Document O3JKZRvaX3ZB0nNEQqNVNRJrQ
:
Fett pRanco 166
OHIO RIVER WATER SAMPLING
.| RESULTS DUPONT WASHINGTON WORKS FACILITY AND THE LETART LANDFILL
Date: November 2002
Project No.:
DEWW7423 18983635.14000
18983632.00021
am
CORPORATE REMEDIATION GROUP An Alliance between
DuPont and URS Diamond
Barley Mill Plaza, Building 27 Wilmington, Delaware 19805
CONTAIN NO CBI
000028
`SRAT Ono Ruer Wate Samping Results
Table of Contents
TABLE OF CONTENTS
J S----
m--_
20 C-8 Analyses and Analytical REDOING .vrsnsnn 3
3.0 Ohio River Water C-8 Results Near The Washington Works Facility .......3
:
4.0 Ohio River Water C-8 Results Near the Letart Landfills]
5.0 OhioRiver Parameters...
sr----
nll
6.0 RESETENCEScorres
----
Table |
Table 2
Table 3 Table 4
TABLES
.
Ohio River Water Sampling Plan, DuPont Washington Works Facility, and Letart Landfill GPS Coordinates and Field Parameters for Ohio River Water, DuPont Washington Works
Outfall 005 C-8 Results
Ohio River Parameters
Figure IA FigurelB
FIGURES Ohio River Water Sampling Locations - Upstream, DuPont Washington Works Facility Ohio River Water Sampling Locations - Downstream, DuPont Washington Works Facility
#
Figure2 Ohio River Water Sampling Locations, Letart Landfill Site:
Appendix A Appendix B
APPENDICES Ohio River Stage Data from USGS Gaging Station 03150800, Ohio River near Marietta, Ohio Local Climatological Data from NOAA for June, July and October 2002
A Teresdaoc Nov. 19.02 i
`Wimingten, OE.
000029
DRAFT Ono Rover Wate Samping Results
Introduction
1.0 INTRODUCTION
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..
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* .
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Local, Letart, and Dry Run Landfils
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below:
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ounpes-tmrielaem raanddiu1s0fmriolmesthdeofwancsiltirtyeaamnodfthtehelafnadcfiilliltsyaanldonpgubtlhiecOwhaitoerRisvueprp.lies
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rFeascuilltistyf/oLrotchael tLwaond-fmiilllearnaddifuosrspuurbvleiyc awartoeurndsutphpeliWeasshalionnggtotnheWOohrikosRiver are
pcroemspelnettede.d, Aantdwao-rmeipolretsduorcvueymeinntWiansghtihnegsteoanctCioviutnietsyiOs hiinoprheapsarraetcieonnt.lyQbueaertnerly
monitoring of C-8 at three public water supplies (Tuppers Plains, Lubeck, and
2 Q LTiattslke BH:ocAksisnegs)simseonntgooifnEgx.isting Groundwater and Surface Water Monitoring
Data -this task comprises three subtasks:
Compile historical C-8 data. Sample monitoring wells and outfalls a
the
facility and associated
landfills.
Develop a Groundwater Monitoring Plan for the facility.
"STuhbetafisrkst2anisdatnhiorndgsouibntgastkasskwecornedcuocmtpeldemtoendtahnldysfuobrmrietqtueidretdo tshuerfGaIceS-Twaftoerrrevierw. SSaammpplliinngg ppooiinnttss.anSdamqpularitnegrlryesfuolrtsgarroeunsduwbamtiettreadnmdofnotrhnloyn-arnedq/ourirqeudasrutrefrlaycetowtahteer GIST. J aWirgteonn,ad0os2c Nov 19.02 200-- 030 1
CRAFT Ono Rete Saping Ress
Introduction
Q eTvaaslkuaCt:inPgltuhemeverItdiecnatliafnidcahtoriiozno/nGtraoluenxdtweanttoefrCA-s8seismspmaecntted-- gthriosutnadswkatinecrluadneds
sLpaencdiffiilclalalnydiintcsliumdepsacatnoansstehsesOmheinot oRfivCe-r8ainmdppaucbtleidc gwraotuenrdswuaptpelrieast atlhoenLgettahret
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the all monitoring wells was recently completed, and C-8 analysis is underway.
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:
is impacting the Water Sampling
Ohio River. Proposal for
DuPont agreed with this request and the Ohio the Washington Works facility and the Letart
River
sLaunbdsfeiqlulewntalsysaupbpmriotvteedd binyFtehberGuIaSrTy.20S0h2orttoltyhaefGeIrSaTp.prTovhails,ptrhoepoOshailowas
Environmental Protection Agency recommended slight modifications.
(Ohio EPA) reviewed the proposal and DuPont agreed to change the proposal
as
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This report presents the resultsofthe Ohio River water sampling and is organized in the
following manner:
Q Section 2 provides information on C- analyses and analytical reporting.
Q Saedcjtaiceonnt3topraensdendtoswtnhsetOrheiaomRoifvtehrewWaatsehriCn-g8torensuWlotrs kfsorFlaoccilaittiyo.ns upstream,
Q Section 4 provides the Ohio River water C- results for locations sampled
adjacent to Letart Landfill
Q Section 5 presents the Ohio River parameters.
Q Section 6 provides references.
@i
J Wriemroegsiuotns.dOoFc Nov. 18.02 000031 7
SRAFY OH; River isis Suonjing Sei
C-8 Analyses and Analytical Reporting
2.0 C-8 ANALYSES AND ANALYTICAL REPORTING
`The Quality Assurance Project Plan (QAPP; DuPont, 2002) discusses the procedures
and protocols developed to ensure that project information, data, and decisions derived.
from or based on data acquired during the C-8 investigation at Washington Works
Facility and associated landfills are technically sound, usable, and properly documented.
`The QAPP was submitted to the GIST in January 2002. Specifically, Sections 5, 6, and
10 present sampling protocols, sample and document custody procedures, and intemal
.
quality control checks that were followed during the field sampling activites associated
with the groundwater well and water-use survey.
`The QAPP also presents information on quality assurance, calibration procedures and frequency, analytical procedures, data reduction, verification, and reporting. Information on the analytical method and the precision criteria used for the C-8 reporting are. `summarized below.
In October 2001, Exygen Research, Inc. (Exygen), located in State College, ChPreonmnsaytlovganriaap,hdye/vTealnopdeedmaMnadstsesStpedecatrnoemwetarnyal(ytLiCc/alMSm/eMtSh)o.d tDhautPuotnitlizaedsopLtieqduitdhis
`method (LC/MS/MS) for analyzing C-8 in water in November 2001. Currently, Exygen performs all C-8 water sample analyses for DuPont.
Exygen reports C-8 results for the laboratory replicate ofeach field sample. These results are evaluated for precision by comparing the field sample result to the corresponding laboratory replicate result:
Q Ifboth results are less than the practical quantitation limit (PQLY), the replicate sample for that analyte is considered to have passed the precision criteria.
Q Ifone or both results are between one and five times the PQL, the replicate is considered to have me the precision criteria if the two results differ by less than the PQL.
Q Ifone results less than the PQL and the other is not andifthe two results differed by a value less than the PQL, the replicate is said to have met the acceptance criteria
i
Q
Ifboth results are at least five
met the criteriaifthe relative
times the PQL, the replicate is considered
percent difference (RPD) between the two
to have
results is
less than or equal to 20%. The RPD is the absolute valueofthe differenceoftwo
measurements divided by their average.
`When the precision criteria outlined above are met, Exygen reports the averageof the field sample and the laboratory replicate results reported. If criteria for precision are eFixncaeleldye,dw,hEexnyogneen rreespuolrtts(ftrhoemhtihgehesraomfptlheelasbaomrpalteoraynrdepllaibcoartaetopariyr)reipsliacbaoteveretsuhletsP.QL and one below, the result that is above the PQL is reported. C-S results are recorded in the Corporate Environmental Database (CED) and are reported as FC-143 for consistency with historical results.
TWimengrioen, dOoFr No 9.02
000032 3
_DRAFT OtoRiverWate Samping Resuts
C-8 Analyses and Analytical Reporting
An MS
aliquotofeach field analysis are used to
sample i also analyzed as assess accuracy. The MS
a matrix recovery
spike value
(MS). Results of must fall between
the 70
to
m13a0x%i,muunmleasmsotuhnetsaumspeldetocosnpcieknetrfaietlidosnaimspaltelseaisst
four times 500 ug/L.
the
amount
spiked.
The
AllalbodraattaorpyacSktaangdeasrgdenOepreartaetdinbgyPErxoycegdeunreasre(rSeOvPi)ewaendd idna-thaouussaebifloirtyc,omuspilnigantcheecwhietchkltihset
pErxoyvgiednedhainvethbeeQenAPgPen.erRaetseudltisn ocofmtphleiiann-cheouwsiethretvhieelwabionrdiactaotrey tShOaPt,dawtiatrhefpoerwteedxcbeyptions
as noted in the individual review summaries. All data reported by Exygen have been
:
judged usable for the purposesofthe project.
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Rdaetsaulitssoacfctehpteabalddeiatinodnaqluaqluiafliictaytiaosnsoufratnhceedraetaviweawsalnsoot
indicated that warranted.
the
qualityof
the
000033
J "Wimringeiosn.dtOoFc Now 18.62 3
. GRAFT Of RiverWate Samping Results
Ohio River Water C-8 Results Near the Washington Works Facility
3.0 OHIO RIVER WATER C-8 RESULTS NEAR THE WASHINGTON WORKS FACILITY
Near the the Ohio
facility, Ohio River water was sampled River. The sampling investigation was
to measure the concentrations of C-8 in designed to meet three main objectives
Q Characterize background C-8 concentrations in river-water upstreamofthe
facility.
:
Q Assess C-8 concentrations in river-water along the facility reach.
Q Evaluate C- concentrations in river-water downstreamofthe facility.
fOahciiloitRyiwvaers wsaatmeprluepdsdturreianmgoftthihs einfvaecsitliigtayt,iaonl.ongInthteotfaalc,il4i9tyr,iavnerd-dwaotwenrsstarmepalmeosf twehree
collected, including river-water samples
two duplicate samples. were collected along a
At selected sampling single transect across
areas, as many the river and as
as three many as
athnraeleyzdeedptfhosr wCe-r8eisnaamcpcloerdda(ndciep,wmiitdh-tchoeluSmtnan,daanrdd Oboptetroamt)i.ngAPlrlorcievdeurr-ewaatpeprrsoavmepdlebsywtehere
GIST and the Quality Assurance Project Plan (DuPont, 20026).
wDuarsianlgsothseasmapmleedttiomeevpaelruiaotdetdhiastptehresiroinvedro-wwnastetrrewaams osfamtphleeodu,tfaelflf.lueHnitstforriocmalOluyt,faOlultf0a0l5l
e0f0f5luheanst csohmopwanrtehdethoigthheesottchoenrcoeunttfraaltlisoannsodfouCt-le8tsanatdtdhiesWchaasrhgiendgatolnarWgeorrvkoslFuamcieliotfy.
However, the C- concentration at Outfall 2002 following the installationof a carbon
005 has been steadily adsorption treatment
decreasing in system in the
2001
and
flouropolymers process.
Table 1 summarizes the Ohio River Water Sampling Plan including
QA descriptionofthe sampling transect locations on the river
Q The numberof sampling points along each transect
Q The sample type, dip (surface), mid-column and/or bottom collected at each
sampling point
%
In addition, for each sample collected, the following information is provided:
Q The transect number
Q The location of the individual sample along the transect (WV-side, center, or OH-
side)
Q The typeof sample (dip, mid-column, or bottom)
Q The sample identification
Q The C-8 result (in ug/L)
Q The date of sampling
000034
E eratEerdEo-- c Nov-- 15.02------------------------ree5 Winngion, 08
ORAFT Ono ReWater Samping Results
Ohio River WWaatsehrinCg-t8oRnesWuolrtkssNeFaacriltihtey
Ftirganusreecst 1loAcaatniodn,BaprseusmenmtarthyetOahblieooRfiCve-r8 wraetsuelrt-ssaismsphloiwnng.reTsaubltlseg2rapprhoivcaildleys. thAetGelaocbhal P`moosniittioorneidngdSuryisntgemco(llGePcSt)iocnooofrdeiancahtessaomfpleeac(htesmapmepraltiunrge,lopcHa,tiaonndansdpetcihfeicficeoldndpuacrtaamnectee)r.s Table 3 provides the C-8 results for Outfall 005.
#
000035
e eresas dos Nov. 18.02 e5 Wimingion 02
DRAFT Ono River Water Samping Results.
-_--
Ohio River Water C-8 Results Near the
Letartlandfill
4.0
OHIO RIVER
LANDFILL
WATER
C-8
RESULTS
NEAR
THE
LETART
Adjacent to the Letart Landfill, Ohio River water was also sampled to measure the
concentrationsof C-8 levels in Ohio River. Two locations were sampled. One sampling
location was positioned in the river near the point where the ravine originating at the
.
landfill discharges surface-water into the river. The other sampling point was located approximately 1000 feet downstream of the first location. All samples were collected
near the shoreline (approximately 100 feet eastof the shoreline). Dip and mid-column
samples were collected at both locations. In total, five river-water samples were
collected, including one duplicate sample. All river-water samples were analyzed for C-8
in accordance with the Standard Operating Procedure approved by the GIST and the
Quality Assurance Project Plan (DuPont, 2002e).
LSaanmdpflililngariensfourmmmaatriionzeadndinCT-a8blreesu1ltasndfoarrtehperOehseinoteRdivgerrapwhaitcearllsyaminplFeidgunreea2r.
the Letart
At cach
transect location, a summary tableof C- results is shown in Figure 2. Table 2 presents
the GPS coordinates and field parameters (temperature, pH, and specific conductance) for
all samples near the Letart Landfill.
i Weiminegon,e08 nme
000036 7
RAFT OnoRiverWater Samping Resuls
Ohio River Parameters
5.0 OHIO RIVER PARAMETERS
Twaibnldes4peperdovfiodretshtehteiOmheipoerRiiovderthsattasgaemdpaltianagnwdatshecodnadiulyctreeds.ultRainvtewridnidscdhiarregcetiiosnnaontd
mThoenrietfoorreed, atthitshedaUtaSGisSnoGtaagvianiglaSbtlaetifoorn t0h3e1t5i0m8e00p,erOihoidothRaitvsearmnpelairngMawraiesttcao,ndOuhcitoe.d.
AOphpieonRdiivxerAneparrovMiadreisettthae,OOhhiioo.RiAvperpeSntdaigxe dBatparofvriodmesUtShGe ScoGmaplgeitneg sSptraetiaodnsh0e3e1t5so08f0d0a,ily
.
Local Climatological Date for June, July, and October 2002 recorded at the Wood County Airport weather recording station.
rWiamnsgiaondOoFc Nov. 19.02
000037
--5
(GRAFT Ono RiverWater Samping Resuls
References
6.0 REFERENCES
DuPont,Pu2b0li0c22W.aOtneer-SMuiplpelRyaSdaimupsliSnugr,veDyuPaonndtC-WasShaimnpgltionng WRoerpokrst(aDnedcOehmiboerRi2v0e0r1February 2002), April 2002. DuPont Corporate Remediation Group and URS Diamond.
.
`+ C2o0u0n2tby., OOhnieo-M(iMlaercRhad--iJuusnSeu2r0v0e2y),anAdugCu-s8tS2a0m02p.linDguPReosnutltCso,rWpaorsahtiengton
Remediation Group and URS Diamond.
"W2o0r0k2s.FaTciwloi-tMy/iLloecaRlaLdainudsfiSllu,rvWeeystanVdirCgi-niSaa(mMpalricnhg --ReMpoaryt,20D0u2P)o,nAtugWuassthi2n0g02t.on DuPont Corporate Remediation Group and URS Diamond.
". W2a0s0h2i4n.gtPounblWiocrkWsa,teWrasShuipnpgltyoRne,suWlVts,, AWuegsutsVtir2g0i0n2i.a DanudPoOnhtioC,oDrpuoProatnet Remediation Group and URS Diamond.
.fo2r 0W0a2s.hiJnagntuoanryW2o0r0k2s GPrloanutndWwaasthienrgItnovne,stWigVa,tioJnanQuuaarlyit2y00A2s.surDaunPcoentPrCoojrepcotrPatlea:n Remediation Group and URS Diamond.
USEPA. 1994. Region III Modifications to National Functional Guidelines for Organic Data Review.
000038
I WToimnriensagtosnd0o%c Nov. 19.02 5
000039
TABLES
'
000040
en
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Hd p H E E iee m r i E r SE a E e as e m m IE ad Em yaSEm -- m Em EmE SEe eaSEa r o e o E te ie Ee
HHCE E EEeE a esEen mEa eEe ek aee e eeeT PE e e a a ae ree ee e
CE BCEB eeEea mtleeo s--ee aem e EeeeEmr m eSe eiE e ler e a 2 a e a e t ee a o
CHHB I E EEeRemo sroa ve |e m rote fat tE mioe i mna etbss or_e iJe orSe anseer | Te| aaea e 1e aelmel 3
| EBB E S E emteew ram o e smE e te a l e a tn a e e -- a C r r t e a o e o m e s a ee e
E e eee a e e a e e a e
LFS aas Tao : we 2rFos
83) .
comianse tose .
CE o EiLErSC HtRA e weEm EaCloudyv rSea la E ee m am Tsare| S RSasREos vwe aElST)aeyre re
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000043
.
uta 005 C8Tacovnicsentraton (ug) DuPantWasnngion Works
[Sempe --_] bas[Cougt] [Fri 2JouTeALL00s |_sizsz002l 75]
.
[wwicZ00Js | ou7rTrizEacezAL23Ls)
[[wCvivizczJoouuTTeFaALLLLoooss || tfoorrrtrerraooceazl] TaTis.o))
enone
000044
Page
anirver sis
.
Ohio RivTearblPear4ameters DuPont Washington Works
E"Dar te *| OE hioRE iver T Stage*[ResSpu eed|lRestultaant Dn irecttion| 6S/2262/0200022| 5s82a.6b3 | amon [0[d23e0 qdergeresess || 7102002| 52% | amen [30degrees | Conrzooz]-- SSe0s7z8z | |7z3ommponn [Jessoodedgreessgee|s|
"Data from USGS Gaging Station 03150800, Ohio River near Marietta, OH
4 "1nar2002
000045
Page 1
oniorver xis
000045
FIGURES
:
000047
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5<
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.
i } --. JY
.
~
TF
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8 ~. --
-
LETART\ : NT--T
f QOgP
NY TM\O u N
LANDFILL PERIMETER
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-- Fonta
APPENDICES
!
000029
000058
APPENDIX A
'
OHIO RIVER STAGE DATA FROM USGS GAGING STATION 03150800, OHIO RIVER NEAR MARIETTA, OHIO
j
000051
20.0 UGB 03150800 CHIO RIVER NEAR MARIETTA, OH 1.0
Bo
E mo
geo
Hgiso 100
no
a Meo seo Gam wea
OATES: 06/10/2002 to 11/0572002
Provisional Data Subject to Revision
rage ors
000052 tpwalerdautspssRoviRwisdvd.cas02 O0065 O0DU3Eformatmimedei mrt SRNMEcat foatals Cefibbacin he mwrn
care da Us 510FRORi Nr MARIE,
USGS 03150800 OHIO RIVER NEAR MARIETTA, OH
PROVDAI TAS SUBI JECO TTON REA VISL ION Available data orthis site [Reema3] Go|
eng stem rame + TiS. Amy Cas ofEngines
prs[oR] [Avaiiabie Parameters [output format [Days |
1
s TONDEAm 3L3Y00METJAOiNNtVOe AVLEUMESBE6R|
ERE ERER jun] Jul [Aug] Sep]Oct]N
I sisafisol Jie) [sissies C[sCdeSissshiisodfissfiss |
. 000053
--_----
Rearmed or Uses 315080 00RINE NEAK MARIETTA,Of
-
Pae2or3
Ls ds 159)
--oJ JsfiIssaffiissaaffiisssah|le|
([>C[apaslssiiess]]
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5J Jisalesfisd sfissd fiss]]
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[=2Jr issfisslr isrlrsaliss |I
:
000054
Rear-une daa 10r Usus 0310000 Gris) RIVER NEAK MAKIE TA, OH
||
20eJiesabidsslisabisshsal
Jf
|
Da[coxon]Jzo=afoiena[fsiiea[fissofiseofi=cs]
Coan fissiaisafisafisaliss)
Toren, `Questions about data SEEN h2otcam@usgs.gov.
-
ns wis
F[O EE asy tot fares
Page of 3
oo Recmt . oewe
000055
000856
APPENDIX B
'
LOCAL
CLIMATJOULLOYG,IACNADL
DATA FROM NOAA OCTOBER 2002
FOR
JUNE,
i
000057
LCL rom
-
er -- eesmre
{TEE
rage Lol b
rot r Ee EE RE
ELLE LEE
rTFE
ERE
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