Document QJOokMGRwEJEXBq0rvvYoYNY6

..... .......... iin.ilu iim .im. E. I. DU PONT DE NEMOURS & COMPANY 256 VANDERPOOL STREET NEWARK, NEW JERSEY >Hir m r et ur n t o JACKSON LABORATORY f il e r o o m y j'-y s ^ y y 1 NEWARK PLANT PIGMENT COLOR RESEARCH REPORT STUDIES OR ACETONE MILLED EG TYPE PIGMENT Period Covered JUNE 1974 TO FEBRUARY 1975 (PART TIME) FILE: DATE: 223.4 9/9/76 NJ 5049 N35364 ..... .... | , , KN-76-7 /) NEWARK IliNf Issued 9/9/76 Copy No . 14 PIGMENT COLORS RESEARCH AND DEVELOPMENT REPORT E. I. DU PONT BE NEMOURS AND COMPANY TITLE: STUDIES ON ACETONE MILLED BG TYPE PIGMENT Work Done by - J. Jackson Report Written by - J. Jackson Previous Related Reports - None Project Code ** 4671-400 Period Covered - June 1974 to February 1975 (Part Time) Notebooks - E6124 - 6147 ABSTRACT Attempts to achieve the quality level demonstrated by laboratory and semi works solvent milling at controlled milling temperatures 30-40C in the plant were unsuccessful. Factors contributing to this are: 1) Lower than, optimum grind temperatures 2) Poorer quality grinding media 3) Lower quality acetone 4) Use of Triton X100 in plant mills Prolonging the standard grind cycle at Newport will not compensate for the above differences, particularly the lower operating temperatures currently utilized. DUP050109058 6S060L0S0dna asi uo uo-pqnqiraqsTa L aStea S aSa <7 38B5 i sSBa Z aSad 1 33b ,j I aSaa I aSea: T aa saotraaajBg quBia *0 s^aoM-paas *3 t<neaoqi3'i *v -[Battanipaadxa sriqaas quaqea *a i ^*11 aariqna aoj euopaBpusnunotJB^ * m suopsn-pouoQ ptiB aasuramg *U siuaiNOD ao aiavi uo-paanpoaatii *i 09060 Losodna Xpnpg spqq up paaaAOOspp s b/i aanpau apqaquapad 30 Supqpou uopupdo saappa/i aqp up snxvis iKaiva *a i (5s? pug) sopnao papaposp prre papaaap ppoa go asn agaSggsaAup (z PB auopaoB up raapsXs pasopa up XpagBs SuppupaS go suBara apaSppsaAui *(p3o0t- sraoa agoiiia ma HouvQKawkooaH -`in gpoapttoo Supansaara aanpaaadraap pus fsopg aapBm apartbapaup jo asnaoaq `quamdpnba puaaano qppA paAapqoa aq pouueo SAoqe aqp go uopponpoadaa puapg mnrappdo sraaas 0o0t?-G 8uaa aAnpaaadmap up Suppupag papopgauaq ApqSpq oae sapoAo Suppppra paSuopoaj nmmppdo sraaas auopaoa snpd %86 Xpppanb qgpg (mnmpqdo sraaas auasoaaq %p uaqp ssap) apoAa apnao papppmaad anoq 5 ( (Z (p saaa aouapaodmp aofaui go saopoag apaos sqaoa-praas b u o papaapsuomap Apaaapo uaaq saq audpaoe up Suppppra ppeq Aq puaraSpd adXp Qg 8 Apppanb qSpq Xu q a b op (apaqs paqaSaaSSa XpaaaAas - sappppapsXaa ppants Xparaaapxa ~ $/ go aanqxpm) goi papppmdad paaAUoa op Xppppqa aqp SKoismogoo cm XptWMls *ii `(tazi`S2P-886T sqdaSoaopm uoapaapa aas)'(I-GSE-XS aappams aqp apqmasaa Xpasopo aaora qppqa eaxa papsXaa BAaq a-i6Z-XS UBtn asuapup aaora aaa qopq `spuaragpd papppm auopaaa Xaopsaoqag *(T *ON *3H) saouaaaggpp aopoa qqp. aqepaaada pou saop qpppa aupp Xaa-x (ran tp* sA ran go*) spxa auo up a-8E-iS 3 uzps aqp aopftq puoqa a-ZSZ-XS qppw pappuBpsqns sp azps aqpppaqsAao up saouaaaggpa *(Suppppra Uopsaadspp a-8-XH puu Suppppra quaApos xa a-Z6Z-Xa) squamSpd asaqd-g cap aqp uaataqaq saauaaaggpp aopoo opsaq aqp aog suosaaa aqp op papoAap uaaq saq Xpnps apqaaappsuoo , o*HgpECos)sPY ' qppra SUppppm uopsaadspp apA apera sp qopqa (a-E8-ia) udXp a98 aqp aqpp aaora `puaraSpd asaqd-apaq asuapup aaora aauaaaS 5aaSuoaps `auopssam puaaadsuaap aaora - aaqaap aAapqoa op pdraapps ua $aa sappnps asaqp go pOafqo aqp (a-Z6Z-IS) 3dXp SOS sqi 30 Xpppanb papppm puaApos puapd snsaaA Xpppanb papppm puaApos Xaopaaoqap go saSapUBApa aqp Supuaaouoo e(saaqpo pua p gag) Xaopaaoqap aqp up apara suoppaAaasqo go aacpnu a `aoppoead op aanpaa pua Xpflps op papsanbaa sm aappaA aqp -X- KoixonaoKtHi *i 1-9060 i.0Q0dn a aqa SufSSofoia' rnoaj paaapjsuaq pue aopaadns 4t5HSpis s e m (pBapapla % aaqSpq) 3uppupa3 aaasB,j *%CCI 03 gg raoap SnpSuBa ixpu Up paads xeopapau JO % q paaoajjBun ^Xtup3uassa Bxaa, auf *zo 8 up apa/Co aq ZL u aop spBH (aoqs ,,8/T uS 009/TM>*V paads OdT/^uamSpa aS pp) spupa3 AtopBaoqBp ' % pBopapao SupXaBA-HaS ssaooaa o n u t ih xaoivsom mo saianis auapBApnba papppmaacT aqa oa qSnoaqa papaxBD qou sua /pnas aqj ($sy `jafl aas) (Xianps spsaqau/Cs 30 dn qaoa auppBqpB) apnao op aepnSaa snsaaA sqonpoad aopaadns 0a b8 Xaanps spsaqauZs 30 auamaBSia ppae (paaosaaxa *OSeH) BpA papaposp apnaa adfo 53/dO pan S (psaaposp "OS'H)PU*0 01 pnpntaBq sp auaauoa anasoaaq SupseaUDUp paEptreas a-Z63-IS pus * spoaanoa 231 papppmaad 05 aopaapup `paaaadxa sB `aaaa paupaaqo sqaupoad aqp squaquoo auasoaa^ Sup^XBA-apnao 37 gupxppni qBX BpA pas a-z63-IS 9 aopaadns saanpoad pappap^ puB axquadaooB aaajn ppa 333 %g*86-S*6 auasoaaq %Q*p-S SupupBauoa ZOI auaauoo anasoaaH-ZOl * (aaEa uopaBtnaopsuBaa asBqd SupaoajpB pupaS Jo aanaaaadmaa) `jCaa-x jq apqaaaaaap s Ab a x b aou s b a a punppsaa dqp (sanpBA aopoa Zq paSpnf s b) asBqd-8 oa dpaaapdnioa aaaAuoo aou saop qapqu pBTaaaBta asBqd-n aApssaaxa snpEauoo pBpaaaBin papppraaad aaSuop *asaq s ba Suppppm -aad *aq g sanoq 8X-9 tnoaj Supguaa sSuppppn Z01 jo apuui sua uospaBdaoo y apads Supppptaaaa 30 dpnas-ZDl SMOISfllONOD 30 XdfllS 1 C-1?3T93 gp CETI 8-172193 91-173193 CZ6-173T93 gg_ gV- S-V3T93 8308333333 sonso oEnirasa cow sonao h o ssionis ssaooad spqa SupaoapjB saaaaniaaed snopiBA aqa 30 aaUEaaodmp aqa aaBSpasaAup oa dn aas s b a ttreaSoad y sappnas XaoaBaoqBi *y I?IK3HI33dX3 *A -Z - 29060 i-osodna * (spuaraSpd uoppnp - aa-qaa/i (s,pm aapqSpp) spanpoad aopaajttp pappapX pp auasoaaq `attapaaag * auazuaqoaopqapap `auazuaqoaopappoqpao auazuaqaopqoouam %z jo uopppppy saamaojsueaj asqg g= aAppoy qpp* pupag-OQ apa SuppupaS aapsaj a apqpssod aqum 30u ppp .gjqa jo uopppppy (%S-Z)a/wo33ov qpp pupag-og ppjauaq pspaopoupp qawoag papsAag ou pq ax-033 pua saq g - ZOT Suppppmog apqxqui up gy-OdD jo asq S3IVH HIMONO TVISAdO MIT? 01 SIdK3IIV NO SEICUIXS pappnps pou s ssaooad Apppsini) aa/iop uo paajpa sap `aanpaaoad Suppppm Apppunb tppq uo sappaadoad pspaopoupp pspopjauaq XT'6 poq aanpaaoad spqp e py aouasaaj up uopposapxg ppay ____ * Appsuapup ppjauaq XpqBpoaadd aou ppp uoppoaapxa ppOB aqp Supanp (pqSpaa puanSpd %z-p) XPPS ao ^oao'^N * B0PDK jo uoppppp aqp uoppouapxg ppuy uappBp-pto Noiiovaixa n o saitmxs pappprao aq ppnoqs puB pnjmaBq pttnoj $m aoppoBad puapd up pasrt puaS spqj OOPX uoppap jo asq qsp qaB*aji pa pasn AppzBuppao auopaa Aau snsaaA sppnsaa aopaajup ppapA op puno| s b a auopaaB paaaAoaaa aaod^aq auopaoy paaaAooag paodwa^ puatnSpd aappaq sppapA poqs qxBttBfj Aoqs spuampaadxa apqBaBdinog `sqaafaa SupaBaq PPq xasas ,48/I s4qa*iaH treqp pazps Appeoppuaaa aaora sp poqs pUBpd paodwaN poqs PUBp^ paodiaaN apaXo psaSuop - pjdH PsaqSpH - opqsa auopaoy /OdD psaaop *a*p SuppUpaS rnnrapxBm qppa paAupqo sppnaaa psag saouaaapppp appupjap pnq pperas oqs auopaoy oo OOP aad 201 *sa3 sp`zp`6- jo suospaBdraog oppag auopaoy/gjg * saq u pus gp uasApaq anooo saSuaqo aassap qonra **saq pz usqp ssap up anoao saSusqa mranpxBH apoXo piieaaoup qppa spanpoad asuapup aaou ~ aauaaaS - aaSuoaps XauaaBdsuaap aapBdaS `auopssen jo qpdap up BBBaaaup aApssaaSoad Aoqa pua q8pq pB apam spupa8 aq ZL-*lZ jo Xpnpg apoXo SUppppM puaApos qap - - PS-92P93 15-172193 6<M7ZP93 Z9-9ZP93 69`P-9ZP93 6S-17ZT9H 65-VZI93 C9-t2I91 L-nxm 9-92193 e9060iosodna *a-8-ia p u b a-6Z-ia osxB pu b (pupxS aq zi Q/3 6-t?ZT9a) pepppm AioqBXoqBp pBpaaqBui antes aqq snsxaA qsBW HO*HM `uopqoBaqxa ppoB paBpueqs b aaqjB qno paqqhx aza sqanpoad aqp aqp *XppBu.iaqiip q o 0V 03 dn Supgusa saanqBaadmaq qB apBta sew pupzg aqi saq & 2* <z *Z/T 82 st?2 1* uaqBq aaa* sapdntes * (T`21 *8-^191)' 2aoqBaoqep aqq up Xpnqs aApsuaqxa aaqjB pasn sfe (oBZT qop) Z01 **H 6 `Bpem S6& was 6 5B pupag (pppm pBS 8S/qoqs paaqs ,,8/P qt 996/euoqaoy qp 602/91 22) paBpueqs Y LZ900-Um sqaofl-pmag up sappnqg *q aaqaa %g - auoqaaB %gg pppra quaApsoo *() auapoaad %ot - auoqaav %06 ITT quaApsoo (p) papppm auoqaoe qap poaquoo (p) aseqd aoBaq aAaq Xeiu. squaragpd xaqqo * Z'9T apqaqoaqap o j j j # ppup ps 26 q pa pa a pSA as qpsA *qup ps 66 paa `a3 ps SA aq asuaqup aS 06 paa aqAA qpAA i i i 2/T SI Z/I ST 21 St S2* asuqd 8 62* #asBqd 8 S8* asBqd 8 98* gdsaqd 8 lira SIS 151 m 02*6 3B sapqaadoa^ qtvoqnq qdPPM 3IH t*2 2*6 OT3S ^H-X () E2S^2T9a (z) azs-moa (T) V2S-172T9H 0SI86 P3S a-262-IS sapqaadoad pepaoqaupq qqpa uopqepaaaoa apqqpp AaaA paAoqs anpBA aopoa up Supiapjpp XpappA sapdnres paxaAas jo uopqBupnrexa Xb i-x quaqod ApaApssaaxa quaApos*tsqupq aappnp aaqBaw. *s,iw aBqqgpp asaaApe qaappa pensq auoqaaB srtsaaA /xoquBqspqBsun Az b a azaa <*a`g aaqgpq apqaxpsap) pouBdoadosp ao poqoapB pXqqa 82 3 ^P^SS apapoxaa; quaApos aApqoB aaom moxp asoqq UBqq s,iw xappnp xaqBaa s (b j aaqqSpp) asxo. U3A8 3XB qopqa sqonpoad aopaajup 3AB0 sqonpoad xopaapup 3a b S auapoaaa %S- uopqpppy BqqqdBM aHA /auoqaoy W" pupxo-oo auoqaay 3 pBaqsup spoqoopv 30 asn Xpnqg 0*H %S-Z q3P pupxg-OD auapoxa^/auoqaoy qqpjst pupig-oo S6-42T9KS 9S-21?T9a 2S-B2T93 ZS-172T9H *90601, OQOdna paqoeqqa L -o h 'jaq sag *wepd poa (2900-^1) sqaa-pm3s iSuppppra (2P-92I9H) /aoqaaoqBp b qSnoaqq psaoppoj poa paopBqqo sea (saq 6-09ZI) 201 paaposqs y 266'166`066 ^ Tttepx (I `(a`2T`n`0I ` J^) pnjsssaans qoo aaaii. SoppopaS paSuopoad q sqpnsaa aBppmps SASpqoa op sqdmaqqa snopaBA *3pBra 33A3U aaa* spupoS qons pus '3U3tadpnba pusssad qqp/i 0o0i?-C J aSaBa aanqaasdtiisq psqsanbaa aqq qe popaS oq spqBun aaea aqq paqaqs quapd aqx (paqoBqqB eapdoa g`8`^`9 'I33 ss) 'Xauuosaad qaodwas oq pauppqno saw raaaSoad quepd pasodoad B soopqBAaasqo snopAaad aqq uo pasag sSupxXTI*! qoaApos qoBpg jo Apnqg `0 Supxppm jo *saq gg 3B uaAa asaqd g 03 uopsaaAuoo aqapdnooup paaoqs `3X33003 3003930 aamop Supsn (aqoBH*H*y) 02900-9MS) 3oatnpaadxa aappmps y tTP Ts paa ps 86 a3qj& anbado pa`3T (saq 6*>Z900-*MS ba saq z/X E6-17S900-V6MS ana HIS ini II1H IH ITIVIH0I0MI1 * (ssap 00 saq g) asaqd g 03 Suppppmaad xa aanqxpm 8/0 jo uapjBmaojsuaaq ppdaa Kpamaaqxs paaoqs soopqBraaojsuaaq iCaa-x saq 6 aoj partoaS aaqa 03A3 sqonbapBop ^ppaqoq ponoj s b a ssaooad aqx quBpd sqq aoj raaqsAs apqBqdaooB aaom b sqam 03 qdmaqqa oe sa spqx *3303 qq&oaS asaaaoap 03 qdnraqqa u b op pasrt (gop) amqaaadmaq aaaop pos (3333 SoppupaS aanpaa 03) pasn qoqs paaqs z/T Odaoxa ZZ900-9MS aqpi ana s ba - 9S900-9Z MS sapqasdoad pBpaoqoopq coa jo sqosmSpd SopppspI jo apqBdBO sp aanqaasdraaq qSpq 3B Soppppra anoqaaa qsqq saoqs ssaaoad spqx *saq 6*-W teoaj saSuaqo apqqns qqpa `paopBqqd qoamSpd asaqd 8 poo3 paaoqs oaaqqad /Caa-x a3 qup `a3 paa 08 `Saqs a pa psA 86 `qm ps dsooaq a dsueaq a qp 3X3 qp `3x3 a-888-ia SA a-z62-ia SA ppnp aq `paa 33 WI lop pSA `833s pSAA HIS 13i anbado PSAA lira pa SAA *3p pSAA m 096-^2192 SA *saq 69 apa^o popaS pasBaaoop qapa asuaqop aaom `aaoaaaS - arm. `aaSooaqs - gxs `*3op aaom aappaa aaSuoaqs - xnx `qaeasdsnaaq aaom - T.rw `aaqaap XpaApssaaSoad s,XR woqs sqpnsaa aqx -S- S906cuosodna ___ STIOpappUOO pupag aanaBaadmaq qgpq sen 3ou ppp ou spqp (ZT *N 'J^a) pnjssaootisun XppBnba s ea (8*M7ZT9a Sil tip pspioosa - slop 69`T9`T99) (01 3^) tB-P3 nuapd papqa y (C np paepuBasqne Xx b a gapaq saop ppe saq *i pae eg *o is paasaa uaqa XpppBnb ^xoqoBjspqBBun Appepoa sea asap spqp papsanbaa se eanaEaadinaa aqa gupspea 300 pnq *saq gy 03 apao pupaS aqa guppiiaaxs una s b a (y-yZP93 aas) bLZ^LZ* LLZ PBP*3 auepd pttooas y (z '0o -' una spoaaaoa papppm qBt snsaaA ppnp pua paa - q %-Z 3M enbado aaora - aaaqSpp (2 apqponpoadaa jCpqgpq (p :&Ba Suppppra 3UBpd ___ pazps paapueas - -aq o *(266*166*066 s^opjjnBpd - pp6-92X93 panpaaqo 3ou sea papsanbaa aanpaaadsaaa qgpq aqa aeqa adaaxa auppano spqa paaoppop puepd aqj -g- 99060 i-osodna Z17X93 prar ^2X93 s^ooqaaoM pire sa-txatmms XxSW>H sux^xag *h -g saottaxarfa-a xa*au0 SA-8Z-T SuxxXTK 3U3AX0S aasuaxadmaj; qSpH - xp`q;jpBs-<I*v-pp *X 1?Z-XX-Zt 6Z9`TZ9`I99 0098H SOS psAox&aj gpA-pp *ZT U-6Z-0T K17 dOX 0098H SOS paAoxdmi xTA-rf `XT VL-LX-6 STB^O XtTW XXS JO *Pd3 - 4-L6Z-IS paAoidmi xpA-pp 'OX W-17Z-6 SOS Xx t s u s x u i paAoxdmi ygy i0X XPA-ldV *6 M-ST-6 SOS Xxxsttaqoi paAoxdmi pp JOX XaV-iPA *8 panssp xaAau anq pasodox-i - tl7 dOX `L U~ 1-8 TX^b (a-Z6Z-IS) SOS paAoxdrai sxaXT*A -PP *9 9A-8X-0T apnxo ox paaoaxaxg ppoy xpeqa-pnS',d*Y - rr * l7Z-l7t-8 ssaooxg SOS- apaxo ox paaoaxqxa ppoy xp`qaTias*a,T-ff *17 oz-es'ex-es'eT-zs h x *e "SZ6X XxanxqsA - pi ST Sr Xxas-pnaqo paaTSiCqa; ptce sa-pwjSxoui aa& pp YZ6X Xxenxqag 4C46X`ZT xaqnso3G`c/;6x`g2 xaqoaao - qaxaaeag: raaqo xeaxsXqj a^uaa *y *x saoHaxaaaa *x a -L - z906(Hosodna Xacssaoau aaa saSaeqd ananidjiYba aaqa *aou jf pus aqaas V*B"[d a uo 6-pqa Aprils u bo an aou ao aaqaaqw uxBaaaosa no tret) aonpoad paaaaaaxa auxx3!! Xb u o t 4U3au o o aqa tttoaj SuTax^saa qaqa treqa augtnSqd paxipn anaAXoa fjg asuaauj axcra papXSjit saq auasoaaq moaj apnao gq aqa aaexosx oa seaaoad opppoa na jo aan aqj ssao'oaa sba- aanao oi aaioyaxxa aiov laodMH SINaKDId ar `Huns *a *v ^6t *>T isnSny jCasaap &&& `apawati a^codadH * *tn$x4 * esnoaas *W *a uoaSupnxTM **3Td `TXH `I *0 azod/tan ` *m3xg `spaaq *4 *y aaodas `raSxa `xazaaft *H *H qaattaii ` *mSxa `aAtiaas *S *fl *00 atxaoaaadaa saosnSxa AMVdHOO QNV SHH0KaH m XHOd 1KT *1 89060 tosodna dTS/ff sups axqBXsppsuoo babs ppnoa uop3B3ttarap;iadxa pazps 3uap j*apqapuaxq sq 03 pasoadxa aq ppnoa Xpnps suepd e epA paAapqoa sqanpoxd aqp Xsppanb pus sUQpsppuoo juapd pasaadxa jo aApjeappup aq sou ppnoa toppanb asenrpqpn Pb Suppppo auojapa pro Suppppmaad xoj BapoXo pppm ipaq *a*p suops -ppuoo pansoa aqs `paupejqo aq ppnoo pepaaaetn poxsuoo pa^oeiqxa auppaqpa bu s x ba tios -pxadraoo pppBA qSnoqspv *sqaqtt-prasg aq^T pappnss uaaq sou saq aauanbas spqi spupxS *xq o - TXT aas tip papnpaqos - apnxo moxj ^psoaxpp sSuppppu S3S Z a3PH *V uoppaupraaq -uoo aonpax 03 aauanbas up ppptn anas naqs Suppnpaqos (s8uppppra Mq 0) S32 03 3iaA -uoo uaqs pua apnxa pasaaxsxa ppaa tooxj sSuppppm *xq 6 231 ao g aqsft *sqx ?* ppapX apnxa /aq- (ttopjezppexsnau qnoqjpa) qspa xasTTa *xnoq p PIH - 0o6 3 Peas *'OS'H *qp 60* SupupBSuoa jtaqea *qp X ppv `OoOe spsaqstuCs 'qp p ipaa ioj suoppppuoa Supaoppoj Supsn apnao soaaqxa ppoy 'z Kaxtips sasaqsuXs pJapuaps aqBft *p :aq ppnoa ssuamaapnbax aqp *3dao -Uoo spqs jo spepaq pazps quapd aqani u bo aa 30U xo xaqsaqa upasxaasa na& uajp apqBppBAB saa suamdpnba `a*p apqpssod sea spqs 3q3 ssnoapg 'H *a ^q Suamapass a up paspnsax apnxa papaaxSxa ppoa ue Supqsnt jo Ajpppqpsaaj aqs 03 ss sapxpnbup 3uam3pd ssa xopxadns a up paqpneax uopsaaxsxa auppeqpa jo paa3sup uopsoaxaxa ppaa epA pasaxosp apttxo j)q seqs paseoppup qopqa suarapxadxa ua passnospp iCp3uaaax p apnxo op pajoaxsxa PTOV pxodaait 83uattSp3 *xp `qspms * & *V W6P *8T xaqosao iasaap aaq `qxaaaH qaodaajg ` ssuamSpj `ssnoXSg *M *a sxodaaji ssuasnSpj *spaap `y qxaaau `ssuamSpa `supqxaj *h *g 33odaa{j *83uani8pg `pazsaft 'H *H qaaaan `ssuamSpi `aAiuss *S *tt too J**V& SUamsxedaa esuamSpj XNPdHOO (HIV SHIKHOll 20 XUOd 20 *2 *2 690601-OSOdna uopspApg a ptra H 3po/j? ttopqonpoud qtrexd qqpA aoTiajajjaqup azpnrpupra oq uoxqdn.Liapup qnoqqpA ssaaoud Asm noA 'spam uaaq aAaq sSupxipn aqq iaqjy Supxdnres jo anrpq aqq qa a;mq.ajadnaq. XXT XP^tisW PJOoaa asaaxg *osxa s.moq "pus <g qB saxdnres XBuopqpppa aqpx PX^o a aa 'sqpnuad uoqax jo .fiqqxpqaxpBAB jj `scmoq gy ptre sjnoq o qa uaspsq Autixs txp jo u o x x b3 x jo saxdnres rannrtupra asftx PX^o j h a^ sSaxxXpnsJtd aa-xqq 75b t io axqpssod SB uoos s b spupuB aqq aqBni assaxd `axnpaqos unoA j o j quSpuaAUoo qou sp spqq jp `jcaAaiaoH *t46X ' iCxtif pu b %6x -XX aunj? jo suaqqax Am up paqsanba.1 SAaq o m saxdnres aqq Buonre raouj %01 spuia paxxpnaaid aqq aqaugpsap XXI* 341 'sqpuuad Bupxnpaqos JI saunqBjadmaq asaqq qa sajnssajd euoqaoa TBtMOUOqB ou paAuasqo aAaq aju `OoOi~$ jo djrnq.B'iddniaq. XXT XBUuaqup tre qqpa apata spupjB asaqq SAaq oq asrpp PX^o a sg *s.moq gy qBnouqq o ao^j axoAo pupjc3 go uoxqaSuoxojd a Supfipuqs `aouapuaAuoo # qsapx-iBa rooi qa `sBupxXpn quaAxos gg aa.xqq zo OMq apnpaqos asaapd noA XXTM sapqjtadoxd g Bupqoaojdda jo uopqoa.ipp aqq up s ab sapquedojd asaqj saxoAo .pupuB pauaqqBuax moaj Bupqxnsao: 'qtrtq jo Aqpsuaqup japaaaB pua 'auoquaptm up ssaquaajcS pasaauoap iCouausdsaBuq pua qqdap auoqssam up sasaauoup paq-retn papBUpsuomap SABq sspioApuiag pus Axoqajoqax aqq tip Bupxxpn puaApos jo sappnpg * spuaraSpd adiCq cK)g jo ^qpxanb aqq qoaootdda oq s b o s puamBpd paxxpni quaApos $g jo Appsuapup aqq apauSdn oq BuppcBnappa Apnqs b up pa3a3ua axB an `ao u j [ tioA Sy ffmo OHiTiiw Tivg j o xanxs x iit t o s a-462-ia aaA.oaara JHOdfflSN W siNaroia ?IMX T `A V46X `X ^smSrxy ^asuap mag '^iatiafq uoqSupnxTM 'f*m3pd faxXH *d *0 quodkag ` mSpg op/ioq `y qaaAaN `'tnSpg aquBg -g *y qjBAag ` *to3pg ^supquag *H *g quodASN ` ni3pc[ ,rX `qqprag *g *y quodttaN ' "taSpg `xsz^SAi *H 'H qaBAaN ` `tnSxg `aAtutqg *g :q 0 hh'jJt A A r quaraquBdaa squamBpg juivdoraOD q n v sanoraN m iNOd na *i *a 0/060 i-osodna 1/ 0 00 00 Z^-00. *?k< JZZ* 'ZZn^?/2^ S-9 Z 'W ~zpy ^y^-zsz -jn? efAAJf?*&%?/' ^PWp J^PU,0l7^ ?ZZa^x<,?'24s'0^' >g&- '-*---^->^y p-pytX rf-p ^0 0PP7^ tP'tyi <t^r? 'z^^y^2/p v 0n<JH00 ^t PPPt P'PAPPP^y JZ^' 9vPt ? ^V <??&/r- -V -r * 4' * *^syiL <yy ^ Z^ eoZ TC't&jtypz? p? 0 00077^ ypZ^-pZ/^ -9/ p 0/ n P0 'pp-^'t-Jl,/ 7&S/J&J&<? * Z01 c; ^ <?/V P2>403?'?t/ 7?/2"`J pppjtf) ptynetirtjwf-fc y'cfow/tf -jJ? <?' M'f'# f: $ ri =?*? ------ 7^-- r"^`^'"*^y^-^/J 7} (xZi J yy&/.s.s/P! 0 (h%ba <1- <? c /j ?s -- 0f i-Z060i.osodna ypifc ;/?"te#///' 4'?ywi/r/c /Wy&J?S iys V* rwy p ifp^t c/ SJfl/**Z?-2ji'/g&0/fy s=tf?S- - -- <?,F ^ jW(J ,/Klf??{/ SM& z~ (g) p&pyv zjy fp/se '^fcfcr ^ t <'pmfJ+n// OPA'J'$ ^ r-A/s* Ju-2. </ &&tr. *#*&* ^a/T~p744t/ $**//'/* f'&y*? PA PSVc/os- - r<7/0VZY 0; UiqPvzJ-ijjf if' */ 0/ ; JUV(f i>^YJ0^/AS. > &/t*#p2SU -? ^,1 zz06CH0Q0dna Xc&/ 'z s^y rr/j ^ A-^/v /t j J,jf)(iQ^ , p ------------- ---------- \cvos^^s i" yJ- ^4 o >ssjj ezoecnosodna io h j j io o isontroM msiAmans wa? sim *r :a ms/'ifA " *uSX<&rs SOS .xaqoqoo aqq Sux*zl> sSajuuai aqq qaadao: XTT 'qogfqo qow op noiC j x awtq 2u|ttpa qqx& o ao j k &ix pqp qqSuajtqs? qSnoqqx (ijl/T/6 fTCA 05 Xf *o:aqqax) ajaOft Ai 3a t s 390X9 00:3a gSuxiITW o:noq-.& aaj:q3 qsotXJ 9qq sqotodeut w o s ^o t s x stitT^r *02~x q raw .Apsajrt aSwTXTT papuaqxa aqq qaada.* ptnoqs m `aiaqq araos gaps* Amu s s j x q aouxs aopAOJt Aqajaa qSnojtoqq.'e spaau Ooi?-S q SwTTXpa quaAxos quatd jo qdaowoa aqq *osx fjox sqqq otu 0$ papaau ajt quamdxnba gtrj -qspxs oq. suoxq-so-jjfpow jta/pxvs qwaradxnbs wsti qaqAi swxrooaqap qsnw Q& * qxratd .u aqq. oq s s ao x u ixoxqonpo^g ediCq-sagg pua gSS It aaqa ttP quaAxos aqq azxTTq diaq xtx pa qonpood addq-aga: ooj Aq.xoadao ino sasaa^aux Arexqwaq.od qx aouxs q-jJara sat* aoX SXWX ^qa-iado aqq ocoj pjcazat; Aqsjes a aaqaaora sxtpj. (Ao^quoa aqq 04 aowapxAa s sa{d;oM-paas qaaaaseH aqxdsap} xiP aqq ux aonssaod aq data ao:qq ,,oi?-5 q aatxTS ' jceqatuomaqq tnaqs Sixox a Suxen ptta ftt qq 9wt0fo ptta Euxddoqs Aq Axwo paonsaata aq tiao a^n^aotadiaaq. TITTM xawocsqux *osxv *-OfrS oq aanquiadTaaq xojquao oq qShoua Araqao:RPo ora.qai* pasaqa^fta o:aaam 03. raa aq aoix Asm aw ^aaeauuux Oq ^Iftqajcaswuaq. xxxra xx oq seqoq.xas woxi MOT atiij. yy'AdAq ptm mo x j ocaq.ajsi asaa^aap oq a m PXROM o 01j -S q XTT ox , 4 %S2 03 0St -ia mo w sao.oq-Btiadaja'}. npii xwJtqI "quxod peupa.taqsp -aad a Moxaq sao mo x j JqM j j siXT qq tmop qaqs AxXxqoqR ssqoqx^e mo ij ftog 0 sxiT qxraAtos aqq sxooo pasaqoawg 4uawdxwba qwat^ Sttxqsxxa qqx^ sxqq op q.owtmo h *agg oq. exq^vdmoo AqjBUdqaj qqjn SOS aonpojcd oq eQ1>Qij~<i jo a^cnqaoradDaq XXT xw^qwx tia qs ^uxxiPJ qwaAxos adAq^gxig paSaoxo^d ioj sxx3 qi *,uaqqxtw sa panssx pua paAOJdda uaaq qoti aaq dox SOETSi SMMI OSAOHd^lI :'t?l7~dOX tfA6X '8t Jaqtnaqdag ajcawaxsa eqaodnsu sm'i d *v uoq^eqwjad *0 sanoaqg *pj jjiupoo^i *a jaxEQa5[^as * qqxtns *d taaqaft *H wa^qSfnox *w o^nTOOK ,, - tsosiroax ^jcaMaH - aAWJtqg *S ttoqSuxwxTft ** Xtoa " *0 *00 qiiatuqoiBdaci sqttaSx<j xHvdwoo % smomm aa xaod na "i *& w.o6cuosodna XI XnOHXIM 33 OX Q3033V X.NVO DOA--AX33VS jgtutpooM *3 *D jexsuisipisg ''i *1 ssnoxqs *w 'd , TIH *A *0^ qqTWS *<3 *V/X23M *H `H uexufcnoT *w *s *o d Deo = rid^ jreqoqoO X03 Aquo xoAo V putJ6 go qssqea qq xnpsqos sextf qoC qq op qou TTTm euoie xx>Ao xns ae m. XT^un Apnqs 50 dAq sxqq qBxqxux oq quBA qou op I 'ssoxnossx peqxuixx quaaxno xno qqTM qusuiqseAUT Aiqeqoxd pue Apnqs queoxgxuBxs xxnbsx xxp* Xoxquoo anqejceduisq pqeAxa *pqsnb;t osje s x a x ^q&xq qq q xnqexsduieq BuxxXP11 loxquoo qouueo . 'qno pequxod Axqoa^^oo noA se aA/ioq -'Aqxxenb BuxAoxdurr uo qoajg sqx uixxguoo oq Apnqs xoAo puxab pepusqx qq unasx oq buxxXP4 S3B Bn- 'psssnosxp sq frU/fr Z/6 3<DQ "N UOl^d /U sos AiisNaiki aaAoadwi UOJiDOO*! uoj|0>0] 1 t^-dLOX pajcjns siwaa *A 1 UJOy siwaa T * A ... l * XL3MMM-rU AVS LNOO szosoi-osodna uopspApa a PB t j sfo/rf <*> *uaqpa si andares qoaa uaqa (pppm oanp aqoad Xq uaqBa) aanaeaadraaa pppm pauaaaup Xpddns asBapg apdraes Xaanps auoqaoe uotT8 x pa s b ppaa s b `qBqBq qosa X pasn (aq 6) ZDP 3 apdores appAoad asBapp apaXo (aq OX) iBatxou aqa up paAapqoa paaap qaSuaaas aop aqa jo asnaoaq pBapsap paAap paoS aqa aABpqaa oa apqBun aaa/1 a* anq *apoXa papas pasaaaoup eqa Xq tiaoqs aaua sauamaAoadnip psqaaq (a - a - V SIXTH) <64X~8LZ-LLZ saop 0098H) saonpoad qaa `aaoassam aqSpp UT paapnsaa pire asps apapaaad up aSaap XpaApssaoxa aaaa spoaauoa *aq ox aqa aaups Xaassaaau sp spqj, saanaaaadmaa apqBqpSAB Xpauaaana aqa as paasanbaa Xpaas apoXa pupaS aqa aaadaa *(0,,0$-Se) paasanbaa aSuBa aanaaaadmaa aqa aAapqoB oa anaradpnba aaBnbapaup jo asnaaaq * apqBppoAB sp Xpnas epqa aoj Xapap paSuopoad B pi *aaaaap SAOqB aqa oa Xpdaa up apBm sSuppppm ppaq aqa aBadaa assapg ,, W-I-8 Spaap *f *A - rr #J^a aiDXD DHiraw ppva 'do xcmis - miv ct-462-ia aaAoaata j-aodfiaN siNawaia s imp *r *& SOIID2U05 <7461 *4t aaqnaadas Xasaap waft `qaBaan uoaSuprapp/i ` *m9p3 `appoq *j *o aaodaa^ * raSp.j `ssnoaas *W *a aapdaaq **mSpA `spaap '& *y qaaaaN `*mSpj `supqaaj *h *g aaodaaH `tnSpg **ap *qapms *a *y aaodaau * *m3pa `pazaafl *H *H qaBaan " mSpj `aAnaas *s *M :d o auamaaadaa sauaaiSpg MVdHOD av sHfloHan aa inoa na *i *a 9Z06CH0G0dna 3po/ff Supiduies jo aupq ye aqoad Aq uajfeq aunqeaadujaq xrpn xeuaaqup pue Aunts auoqaoe jo uotteS p `pasn aptuo pairpaaocd jo *zo g appAoxd aseapa jaaqqeq xo %q $ sp Aqpmd auoqaoe qeqq upeqxaose ospe noA u bq *tpput %t( i tip sprau ospe uSpeduieo snopAaad aqq jo qsaq aqq s u m qopqM 055 pop qsupeSe apetti aq ppnoo suospjedtuoo pue sopqspiaqoeueqo pppui jo apqepxeA aqq aqeupuipta ppnow `aouanbas up ttpui auies aqq jo apfl apqejpsap qsoui aq ppnoM (tj pue o ye sapduies) sunoq oq uopsuaqxa `qpuuad squaompnbaa uopqonpoad j j sonoq 0 jo urrarpupm a aoj (pppm i,ai Atqeaajaad) pppur auiee aqq up spot Z03 qseap ye ptrpjS oq Supqsaaaqup qsoui aq ppnoM qp `uapuriq e jo qonui ooq qou sp qp jj auoqaoe jo *spe9 xgg pus ZCfl *sqt 09fr Sfcrpen pupjS oq aqpp ppnoMi aw `atunpca pasreaaoup aqq aqepoutMoooe ueo spppta sqq JI sopqea auoqaoe-oao jo iaqqeui aqq Apnqs oq aqpp mo u ppnoM a^ '0o0~0S JO aSusu aqq up paqonpuoo aaaw spupjS asaqp *squpq asuaqup aaom pue aauaaoS ApqipSpps Azq a pue squamaAoadop qqSuajqs (% ") aouput Apuo qoaqap o m sunoq Sfj aaqjv ijtj aox 0093N - soa aaAoadwi dHCHHSM sMiOld SD0I *f `A Aasaap waN `q.ieMaH uoqSupiuxpjvi * -uSpj `appon M *0 quodwatj <*u@pa*Ssnoaqs *W *d qaodwaN c,u0p<3 *spMaq qurnaw f`uSp^supypraj *H "3 qaodwaN **u(3pj `qqping *<j `V qaodMSN `utiSpj `pazqaft *H *H 3PBM3N e *ufipa `aAniqs *S `-Q0 quauiqredsa squauSpj xtwdwoo am sanc&EN aa mod m zzo6cuoeodna 82.060 i-osodna uofsfAfo: a pu b h sfo/rr aAp4oapqo spqq aAapqoB 04 paqsnpeAa aq ppnoqs sSuppppui aunquoactaaq cppt* qeqq aAappaq pppqs I *OoOfr"5 paqsarbaa jno MOpaq pppqs JB aqq amnsss vtpuo uso I (psqssnbea SB pappdcfis qou) `saanqBjadwaq Supipptu qq mo u j i qou op j eoirpg *009 pue SD9 uaaMqaq saouaaajjpp opssq aqq amoox3Ao 04 aqBnbapBup gp quaraaAOJdtrp aqq jo quaqxa app `(aiqBjpsap pauappsuoo p-ps) asuaqup ajota pus `.xappaa aatuoqqs qupq pus auoquapun aqeui pus '^ouauedsueaq `qqdap auoqsssm aAoadurp 04 sp Suppppw paSuopoud jo qoajja aqq `upaSy sappnqs opqea aawop snopAaad rnojj quauajjpp /CpquBopjpuSps 40a 9J3m. eqop owq uaqqo aqp auoqssBtH up qi^Pt AlBUopqdaoxa Supaq xL$ 4T U4PM. `pqBpjBA aqpnb s bm paupBqqs AqppBnb am s3ttoft puias up pappnqs sopqaa aqBpnurps Apasopo aaoux 04 uapjo up soppsu 09D/SUO4SOB <xt{3pq qs pei aaM qopqM aAoqB paqspp sqop aqq paupmexa aABq p 6l q 6izq `pqq sqm o q 9r m ten <iox - sag aaA.oaan te/62/oi t t a - rr dan E9CHMSK SJlEMDIdf SIM3I *f A nZ6P *TC jacpaoacf ilasoap MSN e3pBMiaH uoqSupuirpM e*w@Pd `9PP0H *0 4UodM3N trttpa *ssnoT4f 'M *<2 quodMON t*irSp<2 `spaai *d `V jptBttaN ufeta `supspiaj & *g qaodMptt `-uSpd **<if *U4PUB *d * qaodwajtf ``itSpd `pazqajyi *h `h 3PCBM3N **tlfip<i 'SATUpg *g *M 500 quaiuqjcBdaa squaufipj JJW9W0D q n v SanaTM m j mh m *i *a 6^0601-osodna paepueps aq pep sSuppppm puepd jo dn qacqi sanoq * 8 * 0 pe (iCapnts TeS uSaeqo Supxdmes - *saq gy pspop puppg - g daps (xeaaapup) o,,gc pe pupaS op se os aanpeaadmaq pXPTM peupopup pus `aspa aanpeaadmap aspen * Aopp aepe Supxioapaoo pop--saanpaoopd apnpoup op epppAap - i dapg (Appand pseqSpH) euoqaov * speS X99 asn <- 5 daps QOXX uoppai ppmo - daps Z# papsepead qpprn aSaeqo - z daps ts3ueqo SupaopxP u p qqpA pe*otxJ sq xiP f- dOS aanpaooad Suppeaado paepueps - y *K psap Paputt aiB sSupxXP auopaoe aAppeaeduiop poqs qaeAafl ueqp uoppnqpapspp azps up rapoppun ssap qontn sp poqs spqp (uoppeuSpsap aaqmnu xtTra ou> t ,SupxxP puaAXOs aanpeaadmap qSpn,, papsqst apdmes e paApaoaa aAeq a poadsaa spqp ax asn op aopPd `ff iCq paupmexa aaaq SAeq XTP" paapuoo poqs asoqA ptT e up apem aq XPP* spapaS puepd penpoe aqi - o j j Apppenb op pepuarapppap sp paapuoo aaqeA aApsaaoxg *suna asaqp pop auopaoe Apppenb pqeppeAe psaq aqp SupAeq pop Appppqpsuodsap amnsee pppA puepd aqj - % *op. asn paepd op aopad 'ff dq papsapaad pue appse pas aq pppn qopqA apnao papppm -aad pnoq g po saSPeqo paepueps apedaad pppA puepd aqj - p *o n eape spqp up uoppoe p0 uepd pasodoad Pno jo Sppepep SuppaeAPop me 1 `XaeiiuBf jo pa2 aqp uo paqoeea puaraaapSe aqp aad sy ONiniit iNaAaos aanivaaaHax aain laodwaa siHanoid (2) *ar `h x ir s *a *v is*. f"V SL61 `82 4aenuep dasaap a s h * qieAaq uopSupraxpw * m3p.dL_i-a^T^t ppodASK * *mSpx * s p a s '! uopSupmppfi `m3pa <spAeq paodASN ` *mapj *pezpa/i qaeASit m3pd * aAnaps *d . *4 *y 4h *S *W ri" r I** puamppedaa spaaniSpj ANvaKoo q h v saflowatt aa xnoa na *i\*a 08060 i-osodna 4 uoTsiAfa a h UOS^O^f * s'*/.*-v:) ' tV A 3fo/rr sinoq pa3Bu8psap apBpXdoxddB taoxp jou sp 3B np moAj sapdraBs a*nps auoqaoB ^Ttt paApaoax apduiBs jp) pasn aq 03 3oqs pasn aq 03 ZD 1 pappptna^d ( (z (p Ipaxprtbaz sapdmas 1-8060 i-osodna Bxqxa 'ST exqxg n axnxg *ET xspuj qaodaa pmtrao - 4xe*qTI qaBflSM *ZT xapux qaodefc x bx x u q o - XxaxqxT siXBAaH TT ' rzzz - 3TT2 TBOpxaimH qaej&au '01 qXBttSH * t bSt ;3 *oaag *o *0 *6 aiod/43H * "taS-pj * Sf'V *8 ttOS^OBf *4 Arexqji/qTpaS *d "3 *V/'T^TB3 *3 T *9 stxeasK ` raS-ja *strpiasa *h *2 *S 4xXqpq/q3TBW *H/aAnx3s *S *tt ** j&rexqpi VodasKt aqBinox-po/qxodAau ` -m3-pa *3J3Br '3 *3 'Z Axvxqj'i ^XBasH/uoaSu-pniTM * *tn3ia *^Tn3 *3 *T HOiinarpsia