 LMS Dil.xSO DAL DF05 SS SS10 0 0000 Lab Matrix Spike Dil.x50 PFOS 871 s100421a175 09004-129 solvent blank PFOS Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Double Blank Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Use Record A n a ly te C o n c e n tra tio n (n g /m L ) ..................... ----------------------------- A n a ly te R e te n tio n Time (min) Analyte P eal Area (counts; 13 _, Peak .. r|S Peak Arai Name (colmK| IS Concentration (n g /m L ) IS Retention Tim e (min) Calculated C o n c e n tra tio n (ng/m L) Accuracy (%> Record Modified File Name N/A 12.82 15972214 M 8PFOS 55616 3 .X N/A ~ ........... 12.81 39949154" " M8PFS 3 4 4 1 0 ....... 3.00 N /A ..... ................ 12781............. 13785576....... M8P FO S "...... 49577............ 3 . X N/A 12.81 12857720 M8PFOS 52762 3 .X N/A 12.80 36523070 M 8PFOS 33577 3 .X 0.00 12.81 9666 M8PFOS 0 N/A E 5.00 0.00 12.81 12.65 245447 1361 M8PFOS M8PFOS 59118 0 3 .X N/A N/A 12.61 33939942 M8PFOS 38066 3 .X N/A 12.80 37303621 M8PFOS 35947 3 .X N/A 12.60 54414979 M8PFOS 26515 3 .X N/A 12.80 40685616 M8PFOS 37521 3 .X N/A 12.79 44151325 M8PFOS 35618 3 .X N/A 12.78 119774509 M8PFOS 15490 3 .X N/A 12.82 56819172 M8PFOS 30627 3 .X N/A 12.80 60105743 M8PFOS 30016 3 .X jN /A 12.79 12S428339 M8PFOS 15179 3 .X N/A 12.80 53744339 M6PFOS 31285 3 .X N/A 12.81 55143521 M8PFOS 32729 3 .X N/A 12.79 121245090 MSPFOS 15001 300 N/A 12.80 28515989 M8PFOS 42325 3 .X N/A 12.82 26446522 M8PFOS 41345 3 .X IN/A 12.79 113025765 M6PFOS 14963 3 .X 0.00 12.60 73023 M8PFOS 0 N/A E 10.0 0.00 12.81 12.81 474128 10388 M8PFOS M8PFOS 57817 0 3 .X N/A N/A 12.79 63841315 MSPFOS 29143 3 .X :N/A 12.80 40307779 M8PFOS 35S36 3 .X N/A 12.78 118440730 MSPFOS 14280 300 N/A 12.79 36692965 M8PFOS 37486 3 .X IN/A 12.80 57948330 MSPFOS 30058 3 .X N/A 12.77 113180476 MSPFOS 14691 3 .X N/A 12.79 47055891 M8PFOS 32568 3 .X N/A 12.80 50321252 MSPFOS 29774 3 .X iN/A 12.78 112924781 MSPFOS 14311 3 .X 0.00 12.79 66062 M 8PFOS 22 N/A .0 12.79 19363 MSPFOS 58 N/A 0.00 12.79 11093 MSPFOS 22 N/A E 2.50 0.00 12.80 12.85 131304 4486 M 8PFOS M8PFOS 60954 45 3 .X N/A N/A 12.79 45402813 M 8PFOS 34277 3 .X N/A 12.80 52713492 MSPFOS 31676 3 .X N/A 12.77 111892123 M 8PFOS 15683 3 .X N/A 12.61 241242275 M 8PFOS 6534 3 .X N/A 12.60 252663270 MSPFOS 3625 3 .X N/A 12.62 253352533 M 8PFOS 2698 3 .X N/A 12.80 93145185 MSPFOS 18089 3 .X iN/A 12.60 97693209 MSPFOS 18638 3.00 iN/A 12.60 137741875 MSPFOS 13333 3 .X 0.00 12.61 144601 M8PFOS 46 N/A 0.00 12.64 48554 MSPFOS 34 N/A 0.00 12.82 24919 M8PFOS 34 N/A E 5.00 0.00 12.65 12.63 251678 12S05 MSPFOS M8PFOS 61775 22 3 .X N/A N/A 12 .6 6 12819 M 8 PFOS 66119 3 .X N/A 12.84 12234 M 8 PFOS 60512 3 .X N/A 12.86 10392 MSPFOS 60530 3 .X N/A 12.83 9633 MSPFOS 56565 3 .X N/A 12.64 7594 M 8 PFOS 62470 3 .X N/A 12 .6 6 281090 M 8 PFOS 59891 3 .X N/A 12.84 294909 M8PFOS 64349 3 .X N/A 12.83 292071 M 8PFOS 61614 3 .X N/A 12.84 1238621 M 8PFOS 64323 3 .X N/A 12.88 1046795 M 8PFOS 61039 3 .X N/A 12.84 1204700 M 8PFOS 60246 3 .X N/A 0.00 12 .6 6 12.87 1600635 2640 M 8PFOS MSPFOS 59894 46 3 .X N/A .. 12.X 3X. 1279 1570.'.... ... ... 1Z81.......... 356. 12.78 311. 12.75 14X. o.ox N/A 12.X 5.15 O.OX N/A 12.X 11X. 12.X 13X. 12.79 2950. 12.X 14X. 12.78 16X. 12.75 No Intercept 12.79 2710. 12.X 2870. 12.78 No Intercept 12.X 2410. 12.X 2350. 12.77 No Intercept 12.76 882. 12.79 836. 12.82 No Intercept O.OX N/A 12.X 10.3 O.OX N/A 12.79 31X . 12.78 15X. 12.77 No Intercept 12.79 1310. 12.77 2740. 12.72 No Intercept 12.79 19X. 12.X 23X. 12.75 No Intercept 12.81 N/A 12.69 N/A 12.X N/A 12.79 2.63 12.65 N/A 1 2 .X 1810. 1 2 .X 2320. 12.79 No Intercept 1 2 .X No Intercept 12.79 No intercept 12.84 No Intercept 1 2 .X No intercept 12.63 No Intercept 12.79 No Intercept 12.82 N/A 12.95 N/A 12.77 N/A 12.83 5 .X 12.92 N/A 12.84 0.153 12.64 0.164 1 2 .X 0.125 12.84 0.123 12.63 0 .X 1 9 12.84 5.83 12.84 5.69 12.82 5.89 1 2 .X 24.2 12.X 21.6 12.82 252 12.84 33.7 12.77 N/A N/A N/A N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A hN/A N/A N/A N/A N/A 103. N/A N/A N/A N/A ft/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 10 1. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A IN/ N/A H ill jI E 8100421 a.wiff R 8100421 a.wiff R "042.wiff ....... R 8100421 a.wiff E 8100421a.wiff 8100421 a.wiff 8100421a.wiff E s100421a.wiff R 8100421a.wiff E s10O421a.wiff E 8100421a wiff E 8100421 a.wiff E s100421a.wiff R 8100421a.will E 8100421a.will E s100421a.wiff R 8100421a.wiff E 8100421a.wiff E 8100421a.wiff I-- s10O421a.wiff E 8100421a.wiff E 8100421a.wiff R s100421a.wiff 8100421a.wiff 8100421a.wiff R 8100421a.wiff E 8100421a.wiff R 8100421a.wiff R siX421a.w iff E 8100421a.wiff E 8100421a.wiff R 8100421a.wiff E s10O421a.wiff E 8100421a.wiff E 8l00421a.wiff E s100421a.wiff 8100421 a.wiff s 100421a.wiff s100421a.wiff 8l00421a.wiff E 8100421 a.wiff E s 100421a.wiff E 8100421a.wiff R 8100421a.wiff R 8100421a.wiff E 8100421a.wiff R 8100421a wiff K 8100421 a.wiff E 8100421a.wiff E s100421a.wiff 8100421a.wiff s100421a.wiff 8100421a.wiff n 8100421a.wiff R 8100421a.wiff 8100421a.wiff n 8100421a.wiff s100421a.wiff 8l00421a.wiff R s100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff E 8100421a.wiff r 8100421 a.wiff R 8100421a.wiff 8100421 a.wiff Printing D3MStUay?G&P10iQl-0226- 2010 Printing TlffierimRepOit^ f M Page 13 of 14 Page 116 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Sampla Name Sam ple ID B72~ s100421a176 873 s100421a177 874 s100421a178 875 islb421a179 876 s100421a180 877 s100421a181 878 !s100421a182 879 s100421a183 880 s100421a184 881 s100421a185 882 a100421a166 883 s100421a187 884 b 100421a188 885 s100421a1X 886 s100421a190 887 s100421a191 888 s100421a192 889 s100421a193 890 s100421a194 891 s100421a19S 692 s100421a196 893 a100421a197 894 s100421a198 895 s100421a199 896 8100421a200 897 8100421a201 898 8100421a202 899 8100421a203 90b s100421a204 901 s100421a20S 902 8100421a206 903 s100421a207 904 8100421a208 90S 8100421a209 906 8100421a210 907 8100421a211 908 8100421212 909 8100421a213 910 s100421a214 911 s100421a215 912 s100421a216 913 8100421a217 914 s100421a218 915 8100421a219 916 81004213220 917 8100421a221 918 8100421a222 919 8100421a223 920 8l00421a224 921 s100421a225 922 s100421a226 923 8100421a227 924 8100421a228 925 s100421a229 926 8100421a230 927 8l00421a231 928 s100421a232 EC-10041S-07 10 ng Extracted Curve Point 09004-129 solvent blank GLP1 CH)1-01-01-012 LMS Dii.xSO DAL DPOS SS SS 10 O O Lab Matrix Spike Dl.xSO G LP10-01-01-01-013 LMS Dil.x50 DAL DF8C SS SS01 0 0000 Lab Matrix Spike Dii.x50 GLP10-01-01-01-014 Dii.xSO DAL DF8C SS SS01 0 0010 Dil.x50 GLP10-01-01-01-014 Dup Dii.xSO DAL DF8C SS SS01 0 0010 Sample Duplicate Dii.xSO GLP10-01-01-01-014 LMS DI.X50 DAL DF8C SS SS01 0 0010 Lab Matrix Spike Dii.xSO GLP 10-01-01-01-015 LMS Dii.xSO DAL DF8C SS SS02 0 0000 Lab Matrix Spike Dii.xSO GLP10-01-01-01-020 LMS Dii.xSO DAL DF8C SS SS04 0 0000 Lab Matrix Spike Dii.xSO 09004-129 solvent blank EC-10041505 2.5 ng Extracted Curve Point 09004-129 solvent blank GLP1001-01-01-021 LMS Dii.xSO DAL DF8C SS SS04 0 0010 Lab Matrix Spike Dil.x50 GLP104)1-01-01-022 LMS Dii.xSO DAL DF8C SS SS05 0 0000 Lab Matrix Spike Dil.x50 G LP 10-01-01-01-028 Dii.xSO DAL DF11 SS SS06 0 0010 Dii.xSO GLP10-01-01-01-028 Dup Dii.xSO DAL DF11 SS SS06 0 0010 Sample Duplicate Dii.xSO GLP10-01-01-01-028 LMS Dii.xSO DAL DF11 SS SS06 0 0010 Lab Matrix Spike Dii.xSO GLP 1001 -01-01-017 Dil.x50 DAL DF6C SS SS03 0 0000 Dil.x50 GLP1001-01-01-017 Dup Dii.xSO DAL DF8C SS SS03 0 0000 Sample Duplicate Dii.xSO GLP10-01-01-01-017 LMS Dii.xSO DAL DF8C SS SS03 0 0000 Lab Matrix Spike Dii.xSO GLP1001-01-01-018 Dii.xSO DAL DF8C SS SS03 0 0010 Dii.xSO GLP1001-01-01-018 Dup Dii.xSO DAL DF6C SS SS03 0 0010 Sample Duplicate Dil.x50 GLP10-01-01-01-018 LMS Dil.x50 CAL DF8C SS SS03 0 0010 Lab Matrix Spike Dii.xSO 09004-129 solvent blank EC-10041506 5 ng Extracted Curve Point 09004-129 solvent blank GLP 100101-01-019 Dil.x50 DAL DF8C SS SS03 1 0010 Dii.x50 GLP 10010 1 0 1 0 1 9 Dup Dii.xSO DAL DF8C SS SS03 1 0010 Sample Duplicate Dil.x50 GLP10 0 1 0 1 0 1 0 1 9 LMS Ol.xSO DAL DF8C SS SS03 1 0010 Lab Matrix Spike Dit.x50 GLP10 0 1 0 1 0 1 0 2 3 Dii.xSO DAL DFSC SS SSOS 0 0010 Dii.xSO GLP1001-01-01-023 Dup D I.x X DAL DF6C SS SS05 0 0010 Sample Duplicate Dii.xSO GLP10 0 1 0 1 0 1 0 2 3 LMS Dil.x50 DAL DF8C SS SSOS 0 0010 Lab Matrix Spike Dii.xSO G L P 10-0101010 24 Dii.xSO DAL DF11 SS SSOS 0 0000 Dii.xSO G L P 1 0 0 1 0 1 0 1 0 2 4 Dup D I.x X DAL DF11 SS SSOS 0 0000 Sample Duplicate Dii.xSO GLP10O10 1 0 1 0 2 4 LMS Dii.xSO DAL DF11 SS SSOS 0 0000 Lab Matrix Spike Dii.xSO GLP10O10 1 0 1 0 2 5 Dii.xSO DAL DF11 SS SSOS 0 0010 Dl.xSO G L P 1 0 0 1 0 1 0 1 0 2 5 Dup Dii.xSO DAL DF11 SS SSOS 0 0010 Sample Duplicate Dil.x50 G LP 1 0 0 1 -0 1 0 1 0 2 5 LMS Dii.xSO DAL DF11 SS SSOS 0 0010 Lab Matrix Spike Dii.xSO 09004-129 solvent blank EC-100415-07 10 ng Extracted Curve Point 09004-129 solvent blank G LP10-01-0101-026 Dii.xSO DAL DF11 SS SSOS 1 0010 D l.x50 GLP10-01-01-01-026 Dup Dl.xSO DAL DF11 SS SSOS 1 0010 Sample DupGcate Dl.xSO G LP10-01-01-01-026 LMS DI.X50 DAL DF11 SS SSOS 1 0010 Lab Matrix Spike D l.x5 0 GLP10-01-01-01-027 Dl.xSO DAL DF11 SS SS06 0 0000 Dl.xSO GLP10-01-01-01-027 Dup D l.x50 DAL DF11 SS SS06 0 0000 Sample Duplicate Dl.xSO GLP10-01-01-01-027 LMS Dl.xSO DAL DF11 SS SS06 0 0000 Lab Matrix Spike Dl.xSO GLP 1001-01-01-029 Dl.xSO DAL DF11 SS SS07 0 0000 Dl.xSO G LP 10-01-01-01-029 Dup Dl.xSO DAL DF11 SS SS07 0 0000 Sample Duplicate Dl.xSO G LP10-01-01-01-029 LMS Dl.xSO DAL DF11 SS SS07 0 0000 Lab Matrix Spike Dl.xSO G LP10-01-01-01-030 Dl.xSO DAL DF11 SS SS07 0 0010 D!.x50 GLP10-01-01-01-030 Dup Dl.xSO DAL DF11 SS SS07 0 0010 Sample Duplicate D l.xS0 GLP10-01-01-01-030 LMS Dl.xSO DALDF11 SS SS07 0 0010 Lab Matrix Spike Dl.xSO 09004-129 solvent blank EC-100415-05 2.5 ng Extracted Curve Point 09004-129 solvent blank 09004-129 solvent blank Analyte Pea Name ' Sample Type PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Quafity Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Use Record A n a ly te C o n c e n tra tio n (ng/mL) A n a ly te R e te n tio n Tim e (min) Analyte Peal Area (counts; IS Peak Nam* IS P eak Area (counts) IS C o n c e n tra tio n (ng/m L) IS Retention Tim e (min) Calculated Concentration (n g /m L ) Accuracy <%) E 10.0 0.00 ;N/A jN/A N/A N/ N/A N/A N/A 0.00 E 2 .S0 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 E 0.0 0.00 N/A N/A iN /A |N/A iN /A j N/A N/A N/A N/A N/A N/A N/A 0.00 E 2.50 0.00 0.00 12.90 12.91 12.87 12.84 12 .6 6 12.87 12.87 12.88 12.86 12.86 12.88 12.94 12.88 12.87 12.87 12.87 12.91 12.88 12.88 12.88 12.89 12.90 12.88 12.87 12 .6 8 12.92 12.88 12.89 12.88 12.90 12.88 12.87 12.87 12.87 12.87 12.87 12.87 12.86 12.85 12.87 12.93 12.65 12.85 12.80 12.82 12.82 12.81 12.62 12.80 12.79 12.81 12.80 12.81 12.81 12.84 12.86 12.76 1482 1704 76397 989711 492952 434006 1340470 1032891 1117618 1059 122798 944 1282S54 1100749 1014915 1111734 2307478 1091243 1227762 8961513 1657293 1936317 9549674 2299 2413SS 379 1672605 1628505 9162637 625289 614709 6317945 2276427 12699S9 9668982 1093701 213089 9053731 1687 462508 726 1690419 1732188 8682130 1371466 1600766 8399204 21233175 24503452 24203602 5963940 6377069 12029696 2868 127S43 410 3S9 M8PFOS M8PFOS M8PFOS M8PFOS M 8P F O S M8PFOS M8PFOS M8PFOS M 8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M 8PFOS M8PFOS M 8PFOS M 8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M6PFOS M6PFOS M 8PFOS M8PFOS M 8PFOS M8PFOS M 8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M 8PFOS M 8PFOS M 8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M 8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS 22 j 22 62670 64646 64067 64776 62831 61765 61647 22 61173 22 64718 66326 60364 63168 60992 63905 63261 55753 59033 61768 S7426 70 59144 22 56752 60843 54467 6247S 61639 60228 59033 63162 S6451 61662 S9354 S6499 46 57778 0 60838 58303 58013 60112 63157 59802 51332 48739 48963 61288 61169 S7126 58 65354 22 46 3.00 N/A 3.00 3.00 3.00 ^ 3 00 3.00 3.00 3.0 N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3.0 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X 3 .X N/A 3 .X N/A N/A 12.69 13.01 12.65 12.66 12.66 12.87 12.87 12.69 12.65 12.84 12.86 12.97 12.87 12.89 12.68 12.87 12.69 12.87 12.87 12.87 12.X 12.88 12.87 12.72 12.87 12.93 12.88 12.87 12.91 12.66 12.88 12.68 12.87 12.88 12.87 12.85 12.66 12.68 12.86 12.87 0.000 12.83 12.81 12.77 12.82 12.X 12.61 12.79 12.79 12.X 12.79 12.76 12.78 12.61 12.X 12.77 12.64 X .1 N/A 21.6 19.2 9.62 8.37 26.9 21.0 22.8 N/A 2.44 N/A 24.9 20.9 2 1 .1 22.1 47.7 21.5 24.4 204. 39.7 39.5 212. N/A 5 .X N/A 35.9 33.7 214. 12.5 12.5 175. 48.7 25.3 218. 22.3 42.8 197. N/A 0.0 N/A 35.0 37.5 190. 28.7 31.9 178. 534. 652. 641. 124. 132. 269. N/A 237 N/A N/A 861. N/A N/A N/A N/A N/A N/A N/A N/A N/A 97.7 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 10 1. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 94.9 N/A N/A Record M o d if ie d File Name E s 100421a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E 8100421 a.wriff E 8100421a. wilt E s100421a.wiff E s100421a.wiff 8 100421a.wiff E s 100421a.wiff E s100421a.wiff K 8100421a.wiff E s10O421a.wiff E 8100421 a.wiff E 8100421 a.wiff E S100421a.wiff E 8100421 a.wiff K s100421a.wiff E s100421a.wiff E s100421a.wiff E s100421a.wiff 8100421a.wiff E s100421a.wiff 8100421a.wiff E 8100421 a.wiff E 6100421 a.wiff E 8100421 a.wiff E s100421 a.wiff E s100421a.wiff E s100421a.wiff E s100421a.wiff E s100421a.wiff E 8100421a.wiff E s100421a.wiff E 8100421 a.wiff E 8100421 a.wiff s100421a.m ff s100421 a.wiff 6100421a.wiff E s100421a.wiff E s100421a.wiff E &100421a.wiff E s100421a.wiff E 8100421a.wiff K 8100421 a.wiff E s100421a.wiff E 8100421 a.wiff E 8100421 a.wiff E s100421a.wiff E s100421a.wiff E s100421a.wiff s100421a.wiff n 8100421 a.wiff E 8100421a.wiff 8100421 a.wiff Printing Printing Time: L^ 0 T: :L P m In!erim `R e p o rte o f ' 2010 Page 14 of 14 Page 117 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P rin tin g ^ S t ^ ^ P l d - O i ^ 6 ' 2010 P rin tin g Page 1 of 1 Page 118 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Tiftt'e rm R e p o ft'b 'P ' 2010 Page 1 of 1 Page 119 of 539 Stan V1660305 *3M Environmental Lab 0 Results Name: sl0042la.rdb ^ m p M ^ - 0 2 6 - 2010 in te rim R e p o rt OT Page 1 of 1 Page 120 of 539 *Stan V1660305 *3M Environmental Lab \ C r ' O' , \ 0 lA', V Results Name: sl00421a.rdb Printing Printing Time : 2,^08 :g_Ck^M In te rim R e p o rt eDr ' 2010 Page 1 of 1 Page 121 of 539 \<J Stan: API4000: V1660305 DATE 4/21/10 ANALYSTkje STUDY NUMBER: GLP10-01-02-01 Matrix: soils Injection volume: 25 uL Electrode: turbo ion spray Mobile Phase: (A12 mM ammonium acetate (B) acetonitrile TN-A- or standard number (A) 10 001-206______ (B) tn09-0095 7/8 page 1/1 Guard (pre-autosampler) column prism RP Size: 2.1 mm X 50 mm__________ Type: C12 Sphere size: 5 Part number: 32105-052130 Lot number: 9411 Serial number 0991875T Analytical column 1 Oasis HLB Size: 3 X 20 mm________ Type: NA Sphere size: 25 um Part number: 186002039 serial number: 006A36131107 Analytical column 2 betasil C18 Size: 2.1 mm X 100 mm_________ Type: C18 Sphere size: 5______ Part number: 70105-102130 Lot number: 8606 Serial number 1173915T Printed: Wednesday, April 21, 2010 7:57 AM 3M Study: GLP10-01-02 Interim Report 01 Page 122 of 539 ETS Stan V1660305 \0 'b ^ e> Acquisition Information: Acquisition Method: Created: last Modified: Content: Synchronization Mode: Auto-Equilibration: Acquisition Curation: Nurfoer Of Scans: Periods In File: Acquisition Module: Software version Agilent IC Punp Method Properties Purrp Model: Minimum Pressure (psi): Maximum Pressure (psi): Dead Volute (pi): M a x i m m Flow Ranp (ml/min2): Maximum Pressure Ranp (psi/sec): EPS 8-53 23 min Sulfonates.dam Friday April 09 2010 13: 54: 09 EM Friday April 09 2010 16: 54: 27 EM Method for Sulfonates 23 minute gradient LC Sync Off 23min0sec 2281 1 Acquisition Method Analyst 1.4.2 Agilent 1100 LC Binary Punp 0.0 5801.0 40.0 100.0 290.0 Step Table: Step Total Time (min) C 0.00 1 3.00 2 3.50 2 17.00 4 17.50 5 19.50 6 20.00 7 23.00 Flow Fiate (pl/min) 400 400 400 400 400 400 400 400 A (%) 97.0 97.0 70.0 40.0 10.0 10.0 97.0 97.0 B (%) 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0 Left Carpressibility: 50.0 Right Ccrrpressibility: 115.0 Left Dead Volute (pi): 40.0 Right Dead Volute (pi): 40.0 left Stroke Volume (pi): Right Stroke Volume (pi): Left Solvent: A1 Right Solvent: B2 -1.0 -1.0 Agilent Autosanpler Properties Autosanpler Model: Agilent 1100 Thermo Autosanpler Syringe Size (pi): 100 Injection Volume (pi): 25.00 Draw Speed (pl/min): 200.0 Eject Speed (pl/min): 200.0 Needle Level (nm): 0.00 Tarperature Control Enabled Setpoint (4 - 40 C): 10 Wash is not used Use Custom Injector Program No Agilent Column Oven Properties Left Temperature (C): 30.00 Right Temperature (C): 30.00 Tarperature Tolerance +/- (C): 1.00 Start Acquisition Tolerance +/- (C): 0.50 Time Table (Used) C o l u m Switching Valve Installed Position for first sanple in the batch: Right Use same position for all samples in the batch Total Time (min) Valve Position 0.0C Left 5.0C Right Period 1: Scans in Period: 2281 Relative Start Time: 0.00 msec Experiments in Period: 1 Period 1 Experiment 1: Scan Type: Polarity: Scan Mode: Ion Source: Resolution Ql: Resolution Q3: Intensity Thres.: Settling Time: MR Pause: MPM (MPM) Negative N/A Turbo Spray Unit Unit 0.00 cps 0.0000 msec 5.0070 msec Printing Date: Wednesday, April 21, 2010 Printing Time: 7:53:07 AM 3M Study: GLP10-01-02 Interim Report 01 Page 1 of 3 Page 123 of 539 ETS St. V I 6 60305 MCA: No Step Size: 0.00 amu Q1 Mass (amu) 399.0C Q3 Mass (amu) 99.00 Dwell(msec) 50.00 Pararr DE CE CXE Start Step -100.00 -100.00 -54.00 -54.00 -5.00 -5.00 Q1 Mass (arru) 399.0C Q3 Mass (amu) 80.00 Dwell (msec) 50.00 Parair DF CE CXE Start Stop -100.00 -100.00 -82.00 -82.00 -5.00 -5.00 Q1 Mass (amu) 403.0C Q3 Mass (amu) 84.00 Dwell(msec) 50.00 Pararr DF CE CXF Start Step -100.00-100.00 -82.00 -82.00 -5.00 -5.00 Q1 Mass (amu) 299.0C Q3 Mass (arnu) 99.00 Dwell(msec) 50.00 Pararr DE CE CXF Start Step -65.00 -65.00 -44.00 -44.00 -15.00 -15.00 Q1 Mass (ami) 299.0C Q3 Mass (amu) 80.00 Dwell (msec) 50.00 Pararr DE CE CXF Start Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00 Q1 Mass (amu) 303.0C Q3 Mass (amu) 84.00 Dwell (msec) 50.00 Pararr DF CE CXE Start Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00 Q1 Mass (amu) 499.0C Q3 Mass (amu) 80.00 Dwell (msec) 50.00 Pararr DE CE CXF Start Step -120.00-120.00 -98.00 -98.00 -5.00 -5.00 Q1 Mass (amu) 499.0C Q3 Mass (arru) 99.00 Ctoell (msec) 50.00 Pararr DF CE CXE Start Stop -120.00-120.00 -82.00 -82.00 -5.00 -5.00 Q1 Mass (amu) 499.0C Q3 Mass (ami) 130.0C Dwell (msec) 50.00 Pararr DE CE CXF Start Stop -120.00 -120.00 -66.00 -66.00 -7.00 -7.00 Q1 Mass (amu) 503.0C Q3 Mass (amu) 80.00 Dwell (msec) 50.00 Pararr DF CE CXF Start Step -120.00-120.00 -98.00 -98.00 -5.00 -5.00 Q1 Mass (ami) 507.0C Q3 Mass (amu) 80.00 Dwell (msec) 50.00 Pararr DF CE CXF Start Stop -120.00 -120.00 -98.00 -98.00 -5.00 -5.00 Parameter Table (Period 1 CAD: 6.00 CUR: 35.00 GS1: 45.00 GS2: 60.00 IS: -4500.00 TEM: 450.00 ihe: CN EF -10.00 Experiment 1): Printing Date: Wednesday, April 21, 2010 Printing Time: 7:53:07 AM 3M Study: GLP10-01-02 Interim Report 01 . Page 2 of 3 Page 124 of 539 ETS Stan V1660305 Printing Time: 7:53:07 AM 3M Study: GLP10-01-02 Interim Report 01 Page 125 of 539 ETS Stan V1660305 Project: P:\Lab_lnstrument Data\Stan\Stan Data Files\Projects\fluorochemicalsteoil Batch:s100421a Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample Sample Name Sample ID Vial Position Data File Inj.Volum e (pil)i 1 s100421a001 09004-129 solvent blank 2 s100421a002 ,09004-129 solvent blank 3 s100421a003 i EC-100415-09 50 ng Warm up standard 4 s100421a004 EC-100415-09 50 ng Warmup standard 5 s100421a005 EC-100415-09 50 ng Warmup standard 6 s100421a006 09004-129 solvent blank 7 s100421a007 ;09004-129 solvent blank 8 s100421a008 09004-129 solvent blank 91 s100421a 25.000 91 s100421a 25.000 9 s100421a 25.000 , 9 s100421a 25.000 3 9 s 100421a 25.000 91 s100421a 25.000 " 91 s100421a 25.000 91 s100421a 25.000 ;j 9 s100421a009 09004-129 solvent blank 10 's100421a010 09004-129 solvent blank 11 s100421a011 EC-100415-01 0.2 ng Extracted Curve Fbint 12 s100421a012 EC-100415-02 0.5 ng Extracted Curve Paint 13 s100421a013 EC-100415-03 0.75 ng Extracted Curve Paint 14 s100421a014 EC-100415-04 1 ng Extracted Curve Fbint 91 s100421a 25.000 3 92 s100421a 25.000 ' 1 s100421a 25.000 ' 2 s100421a 25.000 3 s100421a 25.000 4 s100421a 25.000 15 s100421a015 EC-100415-05 2.5 ng Extracted Curve Paint 5 s100421a 25.000 : 16 s100421a016 EC-100415-06 5 ng Extracted Curve Paint 17 s100421a017 EC-100415-07 10 ng Extracted Curve Ftoint 18 s100421a018 ' EC-100415-08 25 ng Extracted Curve Paint 19 s100421a019 1EC-100415-09 50 ng Extracted Curve Point 6 s100421a 25.000 7 s100421a 25.000 8 s100421a 25.000 9 s 100421a 25.000 |l 20 s100421a020 ,EC-100415-10 100 ng Extracted Curve Paint 10 s100421a 25.000 21 s100421a021 ' EC-100415-11 200 ng Extracted Curve Point 22 s100421a022 EC-100415-12 500 ng Extracted Curve Point 23 s 100421a023 ,09004-129 solvent blank 24 s100421a024 09004-129 solvent blank 25 s100421a025 09004-129 solvent blank 26 s100421a026 09004-129 solvent blank 27 s100421a027 MB-100415-01 Method Blank 1 w /o IS 28 s100421a028 MB-100415-02 Method Blank2w /o IS 29 s100421a029 MB-100415-03 Method Blank 3 w /o IS 30 |s100421a030 ;MB--100415-04 Method Blank 4 w / IS 31 s100421a031 ,MB~100415-05 Method B lank5w /IS 32 s100421a032 |MB-100415-06 Method Blank 6 w / IS 33 s100421a033 LCS-100415-01 3 ng LCS in TCR-842 34 s 100421a034 LCS-100415-02 3 ng LCS in TCR-842 35 s100421a035 LCS-100415-03 3 ng LCS In TCR-842 36 s100421a036 LCS-100415-04 30 ng LCS In TCR-842 37 s100421a037 LCS-100415-05 30 ng LCS in TCR-842 38 s100421a038 LCS-100415-06 30 ng LCS In TCR-842 39 s100421a039 :LCS-100415-07 300 ng LCS in TCR-842 40 s 100421 a040 1LCS-100415-08 300 ng LCS In TCR-842 41 s100421a041 !LCS-100415-09 300 ng LCS In TCR-842 42 s 100421 a042 09004-129 solvent blank 11 s100421a 25.000 : 12 s100421a 25.000 , 92 s100421a 25.000 ,, 92 s 100421a 25.000 92 s100421a 25.000 93 s100421a 25.000 - 13 s100421a 25.000 14 s100421a 25.000 15 s100421a 25.000 : 16 s100421a 25.000 17 s100421a 25.000 18 s100421a 25.000 '' 19 s100421a 25.000 20 s100421a 25.000 J 21 s100421a 25.000 22 s100421a 25.000 , 23 s100421a 25.000 24 s100421a 25.000 1 25 s100421a 25.000 26 s100421a 25.000 3 27 s 100421a 25.000 93 s100421a 25.000 1 43 s100421a043 EC-100415-05 2.5 ng Extracted Curve Fbint 5 s100421a 25.000 44 s100421a044 09004-129 solvent blank 94 s100421a 25.000 45 s100421a045 GLP10-01-01-01-033 Soil Trip Blank 1 28 s100421a 25.000 46 s100421a046 GLP10-01-01-01-033 Dup Soil Trip Blank 1 Sample Duplicate 47 s100421a047 GLP10-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike 48 s100421a048 ' GLP10-01-01-01-034 Soil Trip Blank 3 49 s100421a049 GLP10-01-01-01-034 Dup Soil Trip Blank 3 Sample Duplicate 50 s100421a050 GLP10-01-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike 51 s100421a051 GLP10-01-01-01-001 DAL DF05 SS SS06 0 0000 52 s100421a052 GLP10-01-01-01-001 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate 53 s100421a053 GLP10-01-01-01-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike 54 s100421a054 GLP10-01-01-01-002 DAL DF05 SS SS06 0 0010 55 s100421a055 GLP10-01-01-01-002 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate 56 s100421a056 GLP10-01-01-01-002 LMS DAL DF05 SS SS06 0 0010 Lab Matrix Spike 57 s100421a057 GLP10-01-01-01-003 DAL DF05 SS SS06 1 0010 58 s100421a058 GLP10-01-01-01-003 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate 59 s100421a059 GLP10-01-01-01-003 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 29 s100421a 25.000 . 30 s100421a 25.000 31 s100421a 25.000 32 s100421a 25.000 33 s100421a 25.000 34 s100421a 25.000 35 s100421a 25.000 ' 36 s100421a 25.000 ' 37 s100421a 25.000 38 s100421a 25.000 39 s100421a 25.000 40 s100421a 25.000 41 s100421a 25.000 * 42 s100421a 25.000 ; 60 s 100421 a060 ' 09004-129 solvent blank 94 s100421a 25.000 61 s100421a061 EC-100415-06 5 ng Extracted Curve Point 62 s 100421 a062 109004-129 solvent blank 63 s100421a063 GLP10-01-01-01-004 DAL DF05 SS SS07 0 0000 -' - ................... ..... - * -- Printing Date: Wednesday, April 21, 2010 -- 6 s100421a 95 s100421a ------------------- -- ------- ' - ------ - 43 ------------- -- ---s-1-004-2-1-a. .. Page 1 of 4 25.000 25.000 ; 25.000 -- -- -------- -- - Printing Time: 1:09:16 PM ' . 3M Study: GLP10-01-02 Interim Report 01 Page 126 of 539 ETS Scan V I 660305 Project: P:\Lab_lnstrum ent D ata \S tan \S ta n Data Files\Projects\fluorochemicalsteoil B atch:s100421a T a b :S a m p le S et:S E T 0 1 A cqM ethod:ets 8 -5 3 2 3 min S ulfonates Sam ple Sample Name Sample ID Vial Position| Data File Inj.Volume (\i\) 64 s100421a064 GLP10-01-01-01-004 Dup DAL DF05 SS SS07 0 0000 Sample Duplicate 44 s100421a 25.000 65 s100421a065 GLP10-01-01-01-004 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike 66 s100421a066 GLP10-01-01-01-005 DAL DF05 SS SS07 0 0010 67 s100421a067 GLF10-01-01-01-005 Dup DAL DF05 SS SS07 0 0010 Sample Duplicate 68 s100421a068 GLP10-01-01-01-005 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike 69 s100421a069 GLPt 0-01-01-01-007 DAL DF05 SS SS08 0 0000 45 s100421a 25.000 46 s100421a 25.000 ( 47 s100421a 25.000 :. 48 s100421a 25.000 49 s100421a 25.000 70 s100421a070 GLP10-01-01-01-007 Dup DAL DF05 SS SS08 0 0000 Sample Duplicate 50 s100421a 25.000 71 s100421a071 GLP10-01-01-01-007 LMS DAL DF05 SS SS08 0 0000 Lab Matrix Spike 51 s100421a 25.000 72 s100421a072 GLP10-01-01-01-008 DAL DF05 SS SS08 0 0010 73 s100421a073 GLP10-01-01-01-008 Dup DAL DF05 SS SS08 0 0010 Sample Duplicate 74 s100421a074 GLP10-01-01-01-008 LMS DAL DF05 SS SS08 0 0010 Lab Matrix Spike 75 s100421a075 GLP10-01-01-01-010 DAL DF05 SS SS09 0 0010 52 s100421a 25.000 53 s 100421a 25.000 54 s100421a 25.000 55 s100421a 25.000 76 s100421a076 GLP10-01-01-01-010 Dup DAL DF05 SS SS09 0 0010 Sample Duplicate 56 s100421a 25.000 ; 77 s100421a077 GLP10-01-01-01-010 LMS DAL DF05 SS SS09 0 0010 Lab Matrix Spike 57 s100421a 25.000 78 s100421a078 09004-129 solvent blank 79 s100421a079 EC-100415-07 10 ng Extracted Curve Paint 95 s100421a 25.000 7 s100421a 25.000 1 80 s100421a080 09004-129 solvent blank 96 s100421a 25.000 81 s100421a081 GLP10-01-01-01-016 DAL DF8C SS SS02 0 0010 58 s100421a 25.000 82 s100421a082 GLP10-01-01-01-016 Dup DAL DF8CSS SS02 0 0010 Sample Duplicate 83 s100421a083 GLP10-01-01-01-016 LMS DAL DF8C SS SS02 0 0010 Lab Matrix Spike 84 s100421 a084 GLP10-01-01-01-009 DAL DF05 SS SS09 0 0000 59 s100421a 25.000 60 s 100421 a 25.000 .. 61 s100421a 25.000 " 85 s100421a085 GLP10-01-01-01-009 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate 62 s100421a 25.000 86 ps100421a086 GLF>10-01-01-01-009 LMS DAL DF05 SS SS09 0 0000 Lab Matrix Spike 87 s100421a087 GLP10-01-01-01-011 DAL DF05 SS SS10 0 0000 88 s100421a088 GLP10-01-01-01-011 Dup DAL DF05 SS SS10 0 0000 Sample Duplicate 63 s100421a 25.000 64 s100421a 25.000 65 s 100421a 25.000 - 89 s100421a089 GLP10-01-01-01-011 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike 66 s100421a 25.000 ;; 90 s100421a090 GLP10-01-01-01-012 DAL DF05 SS SS10 0 0010 67 s100421a 25.000 91 s100421a091 GLP10-01-01-01-012 Dup DAL DF05 SS SS10 0 0010 Sample Duplicate 68 s100421a 25.000 : 92 ;s100421a092 GLP10-01-01-01-012 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike 93 s100421a093 GLP10-01-01-01-013 DAL DF8C SS SS01 0 0000 69 s100421a 25.000 70 s100421a 25.000 94 s100421a094 GLP10-01-01-01-013 Dup DAL DF8C SS SS01 0 0000 Sample Duplicate 95 s100421a095 GLP10-01-01-01-013 LMS DAL DF8C SS SS01 0 0000 Lab Matrix Spike 96 s100421a096 09004-129 solvent blank 97 s100421a097 EC-100415-05 2.5 ng Extracted Curve Paint 98 s100421a098 09004-129 solvent blank 71 s100421a 25.000 72 s100421a 25.000 96 s100421a 25.000 5 s100421a 25.000 " 97 s 100421a 25.000 99 s100421a099 GLP10-01-01-01-014 DAL DF8CSS SS01 0 0010 73 s100421a 25.000 ' 100 s100421a100 GLP10-01-01-01-014 Dup DAL DF8C SS SS01 0 0010 Sample Duplicate 101 s100421a101 GLP10-01-01-01-014 LMS DAL DF8C SS SS01 0 0010 Lab Matrix Spike 102 s100421a102 GLP10-01-01-01-015 DAL DF8C SS SS02 0 0000 103 s100421a103 GLP10-01-01-01-015 Dup DAL DF8C SS SS02 0 0000 Sample Duplicate 104 s100421a104 GLP10-01-01-01-015 LMS DAL DF8C SS SS02 0 0000 Lab Matrix Spike 74 s100421a 25.000 75 s100421a 25.000 76 s100421a 25.000 , 77 s100421a 25.000 78 s100421a 25.000 105 s100421a105 GLP10-01-01-01-020 DAL DF8C SS SS04 0 0000 106 s100421a106 GLP10-01-01-01-020 Dup DAL DF8C SS SS04 0 0000 Sample Duplicate 107 s100421a107 GLP10-01-01-01-020 LMS DAL DF8C SS SS04 0 0000 Lab Matrix Spike 108 s100421a108 GLP10-01-01-01-021 DAL DF8CSS SS04 0 0010 109 s100421a109 GLP10-01-01-01-021 Dup DAL DF8CSS SS04 0 0010 Sarrple Duplicate 79 s100421a 25.000 80 s100421a 25.000 81 s100421a 25.000 ;; 82 s100421a 25.000 83 s100421a 25.000 110 s100421a110 GLP10-01-01-01-021 LMSDALDF8CSS SS04 0 0010 Lab Matrix Spike 111 s100421a111 GLP10-01-01-01-022 DAL DF8C SS SS05 0 0000 112 s100421a112 GLP10-01-01-01-022 Dup DAL DF8C SS SS05 0 0000 Sample Duplicate 113 s100421a113 GLP10-01-01-01-022 LMS DAL DF8C SS SS05 0 0000 Lab Matrix Spike 114 s100421a114 09004-129 solvent blank 115 s100421a115 EC-100415-06 5 ng Extracted Curve Paint 84 s 100421a 25.000 " '! 85 s100421a 25.000 86 s100421a 25.000 87 s100421a 25.000 97 s100421a [25.000 6 s100421a 25.000 116 s100421ai16 09004-129 solvent blank 117 s100421a17 ^ L P I0-01-01-01-028 DAL DF11 SS SS06 0 0010 118 s100421a118 GLP10-01-01-01-028 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate 98 s100421a 25.000 13 s100421a 25.000 14 s100421a 25.000 119 ' s 100421a119 GLP10-01-01-01-028 LMS DAL DF11 SS SS06 0 0010 Lab Matrix Spike 120 s100421a120 GLP10-01-01-01-017 DAL DF8C SS SS03 0 0000 15 s100421a 25.000 ; 16 s 100421 a 25.000 121 ,s100421a121 GLP10-01-01-01-017 Dup DAL DF8CSS SS03 0 0000 Sarrple Duplicate 122 s100421a122 GLP10-01-01-01-017 LMS DAL DF8C SS SS03 0 0000 Lab Matrix Spike 17 s100421a 25.000 18 s 100421 a 25.000 ; 123 s100421a123 GLP10-01-01-01-018 DAL DF8C SS SS03 0 0010 124 s100421a124 ` GLP10-01-01-01-018 Dup DAL DF8C SS SS03 0 0010 Sample Duplicate 125 s100421a125 GLP10-01-01-01-018 LMS DAL DF8C SS SS03 0 0010 Lab Matrix Spike 19 s100421a 25.000 ' 20 s100421a 25.000 21 s 100421a 25.000 126 s100421a126 GLP10-01-01-01-019 DAL DF8C SS SS03 1 0010 22 s100421a 25.000 ; Printing Date: Wednesday, April 21, 2010 Page 2 of 4 Printing Time: 1:09:16 PM 3M Study: GLP10-01-02 Interim Report 01 Page 127 of 539 ETS Stan V1660305 Project: P:\Lab_lnstrum ent D ata\S tan\S tan Data Rles\Projects\fluorochemicalsftsoil B atch:s100421a T a b :S am p fe S et:S E T 0 1 A c q M e th o d :ets8 -5 3 23 m in Sulfonates Sam ple Sample Name Sample ID 127 s100421a127 GLP10-01-01-01-019 Dup DAL DF8CSS SS03 1 0010 Sample Duplicate 128 s100421a128 IGLPI 0-01-01-01-019 LMS DAL DF8C SS SS03 1 0010 Lab Matrix Spike 129 s100421a129 IGLPI0-01-01-01-023 DAL DF8C SS SS05 0 0010 130 s100421a130 GLP10-01-01-01-023 Dup DAL DF8CSS SS05 0 0010 Sample Duplicate 131 s100421a131 GLP10-01-01-01-023 LIVE DAL DF8C SS SS05 0 0010 Lab Matrix Spike 132 s100421a132 09004-129 solvent blank 133 s100421a133 EC-100415-07 10 ng Extracted Curve Fbint 134 s100421a134 09004-129 solvent blank 135 s100421a135 GLP10-01-01-01-024 DAL DF11 SS SS05 0 0000 136 s100421a136 GLP10-01-01-01-024 Dup DAL DF11 SS SS05 0 0000 Sample Duplicate 137 s100421a137 GLP10-01-01-01-024 LMS DAL DF11 SS SS05 0 0000 Lab Matrix Spike 138 s100421a138 GLP10-01-01-01-025 DAL DF11 SS SS05 0 0010 139 s100421a139 GLP10-01-01-01-025 Dup DAL DF11 SS SS05 0 0010 Sample Duplicate 140 s100421a140 GLP10-01-01-01-025 LMS DAL DF11 SS SS05 0 0010 Lab Matrix Spike 141 s100421a141 GLP10-01-01-01-026 DAL DF11 SS SS05 1 0010 142 s100421a142 GLP10-01-01-01-026 Dup DAL DF11 SS SS05 1 0010 Sample Duplicate 143 s100421a143 GLP10-01-01-01-026 LMS DAL DF11 SS SS05 1 0010 Lab Matrix Spike 144 s100421a144 09004-129 solvent blank 145 s100421a145 09004-129 solvent blank 146 s100421a146 09004-129 solvent blank 147 s100421a147 EC-100415-05 2.5 ng Extracted Curve Point 148 s100421a148 09004-129 solvent blank 149 s100421a149 GLP10-01-01-01-027 DAL DF11 SS SS06 0 0000 150 s100421a150 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sarrple Duplicate 151 s100421a151 GLP10-01-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike 152 s100421a152 GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 153 s100421a153 GLP10-01-01-01-029 Dup DAL DF11 SS SS07 0 0000 Sarrple Duplicate 154 s100421a154 IGLPI0-01-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike 155 ;s100421a155 |GLP10-01-01-01-030 DAL OF11 SS SS07 0 0010 156 s100421a156 IGLPI0-01-01-01-030 Dup DAL DF11 SS SS07 0 0010 Sample Duplicate 157 s100421a157 GLP10-01-01-01-030 LMS DAL DF11 SS SS07 0 0010 Lab Matrix Spike 158 s100421a158 09004-129 solvent blank 159 s100421a159 '09004-129 solvent blank 160 s100421a160 '09004-129 solvent blank 161 s 100421a161 (EC-100415-06 5 ng Extracted Curve Paint 162 s100421a162 109004-129 solvent blank 163 ,s100421a163 :MB--100415-07 Method Blank 5g w / IS for Dilutions 164 s100421a164 MB--100415-08 Method Blank 5g w / IS for Dilutions 165 s100421a165 (MB--100415-09 Method Blank 5g w / IS for Dilutions 166 s100421a166 |MB--100415-10 Method Blank 5g w / IS for Dilutions 167 is100421a167 !M B -100415-11 Method Blank 5g w / IS f or Dlutions 168 s100421a168 iLCS-100415-07 Dil.x50 300 ng LCS in TCR-842 Dil.x50 169 s100421a169 LCS-100415-08 DI.X50 300 ng LCS in TCR-842 Dil.x50 170 s100421a170 LCS-100415-09 Dil.x50 300 ng LCS in TCR-842 Dil.x50 171 s100421a171 GLP10-01-01-01-009 Dil.x50 DAL DF05 SS SS09 0 0000 Dil.x50 172 s100421a172 GLP10-01-01-01-009 Dup Dil.x50 DAL DF05 SS SS09 0 0000 Sample Duplicate Dil.x50 173 s100421a173 GLP10-01-01-01-009 LMS Dil.x50 DAL DF05 SS SS09 0 0000 Lab Matrix Spike Ql.x50 174 s100421a174 GLP10-01-01-01-011 Dil.x50 DAL DF05 SS SS10 0 0000 Dil.x50 175 s100421a175 GLP10-01-01-01-011 Dup Dil.x50 DAL DF05SS SS10 0 0000 Sample Duplicate Dil.x50 176 s100421a176 GLP10-01-01-01-011 LMS Dil.x50 DAL DF05 SS SS10 0 0000 Lab Matrix Spike Dil.x50 177 s100421a177 09004-129 solvent blank 178 s100421a178 iEC-100415-07 10 ng Extracted Curve Paint 179 s100421a179 ' 09004-129 solvent blank 180 s100421a180 GLP10-01-01-01-012 DI.X50 DAL DF05 SS SS10 0 0010 Dil.x50 181 s100421a181 'GLP10-01-01-01-012 Dup Dil.x50 DAL DF05 SS SS10 0 0010 Sarrple Duplicate Dil.x50 182 s100421 a182 GLP10-01-01-01-012 LMS Dil.xSO DAL DF05 SS SS10 0 0010 Lab Matrix Spike Dil.x50 183 s100421a183 GLP10-01-01-01-013 DI.X50 DAL DF8CSS SS01 0 0000 Dil.x50 184 s100421a184 GLP10-01-01-01-013 Dup Dil.x50 DAL DF8CSS SS01 0 0000 Sample Duplicate Dil.x50 185 s100421a185 GLP10-01-01-01-013 LMS Dil.x50 DAL DF8CSS SS01 0 0000 Lab Matrix Spike Dil.x50 186 s100421a186 GLP10-01-01-01-014 Dil.x50 DAL DF8C SS SS01 0 0010 Dil.x50 187 s100421a187 GLP10-01-01-01-014 Dup Dil.x50 DAL DF8CSS SS01 0 0010 Sarrple Duplicate Dil.x50 188 s100421a188 GLP10-01-01-01-014 LMS Dil.x50 DAL DF8C SS SS01 0 0010 Lab Matrix Spike Dil.x50 189 s100421a189 GLP10-01-01-01-015 Dil.x50 DAL DF8C SS SS02 0 0000 Dil.x50 Vial Position Data Rie 23 s100421a 24 s 100421 a 25 s100421a 26 s100421a 27 s 100421a 98 s 100421a 7 s100421a 99 s 100421a 28 s100421a 29 s 100421a 30 s100421a 31 s100421a 32 s 100421a 33 s100421a 34 s100421a 35 s 100421a 36 s100421a 99 s 100421a 99 s100421a 100 s100421a 5 s100421a 100 s100421a 37 s100421a 38 s 100421a 39 s100421a 40 s100421a 41 s100421a 42 s100421a 43 s100421a 44 s100421a 45 s100421a 100 s 100421 a 100 s100421a 91 s100421a 6 s100421a 91 s100421a 46 s100421a 47 s100421a 48 s100421a 49 s100421a 50 s100421a 51 s100421a 52 s100421a 53 s100421a 54 s100421a 55 s100421a 56 s100421a 57 s100421a 58 s100421a 59 s100421a 91 s100421a 7 s 100421a 92 s100421a 60 s100421a 61 s100421a 62 s100421a 63 s100421a 64 s100421a 65 s100421a 66 s100421a 67 s100421a 68 s100421a 69 s100421a Inj.Volume (pi) 25.000 25.000 25.000 25.000 ' 25.000 25.000 , 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 . 25.000 25.000 25.000 ; 25.000 25.000 25.000 25.000 25.000 ; 25.000 25.000 . 25.000 ' 25.000 25.000 25.000 , 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 J 25.000 25.000 25.000 ' 25.000 25.000 , 25.000 25.000 25.000 25.000 j 25.000 } 25.000 25.000 25.000 25.000 25.000 25.000 ; 25.000 25.000 . 25.000 25.000 ' 25.000 ' 25.000 ?rinting Date: Wednesday, April 21, 2010 Page 3 of 4 Printing Time: 1:09:16 PM 3M Study: GLP10-01-02 Interim Report 01 i Page 128 of 539 ETS Stan V1660305 Project: P :\Lab _ln s tru m e nt D a ta \S ta n \S ta n D ata FilesftProjects\fluorochemicals&soiI Batch:s10 0 4 2 1a T a b :S a m p le S e t:S E T 0 1 A c q M e th o d :e ts 8 -5 3 2 3 m in S ulfona te s Sam ple Sample Name Sample ID 190 s100421a190 GLP10-01-01-01-015 Dup M.x50 DAL DF8C SS SS02 0 0000 Sample Duplicate Dll.x50 191 s100421a191 GLP10-01-01-01-015 LMS Dil.x50 DAL DF8C SS SS02 0 0000 Lab Matrix Spike Dil.x50 192 s100421a192 GLP10-01-01-01-020 Dil.x50 DAL DF8CSS SS04 0 0000 Dil.x50 193 s100421a193 GLP10-01-01-01-020 Dup Dil.x50 DAL DF8CSS SS04 0 0000 Sample Duplicate Dil.x50 194 s100421a194 GLP10-01-01-01-020 LMS Dil.x50 DAL DF8CSS SS04 0 0000 Lab Matrix Spike Dil.x50 195 s100421a195 09004-129 solvent blank 196 s100421a196 !EC-100415-05 2.5 ng Extracted Curve ftiint 197 s100421a197 09004-129 solvent blank 198 s100421a198 GLP10-01-01-01-021 Dil.xSO DAL DF8C SS SS04 0 0010 Dil.x50 199 s100421a199 IGLP10-01-01-01-021 Dup Dil.x50 DAL DF8CSS SS04 0 0010 Sample Duplicate Dil.x50 20 s100421a200 >GLP10-01-01-01-021 LMS Dil.x50 DAL DF8C SS SS04 0 0010 Lab Matrix Spike Dil.x50 201 s100421a201 GLP10-01-01-01-022 Dil.x50 DAL DF8C SS SS05 0 0000 Dil.x50 202 s100421a202 GLP10-01-01-01-022 Dup Dil.x50 DAL DF8C SS SS05 0 0000 Sample Duplicate Dil.x50 203 s100421a203 GLP10-01-01-01-022 LMS Dil.x50 DAL DF8C SS SS05 0 0000 Lab Matrix Spike Dil.x50 204 s100421a204 GLP10-01-01-01-028 Dil.x50 DAL DF11 SS SS06 0 0010 DII.X50 205 s100421a205 GLP10-01-01-01-028 Dup Dil.x50 DAL DF11 SS SS06 0 0010 Sample Duplicate Dil.x50 206 s100421a206 GLP10-01-01-01-028 LMS Dil.x50 DAL DF11 SS SS06 0 0010 Lab Matrix Spike Dil.x50 207 s100421a207 GLF>10-01-01-01-017 Dil.x50 DAL DF8C SS SS03 0 0000 Dil.x50 208 ,s100421a208 GLP10-01-01-01-017 Dup Dil.x50 DAL DF8CSS SS03 0 0000 Sample Duplicate DII.X50 209 s100421a209 GLP10-01-01-01-017 LMS Dil.x50 DAL DF8C SS SS03 0 0000 Lab Matrix Spike Dl.x50 210 s100421a210 GLP10-01-01-01-018 Dil.x50 DAL DF8C SS SS03 0 0010 Dil.x50 211 s100421a211 GLP10-01-01-01-018 Dup Dil.x50 DAL DF8CSS SS03 0 0010 Sample Duplicate Dil.x50 212 s100421a212 GLF>10-01-01-01-018 LMS Dil.x50 DAL DF8C SS SS03 0 0010 Lab Matrix Spike Dil.x50 213 s100421a213 09004-129 solvent blank 214 s100421a214 EC-100415-06 5 ng Extracted Curve Ftolnt 215 s100421a215 09004-129 solvent blank 216 s100421a216 GLP10-01-01-01-019 Dil.x50 DAL DF8C SS SS03 1 0010 Dil.x50 217 s100421a217 GLP10-01-01-01-019 Dup Dl.x50 DAL DF8CSS SS03 1 0010 Sample Duplicate Dil.x50 218 s100421a218 GLF>10-01-01-01-019 LMS Dil.x50 DAL DF8C SS SS03 1 0010 Lab Matrix Spike Dil.x50 219 s100421a219 GLPI 0-01-01-01-023 Dil.x50 DAL DF8C SS SS05 0 0010 QU50 220 s100421a220 GLP10-01-01-01-023 Dup Dil.xSO DAL DF8C SS SS05 0 0010 Sample Duplicate M.x50 221 s100421a221 iGLP10-01-01-01-023 LMS Dil.x50 DAL DF8C SS SS05 0 0010 Lab Matrix Spike Dil.x50 222 s100421a222 GLP10-01-01-01-024 Dil.xSO DAL DF11 SS SS05 0 0000 Dil.x50 223 s100421a223 IGLP10-01-01-01-024 Dup Dil.x50 DAL DF11 SS SS05 0 0000 Sample Duplicate D'l.x50 224 s100421a224 GLP10-01-01-01-024 LMS Dil.x50 DAL DF11 SS SS05 0 0000 Lab Matrix Spike Dl.x50 225 s100421a225 GLP10-01-01-01-025 Dil.x50 DAL DF11 SS SS05 0 0010 Dil.x50 226 s100421a226 GLP10-01-01-01-025 Dup Dil.x50 DAL DF11 SS SS05 0 0010 Sample Duplicate Dil.x50 227 s100421a227 jGLPI 0-01-01-01-025 LMS Dil.x50 DAL DF11 SS SS05 0 0010 Lab Matrix Spike Dil.x50 228 s100421a228 09004-129 solvent blank 229 s100421a229 EC-100415-07 10 ng Extracted Curve Point 230 s100421a230 09004-129 solvent blank 231 s100421a231 GLP10-01-01-01-026 Dil.xSO DAL DF11 SS SS05 1 0010 Dil.x50 232 s100421a232 GLP10-01-01-01-026 Dup Dil.xSO DAL DF11 SSSS05 1 0010 Sample Duplicate Dil.x50 233 s100421a233 GLP10-01-01-01-026 LMS Dil.xSO DAL DF11 SS SS05 1 0010 Lab Matrix Spike Dil.x50 234 s100421a234 ,GLP10-01-01-01-027 Dil.x50 DAL DF11 SS SS06 0 0000 Dil.x50 235 s100421a235 GLP10-01-01-01-027 Dup Dil.xSO DAL DF11 SS SS06 0 0000 Sample Duplicate Dil.xSO 236 s100421a236 GLP10-01-01-01-027 LMS Dil.x50 DAL DF11 SS SS06 0 0000 Lab Matrix Spike Dil.x50 237 s100421a237 GLP10-01-01-01-029 Dil.x50 DAL DF11 SS SS07 0 0000 Dil.x50 238 s100421a238 GLP10-01-01-01-029 Dup Dil.x50 DAL DF11 SS SS07 0 0000 Sample Duplicate Dil.x50 239 s100421a239 GLP10-01-01-01-029 LMS Dil.xSO DAL DF11 SSSS07 0 0000 Lab Matrix Spike Dtl.x50 240 s100421a240 GLP10-01-01-01-030 Dil.x50 DAL DF11 SS SS07 0 0010 Dil.x50 241 s10042ia241 GLP10-01-01-01-030 Dup Dil.x50 DAL DF11 SS SS07 0 0010 Sample Duplicate Dil.x50 242 s100421a242 GLF>10-01-01-01-030 LMS Dil.x50 DAL DF11 SSSS07 0 0010 Lab Matrix Spike Dil.x50 243 . s100421a243 09004-129 solvent blank 244 s100421a244 EC-100415-05 2.5 ng Extracted Curve Point 245 s100421a245 09004-129 solvent blank 246 s100421a246 ;09004-129 solvent blank Vial Position Data File 70 s100421a 71 s100421a 72 s100421a 73 s100421a 74 s100421a 93 s100421a 5 s100421a 94 s100421a 75 s100421a 76 s100421a 77 s100421a 78 s100421a 79 s100421a 80 s100421a 81 s100421a 82 s100421a 83 s100421a 84 s100421a 85 s100421a 86 s100421a 87 s100421a 88 s100421a 89 s100421a 94 s100421a 6 s100421a 95 s100421a 13 s100421a 14 s100421a 15 s100421a 16 s100421a 17 s100421a 18 s100421a 19 s100421a 20 s100421a 21 s100421a 22 s100421a 23 s100421a 24 s100421a 95 s100421a 7 s 100421a 96 s100421a 25 s 100421a 26 s100421a 27 s100421a 28 s100421a 29 s100421a 30 s100421a 31 s100421a 32 s100421a 33 "I s100421a 34 s100421a 35 s 100421 a 36 s100421a 96 s100421a 5 s100421a 97 s100421a 98 s100421a Inj.Volume (pi) 25.000 25.000 25.000 25.000 25.000 : 25.000 25.000 25.000 25.000 1 25.000 1 25.000 25.000 ! 25.000 * 25.000 25.000 ; 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 ' 25.000 25.000 , 25.000 25.000 ; 25.000 25.000 , 25.000 ; 25.000 ; 25.000 25.000 25.000 25.000 i 25.000 ; 25.000 | 25.000 25.000 i 25.000 1 25.000 ; 25.000 | 25.000 ; 25.000 ! 25.000 ; 25.000 25.000 25.000 25.000 25.000 25.000 a 25.000 25.000 25.000 ; [25.000 , Printing Date: Wednesday, April 21, 2010 Printing Time: 1:09:16 PM 3M Study: GLP10-01-02 Interim Report 01 Page 4 of 4 Page 129 of 539 ETS Stai VI 660305 e u \& \o (A r^ .< e c\ o l i L K z/a . C ^A ^ec^ Ui't-l | . W - r /+ iv r e 6c^^pbi>. (S ? ^'2 S -/o Project: P:\Lab_lnstrument Data\Stan\Stan Data Files\Projects\fluorochemicalsftsoil Batch:s100421a2 Tab:Sample Set:SET01 AcqMethod:ets8>53 23 min Sulfonates Sample Sample Name' Sample ID 1 s100421a001 |09004-129 solvent blank 2 s100421a002 09004-129 solvent blank 3 s100421a003 EC-100415-09 50 ng Warm up standard 4 s100421a004 IEC-100415-09 50 ng Warm up standard 5 ,s100421a005 jEC-100415-09 50 ng Warm up standard 6 s100421a006 ;09004-129 solvent blank 7 !s100421a007 09004-129 solvent blank 8 ,s100421a008 [09004-129 solvent blank g is 100421a009 09004-129 solvent blank 10 s100421a010 09004-129 solvent blank 11 s100421a011 i EC-100415-01 0.2 ng Extracted Curve Paint 12 s100421a012 EC-100415-02 0.5 ng Extracted Curve Point 13 s100421a013 EC-100415-03 0.75 ng Extracted Curve Point 14 s100421a014 ;EC-100415-04 1 ng Extracted Curve Roint 15 s100421a015 !EC-100415-05 2.5 ng Extracted Curve Point 16 's100421a016 ,EC-100415-06 5 ng Extracted Curve Point 17 s100421a017 EC-100415-07 10 ng Extracted Curve Point 18 !s100421a018 !EC-100415-08 25 ng Extracted Curve Point 19 s100421a019 EC-100415-09 50 ng Extracted Curve Point 20 s100421a020 EC-100415-10 100 ng Extracted Curve Point 21 ,s100421a021 EC-100415-11 200 ng Extracted Curve Point 22 s100421a022 EC-100415-12 500 ng Extracted Curve Point 23 s100421a023 09004-129 solvent blank 24 s100421a024 09004-129 solvent blank 25 s100421a025 09004-129 solvent blank 26 s100421a026 09004-129 solvent blank 27 s100421a027 MB--100415-01 Method Blank 1 w /olS 28 s100421a028 MB--100415-02 Method Blank2w /o IS 29 s100421a029 MB--100415-03 Method Blank 3 w /o IS 30 s100421a030 MB--100415-04 Method Blank4 w / IS 31 s100421a031 MB--100415-05 Method Blank 5 w / IS 32 s100421a032 M B -100415-06 Method Blank 6 w / IS 33 s100421a033 LCS-100415-01 3 ng LCS in TCR-842 34 :s100421a034 LCS-100415-02 3 ng LCS in TCR-842 35 s100421a035 LCS-100415-03 3 ng LCS in TCR-842 36 ;s100421a036 ILCS-100415-04 30 ng LCS In TCR-842 37 ,s100421a037 j LCS-100415-05 30 ng LCS in TCR-842 38 s100421a038 |LCS-100415-06 30 ng LCS in TCR-842 39 s100421a039 LCS-100415-07 300 ng LCS In TCR-842 40 s100421a040 ;LCS-100415-08 300 ng LCS In TCR-842 41 s100421a041 LCS-100415-09 300 ng LCS in TCR-842 42 s100421a042 09004-129 solvent blank 43 s100421a043 jEC-100415-05 2.5 ng Extracted Curve Ftoint 44 s100421a044 09004-129 solvent blank 45 s100421a045 jGLPI 0-01-01-01-033 Soil Trip Blank 1 46 s100421a046 jGLPI 0-01-01-01-033 Dup Soil Trip Blank 1 Sample Duplicate 47 s100421a047 JGLPI0-01-01-01-033 LMS Soil Trip Blank 1 Lab Matrix Spike 48 s100421a048 GLP10-01-01-01-034 Soil Trip Blank 3 49 s100421a049 :GLP10-01-01-01-034 Dup Soil Trip Blank 3 Sample Duplicate 50 s100421a050 GLP10-01-01-01-034 LMS Soil Trip Blank 3 Lab Matrix Spike 51 s100421a051 GLP10-01-01-01-001 DAL DF05 SS SS06 0 0000 52 s100421a052 GLP10-01-01-01-001 Dup DAL DF05 SS SS06 0 0000 Sample Duplicate 53 :s100421a053 JGLPI0-01-01-01-001 LMS DAL DF05 SS SS06 0 0000 Lab Matrix Spike 54 s100421a054 GLP10-01-01-01-002 DAL DF05 SS SS06 0 0010 55 ,s100421a055 GLP10-01-01-01-002 Dup DAL DF05 SS SS06 0 0010 Sample Duplicate 56 s100421a056 GLP10-01-01-01-002 LMS DAL DF05 SS SS06 0 0010 Lab Matrix Spike 57 ,s100421a057 GLP10-01-01-01-003 DAL DF05 SS SS06 1 0010 58 s100421a058 GLP10-01-01-01-003 Dup DAL DF05 SS SS06 1 0010 Sample Duplicate 59 s100421a059 GLP10-01-01-01-003 LMS DAL DF05 SS SS06 1 0010 Lab Matrix Spike 60 s100421a060 09004-129 solvent blank 61 s100421a061 EC-100415-06 5 ng Extracted Curve Point 62 s100421a062 109004-129 solvent blank 63 s100421a063 GLP10-01-01-01-004 DAL DF05 SS SS07 0 0000 Vial P osition Data File 91 s 100421 a 91 s 100421 a 9 s 100421 a 9 s 100421 a 9 s 100421 a 91 s 100421 a 91 s 100421 a 91 s100421a 91 s100421a 92 s100421a 1 s100421a 2 s100421a 3 s100421a 4 s100421a 5 s100421a 6 s100421a 7 s100421a 8 s100421a 9 s100421a 10 s100421a 11 s100421a 12 s100421a 92 s100421a 92 s100421a 92 s100421a 93 s 100421a 13 s 100421 a 14 s 100421 a 15 s100421a 16 s 100421a 17 s100421a 18 s100421a 19 s100421a 20 s100421a 21 s100421a 22 s100421a 23 s100421a 24 s100421a 25 s100421a 26 s100421a 27 s 100421a 93 s100421a 5 s100421a 94 s100421a 28 s100421a 29 s 100421a 30 s 100421a 31 s100421a 32 s 100421 a 33 s 100421a 34 s 100421a 35 s 100421a 36 s100421a 37 s100421a 38 s100421a 39 s100421a 40 s100421a 41 s100421a 42 s 100421a 94 s 100421 a 6 s 100421 a 95 s 100421 a 43 s100421a Inj.Volum e (pi) 25.000 25.000 . 25.000 25.000 25.000 25.000 25.000 ; 25.000 25.000 j 25.000 25.000 25.000 25.000 25.000 ' 25.000 25.000 25.000 ; 25.000 ; 25.000 , 25.000 J 25.000 25.000 * . 25.000 25.000 25.000 25.000 J 25.000 25.000 25.000 ; 25.000 ; 25.000 ; 25.000 25.000 25.000 25.000 25.000 25.000 25.000 : 25.000 25.000 , 25.000 25.000 25.000 25.000 ` 25.000 : 25.000 ' 25.000 25.000 ' _ 25.000 ; 25.000 " 25.000 : 25.000 25.000 25.000 : , 25.000 25.000 25.000 25.000 25.000 25.000 25.000 . 25.000 . 25.000 ; Printing Date: Friday, Aprii 23, 2010 Page 1 of 4 Printing Time: 1:52:49 PM 3M Study: GLP10-01-02 Interim Report 01 Page 130 of 539 ETS Stan V1660305 Project: P:\Lab_lnstrument Data\Stan\Stan Data Fi[es\Projects\fluorochemicals\soil 8atch:s100421 a2 Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample Sample Name Sample ID Vial Position! Data File 64 s100421a064 GLP10-01-01-01-004 Dup DAL DF05 SS SS07 0 0000 Sample Duplicate 44 s 100421 a 65 s100421a065 ' GLP10-01-01-01-004 LMS DAL DF05 SS SS07 0 0000 Lab Matrix Spike 45 s 100421a 66 s100421a066 GLP10-01-01-01-005 DAL DF05 SS SS07 0 0010 46 s 100421a 67 s100421a067 GLP10-01-01-01-005 Dup DAL DF05 SS SS07 0 0010 Sample Duplicate 47 s 100421a 68 s100421a068 ,GLP10-01-01-01-005 LMS DAL DF05 SS SS07 0 0010 Lab Matrix Spike 48 s100421a 69 s100421a069 GLP10-01-01-01-007 DAL DF05 SS SS08 0 0000 49 s100421a 70 s100421a070 GLP10-01-01-01-007 Dup DAL DF05 SS SS08 0 0000 Sample Duplicate 50 s100421a 71 s100421a071 GLP10-01-01-01-007 LMS DAL DF05 SS SS08 0 0000 Lab Matrix Spike 51 s 100421a 72 's100421a072 GLP10-01-01-01-008 DAL DF05 SS SS08 0 0010 52 s100421a 73 s100421a073 GLP10-01-01-01-008 Dup DAL DF05 SS SS08 0 0010 Sample Duplicate 53 s 100421a 74 s100421a074 GLP10-01-01-01-008 LMS DAL DF05 SS SS08 0 0010 Lab Matrix Spike 54 s100421a 75 s100421a075 GLP10-01-01-01-010 DAL DF05 SS SS09 0 0010 55 s 100421a 76 s100421a076 GLP10-01-01-01-010 Dup DAL DF05 SS SS09 0 0010 Sample Duplicate 56 s 100421a 77 s100421a077 GLF>10-01-01-01-010 LMS DAL DF05 SS SS09 0 0010 Lab Matrix Spike 57 s 100421a 78 s100421a078 09004-129 solvent blank 95 s 100421a 79 s100421a079 EC-100415-07 10 ng Extracted Curve Fbint 7 s 100421 a 80 s100421a080 ,09004-129 solvent blank 96 s 100421 a 81 s100421a081 :GLP10-01-01-01-016 DAL DF8CSS SS02 0 0010 58 s100421a 82 s100421a082 .GLP10-01-01-01-016 Dup DAL DF8C SS SS02 0 0010 Sample Duplicate 59 s 100421 a 83 s100421a083 GLP10-01-01-01-016 LMS DAL DF8CSS SS02 0 0010 Lab Matrix Spike 60 s 100421a 84 s100421a084 GLP10-01-01-01-009 DAL DF05 SS SS09 0 0000 61 s 100421a 85 s100421a085 GLP10-01-01-01-009 Dup DAL DF05 SS SS09 0 0000 Sample Duplicate 62 s100421a 86 s100421a086 GLP10-01-01-01-009 LMS DAL DF05 SS SS09 0 0000 Lab Matrix Spike 63 s100421a 87 s100421a087 GLP10-01-01-01-011 DAL DF05 SS SS10 0 0000 64 s100421a 88 s100421a088 'GLP10-01-01-01-011 Dup DAL DF05 SS SS10 0 0000 Sample Duplicate 65 s100421a 89 s100421a089 'GLP10-01-01-01-011 LMS DAL DF05 SS SS10 0 0000 Lab Matrix Spike 66 s100421a 90 s100421a090 iGLPI0-01-01-01-012 DAL DF05 SS SS10 0 0010 67 s100421a 91 s100421a091 'GLP10-01-01-01-012 Dup DAL DF05 SS SS10 0 0010 Sample Duplicate 68 s100421a 92 s100421a092 GLP10-01-01-01-012 LMS DAL DF05 SS SS10 0 0010 Lab Matrix Spike 69 s100421a 93 s100421a093 GLP10-01-01-01-013 DAL DF8CSSSS01 0 0000 70 s 100421a 94 s100421a094 :GLP10-01-01-01-013 Dup DAL DF8C SS SS01 0 0000 Sample Duplicate 71 s100421a 95 s100421a095 :GLP10-01-01-01-013 LMS DAL DF8C SS SS01 0 0000 Lab Matrix Spike 72 s100421a 96 s100421a096 109004-129 solvent blank 96 s100421a 97 s100421a097 EC-100415-05 2.5 ng Extracted Curve Point 5 s100421a 98 ^1004218098 109004-129 solvent blank 97 s100421a 99 ;s100421a099 iGLPI0-01-01-01-014 DAL DF8CSSSS01 0 0010 73 s100421a 100 ,s100421a100 i GLP10-01-01-01-014 Dup DAL DF8C SS SS01 0 0010 Sample Duplicate 74 s100421a 101 s100421a101 iGLPI0-01-01-01-014 LMS DAL DF8CSS SS01 0 0010 Lab Matrix Spike 75 s100421a 102 is100421a102 GLP10-01-01-01-015 DAL DF8C SS SS02 0 0000 76 s100421a 103 s100421a103 GLP10-01-01-01-015 Dup DAL DF8C SS SS02 0 0000 Sample Duplicate 77 s100421a 104 s100421a104 GLP10-01-01-01-015 LMS DAL DF8C SS SS02 0 0000 Lab Matrix Spike 78 s100421a 105 s100421a105 GLP10-01-01-01-020 DAL DF8CSS SS04 0 0000 79 s 100421a 106 s100421a106 GLP10-01-01 -01-020 Dup DAL DF8C SS SS04 0 0000 Sample Duplicate 80 s100421a 107 s100421a107 GLP10-01-01-01-020 LMS DAL DF8C SS SS04 0 0000 Lab Matrix Spike 81 s100421a 108 |s100421a108 GLP10-01-01-01-021 DAL DF8CSS SS04 0 0010 82 s 100421a 109 |Sl00421a109 GLP10-01-01-01-021 Dup DAL DF8CSS SS04 0 0010 Sample Duplicate 83 s100421a 110 s100421a110 IGLPI0-01-01-01-021 LMS DAL DF8CSS SS04 0 0010 Lab Matrix Spike 84 s100421a 111 s100421a111 GLP10-01-01-01-022 DAL DF8CSS SS05 0 0000 85 s100421a 112 s100421a112 GLP10-01-01-01-022 Dup DAL DF8C SS SS05 0 0000 Sample Duplicate 86 s100421a 113 s100421a113 ;GLP10-01-01-01-022 LMS DAL DF8CSS SS05 0 0000 Lab Matrix Spike 87 s100421a 114 s100421a114 09004-129 solvent blank 97 s100421a 115 s 100421a i 15 ;EC-100415-06 5 ng Extracted Curve Rsint 6 s100421a 116 s100421a116 .09004-129 solvent blank 98 s100421a 117 s100421a117 GLP10-01-01-01-028 DAL DF11 SS SS06 0 0010 13 s100421a 118 ,s100421a118 IGLPI0-01-01-01-028 Dup DAL DF11 SS SS06 0 0010 Sample Duplicate 14 s100421a 119 s100421a119 ' GLP10-01-01-01-028 LMS DAL DF11 SS SS06 0 0010 Lab Matrix Spike 15 s 100421a 120 ;s100421a120 GLP10-01-01-01-017 DAL DF8CSS SS03 0 0000 16 s100421a 121 s100421a121 GLP10-01-01-01-017 Dup DAL DF8C SS SS03 0 0000 Sample Duplicate 17 s 100421a 122 s100421a122 GLP10-01-01-01-017 LMS DAL DF8C SS SS03 0 0000 Lab Matrix Spike 18 s100421a 123 s100421a123 GLP10-01-01-01-018 DAL DF8C SS SS03 0 0010 19 s100421a 124 s100421a124 GLP10-01-01-01-018 Dup DAL DF8C SS SS03 0 0010 Sample Duplicate 20 s100421a 125 s100421a125 GLP10-01-01-01-018 LMS DAL DF8C SS SS03 0 0010 Lab Matrix Spike 21 s100421a 126 s100421a126 GLP10-01-01-01-019 DAL DF8CSS SS03 1 0010 ---------------- -- ----- _ 22 -- -- ------ ----- ---------- ---------- ------------- - s100421a --- Printing Date: Friday, April 23, 2010 Page 2 of 4 Inj.Volume (pi) 25.000 , 25.000 25.000 25.000 ' 25.000 - 25.000 25.000 25.000 ; 25.000 ; 25.000 25.000 25.000 . 25.000 ' 25.000 . 25.000 ' 25.000 . 25.000 25.000 ` 25.000 1 25.000 25.000 25.000 : 25.000 . 25.000 > 25.000 < 25.000 j 25.000 \ 25.000 : 25.000 ! 25.000 25.000 25.000 25.000 i 25.000 ; 25.000 25.000 25.000 1 25.000 25.000 25.000 ; 25.000 1 25.000 25.000 25.000 25.000 , 25.000 ! 25.000 25.000 a 25.000 - 25.000 25.000 .1 25.000 , 25.000 25.000 ! 25.000 , 25.000 ; 25.000 25.000 , 25.000 . 25.000 ; 25.000 25.000 , 25.000 ; - ................ .....--V Printing Time: 1:52:50 PM 3M Study: GLP10-01-02 Interim Report 01 Page 131 of 539 ETS Stan V166030S Project: P:\Lab_lnstrument Data\Stan\Stan Data Files\Projects\fluorochemicals\soil Batch:s100421 a2 Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample Sample Name Sample ID 127 s100421a127 GLP10-01-01-01-019 Dup DAL DF8C SS SS03 1 0010 Sample Duplicate 128 s100421a128 'GLP10-01-01-01-019 LMS DAL DF8C SS SS03 1 0010 Lab Matrix Spike 129 s100421a129 iGLPI 0-01-01-01-023 DAL DF8CSS SS05 0 0010 130 s100421a130 GLrn0-01-01-01-023 Dup DAL DF8C SS SS05 0 0010 Sample Duplicate 131 s100421a131 IGLFh0-01-01-01-023 LMS DAL DF8C SS SS05 0 0010 Lab Matrix Spike 132 s100421a132 09004-129 solvent blank 133 's100421a133 i EC-100415-07 10 ng Extracted Curve Paint 134 s100421a134 :09004-129 solvent blank 135 s100421a135 GLP10-01-01-01-024 DAL DF11 SS SS05 0 0000 136 s100421a136 GLP10-01-01-01-024 Dup DAL DF11 SS SS05 0 0000 Sample Duplicate 137 s100421a137 GLP10-01-01-01-024 LMS DAL DF11 SS SS05 0 0000 Lab Matrix Spike 138 s100421a138 GLP10-01-01-01-025 DAL DF11 SS SS05 0 0010 139 s100421a139 GLP10-01-01-01-025 Dup DAL DF11 SSSS05 0 0010 Sample Duplicate 140 s100421a140 GLFh 0-01-01 -01-025 LMS DAL DF11 SS SS05 0 0010 Lab Matrix Spike 141 s100421a141 GLP10-01-01-01-026 DAL DF11 SS SS05 1 0010 142 s100421a142 GLP10-01-01-01-026 Dup DAL DF11 SS SS05 1 0010 Sample Duplicate 143 ;s100421a143 ;GLP10-01-01-01-026 LMS DAL DF11 SS SS05 1 0010 Lab Matrix Spike 144 s100421a144 09004-129 solvent blank 145 Is100421a145 09004-129 solvent blank 146 s100421a146 i09004-129 solvent blank 147 s100421a147 i EC-100415-05 2.5 ng Extracted Curve Fblnt 148 s100421a148 09004-129 solvent blank 149 s100421a149 GLP10-01-01-01-027 DAL DF11 SS SS06 0 0000 150 s100421a150 GLP10-01-01-01-027 Dup DAL DF11 SS SS06 0 0000 Sample Duplicate 151 s100421a151 GLP10-01-01-01-027 LMS DAL DF11 SS SS06 0 0000 Lab Matrix Spike 152 s100421a152 ,GLP10-01-01-01-029 DAL DF11 SS SS07 0 0000 153 s100421a153 GLP10-01-01-01-029 Dup DAL DF11 SS SS07 0 0000 Sample Duplicate 154 s100421a154 IGLP10-01-01-01-029 LMS DAL DF11 SS SS07 0 0000 Lab Matrix Spike 155 s100421a155 |GLP10-01-01-01-030 DAL DF11 SS SS07 0 0010 156 s100421a156 IGLP10-01-01-01-030 Dup DAL DF11 SS SS07 0 0010 Sample Duplicate 157 s100421a157 GLP10-01-01-01-030 LMS DAL DF11 SS SS07 0 0010 Lab Matrix Spike 158 s100421a158 09004-129 solvent blank 159 s100421a159 09004-129 solvent blank 160 s100421a160 09004-129 solvent blank 161 s100421a161 EC-100415-06 5 ng Extracted Curve Paint 162 s100421a162 09004-129 solvent blank 163 s100421a163 IMB--100415-07 Method Blank 5g w / IS for Dilutions 164 s100421a164 MB--100415-08 Method Blank 5g w / IS for Dilutions 165 s100421a165 MB-100415-09 Method Blank 5g w / IS for Dilutions 166 s100421a166 MB--100415-10 Method Blank 5g w / IS for Dilutions 167 s100421a167 IMB--100415-11 Method Blank 5g w / IS for Dilutions 168 s100421a168 LCS-100415-07 DI.X50 300 ng LCS in TCR-842 Dil.x50 169 s100421a169 |LCS-100415-08 Dil.x50 300 ng LCS In TCR-842 Dil.x50 170 s100421a170 LCS-100415-09 Dil.x50 300 ng LCS in TCR-842 Dil.x50 171 s100421a171 GLP10-01-01-01-009 LMS Dil.xSO DAL DF05 SS SS09 0 0000 Lab Matrix Spike Dil.x50 172 s100421a172 GLFM0-01-01-01-011 Dil.x50 DAL DF05 SS SS10 0 0000 Dil.x50 173 s100421a173 GLP10-01-01-01-011 Dup Dil.x50 DAL DF05 SS SS10 0 0000 Sample Duplicate Dil.x50 174 s100421a174 ;GLP10-01-01-01-011 LMS Dil.x50 DAL DF05 SS SS10 0 0000 Lab Matrix Spike Dil.x50 175 ;s100421a175 09004-129 solvent blafik 176 s100421a176 i EC-100415-07 10 ng Extracted Curve Paint 177 s100421a177 109004-129 solvent blank 178 s100421a178 GLP10-01-01-01-012 LMS Dil.x50 DAL DF05 SSSS10 0 0010 Lab Matrix Spike Dil.x50 179 s100421a179 GLP10-01-01-01-013 LMS Dil.x50 DAL DF8CSS SS01 0 0000 Lab Matrix Spike Dil.x50 180 s100421a180 GLP10-01-01 -01-014 DI.X50 DAL DF8C SS SS01 0 0010 Dil.x50 181 s100421a181 GLP10-01-01-01-014 Dup Dil.x50 DAL DF8CSS SS01 0 0010 Sample Duplicate Dil.xSO 182 s100421a182 GLFd0-01-01-01-014 LMS Dil.x50 DAL DF8C SS SS01 0 0010 Lab Matrix Spike Dil.x50 183 s100421a183 GLP10-01-01-01-015 LMS Dil.x50 DAL DF8C SS SS02 0 0000 Lab Matrix Spike Dil.x50 184 s100421a184 GLP10-01-01-01-020 LMS Dil.x50 DAL DF8C SS SS04 0 0000 Lab Matrix Spike Dil.x50 185 s100421a185 09004-129 solvent blank 186 s100421a186 EC-100415-05 2.5 ng Extracted Curve Fbint 187 s100421a187 09004-129 solvent blank 188 s 100421a188 GLP10-01-01-01-021 LMS Dil.x50 DAL DF8CSS SS04 0 0010 Lab Matrix Spike Dil.x50 189 s100421a189 GLP10-01-01-01-022 LMS Dil.x50 DAL DF8CSS SS05 0 0000 Lab Matrix Spike Dil.x50 Via! Position Data File 23 s 100421 a 24 s 100421 a 25 s100421a 26 s100421a 27 s100421a 98 s 100421 a 7 s 100421 a 99 s 100421a 28 s100421a 29 s 100421 a 30 s 100421 a 31 s 100421a 32 s 100421a 33 s 100421a 34 s 100421a 35 s100421a 36 s 100421a 99 s 100421a 99 s 100421 a 100 s 100421 a 5 s100421a 100 s100421a 37 s100421a 38 s100421a 39 s100421a 40 s100421a 41 s100421a 42 s100421a 43 s100421a 44 s100421a 45 s100421a 100 s100421a 100 s100421a 91 s100421a 6 s100421a 91 s100421a 46 s100421a 47 s100421a 48 s100421a 49 s 100421a 50 s100421a 51 s100421a 52 s100421a 53 s100421a 56 s100421a 57 s100421a 58 s100421a 59 s100421a 91 s100421a 7 s100421a 92 s100421a 62 s100421a 65 s100421a 66 s 100421a 67 s100421a 68 s100421a 71 s100421a 74 s 100421a 93 s 100421a 5 s 100421 a 94 s 100421 a 77 s100421a 80 s100421a inj.Volume (pi): 25.000 25.000 , 25.000 25.000 t 25.000 ,. 25.000 ^ 25.000 25.000 : 25.000 25.000 ' 25.000 25.000 25.000 ( 25.000 25.000 25.000 ' 25.000 25.000 : 25.000 25.000 , 25.000 25.000 . 25.000 ! 25.000 25.000 25.000 , 25.000 ' 25.000 . 25.000 , 25.000 ' 25.000 ; 25.000 , 25.000 ( 25.000 t 25.000 : 25.000 ' 25.000 25.000 : 25.000 ' 25.000 25.000 j 25.000 25.000 25.000 . 25.000 f 25.000 ; 25.000 ; 25.000 25.000 ` 25.000 25.000 ; 25.000 ; 25.000 " 25.000 ; 25.000 ; 25.000 25.000 25.000 25.000 . 25.000 _ 25.000 ; 25.000 ] 25.000 - Printing Date: Friday, April 23, 2010 Page 3 of 4 Printing Time: 1:52:50 PM 3M Study: GLP10-01-02 Interim Report 01 Page 132 of 539 ETS Stan V1660305 Project: P :\Lab_lnstm m ent D ata \S tan \S ta n Data Files\Projects\fluorochem icals\soil Batch:s100421 a2 T a b :S a m p le S et:S E T 0 1 A cqM ethod:ets853 2 3 m in Sulfonates Sam ple Sample Name Sample ID Vial Position Data File Inj.Volume (pl)< 190 ,s100421a190 GLP10-01-01-01-028 DI.X50 DAL DF11 SS SS06 0 0010 Dil.x50 81 s100421a 25.000 191 s100421a191 GLP10-01-01-01-028 Dup Dii.x50 DAL DF11 SS SS06 0 0010 Sample Duplicate Dil.x50 82 s100421a 25.000 192 s100421a192 GLP10-01 -01-01 -028 LMS Dil.x50 DAL DF11 SS SS06 0 0010 Lab Matrix Spike Pl.x50 83 s100421a 25.000 193 s100421a193 GLP10-01-01-01-017 DI.X50 DAL DF8C SS SS03 0 0000 Dil.x50 84 s100421a 25.000 194 s100421a194 GLP10-01-01-01-017 Dup Dil.xSO DAL DF8C SS SS03 0 0000 Sample Duplicate Dil.x50 85 s100421a 25.000 195 s100421a195 GLP10-01-01-01-017 LMS Dil.x50 DAL DF8C SS SS03 0 0000 Lab Matrix Spike Dil.x50 86 s100421a 25.000 , 196 s100421a196 GLP10-01-01-01-018 Dil.x50 DAL DF8C SS SS03 0 0010 Dil.x50 87 s100421a 25.000 , 197 s100421a197 GLP10-01-01-01-018 Dup Dil.xSO DAL DF8CSS SS03 0 0010 Sample Duplicate Dil.x50 88 s100421a 25.000 : 198 s100421a198 GLP10-01-01 -01-018 LMS Dil.x50 DAL DF8C SS SS03 0 0010 Lab Matrix Spike Dil.xSO 89 s100421a 25.000 199 s100421a199 09004-129 solvent blank 94 s100421a 25.000 200 s100421a200 EC-100415-06 5 ng Extracted Curve Point 6 s100421a 25.000 201 s100421a201 09004-129 solvent blank 95 s100421a 25.000 . 202 s100421a202 GLP10-01-01-01-019 Dil.x50 DAL DF8CSSSS03 1 0010 Dil.x50 13 s100421a 25.000 203 s100421a203 GLP10-01-01-01-019 Dup Dil.x50 DAL DF8CSS SS03 1 0010 Sample Duplicate Dil.x50 14 s100421a 25.000 204 s100421a204 GLP10-01-01 -01-019 LMS Dil.x50 DAL DF8C SS SS03 1 0010 Lab Matrix Spike Dil.x50 15 s100421a 25.000 , 205 s100421a205 :GLP10-01-01-01-023 Dil.x50 DAL DF8C SS SS05 0 0010 Dil.x50 16 s100421a 25.000 206 s100421a206 !GLP10-01-01-01-023 Dup Dil.x50 DAL DF8CSS SS05 0 0010 Sample Duplicate Dil.xSO 17 s100421a 25.000 - 207 s100421a207 GLP10-01-01-01-023 LMS Dil.x50 DAL DF8C SS SS05 0 0010 Lab Matrix Spike Dil.x50 18 s100421a 25.000 208 |s100421a208 GLP10-01-01-01-024 Dil.x50 DAL DF11 SS SS05 0 0000 Dil.xSO 19 s100421a 25.000 , 209 s100421a209 GLP10-01-01-01-024 Dup Dil.xSO DAL DF11 SS SS05 0 0000 Sample Duplicate Dil.x50 20 s100421a 25.000 210 s100421a210 GLP10-01-01-01-024 LMS Dil.x50 DAL DF11 SS SS05 0 0000 Lab Matrix Spike Dil.x50 21 s100421a 25.000 , 211 s100421a211 .GLP10-01-01-01-025DU50DALDF11 SS SS05 0 0010 Dil.x50 22 s100421a 25.000 ; 212 s100421a212 IGLP10-01-01-01-025 Dup Dil.xSO DAL DF11 SS SS05 0 0010 Sample Duplicate Dil.x50 23 s 100421 a 25.000 213 ,s100421a213 |GLP10-01-01-01-025 LMS Dil.x50 DAL DF11 SS SS05 0 0010 Lab Matrix Spike Dil.x50 24 s100421a 25.000 214 is100421a214 09004-129 solvent blank 95 s 100421 a 25.000 215 s100421a215 |EC-100415-07 10 ng Extracted Curve Paint 7 s 100421 a 25.000 216 s100421a216 ;09004-129 solvent blank 217 s100421a217 GLP10-01-01-01-026 Dil.x50 DAL DF11 SSSS05 1 0010 Dil.x50 96 s 100421a 25.000 25 s 100421a 25.000 ' 218 s100421a218 GLP10-01-01-01-026 Dup Dil.x50 DAL DF11 SSSS051 0010 Sample Duplicate Dl.x50 26 s100421a 25.000 219 s100421a219 GLP10-01-01-01-026 LMS Dil.x50 DAL DF11 SS SS05 1 0010 Lab Matrix Spike Dil.x50 27 s100421a 25.000 220 s100421a220 GLP10-01-01-01-027 Dil.x50 DAL DF11 SS SS06 0 0000 Dil.xSO 64 s100421a 25.000 221 s100421a221 GLF>10-01-01-01-027 Dup Dil.x50 DAL DF11 SS SS06 0 0000 Sample Duplicate Dil.x50 69 s100421a 25.000 "" 222 s100421a222 GLP10-01-01-01-027 LMS Dil.x50 DAL DF11 SS SS06 0 0000 Lab Matrix Spike Dil.x50 70 s100421a 25.000 , 223 s100421a223 iGLFM0-01-01-01-029 Dil.x50 DAL DF11 SS SS07 0 0000 Dil.x50 72 s100421a 25.000 ' 224 s100421a224 GLP10-01-01-01-029 Dup Dil.x50 DAL DF11 SS SS07 0 0000 Sample Duplicate Dil.x50 73 s100421a 25.000 225 is100421a225 IGLPI0-01-01-01-029 LMS Dil.x50 DAL DF11 SS SS07 0 0000 Lab Matrix Spike Dil.x50 75 s100421a 25.000 226 s100421a226 GLP10-01-01-01-030 Q1.X50 DAL DF11 SS SS07 0 0010 Dil.x50 76 s100421a 25.000 227 s100421a227 l GLF>10-01-01 -01-030 Dup Dil.x50 DAL DF11 SS SS07 0 0010 Sample Duplicate Dl.x50 78 s100421a 25.000 : 228 s100421a228 |GLP10-01-01-01-030 LMS Dil.x50 DAL DF11 SS SS07 0 0010 Lab Matrix Spike Dil.x50 79 s100421a 25.000 229 s100421a229 109004-129 solvent blank 96 s100421a 25.000 230 s100421a230 1EC-100415-05 2.5 ng Extracted Curve Paint 5 s100421a 25.000 231 s100421a231 109004-129 solvent blank 97 s100421a 25.000 232 s100421a232 09004-129 solvent blank 98 s100421a 25.000 Printing Date: Friday, April 23, 2010 Printing Time: 1:52:50 PM 3M Study: GLP10-01-02 Interim Report 01 Page 4 of 4 Page 133 of 539 Stan V1660305 *3M Environmental Lab * 'i Results Name s10042la.rdb Printing Printing 1r * 3 i - i t s m R e p o rt 01 ,1 28, 2010 Page 1 of 406 Page 134 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 ril 28 2010 Page 2 of 406 Page 135 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Interim Report 01 Page 136 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S B S . .. In te rim R e p o rt 01 1 28, 2010 Page 4 of 406 Page 137 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3P r i n t i n g D M S tff0 y nG L cP l O O l O 2 ` ^ P rin tin g T ^ ls m ^ d y fO O - ^010 Page 5 of 406 Page 138 of 539 Page 139 o f 539 SS 55 ^a Ups il Sc5 5.W -W S> to CD to o p-> o p> IQ o o cn S 5. & a Results Name: s!00421a. Stan V1660305 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ? 3InMte rsriimm Report 0 to I-0 2 1 28 2010 Page 7 of 406 Page 140 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date :,Wedn^dayw April 28, 2010 Printing ^ P -0TM 2 In te rim R e p o rt 01 Page 8 of 406 9 P age 141 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S B 0 2? t ? e f f i , o ` 2` In te rim R e p o rt 01 2010 Page 9 of 406 Page 142 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g 3D M t f f 3 y n@L<P ^ 0 ' 0 l 0 2 ^ 28 2010 P rin tin g R epO tfolP 5 Page 10 of 406 Page 143 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing S tu S ^ e L P lO - O l- O ^ 1 28' 2010 Printing T ^n je n m R e p o n o l Page 11 f 406 Page 144 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing T ^ J 28 ' 2010 Page 12 of 406 Page 145 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S t7 S $ n L<P l 0 - 0 l - 0 i * 28 , 2010 Printing Ti me s 7 ^ 3 1 : l i n n 0- 01In te r im R e p o rt Page 13 of 406 Page 146 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing D3 Printing Interim Report 01 il 28 2010 Page 14 of 406 Page 147 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g S tM ? G L p i0 -C l-C f:i1 P r m t m g T j f f l l h m| R e ^ C I - ' 201 Page 15 of 406 Page 148 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g S tM ^ e p Iti'- O l- W 1 28' 2010 P r i n t i n g T ^ e : . ^ R e p b f ^ O t 4* Page 16 of 406 Page 149 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 3 1 28D M S tffS y iG P l !0 - 0 t - 0 2 ' 2010 P rin tin g o f" Page 17 of 406 Page 150 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 5 W & W8 5 8 S u o o i1 2 1 ' 2" ` D In te rim R e p o rt 01 Page 18 of 406 Page 151 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P r i n t i n g 3 1D M s tH 8 y n G L<P l 0 o 1 - 0 2 2 8 , 2010 P rin tin g Page 19 of 406 Page 152 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb s a S 'W a f f t P 1 a1' 2" ` In te rim R eport 01 Page 20 of 406 Page 153 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing tn tlrim R eport 0 1 2010 Page 21 of 406 Page 154 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S tU d y nS t ^ & - 0 l - 0 2 1 28 ' 2010 Printing T im e s 7 iy 2 : L ^ ^ /0Interim R eport 0 1 Page 22 of 406 Page 155 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M 1g t7 9 y :nG.<P ^ 0 , 0 l 0 2 28 2010 P rin tin g Page 23 of 406 Page 156 of 539 *Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing Printing In te rim R e p o rt 01 1 28 2010 Page 24 of 406 Page 157 of 539 *Stan V1660305 *3M Environmental Lab Results Name: s!0042la.rdb S < o s ` 2 ` - 2010 Tnterim R e p o rt O f Page 25 of 406 Page 158 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S tU p l ,, In te rim R e p o rt 01 d.1 28 2 0 1 0 Page 26 of 406 Page 159 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 27 of 406 Page 160 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 28 of 406 Page 161 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g 3 ^D M S t M ^ E P m o t 1 28' 2010 P rin tin g T ^ m O l " Page 29 of 406 Page 162 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Page 163 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 31 of 406 Page 164 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D a te S twd d : iG ! cP i 0 o 1 - O 4 10-0P r i n t i n g T i M ^ 7 ^ 5 2 : ^ ^ " In te rim R eport O f Page 32 of 406 Page 165 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 1 28 2 0 1 0 j s S S jS G jp fc o W o i Interim Report 01 Page 33 of 406 Page 166 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D Printing TS i Interim Report 01 2010 21 Page 34 of 406 Page 167 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 K .. Interim Report 01 1 28, 2010 Page 35 of 406 Page 168 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing TiInmate:r.im7 Report 0J1AM 28 ' 2010 Page 36 of 406 Page 169 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing interim7ReporfQ 1- 0 2 1 2 8 , 2 0 1 0 Page 37 of 406 Page 17Q of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ^TamMes;t U d y ^ :2L2P^iAPM- P l - P ^ 1 28' 2010 interim ReporfPI Page 38 of 406 Page 171 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb S In te rim R e p o rt 01 28' 2010 Page 39 of 406 Page 172 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb E S p rtm t j o 1 * 1 2 > ' 2010 Interim Report 01 Page 40 of 406 Page 173 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report OT 2010 Page 41 of 406 Page 174 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb p r in tin g S tU ^ G - P O - O lO S 1 28 ' 2010 Printing T ^ m RepOrt 0 1 Page 42 of 406 Page 175 of 539 Stan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P rin tin g P rin tin g RepOS 0 1 28' 2010 Page 43 o f 406 Page 176 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b 01P r in tin g D ^M StflaynG f.P l0 -01 -02:1 28 ' 2010 P rin tin g Page 44 o f 406 Page 177 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P rin tin g $63 P r i n t i n g T im e :. 7:_3!2:3 inte rim R epoi ,_0^P02^ ^ ' 2010 Page 45 of 406 Page 178 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing r-o l- 0 2 1 28 2 0 1 0 Page 46 of 406 Page 179 of 539 Stan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P rin tin g P r in tin g S t B a P l 0 , - 0 l 0 2 :1 28' 2010 Page 47 o f 406 Page 180 of 5 t9 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S 'S s iw iw In te rim R eport 0 ! 1 2010 Page 48 of 406 Page 181 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing -0 1 5 2 1 28 2 0 1 0 Interim Report 0 Page 49 of 406 Page 182 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 M Interim R eport OT^ 1 28 2010 Page 50 of 406 Page 183 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ____ s t i __________ In te rim R e p o rt 01 Ll 28 2 0 1 0 Page 51 of 406 Page 184 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 1 28, 2010 Page 52 of 406 Page 185 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S H S t S d S f i V - 0 2 1 21 In te rim R e p o rt 01 2010 Page 53 of 406 Page 186 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing T im e :. 7 1432 : 4 ji In te rim R epo rt 0 1 1 28 2010 Page 54 of 406 Page 187 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S B G . In te rim R e p o rt 01 1 28, 2010 Page 55 of 406 Page 188 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 56 of 406 Page 189 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 57 of 406 Page 190 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 58 of 406 Page 191 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing 2010 Page 59 of 406 Page 192 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M stU Time~ Yj3'2 :. rnterim R epoi il 28, 2010 Page 60 of 406 Page 193 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb P r i n t i n g D 3 m S tB 9 y n GLcP l 0 - 0 l I- 5 i 1 2 8 ' 2 0 1 0 P rin tin g R lp O rt 0 1 Page 61 of 406 Page 194 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 62 of 406 Page 195 of 539 Stan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in t in g D3M P rin tin g * 3 ^ RSpOfOP" ^ 28' 2010 Page 63 o f 406 Page 196 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3P r i n t i n g D M P r i n t i n g T im e 7 ^ 3 2 :5 8 -10Interim R e p o rt O r ^010 Page 64 of 406 Page 197 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M 1S t H a ^ G l P l O - O l O r i 28' 2010 P rin tin g ^ O ftO r Page 65 of 406 Page 198 of 539 *Stan V1660305 *3M Environmental Lab to to o I-* o d pi IQ 0 a tr cn co CD Results Name: sl0042la. Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1 28Printing 3 M s t a a y e G L P & o l - s 2010 t n t ir i m R e p o rt Cn Page 67 of 406 Page 2CC of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ..... In te rim R e p o rt 01 2010 " Page 68 of 406 Page 201 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing S s P l O i o i 1 21 2 0 1 0 In te rim R e p o rt 01 Page 69 of 406 Page 202 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing 3 M s t S a y ^ t P T O - o T o ? 1 28 in te rim R eport O T1 2010 Page 70 of 406 Page 203 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb L1 2010P r i n t i n g D 3 M s t J d y i'G e p 1 0 ` 0 lJ O 2 2 8 ' 7 7P r i n t i n g T |n e r |m Re?lOft 0 ? M Page 71 of 406 Page 204 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing ? 3 M ? t ? S f ? L .. In te rim R e p o rt 01 il 28 2010 Page 72 of 406 Page 205 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Interim Report 01 Page 73 of 406 Page 206 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Time 7-^3 interim R eport 01^ il 28 2010 Page 74 of 406 Page 207 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing S M s t w . , . ^ p - p l - ^ 1 28 2010 Interim R epo r Page 75 of 406 Page 208 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing Time:. 7 -33 :14-.AM Interim R eporT 0 T 28 2010 Page 76 of 406 Page 209 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing s t U d ^ L P T O o i o ? 1 28 fnierim R e p o rfo f" 2010 Page 77 of 406 Page 210 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 9P r i n t i n Printing 28S tU d J g G R eport L0P1l O 'O I^ 1 ' 201 Page 78 of 406 Page 211 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing _ _ tt= fr" T V 3 3 -:T 8 In te rim R e p o rt 01 1 28, 2010 Page 79 of 406 Page 212 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing StM 'G E P lfto l O ? 1 28' 2010 Printing T m tlrim R e p o rfO ^ Pa9e 80 of 406 Page 213 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing .W ed: nterim Report 01 il 28 2010 Page 81 of 406 Page 214 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3 M printing Tfnterim7R e p o n O ^ 28' 2010 Page 82 of 406 Page 215 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing d3 M Printing 1 28 2010 Page 83 of 406 Page 216 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing 2010 Page 84 of 406 Page 217 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1 28 2 0 1 0 Printing 3 M S i W M Interim Report 01 Page 85 of 406 Page 218 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D Printing T3 M Interim Report 01 2010 21 Page 86 of 406 Page 219 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 Interim Report 01 il 28 2 0 1 0 Page 87 of 406 Page 220 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing D3 M StM ' G EPIfro f W 1 28' 2010 Printing T in t l- m R lp O r f o r 1 Page 88 f 406 Page 221 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 89 of 406 Page 222 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 2010s t a a y n g L P i o - o i - o : 2 1 2 8 ' P rm tm g Ttf l | J R | ^ 0 1 Page 90 of 406 Page 223 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M S tffS y iG P TO- 0 1 - 0 2 1 28' 2010 Printing Time:. 7^33:37^.2^ Interim R eport 0 1 Page 91 of 406 Page 224 of 539 i?s M- M- 33 rr rr S' 5' U3 IQ -3 O fl><! ! cd^FS* "crS ^.ortn 5 tg f V 0 inf>l Kt> to O "0 i* Q) CQ ocr> fl> K) hcno cn co CD l & Results Name: sl00421a. Stan V1660305 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S t M rG E P 1 :0 - 0 i -- 0 2 1 28 ' 2010 Printing Time:. 7f33:4p AM Interim R e p o rtO l Page 93 of 406 Page 226 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S s t U S S f i i & f w 1 21 In te rim R e p o rt 01 2010 Page 94 of 406 Page 227 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g ^ 1^ M S t U d y ^ G E P lO - O lO 28' 2010 P r in tin g T jto g rtm R e p c fftt" Page 95 of 406 Page 228 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M ? 1S t U a y ^ t P l O - O l O 28' 2010 P r in tin g T fo g fim R e p o tf 0 1 Page 96 of 406 Page 229 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing m p o in te rim R epoi ^ ^ ' 2010 Page 97 of 406 Page 230 of 539 n 33 rr rt si m o-- -w o to 03 to o O L0>a (5 kCOO 0Ml > OCPl Page 231 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 99 of 406 Page 232 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StffSy^ tpTO -OTO?1 28 ' 2010 Printing TiInmete:r.im7fR3e3p:o4r9t ,,OATM Page 100 of 406 Page 233 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M St y ng E P l:0'-0 t -- 0 2 1 28 ' 2010 Printing TiInmete:r.im7iR3e3p:boLrt)0rt1AM Page 101 of 406 Page 234 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 1 28S t0 a y ne f.P lO -O lE O '2 ' 2010 P rin tin g T ^ m o1 Page 102 of 406 Page 235 of 539 to 00 to o o fu o ui o "Q0) (Q fl> o cn K) CO O) cn CO CD s h-* S a Results Name: sl00421a. Stan V1660305 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Staat e P lO -o l-O ? 1 28 ' 2010 Printing Time:. 7 ^ 3 : 5 4 _a M Interim Report 01 Page 104 of 406 Page 237 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S tU d yirG P l ^ - 0 l- 0 2 '1 28 ' 2010 printing T jn t|fim 7 R e p b f f o ^ - Page 105 of 406 Page 238 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 1 2010P r i n t i n g D a ^ S tffS y n t P l :0 '- 0 lS 0 2 2 8 ' P rin tin g 1R e P O tf O f Page 106 of 406 Page 239 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M S t M ^ E P l O - O l W 1 28- 2010 P rin tin g R e ^r Page 107 of 406 Page 240 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 1 28S ttta y n G L P l 0 - 0 l - O 2 ' 2010 P r in t in g T ^ m RepOW 0 1 Page 108 of 406 Page 241 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing Tim e s v ^ S ^ o ^ i 0 - in te rim R epo rt 01 1 28 ' 2010 Page 109 of 406 Page 242 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb 1 28Printing 3 M s t M ' G L P l O . o t - W 2010 Printing 1fH tlr im R e p o r f O r Page 110 of 406 Page 243 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb ^ 1 28 2P r i n t i n g ^ M S t i T ^ ^ ^ L P l O 'O l - O 1 P rin tin g T ^ m illp .P P o O " Page 111 o f 406 p a g e 244 Qf 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g P rin tin g ^ ^ * 1 ^ 0 1 " 2 8 ' 2010 Page 112 of 406 Page 245 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing In te rim R e p o rt 01 2010 Page 113 of 406 Page 246 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 3M Printing In te rim R e p o rt OT zs 2010 Page 114 of 406 Page 247 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3P r i n t i n g D M S tu d P r in t in g T i m Stu^ ^ '4 In te rim R e p o rt 01 ^ 2i* , 2010 Page 115 o f 406 Page 248 o f 539 ^a |,- M "O It K3 00 (O O M O o 0> IQ 01 o ho CO o cn co CD Stan V1660305 *3M Environmental Lab Results Name: sl0042la. *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g 3 ^D M S tU d y ^ G E P lO -O l 1 2 8 ' 2010 P rin tin g R lfa ^ O -T Page 117 of 406 Page 250 bf 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing 3 M s t M l M O o T - O ? 1 28 F riilrim R e p o rt 0 T 1 2010 Page 118 of 40G Page 251 of 539 to 00 to o h-* o o &> LQ H 1-* VO 0 o cn fl> ho cn ho o cn co CD Results Name: sl00421a. *Stan V166030S a Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Interim Repo l-01021 28, 2010 Page 120 of 406 Page 253 of 539 Stan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P rin tin g P rin tin g T ^M eim ^eP oV oF ` 28 ' 2010 Page 121 o f 406 Page 254 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1 28Printing 3 M s t ^ G L P l & o l - W *1in te rim R e p O rfO T 2010 Page 122 of 406 Page 255 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 11 28 2010 Page 123 of 406 Page 256 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 M s t U d ^ S L p T O o f - O ? 1 28 F n lirim R e p o rfO T ^ 2010 Page 125 of 406 Page 258 o f 539 Page 259 o f 539 33 Srt' Srt' H- H* & to 00 to o M O 0 CD IQ rt> to CTi 0 fh A o o\ OJ 2 I 3 E & Results Name: sl00421a. Stan V1660305 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing 3 S Interim Report 01 2010 2* Page 127 of 406 Page 260 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Time i 7x34 :. m t:ee rlm R e p o rt 0 2 8 , 2010 Page 128 of 406 Page 261 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing TI.nitmeer;im7xR3e4p:o2r,t90.1) ;dl 28 2010 Page 129 of 406 Page 262 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D aM Printing Interim Report Of ^8, ^010 Page 130 of 406 Page 263 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date W e d n e s d a y ^ p r i l 28, 2010 Printing Tinte i ^ i r ^ 10-01"02 Interim Report 01 Page 131 of 406 Page 264 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D< Printing T; 28- 2010 Page 132 of 406 Page 265 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g D a ^ P r i n t i n g T f n t|r ^ m 'R | p 0 r t 1O r 2 8 ' 2010 Page 133 of 406 Page 266 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing S tM ^ E p I l- O t W 1 28 2010 Printing Time:. 7.^34 :3b.AM Interim R e p o rfO l Page 134 of 406 Page 267 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g ^ M S t l M IG e P l0 - O lJ 0 2 i l 28- 2010 P rin tin g T ^ ^ V e ^ O r Page 135 of 406 Page 268 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing T3imMe :. 7:_$4:3 a JAM Interim R e p o rt 0 1 2010 28 Page 136 of 406 Page 269 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M S tU S y ^ t P lO - O l- O ? 1 28 ' 2010 Printing Time:. 7^4:3?-.AM Interim R epo rt 0 1 Page 137 of 406 Page 270 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing Time:. 7,^3'4:4i-AM Interim R eporfO T 28 ' 2010 Page 138 of 406 Page 271 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Print in9 printing ^ n jlr im R e p o r t 0 1 28 ' 2010 Page 139 of 406 Page 272 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing a n In te rim R e p o rt 01 il 28 2010 Page 140 of 406 Page 273 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim R eport 0' 28 2010 Page 141 of 406 Page 274 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing G Lp ' In te rim R e p o rt 01 il 2 8 , 2 0 1 0 Page 142 of 406 Page 275 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M interim RepoifOT4 28 2010 Page 143 of 406 Page 276 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M ntlrim ReporfOT* 1 28 2 0 1 0 Page 144 of 406 Page 277 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M s tS C e ip T & o T O ? 1 28 2010 Interim Report OT1 Page.145 of 406 Page 278 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M interim ReporfOT*1 1 28 2010 Page 146 of 406 Page 279 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 147 of 406 Page 280 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M ? 1S t l M 'G E P l O - O l O 28- 2010 P rin tin g 0 fM Page 148 of 406 Page 281 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing in U rim 7R e p o rt 01 1 28, 2010 Page 149 of 406 Page 282 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3 M S tU d y i l G E P l0 i Q f - Q 2 '1' 28' 2010 Printing T|n 7f | t;im R | 4po5r i!Q^ 1 Page 150 of 406 Page 283 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 3 1 28D M g tU 0 y n G t.cP ^ O o l O 2 ' 2010 7P r i n t i n g T 3 fteH m R e i* 0 r ? O r Page 151 of 406 Page 284 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 28 2 0 1 0 Printing ?3 M St4wi^ G L dF i]0 1o1?ori 1 Interim Report 01 Page 152 of 406 Page 285 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing D 3M stS C G LP l& ot-O ? 1 T 28 2010 Interim ReporfOl Page 153 of 406 Page 286 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3M s t ^ u _ nterim Report*0 1 ;il 28 2 0 1 0 Page 154 of 406 Page 287 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ' Interim Report 01 2010 Page 155 of 406 Page 288 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb SB In te rim R eport 01 " 2010 Page 156 of 406 Page 289 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 157 of 406 Page 290 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 158 of 406 Page 291 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 1 28, 2010 Page 159 of 406 Page 292 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing interim Report 01 2010 21 Page 160 of 406 Page 293 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 161 of 406 Page 294 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing Printing Page 162 of 406 Page 295 of 539 *Stan VT660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing S tU S y 'G t P f O - o f - O t 1 28' 2010 Printing Time:. 7i3'5:r7rtAM Interim Report O f Page 163 of 406 Page 296 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing a ? t r n Interim Report 01 i.1 28 2010 Page 164 of 406 Page 297 of 539 Stan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 la .rd b P r in t in g DgMStUay^GEPlO-OlIO? 1 28 2010 P rin tin g ft p O ifo r Page 165 o f 406 Page 298 of 539 *S ta n V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in t in g D3 M S tU d y^G P p lO -O lW 1 28 ' 2010 P rin tin g ^ ^ ^ 0 ^ 0 1 " Page 166 o f 406 Page 299 of 539 *Stan V1660305 *3M E n viro n m e n ta l Lab R e su lts Name: s l0 0 4 2 1 a .rd b P rin tin g ^M StU &y^LPlO -O lJO ^ 1 28' 2010 P rin tin g Page 167 o f 406 Page 300 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing D T3 M stuay:" S f.p i 1-0 1 -8 2 1 28 2010 In te rim R epoifcC Page 168 of 406 Page 301 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing D03M tH8yn@L<P lO -O l0 2 ^ 28, 2010 Printing Tiinmete:r.im7iR3e5p:2ojrtTr0A1M Page 169 of 406 Page 302 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g DaM P r i n t i n g Tim e Interim R eport 0 1 1 28' 2010 " Page 170 of 406 Page 303 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S t U d y ^ G E P lO - O l- O ^ 1 2 8 ' 2010 7printing T ^ g r i m R e p b ? ^ 0 ^ ^ Page 171 of 406 Page 304 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 M S tJ _ _*-01-02 1 28 2 0 1 0 fn ilrim R e p o rf 0' Page 172 of 406 Page 305 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3 M Stujy?IG P p1fi'o1102i' 1 28 ' 2010 Printing TimeSiud^ 5 : 3r (^j01r fnterim ReporTOI Page 173 of 406 Page 306 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M ?S tM 'G E P T O - O t - O 1 28' 2010 P rin tin g T ^ m R e p O tfo -T Page 174 of 406 Page 307 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 3 1 28D M S tH a y n t P l O - O l 0 i '2 ' 2010 P r in t in g T j ^ m R #pO rf O f" Page 175 of 406 Page 308 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3 M Stl M ^ E P lO -O lO ? 1 28 ' 2010 Printing TiInmete:r.im7iR3e5p:o3r.t70,,1AM Page 176 of 406 Page 309 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StM rGp1:0'-O t-021 28 ' 2010 Printing TiInmete:r.im7iR3e5p:o3rt80rt1AM Page 177 of 40G Page 310 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1 28Printing 3 M S t M S L P l f e o T O i ? 1F n ilr im R e p o rt O T 2010 Page 178 of 406 Page 311 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D&M 3t70$nG4.cP ^O-Ol-O21 28, 2010 Printing T iImnteerim7 -R3e5p:o4r1t 0.110- Page 179 of 406 Page 312 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D. Printing Ti s w j i a m o f i a 1 In te rim R e p o rt 01 2010 Page 180 of 406 Page 313 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 181 of 406 Page 314 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 182 of 406 Page 315 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 K .... In te rim R e p o rt 01 2010 Page 183 of 406 Page 316 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a . rdb P r in t in g D3 M S tlM iG P 1 0 -0 1 -0 2 1 28' 2010 P rin tin g T ^ m R ^ p O T fo r Page 184 o f 406 Page 317 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing n e rim i R e p o rt 01 il 28 2010 Page 185 of 406 Page 318 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing rim e 7 ii'5 :5 Interim Repoi 1 28 2010 Page 186 of 406 Page 319 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in t in g D3M P rin tin g Rep^vTOr- 1 28 ' 2010 Page 187 o f 406 Page 320 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 188 of 406 Page 321 of 539 *S ta n V1660305 * 3M E nviro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g D&M St08ynGL<P ^O O l-O 21 28 , 2010 P rin tin g T jfle H m 'fe fO r Page 189 o f 406 Page 322 of 539 *S tan V1660305 * 3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in tin g D3 M S t M 'TgEPlO-Ol-O^ 1 28 ' 2010 P rin tin g Re!pb!rt*o1M Page 190 o f 406 Page 323 bf 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StS8yj G ]P 1-0t-021 28' 2010 Printing TiInmete:r.im7iR3e5p:o5r9t 0rtA1M Page 191 of 406 Page 324 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in tin g D&M St78ynG0:P^O-Ol-021 28 ' 2010 P r in tin g3 TiImnteersim7 rR3e6p:o0r1t 0/11O- Page 192 of 406 Page 325 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 M s . U & m , " ' In te rim R e p o rt 01 1 21 2010 Page 193 of 406 Page 326 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P r in tin g D3M S tu 5 y '6 P j0 -O J -0 2 :L 28' 2010 P r in tin g Time Interim Report 0 1 Page 194 of 406 Page 327 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing In te rim R e p o rt 01 1 28 2 0 1 0 Page 195 of 406 Page 328 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 196 of 406 Page 329 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing F rrU fim R e p o rt OT" 2010 Page 197 of 406 Page 330 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. M l l r i m Re6p'or? O r 4 28- 2010 page 198 of 406 Page 331 o f 539 Stan V1660305 *3M Environmental Lab ?3 Piii 1S' S' J r s i p M ; 1!iq iq ' i V !i si! 'si"::'* s k r *!i s s I 5 s 5: ? ? ? i s U-m| o S3 sss >-rs 3> us < "i-""y si s s P - c = " is *5 *!,, 9 ss " ss" ?? g ,, e H H Is f '! HligMiingnililNI d iQ "0 Q) CQ fl> CO CO K) cn CO CD |S P I" r r isii sspss s s ? ??is H ih Isfss1 Intensity, cps Results Name: sl00421a. *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing D3M Printing T im e S t 7;.y ,6 Interim R eport 0 1 2i*' 2010 Page 200 of 406 Page 333 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M S tU 8 y jlG E P l:0 '- 0 l -- 0 2 1 28 ' 2010 Printing Time:. 7i56:r3rtAM Interim R epo rt 0 1 Page 201 of 406 Page 334 of 539 *S ta n V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in tin g D3 M P rin tin g T jntgrsm R epol^^ 28' 2010 Page 202 o f 406 Page 335 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 1 28, 2010 Page 203 of 406 Page 336 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D 1 28 1 0Printing 3M T s t & Lp O -o l :l 0 1tn U r im Ffe p 'o rt 2010 Page 204 of 406 Page 337 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 38 S i M p f o o W i 1 2 * ' 2 " ` Tnterim R e p o rt 01 Page 20S of 406 Page 338 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Wedn Printing in iirim 7Report 01 1 28, 2010 Page 206 of 406 Page 339 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 207 of 406 Page 340 of 539 S'S' Ji I s I to oo M o H O >0 0 IQ a to o o a cr Stan V1660305 Results Name: sl00421a. Page 341 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 209 of 406 Page 342 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Report 01 il 28, 2010 Page 210 of 406 Page 343 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S t l d y fG L P ^O o l - O ^ ^ Printing Tim e l & Z i Z j J 0 inte rim R eport 0 1 2 010 Page 211 of 406 Page 344 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 28 2 0 1 0 Page 212 of 406 Page 345 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1 28s tffd y l'p e p i & o t - o ? 2010 Printing 01fn ie rlm R e p o lf , Page 213 of 406 Page 346 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Page 347 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P rin tin g 3 ? 1D M S t U a y G p T O - O lO 28' 2010 P rin tin g Of Page 215 of 406 Page 348 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing S tH 0 ? nS i .`P lO - O lI O 2 1 28 ' 2010 0 1p r i n t i n g ^ m r i m R e p o r t Page 216 of 406 Page 349 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Date: Wednesday, April 28 Printing T3 M S tu d y :6GL p i Q i0 1 -0 2 Interim Report 01 2010 Page 217 of 406 Page 350 of 539 *Stan V1660305 *3M Environmental Lab Results Name: s!0042la.rdb P r in t in g D a te : W ednesday, A p r i l 28 , 2010 p r i n t i n g t 3M 6S tu d y : G i f 1;0- 01-02 Interim Report 01 Page 218 o f 406 Page 351 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28, 2010 Printing T3 M $ t u d y j (G L P 1 B -P 1 -J0 2 ' Interim Report 01 Page 219 of 406 Page 352 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 2 0 1 0 Printing t 3M S tu|y:6GtFl0-O1-PO2 Interim Report 01 Page 220 of 406 Page 353 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 21 Page 221 of 406 Page 354 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing D Printing T s s t i s s i i & i f In te rim R e p o rt 01 12* 2010 Page 222 of 406 Page 355 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 2 0 1 0 Printing t 3 M StUdy^LP10O 1-O 2 Interim Report 01 Page 223 of 406 Page 356 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report P1 2010 Page 224 of 406 Page 357 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing S s t In te rim R e p o rt 01 2010 12* Page 225 of 406 Page 358 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Date: Wednesday, April 28 2010 Printing T3 M S^ d& f ^ t ^ ^ -01-02 Interim Report 01 Page 226 of 406 Page 359 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 28 2 0 1 0 Page 227 of 406 Page 360 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 2 0 1 0 Printing t 3M Study:6G tf1Q -01-02 Interim Report 01 Page 228 of 406 Page 361 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 LI 28 2010 Page 229 of 406 Page 362 of 539 Stari V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, Aprriii 28 Printing T3' M S tu d y jiG L P ^ ^ l - 10 2 Interim Report 01 2010 Page 230 of 406 Page 363 of 539 Stan V16603 05 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 il 28 2010 Page 231 of 406 Page 364 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 2010Printing Date: Wednesday, April 28 Printing t 3 M Study:GLPlQ-01-02 Interim Report 01 Page 232 of 406 Page 365 of 539 *Stan V1660305 *3M Environmental Lab Results Name; sl00421a.rdb Printing Printing iterim Report 01 2010 Page 233 of 406 Page 366 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday. April 28, 2010 Printing t S M :S tV d y 7 In te rim R e p o rt 01 Page 234 of 406 Page 367 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28, 2010 Printing iQ feS^ ^ ^ bP1 0 0 1 "02 Interim Report 01 Page 235 of 406 Page 368 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 2010 Printing T3 M StudW'iGLP1,0-P 1-02 Interim Report 01 Page 236 of 406 Page 369 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 237 of 406 Page 370 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28, 2010 Print ing T3 M S tMd y J:'^L p i .P p i ~P2 In te rim R e p o rt 01 Page 238 of 406 Page 371 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ___ r^r-Tl'In te rim R e p o rt 01 ;il 28, 2010 Page 239 of 406 Page 372 of 539 Stan V2660305 *3M Environmental Lab Results Name: sl00421a.rdb SI In te rim R e p o rt 01 2010 Page 240 of 406 Page 373 of 539 Stan V1660305 * 3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in tin g Date: Wednesday, A p r i l 28 2 0 1 0 P r in tin g t 3M Stydy7GiP1i0-01-02 Interim Report 01 Page 241 o f 406 Page 374 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 B s t ; 3 5 ; s f p i i , o t 5 f i 1 21 In te rim R e p o rt 01 2010 Page 242 of 406 Page 375 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Page 376 o f 539 T> *0 NJ oo fO o M O *0 V IQ n> to "0 Q) CQ fl> CO -s] "vl o A o U\ cn CO CD u> 3 E I Results Name: sl00421a. Stan V1660305 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing l Wedn Printing Interim Report 01 il 28 2 0 1 0 Page 245 of 406 Page 378 of 539 Stan V1660305 2. $ h-> I a tr Results Name: sl00421a. Stan V1660305 *3M Environmental Lab iH,e i | ! .tm m m tm h -5 1 J ; m m I'-ri lilt i=-...--=l=IN '"p 9 55=eE : f 11 1 Isiiiiiiillllllllllllsg ii'f pijjjj, EHlt si'tisi P f W i i - SIB ".j r lift r!$ *i'n|*ipsf^Ii esifs IsfsS1 | Results Name: sl00421a. ff3 US i0o) "O ^ Q) o C o> CO 00 en co CD a * *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing _ _ S t _ ' Interim ' R eport" 01 il 28 2010 Page 249 of 406 Page 382 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 250 of 406 Page 383 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing W edn Printing Interim Report 01 il 2 8 , 2010 Page 251 of 406 Page 384 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printin9 n n m g In te rim R e p o rt OT" 1 28' 2010 Page 252 of 406 Page 385 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 2 0 1 0 Printing In te rim R e p o rt 01 Page 253 of 406 Page 386 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing InTerim^epor^O ^ 28 2010 Page 254 of 406 Page 387 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 1 28, 2010 Page 255 of 406 Page 388 of 539 Stan V166030S *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 0 2 1 28 2010 Page 256 of 406 Page 389 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 Printing A M S tu d y i G L P 1 R - P 1 -0 2 In te rim R e p o rt 01 2010 Page 257 of 406 Page 390 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing interim Report 01 2010 Page 258 of 406 Page 391 of 539 V1660305 Results Name: sl00421a. IQ lQ HO * I ' 3 K / P 1 2 8 ' 2010 Page 259 o f 406 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Date:,Wednesdav. Anril 28, 2010 Printing T? ! In te rim R e p o rt 01 Page 260 of 406 3 Page 393 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 261 of 406 Page 394 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Datel WedMsdav, Anxil 28, 2010 Printing T? I Interim Report 01 Page 262 of 406 Page 395 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 1 28 2 0 1 0 Page 263 of 406 Page 396 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing ? 3 f i In te rim R e p o rt 01 1 28, 2010 Page 264 of 406 Page 397 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing t m Interim R epo rt 0 1 - 0 2 1 28 201 Page 265 of 406 Page 398 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing P i In te rim R e p o rt 01 il 28 2 0 1 0 Page 266 of 406 Page 399 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 3 M s t i O T M In te rim R e p o rt 01 1" 2010 Page 267 of 406 Page 400 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 21 Page 268 of 406 Page 401 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing nterim Report" 0T ;ii 28 2 0 1 0 Page 269 of 406 Page 402 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28, 2010 Printing S t y d y gG L P f f l- 0 1 - 0 2 ' Interim Report 01 Page 270 of 406 Page 403 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28, 2010 Printing T3 M Interim Report Q1 Page 271 of 406 Page 4Q4 of 539  rt rt II fl) (Xr^fD isfis.. -g ftS -s. hp-- CO J `r Sf io 2 . o J i en CO CD E sE Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing nterW Repoi 28 2 0 1 0 Page 273 of 406 Page 406 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 28 2 0 1 0 Page 274 of 406 Page 407 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report P1 2010 2* Page 275 of 406 Page 4P8 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 276 of 406 Page 409 of 539 a?|s?s If? sriijrdFsi'isirf* uf % \\ m is sihr. s | " P i 1"P I smilJhsf nlu1 Ms ^ '$ jf I i j S I g S I 1 II 1 i ------------------------------------------------s .j.M .IJ.I.i.M .M .M !| II E I Results Name: sl00421a. Stan V1660305 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 il 28 2 0 1 0 Page 278 of 406 Page 411 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb 's s s , t * in te rim R e p o rt 01 "0 2 1 2010 Page 279 of 406 Page 412 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 il 28 2 0 1 0 Page 280 of 406 Page 413 of 539 *Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing Printing X s t i g K P W In te rim R e p o rt 01 ?1 2010 Page 281 of 406 Page 414 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing Interim Report 01 il 28 2 0 1 0 Page 282 of 406 Page 415 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date: Wednesday, April 28 Printing T ? M S tq d ^ gG id P 'bQilO I-O 2 In te rim R e p o rt Q1 2010 Page 283 of 406 Page 416 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing Printing i l K S ' u d i B P J In te rim R e p o rt 01 2010 Page 284 of 40G Page 417 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 Ll 28 2 0 1 0 Page 286 of 406 Page 419 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 28 Printing ; s i s t ; s ; s E P i i , o ? 9 f i ` In te rim R e p o rt 01 2010 Page 287 of 406 Page 420 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2 8 , 2010 Page 288 of 406 Page 421 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Date- Wednes Printing T M S tyd y :8r l In te rim R e p o rt 01 il 28, 2010 Page 289 of 406 Page 422 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing ,w ? $ Interim Report 01 11 28, 2010 Page 290 of 406 Page 423 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 il 28 2 0 1 0 Page 291 of 406 Page 424 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 il 28 2 0 1 0 Page 292 of 406 Page 425 of 539 Page 426 o f 539 *G >nG S' 5' rt rr gits ^Ur-tA o _i57 7*> 35 n . 0to0 to oH* O &>G IQ to uXiI o o0> I E I Results Name: sl00421a. Stan V1660305 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 3 M Printing Interim R e p o rfo i 2010 28 Page 294 of 406 Page 427 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Date: T3M S 0Wednesday, ty d y fiG L P ij ,o Ai -pOr2il 28 In te rim R e p o rt 01 2010 Page 295 of 406 Page 428 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 2010 Page 296 of 406 Page 429 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 297 of 406 Page 430 of 539 rwlii J ? *W- ^ "i eesh n h i 1 *'* ^ s.11111.3 I I 1 1 1 1 1 1 1 1 1 1 .1 a o* *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. ,. jl sl!3lf llsif'l f I5ll|i' "i^ji -!, s:? inting D5)^stlL<?$^tLi^&'0^i&'*' 2 8 ' 2010 m tm g T^nj|..m ^g ^ Q ^o i " Page 298 of 406 Page 431 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g !i$ M S tU d v <iG P t 0 - o 1 - O 2 i l 2 8 ' 2 0 1 0 Printing | n f | rj m R e p 0 rt30 ^ page 299 o f 406 Page 432 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 1 28 2010 Page 300 of 406 Page 433 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb " 5 3 In te rim R e p o rt 01 " 1010 Page 301 of 406 Page 434 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Interim Report O f Page 302 of 406 Page 435 of 539 ? i? Sft' Srr' S'S' IQ LQ -3 a ii to 00 oM O &d IQ u> ou> o I I 1 l I Results Name: sl00421a. Stan V1660305 Page 437 o f 539 >d ^H- Hli33 fHt- Hrr(3 C3Q s& B fD ^ i" 2 - np-fto O" nTOl _^u 7*> 2 Mi CQ>d st--* g ? E Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 2010 Page 305 of 406 Page 438 of 539 Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb 1 28 2010P r i n t i n g S tU Q ^ G L P lO -O lO i 7P r i n t i n g T iInmt e r im d3!?: 15 .J O R eport 01 ' Page 306 of 406 Page 439 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g D3M ?S tlM 'G E P T O -O t- O 1 28' 2010 P rin tin g R g p O lfo r Page 307 of 406 Page 440 of 539 *Stan V1660305 *3M Environmental Lab HO ^vO Ju ^a^r |,M.(D rtTTTt " eS ^.H-M 'oZ ^_r<pUi &>d IQ O 0 cn co CD Results Name: sl00421a.rdb Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb SS '21 2010 Page 309 of 406 Page 442 of 539 Stan V1660305 *3M E nviron m ental Lab R e su lts Name: s l0 0 4 2 1 a .rd b P rin tin g P r in tin g Tflterm 7Re?oi!f io f M 28' 2010 Page 310 o f 406 Page 443 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb printing I3|M S tU & y ? G lfP t P - 'p 1 -P 5 il 28 2 0 1 0 Printing Time : 7Z<39:2l4_a m In te rim R e p o rt 01 Page 311 of 406 Page 444 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim R e p o rt OT 1 28 2 0 1 0 Page 312 of 406 Page 445 o f 539 u> 2 I 3 E & Stan V1660305 Results Name: sl00421a. Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 1 28D<3m S t H a ^ G L P T O - O W i ' 2010 P rin tin g $ ^0 ? 01 Page 315 of 406 Page 448 of 539 Stan V1660305 Results Name: sl00421a. Printing Printing 28, 2010 Page 316 of 406 Page 44g Qf 53g Stan V1660305 Results Name: s!00421a. *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 5 tU 8 y jW p r O - O r - 0 2 1 28 ' 2010 Printing Time:. 7 -39:37 Ja m In te rim R eport O r Page 318 of 406 Page 451 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g D ^M P rin tin g T 3 me In te rsi 7 m d3 ^ : 3 9 R eport /1 0 01 - 2010 Page 319 of 406 Page 452 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StUay^ EPYO-Ol-O?1 28' 2010 Printing TiInmete:r.im7iR-e3p9:o4rt10r.1AM Page 320 of 406 Page 453 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StM ' GEpW -O liO ? 1 28 ' 2010 Printing Tiinmete:r.im7rRie3p9:o4r2t 0,,1AM Page 321 of 406 Page 454 of 539 *S ta n V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a . rdb P r in tin g D3MStUdyilGeP^'0-0l-02L1 28' 2010 P rin tin g T ^ m 0 1 M Page 322 o f 406 Page 455 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing 1Printing 3 M S t U d M l f t o l W 26 2010 interim R eport 0 1 Page 323 of 406 Page 456 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D^M StUd^11G tP l0 - 0 l0 2 1 28' 2010 Printing T iinmteersim7dR3e9p:o4r7t p0110 Page 324 of 406 Page 457 of 539 Stan V1660305 * 3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P rin tin g StHaynS LP l0-0 lB ff2 1 28 ' 2010 P r in tin g T ^ m R^pOTt 0 1 Page 325 o f 406 Page 458 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in tin g DgM StW ^GEpTO-OlO? 1 28' 2010 P rin tin g T ^ m Page 326 o f 406 Page 459 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb Printing ^ M S t U d y ^ G E P lO - O l- O ^ -1- 2 8 ' 2010 Printing T j n g rim7 R p b rf i 20 ^ Page 327 of 406 Page 460 o f 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P rin tin g P r in t in g Tjntgrjm' R |p 6fl,0 l M 28' 2010 Page 328 o f 406 Page 461 of 539 *S ta n V1660305 * 3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 la .rd b P r in tin g D3M StSSy^GEPlO-OlO?1 28 - 2010 P r in tin g Tjfltgfim Rg^Otf 01" Page 329 o f 406 Page 462 of 539 660305 Results Name: s!00421a. i aw - J r !' ||5 liil ^H? i tH,f ; ` t I I jM jM M li o 2 ^ inting Dafyf anting T ^ e : . ^ f 4 9p:o5r?eft" 1 28 2010 Page 330 of 406 Page 463 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing Interim Report 01 28 2010 Page 331 of 406 Page 464 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb L1 2010P r i n t i n g D 9 M S t U d y i l G E P ^ 1 0 - 0 l I D 2 2 8 ' 2P r i n t i n g T ^ e r i m Rk'P b 'T to l Page 332 of 406 Page 465 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing Time:. 7 ^ `0:u5-AM Interim Report 0 1 ^010 Page 333 of 406 Page 466 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing Tftftlrim7 Report 0 ^ 1 28 ' 2010 Page 334 of 406 Page 467 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing ^ M Stdd^ 'GEPlO^OfJOS11 28 ' 2010 Printing T|n frjm 7R fft6 fi60 'F 1 Page 335 of 406 Page 468 of 539 Stan V1660305 *3M Environmental Lab Printing Printing I f lilii j r p j \ % H|^l ^ * m ' I sH ! l ttH " \ i! Intensity, cps oSSSgSgggSgglgSSS P I Ib iw p rrif "Pill :? W , s= c s s g I, P i # iH ' le l H Intensity, cps r :1 t u- 3JJJJJJJJllf.il 11.11 28, 2010 if - | I p f '| H ilt r ilii8 ''} j| j ;ft ir!|ii Ill'll ^ i* Hisp'll h H fiil Results Name: sl00421a. 2 cr Page 336 of 406 p gge 46g Qf 53g *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing DgM St0Syn6 f .<PTO-0lH 321 28 ' 2010 P rin tin g RepOrt0^ Pa9e 337 of 406 Page 470 of 539 *Stan V1660305 *3M Environmental Lab Sff S' rr rt U Ho * / rilfl T'ij} I I hOS nUi\' |fis|"fl ssih 5I Intensity, cps 35! l i l l l i l l l i l l i l l i l l l i i N pl. ----------------------------------- s ; w m w w v mm l sHSs 'd SS i .! jii I am ! m !" jg It { j I l l | | 1| j I 11 ef----------- s J ? j niii jK ij ,,,h "i"! IsiPb! * ! / i & "'t i 888I aI 8I 8I i I s1888I I I tJ iQ -i L Results Name: sl00421a. Page 471 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r i n t i n g 03^ ? 1S tH a ^ G L P P O -O l- O 2 8 ' 2010 P rin tin g 0Re p:O ? 0 1 Page 339 of 406 Page 472 of 539 *Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing D3 M StUdy^GEPl^ 'O l-O ^ ^ Printing TfnterimTRepbrPo^" ^010 Page 3 4 0 of 4 0 6 Page 473 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M p r in t in g T fn if im RWPbVf01M 1 28 ' 2010 Page 341 of 406 Page 474 of 539 *Stan V1660305 Results Name: sl00421a. a `ting Da)|^f St0S$PtliBK)-O4ltEj1 28 - 2010 , t in 9 Tfffl^ n n ? F ^ 3 *i'o 1 Page 342 of 406 Page 475 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StU&^ G EPl^ O lO ? 1 28' 2010 Printing Tptftefim7R e p o t 0^ Page 343 of 406 Page 476 of 539 V1660305 Printing DgR/f Stfi8^nE1iaIX^0^BD2'1 28 - 2010 Printing T ^ g f ^ r^ ^ oF 1 ipHlIIP 111 I >> ss*s s v * : h iS -V -5 * i b ? m SKSS- - SS| ijj:: f sh! s isfss! 5n Intensity, cps i jH HI j l f l f j i l Hl j l . i l . I. 111f l ! f !rr if ip ll ll Is S SI M M M M M M E 1 E I I 1= Siss ; 1 T| B'S r i IIP IS \ i r 1 r ? f wA i b isf inn? ii ills'" Time: fled: . Algoriths Peak Heigl Peak widcl thing Widtl cted RT: Relative Rt Type: ntion Time: t Time: if s?ss|soss!i llIl ssf Is!:e1 shsi f ' P fI Results Name: sl00421a. Page 344 of 406 Page 477 o f 539 ao* V1660305 nting Dj|^tdftVileF1t0-`O ^ B 2 il 28, 2010 n t i n g Tlfi,fWrim7R i ^ 6f t^ D fjyl w 9 l in.a '" ! F i l l # 1 '55' &Hp '55f|s|!,{i E m U is g ,r ,S| ,* [ jf|l|*j| HiU 5 | jf ,,8I 1i 1I 1I I I I I I I p -------------------------------------- 1 " i sp?^ l#I '55 fHS& PS 5 * S 8 8 8 S I S I S 8 8 1 I l.lll I I -1 * Results Name: s!00421a.rdb Page 345 of 406 Page 478 o f 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g D3M P rin tin g 1 28' 2010 o1 " Page 346 o f 406 Page 479 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing d 3M 1s t U a y ^ e i P i o - o i - o i 28 2010 Printing m <o? o i Page 347 of 406 Page 480 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042la.rdb P rin tin g P rin tin g 1 28S tH a ^ S L P lQ - O lE Q J - 2010 RSpSTt Q T Page 348 of 406 Page 481 of 539 tra *Stan V1660305 Results Name: sl00421a. s & U) 3 S!? inting i n t i n g T ^ j . ^ p ^ 0p:i r i eft" 28, 2010 Page 349 of 406 Page 482 o f 539 Stan V1660305 * 3M E nviro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P rin tin g DgM P rin tin g ^0 ^0 1 " 28' 2010 Page 350 o f 406 Page 483 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Printing P rin tin g 28, 2010 Page 3S1 of 406 Page 484 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M S tff8f ij3<SPlO '-O ?i021 28 2010 Printing 7T f iflir im R eporto r Page 352 of 406 Page 485 of 539 Stan V1660305 *3M Environmental Lab | Sample Name: "s100421a017" Sample ID: "EC-100415-07 10 ng Extracted Curve Point" Peak Name: "PFOS' Masses): '499.0/60.0 amu.499.0/99.0 amu,499.0/130.0 amu" Comment " Annotation: "" Sample Index: 17 Sample Type: Standard Concentration: 10.0 ng/mL Calculated Cone: 9.68 ng/mL 4.6e4 Acq. Date: Acq. Time: 4/21/2010 2:16:12 PM 4.4e4 Modified: Yes Proc. Algorithm: IntelliQuan IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 12.8 min Use Relative RT: NO 4.2e4 4.0e4 3.6e4 3.6e4 3.4e4 3.2e4 Int. Type: Valley Retention Time: 12.78 min Area: 468344 counts Height : 4.7Se+004 cps Start Time: 12.559 min End Time: 13.286 min 3.0e4 2.8e4 2.6e4 2.4e4 File: "s100421a.wtfT 2.2e4 2.0e4 1.8e4 1.6e4 1.4e4 1.2e4 1.0e4 6000.0 6000.0 4000.0 2000.0 I Sample Name: "s100421a019* Sample ID: "EC-100415-09 50 ng Extracted Curve Point" Peak Name:'PFOS* Masses): '499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" B Comment"" Annotation: -- Sample Index: 19 Sample Type: '' Concentration: ng/mL 2.3eS Calculated Cone: Acq. Date: ng/mL 2.2e5 Acq. Time: 2.1eS F6e: 's100421a.wifr Modified: Proc. Algorithm: IntelliQuan IQA Min. Peak Height 0.00 cps Min. Peak width; Smoothing Width: RT Window: Expected RT: Dee Relative RT: 2.0e5 1.9e5 1.8e5 1.7e5 1.6eS 1.Se5 Area: Height : start Time: End Time: 2.31e*00S cpa 12.S19 min 13.417 1.4e5 1.3eS 1.2eS 1.1e5 1.0e5 9.0e4 8.0e4 7.0e4 6.0e4 5.0e4 4.0e4 3.0e4 2.0e4 1.0e4 3Printing D M S tlS & ^ G P lO -O IO ?-1 28 - 2010 7Printing T |n tg rim R e p o f f o ^ Results Name: sl00421a.rdb [Sample Name: "s100421a018' Sample ID: "EC-100415-08 25 ng Extracted Curve Point" Peak Name: "PFOS" Masses): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment "" Annotation: "* Sample Index: 18 Sample Type: Standard Concentration: 25.0 ng/mL Calculated Cone: 24.9 ng/mL Acq. Date: 4/21/2010 Acq. Time: 2:42:25 PM File: "s100421a.wifr Modified: NO Proc. Algorithm: IntelliQuan IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 1 2 .a min Use Relative RT: NO Int. Type: Valley Retention Time: 12.77 min Area: 1236151 counts Height : 1.21e+005 cps Start Time: 12.509 min End Time: 13.276 min I Sample Name: "s100421 a020" Sample ID: "EC-100415-10 100 ng Extracted Curve Point" Peak Name: "PFOS" Masses): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" I Comment " Annotation: "" sample index: sample Type: concentration: ng/mL 4.2eS calculated Cone: Acq. Date: ng/mL 4.0e5 Acq. Time: 3.8e5 Modified: Proc. Algorithm: IntelliQuan IQA Min. Peak Heighi:: 0.00 cps Min. Peak Width : 0.00 sec Smoothing Width : 3 points RT Window: 30.0 sec Expected RT: 12.8 min Use Relative RT:: NO Int. Type: valley Retention Time: 12.76 min Area: 4 >62103 counts Height: 4.22e*005 cps Start Time: 12.519 min End Time: 13.316 3.6e5 3.4e5 3.2e5 3.0e5 2.6e5 2.6e5 2.4e5 2.2e5 2.0e5 File: "s100421awifT 1.8e5 1,6e5 1.4e5 1.2e5 1.0eS 6.0e4 6.0e4 4.0e4 2.0e4 Pa9e 353 of 406 Page 486 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3P r i n t i n g D M S t lW y ^ G E P lO - O lO ? 1 2 8 ' 2 0 1 0 P rin tin g T ^ m R e P o ttO * " Page 354 of 406 Page 487 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g 1 28D<3m S ffiS y n S L P lO - O l]- 0 2 - 2010 P r in t in g T ^ r i m R pO rt 0 1 Page 355 of 406 Page 488 of 539 a -rr a E -p l s 3 a tr Stari V1660305 Results Name: s!00421a. Page 489 of 539 ** u en 3 rr E I ) ? E ir+ CO i-* o 0 to H* 0 1 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g P rin tin g 1 28S ffid y n 8 i i P l 0 - 0 l l - 0 2 - 2010 R epO /l 0 1 Page 358 of 406 Page 491 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. Printing Dajfyf Printing 28, 2010 Page 359 of 406 P a g e 4 9 2 o f5 3 9 Stan V1660305 *3M Environmental Lab s S' if n35 S j 1i ri ~S rm '" " i l l ! i m H U ilssl^l t j!H i U is SSSg8 3SS? 3 11 ills m * 14=11 H i l l Is I JIS - s :l :S si t III l i Intensity, cps is 0 CD iQ cn co CD .. r 1 1 HU mn 'it iiHfi m b I* i! S8S i I -5 S 8 Results Name: sl00421a. Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in t in g D a ^ S tU 9yn G L P l0 - 0 l- 0 2 1 28 ' 2010 P rin tin g R epO tf 0 1 Page 361 of 406 Page 494 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing 1 28' 2010 Pa9e 362 of 406 Page 495 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3 M Printing T fm ir im 0^ ^ 28, Page 363 of 406 Page 496 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 3Printing D M S tU d y ^ G E P l^ O lS O ? 1 28 2010 p r i n t i n g T f n d n m RejbOH*0 ^ Page 364 of 406 Page 497 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in t in g D gM S tU d y n S tP lO -O lIO ? 1 28 ' 2010 P r in t in g T jfle fjm R^PoTf OP* Page 365 of 406 Page 498 of 539 660305 Results Name: sl00421a n3 S3 i I IQ0> (D O D3,wtstHaffi t<itaK)-oiyEQ21 28- 2010 Stan V1660305 *3M E nviron m ental Lab R e su lts Name: s l0 0 4 2 1 a .rd b P rin tin g :Sf&dynGLtP f0 -0 l!-ff21 28 ' 2010 P r in tin g T ^ m =0* 0 1 Page 367 o f 406 Page 500 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl0042ia.rdb Printing Printing T^ffterm R^pOtt 0 1 28' 2010 Page 368 of 406 Page 501 of 539 *S ta n V1660305 * 3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in t in g D3M StBSy^GtPlO-OlO^ 1 28 ' 2010 P rin tin g OP1 Page 369 o f 406 Page 502 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in tin g D3M P rin tin g Report0 ^ 1 28' 2010 Page 370 o f 406 Page 503 of 539 Stan V1660305 * 3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g D a ^ S tH a fW P lO -O lE O i1 28 ' 2010 P r in tin g T ^ m RepOtf 0 T Page 371 o f 406 Page 504 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing StUla^ GLPlO^ - O j1 28 2010 Printing T in d n m RepOT? 0 1 Pa9e 372 of 406 Page 505 of 539 n| i1 a *Stan V1660305 Results Name: sl00421a. nnttiirn"g9 TD<igfjfffleSrtiir5r9^iif^1Sia(.HtfoK)1-O^Bro1 28 2010 Pa9e 373 of P4a06ge 506 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in t in g D3M StHaynGiL<P l0 - 0 l- 0 2 1 28' 2010 P rin tin g RpO? 0 1 Page 374 o f 406 Page 507 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StUGy^ L P lO -O lO ? * 28' 2010 Printing T ^ i f i m RepOTt0 ^ Page 375 of 406 Page 508 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g D<3m StHflynSLP*ro-01-21 28- 2010 P r in tin g T^nerim RepOrt 01M Page 376 o f 406 Page 509 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M StUdy^G L P l^O-Ol-O?1 28' 2010 Printing Tfnu rim R e p O tfo ^ Page 377 of 406 Page 510 of 539 *S tan V1660305 *3M E n viro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g D3M S tH a 'G 'P W -O I-O j1 28 ' 2010 P rin tin g R jpO f 0 T Page 378 o f 406 Page 511 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Da M Printing TantiSrUlRlitbLrfcDl^0- 28' 2010 Page 379 o f 406 Page 512 of 539 Stan V1660305 *3M E nviro n m e n ta l Lab R e s u lts Name: s l0 0 4 2 la .rd b P r in tin g D3M S tS S yrG E P m O lO ? 1 28 ' 2010 P r in tin g T j ^ m R ipO ff 01" Page 380 o f 406 Page 513 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb 1 28P r i n t i n g I $ M S t U d y Jr 8 e P i1 0 - 0 l 0 2 2010 P rin tin g R e p o rt" Page 381 of 406 Page 514 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in t in g DaMStffdi^SEPlfy-OlIO^ 1 28 ' 2010 Printing T ^ e rm R p o fto ^ Pa9e 382 o f 406 Page 515 of 539 660305 Results Name: sl00421a. DM ;StS#Si:n,WXP0*G5-1 2 8 - 2010 T Prftfirr7 0^M Pa9e 383 of 406 Page 516 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing Printing StHQ^ GLPlO-OlEO?1 2 Q > 2010 Repotf 0 ^ Page 384 of 406 Page 517 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing p rin tin g StHdynL(P lO -OlP021 2 8 ' 2010 Report O F Page 385 of 406 Page 518 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s!0 0 4 2 1 a .rd b P r in t in g DgM Stti&ytaS&PlO-OllO? 1 28' 2010 P r in t in g Tptftefjm7KepOH)0 t M Page 386 o f 406 Page 519 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: sl0 0 4 2 1 a .rd b P r in tin g D3M S tffayiG tP lO -O l^ :1 28' 2010 P r in tin g T jflg fim RypOTf 0 T Page 387 o f 406 Page 520 of 539 *S tan V1660305 * 3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 la .rd b P r in tin g D3 M StffayiG P l0 - 0 l0 2 1 28' 2010 P rin tin g ^0 ^0 1 " Page 388 o f 406 Page 521 of 539 W 3| I E *Stan V1660305 Results Name: sl00421a. `ting `t i n g 28 - 2010 Pa3e 389 of 406 Page 522 of 539 *Stan V1660305 Results Name: s!00421a. I inting inting St0a^?5Sf.`f:aIX>O4lG2-1 28 2010 Pa9e 390 of 406 P age523of539 *Stan V1660305 *3M Environmental Lab Results Name: s!00421a.rdb Printing D3 M st0 8 yn L (^ O-Ol-O21 28' 2010 Printing T jflg fim RepOif O P Page 391 of 406 Page 524 of 539 Stan V1660305 *3M Environmental Lab ? ? 3 3 rr rt i'fipiiftiII <-) O SS" ??i% r*5." SsSi 4 l ="L"* sss s s - * : jh .i.irnj t. 5.?:i -M/ . =. PipI in k r q u 1 5 || tsiis si '''. || li ?l Intensity, cps .P iiiiiiilffTFitiifffiit j P ill j jli ' ; s s 5 . _ a l i i 55,1555| !ih5 ' ~ if "iItt |1 . 8 8 M 8 8 8 8 M 8 8 M fi If SI 1 li!5rt nit IbHlI " i % H i U | ^ 55,15 55 ' ) I ******** * r t .f .f I! 1 b Results Name: sl00421a. "0 * Q) S CQ o> fl> cn hcno o cn co CD I ! s ', --i I a tr Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g DgM P rin tin g 28' 2010 Page 393 of 406 Page 526 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a. inting Dg|%pStlSfl3fl:nSEiBIXV0^IO2-1 2 8 ' 2010 inting T p ^ g ^ R ^ y f t c r t " Pa3 394 of 406 Page 527 o f 539 Stan V1660305 *3M Environmental Lab I ip-If ilifliliHti !foif{ ii -3 O -e ft . ? i` HfilfH !'"|ii ` r r iil!!i!l r nlSrAt m M ii!1iSODi iSIH S W 51 l 1 : 1 :v ji mb h ji f *s i r i `& Results Name: sl00421a. J " i " ............ W A '& imeiivujr, up 81 M f 1 i.l1..!..l..fi..S..I.1J..1.1..I..S18.i *0 p) IQ re f*U s *P I i *S a 8 H iU ssi &}*? ^ :s s 1II i i i i ! I n II 1 t s Page 528 o f 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in tin g D3 M P rin tin g R e pO tfo l1 1 28 2010 Page 396 o f 406 Page 529 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in tin g D3M P r in t i n 9 Ttn tlrim Rfeport10 T 28' 2010 Page 397 o f 406 Page 530 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D^M StH0?nl.<Pa1O-Ol-O2:1 28 ' 2010 Printing 0T Page 398 of 406 Page 531 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing DaMStUd^ IG LP lO ` O lJ0 2 1 28 * 2010 Printing T jn fffjm R ip O fO ^ Page 399 of 406 Page 532 of 539 Stan V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in t in g D3M S tU a y'G .P fO -O l-O i1 28 ' 2010 P rin tin g 0T Page 400 o f 406 Page 533 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing ^ M S ttidy^ LPlO-Ol-O1?-1 28 2010 Printing TfnterjmVR ^ p o f^ O ^ Page 401 of 406 Page 534 of 539 *S ta n V1660305 *3M E nviron m ental Lab R e s u lts Name: s l0 0 4 2 1 a .rd b P r in tin g DgM StUdy^GEPlO-Ol-OS1 28 ' 2010 P rin tin g T m efim R epO P ol1 Page 402 o f 406 Page 535 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a. i n t i n g D g fy fst08#:nf.<iiBIX)-C)Jf(J2'1 28 2010 in trin g P a9 e 403 o f 406 Page 536 o f 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P rin tin g P r in tin g Ta^e^ 7^42 I in te rim R e p o rt 01 2010 Page 404 of 406 Page 537 of 539 *Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb Printing D3M Printing T frfl| r im 1 28 2010 0^ Page 405 of 406 Page 538 of 539 Stan V1660305 *3M Environmental Lab Results Name: sl00421a.rdb P r in tin g D3M P rin tin g RepOTf01* 1 28' 2010 Page 406 of 406 Page 539 of 539