Document O3Kbo4nxGvMQrVY7bEvYvgRdM

PI 125 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE MAI- TO: 45000382 CONOCO INC REFINING P O BOX 37 WESTLAKE LA 70669 P 1 REVISION OF:06-01-90 GS192 ORDER NO: 451503789 PROD NO: 04310054 VAN WATERS 4-. ROGERS INC. SUBSIDIARY OF UNIVAR 1600 NORTON BLDG. SEATTLE* WA 98104-1564 (408> 435-8700 ---------------------------------------- ------------ EMERGENCY ASSISTANCE---------------------------------------------------------- FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC (800)424-9300 ------------------------------------------ FOR PRODUCT AND SALES INFORMATION----------------------------------------- CONTACT YOUR LOCAL VAN WATERS *. ROGERS BRANCH OFFICE -------------------------------------------------- PRODUCT IDENTIFICATION-------------------------------------------------------- PRODUCT NAME: HYDROCHLQRIC ACID COMMON NAMES/SYNONYMS: HYDROCHLORIC ACID; MURIATIC ACID; HYDROCHLORIC ACID 10 BE; HYDROCHLORIC ACID 9Xi HYDROCHLORIC ACID 12X CAS NO. : 7647-01-0 VW5-.R CODE: PI 125 FORMULA: H CL HAZARD RATING (NFPA 49) HEAL7*-;: 3 FIRE: 0 REACTIVITY. 0 SPECIAL: NONE DATE ISSUEO: 04/90 SUPERCEDES: 03/90 HAZARD RATING SCALE: 0=MINIMAL 3=SERIOUS 1"SLIGHT 4"SEVERE 2-MODERATE -HAZARDOUS INGREDIENTS- COMPONENT CAS NO. ppm OSHA ACGIH OTHER X PEL TLV LIMIT HAZARD HYDROCHLORIC ACID 7647-01-0 9-37 5 5 CEILING CEILING WATER 7732-1G-5 BALANCE NONE NONE -----------------------------------------------------PHYSICAL PROPERTIES"----- NONE NONE CORROSIVE NONE BOILING POINT* DEG F: 150 - 230 VAPOR PRESSURE. MM HO/20 DEG C: 30 AT 77 DEG F MELTING POINT, DEG F: N/A VAPOR DENSITY <AIR*1); N/A SPECIFIC GRAVITY (WATER1): A*1.14; B"1.16; WATER SOLUBILITY, X: C=l. 16; D=t. 07 APPEARANCE AND ODOR: CLEAR. EVAPORATION RATE (BUTYL ACETATE=1) : N/A COLORLESS TO PALE YELLOW WITH PUNGENT, IRRITATING ODOR (A=t8 DEG BE HYDROCHLORIC ACID* B"20 DEG BE HYDROCHLORIC ACID* C =22 DEG BE HYDROCHLORIC ACID, D=10 DEG BE HYDROCHLORIC ACID) FIRST AID MEASURES* IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. PROD: 04310054 03:06:00 27 JUN 1990 COST: 45000382 INVOICE: 451503709 SAL 000009400 ph25 g g 1 92 MATER IAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE PG 2 REVISION OF:06-01-90 IN CASE OF EYE CONTACT IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 30 MINUTES. ' LIFTING THE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. IN CASE OF SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH LOTS OF RUNNING WATER FOR 30 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES; WASH BEFORE REUSE. GET IMMEDIATE MEDICAL ATTENTION. IF SWALLDWED: DO NOT INDUCE VOMITING. IF CONSCIOUS/ GIVE LOTS OF WATER. GET IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCCNSCIQUS OR CONVULSING PERSON. ------------------------------------------------- HEALTH HAZARD INFORMATION------------------------------------------------- PRIMARY POUTES OF EXPOSURE: SKIN OR EYE CONTACT/ INHALATION. SIGNS AND SYMPTOMS OF EXPOSURE INHALATION: VAPORS AND MISTS ARE EXTREMELY CORROSIVE TO THE NOSE/ THROAT, AND MUCOUS MEMBRANES. BRONCHITIS, PULMONARY EDEMA. AND CHEMICAL PNEUMONITIS MAY OCCUR. IRRITATION, COUGHING, CHEST PAIN, AND DIFFICULTY IN EREATHING MAY OCCUR WITH BRIEF EXPOSURE WHILE PROLONGED EXPOSURE MAY RESULT IN MORE SEVERE IRRITATION AND TISSUE DAMAGE. BREATH TNG HIGH CONCENTRATIONS MAY RESULT IN DEATH. EYE CONTACT: VAPORS. LIQUID. AND MISTS ARE EXTREMELY CORROSIVE TO THE EYES. BRIEF CONTACT OF THE VAPORS WILL BE SEVERELY IRRITATING. BRIEF CONTACT OF THE LIQUID OR MISTS WILL SEVERELY DAMAGE THE EYES AND PROLONGED CONTACT MAY CAUSE PERMANENT EYE INJURY WHICH MAY BE FOLLOWED BY BLINDNESS. SKIN CONTACT: VAPORS, MISTS, AND LIQUID ARE EXTREMELY CORROSIVE TO THE SKIN. VAPORS WILL SEVERELY IRRITATE THE SKIN AND LIQUID AND MISTS WILL SEVERELY BURN THE SKIN. PROLONGED LIQUID CONTACT WILL BURN OR DESTROY SURROUNDING TISSUE AND DEATH MAY ACCOMPANY BURNS WHICH EX TEND OVER LARGE PORTIONS OF THE BODY. SWALLOWED: VAPORS, MISTS, AND LIQUID ARE EXTREMELY CORROSIVE TO THE MOUTH AND THROAT. SWALLOWING THE LIQUID BURNS THE TISSUES, CAUSES SEVERE ABDOMINAL PAIN, NAUSEA, VOMITING, AND COLLAPSE. SWALLOWING LARGE QUANTITIES CAN CAUSE DEATH. CHRONIC EFFECTS OF EXPOSURE: MAY RESULT IN AREAS OF DESTRUCTION OF SKIN TISSUE OR PRIMARY IRRITANT DERMATITIS. SIMILARLY, INHALATION OF VAPORS OR MISTS MAY CAUSE VARYING DEGREES OF DAMAGE TO THE AFFECTED TISSUES AND ALSO INCREASING SUSCEPTIBILITY TO RESPIRATORY ILLNESS. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE REPORTED. TOXICITY DATA ORAL: RABBIT LD50 * 900 MG/KG DERMAL. NO DATA FOUND INHALATION: RAT LC50 - 3.124 PPM/1HR CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM, THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER DATA: NONE PERSONAL PROTECTION SAL 000009401 VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE QF MAIN TAINING EMISSIONS AT THE POINT QF USE BELOW THE PEL. RESPIRATORY PROTECTION: WEAR A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION AT THE POINT OF USE APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CART RIDGE PESPIRATQR EQUIPPED FOR ACID GASES/MISTS, A SELF-CONTAINED PROD: 04310034 03:06:00 27 JUN 1990 CUST: 43000382 INVOICE: 431503709 I PI 125 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 EE PC 3 REVISION OF: 06-01-90 I BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR fi fi 1 } respirattf. o^ + j EYE PROTECTION: CHEMICAL GOGGLES AND FULL FACESHIELD UNLESS A FULL FACEPIECE RESPIRATOR IS ALSO WORN. IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE , CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. PROTECTIVE CLOTHING: ACID-RESISTANT SLICKER SUIT WITH RUBBER APRON* RUBBER BOOTS WITH PANTS OUTSIDE, AND RUBBER GLOVES WITH GAUNTLETS. OTHER PROTECTIVE MEASURES: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. ------------------------------------------ FIRE AND EXPLOSION INFORMATION------------------------------------------------ FLASH POINT, DEG F: NONE FLAMMABLE LIMITS IN AIR. X METHEO USED: N/A LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: USE WATER SPRAY. DRY CHEMICAL OR C02. SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR SELFCONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTINGUISH ALL NEARBY SOURCES OF IGNITION SINCE FLAMMABLE HYDROGEN GAS WILL BE LIBERATED FROM CONTACT WITH SOME METALS. ---------------------------------------------------- HAZARDOUS REACTIVITY---------------------------------------------------------- STABILITY. STABLE CONDITIONS TO AVOID: NONE POLYMERIZATION: WILL NOT OCCUR MATERIALS TO AVOID: ALKALIS, OXIDIZING OR REDUCING MATERIALS* CYANIDES* SULFIDES. OR COMBUSTIBLE MATERIALS. KEEP AWAY FROM FORMALDEHYDE SINCE THERE ARE REPORTS THAT BIS-CHLORQMETHYL ETHER, A POTENTIAL CARCINOGEN* MAY BE FOPMED. ALSO KEEP AWAY FROM AMINES, VINYL ACETATE* PROPYLENE OXIDE, BETA-PROPIOLACTONE, AND METAL OXIDES. HAZARDOUS DECOMPOSITION PRODUCTS: MAY LIBERATE HYDROGEN CHLORIDE. ----------------------------------- SPILL, LEAK, AND DISPOSAL PROCEDURES----------------------------------------- ACTION TO TAKE FOR SPILLS OR LEAKS: WEAR ACID-RESISTANT SLICKER SUIT AND COMPLETE PROTECTIVE EQUIPMENT INCLUDING RUBBER GLOVES, RUBBER BOOTS. AND A SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE OR A SUPPLIED-AIR RESPIRATOR. IF THE SPILL OR LEAK IS SMALL. A FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ACID GASES MAY BE SATISFACTORY. IN ANY EVENT. ALWAYS WEAR EYE PROTECTION. FOR SMALL SPILLS OR DRIPS, MOP OR WIPE UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, CONTAIN BY DIKING WITH SOIL OR OTHER NON COMBUSTIBLE ABSORBENT MATERIAL AND CAREFULLY NEUTRALIZE WITH SODA ASH OR LIME. IF SODA ASH IS USED, PROVIDE ADEQUATE VENTILATION TO DISSIPATE THE CARBON DIOXIDE GAS. KEEP NON- NEUTRAL I ZED MATERIAL OUT OF SEWERS* STORK DRAINS, SURFACE WATERS. AND SOIL. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING. AND HANDLING AND DISPOSAL OF WASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL, j CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ( ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TQ PROPER WASTE DISPOSAL, AS ABOVE. ---------------------------------------------------- SPECIAL PRECAUTIONS------------------------------------------------------------ STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL. DRY, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE DO NOT USE PRESSURE TO EMPTY CONTAINER. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. PROD: 04310054 03:06:00 27 JUN 1990 CUST: 45000382 INVOICE: 451303789 SAL 000009402 I PI 125 g, g 1 9 2 MATERIAL SAFETY DATA SHEET ! HYDROCHLORIC ACID 22 BE PC 4 REVISION OF:06-01-90 I REPAIR AND MAINTENANCE PRECAUTIONS. DO NOT CUT, GRIND, WELD, OR DRILL ON OR NEAR THIS CONTAINER. OTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RES IDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. ----------------------------------------------FOR ADDITIONAL INFORMATION---------------------------------------------------- CONTACT USDS COORDINATOR, VAN WATERS *. ROGERS INC. DURING BUSINESS HOURS, PACIFIC TIME (408 >435-8700 --------------------------------------- OTHER REGULATORY INFORMATION---------------------------------------------------- THE COMPONENTS OF THTS PRODUCT ARE ON THE TSCA INVENTORY OF CHEMICAL SUBSTANCES. DO NOT DETACH THIS SECTION FROM THE MSDS AND BE SURE TO INCLUDE THIS SECTION WHEN COPYING THE MSDS. THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR IZAT ION ACT OF 1986 AND 40 CFR PART 372: NAME CAS NQ. X, WT. HYDROCHLORIC ACID 7647-01-0 9-37 UNDER MASSACHUSETTES RIGHT-TG-K.NCW LAW. HAZARDOUS SUBSTANCE AND EXTRA ORDINARILY HAZARDOUS SUBSTANCES COMPONENTS PRESENT IN THIS PRODUCT WHICH REQUIRES REPORTING ARE: EXTRAORDINARILY HAZARDOUS SUBSTANCES CHEMICAL CAS NO. CONCENTRATION 0.0001%) HYDROCHLORIC ACID 7647-01-0 9-37 UNDER THE PENNSYLVANIA RIGHT-TO--KNOW LAW, HAZARDOUS SUBSTANCES AND SPECIAL HAZARDOUS SUBSTANCES COMPONENTS PRESENT IN THIS PRODUCT WHICH REQUIRE REPORTING ARE: HAZARDOUS SUBSTANCES CHEMICAL CAS NO. CONCENTRATION (> 1%) HYDROCHLORIC ACID 7647-01-0 9-37 CALIFORNIA SCAGMD: NONE --------------------------------------------------------------NOTICE------------------------------------------------------------------------------ VAN WATERS ROGERS INC. ("VWkR'`> EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRENTreS OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN.** ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA TION IS BELIEVED TO BE ACCURATE, VW&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VW&R'S CON1 TROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER ' THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICA TION OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOGS NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS. --------------------------------------------------------- REVISION----------------------------*-------------------------------- 04/90: ADDED SYNONYM, COMPONENT < CAS NO. >. SAL 0009403 PROD: 04310054 03:06:00 27 JUN 1990 CUST: 45000382 INVOICE: 4515037S9 PI 125 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE rU?sk$& PG 5 06--01--90 **** END OF MSDS **** PROD: 04310054 03:06:00 27 JUN 1990 COST. 45000382 INVOICE: 451503789 SAL 000009404