Document Ozjxm8m3dw9O0wxMvr3y9bnZK
ARns-0lqy
PRE-1976AETNTVAICRHOMNEMNETNTTAOLLSETTUTDEIRESTOONC.PAEUREFRLUDOARTOEODCMTAAYNE4,S2U00L0F:ONATES
/-
2--
3=
Data from Fathead Minnow Study on FC-93 (25% NH4 salt of PFOSinIPA and water), 3M
pErnovviirdoendmetnotEaPlAL)aboratory, Aug. 2, 1974. (Robust summary, MSDS and copies ofdata being
Data from Fathead Minnow Study on FC-93 (25% NH salt ofPROS in IPA and water), 3M
Environmental Laboratory, Oct. provided to EPA)
19,
1974.
(Robust `summary,
MSDS and copiesof databeing
pBLraOobovDri/adtCeodOrtyDo. ErCePsoAuml)ptsleftorioFnC-da9t3e:(2J5ul%yN18H, 1s9al7t,of(PRFoObSustinsuImPmAaranydawnadtecro),py3ofMreEsnuvlitrsonbmeeinntgal
04599
Pres--y
ACUTE TOXICITY TO FISH TEST SUBSTANCE
Identity:
Perfluorooctanesulfonate, Ammonium salt; may also be referred to as PFOS NHy' salt or FC-93. (1-Octanesulfonic acid, 1 11,2,2,3,.3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-,`ammonium salt, CAS # 29081. 56-9)
sample. Remarks: Test sample was taken from 3M production lot #1. The test
sample is a mixture of the test substance in isopropanol and water (25% test substance, 20% isopropanol, 55% water). No calculations were made to adjust for the actual concentration of the test substance in thetest
METHOD
Method: Not noted.
Type: Static acute
GLP: No
Year completed: 1974
Species: Pimephales promelas
`Supplier: Not noted. Analytical monitoring: pH and DO content Exposure period: 96-hours Statistical methods: Plotted LCso Test fish age: Not noted. Length and weight: Average length = 2 inches, Average weight = 1.5 9 Loading: Not noted.
Pretreatment: Not noted
Test conditions:
Dilution water: carbon filtered city of St. Paul, MN water Dilution water chemistry: Not noted.
Stock and test solution preparation: Not noted.
Concentrations dosing rate: Once
Stabilityof the test chemical solutions: Not noted.
Exposure vessels: Not noted.
Numberofreplicates: One.
Number of concentrations: five plus
Water chemistry during the study:
a
negative
control
Dissolved oxygen range (0 -- 96 hours):
04600
5.0-5.9 mglL (control exposure) 4.25.0 mg/L (100 mg/L exposure) pH range (0-96 hours) 7.0-7.1 (control exposure) 7.0-7.1 (100 mg/L exposure) Test temperature range (0 -- 96 hours) 21-22C (70-72F)
RESULTS
NEolmeimneanlt vcaolnucee:nt9r6a-thioounrs:LCBsk =co8nt5romlg,iL1.0,(C2.5l., n5o0t, d7e5t,er1m0i0nemdg)/L
Mortality of controls: None
Remarks: Additionally,
95% confidence limits testing was conducted
were not calculated for this material. on the mixtureofthe test substance
in
2mi0x%turiesoapnrdopnaontolthaentdes5t5s%ubwsattaenrc.e.ThNeovaatltueemrpetpworatsedmaapdpeliteos dteottehramtine
ttohxeiciimtypaccatnobfethceonptrreisbeutnecde toof tthhee Poerrgfalnuiocrosoocltvaennetsourlfwohnaattep,oratmimonoonfituhme
salt.
CONCLUSIONS
The test sample containing 25% Perfluorooctanesulfonate, ammonium salt exhibited a 96-hour LCs for fathead minnow of 85 mg/L
Submitter: 3M Company, St. Paul, Minnesota, 55133
Environmental
Laboratory,
P.O.
Box 33331,
DATA QUALITY
Reliability: Kiimisch ranking 3.
REFERENCES
This study was conducted by the 3M Company, Environmental Laboratory, 7/29/74 to 8/2/74.
OTHER
Last changed: 5/3/00
04601
D REE o AT ssra
|
Tost_oU LW aul static
Material
re ETI aa "Test Organi Fathead Minow)
Avg. Weight
Ting Started,
2:30pM
Plotted Lgy
Dutton wacer C0tban Pilfe edly wate!
Let
Size 2 Ymohes
BE pp
PT TBE we grep mA ea24thrs on
mem] togBd
52 su48nhtrsan 5
&al a0Tole]
i7e2 hsrs pt s9u6rherss gu 2
von[ila] vo:Filed
:
`anoon|Ftooeop[iafss]vhaoid[7dn] stoofFuolwal1o0og|fd |
so
25
|von Pole]
| ao[ols
oe lzlodao dud
ooJ2fuid] 0fede]
so Jui
co ry]
Doo aeloo olalun ful
Mersge Temperature 70|Jv|
n
Tal] |
0
|
: = oY Sk Clete Ce |
TREE ne
So intr Ll ISAT
In hme i= oT
T 5 LPL l
yo El hep Cl
rhe
boi0
Hl]
HLaA id
#
1 0" 10 4 30 5 50 =k 70 J 50 "100
:
%Survival
.|
|
: |||
04602 a
DMAATTEARISHAELETSAFETY
a3Mn center 5St5.144P-au1l0,00Minnesota 1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, ALL rights
r1e9s89e,rveMdi.nnesCootpayinMginianngd/oarnddoMwannluofaadcitnugrinogf
Ctohmipsany.
iisnfoarlmlaotwieodn prfoovridtehde
purpose that:
of
properly
utilizing
GM
products
1) tprhieorinafgorremeamteinotn iiss ocbotpaiiendedinfrfoumllaMw,ithandno changes unless
2) ndeiistthreirbuttehde cwoiptyh ntoher tihnetenotriiogninaofl iesarnriensgolda oprrofoittherthweirseeon.
TDIRVAIDSEIONNA:ME: 3M SPECIALTY MATERIALS 10FNOU-M0B3ERF/LUU.OPR.ACD.:Brand Etching Bath Additive IS9S8UE-D0:211D-e0c1e9m2b-e2r 107,0-511919935-00187-6 98-0211-0201-1 DSOUCPUEMRESNETD:ES:10S-e3p79t5e-m1ber 04, 1998
00-51135-09190:6
1. INGREDIENT
C.A.S. NO.
PERCENT
HAAMTMEORN.IUoMovPtEiRiFiLUiOnRiOeAeLeKsYiLnSnUiLaFnOnNnAeTEe.e.s.s.e.s.,. 2707008210-15862-59 19.0 - 5253..00 AIMSMOOPNRIOUPMYLPAELRCFOLHUOOLROA(LIKPYAL).S.U.L.F.O.N.A.T.E............... 6678-26530--007-4 0.1 - 22.00.0 AAMMMMOONNIIUUMM PPEERRFFLLUUOORROOAALLKKYYLL SSUULLFFOONNAATTEE.............. 6688225500--0098--65 00..11 .- 22..00 AMMONIUM PERFLUOROALKYL SULFONATE....... 68259-10-0 0.1 - 2.0
nThoetifciocmaptoinoenntsreoqfuirtehmiesntpsroodfuctTSCaAr.e inALLcomapplpilaincacbeleWitchhemtihcealchemical EixnigsrteidnigentCshemiincatlhisSumbasttearnicaels a(rEeINElCiSs)t,edoronarteheexEeumrpotpeapnolyImnevresntwohroyseof monomers are listed on EINECS.
2. PHYSICAL DATA
BOILING POINT:................. ca. 82 C VAPOR PRESSURE:................ ca(.In3i4tiamlm)Hg VAPOR DENSITY:.......errrrn... caC.alc1..0@Ai2r0s!C. EVAPORATION RATE:.............. <Ca1l.c0.Bu@OA2c0=1C. SSPOELCUIBFIILCITGYRAIVNITWYA:T.E.R.:...................... cmao.der1a.1teWater=1 PPERHCEINT.VO.LA.TIoLEo: .i..i..i..L.i.Li. i ccaal. 776 % Abbreviations: N/D - Not Determined N/A - Not Applicable
CA - Approximately
04603
DSeOcSe:abeFrO-9137, FL1U9O99RAD Brand Etching Bath Additive 2. PHYSICAL DATA (continued)
PAGE 2
VIMSEOLTOISNIGTPYO:ILNT:o...v01i01n110a110.00
N(D0.1% Nya
Aqueous)
APPLEiqAuRiAdN,CECAlNeaDrODaOmRb:er solution, Ammonia, Isopropyl Alcohol odor.
3. FIRE AND EXPLOSION HAZARD DATA
FFLLAASMHUPBOLIENTL:I.M.I.T.S..C.'.L.E.L.E.1..1.1..1.. N2i7pC Sotaflash AFULTAOMIAGANBILETIOLNIMTIETMSPE-RAUTEULR:E.:...........0. NN//DD EXWTaItNeGrU,ISCHaIrNbGonMEDdIiAo:xide, Dry chemical, Foam
SPpWEoeCsaIiArtLifvuFelIlRpErpeFrsoIstGueHrcTetIiNvoGerPcRplOroCetEshDsiUunRrgEe,S:deimnacnldudibnrgeathheilmnegt,appsaerlaft-ucso,ntabiunnekde,r coat panrdotepacnttisv,e bcaonvdesrinagroufnodr earxmpso,sedwaiasrteasandofletghse, hefaadc.e mask, and
UNUSSeeUALHazFaIrREdouAsNDDEeXcPomLpOoSsIiOtNioHnAZAsReDcSt:ion for products of combustion.
4. REACTIVITY DATA
STABILITY: Stable INNCoOtMPAaTppIlBiIcLaIbTlYe.- MATERIALS/CONDITIONS TO AVOID: HAZARDOUS POLYMERIZATION: Hazardous polymerization Will not occur. HAFCZlaAurRobDroOiUndSeM,oDnEAoCmxOmiModPneOiSaIa,nTdITOCoNaxriPbcRoOnVDaUpCDoTirSos:x,ideG,aseOsxidoersPaorftiScuullfautre,s.Hydrogen
04604
Abbreviations: N/D - Not Deterained N/A - Not Applicable CA - Approximately
DMSeDcSe:nbeFrC-9137, FL1U9O99RAD Brand Etching Bath Additive 5. ENVIRONMENTAL INFORMATION
PAGE 3
SPILL RESPONSE:
pRheyfseircatlo aontdherheasletchtiohnazsarodfs,thirsesMpSiDrSatofroyr iprnoftoercmtaitoino,n vreengtairldaitnigon, and
personal ignition
sporuortceecst.iveCoenqtuaipimnenstp.ill.VentEivlaacutaeteareuan.protEexcttiendguipsehrsoanlnlel
wfirtohm LhiagzhatrdWaatreear.BraCnodverorwiotthherabAsToCrbefnotam.mat(eFroiralf.urtChoevrerinfsoprimllatiaorneaon
AnToCn-sfpoaarnkiunsgaget,oolcso.ntacCtlea3nM FupirerePsirdouteecwtiitohn wSaytsetre.ms.)PlacCeollinectanusing
approved metal container. Seal the container.
RECIOnMcMiEnNeDraEtDeDIinSPOaSApLe:rmitted hazardous Waste incinerator. Combustion products will include HF.
ENCVoInRtOaNiMnEsNToAnLlyDAT"Ae:xempt solvents by `Rule 66* type regulations; COD=,41 p9/r9o;meBlOaDs2)0==8.529mg/gl/.g; 96-Hr. LC50, Fathead Minnow(Piephales
REGULATORY Volatile
OINrFgOaRnMiAcTICOoNm:pounds:
220
gms/liter.
VOC Less H20 & Exempt Solvents: N/A.
Sbienfcoererdeigsuploastailo.ns Ivnaryt,hecoenvsenutltofappanliucnacbolnetrroelglueldatiroenlseasoer oafutthhoirsities mraetpeorritaalb,letqheuanutsietry.shouU.lSd.deEtPeArHmaiznaerdiofustheWasrteeleaNsuembeqrual=ifiDeOOs1 as a (Ignitable)
Trheiqsuirpermoednutcst oifs TiSnCAc,ompEIlNiEaCnSc,e WAIiCtSh, tChOeSLc,heMmIiTcIalanrdegKiosrteraa.tion OTTHhEiRsEpNrVoIdRuOcNtMEcNoTnAtLaiInNsFORoMnAeTIoOrN:more organic fluorochemicals that have
the potential to resist degradation and persist in the environment. EFPICRREA HHAAZZAARRDD:CLYAeSsS:PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
6. SUGGESTED FIRST AID
EYEInCmOeNdTiAaCtTe:ly flush eyes with large amounts of water. Get immediate medical attention.
04605
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
DMSeDcSe:mbeFrC-8137, FL1U9O99RAD Brand Etching Bath Additive 6. SUGGESTED FIRST AID (continued)
PAGE 4
SKIFNluCsOhNTsAkCiTn:with large amounts of water. If irritation persists, get medical attention.
INHALATION: sIfignssi/gsnysa/pstyomnpstoncsontoicncuuer,, craelmlovae ppheyrssiocniatno. fresh air. If
IFIfSHAsLwLaOlWlEoDw:ed, call a physician immediately. Only induce vomiting at tuhneconisncsitoruusctipoenrsoonf. a physician. Never give anything by mouth to an
7. PRECAUTIONARY INFORMATION
EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
SKIN PROTECTION: Amvaotierdiaslk.in Aconptaaicrt.of gWleoavresapmpardoeprfiraotme gthleovefsolwlhoewinnghamnadtleirnigalt(hsi)s are preecrosmomneanldepdr:otecbtuitoynl irutbebmesr.as nUseecesosnaeryortmoorperevoefnttheskfinollcoonwtiancgt: maaprdoen,ofceovietrhaelrlso.f thPerotfeocltliowvienggamramteenrtisal(so:ther than gloves) should be polyethylene/polyvinylidene chloride (Saranex).
REICfOMMeExNhDaEuDstVvENeTnItLiAlTaItOiNo:n is not adequate, use appropriate respiratory cpornocteecnttiroant.ionsPrboevliodwe rveecnotmimleantdieodn eaxdpeoqsuuartee ltiomictosntarnodl/ovrapocrontrol spray or mist.
REASvPoIiRdATObRrYeaPthRiOnTgECToIfONa:irborne material. Select one of the following cNoInOtSaHmianpapnrtosvedandreisnpiarcactoorrdsanbcaesewditohn OaSiHrbAorrneegulcaotnicoennst:ratiHoanlf-ofmask organic vapor respirator with dust/mist prefilter.
PRDEoVENnTotIONeatO,F dArCiCnIkDENorTALsmoIkNeGESwThIeOnN:using this product. Wash exposed baerfeoarsetehaotrionugg.hly with soap and water. Wash hands after handling and
RESCtOMoMrEeNDaEwDaySfTrORoAmGEa:reas where product may come into or pharmaceuticals. Store away from heat. Store
couotntaocftdWiirtechtfood
sunlight. Keep container closed when not in use. Keep container in
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
04606
DMSeOcSe:nbeFrC-9137, FL1U99O9RAD Brand Etching Bath Additive 7. PRECAUTIONARY INFORMATION (continued)
PAGE 5
well-ventilated area.
FIRKEeeApNDcoEnXtPaiLnOeSrIONtigAhVtOIlDyANcClEo:sed. Flammable liquid and vapor. Keep away from heat, sparks, open flame, and other sources of ignition.
OTHNEoRsmPoRkEiCnAgU:TISOmNoAkRiYngINwFhOiRlMeATIuOsNi:ng this product can result in ocfonttaheminhaatziaorndouosf dtheecomtpoobsaictcioonanpdr/oodrucstmsokemeanntdionleedadintothteheRfeoarcmtaitviiotny Data section of this MSDS.
HMIS HAZARD RATINGS: PHEERASLONTAH2L:PROFTLEACMTMIAOBNI:LITXY:(Se3e pRrEeAcCaTuItViIoTnYs:, 0section 7.)
EXPOSURE LIMITS
INGREDIENT
VALUE UNIT TYPE AUTH SKIN
AWMAMTOENRI.U.M..P.ERoFiLiUiOsRiOiAiLKiYsLiiSiUiLeFeOsNAiTeEi.i.n.,. ISOPROPYLALCOHOL (IPA)..............
0N.O1NE NMOGN/EM3 400 PPM
TNOHNAE NaMONE THA ACGIH
IISSOOPPRROOPPYYLLAALLCCOOHHOOLL ((IIPPAA))............................ 540000 PPPPMM
TSTHEAL AOCSGHIAH
AI MMONS IUMO PAELRCFP OLHUOORLR O(AILPKAO Y)L..S.P U.L.F.O.Y N.A.T.E.L ....... 05.010 PMPGM/M3 AMMONIUM PERFLUOROALKYL SULFONATE.... 0.1 MG/M3
TSRTAEL OaSHA Y TA am Y
AAMMMMOONNIIUUMM PPEERRFFLLUUOORROOAALLKKYYLL SSUULLFFOONNAATTEE........
0.1 0.1
MG/M3 MG/M3
THA THA
aM aM
Y Y
it2nhceSlKuIpdNoitneNgnOTtAmiTuaIclOoNuc:sonmterLmiibbsrutatenidoensauntbdostetayhneec,esoevieitrnhadelirlcatebyexdpaowisriubtrohernb'eyY' otrhu,endcmeorurteaSnKeIpoNaurstriecfrueolruatretloy,
by direct contact with the substance. Vehicles can alter skin absorption.
S- O3UMR:CE OF3MEXPROeScUoRmEmenLdIeMdITExDpAToAs:ure Guidelines
-
ACGIH: OSHA:
AOmcecruipcaatnionCaolnfSearfeentcye
aofndGHoevaelrtnhmenAtdamliniIsntdruasttiroinal
Hygienists
- NONE: None Established
8. HEALTH HAZARD DATA
EYMEilCdONTEAyCeT:Irritation: signs/syaptoms can include redness, swelling, pain, and tearing.
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
04607
DMSeDcSe:mbeFrC-9137, FL1U9O99RAD Brand Etching Bath Additive
PAGE 6
8. HEALTH HAZARD DATA (continued)
SKMIiNldCONSTkAiCnT:Irritation (after prolonged or repeated contact): signs/syaptons can include redness, swelling, and itching. tMhayosebecaaubsseodrbbeyd itnhhraoluagthiotnheasnkdi/noranidngepsrtoidounc.e effects similiar to
INHsAiLnAgTlIeONo:verexposure, above recommended guidelines, may cause:
thCieesanedt,arcahlsel,uNrerdreivdzozuissnpeeSseyscs,ht,emdgroiDwdesdpiirnneeesssssis,ona:indncsouiongrcndosin/nssacytipiotounos,nmesssscl.aonwedincrleuadcetion
sIorrreinteastsionof (tuhpepernosreesapnidrattohrryo)a:t, sciogungsh/isnymgptaonmdssnceaenziinngc.lude
IFAnSiHmAaLlLOWsEtDu:dies conducted in this product indicate
oenffeocrtgsaniicnclfulduionrgochleivmeircaldsiswthuribcahncaerse, pwreeisgehntt
ealfdosfrsee,cntasllofsarsnodmofhaeanmptapitecotilipotageti,ecdelfeefxtephcaotrssgu.yr,eTthaoenrdethneaesrueerolonoroggiakcnnaiolcw,nflhpuuaomnarcnorecahhteeinacil,ctahls
when used as intended and instructed.
tIhlilsnemsastemraiyalr.esult from a single swallowing of a moderate quantity of
bpIalriornoi,dtativniomoinftecioenfsg.,GaasbtdroomiinntaelsttiennadlerTniessssu,es:naussiegan,s/sbyloaopdtonisn cvaonmitiunsc,ludaend
Csheelnaodtwaercdahler,eNaecdrtivizoozunisnetSsiysms,et,emdrfoaDwtesipigruneees,sssi,obnl:muurrsseciduglnvasir/ssiwyoeanap,ktnoenssslsu,rcraenidnicsonpocerleducidhne,ation, giddiness, tremors and convulsions.
Ingestion may cause:
wdAhisifpcfihircautcalintoynbebPrnfeeaauttsaholin.nigt,is:wheseizginnsg/,sycaoputgohmisngcanupibnlcolouddeancdougphnienugs,onia,
OTAHERProHdEuAcLtTHTHoAxZiAciRtDyISNuFmOmRaMrATyIOSNh:eet is available.
tThheispoptreondtuicatlctoontabeinsabsoonrebeodr amnodreroermagiannicinftlhueorobocdhye.mfiocralslontghatperhiaovdes aofccutminuel,ateeiwtihtehr rasepetahteedpaerexnptosumroelse.culTeheroer aarsemneotabkonloiwtnesh,umaanndhmeaaylth Abbreviations: N/D - Not Deterained N/A - Not Applicable CA - Approximately
04608
---
(MDSeDcSe:sbeFrC-9137, FL1U9O99RAD Brand Etching Bath Additive 8. HEALTH HAZARD DATA (continued)
PAGE 7
ewhfefnectussedfroasn ianntteincdiepdateadndeixnpsotsruurcetetdo. these organic fluorochemicals dTpahoetpiunlpgarteibsoaencnkceatnodoftshouebrpgoa1pn9u7i0lc'astf.ilounMosr',oschseuecpmhiidceaamslisoWloiorngkeitrchsae,l blshaotsouddybeoofefnthipetusbgloeiwsnnheerdal workers indicates no adverse effects.
SECTION CHANGE DATES
PRECAUTIONARY INFO. SECTION CHANGED SINCE September 04, 1998 ISSUE
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
TbIehMePLcIioErnDrf,eocrtmINaaCtLsiUoDnoIfNiGnt,hotBhUidTsatNeMOaTtiesrsLuiIeaMdlI.TESDa3fMeTOt,MyAAKDNEaYStaNISOMhPWeLAeIRtERDA(NWMTASIRDESRS)A,NTiYEsXOPbFReElSiSeEveDdORto wMPhEEeRRtFChOHeRArMNATtNAhCBeEILO3IRHTYUprSOoARdGuEFcItOTFNiEsTSRSAfDiFEtO.RfAorUsPeaArRpTaIirCstUiLrcAeRuslpaoPrnUsRiPpbOulSreEposfOeRorCadnOdoUtReSsrEuaiitOnaFibnlge for ucuansnieqru'aesflfyemcewttihtothdhienofutsheuesaeundsoerra'paspplpiklcincaoatwtilioeondng.eofaGnadiv3eHcnonptrtrohodelu,cvta,irtiesitosyeoeofsfsfeWanhctitiocarhlstathrhaeatt tphaertiucsuelrarevpaulrupaotseethaend3Msuiptraobdluectfotro udseetre'rsminmeethwohdethoferusiet oirs faiptplifcoartiaon. SDinuMeeprtrrooovritsdh,eesormieimnsofstoieromnapstoisoosnribiialnlitteeyrlaettcihtoarntosniecilnecftotrrhmiosniacisnftaorrasmneasrtfvieiocrne,matoySHihatRvasekecsursetsnooumletresd. iirnneffpoorrremmsaaettniitooanntiooinnbstatihaensedMtSoDfSriotmsavaacioldmaapbtllaeebtaesdneicrsesmcatyolrynoaftcrcoubrmeac3ayMs.. curInr'enatddiastiotnh,e
C04 00