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INDUSTRIAL DATA SYSTEMS Friday, February 13, 2009
MATERIAL DATA SAFETY SHEET - TALC
! Product Names
j Synonyms rChem ical Name
IM P 1826L FOC BC
IM P 1888L BC IM P 1822L BC
IMP 1819LBC
IM P 1886L BC IM P 1887L BC
IM P 1890L USP BC
IMP I817L
IMP 1818LBC
IMP 1821LBC
IM P 1824L BC IM P 1820L BC
IM P 1827L
IM P 1828L
IMP 1884LBC
Talcum powder, Soapstone, Steatite
IM P 1829L BC %S&WttQm
Talc ; Hydrous magnesium silicate
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CAS# 14807-96-6
I M anufacturer
Luzenac America, Inc. 345 Inverness Drive South Centennial, GO 80112 Toll-free 800-325-0299
Emergency H ealth Inform ation (24 hrs) 303-623-5716
IMP I823L USP BC IM P 1889L USP F G C B C IMP 1891LUSPBC IMP 1825LFOCBC IMP 1892LUSPEPBC IMP 1885LUSPBC
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C hem ical Fam ily Phytlosilicates
Section 2. ! Substance ; Talc
Com position/Inform ation on Ingredients
CAS#
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TLV- TWA
2 m g /m3 respirable fraction (A CGIH )
Use Talc TLV for total exposure measurements
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1 Section 3.
E m ergency Overview
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Under normal conditions of use, this product is not expected to create any unusual emergency hazards This
product is N O T flammable, N O T reactive, N O T explosive, has N O flash point, and poses N O special
hazards in the presence of fire.
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Potential H ealth Effects from Acute and Chronic O ccupational Exposures to Talc TARGET ORGANS
Inhalation
Skin Contact 1 I Eye Contact I
Ingestion
__L U N G S, R ESPIR A TO R Y SYSTEM ACUTE: Exposure to a large concentration of air-bora dust of this material may cause mechanical irritation of the mucous membranes and respiratory'tract. C H R O N IG Repeated o r prolonged inhalation of air-bom dust of this material may cause scarring of the lungs (pulmonary fibrosis), with shortness o f breath, chronic cough, and respiratory assisted heart failure. Prolonged exposure to talc can produce symptomatic talc pneumoconiosis (talcosis).
ACUTE: Direct contact may cause dryness, or may cause mild irritation if an allergic predisposition exists. CH R O N IG Prolonged contact may cause dryness of the skin, or may cause mild irritation if an allergic pre-disposition exists
ACUTE: Direct contact with dust may cause mechanical irritation of the eyes. C H R O N IG Repeated exposure may cause conjunctivae inflammation.
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ACUTE: This material is considered to be harmless and inert when ingested.
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C H R O N IG Repeated ingestion of large doses of talc for 13 and 1C successive days by rabbits and mice
revealed negative teratogenic and carcinogenic results.
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Luzenac America, Inc. MSDS Group USP Issued 07/01/2006
Talc CAS #14807-96-6
Page 1 of 5
PLAINTIFFS EXHIBIT
C A M-171
SYSTEMS Friday, February 13, 2009
Inhalation Skin Contact Eye Contact
Remove from exposure area to fresh air. If breathing has stopped, perform artificial respiration and get medical attention immediately. Keep person warm and at rest. Treat symptomatically and supportively.
Apply common skin moisturizers to relieve dryness. Irritations are uncommon; however, if irritation or redness develops, seek medical attention. Broken skin can be cleansed with mild soap and water.
Wash eyes with large amounts of water or normal saline solution. If irritation or redness develops, seek medical attention.
iTO; ^ : ' ;S| F lam m ability
Thus product is N O T flammable, N O T reactive, N O T explosive, has N O flash point, and poses N O special hazards in the presence of fire. Firefighters require N O special protective equipment or precautions.
S e c t i o n A c c i d e n t a l Release Measures
Small Spill
. fi Use vacuum to clean up spillage. Place in sealed container.
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Large Spill
For large spills, shovel or sweep up (while keeping dispersion of dust in air to a minimum) and place into suitable sealed containers for reclamation or later disposal Residue should be cleaned up using a highefficiency particulate filter vacuum. The use of water wash-down is not recommended. W et material can cause a surface used for walking to become extremely slippery. Talc is not considered a hazardous waste by RCRA criteria (40 CFR 261).
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Handling and Storage
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H andling & Storage
Handle in ways to minimize the creation of dust. Preserve product in sealed containers.
Personal Protection
sum Controls & Personal Protection
Use N IO S H approved dust respirator. Use safety glasses or dust tight goggles. N o special skin protection is usually required, but gloves should be worn by workers susceptible to skin irritation.
Controls
Dust Respirator
Safety Glasses
Gloves
Provide local exhaust or process enclosure ventilation to meet published exposure limits (TLV).
Appearance
White to grayish-white powder
Odor
Slight earthy odor.
Flam m ability
This product is N O T flammable, N O T reactive, N O T explosive, has N O flash point.
Specific Gravity 2.8 (water = 1.6)
M elting Point None
p H Slightly basic (10% slurry in water)
Solubility
iW;:
Waten <1 m g/m L @ 21 C Ethanol: <1 m g/m L @ 21 C
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Acetone : <1 m g/m L @ 21 C Cold acids: Insoluble
Alkalies: Iasoluble
Luzenac America, Inc. MSDS Group l'SP Issued 07/0.1/2:06
Talc CAS #14807-96-6
Page 2 of 5
SYSTEMS Friday, February 13, 2009
Stability
; Incompatibility | w ith various substances
This product is stable, non-reactive, and non-corrosive. Non reactive/none known.
Toxicology
N IO SH Registry Number: WW2710CG0 SAX Toxicity Evaluation: THR; N o t available Carcinogenic Status:
IARG (2006 in preparation) Has concluded that perineal use of talc- based body powder is possibly carcinogenic to humans (Group 2B), This is not a route of exposure relevant for workers and applies to one specific use of talc only. IARG (2006 in preparation) Inhaled talc not containing asbestos or asbestifoim fibres not classifiable as a human carcinogen (Group 3) OSHA: N ot listed. A C G IH A4 - N ot Classifiable as a Human Carcinogen N IP : N ot listed. A 2-year inhalation study demonstrated clear evidence of carcinogenic activity in female rats at exposure levels o f 18 m g /m3. Some evidence o f carcinogenic activity was observed in male rats at the same level N o evidence of carcinogenic activity was found in mice (N IP TR421). Tumorigenic Data: TCLo: ihkrat 11 m g /m 3 /lY -I TDLo: imp-rat 200 mg/kg O ther Toxicity Data: Skin and Eye Irritation Data: skn-hran 300 ug/3D -I M ID Teratogenicity (Reproductive Effects Data): N o t available. Mutation Data: N ot available.
Section 12. .......Ecological Information :
-
Section 13c :
Waste Disposal In form ation
Disposal Considerations
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Talc is not considered a hazardous waste byR CR A criteria (40 CFR261). D ry material can usually be land-filled. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste.
Luzenac America, Inc. MSDS Group USP Issued 07/01/2006
Talc CAS # 14807-96-6
Page 3 of 5
SYSTEMS Friday, February 13, 2009
i T ransport
j Information
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U.S. Department of Transportation - DOT: N o classification assigned
CANADIAN Transportation of Dangerous Goods; N o classification assigned LAND Transport - ADR/RID: N o classification assigned
AIR Transport - IATA/ICAO: N o classification assigned (International Air Transport
Association/Intemational G vil Aviation Organization)
MARITIME Transport - IMDG: No classifications assigned International Maritime Dangerous Goods)
LIARMONIZED Tariff Code: Talc - crushed or powdered. 2526.20.00. (Stat. Suffix 00)
EPA TSCA 12(B) Export Notification; N ot listed
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Regulatory Information
Chemical Inventories
Other Pertinent Classifications/ Rgulations
EPA TSCA Status: Listed (CAS 14807-96-6) CEPA Domestic Substance List - DSL: Listed AICS (Australian - NICNAS SWISS (Giftliste No: G-6939) E N C S/M i n (Japan) Talc exempt
EINECS (European No: 238-877-9) CEPA Non-domestic substance List --NDSL: N ot listed ECL (Korean No: KE-32773) PI CCS (Philippines) I h CSC (China): I ,isted
CALIFORNIA PROP 65 Status: Talc not listed STATE RIGHT-TO-KNOW : Talc listed - Illinois; Massachusetts; New Jersey; Pennsylvania; Florida CLEAN AIR ACT - Ozone Depleting Chemicals (O DCs): None C O N E G Approved Packaging: Yes N FPA RATINGS: (Scale 0-4) Health = 1, Fire = 0, Reactivity = 0
N P C A National Paint and Coatings Association - Hazardous Material Identification System HMIS)
HEALTH: 1* (Chronic Potential) FLAMMABILITY: 0 PHYSICAL: 0 PERSONAL PROTECTION: dust respirator, glasses or goggles, gloves
Section 16.
\ Label Hazard \ Warning
! Label | Precautions
OtherTtifonuation
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CAUTION - PROLONGED EXCESSIVE INHALATION MAY CAUSE LUNG INJURY
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UTILIZE DUST RESPIRATOR AND EXHAUST VENTILATION. REFER TO MSDS FOR COMPLETE DETAILS
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j Primary
;=| R eferences :: | for Key D ata ;! \ :|
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A C G IH - Documentation of TLV's 2001 O SH A - Chemical Sampling Information: Talc (Containing no asbestos) (Revised 1/15/1999) O SHA - TALC (Containing no asbestos). OSHA comments from the June 19, 1988 Final Rule on Air
Contaminants Project extracted from 54FR2324 eL serf OSHA - Compliance Interpretation Letter dated Aik,us1 22, 2000 regarding talc products containing less than
1% quartz. O SH A - Guidelines for Employer Compliance (Advisory) 1910.1200 App E N IO S H - Pocket Guide to Chemical Hazards. Talc (containing no asbestos and less than 1% quartz), N IO S H - REL's and General Recommendations for Safety and Health. [TALC (containing no asbestos). AIHA - Hygienic Guides Series - Talc(1982) IA R C - Talc VoL: 42 (1987) (p.185) 5. Summary of Data Repotted and Evaluation; Supplement 7: (1987)
(p.349) Talc N ot Containing Asbestiform Fibers (Group 3). CGOHS - Database MSDS FTSS. Network Version 2002. N I P - R oC /N IEH S Database. Network Version 2002.
| Glossary
A C G IH - American Conference of Governmental Industrial Hygienists A IH A - American Industrial Hygiene Association
Luzenac America, Inc, MSDS Group USP Issued 07/0I/20C6
Talc CAS # 14807-96-6
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SYSTEMS Friday, February 13, 2009
Important N otice
Issued by
QCOHS - Canadian Centre for Occupational Health and Safety IARC - International Agency for Research on Cancer N IO SH - National Institute of Occupational Safety and Health N TP - National Toxicological Program OSHA - Occupational Safety and Health Association PEL - Permissible Exposure Level TLV --Threshold Limit Value TWA --Time Weighted Average
Luzerne America, Inc. provides the information contained herein in good faith but makes no representation to its comprellensiveues s or accuracy. This document is attended only as a guide to the approp n ate precautionary'handling of the material by a property trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Richard J. Zazenski
Regulator^ Affairs Manager
E-mail: rich.zazenski@ america.luzenac.com
Phone: 1-303-643-0404
Fax: 1-303-643-0446
Luzenac America, Inc. MSDS Group U5P Issued 07/01/2006
Talc CAS # 14807-96-6
Page 5 of 5