Document OzjRkM32g8aLyeZgvgb2rb3ej
PFAS alternatives for batteries
EU Workshop in Brussels 30. January 2024
AAALedanch
Energy Storage Solutions
Ref. Ares(2024)6205129 - 02/09/2024
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LeclanchSA2024 - Slide 1
Leclanch at a Glance Ledanch Energy Storage Solutions
Leclanch is a vertically integrated manufacturer of energy storage solution for heavy mobility & energy
Swiss Quality & German Manufacturing
114 years of existence
Al
H
350 people, including 50+in R&D European manufacturer, HQ. in Switzerland, production in Germany & Switzerland
Proven sustainable technology Over 160 patents covering key IP
Very low environmental impact
Existing track records 170 customers including blue chip customers
ALSTOM
CP
CANADIAN
Pacific
KONCR D11MEN "'Scandlines
WRTSIL
Leclanch SA 2024 - Slide 2
Why are PFAS used in the batteries ?
Battery cell composition
Cathode Anode
Separator
Pouch foil
PFAS are mainly used as binders for the coating of positive electrode, since they resist to heat, oil, water and grease
Cathode
Ledanch Energy Storage Solutions
Anode
Already water based and PFAS free
LeclanchSA2024 - Slide 3
Water based electrode manufacturing without toxic solvents since 2011
2010-2013 : De-Lion German funded project (7.5M) to demonstrate the ability to replace toxic organic solvent NMP by water at large scale. Project partners: ZSW (Ulm) and Clariant (Mnchen).
2013 Patent US2013/0034651 Al
2023
Patent WO2023/166174 Al
Water based + PVDF as lamination agent
k
From 2023 Water based & PFAS free
2013 EPFL (CH): 750 kW / 500 kWh
2016 Graciosa (PT) : 7.4 MW / 3.2 MWh
2019 E-ferry (DK) : 3.2 MWh
WE ARE IN CHARGE
IMLedanch
Ledanch Energy Storage Solutions
LeclanchSA2024 - Slide 4
Leclanch water based binder-process
Standard battery cell Production using toxic NMP solvent & PFAS
Leclanch battery cell Production
NMP & PFAS FREE
Organic solvent-based Process
Water-based Process
Safety risk for employees
ATEX protection needed
Solvent recovery system
NMP needed High drying temperature in coating
Humidity control space for most of the nn manufacturing process - - .
9 9 9 I
Safer working environment for employees No explosive environment
No solvent recycling Low drying temperature in coating
Reduction in humidity control space in the manufacturing process
Ledanch Energy Storage Solutions
Leclanch SA 2024 - Slide 5
Comparison with and without PFAS
Performance of PFAS free cell is similar or better to PFASbased cell
Energy Efficiency is improved
Ledanch Energy Storage Solutions
100
90
PFAS Free Water-based electrode
i80
.
Cell using PvDF binder
o
70
60
200
400
600
800
1000
Cycle number
Water based G/NMC622_standard
PFAS free G/NMC622
Example with the Leclanch 60Ah GNMC622 cell in production at industrial scale with 1C cycling at 100 % Deep of Discharge, compared with a cell using electrodes which contains PvDF binder.
Leclanch SA 2024 - Slide 6
Impact on existing and future Gigafactories
Existing equipment can be used with Water-based PFAS free chemistry
Existing Gigafactories: is reduced by:
Reducing heating temperature by 50-60C Working in standard environment instead of humidity controlled No need of expensive PFAS
New Gigafactories: CAPEX is reduced by:
Removing NMP recovery equipment
Removing ATEX protection Reducing dry room size
NMP recovery system from airprotech
Health and safety of workers is improved since they are not in contact with PFAS or NMP
Ledanch Energy Storage Solutions
LeclanchSA2024 - Slide 7
Synthesis and next steps
PFAS-free battery using water based Remove toxic solvent and associated emission
^1 Reduce CO2 footprint for battery production in Europe
Protect investment in existing equipment - no change needed Next steps for Leda nch
License the technology to assist the battery industry in shifting towards more environmentally friendly batteries H Find investor to scale up production
Ledanch Energy Storage Solutions
LeclanchSA2024 - Slide 8
Energy Storage Solutions
@leclanche.com
STATIONARY SOLUTIONS
e-TRANSPORT SOLUTIONS
SPECIALTY BATTERY SYSTEMS
Appendix
AAALedanch
Energy Storage Solutions
`iel
LeclanchSA2024 - Slide 10
PFAS free alternative available for Li-ion (wet-process)
-4-- 100% Mn-rich NMC 622 NMC 811
NMC HiNi/NMCA NCA Hi-Ni
LFP/LMFP
2020
2021
2022
2023
2024
2025
2026
2027
2028 2029
2030
NMC 111
NMC 622 NMC Hi-Ni/NMCA NCA Hi-Ni Na-ion1)
NMCHi-Mn NMC 811 E NCA
LFP/LMFP
Other (LMO/LCO/LTO/...)
1) Na-ion share consists of the two cell chemistries nickel-based and Prussian white
Battery cell demand by cathode chemistry, 2020-2030, base-case scenario [GWh/a] Source: Batteriemonitor 2023 Roland Berger, RWTH Aachen, PEM
Na-ion') Other
Ledanch Energy Storage Solutions
NMC chemistry Anode already water based Cathode using PFAS in
general, technology exists to move to PFAS free LFP chemistry PFAS free alternative already available
LeclanchSA2024 - Slide 11
Availability of water-based binder suppliers
Water based binders for Leclanch cathodes are coming from large and well-known material suppliers manufacturing binders for water-based process for Li-ion electrodes for several years and available in Europe.
There are multiple suppliers for each type of binder, making availability and scaling not a problem.
Ledanch Energy Storage Solutions
Leclanch SA 2024 - Slide 12
Ledanch Energy Storage Solutions
@leclanche.com
@leclanche.com
STATIONARY SOLUTIONS
e-TRANSPORT SOLUTIONS
SPECIALTY BATTERY SYSTEMS