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Page 1-1 J. D. Baldwin Cleveland.... April 1, 195h , CUSS 100 Hydrocarbons, non-cyclic, volatile, including their halides. 100-119 C-, through Cy and any mixture of hydrocarbons having Tag Open Cup rlash points below 20F. 120-139 Cg and Co and any mixture -of hydrocarbons having Tag Open Cup flash points between 20F* and 80F. lUO-259 C10 and UP an3r mixture of hydrocarbons having a Tag Open Cup flash point above 80F. 160-179 Volatile, chlorinated, non-cyclic hydrocarbons. 180-199 Open 0007-PMC-000000150 Page 1-2 April 1951* Humber. Material________________ ' Ct through C7 and mixtures -with flash points below 20F, (1A1) (1F5) (1C1) Hexane, Commercial Hexane, Esso Petroleae Naphtha 3 Cr and Co and mixtures with flash points between 20 and 80F (1*026) (1C3) (63) (1N3) (IC9) C-8 Naphtha Iso Octane VM6P Haphtha Super VMScP Naphtha, 8182 Apcothinner and higher and flash points above 80F (3U8) (1A5) (1A6) (1F3) (1N2) (ITT) Mineral Spirits Mineral Spirits, Slops Mineral Spirits, Settled,Decanted Mineral Spirits, Settled,Decanted Mineral Spirits (Salvage), Redistilled Mineral Spirits (Salvage), Redistilled (1C12) (III*) (11$) (1C11) (U5) Odorless - Soltrol 150 Odorless - Soltrol 130 Odorless -- Soltrol 170 Odorless - Shell-Sol 72 Odorless - Amsco (5027) (ll*l) (1C2) (213) (1AU) Mineral Spirits, High Flash Mineral Spirits, Heavy Kerosene, Deodorized Kerosene Kerosene (1C8) (1C5) (1C10) (2J2) Magie 1*70 Oil Magie 500 Oil Magie 535 Oil Dieselene Chlorinated (1A9) (1F2) (ICl*) Carbon Tetrachloride Trichlorethylene Methylene Chloride go go Test Method U30.1 Distillation, F. Of, 5Qj6 10056 151 158 H*7 151* 135 165 161* 160 225 200 212 265 21*1* 263 21& 261 21*0 325 288 289 302 31*0 39U 280 330 390 35U 371 3l*5 361 1*21 1*29 31*5 361* 360 368 358 380 31*0 2*10 338 1*28 350 1*1*5 1*05 1*1*5 1*12 389 1*12 1*85 527 505(9556) 1*67 507 525 535 512 51*9 593 165 172 187 190 101* 11*2(9556) 0007-PMC-000000151 Method U38.3 KB Value Method 157.1 Evap., Minutes Remarks 30-U0 27-32.5 33-39 Vegetable Oil Extraction Traffic Paints - Uo-5U 0.7 3U-39 39 39 2.0 33-U0 9.0 2h 25 23 26 26.5 30-35 26-37 25-3U 30-35 90 27.6 25 27.5 For (3A5) or Redistilled Washing only Use (5027) Dayton Restricted; Bound Brook Restricted; ink Vehicles Restricted; ink Vehicles Restricted; Ink Vehicles Wood Preservatives: Degreaser P & V Remover Page 1-3 April 1, 195U Method 129.5 Test Method U01,,2 FPF. Sp.Gr. #/G TOC 75F 75F. Number -30 0.689 5.7U (1A1) 0 0.686 5.72 (1F5) -20 0.692 5.75 (1C1) 35 O.7l0i 6.20 (U026) 35 0.692 5.75 (1C3) 55 0.750 6.25 (63) 55 0.7liU 6.20 (1N3) 55 0.757 6.30 (1C9) 105 0.780 6.50 (3ii8) 6.5 App.(2A5) 6.5 App.(3A6) 6.7 App.(lF3) 6.6 App. (m2) 6.5 App.(l27) 135 0.757 6.30 (1C12) 130 O.7U8 6.23 (1LU) 190 0.766 6.37 (115) 130 0.757 6.30 (1011) 135 0.757 6.30 (315) Hi5 0,790 6.58 (5027) liiO 0.79U 6.61 (lia) 330 0.793 6.60 (102) 0.797 6.63 (113) (lAlt) 230 0.805 260 , 0.807 285 O.8I45 0.865 6.70 6.72 7.03 7.20 (108) (105) (3010) (112) 1.590 1.It65 1.336 13.27 12.20 31.32 (1A9) (1F2) (ICli) 0007-PMC-000000152 Page 1-U April 1, 195U Remarks (63) VMStP Naphtha is used in thinning paints and varnishes and is frequently employed as a diluent in lacquers, Used for short flow dip paints and in spray type materials. Used in traffic paints because of quick solv ent release, Bids is a red label solvent.- (1l|1) Kerosene, also known as heavy mineral spirits. An institutional policy of replacement with ($027) is in effect, (3U8) Mineral spirits, often referred to as heavy naphtha, has largely re placed turpentine as a thinner and solvent in the paint ai d varnish in dustry, More of this type of solvent is employed than any other. Used in conjunction with other solvents for most any type of application. (U026) Hydrocarbon solvent used in lacquers as a diluent and in fast drying varnishes and enamels. Generally used where VMScP Naphtha is found to be too slow. This is a red label solvent, ($027) Hi-Flash mineral spirits insures good leveling and flow. Slow evapor ation of this solvent from the paint film eliminates lapping. Gives good wet edge in brushing paints. 0007-PMC-000000153 Page 1 R. . Parkins August 10, ho CLASS 200 hydrocarbons, non-cyclic, non-volatile, including their halides 200 - 209 210 - 219 220 - 229 230 - 2U9 250 - 259 260 - 269 270 - 279 280 - 289 290 - 299 Mineral oils with viscosities at 100 F. of not over 75 seconds Saybolt Universal. Mineral oils with viscosities at 100 F. of 75 to 125 seconds Saybolt Universal. Mineral oils with viscosities at 100 F. of 125 or more seconds Saybolt Universal. Open. Petrolatums. Paraffin (slack waxes, scale waxes, white paraffin, and micro-crystalline). Other hydrocarbon waxes (ozokerite, oeresin, montan, candelilla). Non-volatile, chlorinated, non-cyclic hydrocarbons. Open. 0007-PMC-000000154 Page 2 August 10, 1956 Number 200-209 T2'I 37 (2 A U) (2 A 8) (2 A 9) (2 C 16) (2 C 18) (2 K 1) 210-219 {216) (2 C 20) (2 C 23) (2 C 25) (2 D 10) (2 F 2) 220-229 I22F) (2 A 10) (2 C 11) (2 C 15) (2 C 2U) (2 F 6) (2 P 2) (2 1 1) 250-259 25U (2 C 2) (2 c 5) 2 D 50 2F7 2L2 (2 N 1) 2 T3 2 Y5 260-269 261 (263) 266 (2 A 6) (2 A 11) (2 A 12) 2 A 13 2C8 Name Mineral Oil 50 Mineral Oil Gulf 372 Oil Ultrol #5 Mineral Oil,Special Diesel Fuel Light Process Oil Topaz Oil A Mineral Oil Mineral Oil #1*1*62 Mineral Oil 97 Mineral Oil 100 White Rose Oil #2 Mineral Insulating Oil Mineral Oil, Heavy Sohio White Mineral Oil Mineral Oil 215 Inkol No. it 750 Pale Oil Paraffin Oil Base Oil 200 Pale 200 Dormant Oil Petrolatum, Amber Vaseline Solution Vaseline Yellow Petroleum Paste Petroleum Grease Petrolatum Extra Light Amber Vaseline Solution Petrolatum, Extra Light Amber Water Proof Grease #1 Crude Paraffin Wax Paraffin Wax Solution Paraffin Wax, Refined Wax Solution Paraffin Wax Solution Refined Paraffin Wax Solution Sunoco #3U25 Wax Petrolite Crown #1035 NVK % 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 50 100 - 100 100 10 100 100 100 15.2 100 19.1 1.8 10 100 100 Melting Point Body G-H Al* - a2 --- A2 -- -- - - A1 - A1 - A1 - - A1 -X -- -B - z2 --A * -- 138 F.ASTM -- 112F. S.P. - 120F.AS1M -- 120F.ASTM 375F. -- -- A- - 125F.BfcR - 132F.ASTM -- 127F.ASTM 198F.,B&R _ A+ -- A *5 A5 - 0007-PMC-000000155 Viscosity SSTJ 9 100F. 75 69 100 97 _ 205 215 *' mm 208 200 mm _. 1550 mm > mm mm -. Color Gardner Max. n u li - 8 1 2 Dark 1 16 Dark 9 2 - 15 -. -- - lit 5 Ut - 3 - #/Gal. 7.20 7.16 7.33 7.90 7.30 7.37 7.00 7.07 6.72 7.08 7.hi 7.63 7.27 7.1th 7.95 7.76 7.35 7.75 7.61 7.13 7.25 7.30 7.73 7.88 10.08 7.51 - -- 7.25 7.08 - 6.55 7.07 6.59 - Page 3 August 10, 1956 FI.Point Gal./lOO# of (TOC) Number _ 310 (2 A 3) - - (2 A h) -- (2 A 8) - (2 A 9) -- i5o (2 C 16) -- - (2 C 18) -- 3U0 (2 K 1) 350 (216) - 335 (2 C 20) - 365 (2 C 23) - (2 C 25) - -- (2 D 10) - (2 F 2) 500 (228) - 350 (2 A 10) - - (2 0 n) - - (2 C 15) -- 395 (2 C 2h) -- - (2 F 6) - - (2 P 2) -- <2 T 1) -- --- - lh.3 13.1 13.8 - 13.2 - 13.3 12.8 390 25h 81 (2 C 2) hOO (2 C 5) - 2 D 50 - 2F7 - 2 12 2Q5 (2 K 1) - 2T3 h65 2 T 5 375 261 1Q5 (263) - 266 105 (2 A 6) 81 (2 A 11) 105 (2 A 12) h20 2 A 13 - 2C8 0007-PMC-000000156 Page it August 10, 1956 Number Continued 260-269 2 C 10 (2 C 19) 2 D 60 (2D 61) 2 F 10 212 211 (2 N it) 2N5 (2 N 6) 2N7 (2 8 8) (2 N 9) (2 T 2) 2 73 2 110 2 Y 12 (2 Y llj) Name NVM Melting .________ _____ %Point Body- 0-H Sunoco Wax #985 YellowRaybo 1*3 2305 Amber Amorphous Wax Amorphous Wax Solution Paraffin Wax Atlantic 131 Wax Paraffin Ceremul Q Crude Paraffin Wax Paraffin Wax Solution Powdered Polymekon Wax Marproofing Agent Marproofing Agent Paraffin Wax Solution Socal Petrolatum #110 Socal Petrolatum #70 S/V Product 2310 Sure Cure White Vehicle 100 100 ii.5 100 100 100 5o 100 15 100 33.8 33.7 - 100 100 100 55.U 198F.B&R - - 126F. 121F.Cap. 135F. 152F. 155^F. - - - -T7 -- -. - --- - - '* L ' L`---. 270-279 2 Cl 2C3 2C6 2C9 2 C 12 2 C Hi 2 C 17 2 C 22 2 C 26 2F3 2F9 (2 M 1) Refined Candelilla Wax- Durez 219 Blend 100 Solawax ll|02 100 Ceresine Wax 100 Ozokerite 863 100 Ozokerite 861 100 Cornelowax 1822 100 Candellilla Wax,Crude or Prime 100 Estawax 25 100 Extra Light Bleached Candelilla Wax 100 Cerese Wax 100 Ceresin Wax 100 Antifoam S-l Wax Emulsion -- ' l61iF.B&R 181F.B&R -- 193F.B&R 193F.B&R 200F.BStR 153QF.BSc R 2l5F.B&R - 170F.B&R 173F.ASTM -- -- ~ --- - - - - - - - -- 280-289 ~2B7-- (2 A 2) (2 A 7) (2 C U) (2 D 81) Chlorowax 70 Chlorowax hO Chlorowax Dispersion Chlorafin 1*2-5 Chlorowax #70 Solution 100 103F. 100 - 65 100 70 - z G' --. N 0007-PMC-000000157 Viscosity SSU @ 100 F. Color Gardner Max. #/Gal. 7.6 -- 6.35 -- 7.56 -- m. -- -- 8.12 -- -- 7.08 ---- -- 7.86 - - 7.23 -- - 7.30 * ---- -- --_ - -- 7.07 -- _ - -- -- - - - - -- -- -- -- -- - 10 7.66 - -- - - - - a 9.6 - 10 10.52 - 6 9.77 - - 10.7 Page 5 August 10, 1956 FI.Point Gal./IOQ# of (TOC) Number 12.8 12.0 - 13.25 --. 13.15 -- 12. U7 - 12.2 - - 13.U Ui.06 1U.2 -- 66 -- 55 - - - - 105 1*95 35 35 - .- 1*00 It60 -- 2 C 10 (2 C 19) 2 D 60 (2 D 61) 2 F 10 2K2 2L1 (2 N 1*) 2N5 (2 N 6) 2N7 (2 N 8) (2 N 9) (2 T 2) 213 2 X 10 2 T 12 (2 I U*) ll.U 11 ,h 13.3 12.7 12.9 12.6 12.0 12.7 12.0 12.8 13.05 - - -- - 1j 6o - 2 C1 2C3 2C6 2C9 2 C 12 2 C 11* 2 C 17 2 C 22 2 C 26 2F3 2F9 (2 M 1) 7.23 - - - - 80 .. 80 287 (2 A 2) (2 A 7) (2 C U) (2 D 81 0007-PMC-000000158 REMARKS Mineral oils are products resulting from the distillation of crude petroleum. Purification is accomplished through a cold sulphuric acid process. General uses of mineral oils include* low cost reducers in wood preservatives, neutral oil bases and standards, chiller pastes, and marproofing agents. Petrolatums, like mineral oils, are products of petroleum distillation and are purified in a similar manner. Main uses are as marproofing agents, "slip" agents, and in concrete curing compounds. Although waxes have a variety of sources, one of the chief types - paraffin - is again a product of petroleum refinement. Usage other than wax compounds is as marproofing agents, and concrete curing compounds. Our use of chlorinated hydrocarbons is almost exclusively in fire retardant finishes. 0007-PMC-000000159 Page 3-1 J. D. Baldwin Cleveland April 1, 195k CIASS 300 Hydrocarbon, cyclic, both volatile and non-volatile, including halides. 300-309 C3 through C monocyclic (Benzene, cyclohexane, naphthenes).. 310-319 C7 monocyclic hydrocarbons and all mixtures of cyclic hydro carbons having a Tag Open Cup flash point below 80F.- (Toluene, toluene substitutes, methyl cyclohexane and Cj naphthenes). 320-339 Cg and higher aromatic monocyclic hydrocarbons and mixtures of monocyclic hydrocarbons having Tag Open Cup flash points above 80F. (Xylene, cumene, "High Flash Naphtha", crude heavy naphtha, creosote oils).. . 3UO-3U9 Co and higher non-aromatic cyclic hydrocarbons and mixtures thereof having Tag Open Cup flash points above 80F. (Terpenes such as turpentine, pinene, dipentene, limonene, etc.,, aliyl hexane and alkyl naphthenes). 350-359 Non-volatile cyclic hydrocarbons (coal tar neutral oil, rosin oil, naphthalene, anthracene, etc.). 360-369 Chlorinated cyclic hydrocarbons (chlorobenzene, etc., but not chlorinated diphenyls which are in class Ii9). 370-399 Open 0OO7-PMC-OOOOOO160 Page 3-2 April 1, 199U Number Material Cp through Ca monocyclic (3C7) Benzene, 2 Industrial Cy monocyclic and low-flash mixtures (2Ul) Toluene, Industrial, Pure (UoUl) Toluene, 'Hide Range (3F3) Toluene (Specification) (3C23) Toluene (Specification) (3C2) (3C9) (3D10) Bidosol #1 Velsicol IF (Alti Hi-Solve T) T" Sol Toluene Substitute Cr etc a aromatic monocyclic and higher flash mixtures (hou6) (liOUo) (3A2) (3AU) Xylene, 20 Xylene, Wide Range Xylene, Slops Xylene, Ends from Redistillation (3C19) (3N2) (3P2) (3XU) (3A1) Xylene (Salvage), Redistilled Xylene (Salvage), Redistilled Xylene (Salvage), Redistilled Xylene, Amsco Solvent B SC Solvent 2B (U021) (2*OU8) (1297) (3X7) (3D20) (3X8) Aromatic Naphtha Aromatic Naphtha Hi-Flash Solvent Naphtha Shell IS-28 Hi-Flash Naphtha Solvent 7R (3A.6) (3X3) (3X2) (312) Creosote Oil, A.R.E.A* Creosote AW PA#1 Creosote Diluent #1 Shingle Stain Oil 1X767 ___ (3C17) (3A9) (3C1) (311) (3x6) Styrene Monomer N99 Velsicol AR90G (Methylated Naphthylene) Polymethylated Naphthalene 2 Nevinol Union 1*060-0 Aromatic Oil Cr etc, non-aromatic and higher flash mixtures (lU) Turpentine, Wood Sulfate (20li9) Dipentene (3C6) Orange Oil (D-Limonene) (3FU) Turpentine, Gum Spirits Non-volatile cyclic (3D92) Coal i&r Neutral Oil UOJ-l; HSU0 (Part, hydrog. mix* of isomeric terphenyls) Distillation F. 0% $Q% X0(% Value 179 178 118 229 200 220 228 228 221 210 223 239 300 23lt(DP) 23U(DP) 239(BP) 280(DP) 237(BP) 109 82 88 90-99 92 Min. 270 311 270 290 3U0 90 90 260 360 79 299 369 90 270 311(DP) 87 276 390(d p) 79 3^0 379 390 380 302 320 300 332 280 315 326 109 hZ$ 370 390 38it 33li 69-89 89 Min 89-100 7U 33-Uo 107 671 293 380 900 80 970 700 Uoo 600 302 33k 330 3h7 302 360 370(9$%) 379 360 99 69 70 96 302 970 680 0007-PMC-000000161 Evap. Minutes- Remarks FPF TOC Sp.Gr. 75F Page 3-3 April 1, 195U #/G 7>F. Number 1*0 2.5 3.0 - 30.0 30.0 7.5 P & Remover -- Vest Coast Spec. TT-A-51*8a Spec. TT-A-5U8& lacquer Lacquer Alt. for (3C9); use (3C9) West Coast For Redistillation Ends from (3A2) RedistiUation Washing Only Washing Only Vest Coast alt. (l*0l*6) Restrictedr TT-V-119 West Coast alt. (1257) Acme only; R.B.L. pres ervatives Shingle Stains. vast Coast alt. (3A6) Preservatives Solvent Lowe Bros. Alkyd Tarnishes Restricted; Bound Brook VB & Awning, etc. Plasticizer Preservatives Solvent 12 0.880 7.38 (3C7) 1*0 0*863 1*2 0*828 2*5 0*863 1*5 0.863 0*831 0*82*2 35 0.835 7.18 6.90 7.18 7.18 6.92 7.01 6.96 (21*1) (l*oi*i) (3F3) (3C23) (3C2) (3C9) (3D10) 81 0.863 81 0*863 65 80 0,81*3 81 0.831 135 0.865 135 0*879 105 0.870 125 0.81*0 0.780 100 0.873 1.080 l*oo 1*095 0.963 0.906 80 0.905 160 0.91*3 1.01*1* 0.935 7.28 (1*01*6) 7.18 (1*01*0) 7.2: Af p. (3A2) 7.2 Ah >. (3Al*) 7*1 Ar >. (3C19) 7.0 Ajp..(3N2) 7.2 A0>,(3P2) 7*02 (3x1*) 6*92 (3A1) 7.21 7.32 7*25 7.00 6.50 7.27 (1*021) (l*0t*8) (1257) (317) (3D20) (3X8) 9.00 9.08 8.02 7*55 (3A6) (3X3) (3X2) (312) 7.51* 7*85 8.70 7.78 (3C17) (3A9) (3C1) (311) (3X6) 6.0 10.0 Emulsions Restricted* Sherdye 85 0.861* io5 0.853 120 0.81*0 75 0*861* 7.20 7.10 6.99 7.20 (1U) (201*9) (3C6) (3Fl*) Salamander Black 100 1*020 155 0.91*3 *, 0007-PMC-000000162 8.50 7.85 (3D52) ,(3P1) M3C11) Page J-U April 1 195>k Number Material______________________________Restricted Chlorinated Cyclic 3A5 Dichlor Diphenyl Trichlorethane 347 Benzene Hexachloride 3A8 lindane (99% Gamma Isomer of Benzene Hexachloride) 3410 IDE (BED) Technical 3411 Marlate $0 (Metho^ychlor $0%') Bound Brook Bound Brook Bound Brook Bound Brook Bound Brook REMARKS Toluene Toluene is one of the most conation solvents for lacquers and synthetic resins and is extensively employed as a thinner for such coatings Its very rapid rate of evaporation makes it desirable in these appli cations in which quick drying is an essential quality. Xylene like toluene, xylene possesses high solvent power for most synthetic resins. Its slower evaporation rate indicates its use, in preference to toluene, in certain cases where such property is desired. High Flash Naphtha High flash naphtha does not possess as much solvent power as toluene. On the other hand, its much slower evaporation rate and high flash make it desirable for use as a solvent or thinner requiring such properties. Turpentine Turpentine has more solvent power for most resins than petroleum naph thas, but less than aromatic or coal tar solvents. Its main use is as a thinner in certain paints and as a solvent in varnishes. Wood turpentine contains less dipentone and more pinene than gum turpen tine. For this reason, it has slightly less solvent power and slightly greater speed of evaporation. Dipentene Dipentene has more solvent power and is slower evaporating than turpen tine. It is largely used as an anti-skinning agent. Creosote The creosotes are used mainly in preservatives as fungicides. 0007-PMC-000000163 Page 4-1 E* Kulish Chicago February 8, 1955 CLASS U00 400 through 429 4oo - 409 410 - 419 420 - 429 Alcohols, mcuohydric Alcohols, 0^ through C3 Alcohols, Cj through C7 Alcohols, Cg through C^g 0007-PMC-000000164 Page U-2 February 8, 19?? Material No. (Uoi) (UC16) (U03) (1*0?) (U06) (1*C19) (108) 0*11) (1*C20) (l*ll*) OlDlO) (U09) (U6) 0*15) UT6 0*17) (Ua U) 00-6) 0*18) (1*C22) `.(1*21) OiCl) (1*C18) (UC17) (1*F7) 0*22) (1*19) 0*23) (UF1) 0*2?) 0*F9) I*A3 Previous No (2617) (1891) (30) (330) (3031* (1167) 0*037) (2602) (l6?6) 0*033) (1682) (3031) (3032) (2610) (3039) (293) Material Methyl Alcohol Methyl Alcohol (Heads) Ethyl Alcohol - Anhydrous Ethyl Alcohol - 9$% Ethyl Alcohol - S. D. #1 Alcohol Blend Isopropyl Alcohol N. Butyl Alcohol N. Butyl Alcohol Mixed Butanols Mixed Solvent"6?$ But. Al., 32$ Tol.s 3% water Methyl Cellcsolve Pensolve Alcohol Ethyl Cellosolve. Cyclohexane! Methyl Any! AIcchel Benzyl Alcohol Diacetone Alcohol Butyl. Cellosolve Methyl CarbitcX .......... Octyl Alcohol. Amyl Alcohol, Tech. Octyl Alcohol Iso-octyl Alcohol Iso-octyl Alcohol. Solvent C-8 Carbitcl Butyl Carbitol Lauryl. Alcohol. Pine Oil Pine Oil Di (p-chlorophenyi) methyl carbinol 0007-PMC-000000165 Distil* Range C Test Method 1*03.3 61* 66 61 69 7h 79 75 80 75 80 70 82 81 83 115 118.5 115 118.5 113 121 Flash Point F - T.O.C. Test Method 1*29.5 52 52 65 1*5 15 1*1* 60 nit llh 122 126 109 130 137 152 162 135 170 127 133 199 20lj 135 170 163 173 185 195 131 212 llih 165 200 180 192 132 136 181 186.5 175 200 175 200 182 111. 182 180 180 171* 181.5.(85* .180 185 205 between;205 220 235 230 261* 332. 190 250 165 190 250 172 Sp. Gr. Wt/Gal. 75F. 75F. Test Method - 1*01.2 0.790 0.791 0.790 0.808 0.808 6.58 6.59 6.58 6.73 6.73 0.808 0.782 0.808 0.808 0.810 6.73 6.52 6.73 6.73 6.75 6.93 0.963 8.02 0.928 0.960 7.73 8.00 0.80'U 1.03*0 0.937 0.900 1.030 6.70 8.67 7.81 7.50 8.58 0.832 0.815 0.82? 0.831 0.831 6.93 6.79 6.89 6.92 6.92 0.811* 1.021* 0.953 0.83U 0.920 6.78 8.53 7.91* 6.95 7.67 0.930 7.75 Page ii3 February 8, 1955 Material 0*oi) (1*016) (U03) (UQ5) (U06) (1*019). (108) (l*H) (1*020) (lolt) (1*D10) (1*09) (1*6) (1*15) I*x6 (1*17) (l*Al*) (ia6) (1*18) (1*022) (1*21) (l*ci) (UC18) (1*017) (1*F7) (1*22) (1*19) (1*23) (1*F1) (1*25) (1*F9) 1*A3 0007-PMC-000000166 CLASS LOO - (LCD through L29) Remarks The lower boiling members of this class (through C-12) are used principally as solvents in nitrocellulose lacquers. Certain mem bers are also used in enamels and stains such as methyl alcohol in stains and butyl alcohol in alkyd resin enamels (particularly those enamels modified with urea or melamine resins). As the bell ing point increases (above 170C.) the use of these alcohols as lacquer solvents decreases. These higher boiling alcohols are used as anti-foam agents, leveling agents, and wetting agents. The principal use cf alcohols is in nitrocellulose lacquer. Alco hols are in themselves non-solvents for nitrocellulose, but in the presence of an active solvent (such as esters or ketones) they be have as though they were true solvents. It has been proved that the use of active solvent plus. alcohol will result in a lower vis cosity than active solvent alone. Also, most alcohols are lower costing than, the corresponding ester and by using them, raw material costs are lower. 0007-PMC-000000167 Page 4-5 E. L. Superits Chicago November 30, 1956 Class 400 Monohydric alcohols (C^3 and above) and polyhydric alcohols, including halogen-substituted. Also additional similar reacting poly-functional oxides. 430 - 439 Monohydric alcohols (C13 and up) 440 - 449.1'Open450 - 459 Dihydric alcohols 460 - 469 Trihydric alcohols 470.- 479 Tetra-and higher-hydric alcohols 460 '- 499 Open 0007-PlVfC-000000168 Vfeagh 4-6 November 301 1956 Number Prev Wo. Kama Flash Wt. X Wt. X Point *F. `Water Add Viscosity Monohvdtic Alcohols Sub-Class 430 (430) <4A7) .(4A9) (4C6) (4C13> CW(2967) CW(309l) Abitol Tergitol HP-14 Triton-Xl02 Triton-XlOO Triton-W1756 420 i 6*50 (4C15) (4C24) (4F2). (4m) (29C29) Tergitol-XC Tergitol-NPX Abitol (90X in Xylene)' Triton X-45 500 Di-Hvdric Alcohols A Di-Functional Oxides Sub-Class 430 (450) (451) (452) (453) (4A10) (3075) CW(1677) (4098) CW(2819) 0W(612) Ethylene Glycol Di-Propylene Glycol Propylene Oxide Plasticizer X565 Hexylene Glycol 240 280 f-35 6,50 6,50 1.00 0.01 0.01 0.05 0.01 (4C7) (4Gll> (4C12) (4C23) (4C30) 4C31 (4034) (24C6) Di-Ethylene Glycol Eplchlorohydrin Polyglycol P-1200 Pluronic L-44 Dimethyl Octynediol Carbowax 1500 Tri-Hvdric Alcohols Sub-Class 460 245 105 430 0.30 6.10 0.Q2 654 cps (462) 4C14 (2666) Glycerine Trimet Tetra-Hvdric & Richer Alcohols Sub-Class 470 472 473 475 4F6 2296 1986 Pentaerythritol-49 Pentaerythritol-47 Di-Pentaerythritol Stabiliser A-5 0.50 0007-PMC-000000169 Page 4-7 November 30 1956 Hydroxyl Distillation Melting Bolling Value ColorRange *0.Point *F. Point *C. Wt./Gal. Number 5.0 8.34 (430) 8.53 (4A7) (4A9) - 8.85 (4C6) (4C13) 8.6 8.9 8.65 (4C15) (4C24) (4F2) (4F11) 15(APHA) WW 15 (GH) 15(Hazen) WW ww Cloudy 3(GH) 190-210 215-245 30-40 193-200 230-270 197 232 30 250 116 9.28 8.53 6.93 7.70 9.88 9.85 8.85 8.5 9.48 (450) (451) (452) (453) (4A10) (4C7) (4C11) (4C12) (4C23) (4C30) 4C31 200 10.51 (462) 4C14 482 428 9.50 472 473 . 475 4F6 0007-PMC-000000170 Page 4-8 November 30, 1956 Remarks (430) Abltol (Hydroabletyl Alcohol) - produced by hydrogenolysis of rosin and represents a colorless, tacky, viscous liquid at room temperatures. Chemical reactions are typical of a primary monohydric alcohol plus what might be expected from the residual unsaturation in the ring structure. Uses! Modifiers for chlorinated rubber, plasticiser in many synthetic resins and waxes, modifier for hydrogenated oils and essential oil vehicles. (4A7) Alkyl Phenyl Ether of Polyethylene Glycol - surface active agent finding use in Brush cleaner formula - can be used in oil soluble emulsifier. (4c6) Triton X100 - (Alkyd Aryl Polyoxy Ethylene Glycols) an anhydrous liquid non-ionic detergent and wetting agent which is freely water soluble. An outstanding emulsifier for many applications, (4C15) Tergltol XC - Polyalkalene Oxide used as emulsifying agent. (4C24) Alkyl Phenyl Ether of Polyethylene Glycol - surface active agent used as dispersent in emulsion. Good detergent, vetting agent and emulsifier. (4F2) (4F11) Abltol (90% in Xylol) - (Hydroabletyl Alcohol - 90Z in Xylol) - would dis play much the same type characteristics of (430) with consideration being allowed for 102, Xylol which is present. -K Alkyd Aryl Polyether Alcohol - surface active agent - good detergent for non-aqueous system - miscible in all proportions in aliphatic solvents. (450) Ethylene Glycol - difunctional alcohol which finds use as printing ink solvent, formation of plasticizers, special alkyd resins, esterification of rosin to obtain lower melting point ester gum with improved alcohol solubility. ' (451) Dipropylene Glycol - similar in properties to (4C7), having greater molecu lar weight. Has great solvency for castor oil. Much wider compatibil ity. Should provide more flexibility and better solvency for printing ink resins. (453) Dow Plasticizer X565 - (Technical 4-4' Isopropylidene bis Phenoxy Propanol)* difunctional viscous plasticizer which dissolves in all common solvents except aliphatic naphthas, glycerin and water. It is generally compat ible with alcohol soluble resins such as ureas, melamines and shellac however, it is not compatible, with vinyl resins. Can be used to form large size molecules in esterification processes in order to enhance viscosity. Varnishes employing.this plasticizer exhibit extremely good flexibility and toughness. 0007-PMC-000000171 Page 4-9 November 30, 1956 (4C7) Diethylene Glycol - difunctional alcohol which finds use as printing ink -solvent, formation of plasticizers, and makes possible more stable emulsions in soluble oils acting as a coupling agent between free fatty acids and fatty acid soaps. (4C11) Epichlorhydrin - a reactive intermediate for the synthesis of materials which may be used in surface active agents, resin intermediates, stabilizers and plasticizers. The reactivity of this item is due to the presence in the molecule of both an epoxide ring and a chlorine atom. (4C12) Polyglycol P-1200 - Polypropylene glycol finding some use as an emulsifying agent in latex paints. (4C23) High Molecular Weight Polyethylene Glycol - surface active agent - water miscible - relatively non-hygroscopic - dispersing agent in emulsions, polishes and abrasives. 4C31 Polyethylene Glycol 1500 - molecular weight 500-600 - water soluble polymers used to modify alkyds for emulsion vehicles. Used as water soluble lubricants - good solvents for dyes, resins, proteins. Dispersent for casein, glues, zeln and cork. 4C14 Trimet - Xrimethyolethane represents a polyhydric. alcohol that could be con sidered as a substitute for pentaerythritol which can give a tougher film along with improved color retention under certain conditions. (4F6) Stabilizer A-5 - produced by Carbon & Carbide and believed to be essentially the diglycidyl ether of Bisphenol A. It could be considered a monomer but it also resembles polymeric materials. in regard to its character istics . 0007-PMC-000000172 Page 5-1 E. Kulish Chicago February 3> 1955 CLASS 500 Aldehydes, Ketones, Quinones, and any other compound in which a carbonyl is the sole or principal functional group, includ ing halogen substituted. 500 - 519 520 - 529 530 - 5U9 550 - 559 560 - 569 570 - 579 580 - 599 Open Aldehydes Ketones of Cp through Cg Ketones of Cg and higher Open Quinones Open 0007-PMC-000000173 Page 5-2 February 3> 1955 Material Number (5C1U) (5C9) (5C13) (5C10) (5M1) (5CU) (5C15) (5C12) (530) (533) (507) (5A2) (5Uo) (5U6) (5F1) (5C2) (556) (5cn) 5F2 5L1 503 Previous Number (5A1) (1826) (2639) (3038) Oi03l) (U030) Material Formaldehyde Solution Formaldehyde Solution (37/0 N. Butyl Formcel (U0^) Glyoxal (30^) Glyoxal Cisco Solve H Methyl Acetone Acetone Acetone Methyl Ethyl Ketone N. Butyraldehyde Mesityl Oxide Methyl Isobutyl Ketone Cyclohexanone Pentanedione Paraldehyde Isophorcne Di-isobutyl Ketone Synthetic Camphor Anthraquinone Chloroanthraquinone Distil. Range C Test Method 1*03.3 56-77 52-62 55-57 55-57 78-81 70-80 120-135 11U-H7 130-157 125-lUU 100-127 205-220 163-173 0007-PMC-000000174 Flash Point F. T.O.C. Test Method 1*29.5 Above 80 150 127 Below 32 20 15 15 22 6U 98 81 116 105 90 205 11*0 Sp. Gr. 75F. Test Method 1*01.2 Wt./Gal. 75F. Test Method 1*01.2 1.038 1.087 0.980 1.257 8.65 9.06 8.17 10.00 10.U8 0.81U 0.832 0.788 0,788. 0.803 6.79 6.93 6.57 - 6.57 6.69 0.802 0.853 0.799 0.9U3 0.972 6.62 7.11 6.66 7.85 8.10 0.990 0.919 0.805 8.25 7.66 6.71 Page 5-3 February 3> 1955 Bulk Gal/100 12.1 8.0 12.0 Material Number (5C1U) (509) (5013) (5010) (5M1) (5cl*) (5ci5) (5012) (530) (533) (507) (5A2) (5Uo) (51*6) (5F1) (502) (556) (5CH) 5F2 5u 503 0007-PMC-000000175 Page 5-U February 3, 1955 Remarks The ketones in this class display exceptional solvency for a vide variety of materials, particularly those which are used for surface coatings. Cellulose nitrate, ethyl cellulose, cellulose acetate butyrate, acrylic resins, vinyl acetate, vinyl chloride--vinyl acetate copolymers, in fact, practically all snythetic and natural resins commonly used in lacquers are soluble in one or more of these ketones. Other uses consist of solvents for camphor, fats, grease, gums, oils, and dyes. Aldehydes such as butyraldehyde are excellent antioxidants. They are used in the manufacture of snythetic resins (phenolics and ether resins). The quinones find usage as oil bodying catalysts. 0007-PMC-000000176 :Class 600 Acids, carboxylic, fatty Page 6-1 Formulator *s Hdbk, Cleveland Aug* 1956 "n u mber NAME . sc 600, :1~C10 (6 F 3) Formic, 85$ (602) Acetic, Glacial (6 C 2it) Acetic, 58$ (6 A U) Acetic, 56$' (6 A 23) Acetic, 28$ (6 C 20) Pelargonic, 90$ (6 CA9) Capric . ACID TITR I.V. 7ISC. VALUE OHT C COLOR GARDNER . FLASH PTF TOC SP. cm 77F LBS. /Gal 77F * 9.95 . 8.65 350 .5 333 26 53 .910 7.63 sc 620, -li-ciu (62U) Laurie, 90$ (62^) Cocoarrat (6 c 25) Myristic .- 280 1*3 1.0- .......... ___ 2------ -- ---- "I . .870 7.2U .. 260 21; 10 3 .880 : 7.33 5 2U6 50 1 2 ..888- 7.1*0 sc 630, ZXd- Sc Up (6 C 7)- Stearic, Triple Pr 202 (632) Oleic 195 (6 X 9) Oleic, Emersol 233 202 (6 F 2) Soya, Emersol 610 193 (6 X 11) Soya, Neofat 127 200 (6 A 6) Scya, 195 (6 C 26) Aliphat 16 W 200 (63U) Linoleic, 55$ 198 (6 C 1*) Linoleic, 59$ 198 (6 c 15) Linoleic, Emer.9310 19U (6 X 12) Linoleic, Emer.9310 19U (6 A 8) Linoleic, Emer.9315 19u 55 5.o 9 90 5 88 28 115 m 28 315 m 29 125 m 25 125 5 138 m 19 138 m ll*0 m 1U0 m 11*5 m 1 5 5 1* 2 2/ .u k 1*. .891* .888 7.1*5 . 7.1;0 .89k 7.1*5 .891* 7.1*5 6: .900 7.50.. .900 7.50 ..900 7.50 .900 7.50 .900 1-7.50 ' .906 7.55 (639) (638) Black Oil Linseed 70-170 200 150 m 15 180 m Dk 6 .921;. -7/7Q : .90U. 7.52 ( 6 A 3) (6 C 9) (6 X 10) (6 A 1) (6 A 5) (6X6) D.C.O.F.A. D*C. O.FJU Synthenol Tung Tung, 35$ NV Soln Tung, 25$ NV Soln 170 195 11*5 195" sc 650, C-icr & Up, with rosin acids (6 C 17) Acintol F A 2 195 (6 L5) Aliphat kh A 195 (6 A 7) Acintol FA 1 189 (6 I) 51) Indusoil (6 T 1) Acolin 180 (6 C 18) Acintol D 190 15 120 m 5 150 m 130 m 1*0 158 in ROSIN ACID $ 1M 127 m A 2M 120 m UM 138 A 28 158 GH 32- 161* D ' 6M 5M 8M 12 M 13 M 8M 8M 9M 8 .908 .900 .900 .913 .882 .8U6 7.57'' 7.50 ` 7.50 7.60 : 7.3k 7.05 380 .898 7.1*8 . 380 .900 7.50 7.59 7.8 U00 .91*7 7.90 (662) (6 N 1) (6 C 22) (6 C 10) (6 C 21) (6 C 8) (6 L 1) Tall Oil, Acid Ref. 160 Tall Oil, Unitol R Tall Oil, Unitol G? 170 Tall Oil, Crude 165 Aliphat \6 A 180 Faresac 69 Pitch Dimer Acid, KU61R 186 1*3 125 he 167 h2 160 70 150" 73" Z3 solid Z2-Z5 12 M 9M A8 10 M 12 M 350 .987 .990 * .965 1.01; .9UU 8.22 8.22* 8.25: 8.03 8.66 * 8.1 7.85 0007-PMC-000000177 Class 700 Acids, carboxylic, non-fatty, Pago 7-1 Formlators Hdbk, Cleveland Aug. 1956 NUMBER NAME MP, or ACID vise. BP V/NV GH-T C sc 700 Monobasic (7 C 13) Crotonic, sc 600 M (7 A 2) Octoic B (7 A 1) Naphthenic 2ij0 (7 A 7) Naphthenic 230 (7 C 12) Naphthenic, Ref (7 A 3) Naphthenic, Crude 72 600 220 380 : 2k0 230 Dark B' B (7 C 6) Lactic, 502 700 Benzoic, 982 7 C 3 Benzoic, Tech 7 Y 3 Benzoic, 932 7 L 1 ~ Ptbutyl benzoic M M 121 166 315 7,A It Naphthalene acetic COLOR FLASH GARD. PT F or Pt Co TOC SP BULK LBS GR GAL /GAL 77F /CWT 77 F Ft 30 G8 G8 190 260 .903 11.8 7.31 260 .978 ff.13 260 .978 e;i3 8.13 t?*' . v' ' . __________ 1.1U2 10.3 ' sc 75>0 Di- & Folybasic 731 Oxalic, dihydrate M 101 883 (7 C 11) Ctxalic A sol*n 733 Maleic anhydride M 32 1130 737 Fumaric M 287 91x6 7 C 10 7F1 7 C 17 7C1 7 C 13 Malic Malic Tartaric Diglycolic, 982 Citric, monohyd M 100 M 100 M 138 K 133 837 837 1*653 7.3 8.1 1.6U 7.3 7.3 7.3 6.8 .. 1.3U2 7.8 7 C U Adipic 7 A 8 Azelaic M 293 767 M 203 367 376 763 Phthalic, flake K 130 770 Phthalic, molten M 130 Pt 33 Pt 33 7C7 7C8 7Y1 7Y 2 Phthalic, crude Phthalic, crude Phthalic, tech Phthalic, recov. M 190 (.82 non-sublimable) (.1x2 " -) 7 C 18 Isophthalic acid K 669 7 C 19 Tetra-cl phthalic an. K 15U 7 A 9 Chlorendic anhydride M 239 303 7 C 3 Bromo TS (7 M 1) Menthadiene * -(sub class 8800) . (sub class 3U0) 7.8 7.8 7.8 7.8 7.5 6.9k -..... .... 0007-PMC-000000178 Page 7-2 June* 1956 (7A2) (7A1) 755 707 Is limited to drier Manufacture For driers is preferred over (7A7) which Is wore available* f t Should he used only where 757 drier is not satisfactory. ' ' v And related lspure grades of phthalle anhydride stolid not W ; used in general alkyd fonailatlens* 0007-PMC-000000179 Page 6-1 ft. S. Taylor Cleveland May 1$, 195U CIASS 800 Soaps or salts of carboxylic acids of classes 600 and 700 con taining metals of the first three major and minor periodic groups, including mixed soaps also derived from phenols. (Rosin salts are classified 3320-3329.) 800 - 819 .Major Group I plus ammonia (Li, Na, K, fib, Cs) 820 - 839 Minor Group I (Cu, Ag, Au) 6li0 - 859 Major. Group II (Be, Mg, Ca, Sr, Ba, Ra) 860 - 879 Minor Group II (Zn, Cd, Hg, Phenyl Hg Oleate) 880 - 899 Group III, Major and Minor (Al, A1 Stearate, Etc.) 0007-PMC-000000180 Page 8-2 May 15, 19$h Number % Metal Salt or Soap 1122 813 l(8Al) Potassium Flaxoap MI >. Sodium Ivory Soap Powder Sodium Ivory Soap Solution 8d5 (82Uo: Copper 8 Copper Oleate Naphthenate (8D22) 28 Copper Hydroxy Naphthenate (8A9) 8F3 3.5 Magnesium Octoate Magneisum Stearate (2236) (8C20) (2235) 1826 8A10 8C28 (8C26) 'll.. Calcium U Calcium 5 Calcium Calcium 13.5 Calcium 9.3 Calcium Calcium Naphthenate Naphthenate Octoate Stearate Soyate Pulp linoleate Pulp Linoleate Base (5096) (811) 1U09 8d 6o 8C27 8 Zinc 8' Zinc III Zinc Zinc Zinc Naphthenate Octoate Stearate Stearate N/C Disp. Vistex #20 C8A12.) 10 Mercury (8d9) Mercury 8P3 59.5 Mercury Phenyl Hg Succinate (Super Ad-It) Phenyl Hg Oleate Phenyl Hg Acetate 1938 51x7 8A11 (8p2i) (8C22) 8A7 6.0 Aluminum 8.3 Aluminum 11 Aluminum Aluminum Aluminum 16 Aluminum Tristearate Distearate (Mixed) Stearate Stearate Gel Stearate Primer Palmitate (8D80) 6 Cerium Naphthenate m) It Rare Earths Tt aphthenate NVM Body % GHT it2.5* 100 ...20* 100 73 ` Color Gard Max, White White Green 53 100 57-60 60 R U8 W 100 30* 30-36* 8 ... White 11 10 5 White White White 5U E-F 50 100 100 22 a 5 10 100 100 1X50 7 a. 5 1X50 8 8 White 9 9 White White White White Ijhite 25.6 32 Volatile as water 0007-PMC-000000181 MPC H&B ' Remarks FPF TOC Emul. & Detergents Bulk G/100# 11.8 Fungicide n.U 105 lacquer Chips S-ttMfr., IOM lUo 1U5 Sherdye 11.7 Drier - 105 Ferro Only 105 Kem-Glo io5 i5o Suspending Agent 11.61 11.9 Use 8A10 11.9 8C28 in Varnish 115-120 Drier Try (5096) Flatting Agent Industrial Xacq. Kem Dura io5 io5 5o 11.0 12.6 12.6 Fungicide 10k . Fungicide l*i9 Fungicide 100 91-99 Flatting Agent U5-160 Thickening Agent 160 Graphic Arts 11.9 11.1 11.9 Primer 200 Thick. & Susp. Agent 11.2 Drier Drier (Baked) Sp.Gr. ?5f . 0.912 1.03 1^195 0.906 0.9UU 0.936 0.91U 0.966 0.900 0.971 0.827 0.783 0.865 0.936 0.883 #/Gal* 75F. 7.60 8.6' 9.9$ 7.55 7.87 7.80 7.62 8.05 7.50 8.10 6.87 6.52 7.20 7.80 7.35 Page 8-3 May 15, 195k Number. 1122 813 (8A1) 8cl5 {my (8D22) (8A9) 8F3 (2236) (8C20) (2235) 1826 8A10 8C28 (8C26) (5096) (811) 11*09 8d 60 8C27 (8A12) (8C19) 8P3 1938 5U7 8A11 (8p 2i) (8C22) 8A7 (8d 80) (8rli) 0007-PMC-000000182 Page 8-I1 May 15, 19$k Remarks Calcium naphthenate is frequently used to replace a lesser amount of lead drier in varnishes exhibiting a poor tolerance for lead to help prevent precipitation. In some cases, complete replacement of lead ob tains equal or better drying when the calcium is activated by the pres ence of cobalt and manganese. Calcium often eliminates the tendency of the enamels and dipping varnishes to exhibit silking or blooming. It has pigment wetting and dispersion characteristics in grinding liquids. zinc naphthenate is noted for its ability to inhibit the wrinkling which is often induced by sizeable quantities of cobalt, especially in baked finishes. Use of three parts zinc to one part cobalt practically eliminates this tendency. While zinc slows the initial set and dry, it does not usually affect the overall drying time. It is said to have a pronounced tendency to inhibit gelation. Ibis inhibition.is also said to be an effective preventative of skinning in some alkyds. Because of its wetting power for pigments, zinc is used as a mixing and grinding agent. It also is used as a fungicide. Copper naphthenate is of prime interest as a fungicide and pre servative. Use as a drier is severely restricted by its color. Aluminum stearates are used as flatting agents and suspending and bodying agents. Rare Earth naphthenate must be baked, it cannot be used in air dry finishes. It wild, gel coconut fatty esters. 0007-PMC-000000183 CIASS 900 - page 9-1 M&y 19, 195U R. S. Taylor Cleveland Soaps or salts of carboxylic acids of classes 600 and 700 contain ing metals of the Uth through 8th major and minor periodic groups, ineluding mixed soaps also derived from phenols. (Rosin salts are classi fied 3320 - 3329). 900 - 919 Group 17, major and minor (lead, tin, Ti, etc.) 920 - 929 Group V, major and minor (antimony, Bi, Va, etc.) 930 - 939 Group VI, major and minor (chromium, molybdenum, etc.) 9U0 - 9h9 Group VII, major and minor (manganese, etc.) 990 - 969 Group VUI, (cobalt, iron, nickel, etc.) 970 - 999 Combinations of any class 9 compounds with or without class 8 compounds. 0007-PMC-000000184 Page 9-2 May 15, 1951* Number i Metal Color NVM Body Gard. % GHT Max. Remarks #/G 75f . ACETATES 9A13 9Ah9 9A?2 9A$9 55 Lead(.3H0) 100 25.UMang. pfHg0) 100 22.I*Mang.(.J*j0) 100 23 Cobalt(.l*H20)100 Solid White Solid Pink Solid Pink Solid Pink Drier Mftr. Drier Mftr. Drier Mftr. Drier Mftr. 1*. 8 (Bulk) 7.5 7.5 " 7.1 '' FATTI ACIDS (UltEDENTIFIED) (9W2) 6 Zirconium 28 A (913) 21* lead . (9L7) 6 Cobalt U Flock Adhesives Odorless; Lowe Odorless; Lowe 7.1*0 LINOLEATES *(51*3) 1.2 Manganese *(37l*) (13 Lead . . * 1 Manganese NAPHTHENATES 3l*.5 A bh A Ifl Dark 7.00 8.00 *(1*090) 21* Lead *(9Cl6) 21* Lead - *(1*230) 10 Lead *(1*091) 6 (9C21) 6 *(9Y1) 6 Manganese Manganese Manganese *(1*231) 2 Manganese *(1*092) 6 (9C22) 6 (9T2) 6 Cobalt Cobalt Cobalt *(1*232) 2 Cobalt (3230) 6 Iron (9Dl*) 6 Zirconium 7$ R-W 13 100 2l*0 17 Hi Flash; Cut:'in oil 9.90 10.61 9.58 32 A1 11 7.50 $7 A-K 70 A-B 60-70 A-K 16 18 16 7.73 Restricted Source 7.98 Rejected (1*091) for (1*231) 8.20 20 a 5^a i 16 6.8? 56 Alt Dark 70 Al-H Dark Restricted Source 7.93 7.98 A-B Dark Rejected (1*092) for (1*232) 7.85 16.8 Al*-A Dark 80 J 28 A Dark 1* Acme Automotive 6.95 8.37 7.1*0 (9D71) ,13.5Lead ' 0.1*8Manganese Acme 8.1*6 9A70 /21 lead 'it Manganese Paste L.O.H. 8*62 * S-W Manufacture Note: Flash point of all liquids is 10f>F. Minimum, TOC, unless otherwise stated. 0007-PMC-000000185 Number % Metal OCTOATES *(9A9) 2U Lead (9C7) - 2U Lead (9A1U) 2U Lead <9A10) 10 Lead (9C9) 6 Manganese (9A71) 6 Manganese (9C8) 2 Manganese <9567 6 - (222U) 6 (9A6U) 6 Cobalt Cobalt Cobalt *(9C18) 2 Cobalt (9TU) .'2 Cobalt MISCELLANEOUS (993) UU Lead (Uo66) Color NVM Body Gard. % GHT Max. Remarks 60 A-B 10 63 Aii-c 7 5U 3 Std.' Odorless 30 A5-A 10 UU A-D Dark i U5 Odorless IS Dark 37.7 A2 16 B Uo Purple Purple Purple Odorless lU 1U.U Purple Purple 79 Paste Gray Nuact Paste 30 Gel 6 5/6 Nuade Page 9-3 May 15, 195U #/G 75f . 8.90 9.17 9.33 7.5 7.5 7.5 6.81 7.U* 7.58 7.U7 6.73 6.86 13.9 7.0 ifS-W Manufacture Notes Flash point of all liquids is 105F. Minimum, TOC, unless otherwise stated. 0007-PMC-000000186 Page 9-1} May 15, 1951} Remarks lead naphthenate is widely used as a polymerization catalyst, promoting through drying.' It must be used in combination with either cobalt or manganese, in order to effect a tough, resistant film. It cannot be used with aluminum paints because it destroys leafing properties# Cobalt naphthenate is generally used with lead to promote rapid surface drying. Excessive use will promote wrinkling, particularly on baking# Manganese naphthenate is regarded as an intermediate drier, having somevhat of an affect on both through- and surface-drying properties. It must be used carefully in white paints as a pink stain may develop# . Use is primarily in baking finishes. 0007-PMC-000000187 pa~e 20-I R. D. Eolrir-er. Cl'ir-o, 111. An-ust 11, 1-2. C!"ss 1000 thru 1099 - Phenolic Compounds and their met"! compounds, inclndi:''halo~en substituted, divided into the followin'- subclasses 1000 - IOC? - Phenol 1.010 - 1019 - Cresols and Xylenols (Cresylic acids, etc. 1 and er-rl 1020 - 1029 - All other PllrfL and aryl phenols l'**'''- - 10* 9 - Phenols, halo-enated (chlcro phenols) 10':o - 10"o - K-phthols 105-0 - 1069.- Dihydric phenols (hydroquinone, hisphenol, etc.) XO^c - 109? - Miscellaneous phenois not previously covered. 50 . c some of the materials in this class are used as fungicides, we quote the 'Vllcwin- from R. fc P. Bulletin # 1*4.2 dated March 2*t, 1?5>0: * X. The followin'* has been received from the Industrial Sales Department: Cenerallv spealdLn", on any material cornin'" under the Federal or State Insecticide. Fun'd.cide, and Rodenticide acts, the Technical Department will assume responsibili+v- for technical preparation. The Technical Department will then furnish information as to label ara-lvses, directions for use, and precautions to be observed, in use and handlin'; of product -rd finished product. The Sales Dep~.rtmoat "Till then nrcnaso final l~bel ccay to ve *arrc"e'" >v le "1 and technic-l 2. This mlir applies to such products as Kenwood Se-lers, Wood Prsser*"t5/'es, ~nd St'inc th't have incorporated into them certain poisonous or toxic components.n 0007-PMC-000000188 10-2 August U, 19?2 Humber Prev. Ho. _ Hame (10C2) (locli) (io a ?) 10C3 10C1 (307U) (1*071) (889) 187U Synthetic Phenol 1, 3, 5, Xylenol Cresylic Acid Para Tert. Butyl Phenol Octyl Phenol 196U (ion) lOClit (lopit) 07733 2260 Pentachlorophenol, Tech. Fentachlorophenol Sol. Ha Pentachlorophenate Toxic Preservative 20?2 (2231) (10T1) W110? Tetrachlorophenol Tetrachlorophenol Sol. Tetrachlorophenol Sol. (10A3) 10C1? 10C6 1061 (306?) AV273 2210 21m lOAlt HV1283 Beta Haphthol Sol. B-oxy Naphthoic Acid Bisphenol A Hydroquinone Hydroquinone Sol. IOC? (1082) (1767) 10C13 CH2800 (1761;) 171? Dichloro Diphenyl Dihydroxy Methane Tech. Guaiacol Guaiacol Sol. Sodium Ortho Phenyl Phenate Tetrahydrate Melting point F S.W.Method 10U h?U.?l 206-210 1*&.?1 161-16? 3ti? 1;?U.?1 120-1?6 l*?l*.c 302 U?U.?l 33o approx. 3?1 approx. Body Liquid Liquid Flakes Flakes AFlakes A- Flakes AB A- Flakes Crystals A- Powder AAFlakes 0007-PMC-000000189 10-3 August 11, 1952 Color Lt. Pink Dark Pale White White Dark Buff 12 Tan 10 ll* 6 Lt, Yellow Cream White WW Off-White 10 10 White HVM 100 100 100 100 100 100 U1 100 1*3 100 20 100 20 100 100 100 9.2 100 loo 18.3 100 Solvent Hone Hone Hone Hone Hone Bulking Value Gals/lOO# 13.2 12.75 Flash Point F TOC #/Gal. 975F 8.92 8.1*2* 8*60 Hone (2650) Hone 79(31*8)12(1*021)9(2003) Hone 5o(l*oli6)5o(3l*8) (2) 75(1*01*6)25(1167) None None None (1168) ll*.l 3l*.0 H*.3 33.3 8.1* 10* 9.61* 7.85 7.60 9.37 7.1*3 '35 7.62 None None ..(31*8) None 18.6 8.95 105 6.83 Number (10C2) (loci*) (1Qa 5) 10C3 10C1 1961* (ion) lOCll* (10Pl*) 2052 (2231) (ion) (10A3) ioci5 loc6 106l (3065) loc5 (1082) (1767) 10C13 0007-PMC-000000190 Pore 10-U August 12. :52 noc2) (locii) IOC3 10c6 lv6t ) (10T1) ) ClOYU) ) 10C13 ) 10C1>4 ) ICC*? ) 20?2 ) (2271) > J (10T1) ) ''10A3) 1061 j (306?) / (1062) / (l7 67) ) 10C1 Used in Used in Used in Used in Remarks and U310. Used in the manufacture of wood preservatives. Used as emulsion preservatives. Used as Used as "as-checking and wrinkle inhibitors. Used as anti-skinning a~ent. Stabiliz: er in cable lacquers. 0007-PMC-000000191 CLASS 1200 Esters of Monohydric Alcohols and Monobasic Acids Page 12-1 E. Kulish Chicago February 3> 1955 1200 1219 1220 1239 12U0 12U9 1250 1269 1270 1289 1290 1299 Volatile esters with initial boiling points (AS'EM D-1078) up to 100C. Volatile esters with initial boiling points (ASM D-1078) above 100C. Mixtures of volatile compounds which contain a substantial fraction of volatile esters (many "thinners" for N/C and other lacquers, vinyl coatings, etc.). Non-volatile esters derived from alcohols of Ci through Cq . Non-volatile esters derived from alcohols of C9 and higher. Open. 0007-PMC-000000192 Page 12-2 February 3 1955 Material Number (1202) (12C13) (120U) (12C6) (1222) (12C7) (1223) (l2Al) (12F1) (1225) (123U) (1232) (12C19) (12P1) (12C18) (12C17) (12C25) (12C2li) (12C23) (1252) (1253) (12F6) (12F5) (12U2) (12U3) (12F2) (1213) (12DU0) (12C22) 12C9 1272 12C16 12C8 (12C11) 12C20 12C12 Previous Number (1168) (2611) (1170) (1670) (1769) (262U) (20U6) (2688) (1868) (1616) (1617) Material Ethyl Acetate No Propyl Acetate Isopropyl Acetate Propyl Isobutyl Acetate N. Butyl Acetate Isobutyl Acetate Sec. Butyl Acetate Methyl Acetate-Methanol Methyl Cellosolve Acetate Amyl Acetate Cellosolve Acetate Methyl Amyl Acetate Butyl Lactate Butyl Carbitol Acetate Butyl 2,h-Biehiorc-phenoxy acetate Butyl 2 j, U,5~Trichloro~phenoxy acetate Vinyl Acetate Isc-octyl Ester of 2,ii D Technical Butyl Stearate Butyl Stearate Hercolyn Hercolyr. D Plasticizer KP-120 Solvent Blend Solvent Blend Recovered Lacquer Thinner Lacquer Wash Thinner Lacquer Thinner Camauba Wax Solution (20^) Camauba Wax Beeswax, Pure Emulsowax 12lU Petrolite Crown 36 Emulsion Wax Crown #15 Emulsion Wax 1530 0007-PMC-000000193 u h im;., Distil. Rang C. Test Method U30.3 72-80 93-105 8U-90 105-121* 115-130 110-119 103-115 55*65* 137-11*7 110-155 11*5-160 138-11*5 165-190 235-250 Flash Point F. - T.O.C. Test Method 1*29.5 l*o 63 51* 100 90 85 30 132 93 150 113 176 2U0 200 23 360 370 361 Sp. Or. Wt/fcal. 75 F. 75 F. Test Method 1*01.2 0.898 0.877 0.866 0.870 0.873 7.1*9 7.31 7.22 7.25 -7.28 0.862 0.859 1.003 0.858 7.18 7.15 7.U 8.36 7.11* 0.970 0.855 0.979 0.975 1.237 ll332 1.136 0.862 0.853 8.08 7.11 8.16 8.13 1.031 lino 7.79 9.U7 7.18 7.09 1.017 1.017 0.961 0.831 0.808 8.1*8 8.U8 . 8.01 6.93 6.7l* 0.837 0.836 0.885 6.98 6.97 7.37 0.957 0.981* 0.968 0.968 1.056 7.98 8.20 8.07 8.07 8.80 Page 12-3 February 3, 1955 Bulk Gal/100# Soft Point F. Test Meth. 1*51.12 Material Number (1202) (12C13) (I20li) (12C6) (1222) (12C7) (1223) (12A1) (12F1) (1225) (123U) (1232) (12C19) (12P1) (12C18) (12C17) (12C25) (12C2U) (l2C23) (1252) 12.0 12.5 12.2 12 .U 11.u 82 Hill 162 180 180 181 (1253) (12F6) (12F5) (12U2) (12U3) (12F2) (12Y3) (l2DliO) (12C22) 12C9 1272 12016 1208 (12Oil) 12020 12C12 0007-PMC-000000194 I Page 12-U February 3, 1955 Remarks Because of their high solvent power for nitrocellulose, the esters are extensively used as an ingredient of nitrocellulose lacquers and other "types of pyroxylin coatings. A blend of fast and medium boiling esters with appropriate alcohols and diluents yields thinners and solvent mixtures of excellent solvency and blush resist ance, good flow and leveling, and compatibility with various resins and oils. Esters are also solvents for camphor, mineral and vege table oils, natural resins, and many synthetic resins. Ester, kauri, manila, pontianak, and dewaxed damar gums dissolve completely in most esters; shellac is partially dissolved; gum rubber is softened but not dissolved. Butyl Lactate is not subject to auto-hydrolysis and is not hygro scopic. Although it is not a solvent for cellulose acetate, solu tions of cellulose acetate containing butyl lactate deposit clear films on evaporation. Butyl Stearate is a stable oleaginous material used in the manufac ture of polishes and in coatings which are to be polished and is used as a lubricant in molding synthetic resins. The waxes in this group are used in furniture cream, self-polishing wax, household wax, and many other such products. 0007-PMC-000000195