Document OED6waB08zJBYpxEbnKxzQrKK

FOR DU PONT USE ONU AR226-2911 Haskell LaEb.orIa.todEryulNstfPeooownrnat-TRkd,ooeaxDdiNc,eoelFalmow.ogauy0rres. anaBnd1od9x7I1n5C10do,u.,stIrniac.l Medicine HASKELL LABORATORY REPORT NO. 109-83 Material Tested* f Study11I/n1i/t8i2at-e2d/2/C8/o8m3 pleted HaNsokneell No. t^^yj^^^ubm itte^by Seaford, DE EVADLEUTEARTMIOINNAOTFIONMEOTHFOADSIRABNDORMNEEmjOB^^E^V^E^LO^E^MBEl^iF.OR Summaryi wdlhtaoeihbsteeoottorrvhmaTreetirhriocneerahasyltttihiismoedetnorxaamprttoaieeacffrlliaam^adrlBeieerdnsbbaaotsoictrarcrpwaetcclpiootthanllbceteljchenet,]trations. ,r mrreedietetehasovicosdacrpleucftpoioatontraencbdltluhmedet.eoetdhoadcBsshaetasesetnsddson `0 neaaisnvndaarlleusycAoaosltmivensmede.wn.entmTdTdehedhetihsesofonmdorpreftt.hoifhoouornddtusmmaroemfaekepstetlhassinmejtguphTsleeaeinnngaoNdxfIOaanSTnHdweanliacaytxhrnsiiatsilessyoraosimpfoirspnoalpeoirfyfbotluoarbairrenolbcs^voojerhjfnrUooaerlflf^jjpcpHaaorcHsilcolmuedrrce^atvtcioeoylnopaneodd i t Introduction: was uAndt etrhtaekerneqwueitsht tohfe TfeoxlltoilweinEgthgeorsalDs:epartment at the Seaford Plant, work 1) acctohnornaoeltmvyaiasaniltusionaggotrefaipsaahoniirpcbreoox(GpisyCtl)l' n^ an m eth alysis odU fl^ of the ^|H H isopto pBy)^f^JrrxcoosLaehtmmholppsllsuoinoybgsslueqtIaimnuodepnni.nt ggearss - 1- Company Sanitized. Does not contain TSCA C35 2) aactnodudsroerGrvebCnaeltaunlynat taetIlunybaseuimssef.eothraotdsatmhfoeprlSinseagamfopofl1CrindBgJIlafa<#nondltl,oawwnahelidychsbisyemotphfleoraymisrabalordsnoeelsm]iodrpition andb'yheicsvohallveuemantpetlodyasensaeowrspmotileoitdnhoaadnddsfooGrrbCesaanmnt aptlluyibnsegisfaoondrf stahanmeapldyliesnsigsorbooiffng dae vtesaHcluraiTabsthkeiioesslnl trhewLepaoobrkprortroaancdtdoeedrsyutchrreefiboemriosesrtahtmhoudesp^;ldienoexgvfpeealtrohnipdmemeasenonntlatavllyednpesistrsocdcrioeebdfseoudarrpei rastbibooaonnvrmden.eerr|eiHAsioup0dpl1dtesnedvfiexolroIptehde Experimental Procedure: . Test Materia i"icrtsctmcthan_etoohaers_mmsHoen-_tpmpud^e_oHovaslaBannireatceegdmeHlfocnnuoeag_ottafs^xrumsHsoat,spcHiswr^eoehliSauner^stGso^srseCfpe^iwlow.pveweabdoaecensrotrritlakNfuefaeyion.floldndiryorecumftsdnosauIwiaeotsrsfla^nde^tt^scywtaM^ehfdiasoe^setTiicbrnv^hHhaglpi^esydaeemrsrrctenuaHeeeksatmecforosiortnse.Sprairdiptucetagaittsa,otiintetnloihn^rivinfa.antoseiootgfacelfnma[cftuahHfontpsiemeJetccljales5opiycaetaoBnkdonnssfamsfBecrtotooanmynijermtnxS.paottoscL5tustihtfppr*auohehbrjndatooeSohitfarpereEoesasoonstSthrtoaf^eteBanriinnsyo_H|dtt^naaonxmHfoaogTfalrBhevotenetfmjilercirotaaashAlltteelalonfac dccooemtnetpcaotiInintoenntstrhsafocoiuenrldtetahrmbfeeoeurGnneCotdsteddoseiftegtrhntmhaieftiinccatahtineootnlsytranir^deaartdtsemp^cpotdosuctnto dusei entelerigctro^j|nwT_ac_sha_epfso,,etuunred to pwcicGinnrooieotnnndhaFsceuntieracganaeniuttnsditrroeadislnttuueie1omsevontnefprtrieoaaITrnfnllaef*ts^iuhwtt^Qhry^eeoAg^^rite^a^kImHnn^HioCden^sMv^opac,ihfntiaerSsalratieeabcvsrndroaiaapt*in-ftlocif.Tro.eudlenonsoiswitlftorumantrattiahaitoomnletnieinmofsotsoe.tilpodtfshetedtp(rhmreIeorHsdaaCsuttoeoecM!rue.Hira^ca|le^eTp^khiisnce^cootHwevgndnaiecupneaeosenicrrrrteharbiateosetgmrideonmannetaieixtcreaadatlelyd aattmosWptehmiethrpeetrhoaeftum5re0amtoefgr/ioa1^l0op.laced ih a daasifnfoiutbrsotiaogiennnedtuf.lboewT(h1ois0f vmILmal/umIe.iDnw.utaexs da1e3t0teernsmatninleodng) - 2 - company Sanitbad. Dons no! contain TSCA CS aaAirr2tfninrael3moldMltomaiCtewoht2i.)ilsea..Clv5ebhero1Tle-eHmAfhNChmgiieMsur1/emexl:m.a5sfpssoloio,uodnusrwieru1rtecdyMr:e1esropa0w(dRltce,eieeHocmlisa)gntnHihicvdwotCteefeSn1(llr-Atoyte2:rh20sE,ae01msLti)ooad,TtO:|:nntojhfmiitetlhoootuoseherbsfteipitodjAvha^naEei^^wl^Lruea^n,^ieiHtohsragSnmHedfamcnmnfotearoarsreorenslaemietsdtoaf-phlhriioolertawunhwrltdefcaem5osddt0tnheou2ictefwseefetRruinwAdsHttshEiricoatLaooeatr,tniiorrrf8thneei0tvugeTissnbepuDeoReltHalufchowtteecP1(iivaa0othtett,nhiltoey5n,.1s. vaps5itt2IIsoiroPmne5moalAmrauppicmtumlniihereyLnnloeenaagsupacttiietemaseihtyrnn.sr.lpdeaalMiceaaneaTnoA6rtlgtcnad0vhheoto-5eoerLeahsstdfrhemlioieaeoEcgtlqhsaofivumrefsn(aolaiI1noolnPmstfuuewaALicnpamrwt)tt/lthsesmoeiapoedtsafliwnoenntcaIi.deufhmna-rif^trkereeltpeERsm.JeidcaWue!ne'olc^r^cagmitVhsioemoReepvca^cIsapeowPpwdo.rrinAoeeynnhaddrtgtieisisTelzenroetxahmarounvelsptuedi.iaaeondatfpriineiritoomrhrfrneooswtiiechzrftranodeewstvdCaisamaedshimmrretiwpaynoboipwesnturriaasanegnnomtltegaugtcrpenhpglalrdreascerohasorrursiittcndooeg^otoddhta^nukitinbtoato^oheepifu^ndeltadeic1cndeoIw2mehtn0ieiotn1tpr^iwhm0uemianrLcilmigtttnehhotLeoedrfirneoef foTbcoI1rHhyf0hfoCeEetmMccst!BkheoeRam^tIBhdnstcpeoBo^awa1lmrSunkiii3snLtlotnioho&rt/oaawnmh,rnsaneaisnorrntegsifuvaasswetmeepetniehrteeprewescrleaocaatmdaisfottvionnpoewpeatlcnaxealleiyyslptnzhsrt.euteeaarrddbmtitawemeTtoi4othueohisoenlnnrioftomtdtasuootode,phgfitsfinhar^tncetg5lgrmHct0siehbofrajleevmsfiotnl^eegwfiira/rlmmnytlbihfaJf.po.oresoliovn.uoefmegIrnfHtieydheratClshcsnH-MdeitomHfth^ordpBectraihincftBneofeaugSvcfsae1ooemirPr-unohyrotrnmocaiuoewuinenrcrttahehcsodpactoomddaenel2rbccwi0tteeoehuranredmlsmta.iLrntsiaenattdenaitohddrnet mwavEcltoiapovniacptnnauehdrculiorufmeaxaotanwhiltmdtrsiaroeoataanwpuittierlrraoiceosmnefsrfrsaepiowttnTrmeeeoathdassfeeottrhimncaftvehritaeree5lbBa0inostDfeaalsroemdLntswsh/eipomeffflroerfipi|alnrIftH^tltiuuCdfejtlblMenl.&He^csfah|rjyoonEidsodpfraetcoec8ehcSmrscaotocrlllilhbflvtbnheoyeeerctrnyodpttpuiewloegaaeDanhccsaeoherscofclmooaibrmfeflpe^iyretbnt.i^dhorj^i^a^eanotA^e^^itM^dn^hvutaeirucctepfhureoblouiaArdtmsctissceceexa.os-puatalnmAtctorptoasrwsfilillxfaoei-swcdpeuosreitnd vssaaomcluvpuelmWnintgiptudhmweptsahsoewrspatvstoaipocsupntuaemdrtutebapdnuemdsptowthoeeifrnefs,iatpmitlaahpctrleeeedetsuaienbmaecpshplionwosgfeitrieatohnnedremaathotfevteretmhdreaaalnthddtwreecoseao-phrmpopeutaidron.nipfeoarlindodsd. theThe The Chennai desorptionsaapletubes were analyzed at the Seaford Plant wsaimthplethecuubses wofere analyM ^a^R sfcell Laabosrtaatnodrayrdw.ithThuesesoltvfeBntB desorf pstiaon Company Sanitized. Does notcontain TSCA CM qusttuaeanndfotairrtdabt.iovtheRleympeoedrvtieaadluanardetestuhtlhetsedwatWteajoremwneeortehrmosdauslb.izjeedctetdo atosasmtaptliinsgticraalteaonfaly50sismLto/mindoo15feb0staaombirnApsLotd/ifmlodouniiutnterius-othacenmoaaouplpvralesecaarimnttuydvpbalaeesrnysixdtiun-whbgseoaermsuetirspafiljjeisolnasrgomintphlrtloeeaeartsdevsesoaadltlvsfoeaanrttortaftlhddtoeieewstseoormrfrmapet5itdeni0iousenmmot.L.hmf/eme1thip0no0rudatmecw.Ltie/cmreaSilonlulovltaieemdneatidntds to cIhroesses-ScsthotaecnckdkastrtahdnesdwaprredersepaaoraxftHSio^Hnz^HoHfvs.ftnathnedIPaAnrodwrsm.earel mexecthhoadnguedsedbyatSeeaafcohrdsaitned Htoaskell. dfapfCaoudderhuersssontloooihidcrrrmebbeptreietonionnoawfttnhsrsoyaSrvwwkcaethmeeebrrapgeeserloctiaosnaiscndug,itlsieieMdstcriieeiaalossdilofitcluigryamcgpesetligif,nonoweenvArlrieatni^jhwsSljcbltaoyiemhsglrvaseareeortetanarhejbstcaedintcXeDeotfrrEeleoi.-dssar3ot4viracTc0pashos,tiei,lloaalaennbobdccutihatMtliTneioetTerdtnynheiadn.otwxaodaxotfe-. aawbTdi reBsahbcsoraoaerscubeerhdsneeonestAeosnf^wIfp#eoorT^erorhaelsl e dehsptTshoqoeoheeeslulruvucoirdleetsr.iibTnnteboaihsttrnnareToigtguwhridecpemnasoe.stgiocsnompoolcnvclrneeaepotcncehntneteioftrcondsfdaenit,trcniwiaionte1etarnifsa.no0fctcinieotco.ymovninoLeatifatlnshuotccoetaftytet|:'jexwicsadsthopaisefrtnhteecbadksyTqnsa1euedrfnt0iwddoaa0lxoirrbdmasrsodagawsdlituotfoseihftoftldeeihurorTptneimsretoaonineonactlttuxniohotoanionccfomoleTl^n^HtwaHrtnabadHt^^Hioewtuhinflil,tfnhniiietlhexciIPboeospiAtmronrhaeeplpetsu--ahaeshrsatrdeiesaoddelnfat.os a mdaddisastleseeLlassosnodooaowdrfrerebbappIpdnreiietonndiirsoggtcttihohntteeheessndoaeroetavstflleuugfisanicocettpcoiio.loooivntnerhnndentaenatcmtiietoyns.1esf0to0tithhhs-Tr1omee0hdngaee,jctxiLaocslpOelonCreoc1cmd^a0tf-eiMmfs-ponjltgiHnatL^rrosa^^eaoenta^^ilcfeo^intt-q^nittjhonhuftahSneeooletfftaoTrnathocfehndtoofeiaTuanoxaerrcrn.deeaos/ncxttf1auotT.rnb0vthahdaeietsmeiaroyarcLndncothdosonetofsncantofcenhslendeoudantaeltrtvirsrsaroedooeatcni,rlntoovbitonveee.ondxnefoprtyoTwfreuhfisetthshtheede1.0 GCs7th6oah7islr2suoACmtirhoaeArtnpoousgmot.orraamtpt.oahDgtireecatqpauShiilaipscmppeAoldfenrawthlwyietashsiosaupA*>eferAldaat--iHfnoiegrwioctlhenotenitz-dPaaiattniicaooklnnaysrsddicseaMtneoocdofte^^Hl^f^5oH8^u8^n0DVAa)TGnnaansdAthpeapeMdnedosidxoerlbIinogf 4 - :ompany Sanitized. Does noi contain TSCA CB . nmidIpt(t shbovulthde b-eSSeetnaoftoerdd Chet under Plant were the conditions reported, "finish solvents" found not to interfere with any of the v b M F" in LrAco. mponents when the solvents were present at a concentration Results: [ avtr1hve0eeesrymruL^afLnlZgti*vsroeTIPsor"'Adtrth8ete8ciatrhtoenthrvvpootaterwudhprogyeoodhEruolisvmzceftaehciplbdo9iuirni7naldd*Igitniteoyfltwrmonoserbpr-aeieinnttwwRsgsoeesueeerecrfinstorferiivesicwteawsireeyolorsnwefe.ttirx8tth`hip7faAro*eel2rr,vesi0em.9qrmla*eumgL,naeIptnsatIiPnntiniAdiwgtndaeai1irstnvswi*vic,hdeitoihnucrneehdracesilluccpafdoarieere5tvce-csdetmoitrvgayvf.rneieomlsarmyaoitpmeviswn>tpehglrieef9etahos5rleorl*f. swnthaeimecthepssilnseeIamcFo+tpuny5ibd*netgooiemflrospuastimhadnmoignstephgerleessaplorrwenceaosdyfuliilcslvettecesodtcesfcdrefuorpromframreordabmm.toetehtahoselcumcrdeapdisifinfowguneessriigsoghnastvineclohcasevmsaeclbusaeerrwsryaiotthv5etQrimm(7e^*.m) ^iInbt teowfoarse s(awmoprslTitnhgecaaismned)pianungnedarelyrmstiehstheoodfcaawnidarsibdoifoornunnesdj to lescr ledic.t urrealtae t iavnedlyrephirgohduccoibnlceenftorrations mEodNp5f0urvoeertmachmsaleoioutnLindmaao/sttlmenpiodaiflnnorooauaifrtfndoievssfi.neaaTmgmTaashpbpnellleeaarimnslryetgaus.1lebcseDta"hsAlercbsoleullooutlwragadpdhteateeeitoddna4natoafhrnnaroeednmdthanthSrraoeeeroiremrlmvpasecalleonloizpttnetdaecdDeredasentotsoetirornparaotptiFcitooiscionagnanmussai,rponeMlnassineastgms2hwooprtdilhaisivtnrtuoeeg-unf lgoTr^MahfhsetoeB7rsr. ep,nsptauirnoledtns of theThtrweoe mquetahloidtastifvoer ssatamtepmlinegntsandregaanradliynsgisoovfHejr ^ ^ ^ ^ t s of the comparison 1) rtheesutlhtesrminalredpeosrotrepdt!iovnalu(TeDs )thmaetthaorde, hwiigthheornethaenxcneopmtioinna,l.consistently 2) vthaeluesos lvthenatt adreesolropwtiieornth(SanD)nmometihnoadl. consistently results in reported 3) mtheethopdrefcoisriornepolifcatthiee TDimmpeletholodadisinmgsu.ch poorer than that of the SD taahnteatlhtyweTsohisethmrireesetehsaousndlsot sfmoairlonlefaolwaplrsoes:ast aednitnitsegdtsi coianvleTraantbiamlelye4.s.is AoTsfhuemaseml larreoysf uoftlht setheirnepds oticaratteitdes t ivpceaarlfuloersmafrnocme - 5 - GsnUized. Does not contain TSCACwf Company 1) mltehevethereol)dIss.beatwseetna tithsteicnaolmlyinasligvnaliufiecsanantddtihffeerreenpcoerte(9d5%vacluoensfidferonmceboth 2) elltoehiatvehdereeiln)rgimssb)eetntwahonoededsn.tathttheiestriercepapoolrltryeteddsirgerenssuifulitlcstasnaatt t8d05i%0f%feRrHReHn(cs(eefcior(n9s5dt%aloncadodnitfnhidgire)dncfoer 3) tthhee mTOeamn ebthioads a(anvderiasjge-15r%elafotirveth- edeSvOiamtieotnhofdr.om nominal) is +27% for 4) mtheethomdeaanndco4e2fffiocrienthte oSfOvmaerithaotido.n for replicates is 21% for the TO 5) albt(e+nhi6vdea%es4ol)1b.v%(ie8a)r2Ts.a))hlelaannacddcocewwufraafassidcyssie:iiggnonntf iiffothiifcceaavnnTaOttrlliyymateiwwtohoonorrdsseewwaaasattsbttbehhseeetstooaattthhteethrrthetelweinvoloteewllresmevse(et+lds3lio7aa-(t23ed18i%n2g 6) n(t2ho%es)irgefonlariftiitvchaeenatSDcdcmuifrefatehcjryoedn(c-w1ee1r%einbbteihasest)seaatnvdtahluetheehsigcfhoorelfotfhaideciineognth,t eborufltovatahdreiinaregtisow.nas mc9cos5tofri%anilnitlmteedhourcafeAmitroedtNcndhooIeO.ftnhSsceHtstihaaTsmretocheevirpesseieltevreccstaarhorlliitulnaotetacensaetrtciinieoncfotdonurn.arrthaoticecafoyaScnptictrhsosaeebfnpaoegntaertawdebmxsooaaipfolmrmrrieeet0peys.tls5ashiennaoodmgatdfolspybmalzyi2eeesns.td0hethwoabefdtreioeamsrfstiohertoltosolhsuobeabtlwtdhmeaaeiipnnmbclgeeeoiondnulgewlvneqbtiicrmuytoothaeenfaittdnmihpomopen+danla:2tit5tc.ae%aalrtiifaToolhnris AOcvceurraalcly - + (Absolute Mean M; as + (2 x Mean Coefficient of Variation)] oTfheveaqruiaattiioonn) inocfoarptoersattesmebthoothd. the accuracy (bias) and precision (coefficient mdaNnoIeOethSsoHovdmTecheriereasitltale+tphr2api3ecol%cinccu.arraoititcTfoeyhnr+ie2vor5oae%nlffu.oeotrhevo,iesfrtah+;El6elq9u%atahctecwiorumhnriaalectl.oyd,thethbasueot trfpthottheiroermnthsaoemllevdstehoenolsvdtoerddnpeottiesodosnerpnsmootitroeptnhmtioeomdenteythtihoedelds bi_ur_OeakantEhdxrpoieu5rg0tiimhmmee(nL>st/2sm5f%oiwnr)uittheoe af Mtch^eHr x^soo^lB^vreJcanionttnetoc.deentshtTorehraeptbitoiraoecnnkssustliuetnsbcdetiiasocraneattesousftmahmTmaeptanlraiiuxnznegdacorcaicnetcepustTrasaboblafleet 50, 5. - 6- Compaq Sanitiz tscacb* glTeihvvoeessel otrhefes2ub.l5tessmt Ignd/mdetiecocarttieolontwhlaeitrm, aiw.t sia(thm0.p3llii>tntiggl/ecroamoterpononofenb1t0)re0afomkttLfhfr/l^oHtuafgurhthe.enfopr ressixenht oautrsa csseoucnittcaieobSnnlatemrdapbutlieeroicnnatugsubsaeseassmolwfpolwiuitnhngaas3ca0c2tem.p55gta0Oobimflge/LTcrbe/nrmaoexafikfnftuhlbHtraeocHfukoge^rdhH4hobl cfvHu^ryH^aoH^^wHloefnrigneetorfouathntde nbaoctkutop be swAtthhtaaee0snr.d3ekaa0nnAro4aadwn2l1ydn.0zpseta0trhodec2eccpkuasatrrtroeasapccotHiykoloaurnsottskei.foodelnlutlhvteiasLoelaunntbwetooorwfafrmaoJtsomemtrh0^oH.|a3Hdna2sas3H'k2*aenitlhd`n(l+eiIt7nPor.Aed6pt2ihcro)eea.rctteeeSdiTevnhaeovefdoaseslrudifgreroePnmwsilafuainstlchttase1nw.1aSta5rsee2eaarfwron(o+raidrl1tyh5ziPi2nnel)da. nt emaliscCtmeuntroehavdrbpdnonoeeritiuodrtasclmhsveaineefwrdodiofoniosf.rftgphbr a2iaSk0clI11saPle0eom.j^AA00jll^ijpldnpeawlmmiregncnLgaWeHtgsidTooodJcuMff2n^ohr0eoiofeTdn0rsoieigbuetntfhjmhnaixgeGmeaCafrierwmostbahmwrlaqtontjijch;drhjoaStjnehtrlohweeylaao^bwvsecilbreieriHhesonagt.t^ctoBeofukmorf)DruueenpdtIDrhsPdseoeAessrsotetpooebtrctrhbsyitporitbitoenenetihedognneM.1cso0eooe0pftm2hlSfhvfo5appiwed0siocnekniim-itteenhegnngbqiStncsewauwicmieeeialarpnisxuesblespradeoceiouhftrucnioommobetfshmeeeesnmaanpnstetoeaatshsliotedthe Conclusions; : dmilasaebttoahthoraadActstoomlrftlayheojecroetrexhddpreieseteatrinoirsmmorniteichnnaefatsoltifrold^enatttlhhadeoAl.ffbaleH^arvehijJiaaerHclbsuc^oHaemrtepnioseteaciti^hb|r^alolnbefdtt.ehasdseairtinmoe ptaalhscnsiegseeesprsrteaapbnwdolhrettthhetehrBrmeahsaceilodsdtnooecnrlsuiocstrhaipoeltnion dgcthoeielnnuedAtriiETatoiLhlonenfsosfuimarfcufppestloernrdsargcecfirtrnaiocummasfeeiltedhaluoddhbsyeiga.sahpthmeperepalvdirnosegltuetmocthetiehsoanvdoefeltiegsmoocoltividtoennbpetrleciuacmusisesiideto.nwofaaHsntohdsweueafvcifencirchu, iereuarnencndyt le,tyr but in ebheelow The.^hmal desorption method in general appears to overestimate the aaslsrubroirnngd^ftlnHaZrotnhceenAtErLatisionnost, but this is ekc^eded. a bias on the safe side in terms of The solvent desorption method that was developed in the couss^^f the -- Is recommended for future sampling and analysis of airbornefl&^Eff Hie method Is convenient and easy to use relative to the others and ^^meets the NIOSH criterion for overall accuracy. - 7- goi*Pat^ Sa^v De3 notcontainfSCkCBl References : 1. Unpublished Du Pont Co. data: Pinal AEL L ist, January 26, 1983. 2. oUf.St.heDeNpIaOrStmHeVntaloidf aHtioenaltTh,esEtsd,u"caPtiuobnliacnadtioWneNlfao.re77(N-1I8O5SH()A, p"rDilo,cu1m97e7n)ta.tion Report by: DRaenseiaerlcih. 'CChaespmiist Approved by: 7 ifatnu.*-a ATSne1aBclTMtyriutocinceaMlS.uCpMheeormvnriiossoetrry t DDaJtKe:jtIds:sWuePd;:12.9March_29^1983 Date: There are 24 pages in this report. / 1 a * U Z l . !9f3 -8 Compaq Sanidad. Doe5not contain -jS C A C B t APPENDIX I PROCEDURE PQR USE OF THE SOLVENT DESORPTION METHOD Equipment and Materials Tenax* sample tubes ~ CAF10oav0utaa/ri5l,lo0agPbAmleFg(24wf2r16oi2t-mh)35Sg9-0K4l3aC1s-9sI7n0sc1e-a, leEdigehntyu-s. Personal sampling pump - rceacloimbmraetneddedwfiltohwahrataeccuracy of +5Z at the Isopropyl alcohol (2-propanol)! - AbCeSforCeerutsiefi.ed grade. Check for impurities GC column Gas chromatograph standards - F5F'AxP o1n/8"80s/1ta00inClehsrosrasatseoreblpWaAcWked with 10Z - teeqmuippepreadtuwreithprofglarmame cioanpiazbaitliiotyn detector and Air Sampling alsOarstinhhaaiktdrmoethbeeuepolsrlpylderoiPrnnacorretgblopioeom1etc0prrhobuu0oemicsontnemcoprcadouiLetpeairun/oea.ncmsntnscterlsaua,nRatttruuiioabetoobgefctrenneuoesfriaildsdokto(wcaewfTsurltifaeriht^nolmhcreXBoweapmttlel|ideik.tnppnosneedogansicna+denadfvex5otlpdoZipofsnsiew.fadgocmpvtaerrsFeptoadoirTlotetvwreueiatnasdaotaprietxpdmeiadbesorne.serndiotsoshcan<deamen2lnwe.ap5ophlplbufeesemmmreeagtpdouu/t)mbsnbetl3reitidetoem,oaaarekbaasnitnutdhfsgtcora6a,aomrTtluhtwiapgaebobhlahcriulecnaehrrhgitesse5.isdfttalhomeiwnple Desorption of Samples ! dpaTtweleecnosroaoioxhrTTfdoSeaCnill^Oai^nxmfi^ntiUoatonosaumenseedacpapltoci!a>ohnsrrhneaevanstaekk.tisain2"lgfP.r0aoonobumdrfraLtucttthhhacbeeerpeij'jimvTifertpiio.naa-acnlrxsatpPthd.(r1voue0vri0iagindllgmeas s.ggas) emaPwnniitondploiemelbtumapmc1leuk.c0oghf(a5mtnoh0Linacomaet fl-ghs)sieashsploaefapkcrrhitanoiotogpeunysrosl trtohoef - 9- Compa"/ Sanitized. Does not contain TSCACB Preparation of Standard From thpree|p|_a_re__a__c_o_m_p_o_s opropyi alcohol as mmacfnloaoadmrnsktphhloawsA.nbeicwetnchAltiutdhrdaItaPhntAdriiesse.loyfqprsuiorCwgaolaeneupilrtgtyciiahlutotalinaaatoinltncved"oe.shttlrhoyeocecl,kptrer(adIxTPnaBAascAnf)t.e"cratomoTanodhlculiinesstnsctoosnrlmoaevtlapeiurootnni0toeh.n0net2s'f5csaeatomangcphab(l2eec52ok5amm-nemdpgpL)todnvofieolofnurltueteamsincixehtpotrgi/ctmhLe Prepare dilutions of the stock TBA as follows: 1) Ptoiptehte2m.0armkLwoifthstIoPAck. AfLlapbJenltothais 10s-tmanLdvarodlum"Ae"t.ric flash and dilute 2) tPoiptehte 1m.0armkLwoifthstIoPcAu^^LKaabenltothais 10st-manLdvaordlum"Be"t.ric flash and dilute 3) tPoiptehte0m.5armkLwoifth8ItPoAck.'wLRapb.ealtoth-is 1s0t-amnLdvarodlum"Ce"t.ric flash and dilute 4) Ptoiptehte 1m.0armkLwoifthstIaPnadLardLaAbeilnttohisa s1t0a-mndLarrodlu"mD"e.tric flask and dilute 5) Ptoiptehte0m.8armkLwoifthstIaPnAd.ardLaBbeilnttohisa s1t0a-mndLavrdolu"Em"e.tric flask and dilute fccEooolannlrocceweeTnni2hntte0rrga0aa,ttiifpooap1nncr0sot0oxo, fifrmos5:re0aa,tceeha2cc0hco, oncmaconpemdonpnt8oreann'jtteiignoi/tnnnLsint,hf oesr terassnetpodaeccackhrtdisvcsoteaAmlnypdt.ohanrroedCnutgaslhoicnluuElstaitbtoaeynndmeabxuryadlctstithpeAly itnhgrouthgeh Standard DECAB Factor 000...0125 00..00028 asanmalpylFesseresas. hrelyanparelypzaered. theUssee dstialnt--daiordnss fBrotmhrotuhgehstEocfkor stgaansdacrhdromeaacthogtriampehic - 10 Compaq SanifaecL Doss not contain TSCA CL GC Analysis are asOjfjeorlalcoinrag: conditions for analysis off(fIl isopropyl alcohol Column Oven temperature ' FHFAP* o1n/88'0s/1t0a0lnmlesha Chteroeml apsaocrbk9edVAwUith inr : ' 200Cfr 3 "inUteS th" 15c/ "inute. to Detector temperature - 275C Injector temperature Carrier gas Injection volume Attenuation 1- 275C - Nitrogen at 30 mL/minute ~ 1 Ml* - 16 t"hefirst XsamiprleLto 1minimize the chance ,*.y~ *>*.thela8t*8taiard and cepr" " s. oeasureaencs were found r e 'r e p r o d u c ib le ""d Pe*t height s s s i r & s s - k K - " ssss"ccftoohomerncptseohannme-e-te-rn-att-h.dtiraoetneTahemofofawarjmeouavoercuahccinuohtmc(oocpmfoolmonHoepnBnoetnnsnei^Lnitsr.i s?hAowrne LinLc-aIlFliSpibe*rluratfrtigfio/rooan aSceuDllLlrenvoteeefTMafcro1a"rrleibtghrr=aaehttesisosiaonmncpuolenrves since the desorbing volt ragreacb " "P1 sum the amounts < rcooum*nbwdilnieiSdnKHotrtnheoesuolfnotrbsotb,naotitnhsiefttchhtteeiheoftnroaotmfnaootlurd^AJtaamndoyufnb^taeofkVMWUrMaf?ne"*no*ff r ------ - 8Teecntalxona1n8d report the >25* of that is an indication of breakthrough. Ponent, report this also since this on the 8aa^ ^ C o g r i j r i n d dr tp ^ nt<h.<insaevaiilui e CaMsar mmiinnim^umf dJ eBteacCthiocnoalPimneint.t 11 com p ly TSC^CBl DJK:j td:WP: 12.9 Oste: f U U 7?, U f i 12 - Company Sanitized. Doss noi contain TSCA CB| MDeetshoordptioofn TShoelvrmenatl TShoelvrmenatl TSohelvrmenatl R_ esu.lts o; : f~IMTM_^THaLbJl^oe-a--1d--l-n-g of 1-12-83 NL(ooMamdgi)innagl RV(eMpaloiu)reted Bias oCfoeVfafirciaietinotn 6600 5685.6 ++;: 321.0 +-17322 42722 3300 3278..05 ++' 02..80 +-120822 3522 1155 1127..92 ++;: 41..18 +-114522 28922 NSuammbeprleosf 23 23 32 I' Table 2 Results b f | n (Loading of 1-18-83 MDeetshoordptioofn NL(oopamgdi)innagl RV(efpiaglou)reted Bias oCfoeVffairciaietinotn TShoelvrmenatl 6600 " 5653.4 ++40.4 -1+1822 37122 TShoelvrmenatl TShoelvrmenatl 3300 2349..56 --++i 20..09 +-138222 1155 1181..96 i+: 20..11 +-221422 4522 11122 NSuammbeprleosf 23 23 32 - 13 Does not contain TSCA CBJ Company. Sanitised. MDeetshoordptioofn TShoelvrmenatl TSohelvrmenatl TShoelvrmenatl Table 3 Resulta of] ading of 2-4-83 LN(oopamgdi)innagl 6600 15151.4RV(e++p1pai1glou1)r1e1te.5d BiaS +-1942%2 oCfoeVfafirciaietinotn 13022 3300 2455..50 + +i 31..10 +-155022 4722 1155 1122..30 ++; 01..34 --128022 12222 NSuammbeprleos f 23 32 32 MDeetshoordptioofn TShoelvrmenatl TShoelvrmenatl TShoelvrmenatl TShoelvrmenatl Table * Summary of Results fo ri adlngs NL(oopamgdi)innagl FrDoAmevveiNaraqtigmoeninal Bias DRSteeavpnildaiactiraodtne VCaoroeiffaftiicoinent NSuammbeprleosf 6600 +-262.f.i5i +-131822 214..115 22922 79 3300 +-141.4.0; +-135722 21..0400 4622 79 1155 +-20..977 -1+8622 03..5175 25022 97 OOvveerraallll --; +-125722 -- 24122 2217 - 14 ornpsn}' Sanitised. Does not contain TSCA CBJ w F(mloLw/mRinatuete) (Thinrse) Table 5 tgling with 100/50 mg Tenax Tubes (Vliotleumrse) Air C(mogn/mceJn)trations Appr(onxgi/mma3te) MDL* 50 642 11826 sSS SSS SSS 011...573 100 150 42 6 231642 42 6 531468 sss BTSS BBTTs B3TTs BBTTS BBTTS 000...473t 0.5 *BSMTDL m<ii.nnin8ddimiijcciugaam/ttceeosdsmepusteoancntatiecisncoftenapcotnltaiobmrtlhyeiet bpGperCeerfarokrctmhomraonpucogenhent in a ir_, with an MDL of ^^S^mg/m ^011 lim lt per coponent a ssu m ln g f^.s present at 15 ,d.T>069 noico^a'inTS' a*****1 tti* Jo mg S 'mg n i3 A i - my mi F igure 1 . Schem atic R ep resen tation o f ttni e. IdHCnMoesnoUon^.nT, ScCrk^CBi - 16- Qgnipany. S a n tt^ - 20 measured amount (jug) Figure 2 measured AMOUNT (JJG) Figure 3 n3> M<aaD. atvo> 3a oo3 a3. (a>oft S %^ Figure 4 \) Figure 5 RESULT VS DAY (15 UG)26.00 T T T T pr-n--;H n j T T T > I i r - n - T - , i i . , 24.00 22.00 20.00 18.001. 18.001. 0 0 0 0 0 +25% RESULT iOl ' I<?/ :l\S91o\o0\-vV\o3>oo \s \a> \S -i 14 .0 0 1 12.00 10.00 8.00 8.00 Q -e- 4.00 u .u u i --L _ i _ _ L l _ J 0 .5 0 l i | i i i i 1 . ~f--J--1_1_L 1.0 0 1 .5 0 3.00 P 2 .5 0 DAY -- MalnollB.DAT Plui26.DAT -------InwSB.MT Q 0 MlvwtIB.Mr n u i AV 0 thrallfi.lUT H0 -25% 0 1L 1I 11 1 3 .0 0 3 .5 0 RESULTmVOSlU!BfU0s lu SsoQ 'P32.IUBS uediuoQ -TZ- RESULT VS DAY (30 JUG) Figure 7 130.00- ...1..1..i..1..1 ' " HRE1 SUI LI TI VS I DAY q -n I (60 i Ii JUG) 1 . 1-^- 1 n i j <i i r 120.00 110.00 100.00 o 0 8 0 .0 0 L ................................................................................................O 1J &/uCVO4 80.00 70 .0 0 +25% Company Sanitized. Does not contain TSCA CB! Rn ointtims.ltouor. iu t 2.00 2.50 3.00 3.50 4.00 DAY Q------- HUUaSoL2V6.BDfAraTo.DAT 0 0 nauiMMj *T - 0.23 CH-HU HTi INTO * OFF MUII ViUOh iHPwt INJECTION * 02 50 F6 3 i*S3 SAMPLE 4 i 0 CODE 31 E m 9.00 S 0 .00 S? 0 .0 0 1 a. o.oo 3.ti*t0 a0 o.:o ,<Dw 0.31 .0 83 :? 3,<*/> ,;O0> F.SEft TYPE 57n HfclChT 54.70W48...02430 SThArSeCsLhohEld9STsAtaRrTtUrNun** PEAK WIDTH a START RUN 8SV8S RF.TTi000 ...11iI|*r30N*>8TTO*6 OFF 0:1 v1 aS4 ...03n33 i nj fi 00 oo BASELINE 3 .*9 .12 Aftfi V *W**0*9l 7.4 437S..223354 14.482 o H> I i CONCENTRATION (JOG/ML) 1V <I o 8 *Uc V Company Sanitized. Does not contain TSCA CS i