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ABDOO105480 BCP MATERIAL SAFETY DATA SHEET PWM A DEEILAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 Emergency Telephone (614) 431-6600 (OPERATION ALERT) A THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.3 200 REQUIRES THAT THE INFORMATION CONTAINED ON THESE SHEETS RE MADE AVAILABLE TO YOUR WORKERS. INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY. FOR INDUSTRIAL USE ONLY VISTA POLYMERS CO INC ATTNJ SAFETY DEPT NON-EMERGENCY TELEPHONE HIGHWAY 25 (504) 387-5101 ABERDEEN* MS 39730 description: vinyl CHLORIDE monomer PRODUCT TYPE: VINYL CHLORIDE MONOMER APPLICATION: USE IN MANUFACTURE OF POLYVINYL. CHLORIDE PAGE 1 COR ISS 20-NAY-89 SIGNAL WORD DANGER! This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to the reauirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. CHEMICAL HAZARD RATING HEALTH-3(hidh) FIRE-4(extreme) REACTIVITY^!(slight) CHRONIC"* 29CER1910.1200 HAZARDOUS INGREDXENTS/REPORTFD HEALTH EFFECTS CAS/REGISTRY NO. MATERIAL DESCRIPTION The ingredients listed Lu'low have been associated with one or more of the listed immediate and/or delsyed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING OR HANDLING* READ AND UNDERSTAND THE MSDS. 75-01-4 fcVINYL CHLORIDE CANCER HAZARD. Can cause cancer* This material has been listed by NTP* 3 ARC or OSHA as a human carcinogen. Can cause liver dama.de. Can cause Kidney damage. Can cause central nervous system depression. Signs and symptoms may include headache* dizziness* nausea* vomiting* unconsciousness and even death. ACGIH TLV: 5 PPM (10 MG/M3) TWA OSHA PEL! 1 PPM TUA* 5 PPM 15-MINUTE STEL NIOSH DOCUMENT NUMBER: 79-102 OTHER: OSHA PEL: CANCER-SUSPECT AGENT* 29CFR1910.1017 READ NEXT PAGE DISCLAIMER --SEE REVERSE SIDE ABDOO105481 DISCLAIMER " SELLER`MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY BORDEN CHEMICALS AND PLASTICS OPERATING LIMITED PARTNERSHIP, BCP MANAGEMENT, INC., except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States patent. The information provided herein was believed by Borden Chemicals and Plastics Operating Limited Partnership, BCP Management, Inc', to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence or otherwise shall be greater in amount than the purchase price of the quantity of product in respect , of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. i" J ABDOO105482 BCP MATERIAL SAFETY DATA SHEET aoDeEiLAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 Emergency Telephone (614) 431-6600 (OPERATION ALERT) A, description: vinyl chloride monomer PRODUCT TYPE: VINYL CHLORIDE MONO Ml: R application: use in manufacture of polyvinyl chloride PAGE 2 CUR ISS 20 MAY-89 29CFR1910*1200 HAZARDOUS INCREDIENTS/REPORTED HEALTH EFFECTS CAS/REGISTRY NO* MATERIAL DESCRIPTION PHYSICAL DATA SOLUBILITY IN WATER -- SLIGHT SPECIFIC GRAVITY f? 25/25 C MELTING POINT VAPOR PRESSURE APPEARANCE BOILING POINT ? 760 MM HG* ODOR VAPOR DENSITY <AIR=t>* 0*908 -256 DEG F AT 68 DEG F 3*39 ATM COLORLESS Limmi GAS 7*0 DEG F FAINTLY SWEET 2*15 IMMEDIATE HEALTH HAZARD DATA SKIN ABSORPTION: No hazards known to Borden* INGESTION: May tie harmful if swallowed* INHALATION: Harmful if inhaled* Can cause burns to nose* throat and lungs* Can cause central nervous system depression SKIN: Causes burns* EYES: Causes burns* HANDLING PRECAUTIONS INHALATION: Do not breathe das or mist. Use with adeauato ventilation* SKIN* Do not set on skin* EYES: Do not set in eyes* Handle in accordance with good industrial hv-dicne and safety practices* These practices include avoiding unnecessary exposure and removal of the material from eyes skin and clothing* Wash thoroughly after handling* EMERGENCY AND FIRST AID PROCEDURES INGESTION* If accidently swallowed? dilute by drinking large ouantities of water* Immediately contact poison control center or hospital emergency room for any other additional treatment directions* INHALATION: If inhaled' remove to fresh air* If not breathing give artificial respiration? preferably mouth-to-mouth* If breathing is difficult? give oxygen* Call a physician. SKIN CONTACT: Immediately flush skin with plenty of water* Remove contaminated clothing. Call a physician* Wash clothing Lief ore reuse* EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with DISCLAIMER --SEE REVERSE SIDE READ NEXT PAGE ABDOO105483 BCP MATERIAL SAFETY DATA SHEET vwa AOOEEILAWARE LIMITED PARTNERSHIP Emergency Telephone (614) 431-6600 'V,, (OPERATION ALERTf, BCP Management Inc. General Partner BOX 427. GEISMAR, LOUISIANA 70734 description: product type: application: vinyl chloride monomer vinyl chloride monomer use in manufacture of polyvinyl chloride PAGE 3 CUR ISS 20-MAY-09 EMERGENCY AND FIRST AID PROCEDURES entire surface of cues and lids* Call a phus i e i an * FIRE AND EXPLOSION HAZARD DATA EXTREMELY FLAMMABLE GAS Keep vapor away from heat* sparks* flame and other ignition sources including* tout not limited to* pilot lights* heaters* cigarettes* electric motors and static discharge# Vapor is heavier than air and itsaj settle in low places or travel outward to a source of ignition and f1ashback In case of fire* allow das to burn if flow cannot be shut off immediately# Apply water from a safe distance to cool container and protect surrounding area# REACTIVITY DATA Normally stable* but mas become unstable at high temperatures or maw react with water# CONTROL MEASURES If airborne contaminants are generated when the material is heated or handled* sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria# ENGINEERING CONTROLS: The following exposure control techniaues maw be used to effectively minimize employee exposure# local exhaust ventilation* enclosed system design* process isolation and remote control in combination with appropriate use of personal protective ecuiirment and prudent work practices# These techniaues may not necessarily address all issues pertaining to your operations* We* therefore* recommend that sou consult with experts of your choice to determine whether or not your programs are adeauate# PERSONAL PROTECTION INFORMATION Wear full protective suit 8 boots if contact is likely# Where air contaminants can exceed acceptable criteria* use NIOSH/MSHA approved respiratory protection equipment# Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA 29 CFR 1?10#134 or other applicable standards or guidelines# Use goggles 3nd face shield if contact is likely# Wear impervious gloves as required to prevent skin contact READ NEXT PAGE DISCLAIMER --SEE REVERSE SIDE ABDOO105484 TM BCP MATERIAL SAFETY DATA SHEET aoDeEiLAWARE LIMITED PARTNERSHIP Emergency Telephone (614) 431-6600 (OPERATION ALERT) BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 description: product type: application: vinyl chloride monomer vinyl chloride monomer use in manufacture of polyvinyl chloride raise 4 CUR ISS 20-MAY-8? SPILL OR LEAK PROCEDURES Keep upwind of spills or leaks* WASTE DISPOSAL Dispose of according to local* state/provinci1* and federal reeuicements* Empty container: May contain explosive vapors* DO NOT cut? puncture or weld on or nearly* STORAGE PRECAUTIONS Violent polymerization maw occur at elevated temperatures DOT CLASSIFICATION Flammable Gas* 600 PM-VCM PREVIOUS ISSUE*19-N0V-88 PRINT DATE: 12-Mar-?3 02IA2 PM CURRENT ISSUE:20-MAY-89 THIS JS THE LAST PAGE DISCLAIMER --SEE REVERSE SIDE ABDOO105485 BCP MATERIAL SAFETY DATA SHEET rwff A DEEILAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 SARA TITLE III SECTION 313 AND 40 CFR Part 372 TOXIC CHEMICAL NOTIFICATION SHEET Emergency Telephone (614) 431-6600 (OPERATION ALERT) & VINYL CHLORIHE MONOMER This product contains the followin'! toxic chemical(s) subject to the reporting reouirements of Section 313 of Title JII of the Sunerfund Amendments and Resuthorization Act of 1986> and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. CAS Registry Number Chemical Name Pet. By Weight 75-01-4 VINYL CHLORIDE (MONOMER) 99.80 This Toxic Chemical Notification Sheet must not be detached from the Materiel Safety Data Sheet (MSDS). Any copying and redistribution of the MSDS shall include copying and redistpibution of this notification sheet attached to conies of the MSDS subsequently redistributed. 600 PM-VCM PRINT DATE 1?-Kr-91 02142 PM DISCLAIMER --SEE REVERSE SIDE