Document OJ4dzw5pBa8RqNVGeDV8QDRZK

no A 041751 nONFJOFNTTA! CARBORUNDUM /a/su^tW gt-Ah/icar (fi-fa Tyiu ut-jcv) MATERIAL SAFETY DATA SHEET 24-HOUR EMERGENCY ASSISTANCE BP America (In Ohio); 800-362-8059 (Outside Ohio); 800-321-8642 CHEMTREC Assist: 800-424-9300 MSDS Number > 105/M0101 GENERAL ASSISTANCE 716-278-2183 NFPA FIRE HAZARD SYMBOL 4*wm Ftonratony >High A A MMn '>$>' y y isight /0A \ AA <x> Y/ MANUFACTURER/SUPPLIER: The Carborundum Company - Fibers Division .ADDRESS: P.O. Box 808, Niagara Falls, New York 14302 TRADE NAME: FIBERFRAX DURABLANKET 2600 CAS NUMBER: MIXTURE By SYNONYM(S): CERAMIC FIBER; REFRACTORY FIBER; MMVF; REFRACTORY CERAMIC FIBER; RCF CHEMICAL FAMILY: VITREOUS ALUMINOSILICATE FIBERS MOLECULAR FORMULA: AI203.Si02 (Amorphous) MOLECULAR WEIGHT: NA PRODUCT CODE: NA HIERARCHY: NA HEALTH WARNING! POSSIBLE CANCER HAZARD BY INHALATION MAY BE HARMFUL IF INHALED (Hazard depends on duration and level of exposure) MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT FLAMMABILITY NON-COMBUSTIBLE REACTIVITY STABLE INGESTION: Ingestion is unlikely. If ingested in sufficient quantity, may cause gastrointestinal disturbances. Symptoms may include irritation, nausea, vomiting, abdominal pain and diarrhea. Copyright 1980, National Fire Protection Assoc., MA 02269. This reprinted material is not the complete and official position of the NFPA on the referenced subject, which is represented only by the standard in its entirety. 00 A 041750 CONFIDFNTTAl SKIN: SLIGHTLY TO MODERATELY IRRITATING. May causa irritati n, inflammaition tad cash. EYE: SLIGHTLY TO MODERATELY IRRITATING, f the eye. Abrasive action may cause damage to the uter surfac INHALATION: May cause respiratory tract irritation. Pre-existing medical conditions may be aggravated by exposure; specifically, bronchial hyper-reactivity and chronic bronchial r lung disease. SPECIAL TOXIC EFFECTS: The existing toxicology and epidemiology data bases for RCF's are still preliminary. Carborundum is continuing to support the necessary investigations and will stake all data available to all interested parties. Information will be updated as studies are completed and reviewed. The following is a review of the results to date: EPIDEMIOLOGY At this time there are no known published reports demonstrating negative health utcomes of workers exposed to refractory ceramic fiber (RCF). Epidemiologic investigations of RCF production workers are ongoing. The preliminary evidence, obtained from employees in RCF manufacturing facilities, is as follows: 1) There is no evidence of any fibrotic lung disease (interstitial fibrosis) whatsoever on X-ray. 2) There is no evidence of any lung disease among those employees exposed to RCF that had never smoked. i 3) A statistical "trend" was observed in the exposed population between the duration f exposure to RCF and a decrease in some measures of pulmonary function. These observations are clinically insignificant. In other words, if these observations were made on an individual employee, the results would be interpreted as being within the normal range. 4) Pleural plaques (thickening along the chest wall) have been observed in a small number of employees who had a long duration of employment. Thera are several occupati nal and non-occupational causes for pleural plaque. It should be noted that plaques are not "pre-cancer" nor are they associated with any measurable effect on lung function. TOXICOLOGY A number of studies on the health effects of inhalation exposure of rats and hamsters are now reaching completion. In a lifetime nose-only inhalation study, rats exposed to the Maximum Tolerated Dose of 30 mg/m3 (200 fibers/cc) developed progressive lung damage (interstitial fibrosis) and cancers of the lung and of the pleura (lining of the chest wall and lung). in contrast, hamsters similarly exposed developed interstitial fibrosis and pleural cancer, but no lung cancer. Cancer of the pleura is called mesothelioma. A multiple dose study (3, 9, 16 rog/m3; 25, 75, 150 fibers/cc, respectively) is currently ongoing in rats. After 24 months of exposure, only reversible cellular changes have been seen in the low dose group. At 9 mg/m3 (75 fibers/cc), areas of lung fibrosis are barely discernible and at 16 mg/m3 (150 fibers/cc) both lung and pleural fibrosis are present. ND = No Data NA s Not Applicable 105/Page 2 ol 8 DO A 041750 CONFXDFNTTAI, At this time, no lung or pleural cancer has been seen in the multiple dose study. This informati n will be updated nee the study is completed. The International Agency for Research on Cancer (IARC) reviewed the carcinogenicity data on man-made vitreous fibers (including ceramic fiber, glasswool, rockwool, and slagwool) in 1987. IARC classified ceramic fiber, fibrous glasswool and mineral wool (r ekwool and slagwool) as possible human carcinogens (Group 2B). INGESTION: Ingestion is unlikely. If ingested, the preferred method of elimination is through natural gastrointestinal elimination. Drink extra water. Get medical attenti n if gastrointestinal symptoms develop, for exasple, irritation, nausea, vomiting, abdominal pain and diarrhea. SKIN CONTACT: Remove contaminated clothing. Wash area of contact thoroughly with soap and water. not rub or scratch exposed skin. Using a skin cream or lotion after washing may be helpful. Get medical attention if irritation persists. Do EYE CONTACT: Flush immediately with large amounts of water for at least IS minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Do not rub eyes. Get medical attention if irritation persists. INHALATION: Remove exposed person from source of exposure to fresh air. Some people may be sensitive to a fiber induced irritation of the respiratory tract. If symptoms such as shortness of breath, cough, wheezing or chest pain develop, seek medical attention. If person experiences continued breathing difficulties, administer oxygen until medical assistance can be rendered. NA The following personal protective guidelines should be followed. However, when the material has been exposed to temperatures greater than 1800 F, more extensive precautions are required as outlined in the "Special Frecautions/Supplemental Information" section. EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Contact lenses should not be worn unless chemical goggles are also used and care is taken not to touch the eyes with contaminated body parts or materials. Have eye washing facilities readily available where eye contact can occur. SKIN PROTECTION: Wear gloves, hats and full body covering to prevent skin irritation as necessary (see Special Precautions/Supplemental Information Section). ND No Data NA = Not Applicable 105/Page 3 of 8 A 0417ca CONFIDENT TAI RESPIRATORY PROTECTION: Properly designed and operated engineering e ntr la are the moat effective methods for minimiring airborne dust and fiber. If exposures exceed our Recommended Exposure Guideline of 1 fiber/ec f air (8-h ur TWA) and engineering controls are n t feasible, respiratory protection (as described below) must be used. Respiratory protecti n must 4 also be used if irritation is experienced, when airborne concentrations are unknown, r the material has been exposed to temperatures greater than 1800 F (see Special Precautions/Supplemental Information Section). When handling RCF products in monitored areas, Carborundum recommends that NIOSH/MSHA approved respirators be worn as utlined in the following table: Concentration (8-hour TWA) Minimum Acceptable Respirator Type 0-1 fiber/cc Optional disposable dust respirator (e.g. 3M 9970 or equivalent). 1-5 fibers/cc Half-face, air-purifying respirator equipped with high-efficiency particulate air (HZPA) filter catridges (e.g. 3M 6000 series with 2040 filter or equivalent). 5-25 fibers/cc Full face, air-purifying respirator with highefficiency particulate air (HEPA) filter cartridges (e.g. 3M 7800S with 7255 filters or equivalent) or powered air-purifying respirator (PAPR) equipped with HEPA filter cartridges (e.g. 3M W3265S with W3267 filters or equivalent). Greater than 25 fibers/cc Full face, positive pressure supplied air respirator (e.g. 3M 7800S with W9435 hose and W3196 low pressure regulator kit or W3061 high pressure regulator kit connected to clean air supply or equivalent). If airborne fiber levels are not known, as minimTM protection, use half-mask air-purifyinc respirator equipped with high-efficiency particulate air (HEPA) filter cartridges (e.g. 6000 series or equivalent). If respiratory protection is used, employees must be given instruction and training as described in 29 CFR 1910.134. BOILING POINT: na SPECIFIC GRAVITY: nd MELTING POINT: nd % VOLATILE: ND VAPOR PRESSURE: na EVAPORATION RATE (WATERsI): NA VAPOR DENSITY (AIR=1): na VISCOSITY: na % SOLUBILITY IN WATER: NA OCTANOUWATER PARTITION COEFFICIENT: POUR POINT: NA pH: na APPEARANCE/ODOR: ND ND ND = No Data NA =* Not Applicable 105/Page 4 of 8 00 4 04 l O-ONF ^ optsjj- FLASH POINT: NONE AUTOIGNITION TEMPERATURE: NONE ifI FLAMMABILITY LIMITS IN AIR (% BY VOL.) LOWER: FLAMMABILITY LIMITS IN AIR <% BY VOL.) UPPER: NA BASIC FIREFIGHTING PROCEDURES: Use extinguishing egent suitable for type of surrounding fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. .STABILITY/INCOMPAT1BILTY: Stable under normal conditions of use. concentrated alkali. Soluble in hydrofluoric acid, phosph rie acid and HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: None. Spill or Leak Procedure: Use vacuum suction with HEPA filters to clean up spilled material. Use wet sweeping or a dust suppressant where sweeping is necessary. Avoid clean up procedures that may result in water pollution, personal safety, handling and exposure recommendations described elsewhere in this data sheet apply to exposure during clean up of spilled material and must be followed. WASTE DISPOSAL: This substance, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however it could be characteristically hazardous if it is considered toxic, corrosive, ignitable, or reactive according to Federal definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This substance could also become a hazardous waste if it is mixed with or comes in contact with a hazardous waste. Cheek 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations at 40 CFR 262, 263, 264, 266 and 270 apply. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. The transportation, storage, treatment, and disposal of this waste material must be conducted in compliance with all applicable Federal, state, and local regulations, and in such a manner as to assure no discharge to a source of drinking water. SARA TITLE III INFORMATION: Listed below are the hazard categories for the Superfund Amendments and Reauthorization Act (SARA) Section 311/312 (40 CFR 370) : Immediate Hazard: Delayed Hazard: X_ Fire Hazard: Pressure Hazard: Reactivity Hazard: ^ ND No Data NA - Not Applicable 105/Page 5 of 8 00 r.ONr 4 2 756 TFNTTai Tbs product does not contain any toxic chamlcal(a) subject to tha reporting requirements of tha Suparfund Amendments and Raauthorization Act (SARA) Sactlon 313 (40 C7R 372) . ADDITIONAL ENVIRONMENTAL REGULATORY INFORMATION: Thara may be specific regulations at the local, regional or state laTel that pertain t tbls material. All components of tbls product are listed on the TSCA Inventory. All consonants of this product are listed on the Canadian DSL Inventory. This product contains the following substance(s) listed by the State of California n Proposition 65, the Safe Drinking Hater and Toxic Enforcement Act of 1986: - cerarac fibers (airborne particles of respirable size) The following Canadian Workplace Hazardous Materials Information System (WHMIS) apply to this product: Compressed Gas Other Toxic Effects - Flammable/Combustible - Oxidizer x BloHazardous - Corrosive - Acutely Toxic - Dangerously Reactive categories - HANDLING/STORAGE: The toxicologic data indicate that ceramic fiber should be handled with caution. The handling practices described In this MSDS must be strictly followed (see section on Personal Protection Information). In particular, when handling refractory ceramic fiber in any application, special caution should be taken to avoid unnecessary cutting and tearing of the material to minimize generation of airborne dust. r, It is recommended that full body clothing should be worn to reduce the possibility of skin irritation. Washable or disposable clothing may be used. Do not take unwashed work clothing home. Work clothes should be washed separately from other clothing. Rinse washing machine thoroughly after use. If clothing is to be laundered by someone else, inform launderer of proper procedure. Work clothes and street clothes should be kept separata to prevent contamination. Product which has been in service at elevated temperatures (greater than 1800 F) stay undergo partial conversion to cristobalite, a form of crystalline silica. This reaction occurs at the furnace lining hot face. As a consequence, this material becomes more friable; special caution must be taken to minimize generation of airborne dust. The amount of cristobalite present will depend on the temperature and length in service. IARC has recently reviewed the animal, human and other relevant experimental data on silica in order to critically evaluate and classify the cancer causing potential. Based on its review, IARC classified crystalline silica as a group 2A carcinogen (probable human carcinogen). The OSHA permissible exposure limit (PEL) for cristobalite is 0.05 mg/M3 (respirable dust). Tha ACGIH threshold limit value (TLV) for cristobalite is 0.05 mg/M3 (respirable dust) (ACGIH 1991-92). Use NIOSH or MSHA approved equipment when airborne exposure limits may be exceeded. Minimal acceptable respirators recommended for given airborne cristobalite concentrations are: ND No Data NA * Not Applicable 105/Page 6 of 8 &0 A 0417cr-ONFTDFNTTAl' Concent ration Minimum Acceptable Respirator Type Up t 5 fibers/ec r up to 10 tines the OSHA PEL for cristobalite Half face, air-purifying respirator equipped with high-efficiency particulate air (HEPA) filter cartridges (e.g. 3M 6000 series with 2040 filter or equivalent). Up to 25 fibers/cc or 50 times the OSHA PEL for cristobalite (2.5 mg/m3) Full face, air-purifying respirator with highefficiency particulate air (HEPA) filter cartridges (e.g. 3M 7800S with 7255 filters or equivalent) or powered air-purifying respirator (FAPR) equipped with HEPA filter cartridges (e.g. 3M W3265S with W3267 filters or equivalent). Greater than 25 fibers/cc or 50 times the OSHA PEL for cristobalite (2.5 mg/m3) Full face, positive pressure supplied air respirator (e.g. 3M 7800S with W9435 hose and H3196 low pressure regulator kit or W3061 high pressure regulator kit connected to clean air supply or equivalent). If airborne fiber or cristobalite concentrations are not known, as minimum protection, use NIOSH/MSHA approved half face, air-purifying respirator with HEPA filter cartridges. Insulation surfaces should be lightly sprayed with water before removal to suppress airborne dust. As water evaporates during removal, additional water should be sprayed on surfaces as needed. Only enough water should be sprayed to suppress dust so that water does not run onto the floor of the work area. To aid the wetting process, a surfactant can be used. After RCF removal is completed, dust-suppressing cleaning methods, such as wet sweeping or vacuuming, should be used to clean the work area. If dry vacuuming is used, the vacuum must be equipped with a HEPA filter. Air blowing or dry sweeping should not be used. Dust-suppressing components can be used to clean up light dust. EMPTY CONTAINERS: Product packaging may contain product residue. Do not reuse. D.O.T. PROPER SHIPPING NAME (49 CFR 172.101): D.O.T. HAZARD CLASS (49 CFR 172.101): UN/NA CODE (49 CFR 172.101): BILL OF LADING DESCRIPTION (49 CFR 172.202): D.O.T. LABELS REQUIRED (49 CFR 172.101): D.O.T. PLACARDS REQUIRED (49 CFR 172.504): NA na na PRODUCT NAME NA na COMPONENT | CAS NO. | % | EXPOSURE LIMITS - REF. Alumino-Zirconia-Silicate (vitreous) NA 99-100 1 fiber/cc 8-hr. THA (Carborundum)* ND No Data NA = Not Applicable 105/Page 7 of 8 DO A 04t7^p OONFTD FNTTAl COMPONENT CAS NO. Remaining components n t determined hazardous and/ r hazardous components present at less than 1.0% (O.lt for carcinogens). NA |* I EXPOSURE LIMITS - RET. Trace NA * *No OSHA or ACGIH exposure limits have been established for these materials. Pending the results of long-term health effects studies, airborne exposures should be controlled at or below the Carborundum Recommended Exposure Guidelines listed above. REVISION DATE: 29-mar-1992 REPLACES SHEET DATED: COMPLETED BV: CARBORUNDUM HSEQ DEPARTMENT 27-jul*1990 NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Matenal Safety Data Sheet However, no warranty or representation, express or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product c ND = No Data NA - Not Applicable 105/Page 8 of 8 no A 041759 OONFTDFNTTAI Material Safety I Data Sheet MvL Manville Manville Calcium SlllcateJnsuiation _ MSDS No.2002-01 Product Name: Manville Calcium Silicate knuladan Generic Name: Cerium Silicate Tlumii Marion Chemical Name: Calchatt ailleata jgv JjS^J][^^|g Manufacturer Manvilla Salaa Corporation Address: p o- x sws Oanvar, CO 803I7-S10S Trade Names: Thermo-12: Thermo-12 Blua APR 0 6 1995 CAS#: Mlxnre/None 1171ad Formula: Miwae , Hazard Label: Thanno-i2 ephone: ow78-4soo irgency: i-eoo-aaa-wco Inaradient Nama symnene calcium aiiiaats CCHAUS-S#5-2 ,* Exoosure y.niitis) 9 mginf reapirscie dust lUbfiAi IS mg/m* total dust (OSHA) Gypsum 7778-18-S M B mg/m* respirstile dust (OSHA) 19 mg/m* total dal (OSHA) Continuous filament fibrous glass strand BSSS7-17-3 1 1 fiber/oc. Manvilla Workplace Expoetse Guideline S mg/m1 respirable dust (OSHA) 10 mg/m* total dust (ACGIH) Mm-made organio fibers Nana aaaijpied 1 Not established Figment Nona roigsd < 2 Not eetabllshed Msy oontsirc crystalline silica aa a V4808-60-7 tai-os 0.1 mg/m* mapli Nils warn (OSHA) ----------------------------------------------------------EMERGENCY OVERVIEW------------------------------------------Under normal conditions of use, this product la not axpaeted to create any unusual emergency hazards. Inhalation of excessive amounts of dust from this product may cause upper respiratory Irritation and/or congestion - remove affected individuals to trash air. Skin irritation may be treated by gently washing affected area with soap and warm water. Eye Irritation may be treated by flushing eyes with large amounts of water. If irritation persists, contact a physician. In the event of fire, use normal fire ghting procedures to prevent inhalation of smoke and gases from other products. Health Hazards Summary: Braadiing dust from Ms product msy cawe s senwtay Croat congestion. rod slight coughing. Getting from this product on yotr skin may coo# dun dryness. Getting dust in yotr eyes msy causa eye irritation. Braadting large amounts of dee from rids product msy lead to other health affects as discussed in section n of this Material Safety Oats Shaft Acute (short-term) health effects: Dust from this product ia a mechanics! Inferot iriMi meant that it may cause irritation or scratchinesa of the throat and/or itdiing of the ayes rod skirt Otmt from this produet may also causa dry skin. Page 1 of 5 Issue Oate: January L 1992 DO A 041760 CONFIDFNTIAl Manville Calcium Silicate Insulation MSDS No.2002-01 Chronic (long-term) health affects: ,^ Hits product may oontain < 0.1 to 0.9% crystalline silica as a contaminant in Cm raw materials. Crystalline siliea la considered a haxsrd by Inhalation Excessive exponas to crystalline silica can east silicosis, a non-eancerous hats dilate. Crystalline silica haa also boon classified a a probable causa of cancer by the International Agency for Research on Cancer (IARQ. father audit are being conducted to determine the risk of cancer when working with crystalline siltei pro duets. More detailed Information concerning the health offsets Of crystalline silica ia prsawed In section n Of this Material Safety Oats Shot Primary routes of entry (exposure): Inhalation (breathing duet), skin, and eye contact Symptoms of Overexposure Inhalation: lulledon of die wper respiratory tract (scratchy droad, ooughinft and congestion may oow in sesame ewoawaa. Skin Contact: Temporary Irritation, and dry skin may occur. Skin Absorption: Not sppiloablfc Ingestion: May cause temperpy Irritation to the gastroinosdnai tract (especially die stomach). Ey Contact: Temporary Irritation (Itching) or redness may ocas. S1 Inhalation: Remove to fresh air. Drink water to dear throw, md blow nose to remove Aw Skin Contact: Wash gently with sow wi warm water. Skin Absorption: Not wplicapia. Ingestion: Product Is not Intended to be Ingested or eaten If dds product la Ingested, hihetioii of die gastrointestinal (GO tract may ocas, and should be traarad symptomaecaily. No efaonic effects w expected following Ingestion Eye Contact: Do not nib or scratch yots eyec. Oust partidae may scratch the lens of die eye. Plush eyes with tea of wear for 5-15 minutee If torttsden pwiea. contact a physician Notes to Physician: this product is s medtmlcai Irritant, and Is net expected to proAicc any chronic health effects from scum exposures. Treatment should be directed toward removing the some of irritation with symptomio treatment sc necessary.i i________________ 1 This material will not bisn Therefore, no specie! proreikrei are neneeswy for dds product Normal fire fighting procedures should be followed to avoid Inhalation of smoke and gsses from other burning materials. SS2EH3G i Measures Procaduraa for containing spili/laaks: To mmmise airborne dusts, vacuum wit*. If sweeping la necoosay. uaa a duet suppressant (such sa wateri - DO NOT DRY SWEEP DUSTS. OR USE COMPRESSS AIR FOR CLEAN-UR. Wasta Management: Weatea are not hatadous se defined by the Resotme Coneervedon md Rainyqy Act (RCRA) (SO CPR 281). Comply with state and local regulations for disposal of csichan silicas, or crystalline silica containing products. States which include csrumo^nr in their definition of hazardous waste may consider **asi* containing this product hataruoua. Page 2 of 5 Issue Date: January 1, 1992 D0 A 041761 CONFTDFNTTAl Manvilla Calcium Silicate Insulation 4* MSOS No.2002-01 Um protective equipment as dMtnbrd in Motion S when handling Ioom or iryeetegeri mstariai. Moariai should bo kept *y. end protected from the clsmwes mtil um to tneintmin deeired produot porformenoo. WarehouM etorogo should be In aocortlaca with peek ego dlresdona. Summary; Protective equipment should bo provided as nanaatwy to provowi Irritation to die ttroM. eyas, end tida end to keep oepootne below die appllcMie eepoowo guitttlnoo. Although oryetoillne eilica may bo preeent In Pom owwm. the actual hoinU horn inhalation Is from nuieanoe duett. These rsnommanrtarions will mlnimln potential rlaka aeaooiatad with exposure. Goggles: or safety glaeaao with sMcshlsids wo tonnmmwoied to keep duet out of yew eyeo. Gloves: Leather or ootton giovee should bo worn to prevert akin oortoet and britadoa Barrier oraanta may also be deed to roAwo akin wontoat and britadoa Respirator Um a NIOSH approved dast/mlst raapbotor to protect againat bdialadon of axooaalvo amoteoa of duet ExamplM Of NIOSH mprovod dlapoaablo duat/mlat roopbotora for dda type of axpoewo are the 3M 9900 and Moldex 2200 raapbaMral. Soma oparodona may generate abbetna duet eonoanoatioro requiring a hl^er level of toapbomty protoetioa For sxpowxe* exceeding tan times the astabllahad exposwa limits, a NIOSH approvsdl half-mask toapbotor with Wjpi Efficiency Partiouiata Air t?AI filter cartridge should bo used (ExamplM Of NIOSH ^ptovaii raspbsrara Of this type are the MSA Comfo II with IT earaidgae. md the Swvtvsb haif-maak with #1090-00 oanridgaa). A respirator should bo used If ventilation la mavallabla, or Is limlaipiaia for keeping dmt levels below tho ^plloahlo oxpoatae limits. Ventilation: Local exhaust ventilation should bo provided-In wom Of exoasslve-duet oonosistations to^ remove obbomo dust, General dilution ventilation should be provided m necessary to kaap abtoome duet levels below the applicable oxpoatae limits and guidelines. The need for ventilation ayotama should bo evaluated by a professional btduaeial hygienist, while Ste daslqi of spooiflo ventilation aystams should bo conducted by o profoeeionoi anginaar. Other Loom fitting, long sleeved clothing should bo Hm to prolout akin from britadoa Exceed ctmo should bo weehed with soap wri warm water attar hmdilng. Special Considerations for rapair/maimananea of contaminated equipment: Um personal protective squtpmsm m dlsouaaod above, vactum equipment (where possible) before repair/maimartanoe to remove dust ^3H9W^Ma:ra[fJ^-VIMriSI3.M[af.3Wj;()a3;l<|:W Boiling Pt CC/*F): Not applicable Malting Pt TC/Th Not determined Vap r Pressure (mmHg) : Not applicable Water Solubility(%): Ml Spaeifie Gravity Evaporation rata (Butyl (water>1): 027 Acetate >1): Not applicable Vapor Density (Air>1): Not appIlMbl* % Volatila by volume: 0 Total VOC (g/liter): Not malleable pH: Net applleabla Solids Content: Not applicable Saturation in air {%): Not appilemie Viscosity: No* applleabla Appearance and odor Blue odorless solid pipe covering or block with mica flams addad m an additional visual marker to btdlsats this is an asbestos-free prockict Page 3 of 5 Issue Data: J rn, A C0^FTdfnTta; ( iii Unusual Fira/Exploslon Hazards: Reactivity: This produet Is not rasetiv* Hazardous Dacomposition Products: None dmnrnnid Manvilla Calcium Silicate Insulation MSDS No.2002-01 HAZXHPg Toxicological and Epidemiological Data Acuta Effects: The primwy sours health offsets Of Ms eyes, and akin dryness as a result of whh amorphous silts*, The LD, and LC, (dess or eenearwsdo lethal to 90% of this produet have not bean determined Chronic Effects: This product may oonorin < Oil to 03% crystalline silloa as a Crystalline allies Is eensldared s heard by Mwlsdon The Cancer flARQ has classified crystalline silica as probably classification is based on the findings Of laboratory animal ctudlee Implantation} that wars, considered sufficierx. considered limited for carcinogenicity. Several studies have bean Of cancer to workers exposed to dusts which contain orystsillne cUic* not consider other factors or elements dtat yttrium may bo exposed the excess deaths due to cancer could not be precisely determined conducted to determine the risk Of cancer whan werkkig with exposure to crystalline silica can eauea silleoeia. Crystalline Silica has not bean classified a caraktdgen by NTP References: A detailed listing of filnene.es on crystalline silica haahh pUriteadon HSE-738R (Crystalline Silica HaaWt and Safety tnfonmriord from Mmvllle. Major rsfersncaa used for the Wormcdon oomMnad bt Of the skin and t mimsis) for the raw material* for Raeearch on C2AJ. TMa ktjeebon, and datattnina the risk studies did of are being Excessive ki Mmvllles Of charge a as follower IARG "IARC Monoyaohe on die Evaluation of the Cmolnoganlo (Oak of Qtasalaala a Manana. VoL 42 Silica md Soma Silicates.'' World Health Organization Lyon Franc* pp. 39-144 UI71 IARC. "IARC Monographs on the Evaluation of Carckiogania Risks to Hana* iidiilww 7. Overall Evaluation of Ctreinogmieity: An Updating of IARC Mnnnyaphx. Voitanaa t 10 A2" World Health Oganizatton, Lyon. Franca, pp. 341-343 0987). Cooper. W.C and G. Jacobson "A 21-yew Radiographic FollowOf Workers bi Am Olwomita Induaay,' Jotanal of Occupational Medicine. 19:553-566 0977). Davis. UC. etal. "Morality Experience of Vermont Granite Miner*1' Amsriam Jowrad of nduasrial Medicine. 4:709-723 (1983). ) Disposal Considerations In Its original condition this proMct Ic not regulated ea a hazardous sea RCRA regulation. Consult local md state regutaaor* for addinon* dlapoeal which include carcinogens in their definition of hazardous waste may eonerc dus product hazardous. US. S>A tatdar States Transport Information Not classified a hazardous materi.-l by the U, S. Department of Transportation Rogulatory Information Crystalline silica has not been classified a carcinogen by the National Toxicology die Occupational Safety md Health Administration (0SHA). VagB 4 of 5 ` upNrT Issua Date: January 199^ Manvilia Calcium Slllcata Insulation MSOS No.2002-01 Crystalline silica (quartz) It Dated se a hazardous manriai wider the Hazvd Commwiiestion md/or environmental protection regulations of the following nans: California. Florida. Illinois. Naw Jersey. Pennsylvania, an Tamasaaa. California Proposition 65 Ustad Substances: Silica, arystsillna silica (airborne panicias of rsspirabls ilia). CrystalIIna silloa la not llatad as a hazardous stratam or hazardous waata wider die following US. fadsrai regulations SARA III sections 303 md 313; CERCUl This produet and Its oomponsras are listed on die following ohemiesl substance inventories; Toxic Scbstances Consol Act Chemical Subsora* Invaraory (TSCA inventory) Canadian Oomaado Substanea List CSU This Is a class 02A eornollad produet wider Canadian WHMIS Regulations Ibaaad on the IARC 3A classification for arystsillna sillea). Miscallanaous For additional Information concerning dlls produet contact the Manvilia Product Information Center at P.0. Box 5105. Denver, CO 50217*5108, or eail toll-free (500)654-3103 (outside die US. esll (303)978-49001 MSDS Raviaion Summary This Matarial Safety Oats Shear (MSOS) Is Issued to replace all previous versions of MSDSs covering die products indicated In section 1 of this sheet MSDSs Issued prior to ISSUE DATE for any produets covered by this MSOS as no longer affect This Issue also reflects s major revision to the format aid style of MSOS previously Issued by Manvilia. All seedone of the MSDS have bean redesigned and rewritten in m effort to communicate the hazards of this product mors effectively. Prepared for Manvilia Saiae Corpenuion P.a Box 5108: Denver. CO 80217-5108 By Manvilia Health, Safety A Environment Department As of the dare of preparation of this document the foregoing information Is believed to be scants ed Is provided In good faith to comply with applicable federal and state lewis). However, no warranty or representation with respect to such information la iraended or given. ---END OF MSDS 2002-01 -- Page 5 of 5 00 A 041?64 CONFTOFNTTA! Issua Date: January 1, 1932