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AR 226 -- O46 TOXICITY TO AQUATIC PLANTS EST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-802. (1- Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-802. Current information indicates it is a mixture of 1% PFOS, 12% diethylene glycol butyl ether, 61.05% water, 20% ethylene glycol, 2% Sultone foamer, 1% sodium octyl sulfate, 1% sodium decyl sulfate, 1% magnesium sulfate, 0.7% xanthan gum, 0.1% starch, 0.1% n-(3-chloroallyl)hexaminium chloride, and 0.05% tolytriazole. ~ The following summary applies to a mixture with incompletely characterized concentrationsof impurities. Data may not accurately reflect the toxicityof the fluorochemical componentof the test sample. METHOD: Method: NS-EN ISO 10253, 1998: Water quality -- Marine algal growth inhibition test Type: Acute Static GLP: No Year completed: 2000 Species: Skeletonema costatum Source: Strain NIVA BAC1, stock culture maintained at RF -- Rogaland Research, Stavanger, Norway. Element basis: Estimate biomass by measuring fluorescence. Exposure period: 72 hours Statistical Methods: Growth rates by Log linear regression on biomass (fluorescence) vs. time, as described in NS-EN ISO 10253. Calculation of NOEC done by single factor ANOVA followed by Bonferronis procedure. Analytical monitoring: pH Test Conditions: Algal Nutrient Medium: Filtered natural seawater (34 ppt salinity) from an unpolluted site in Byfjord, Norway, enriched with nutrients according to ISO 10253 and recommendations from the Paris Commission. This nutrient `medium provided all mineral nutrients essential for algal growth and also ---- served as thediluentfor all algal operations. The pHofthis synthetic algal `medium was 8.4. Stock and test solution preparation: A 102.4 mg/L primary stock solution `was prepared by diluting 0.1024 gof test substance in 1 L of growth medium. 002160 Aliquots were then added directly to growth medium in test vessels to create test solutions. Exposure vessels: 100 mi flat-bottomed flasks containing 50 mi test solution. Agitation: Number of Shaken continuously replicates: 3 on an orbital shaker. N Initiau l celolm flcooandb cienngt:e ra2t.i0or xns1:0sciexlplls/umsLa blank control WLiagthetrinCgh:eCmoinsttirnyu:ous fluorescent lighting at >50 uE/m? sek. pH range (0-96 hours): 8.38.4 (control exposure) 8.3-8.4 (102.4 mg/L exposure) _ Test temperature range: 20 +2 C RESULTS RNeofmeirneanlcecosnucbesnttarnacteio(n3,s5:-dBikchcioonrtorpolh,en0o.l3)2,at1,1.35.2m,g1/0L,. 32, and 102.4 mg/L: Algal Growth Response ECs values (based 72-hour E,Cso = ~78 mg/L on growth rate) 72-hour NOEC = 32 mg/L Element values are based on nominal concentrations. Reversibility of Growth Inhibition: Not conducted. Remarks: Substance TReesmtianrgkwsafsielcd.onTduhcetveadluoensarempioxrttuerde aapspdleystcortihbaetdmiinxtthuereTeasntd not the fluorochemical components alone. CONCLUSIONS EFfCf-e6ct02Coenxcheinbtirtsataio7n2-(hNoOuErCE),Cisso3o2f m~g7/8L.mfgo/rL.groTwhteh7r2at-eh.our No Observed tVahlaindi1ty6cirnitteersitapfeurlfiioldeda.ndCornetfreorlecneclel dseunbssittaynicnecwreaassewditbhiyan nfoarcmtaolr orfanmgoe.re Submitter: 3M Paul, Minnesota, 5C5o1m3p3any, Environmental Laboratory, P.O. Box 33331, St. ~~ DATA QUALITY 002161 tReesltiianbgi.litHyo:weKvieirm,istchhersatnukidnygla=ck2.s Tihnifsorsmtautdiyonmoenetpsurtihtyeocfrtihteeriatefsotrsquuablsittaynce and it in the lacks analytical solution. confirmationof the amountoffluorochemical proportion REFERENCES rTeeqsutwesatsofc3onMduNcotrgeed,byLaRbFreRfoegraelnacnednuRmesbeearrc9h9,31o2f-S3t,a2v0a0n0g.er, Norway at the OTHER --_---- Last changed: 6/26/00 002162 &aareno.; | - Page lof31 lit wdSSiEwa FOSAALE "FC-602 Light Water Brand ATC plus" Toxicity tests Report RF-2000/003 (ee ---- Labo nox 593123 No ofpages: 31 Centex: 3M Norge Version No. date VReersse.ar1c/h0P7r.o0g1ra2m:000 Soma: The following test results were obtained with "FC-602 Light Water Brand ATCPlusTM: Toxicity: Skeletonema costatum 72h EG, (mn): ~78 Acartia tonsa Corophium volutator 48hLC, 10dLC, (mom: (mgikg dry weight): 200 >3070 The results Royworda: relate to the product as `supplied by Novatech. oTopxiecrity,4S2kdeolceutmoenntemmaaycoBsataptruomd,uAcceadrtainaytoonmsai,hCooropahriiusmenvolFutaitonr, ty FE Fogae Feseae Yan = Adsa [hind Jp Inger Lisa Andersen VyoR Rogaland Res0ear% Kare Netland ProfsrClo Hor15,s0,Boex2503Ulery,4091Severe:Nowe:Bl +471873000.Fac+ 002163 : La9b3.1r2e.f3no.: Page 20f31 CONTENTS: 2. TEST FOR TOXICITY WITH SKELETONEMACOSTATUM oom 3. TEST FOR TOXICITYWITHACARTIA TONSA. EE-------- 4. TESTFORTOXICITY WITH COROPHIUM VOLUTATOR cre... ME--_ 5 DATASHEET(S) coves -- 002164 Lsabyret, Pahgaes of31 PREFACE; Cotoxicological Novatech. ests wereperformed on "FC-602 Light Wate Brand ATG pus in agreementwith solution. TTehstesswaemrpelecoinsdaucctoendceinntarcactoertdhaantc`enowrimtahlltyhewi"llHabremuosneidseindaOf3f%s.hAorFeFCFhe/m6i%caAlR Notification Format (OSPARCOM 1995 /SFT 1995). TpheerfporromjeedctbwyaRs.cFa-rMriilejdaloaubt. atStRudFy-RdoirgeacltoarnwdaRsesSeeanirocrhEfnogri3nMeeNroIrnggee.r LAilslatAhnedteersstsenw.ere bTyhNeotveasttercehsu.ltsare presented in separate sections. The results relate to the product as.supplied sTTahhuiesiaptcmecsertnertdeaiptnoadrtitwooinsriskstsiauntegesdpbrtohyacteadtlhuaerbelosarbafotororaratylolartychcemereteetdsstitmthbeeetydNhoNAdosrrewcqeougniitraaeinmneAencdtcsirnecdtoihntecaeatcricnorinend(giNtcAa)ot.mpetence, Iralso states that the laboratory has a satisfactory quality assurance system, shish ion. neluses cienrtteirfniaeldqrueafleitrye.cncoentmraotlersicahlesmaensd,speacrotincdiapraytiroenfienreinncteermlaatbeorriaaltso,ry comparisons, and the use of The tests performed are covered. by the accreditation. This est report writing byRF - may not be Miljlab,. reproduced inanyform other than inful, without thepermission in 002165 ) i Sour tet31 ) TEST FOR ToxICITY W Marine alga: Skeletonema costatum $ 002166 La9b9r3e1f2r3o.: Page sof31 TEST REPORT GROWTH INHIBITION TEST WITH THE MARINE ALGA Skeletonema costatum Qa Ii roti 12SAIANE | TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus" 1 : TEST RESULT: . { The The 72 hours ECs test substance was was calculatedto~78 mg/l. supplied by Novatech, an the est results relate to thisproduct. . E TEST DETAILS: METHOD: ; NS-EN ISO 10253, 1998: Water qualit-y Marine algal growth inhibition test $1: with Skeletonema costatum and Phaeodactylum tricornutum. TEST ORGANISM: Skeletonema costatum, strain NIVA BAC 1. A stock cultureof the tet he 3 & organism is kept at RF - Rogaland Research. ho i PREPARATIONS: Ca2N5naotdbmuabrsraiilsefsTloeyrahwteahategteerrdo(stwaotliahnbimotuey:tdi37u45m9.Cs)pTrfhireoorwmtaaotnuesruen.wpaoTslhlfueitlseteedraeswidattteehirrnowBuaygfshjeaonrGrdFiwcIahCesdiuwlsiset,dh Commmiisssiaocnc.ording 10150 10253, an recommendations from the Paris mmTeesedtisuwomal.sutpOirotenhpsewarerecrdoenbcpyernsetptraarrtieindognfs0.rw1eo0ram2e4spgtrroeacpkmasrseooldfutfthiroeonm.pArtohidsuscsttotcoikcnks|oslolulitutrtieoonfogfr10o2.w4 INCUBATION: ion, Torebsittaclulsthuarkeesro,f3Sr0epmlilcawteersefoirnceuabcahtecodnicaen1t0r0amtilonf.laTte-sbtotcutlotmuerdesflwaseks on an Tlahteedtetsotawbaosurtu2n0u0n0dceerllcso/nmltifnruoomusanliegxhtpo(n>en5t0iaWlEl/ymtgrsoewki)nfg oinmocfulluurmoe rcjuealtsaur.e, tubesofuniversal natural whitetype, at a temperature of 20 2C. bt`hTyeheftletuseotstrfewlsaacsseknsrceeu.ancfphoHrdaamybeoafuostru7rg2ermohewotnuhtrssm,ewaaensrduerspeuembersnfatomsrp.mleeAdslgaosalfi5ngdrmiolcwawtteehdrweoantsadkmaeetnaesfsurhroeemd. ProfessorOho Honssanse 15, 20.Bo2503Ullonchon,4091SovengesNorwoslls a91 moee 002167 9La9b3r1e3f3ro.; Page Gof 4 DATAANALYSIS: | i CALCULATIONS: Gverroswutshtirmaet,esawsedreesccrailbceudlianteNd Sb-yElNogIlSinOea1r0r2e5g3r.ession on biomass (fluorescence) 1 1 EC cTohneceinntbriabtitioornyoeffafepctroodnuctthegigvrionwgth50o%fSreeldeucttoinoenmoafcgoroswttahruraitse e(xp,rCe)ss.edThaissthe J effect concentration 102.4mg/.. was calculated by interpolation between 32mg/l and NOEC: fCaacltcourlAatNioOnVofANOfoEllCow(eNdobyObBsoenrfvererdoEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingle- concentration mean with the control mean. TESTRE-- SULTS: T Table 1. EC and NOEC values obtained witT hhSkeelemoneamaccoossttatauem,: TToesitmsbubeswtasneces EECCoe EEGCu: EEGCwo _--"FC-602 Light Water - Brand ATC plus" ~78 >1024 NEC 3 GerlalupuhspaerdecIacntciaaonl3.0c, beynnreupaotgaetioodgsn.1N0OZ0C%ar0encd9a05lobabytii egdof o rcoowmprue oOnrs rsma COMMENTS: Theresultsarebased on g during which the growth rowth atsfo is considered th to be timespan 0 exponential - 72h,the period in the contre]cultures (see growth curves). "VALIDATION: `The cell validity criteria given density increased by a in the test protocol are factorof more than 16 fulfilled, in that the in the testperiod control v(acroybrryemsoproentdihtnaogn a1g,r0ouwntithsrdautreinogftmhoerteestthaannd0t,h9ed7")2, 3,5-dichlorophenol was in the range normally found. hthoeurcsotnetsrtorlepsuHltdsidwintoht Lab. ref. no: TSeasmtppleeriroedc:eived. Report date: 99312.3 22520..1019.9999 07.01.2000 Enclosed: Data sheets Su Ne EEnlginiHnoerevre Analytical technician Tyre ( SeniAorgeReMsoelavrechrsSmciyerntist Quality Assurance omereshedyts reepyseea dRoe LnaioOAR)TTe eprypsbe roi 002168 L9a9b3r1e2fr3a.; Page 7031 PRIMARY DATA: Growth inhibition test with Skeletonema costatum Test substance: ~Fc.02 Light Water Brand ATC plus" LSaatbd.arteet:; 9229.31112..939 ; MeaCsounrce.mounnist:: Tmhge biomasswas measuredby fluorescence; values in fluorescence units Mme ji| Conssomin 2211.99] 23.11.99] om 24.11.89 oT oy | Ciororne-|aotsrtaert aot eond ] ii 0 00 006 | os | 15 82 0000s6 || o02a3 || 137 | 9113 161| 0999 117616|| 00.s9929 Jj 0 000077|| 004365|| 21195| i9 115698|| 00.999997 0 00322 0.12 000079 || 04 ooas2s || 235 2245 || 15 1m2ss 1.50 | 0.999 116628|| 00999s8 032 1 007| os | 265 | 12 008 | oss | 34 | tas 169| 0906 171 [oss 1 1 007 0.64 3 13 0.09 05 27 125 172 | 0.991 162 | 0999 82 3322 32 000085 00 |+ | "00548s ozs 115 3 11.6732|| 163| 0009.9999898 i| 01 10 0o11 | o[oisss || 5o1s 007| os | 25 T16a5|| 0oss9e7 1.74 | 0990 000089:|| oosss 005 | oss 1145 116627|| 0o3s8s 13 163| 0900 83 1024 01 [013 [ 02 | ous 048 | 0s70 11002244 | 0000s7 | 00.108 | 06.218 | 00433 006690|| 00907s1 83 ReferTeSnmceosnubs|tance (3.5 01 |dchio0ro1p6he|nal):048 1155mmgg | 0o017|| 001158 || ooza Mean 0values: 007 | 0% 032 008 05 312 10 000089 | 009 | 02 0 4 130224 00.0099 | o0s; (Referen-cesubst]009|016| 04 7 12 133 1s 113 75] 500873058|| 0009958%%7| 83 82 [05% 1.66| 0.997 116886|| 00.998985 167 [ 0999|eame*s 01s.t64| itonys 0.999|substance(53% ol he raanmyen 02169 SLa3br1e3gre: Pageserss f | TGeRstOsuWbTstHanCceU:RV"EFcSa:naGirgohwttwhaitnehiBbriatnidonATtCesituWsi"th Skeletonema costatum Lab. rt: 30312 |] , contr j Is a 33 | 3.0 i ja 7 arinvuen ; 02 man 5s 3 HA fa ay I BN7] 3s il i fof 1 mgn = arin lI i} 3s { ' 10 mgt |i L , t I | Lb i | I.4]| 1024 mga !i i i'i - = | o EE iI3si 32 mon 2.4 "= 2 wnsonpam I7 3s 32 mga I3 oe 7 2 naionpon ey 002170 : 9L9a3b1r2e3f. : Paeagee9ofef3l i | wSiitoha:bttion of the growen of skeletonema costatun "9/3 (FC-602 Light Water Brana ATC plus) | Experimental data; fl cFCo-n6c0e2ntLriagthitonWaftner BT rand ATC plT us cCoonnttrrooll 21 Contzol 3 re 11.6661 CCoonnttrrooll 54 Control & 116m6 - iiss 150 control mean : 1.62 00.3322 032 11.6628 16 11.0000 100 117m2 162 33.2200 3120 1.6732 163 1100..0000 10.00 . 11.665 178 3232..0000 32100 11.6627 163 1012012.3400 102130 00..4680 0.69 Iinnhpiebricteinot,n --. -o 00.10 oko 0o.o0 01 00.00 00 l0.o0 oo 00.10 [x] E7603X..40 002171 Shr i |i i i ] 1 | i ge 1031 TEsT FOR TOXICITY Marine herbivore: Acartia tonsa . | 002172 9La9b3.1re2f3no.c Page 110f31 -- TEST REPORT ACUTE TOXICITY TEST WITH THE i MARINE COPEPOD Acartia tonsa QA moxses RR OSAE ARND i i TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus" TEST RESULT: = i `The 48 hours LCs was calculated 0200 mg/l. | The test substance was supplied by Novatech, and the test results relate to this product. i TEST DETAILS: 31{ METHOD: tIoSOma/rDiInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,quCarluisttya-ceDae)t.erminationof acute lethal toxicity 3 TEST ORGANISM:UnAicvaertrisaittyoonsfaC(oDpaenan)h,agseunpp.lied by the Marine Biological Laboratory, i it CULTIVATION: a`Tinhtdehattdehusetlto"srPwagreairnsieCsumossmemwdieisrnsetishouenptpe-lstRi,eidngasTeesgtgsP,roatnodcowle"re(VcKuIl)i.vaLtaerdgiencaocpceoproddaintcees 3 PREPARATIONS: 2N5atbuarsailssfeorawtahteedril(usatliionnitwya:t3er4.%:T)hefwraotmearnwuanspoflilluttereeddsttheroiungBhyfajGoHrdC.waHs eused prior to use. i WmTaget/seltrs.woalOsuttphireoernpscaworneecrdebenytprsratetipiraorrniesndgwf0er.ro9em9p9ar8esgptarorcakemdssoofflrutothimoetnh.pirsAosdtsuotccotkciksnosl1oultluiittorine,oonfdoifl1u0ti0o0n F INCUBATION: The test was run in glass containers (28 mi rolled rim vials) each containing 2Y2i50alm1slwoefCtr.eesktpeHpstoaluunntddieoonrxayagn1ed6n5hm/ae8nhaismluairlghset,m/e4dnarrtekspplhicoattoepsefroiroedaacthactoencmepnetrraattuiorne."ofThe. data sheet. were. `performed as indicated on the BIPTONGER: ProfessorOlowHonvsarmi15BOYBree26031M he.srs ne nr o 002173 L9a9b3r1e2f3ro.: Page 12of 31 : 1 { DATA ANALYSIS: 3 { 4 CALCULATIONS: pThreodeuffcetctleotnhatlhetosu5r0vi%voaflotfhAectaersttiaanitmoanlssa per test concentration were used for cal is (L Cex)p.resTsheed as co mtbhienceodncmeonrtaraltiitoyn of 3 gLiCansdavradlupersocaenddutrheeP9R5O%BIcoTnfAindaleynsciesl,iNmciauttlaiwtoeinroanel.cSaTwlheceduli2as4thehdEonbuvyrisursoainnnmdge4nt8thaehlours cPornocteencttiroantiBoonasrldet(haVlertsoio1n02%3a,nd199900)%.oTfhtihseptreostgarnaimmmalesa.lso calculate jest i 3 NOEC: cfCoaacnltccoeurnltaArtNaitoOinooVnfAmNefOaonlElCwoiwt(ehNdotbhyOebBcsooennrfvererdoEnfifsepctroCcoendcuernetrfaotricoon)mpiasrdionneg.ebaychsingle- trol mean. TESTRESULTS: Table 1. LC and NOEC values btaaed wth "FC:602 Light Wotor Brand ATC,plus" TAcEariRa tEonsa M2e4 hwourss s48hhouurs 1c 1c, 120 (55-150) 350 @50-490) 8 (2-130) 200 (140-270) Lo Ne 970 (650-2200) 450 (320-500) 1 i thhaelceeosmapnutdtiecrptPreRoO1gB0rIa%mT3me0en%Gclraeantpds5ha0P5na%dd e9i3ts7at6leconaf3t0i.deernc2e4nae4vn3 hoadsr.nUineidTsmNaOrEeVatcesoanrdby : VALIDATION: tghTheepeevnracleicdnoitntacygecnertmirotaerrttiiaaolgnitiayvteitnnhitenhe ethceoonn tftetrshtoelpd tsrewosttowacsaorlgrefaltefrltehdannortheaqtuatlhedtios4somlgv,ed LCsof3,5-dichlorophenol (reference) waass ilnestshtehraanng1e0n%o,ramnadltlhyef4ou8nh.one : Lab. ref. no: 9312.3 y TSeasmtppleeriroedc:eived.: 222501.0199.999 Report date: 07.01.2000 : Enclosed: Data sheets Ql oro EEnligninHoerevre Analytical technician W' eis SeniAorgeReMsoelavrcehrsSmcyierntist Quality Assurance ~ i a etpr et y Wre y seidnbyNyorveE g Apcdr OR TThh mayr not be e reprody uced mary i p 002174 | Lab refro.: Page 130731 | | PRIMARY DA terms: TA : Acute toxicity test with Acartia roster amrtopmr tonsa | Lab. rot: 903123 || SMteaarsudarteem:ent: 10N.u1m1b.e9r9of dead [ |l : || I Total number Concentration | Specimen (mgh) pr.conc. `Number of `specimen pr. vessel NUMBER OF DEAD ] 24 hours. 48 hours. | Too ACE BDF | Toa 000 ToACE [BDF 000 Tol |{ { || 0000 | 42 10 7 I Co 55 5 4 l { i || "| | Referencesubstance (3.5-dichlorop enol): -- 331 0 11 Theresultwiththereferencesubstanceiswithintherange normallyfound. = 002175 ||| Lwabrsefno. Page 14of31 | Testsubstance: "FC-602LightWater Brand ATC plus" LStaabr.tdraett:e: 9190.31112939 MeasurofeoxmygeenanndtpsH. [or me { Concentration | Oxygen I (mg") pH - Ougen (mg) pH | Oxygen - (mg) pn - e Che [e e e a | eT eee | 76 82 l1 Eee TT LFfeoroncee swubstJanceo(3,5 odichioropheenoe): TT _ _)_ | 002176 . | L5a9b3.r1e3f3no. || Page 15of31 | ! TEST FOR TOXICITY Marine Amphipode: Corophium volutator | | | ] . 3 002177 L9a9b3.r1e2f3no. Page 16.731 TEST REPORT aa s ! AMACRUITNEETAOMXIPCHIITPYOSDEDCIoMrEoNTphTEi; SuTmWIvToHluTtHaEtor mcQ erema -- R R2CAE RER TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus" TEST RESULT: `The 10d LCso was calculated to >3070 mg kg dry weight sediment. ~ The test substance was supplied by Novatech, and the test results relate to ths product. TEST DETAILS: MeTHOD: ASTM E1367-90, Standard Toxicity Tests with Marine Guide For Conducting 10 and Estuarine Sediments. day Static Sediment TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim, CULTIVATION: aTchreatteedstsoeragwaantiersmast w1e5rCe.suAppslmiaeldlaasmaoduulnttso(f4n-a8tmurmalisnesaiwzee)eadnwdawseurseehdeflodrin feeding. PREPARATION: SNattauvraanlgesreawwaasteurse(sdalfionritdyi:lu3t4io%n)waftrero.maSneudnipmoelnltutcoeldlesictteedinatByafnjuonrpdoelnlouuttesdisdiete | awnaaslyusseedd ffoorroprrgeapnaircincgontteestntseadnidmepnrtosp.orTtihoensseildtifmoernetaicshatemsut.ddy sand and was dEaacmhptseestdicmonecnetnitnraatpiloanstwiacsbupcrkeepta.re2d0b0ymalddoifnsg ethaewparotdweuacrst aindd6e0d0 agnrdamthseof b4u0c0kmetiowfassesahwaakteenr fwoars3 ahdoduersd.toTehaechs,edainmdetnhtewbaesakdeirvsidweedreinateorattherdeeobveearkers, 1 { ntihgehdt.am1p0 saendiimmaelnstwwearse athneanlyrsaenddfoomrlwyatseelreccotnetdefnotr,eaancdhablelackoenrc.enAtrastaimopnlseaoref ! | INCUBATION: calculated as mg kg" sedimentdryweight. The test was run in glass containers (600 ml) each containing 200 gof test i1d i csoendciemnetnrta,tiaopnp.. 400 The mbleoafkseersawwaetreerkaepntd u1n0dearnicmoanltsi,n3uoruesplaiecraatteisofnoarteaach -i tinedmipceartaetduroenotfhe15da+ta1shCe.et.pH and oxygen measurements were performed as | | 00 crlr arr 15,20 fx253 ing1091Ser:Nvoy.Jol +47$187.5000.Fax:+4751 87.52.00.Eve 002178 La9b5r3e1f2r3o.: Page 170f31 DATA ANALYSIS: CALCULATIONS: Ttrhaetieofnoffecat opnrotdhuecsturlveitvhaall toof5C0or%opohftiuhrstevsotlautnaitmoarlsis(eLxCpsr)e.sseTdhaesctohmebcionnecden mvaolruaeliatnydptehret9es5tc%onccoennftirdaetnicoen lwiemirtearuesecadlfcourlcaatlecdulbaytiuosni.ngTthhee s1t0anddaayrdLCsp P293R0,O%oB1f9It9T0h)eA.natTelhsytissainspi,rmNoaalgtsri.aonmamleSawlesodicsalhcEulnavtiertoensmtecnotnaclenPtrroatteicotnisonleBtohaalrtdo(1Ve0r%siaonnd NOEC: CfaacltcourlaAtNioOnVofANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotriocno)mpiasrdionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: TCaobrloeph1t.unLvCoalndaNrOT EC ve alues obtRaineed withT"FOC-O602LLWoiaghhytWsWaatteerr BBrraannddAATTCCpplluuss"".. 1C0 1750 1c, >3070 = NLoCEoC: 00 w>3300w 7700 GVralValaupulehussepiaianrnddeeinc ctaStaer1130a 0%.%.3Sb00yl %%PaRannOddBl I0T0a55n%eai ltylbsilsy. NaafOteCr 1a00rdeoepcye.lUUcrniletnegmdie1cgo"emspetieenpsradryoewemigh VALIDATION: oTthxheyegpveearnlcicedoninttcayegcnertimrtoaerrttiiaaolgnaiitvyietnnhtienhetenhdecootfnettsrthoeplrstowetseotcrwoelalsaersgesretfauhltafenirl1lte5d,%hioanrnteadhqaautnattelhsettdowii6st0sho%l,ved Frisleufcooorumanmndteetnondcbee(drwehifiteghrhieennrcae. c)cweapsteidn ltihmeitrsanfogre onrogramnailclcyofnotuenndt. buTthtehesesidlitmfernatctuisonedis T Table. Characterisdies oftho e sedimenteusdefdoforretetstoisog, e ic content (4) Silt fcton 04) _07 e0ws LSaabm.plreef.rneoc.e:ived: TReesptorpterdiaotde:: 29030192..939 03017.20.11.22.09090 SEliNn Hoerve A*g,eHMoylvierstmyry - AnalyEtnigcailnteeecrhnician SeniQouralRietsyeaArscshurSacnicenetist Enclosed: Data sheets foThrims_oet_ther_reph_oarn_tisnuuld,wbiy3tbE ohepreirmniT sssironeweT byrNobrwiyeRgFia-nnMAicwgcprae:tia on (VAo). Torepr iy or eroded0n0y2179) | L59a31b33o pase tgogt PRIMARY DATA: Acute toxicity test with Corophium volutator Test substance: LStaab. drate:: Measurement: "FC-602 Light Water Brand ATC plus" s03a.n1z26a9 Numobfederad Total | Nsupmebciemreonf NUMBER OF DEAD number | pr. vessel 5days Concentration | specimen] A GE | A E 10 days Ace (mg dry/wekighgt)| pr.conc. | B D F B DF Total B DF Total l| cou 010 1100 1100 000000 I|= l| 0 10 10 | am [ I ow 1 |] ver 10 10 10 el Reference substance (tuoranhons): __ The result withthereference substance iswithinthe range normally found. 002180 Lab.ref.: 993123 Measurofeoxmyge enn ant dps H. | Concentration (mg/kg dry weight) [CoC=oemon [ [[ [ [ww we TTTe e o howwe o o weow e w e e e e u]] | I = Oxygen (%) pH Oxygen - (%) = = oH - 1 [=e e Tn e Te Te | 002181 993123 -" DATA SHEETS ~ 002182 93123 EN SSoaktmteresries o0arr2isensesst ssuspier ue 4sliob/riiisess SesTsen yo as.0n0 BTeSl-adtaatne:sl6a3c6e1r o75c bwtoassbTaeifeesna:v i63ljbeaivrdelbiengen vad I Norge as. {Toni ason NY KrevERALe on Mewar Foren, fapostos: 1 Norge ns sendatsnarn: : | RCCiolas Lae WATER (0) 10 are (rasges snonscrs) | Tetatown,sGitsintomasjonssasceatons || SrruraGE on seen Seve. | I sen | a2(Dr(e2-vroentsuzRsooNrsorMR-zraver. / FaresiSimrihaasoettn eaers: 1 Twhsa Rete . BReEaTnRe || ALEaocTFeEenRcaetssyemrobotrecceistnhoesessninsgess NTLSota saan or mia:TTuedso -----. Sseecezre "io 150.60 e10s.0 SRF EeSrTEERoe AiVaOnRyGANISHE FLOGKIENIKALIER | TSeepaarldesovsSeeerccrreet Tnhoa MSebnRes 00218. 993123 FC-201AT LIGHT WATER (TM) 1% AFFF (FREEZE PROTECTED) 3 VIXTIGSTE FARSMOMENTZR. vikzigsse skadevirkninges Helsesaze: IRRITERNDE (Xi) Irriteres eynene. : Sikkeshes: Hiljotare: | 4 roxsrszsziesTILTAX. Tileak oyne: mSiknyulsltesss.rakKsonzoayknsereleggeruunmdiidgdemlebdazrti.kelSikgyellimneggduenrdervamtaranispmoirnts.: 15 Tilcak hud. Skyll sszaks tilsels toy. huden med sipe vis symptomer og rikelige mengder vama. Fjern oppstiz, kontakt lege. Vask tilsolt toy for cet brukes igjen og kast tilselt skotey. Tileak ianknding: Beviissgonseyrmipntgosmki:ldoepnp.sthSre,gbrfionrgfvreidskkomlmuefcn.deEvbiosr:syfmrpatomene vedvares, korzaks lege. Tiltak svelging: mKoendziaskisnsklegpeezsuomniedldle.lbaGsis.aldFrriemknaolelgbjreenknnoimngmeu:nneknuntiilseanmrbdevimsesdtlos person. S TILTAK VED BRANNSLUANING. Egaet brannslukningsmiddel: Produktet er et brannslukkingsmiddel. Ikke egnet brannslukningsaiddel: Eksponeringsrisike ved brann: i -_ 002184 9312-3 FEI0IT LIGHT WATER (TW) 14 AFT (reas smovecreD) Fomhzentingasradukees vad beams Feosedyzes ved siukking av branns 6 Tomax ves vriareres rei, PezsoSneligVeerveessinlessailktauknsde: andre punkeer dette S-datablades. TiltaoVakbResvzseekicddlbeeeu:rtenineolddmsssivdkemdsaeaenstt..eruiPtSalsoleliesil.ps]pe:rSaepvsiglrleinsseeansmleeausnsiiosdpdpeplebbuamnrtitsd.ednelbbmeaeksske.itoinlRee"mngeidorov FiematSenspauviskje13n,tiafliieersnviinagttasv kjenikaliesvealt, 7 ANDTERING 0G 0223EVARING. Secingelses fos sikker osgbevaring: GBMedaltaiiektlksel.e:lLaalggrezegesesniivdeioedmrr.tdedLmeaprgesrheavstorurveepsdroardvauemkspteestemgknaesnsduvkrionmeem.eoi4im9mkecosnotoeakrntamed beholderen tett lukket Utoranelise mesertaters ndr produktet ikke er i bruk. Ventilasjon: : SikkaOhpeptbsetvialrsaekmbaflorlas4jefaorhpdindestegbordatnav:entilert sted. " SikkeTsihkeerbsrteinsloeaas.for 4 forhindre eksplosjon: Sikkerhetstiltak for 4 forhindre statisk elektrisitet: ForhoHlodlsdraegstbaellvaesdjebneukesct Lukkes. Reyking forbude: Under bruk av SPEeroaoybdkiuelknizzeoetgskfoaagnrlirrseeeyskkdeieinvgkiocmfepocor,nkerrssiaknkaegtseprfriovareduurkeStneesrrnmimnkmugannaevdnaetmnoanbce:kkeona pogo/reelle1ss, | T ||| 85488 593133 FC-201a% LIGHT WATER (TW) 1% AFT (PREECE PROTECTED) EXS0NIAINGSXONTAOLL OG PERSONLIG VERNEUTSTZA. oyevesUan:ssh A 4 dams, vezaebziller ned vsepmrcaiyleerl.ler thie L oynene. suk teste atneve3z2au:k agnede vessenassier hindsering av produkzet. Vaevsnheennasniskksemresasvisfomisgesnedreiemleetevreidale(c) anbefales: Bucyiqummi Annetnhnusdhvehzuackeonnntehiies.dvesn: AncedzeUavntntslshuvfecirfnnoaskrnudziennsinaivngeLsufcibhazreb:eldmseetesrmiossltea.renBasveerigsesphenkoanvsenftorrapsejnogneen oS%rs7ee(n7i)skeSocdkajmepxe:r odgndevdazseksetfaovreasing:e phaarltvimfalsekse:mea/dPalsiiv.er moc svetsiDsaecgto:duakteisk.keVasspiiseust,sesdirsikkoemsrddeelrlergrarneydkiessmeudndesrivearobgeivdamme,d Vask hendene etter hiadtering og for spising. AnbetaESlroitdsisveeunnttssiulgdannsieincogznae:vsecnatvialsansiobnenyiskskees.erSetrislscfrosrikseilllssi,remrhkesiginyet ventilasjon slik at campkonsentzasjonene holdes ander apefalte administrative rormer og/eller kontroller spray eller tike. Adn. nore: for foruzensning azbeidsatmostere, fesruar 1996: van A(w1m7e3s2k-n1i8n5g)ed; Ingen sda. nora. 2+(2-83-UcTiOzKeSsYsETOvKeSrYa) -pZoTmA:NOL35/ (DIZTYLENGLYXOLONOBUTYEETER) (112-34-5) A(nTmaegreknninnogtesr: adAam.ernikoacnmsyk grenseverdi anbefalt av produsenten. 1,2-ETANDIOL (107-21-1) T88-a-cktivinemeezrrdssl pvvpeemrd:dii2m5pap/mm:(dd:a-mp1()0stev()stov) Tekverdi 2q/ad: - (dang) AMFOTER FLUOROALKYLANID-DERIVAT (Trade Secret) Aamerkninger: Ingen adm. norm. ALKYLA-nSmUeLzFkAnTi-nSgAeLrT:ERIn(gTernadeadaS.ecrneotr)m. i |i i : ; |! |! ||i || i |:; i : ; 1] i ;i!fm | | i 00218 993123 FC-201AF LIGRT WATER (TW) 1% AFTF(FREEZE PROTECTED) TT ti8tmienerrss vveerred:i pmogm/sml:- 3 2IRTLaU-GtRiOnAeLsKsYEv-eSUrLiFOmNgAT/-mS:ALT0,E1R (Trade Secre) A(sTmnegzeknninnogresrk: eAdnm.erinkoanrsm-k grensevesdsi sabefalt av produsenten. ASTERS-AtVineOrRsGANvIeSrKdEi FmgL/UmOsR:AIE0,M1IMALGIrZeRns(erveedred Saemcbreefta)lt av IM. Poon p---------- "iissandstors, fase, luke: ee Roepunice/ intervals Saetzepunks/-incervatls Fammepunke: setvassennelighes: Klar ravterges vaske. soe 4100 (Begyanende kokepunke) Tike selevant > 100 c (uiniflash) Ikke relevant Zksplosjonsgrenses, nedre: Ikke relevant Zksplosjonsgrenser, ovre: Despeyiks Loselishes i vann: Ikke relevant - 16 mg (Selkuless v/20 ) Blaseses Spesifikk vekt: k Dasptesthets ) = 1.10 (vann=1) a- 1.0 (ufeal) (Ralkulest v/20 Flyktige organiske forbindelser (VOC): =Pro35d9uige/tl) SCAQMD (g/l av Fordaspningshastighet: <1 (butylacetasl) Viskositet: = 18 centipoise ~ - 002187 L5a9p3ri1y2n3o. ugh vigor FC-201aF LicaT WATER (TM) 1% AFFE (FREEZE PROTECTED) 10 STAsILITEY og REAKTIVETET. Fozhold som skel unnghs: MateriTailkeesKiseonmt.skal uanghes FarlisKSeaaszssaeporanlmteonnliolnkegarsipdpraocadseuikkKslaeersrs:.ondTieomkmsiisdk. deHykderaopgoennetrliunogriadv.bGriukfstfiogredidasmper, blaading forvences ikke & representere noen risiko. StebilSiiteesistso!g rfaerslksiisvipzoersysmesisasion vil Like forekomme. 12 oreLvsNINGER OW AELemeARE. EseksWeordeoryanta:syeirzizesjon: symptomes saester, threr a whlase syn. ken vare rodhet, hevelse, | ZtteksHseoirdmrphtauotdn:ehudkienrzivetreesjornodh(eest,tehrevLealnsgev,ariKgiseelolefrtegrjtehnettastt Kontak): Languazig eller gjentest eksponesing kan fore cil: ! Allersisk o5 kloe. hudsesksjon: symptomer kan vase redhet, hevelse, blemmer | | Effekt2ne2orrmeenizkn,enldtkndainonvgef:roreekspsiolntesing som ovesstiser anbefalte adainistrative azPciehvsaiktzs,konnissnogenviagavh,essse,inermveaelssnqelSceavnleeds,syssktoveeinrmedmtie:nlensesjtyomnopsgteornineeer;ksktaanreedmvveaacceetilhofdeelpliense, | bevisstleshet. - Iesitasjon (evre lufeveier): sysptoner kan vare skehet 1 ness og svelg, hosting og nysing. TT EttaksOeyrcefsvoarlsgoikngu:tters med organiske dette produkter, vise: effakter sfolmuorLkejveearifkoarlsiteyri,reissoenr,fivneeksiteip, bmNuaeknlegapleyeatnted,eeekbaeiprnpyetrfieotreo,gmenshnelaeoasvtkhoeelrtogsfiae.mtbekeesftpfeofknoierererilnigssgomeorvpehrivfnoigrecnkeorkrjqeannnetivessekleogl, luotkenikaies nhe da brukes som forvisstt of i hemhold il __boz218s 9La9b3.1re2f3no.: Page 21 of 31 FC-201AF LIGHT WATER (TH) 13 AFFF (FREEZE PROTECTED) veiledning. Svelging kan fore cil: i Pihuvriizckenninoggavrysngyszemsees:sers.ynptomer ka: vare redisest uriamengde, blod Akosrpmiezxasnjeodnsoinleuunsgoennie.(LZunngaelbmeitnennenleilgsedrssoamksktiylldeSsilastsanfdreenmmeedrlegeme: oHovsptkeesto.p)p: blsoydmptogomeLsunkgaenbetvaernenelhsosetisnogm, kapnusvtaevraenslkievrs,trguiesnpdien.g, Inforaasjon om allerst, overfolsomhes: i Krefsizenkallende egenskeges: i Asvestofskadelige esenskapes: | Reproduksjonsskadelise egenskapers ci1 AireDeSttte rpraoduikstet,inWneahiovleder en elles flere organiske i! ofvleurorkljeenngiekaltiieds,, enscoemsmusloimgeuntsgeknagnamoelbeskorybleezseselloeg:lasgozmes i kroppen || gnieednbcraytstneingeskssipoofnefxeirng(em:e.caDbeotlicftoerre)l,igosgerkeinngaeknkukmjuelnecreeshevlesdsetfekcer | Znodrs mdeennbersukkeess sfzoam efkosrpvoinseartitngogovieshfeosrholodrgacniliskveeilfeldunoirnkgj.emikalier i| Fseonreazkeolnlsetebnefaovloirngianngiesnkeogfulnudoecrkpjoepmuilkaasljioenre:{ sbolmodeatrbetiidlerdee,n har i| vesanret apzubbeliidseerret vsiisdeern i19n7g0enArseknaed.eli3gMse eepfifedketmeiro.logiske studier av || | 12 OPPLYSNINGER OM MILIOFARZ. i PersisDtetetnes/Bpirooldougkitsekt niendnbeehyotlhdaerrheetn:eller flee organiske afillujoerektjen(ipkeaslsiiesrsesntoen).muligens ikke ez nedbrytbare og forblir i = AndreNesdkbardyetvniirnkngi:ngez, milje: |i 5CO0DD 2(0Chdeamgiecrasl O(x3yigoecnheaDiemcaanld)Oxy=ge1n7D10ema0n0d0)mg=/k4g3:4 000 mg/kg: 20020/coD = 291. -- Akvatisk gifsighes: ___|00218 993123 FC-201AF LIGHT WATER (TM) 1% AFFF (FREEZE PROTECTED) 93510tmigm/elr;s LCSO for fisk (Fathead minnow (Pimephales promelas)) = a4a9/1t;iness EC50 for daphnia (Water flea (Daphnia magna)) = > 1000 95 30 timers ICS0 for minusters EC50, Mailgcezot=ox> 1(0P0h0otmogb/alc;terium phosphoreum) = 63 g/l; 3 timers 2C50, Activated Sludge Respiration Inhibition = > 1000 ag/1. Seg for avfallshdndsesing iht. gjeldende forskrifser. 13 FUERNING AV KJEMIKALIZAVFAZL. Metode: for fjerning av kjemikalieaveall: Scesialaviall. mottaks- eller Lbeevheeradlaviinaglslanlteilggenforoffsepnetsilailgavgfoadlklj.ent innsamler, Anbefalce aviallsgruppes: EOVEDKATZGORT UNDERRATZGORI 07: AVFALL FRA ORGANISKZ PROSESSER. 07 06: Avfall fra P3DB av fettstoffes, sipe, zengjeringsmidier, Eax-kode 07 06 03: dEeasliongfeenkesstjeonsomrigadnliesrkeogleksoesmmiedtliekrk,. vaskevaskes og modeslut. Avfallszoffnummes: 7151 Organisk avfall med halogea. Spesielle komponenter: fluorforbindelses. 14 OPPLYSNINGER OM TRANSPORT. AdR-klasse: - sitter: - i bokstav: - margnummer: : - cer1c-kort: - - UN-nunmer: - chO-klasse: - 1MDG-klasse: - &5a9:r1e3.380, ragesyoy FC-201AF LIGHT WATER (TN) 1% AFFF (FREEZE PROTECTED) 0-3 ee: - evs-az.s - weacs - ovsigeTioepplsyisannisnpgoerss:ferlis gods. 15 OPELYSNINGER OM LOVER 0G FORSKALFIZA. verkeetikets: SymbolZeizS)I:S0ELIG (Xa) Zaneho2l-d(e2r-:butokayetoksy)-esenol 19 3 Eeylessiykol 14 + a-setnTtanlgiess: ved svelging. Irziterer eynene. S-setnUinnaggehr:inndnding av damp/spreytetdke. Unngh konssks med eyrene og i sLtarnagkuseziGgrunkdoingtamksedmesdorheudemne.ngdFeArz mveannastogoffkeosnta4lsoynleengee;. Estktyelrl ohundgkhoennsdaeksa,g vviasskdemnesdesbipesholodgerveannn.elVleedr esvteilkgeitntge,n.kontakt lege ra2-- - || Kors. 0y5r30kes3h/y1g. lufcoenov: oveige opplysninger om meskeetiketten: vOvaernene4vnftiennemerpkhinpgroceuxktbeatseretn tpdidtifdrleimgoveerre. mMeerrkkeifnogresnkrivfitler og vil ciemviiddleesrtteidmeerrksetfatotressiziafvtefrolgavendJeanmuearrki1n3g3,8. som er basert pd Symbol: IRRITERSNOE (Xi) - Innetolder: 2-(2-buzoksyetoksy)-etanol, 1,2-etandiol Irriteser oynens. Usagh inndnding av damp/spreysechie. Unngh Khoundetna.k: Fmfedmaonynesnteo.ffeUrnng|hsylnaenngev;arisgkylelllesrtregkjsentGartutndikgonmtaekdt smceodre Vnaennng.desVevdansnveolgginkgo,nzakrtikklegteo.gEltatsesrvehundnkoongtakkotn,tavkatsklemgeed sipe og } ; uniddetnare. 00219: Lav.rej.no.: 593123 ragesuo FC-201A7 LiGaT WATER (TH) 13 AFFE (FREEZE PROTECTED) 0f0Lgriope: SpesiSeSilnklmekesslinocevsierstdeaogtaobnblesausdeessfbnooerildsfeealsr:aleigoegkjdeimsiskiabluisesi,on av Melse-, Milje- og || 3k2..inFFmoorressdikfreeiieffttaioolnmjekkfllaaarssess.iiffiisseerriinngg, ogmermkeirnkginmgva.v afvarlSitgaeffkjseomnikalier. 45.. FFoorrsskkzziiffet oomm sstpoefsfiksalsatvoitaelkl.. 6. Eee. | 16 ANDAZ OPPLYSNINGER AV 3STYDNING FOR BRUKERNZS SIXKERAZT Og AELon. i AavendFeillsaedsuosnsseinddees:sxuakoraansia for slukking av bramn hydrokessonss. || ViksiDgasztaeblkeidlde(zra) JveGdenuezraarlbeOifdfeilcseesn, aSvt.HMSPa-udla,taMbilnadneess:ota, USA. i AsseHetlied doaptpadbaltaedreitng:ex revider:. Tilpasse: nye merke- og HMS-databladforskrifses, fastsatt i januar 1998. Eee. :i E530 oppyssiages: i | oSIsynefldooyrtsmtnaeisnjgpoenrseosdoug9cebsedsetutentedoerpAMpSta-ozdmnaaitlnaegblaafndocemhhtoelneddr.siEruihhkevineihrsolbdbrruutkkilaogvvirhpeiraoddncuiekvrtaiernregnecsseen || pirkokedukesceti 1sakmosmvbaisnnaesdjondemtecde aEnudSz-edatparboldaudkette,r eslllleerr esnohmvmeredfaonrneern bprioksesasv || ec brukerens ansvar. i i i i do I ii i i 002192 . 993125 FC-201A7 LicET WATER (m0) 13 APre (PRezzz sromecrzn) FOLGENOE PRODUKTER DEXKES AV DETTE BNS-ONTASLADET: 3 Towns. + 327-L0i0g0h2e-08W4a2c-e9r 18 APES fire Fighcing Foam, FC-201a7, 200 3M To-r. + 2347-0L0ig0h2t-03W4a1t-e1r 1% ASFF Fire Fighting Foam, FC-20137,1000 3 Ton. + X37-L0i0g0h8t-02W0a5s-e3r 14 AFF rice Fighting Foam, FC-2017, Bulk WInr. Lo: x3r-0L0i0gsh-e02W0a1t-e3r 18 afer Fize - Fighting Foam, FC-201a7,1000 1 34. 10-z. + 3X47-0L0ig0h8t-02W0a2t-e5r 1% AFFF Fire Fighting Foam, FC-201a7, 200 L 3 1onr. . + X37-0L0i0g8h-t02V0a0t-e3r Fishting foes, r1c3-2aorieasr,size201 i : wir ils TARE A eTOf 4 aiif 0.80 2503 Utnahaug 4004 Stanger = = Toghone: +4751 875000 gg Tieslteifnaxg: sac+re4s7:51875200 a a Professor Olav Hanssensiei 15 ) soergen: 2T 7 TSh0or8meshlvennsgt. 55 >s =3 Towa sarsssizse @ m Internet: hitp://www.rt.no 5