Document QXovXjbdo4Jppprv2weoawjJ6
DRILLING SPECIALTIES COMPANY BARTLESVILLE OKLAHOMA 74004 September 2, 1982
916 661-5405 916 661-6153 918 661-5333 TELEX 49-2455 TWX 910 841-2560
PLAINTIFF'S EXHIBIT
HCI-10
Material Safety Data Sheets
J. H. Moore Manager of Purchases NL Baroid/NL Industries, Inc. P.O. Box 1675 Houston, TX 77251
Dear Mr. Moore:
Attached, per your request, are Material Safety Data Sheets for the following products:
"Drispac polymer" "Flosal" "Soltex"
Communication of physical property, health and safety information in Material Safety Data Sheets is a key element in our product safety program. With this information you can better fulfill your obligation to educate exposed person nel in the proper product handling techniques required to maintain safety in the workplace.
If additional information is required, please advise us.
Very truly yours,
RRS:afb Attachments
R. R. Simmons Senior Standards & Regulations Analyst Seneca Building (918) 661-8327
RECEIVED
SEP 71982
BAROIO PUKI1AW OEPt.
iJOVSTOY TEWS
DRILLING MUD AODITIVES AND CEMENT SYSTEMS
f<m AO0'OV4 Ruflmt flornsu No. 4*R13B7 .' ,|rv.i vfnr* Agnl 30. 1371
fl.S. DEPARTMENT OF LABOR
WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards
MATERIAL SAFETY DATA SHEET
form No. LS&*00S*4 M.ty 1969
SECTION I
MANUF AC TURER'S NAME
Hercules Inc
ADOAESS (Number, Sitttt,
State, and ZIP Cnde)
900 Market Street.
CHEMICAL NAME AND SYNONYMS
chemical family
Cellulose ether
EMERGENCY TELEPHONE NO.
302 575-5000
Wilmington. DE 19899
TRADE NAME ANO SYNONYMS
______ Drismc polymer______________
PQlUiCIl JAii
Available in hieh or low viscosity erad<
SECTION 11 HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES. & SOLVENTS % (UTnLVit.) ALLOYS AND METALLIC COATINGS
PIGMENTS
BASE METAL
CATALYST
ALLOYS
VEHICLE METALLIC COATINGS
SOLVENTS ADDITIVES
POFILTLUHLSEERRCSMOEATTAINLG OR CORE FLUX
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR CASES
Note:
As we interpret the Occupational Safety and Health Act of 1970, this product should not be considered hazardous.
% (UTnLiVts) ,
'
% (UTnLiVts)
ir
SECTION III PHYSICAL DATA
SOILING POINT (F.)
HA
SPECIFIC GRAVITY IHj0=l, ^^
^
( film)
VAPOR PRESSURE <*wn Hq.| VAPOR OENSITV <AIR = \)
NA
SOLUBILITY IN WATER & ,
__ ,,
% by wt @ 25 C con plete
PERCENT VOLATILE
<%iby volume
w#
^
Moisture 8% ma X.
EVAPORATION RATE .
i =u(Butvl acetate = 1)
NA
appearanceANOOOOR dry> granular powder of light color: odorless
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used)
NA
FLAMMABLE LIMITS
EXTINGUISHING MEDIA
water, C0o,
SPECIAL FIRE FIGHTING PROCEDURES
None
foam or dry chemical
Ll
h. i
ci'r.
per cu fit
Uel
WA
UNUSUAL FIRE AND EXPLOSION HAZARDS
Treat as a flammable dust in the finely divided aril-
suspended state.
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)
SECTION 1
MANUFACTURER'S NAME
Arnold L Clarke Chemical Company
EMERGENCY TELEPHONE NO.
.713 869-05^1.
ADDRESS (Number, Street, dry. Star and 7.IP Codrt
, _, ,_
6325 Hurst Street, P.0. Box 1C660, Houston, TX 77018
CHEMICAL NAME AND SYNONYMS
TRADE NAME ANO SYNONYMS
CHEMICAL FAMILY
sodium asnhal 1 AiilfnnatP ______________ Solfpv____________________________
FORMULA
_______________________________sulfonate___________
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES, 8f SOLVENTS "
--TLV _
(Units)
allo^'ANd'Metallic coatings
PIGMENTS
BASE METAL
CATALYST
ALLOYS
VEHICLE SOLVENTS ADDITIVES
METALLIC COATINGS
FILLER METAL PLUS COATING OR CORE FLUX
OTHERS
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES
X
TLV (Units)
T'.V X (Unitsl
BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIRM) SOLUBILITY IN WATER APPEARANCE AND ODOR
SECTION III - PHYSICAL DATA
NA .. NA NA
. SPECIFIC GRAVITY (M30*1)
PERCENT. VOLATILE by volume(%>
moiEture
EVAPORATION RATE
< M)
Q OP
8% max NA
75 ins at qn r.
_______________________________________
hrnM,,_hlaplf friah1p flaltP
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
flash point (M.moa used) EXTINGUISHING MEOIA
FLAMMABLE LIMITS
NA
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE ANO EXPLOSION HAZARDS
PAGE (1)
(Continued on reverse side)
FRovr.mMOyS7H2A-20
August 27, 1982
Mr. R.L. Clampitt Drilling Specialties Co309 Short St. Bartlesville, OK 74004
Dear Mr. Clampitt:
N'L Baroid is in the process of updating its safety files, and need Material Data Sheets for the product(s) currently purchased from your company:
Drispac Polymer Flosal/Asbestos Soltex
Please send these sheets to the following:
J.H. Moore, Manager of Purchases NL Baroid/NL Industries, Inc. P.O. Box 1675 Houston, TX 77251
Your cooperation and assistance in this matter is greatly appreciated.
Yours truly,
' C-' "C
,.J.H. Moore Manager of Purchases
K
JHM/css
CGj--It. Somers K. Thoresen
NL Baroid NL Industries. Inc PO Box 1675. Houston. Texas 77001 Tei (7131 527-1100
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
See Section II and attached Federal Register - 6/7/72
EFFECTS OF OVEREXPOSURE
Long term exposure to high concentrations of asbestos fiber may-
cause pulmonary disease.______________________________________________
EMERGENCY ANO FIRST AIO PROCEDURES
Avoid breathing excessive dust when handling, dumping and mixing.
See caution label on bag. ___________________________ ___________ '
SECTION VI - REACTIVITY DATA
STABILITY
UNSTABLE
CONDITIONS TO AVOIO
STABLE INCOMPATABILITV (.Materialt to avoid)
X
HAZAROOUS DECOMPOSITION PRODUCTS '
HAZARDOUS POLYMERIZATION
e
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
X
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TC/ BE TAKEN IN CASE MATERIAL IS RELEASEO OR SPILLED
Vacuum clean spillage. Repair broken bags. If sweeping is necessary, wet down spillage. Use approved respiratory equipment when required.___________
WASTE DISPOSAL METHOD
Place waste in closed containers. Dispose of waste in closed containers. Avoid breathing excessive dust.______________ _________________________________________________ _
- SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory protection (Specify type)
U.S. Bureau of Mines aonroved respirator - See OSHA 1910'.93 Asbestos, Fed. Reg. 6/
VENTILATION
LOCAL EXHAUST
SPECIAL
mechanical (General) Control with mechanical OTHER dust collection eauio. to within TLV
PROTECTIVE GLOVES
eye protection
OTHEP PROTECTIVE EQUIPMENT
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING
Maintain good housekeeping practices. Vacuum clean waste and place
in closed containers._____________________________________________________ _
OTHER PRECAUTIONS
__________________________ SEE CA11TT0K LABEL ON RAG.____________________________________
PAGE (2)
the information and recommendations set forth herein
cr<cif-S`!b'felieved to be accurate as of the date hereof, JOHNS-N&NVILLE CORPORATION MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FRCK RELIANCE THEREON.
FR#ovr.m 72OSHA-20
UT20
RULES AND REGULATIONS
, i 910.03 ' .Air ronuminoni*.
to which any employer may be txa soi <d` fV'.w nn! pro.Vr.Mv vcui
.
shall not exceed two I'tiiet*. longer than (li C"U"!niiCi' Willi llir r\|, ii . iviPiK
Tjnr.t O S-MfsuuJ. Dew
Mpprf HriM'
S micrometers, per cubic cent inn ler of presenl i .1 bv paiaiiraph 11- Ho.. air. as determined by the mcth.xt pre tiim nun urn W- m'liU-w-il by tlw use ,i( scribed in paragraph ie' of thu section. rvspliaims in shut rotation of mu
<3' Ceilinp coiicenlriif-.in. No em plovers, except:
CfgNictUtlMirt ..... rc* C'urd (ucJ Jart)...... %SIOr+ CCr%it^ti'uiKiVrwkiruvu*IVhteMlurmHfMitahnU*ttchtor rjkutotM th tor* AntwiiiiniwiNant<T.MtAicladtac lula.n.i. 30
fillUc'aM.itnwKrai.i(lVi.C.B.)t.;h..a..n...1..%....e..r.y.v.. IFC'otlne*ar*eplsn*dlUviuluu.at<it4O(ihKeMvritnifumnllH?i..O...i...rl.t..e....dM...o...n...
999U000
Wmr./M* 90mc/M H-9%S\0
tOvnc^I* %*io.
or
ployee shall be cxix.scrt at any time to
nkborno ccnccntmtinns ot asbestos fibers In exec.-;s ot 10 Mbo a. limner than
5 micrometers, per cubic centimeter of
air. as determined by the method pre scribed in paragraph (el of this section.
(ci Methods ot compliance--(ll En gineering methods. (11 Engineering con trols. Engineering controls, such as, but not limited to. isolation, enclosure, ex haust ventilation, and dust collection, shall be used to meet the exposure limits prescribed In paragraph (b) of this section.
(ill Local exhaust ventilation, (a) Local exhaust ventilation and dust col lection systems shall be designed, con structed, installed, and maintained In accordance with the American National Standard Fundamentals Governing the Design and Operation of Local Exhaust Systems. ANSI Z9.2-1971. which is In
(|l I'lirln : (he lime irrlivt were* mi;v lo liu.l >i| 111" rurlnrs riii,- ejoiioh aiul
to in uiluic i|i" work prueticvs rcqulnxl by pararra' h (cl of this section:
(ill In work s'fiMlons in which the
method; prc'c`l''Cd In parac-rarh ic> of
this section rrc etth*r technically not
frasiblii or
<o an extent in-uffl-
cicnt to reduce the airborne concentra
tions of n.;l'r'!D'. fll'ri bc|or Uae liaitis
preserved by pamgraph tbi of this
section: or
(111) In rmerrene'e?.
(!v) Where both rcie-lmfon and per sonnel rotation Are allowed by subdivi
sions (1*. (ID. or (liii of this subpara graph. ap.d both ere practicable, person nel rotation shill be preferred end used.
<2) Where a iwln'or la permitted bv
subparagraph (U of this parmcra;!i. It shall be selected from among Uio:t ap
IwTKrant quriltJSeubulbtr.al.nm .ee.iiD.ut,.fMt.;......
I1S0 %UBmIOcy-+U2*tab'll*
corporated by reference herein.
(b) See 11910.6 concerning the avail ability of ANSI Z9.2-1971. and the
maintenance of a historic file in connec
proved be the Bureau of Mines Depart ment of the Interior, or the Nsttonal In stitute for Oceu-"t1"it:,l Safety and
HeaHh. D rorimeut of Health. Educa
I1n4Ihr-|rXS*Ouev|IT<AfiXohHH'itCMl*t*rrrjulomfpe'tX4iWIO:dhOn3*|oW-iC}oclUnJneo*K*t^ionIi*rOvH-ed4pvimrH.ft-roct>uit1nrililOMatniiMi*ormw.|dlKU.olrcf.*friykuvenuyjl*|ril.tu<p4ky.f'ific'f*ilil*fkK*Ot>rntcirHhs*rrtdf*ntlhefxsriamlTlnbiorcrfonVmt+.y-rtdrru*euea.rfpfhmbtermpeWnikcbecrmtnbrorfo.Mr|uvltoln**bM>b%UfellietrI-tl-AortBIbhrQHrflttoemtoeunUrbtroUiore>rotr,fmrbluk<ohslfrodonl.taIlslmttrivorrmdndwofrivlnOltmonrtotneicu.tr A(ettnnwirt^yiefwimUtey(TUTn*ineHr>er PrrctentietepvootrsiaK
tion therewith. The address of the Amer ican National Standards Institute is given In f 1910.100.
till) Particular tools. All hand-op erated and power-operated tools which may produce or release asbestos fibers in excess of the exposure limits pre scribed In paragraph (b) of this section, such as. but not limited to. saws, scorers,
abrasive wheels, and drills, shall be pro vided with local exhaust ventilation sys tems In accordance with subdivision (il> of this subparagraph.
(2) Work practices--U) Wet method*.
tion. and Welfare, tind"' Hie i-rivhionsof 30 CFR Part 11 (37 F it. CIM. Mar. 25. 1972. and shah ar il in accoidancc with subdivision* '1'. (li). <110.and (tv) of this sttbrsreerar>li.
<0 Air ry-yfy're r-'-rv refers. A reusa ble or silicic u-c ."I* "Urifving respirator.
or a respirator described In subdivision (U> or !i!l> o' *li|x eubrararraph. shall be ured !e eo.t'ic ' t':i- cone niruiic;ts of airbomv a.`b"e*oa fibers in tlie melrotor beloiv tii' fx-j-ir.- t'l; ;. I'.-c-c.xtc l ;a pamgrarh <>! of 'h!- s"ctlon. wiicn the cetlinj; or th" 5 h- ur ttmo-weighted xvaracc oirtOT-e e-'ne nlrnMons of asbestos
IQi211...105 t7**4o0404
*t*j :aKi1
uixli-r ti.i' *i<J i-tor tu tir iu* ^ *. ? t1-* " *i,.i,vuf'*rlu"
WIh-iJ .'4 iu* *i* m u* .**- o*. llv*
>V 44
Insofar as practicable, asbestos shall be handled, mixed, applied, removed, cut. scored, or otherwise work'd In a wee state sulhcicm to prevent the emission of airborne fibers r. excc-s of tbc ex posure limits prescribed in' paragraph
<b> of this section. unless the ursfulners of the product would be u'.ir.ir.hhed
ihercrjy.
fibers are rr- -o'iV!>- ev ected to exc>?cd
no mere i*t:i 1 me-, more lisr.lta.
<ii) P.n :r.a c:r rur:,;.inj respirators.
A full facepiece powered air purifying
respirator, .or r. rnwered ;>.;r pert'vine
respirator, ur ic;.p:ra:.>i Joacrilicd ill su'uriivhiir. .ill? cl tii.-. rv.U-'.r_e:.io;i,
rfidll Lr u . d ;r
rl.
tlor.x ol rirt'.-,' : ,'.t. 1.0;: fibers in tlte
5. A new i 1910.93a Is added to Part 1910. reading as follows:
1910.93a Atbestoi.
(a) Definitions. For the purpose of
til) Particular products and opera tions. No asbestos cement, mortar, coat ing. grout, plaster, or similar material containing asbestos shall be removed from bags, cartons, or other containers
respirator briov' the exposure limits pre scribed in pr.rrprr.i'h (b> of th's -retion
when tlie ceiling or the 8-heur tlme-
welghHd average concentrations of asbestos fiber; nrc reasonably expeeled
this section, (1> "Asbestos" includes
chrysotlie. amosilc. crr.cidolitc, tremollte, anthophyllite. and actinolite. /<2) "Asbestos fiber*" means asbestos
fibers lonccr than 5 micrometers. ib> permissible exposure to airborne
In which they ore shipped, without being
either wetted, or enclosed, or ventilated
so as to prevent effectively the release of
airborne asbestos fibers in excess ot the
limits prescribed in paragraph < b) of
this section.
1
to exceed 10 time;, but not 100 untes, those limits.
<Ui> TV'.'jc "C" supplicd-airrespirators, continuous fiow or pressure-demand class. A ty;:e "C" continuous flow or prssure-demand, suppUcd-alr respirator
concentrations of asbestos fibers--(1)
till) Spraying, demolition, or removal. shall be used to reduce the concentra
Sicndard elective July 7. 3972. The t-h-jur linio-v.cighted avernco airborne
Employees engaged in the spraying of asbestos, the removal, or demolition of
tions -of airborne asbestos fibers in the respirator below the exposure limits pre
concentrations of asbestos fibers to plli's. structures, or equipment covered scribed In p.'.-ngraph (hi of th's -.riicn,
w/iirh ui)' employee may be cxpviS'Q or Insulated with asses' as. and In the when the ceiling or Lite- 6-uou: tiuic-
riiall not exceed five fioers, longer than
5 micrometers, per cubic centimeter of air. as determined by the method pre scribed in paragraph (e) of this section.
itiuoval or demolition of asbestos in sulation or covering* shall be provided with respiratory equipment in accord ance with paragraph (d>("Klii> of this
weiahted average airborne ccncentralions ol asbestos fibers are reasonably
expected to exceed 100 times those limits.
(21 Slandord elective July 3. 3976. section and with special clothing in ac (ivl Er'ai'iirdncnf ol a respirator pro
The 8-hour time-weighted average air cordance with paragraph (d((3) of this gram. (a 1 Inc employer siiall establish
borne concentrations of asbestos fibers section.
a respirator program in accordance w;th
FEOCKAl ttCIStt*. VDL 37, HO. 110--Vri ON El DAY, JUNE 7. 1972