Document QXo60xd166w2KMYmXmxZLNJQR
MONSANTO CHEMICAL COMPANY
m tocAnox st, Louis - General Offices
o*".u.)c,
May 19) 1961 . HAZAKD0U3 SUBSTANCES LABELING
Nl.tNtNCK
10 Mr. G. li. Lido
,ohL*
rt c.o,
G. E. Gibson H. 0. Hehner L. E. Klein H. L. Minckler T. 0. Tupper, Jr
" r^
/V/<4 u;
Wo met on flay 16, 1961, to set ground rules for the Organic Division for the interpretation of the federal Hazardous Substances Labeling Act. It v;as decided that the following rules would bo used as the bases for determining whether or not the Organic Division Products are subject to the hazardous Labeling Act:
1. Any product designated u.S.P., N.F., other drug, or food chemical 13 exempt.
2. Products used as drugs and non-drugs are exempt in both cases.
j. Any product whose smallest standard container is too large to be generally found in or around the home Is exempt.
J|. Any product, which by its nature or application is unlikely to be found in or around the home, is exempt.
5. A non-hazardous product is exempt. -- A product whose acute oral toxicity (LD^q for rat3) i3 less than 5 grams per kilogram Is considered ha zardoua.
6. Product Samples (about 1 lb.) are handled separately.
Attachment I lists all of the Organic Division Products which we believe hazardous and subject to the Federal Hazardous Substances Labeling Act. The list gives the product name, smallest standard container size, and oral toxicity of each.
MOMS 097566
Q. R. Lido
-2- May 19, 1961
Sldo v Note '
Attachment II lists all of the Organic Division Products which we believe are exempt from the Federal Hazardous Substances Labeling Act. The list gives the product name, smallest standard container size, and the basis for exemption of each.
Duo to the Great amount of work Involved, Mr. ESlmer Wheeler will not proceed with compilation of the oral toxicity data for all of these substances unless you request it.
us - <- a*"-/' . Marie Vohsen
mv Attachments
MONS 097567
ATTACHMENT I
HAZAUDOUo AMD SUBJECT TO TILE FEDERAL HAZARDOUS SUBSTANCES LABELING ACT
Product Name Intermediates Group
Saritoclilor (paraDluhiorobonzone)
Plasticizers Group Santlclz.cr l'lO Triereuyl Phosphate
Smallest Standard Container Size
Acute Oral Toxicity LDsn (rats)-mg./icp;.
100 lb.
v i
'
'
0620
1] zy*/' >/ - V C'
y
1 M /'t> . :. > * ' - r Wt; /*< r 'S'.
5 Gal.
approx. 2000 to 6000
5 gal.
varies from 500 to 5000
Paper Chemical a Santobritc
10 lb.
90 to 300
HONS 097568
ATTACHMENT II
EXEMPT FHOM DK)iAL HAZARDOUS SUBSTANCES LABELING A
Product Name
Smallest Standard Container Size
Basle for exemption
Kino Chemicals Group
Ace tani J.id
100 lb.
Acetophonctidln
100 lb.
Acetylualicyllc Aeld
100 lb.
Actamer
30 lb.
Benzoic Acid
28 gal.
Benzyl Benzoate
85 sal.
Caffeine Anhydrous
100 lb.
Chloramine - T
125 lb.
Coumarln
25 lb.
litliavan
25 lb.
Methapyrilene Kamarate
5 lb.
Methapyrilene Hydrochloride
5 lb.
Methyl Salicylate
5 gal.
Phenolplithalcin
100 lb.
SA - 326
50 lb.
Saccharin Monsanto
100 lb.
Salicylic Acid
100 lb.
Suntophcn 1
22 gal.
So.ntophen 1 Solution
15 gal.
Sodium Benzoate
28 gal.
Sodium Salicylate
100 lb.
Sopanox
150 lb.
3, )|, A-Trlchlorocarbarilllde
100 lb.
Vanillin Monsanto
25 lb.
Acetyl SulTathiazole Tech.
150 lb.
G'fb Amide
100 lb.
Gualaco.1.
55 gal.
Iletanltrochlorbenzene
55 gal.
Tci'tiary-Butylamlne
55 gal.
Theobromine Hefined
standard bulk container
Adipic Acid, Food Grade*
50 lb.
Fumaric Acid, Food Grade*
50 lb.
N. B.
U.S.P. U.S.P.
size U.S.P. U.S.P.
U.S.P. N. F. M . F. size d rug
U.S.P. U.S.P. U.S.P.
size size
U.S.P. size size U.S.P. U.S.P.
size si:.e Tood size size N. F. size
size Not in dome food food
MOMS 097569
-2-
Product Name
Smallest Standard Container Size
Intermediates Group
Benzoic Acid Tech. Benzoic Acid Industrial Benzyl Chloride Biphenyl Tech, dyolohexanol Oyciohoxyl amino 2,A-Dlchlorophonol Blcyclohexyiamlne Mhydroxydiphenyl Sul Tone 2, A-Mri.l. t roanillne ll-Aeld Meta-Jlilo roan 11 inc Methyl VoluonesuIlonato Monocilierophthalio Anhydride ertho-Anlsldine
ortho-Chlorouniline ortho-Chloi'ophenol ortho-Dlchlorobenzene Tech. ortho-Nitroanlline ortho-Nltroanisole ortho-Nitrochiorobenzene ortho-Phenetidine
pura-Anlsidlne pai'a-Chloroaniline para-Chlorophcnol para-Nltroanl.llne para-Nitrochlorobenzene
para-Nltrophenol para-Phcnetldlne para-To1ueneaulfonamide Paratolucnosuifonylchlorlde Phenol Phenol Solutions PhcnolsiiTonlc Acid Phthaly.1 Chloride Plienyl cyclohexane Sulicyllc Acid Tech. Salicylic Acid Industrial Sodium Benzoate Tech. Sodium Paranitrophenate Thlouroa Tolueneoulfonic Acid Tech.
50 lb. A 2 lb.
55 gal. 100 lb. A30 lb.
55 gal. 55 gal.
55 gal200 lb. 225 lb. 100 lb.
53 gal. 3o gal. 200 lb. 55 gal.
55 gal. 55 gal. 55 gal.
175 lb. 55 gal. 55 gal. 55 gal. 55 gal. 55 gal. 55 gal.
350 lb. 55 gal.
200 lb.
55 gal. 275 lb. 300 lb.
23 gal. 55 gal. 55 gal. 55 gal.
5 gal. 250 lb.
250 lb. 100 lb.
55gal 75 lb. 10 gal.
Basis Tor Cxempt-lon
s L ze size size size size size size size size size size size si ze size size size size size size size size size size size size size size size size size size U. S. P. size size size Not in Home size size size size size size
MONS 097570
-3-
Product Nai.te
Smallest Standard Container Size
Ini.ermedlai.es Group
3,4-Diehloroaniline* Dlmethylueo tamide* D-SuJl'osaiicylic Acid* Totrupropeny1 succinic
Anhydride* t-Butylamlne* Dlcyolohoxyi*
56 l.a l. 5 gal.
200 Id.
55 sal. 55 sal.
5 gal.
Plasticizers Group
Aroc.lors Dlbuty1 Piitnalate Dloyciohexyl Phthalate Diethyl Phthalate Dilsodecyl Adipate Dilsodecyi Pnthalate Dllsooutyl Phthalate Dlwetnyl Pntnalate Dl(n-0ctyl, h-Decyl)Adlpate Dloctyl Adipate Dioctyl Phthalate Diphenyl Phthalate Dytrol
IIB-20 1113-40 Mod Epox Montars Suntlci,,er 1 -11
Suttticlzer 3 Santlolzer 6
Sundolzor y Santlolzer E-15 Santlolzer B-lb
Santlolzer M-1Y Santlolzer 141
Santlolzer loO Santlolzer 165 Santlolzer 213 Santlolzer 214
Santlolzer 216 Santlolzer 409 Santlolzer o02
5 sal. 5 gai. 250 ob.
5 sal. 5 gal. 6 gal.
5 gal. 5 gal.
5 gal. 5 gal. 5 gal. 400 lb.
5 gal 5 gal. Lj gal. 5 gal. 50 lb. 360 lb.
45 gal. 5 gal.
250 lb. 5 sal.
5 gal. 5 gal.
5 gal.
5 gal. 5 gal. 5 gal. 5 gal.
55 gal. 5 gal.
1000 gal.
Basis lor Exemption
size NIH (Not ii size
size size Will
size Non-toxic size Non-toxic NIH NIH NIH Noa-toxic NIH NIH Non-toxic size Non-toxic NIH NIH NIH NIH size HIH HIH size EDA PDA NIH FDA NIH NIH NIH NIH size NIH size
MONS 097571
Product Name
Smallest Standard Container Size
Plasticizers Group
Santiclzer 0O3 Santiclzer 030 Santiclzer uji S rulicizer 030 Santieizer oJt-'t Sanlolite M-H-P Santolite MS 30`S Solution Santomask II Santonox Santonox H 'Pripiicnyi Piiosphate Triphenyl Piiospnite Santiclzer '405>* Santiclzer liy*
5 gal. 1000 gal. 1000 4ai. 1000 gal.
3 gal.
7 gal. 3 gal. 1 gal.
55 gal.
55 gal. 225 lb.
5 gall 5 gal. 55 gal.
Petroleum Cnetnlcal3
Defearner PC-1244 Deloamer PC-1344 Santolene C Santolube 31 Santolube yo Sautolube YO-A Santolube 311 Saritolube 312 Sautolube 353 Saritolube 401 Santuiube 4.L0 Suutolube 41j Sautolube 4-y3 Santolube oil Sanlopold S SantoDold 22 BI HT 2 15-D SM* Suntolube u02* Santolube 002 SM* Pydruul F-y Pydraul AC Pydraul 00 Pydraul 100 Pydraul 000 Pydraul 023 Pydraul A-200
5 gal.
5 gal. 55 gal. 55 gal. 55 gal. 55 gal. 55 gal. 55 gal. p4 gal. 54 gal.
54 gal. 33 gal. 54 gal. 54 gal.
55 gal. 51* gal.
5 gal. 55 gal. 55 gal.
5 gal. 5 gal.
5 gal. 3 gal.
5 gal. 5 gal. 5 gal.
basis l'or Exernptli
/V/
NIH size size sl.-,e NIH NIH NIH Non-toxic size size sl..e NIH NIH size
NIH NIH size size size size size size size size size size size size size size NIH size size NIH NIH NIH NIH NIH NIH NIH
HONS 097572
-5-
Product Name
Smallest Standard Container Size
Basl3 for Exemption
Petroleum Chemicals
Santowax It OS-100 Crosyl Dlpnenyl Piiospnu^e Pnuataue (MOP) Trierosyi Phosphate N-JO Cooluno.1 4 y OS-45 (Types III & IV) Skydrol Skydrol 500 Skydrol 500 A Skydrol '(000 Aroclors Coolanol j5 lnertocn PPO Pyranol 14oY Pyranol l4yo Pyranol i4dl Monoiaopropy1 isipnei.yl* OS-dl* Santowax OMP*
os-t>y* OS-dO* OS-12A (Skylube oOO)*
75 iu. 5 tial.
55 sai. 55 dai.
z,al.
55 e;ai. 1 qt. 1 qt. 1 qt. 1 qt. 1 qt. l qt.
5 oai. 1 qt. 5 dal.
5 &al.
5 Kal.
5 bill 5 tjai. 5 sial. 5 oal. 1 aal. 1 ^ai.
5 dal.
sl^e hill site si .e size size
NIH NIH NIH NIH Will
NIH
Mill NIH NIH
NIH NIH NIH NIH NIH NIH NIH
NIH NIH
Hosin Materials
Adipic Acid
50 lb.
Benthai
200 lb.
Olsplicnol A
50 lb.
Dibutyl Fumaraue Dibulyi Maloate
55 dai. 55 cal.
Fumarlc Acid
50 lb.
Maleic Annydridc
oO lb.
Plitnullc Anhydride
do ib.
Succinic Anhydride
250 lb.
Hydrogenated Bispnenol A*
45 lb.
Piiosiyard C-22-H*
5 tial.
Tetrachlorobisphenol A*
50 lb.
Tetrunydrophthaiic Anhydride * early sta.^es-not l'or
sale
si,,e si.,e NIH size sice 3lze size size 3i.,e size NIH NIH
NIH
MONS 097573
-6-
Product Name
Sniailest Standard Container Size
Paper Chemicals
Mersize CD-2 RM Dry
Mersixe RM 70 & 77# Monsanto Penta Monsanto Penta (Oiled)
bO lb. 30 lb.
bb sal. bO lb. bO lb.
Rubber Crtemlcaj.s
A-32
IbO lb.
A-.100
lbO lb.
iianuex
bO lb.
Piectol H
bO lb.
Survooricx DD
25 lb.
SariboJ' i-ox VlJ>
bo lb.
Sautoliox AW
2b lb.
Santownite Crystals
IbO lb.
Santowlilte Powder
125 lb.
Santovdill.e MK
2b to.
Santownite L
'10 lb.
DPCI
50 lb.
Quanta!
50 lb.
Santoeure
40 lb.
Santocure NS
40 lb.
Smtocure 2u El-Sixty
17b lb. 50 lb.
Mertux (MBT)
150 lb.
TIUotax (MBT)
bo lb.
Thlol'ldo (MBTS)
50 lb.
A-l (Thiocarbanilide)
50 lb.
Santovar A
150 lb.
Ela3topar
2 lb.
Suil'asan R
17b lb.
Insoluble Suli'ur DO
50 lb.
Tblurad
100 lb.
Mono Thlur'ad
100 ib.
R-2 Crystals
50 lb.
Accelerator B
200 lb.
RZ-bOA
40 lb.
RZ-bOB
40 lb.
N-4-DlnitroBo-N-Metnyl Aniline*
Santol'lex CP*
Santocure MOR*
Development Products
Basis iur Exemption
size size size sl/.e 3i..e
size size si,,e size s i 1; e size size 3ize size size size si..e size size size size size size size size size size NIH size size size size size size size size NIH NIH NIH
HONS
SANTOCHLOR (para-Dichlorobenzene) Acute Oral Toxicity: LD^q In rats - 2620 milligrams per kilogram
Acute Oral Toxicity:
DIBUTYL PHTHALATE
Approximate oral lethal dose in rats 5000 milligrams per kilogram
DIETHYL PHTHALATE No toxicity data. Safe as a plasticizer for food packaging.
DIMETHYL PHTHALATE Acute Oral Toxicity: LDun in rats - 6.9 milliliters per kilogram
DIOCTYL PHTHALATE
Estimated Acute Oral Toxicity: LD50 in rats - 30,600 milligrams per kilogram
DYTROL (Santicizer 141)
Acute Oral Toxicity: MLD in rats - greater than 24,000 milligrams per kilogram
SANTICIZER 140
Aoute Oral Toxiolty: LDcq in rats - approximately 2000 to 5000 milligrams per kilogram
Acute Oral Toxicity:
SANTOMASK II
LDcq in rats - probably more than 5000 mllli grams per kilogram
MONS 097575
2TRICRESYL PHOSPHATE Acute Oral Toxicity: LD50 In rats - varies from 500 milligrams
per kilogram to 5000 mg/kg PHOSQARD C-22-R ' Aoute Oral Toxicity: LD50 ln ratB - approximately 2750 milli
grams per kilogram SANT0ER1TE (Pontaehlor aplitrmjl1) Acute Oral Toxicity: LDc0 in rats - 90 to 300 milligrams per
kilogram.
MQNS 097576