Document Ovgbo96jj26LN3vG411NmoKX

ENVIRONMENTAL EVALUATION PILE REPORT Health & Environmental Sciences T.I.M.E. SYSTEM DR-0267-9698 ETHYLENE DIBROMIDE 90 REVISED: 10/24/89 OTHER IDS: SYNONYMS: ETHYLENE DIBROMIDE 90 COMPOSITION: 92.5% 7.5% FORMULA: MOLECULAR WT: DR-0001-5872ETHYLENE DIBROMIDE DR-0011-8343STODDARD SOLVENT ! PAGE 03/26/S rept e; This report is designed for use only by those authorized for input ("update clearance") to the T.I.M.E. databases. *********************************************************************** ****************************P*R*O*P*E*R*T*I*E*S********************************** APPEARANCE: light yellow clear liquid MELTING POINT: SPECIFIC GRAVITY: 2.0 BOILING POINT: 130C PH: VAPOR PRESSURE: 11.6 mmHg @ 20C ODOR DESCRIPTION: sweet, nauseating SOLUBILITY: insoluble in water ******************************************************************** CHEMICAL FATE INFORMATION ******************************************************************** MOVEMENT & PARTITIONING Please also see the two major ingredients of this product: ethyl ne dibromide, DR-0001-5872, and Stoddard solvent, DR-0011-8343. BIOTA: The log octanol/water partitiion coefficient for EDB has been reported to be 1.96 (antilog = 91.2) suggesting very little potential for bioconcentration of biomagnification (R-l). DEGRADATION & PERSISTENCE Please also see the two major ingredients of this product: ethylene dibromide, DR-0001-5872, and Stoddard solvent, DR-0011-8343. CHEMICAL: Hydrolysis rate constants for the active ingredient w re measured under carefully controlled conditions and half-life was calculated at pH 7 and at 25 C to be 8 years (R-6). ES2020 ES2040 20-Day biochemical oxygen demand (BOD20) is below detectable limits for EDB. Theoretical oxygen demand (ThOD) is calculated to be 0.43 p/p for EDB. ******************************************************************** * TRADEMARK OF THE DOW CHEMICAL COMPANY DOW CONFIDENTIAL Do -)3--^-7^ r-'ONFTOFNTTAi ENVIRONMENTAL EVALUATION PILE REPORT Health ft Environmental Sciences T.I.M.E. SYSTEM PAGE 2 03/26/98 DR-0267-9698 ETHYLENE DIBROMIDE 90 KEPT E2 *********************E*C*O*T*O*X*I*C*O*L*O*G*I*C*A*L**IN*F*O*R*M**A*T*IO*N********************* AQUATIC Please also see the two major ingredients of this product: ethylene dibromide, DR-0001-5872, and Stoddard solvent, DR-0011-8343. In tests 6 0.5-2.0 mg/L of EDB, no statistically significant decrease in photosynthesis was seen in estuarine phytoplankton (R-3). It is not expected that this product will behaive toxicologically appreciably different that the pure active ingredient. ES3011 ES3102 Acute LC50 for emerald shiner (Notropis atherinoides) is 40.3 mg/L of EDB. Material is slightly toxic to fish on an acute basis (LC50 between 10 and 100 mg/L). ******************************************************************** ENVIRONMENTAL ASSESSMENT ******************************************************************** Please also see the two major ingredients of this product: ethylene dibromide, DR-0001-5872, and Stoddard solvent, DR-0011-8343. ******************************************************************** *********************R*E*G*U*L*A*TO**R*Y**IN*F*O*R**M*A*T*IO*N*************************** It is the responsibility of the person handling a material to comply with applicable federal, state, and local laws and regulations which are increasingly site- and chemical-specific and may not be included her Changes occur frequently so current status should always be confirmed. Please also see the two major ingredients of this product: ethylene dibromide, DR-0001-5872, 6 Stoddard solvent, DR-0011-8343. EPA has approved an analytical method for satisfying RCRA requirements under 40 CFR Parts 264 ft 270 (R-8). ES7240 ES7180 ES7204 ******************************************************************** DETECTION * TRADEMARK OF THE DOW CHEMICAL COMPANY DOW CONFIDENTIAL 00 a 32376 OONFTDFNTTAl ENVIRONMENTAL EVALUATION FILE REPORT Health & Environmental Sciences T.I.M.E* SYSTEM PAGE 3 03/26/98 DR-0267-9698 ETHYLENE DIBROMIDE 90 REPT E2 ******************************************************************** Please also see the two major ingredients of this product: ethylene dibromide, DR-0001-5872, and Stoddard solvent, DR-0011-8343. INSTRUMENTAL; Portable infrared vapor detectors run at 8.6 urn wavelength on a 20.25 m pathlength through directly-sampled ambi nt air can have detection limits down to 0.6 ppm of the active ingredient (R-9). A GC-MS capillary column method has been validat d for detection of EDB in mixed liquid wastes to an estimated d tection limit (EDL) of 3.0 ug/L over a cone range of 3.0-550 ug/L w/ a calculated method detection limit (MDL) of 0.2 ug/L & a non-detection limit of 1.0 ug/L (R-8). ******************************************************************** **************************R*E*F*ER**E*N*C*E*S********************************* R--1 ES 0006 r_2 es 0018 R-3 Erickson, S.J., et.al., BULL.ENV.CONTAM.TOX.24:910-915, 1980, in K-1715-(100). R-4 USEPA-RCRA. 40 CFR, Part 261, Appendix VIII. R-5 USEPA-TSCA. 1988. Federal Register 53 (115): 22300-22325, June 15. R-6 Ellington,J.J., et.al, Measurements Of Hydrolysis Rate Constants For Evaluation Of Hazardous Waste Land Disposal. Vol. 3, EPA 6000/3-88/028, 1988 R-7 SUSPECT Database, Roytech Publications, 1988. R-8 Yancey,M.F.,R.A.Kornfeld,& J.S.Warner. 1988. Cap column GC-MS deter of 77 org comp in lq wastes. USEPA, EMSL, Cincinnati, OH. EPA/600/4-88/030: 68pp. R-9 Foxboro. 1986. OSHA cone limits for gases... The Foxboro Co., Foxboro, MA 02035. No. 03/86 15M PUB-522B (data for MIRAN series IR analyzers). *********************************************************************** END OF REPORT? FOR ADDITIONAL INFORMATION CONTACT: Chemical Hazard Evaluation & Communication Health & Environmental Sciences Dept. THE DOW CHEMICAL COMPANY 1803 Building, Midland, MI 48674 or Phone (517) 636-2609 * TRADEMARK OF THE DOW CHEMICAL COMPANY DOW CONFIDENTIAL DO 130377 CONFTDFN7 TA1