Document QX3B6kGwo81mN630NNVazdwOR
BIPHENYL 03 - 1 4-1985
AQUEOUS MIGRATION, METERS
HYD/GRD
DAYS
. 00 1
1
. 00 1
7
.00 1
30
. 00 1
365
V
.01 1
rv.
.01 7 . 0 1 30
. 0 1 365
CLAY
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
.1 1
.1 7 C-V\ . 1 30 y.y* . 1 365
0.00 0.00 0.00 0.00
LOAM
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.04
SAND
0.00 0.00 0.00 0.05
0.00 o.oi 0.04 0.46
0.01 0.09 0.39 4.81
GRAVEL
0.87 6.06 25.97 316.19
8.66 60.60 259.71 3161.94
86.57 605.99 2597.08 31619.45
DAYS TO REACH 3 METER GROUNDWATER, WITH NET 1NF1LTRAT1 ON OF 40 CM/YR BY VAPOR D1 FFUSION AND/OR AQUEOUS M1GRAT1 ON
C/CO j#
.00000 1 .00001 .000 1 .00 1 ' _ .01 .1 .2 .4 .8
CLAY
140.6 17 1.6 220.1 304.7 486.3 1103.2 1684.8 3171.6 9617.3
LOAM
1335.1 1630.8 2094.5 2905.7 4656.5 10714.9 16573.2 32141.3 1 07227 . 4
SAND
2 15.3 262.4 335.7 462.9 732.2 1615.5 2409.6 4306.3 1 1 300.7
GRAVEL
12.5 15.3 19.7 27.4 4 4.1 103.4 162.8 329.9 1297.5
DO 074443 confidential
B 1 PHEIMYL 03-14-1985
VAPOR DIFFUSION, X=METERS TO C/CO
C/CO
DAYS
CLAY
.000001 .000001 .00000 1 .000001
1 7 30 365
0.251 0.664 1.374 4.795
.00001 .0000 1 .00001 . 0000 1
1 7 30 365
0.227 0.600 1.242 4 .332
.000 1 . 000 1 . 000 1 . 000 1
1 7 30 365
0.200 0 . 528 1.093 3.814
,00 1 . 00 1 . 00 1 . 00 1
.01 .01 .01 .01
1 7 30 365
i
7 30 365
0.169 0.446 0.924 3.224
0.132 0.349 0.723 2.524
. 1 1 0.084
. 1 7 0.223
. 1 30 0.462
.1
365
1.612
. 2 1 0.066
. 2 7 0.174
. 2 30 0.360
.2
365
1.256
. 4 1 0.043
. 4 7 0.114
. 4 30 0.236
.4
365
0.825
. 8 1 0.013
. 8 7 0.034
. 8 30 0.071
.8
365
0.248
LOAM
0.082 0.216 0.447 1 . 559
0.074 0.195 0.404 1.408
0.065 0.172 0.355 1.240
0.055 0.145 0.300 1.048
0.043 0.114 0.235 0.821
0.027 0.073 0.150 0.524
0.021 0.057 0.117 0.408
0.014 0.037 0.077 0.268
0.004 0.011 0.023 0.081
SAND
0.202 0.534 1.106 3.861
0.183 0.483 1 .000 3.488
0.161 0.425 0.880 3.070
0.136 0.359 0.744 2.596
0.106 0.281 0.582 2.032
0.068 0.180 0.372 1 .298
0.053 0.140 0.290 1.011
0.035 0.092 0.190 0.664
0.010 0.028 0.057 0.200
GRAVEL
0.844 2.233 4 . 624 16.133
0.763 2.018 4.177 14.575
0.671 1.776 3.677 12.831
0.568 1 .502 3.109 10.848
0.444 1.176 2.434 8.493
0.284 0.751 1 . 555 5.424
0.221 0.585 1.211 4.226
0.145 0.384 0 . 795 2.775
0.044 0.116 0.239 0.835
DO 074444
CONFIDENTIAL
APPENDIX A
9* MIGRT' SOIL AND GROUNDWATER CPD MIGRATION ESTIMATES
BIPHENYL & 03-14-1985
^ MOLECULAR WEIGHT IS - WATER SOLUB IN mg/L IS
VAPOR PRESS IN mm Hg IS -vf INPUT KOW ?N
IS COMPOUND A LIQUID ?N DO YOU HAVE AN MP ?Y MP IN DEG CIS: -9
154 6 .1
71
KOW= KOC= BCF = KWA = D1F-A1R
10150.92
LOG(KOW)=
6395.08
LOG C KOC) =
507.5 1
LOGCBCF) =
7.11
= 0.806E -0 1
4.006 3.805 2.705
Baner ]ee/Ya1kowski '80, EO 6 Karickhoff/Brown '79,EQ 5 Vei th/Defoe * 79
SOI L CONDITIONS & SOIL/CHEMICAL PARAMETERS
-jj
CLAY
LOAM
SAND
GRAVEL
P
POROS1TY AIR FRACTION
WATER FRACTION
BULK DENSITY
PERMEAB1L1TY
s ORGANIC CARBON
RF-SOIL COLUMN D1F-SO1L
0.40 0.20 0.20 1 . 50 0.IE-06 0.0010
0.0654 *
0 . 1 52E-03
LO CM
O
0.50
0.25 1 .25 0 . IE-03 0.0145
0.0069 0 . 16 IE- 04
0.30 0.15 0.15 1 .75 0 . IE-02 0.0010
0.0457 0.987E-04
0.50 0.25 0.25 1 .25 0 . 1 E+0 1 0.000 1
0.5010 0.172E-02
FRAC IN AIR FRAC IN WATER
9 FRAC IN SOLIDS
CO-SOIL TOTAL C/CO FOR 1 PPM
0 . 003 0.020 0.977
58.924 0.01697
0.000 0.002 0.998
697.176 0.00143
0.002 0.013 0.985
68.175 0.01467
0.032 0.231 0.737
6.507 0.15368
VAPOR MIGRATION, MICROGRAMS/SO CM, ZERO TIMECC'O) TO GIVEN TIME
DAYS
CLAY
LOAM
SAND
GRAVEL
1 7 30 365
0 . 690 1.826 3.781 13.192
0.280 0.742 1.536 5.360
0.417 1.103 2.283 7.966
STEADY STATE FLUX THROUGH 1 METER SOIL, MICROGRAMS/SQ CM/DAY
3 CLAY
LOAM
SAND
1 . 55
2.42
0.87
2.903 7.680 1 5.899 55.477
DO 074445 CONFIDENTIAL
GRAVEL
2.42