Document NyKKLdRV60EDM7aa1d2J19GV

Caustic Plant 1986 Industrial Hygiene Annual Report Summary The results of previous years' industrial hygiene surveys were evaluated and present problems were identified. Based on the results of the sur veys , it was discovered that the exposure levels did not change over the past few years. Therefore, yearly surveys will be conducted only in problem areas. Several years of study on caustic exposure revealed that the operators were exposed to levels well below the TLV limit. The hydrochloric acid exposure is extensively controlled at present until the plans to improve the iron cell area are executed. Noise studies over the past several years revealed that most personnel samples were within allow able limits, but several area samples were high. Problem areas will be focused on for future plans which include the high exposure level of caustic and hydrochloric acid in the iron cell area and the high level of noise still in the plant. Conclusions and Recommendations 1. Personnel exposure levels of caustic were well below the TLV ceiling limit as a result of several years of study. Based on these results, it is not necessary to perform personnel studies every year except in problem areas or if there is a process change. There are a few potentially high caustic exposure areas that need to be evaluated, such as the iron cell area, the centrifuge seal areas, and the recirculation pump packing leaks. Even though these areas do not exceed the allowable TLV, these are the only areas left in the plant that provide any exposure of operators to caustic. These pro blems will be addressed in 1987 plans. 2. The potential of exposure by the operators to hydrochloric acid is high in the iron cell area when the cells are being acidized. The operators are informed of the problems and presently take specific precautions to avoid exposure to the acid. There is no need to perform surveys in this area every year unless changes are made, since this is the only area where the acid can be found. Future plans include process design improvments to the iron cell area to eliminate exposure to the acid. 3. Area noise surveys of the plant did not reveal any significant changes in noise levels. Because of this, whole plant surveys are not needed on a yearly basis. Only problem areas or areas where process changes occur need to be analyzed. The high noise level areas of the plant are properly posted with ear protection warning signs and the location of these areas are properly communicated to all operators. TBS 4/3/87:mls Page 2 Caustic Exposure Evaluation Sampling Method and Guidelines The caustic that operators may potentially be exposed to In normal operations is 50% regular grade caustic. The American Conference of Governmental Industrial Hygiene (ACGIH) Threshold Limit Value-Ceiling for sodium hydroxide is 2 mg/m , The threshold limit value is the time-weighted average concentration for a normal 8-hour workday and a 40-hour workweek to which all workers may be repeatedly exposed without adverse effect. However, the ceiling is the concentration that should not be exceeded during any part of the working exposure. The method of sampling involved at least one sample per classification taken over an eight hour period. The personnel samples were obtained from the operators breathing zones and represent actual exposures as nearly as possible. The samples were pulled through a milipore filter size 0.8 micron at a rate of 2 liters per minute using a three piece filter at the end of a high flow pump. The pump should be calibrated with a rotometer to 2.0 liters before and after all readings are taken. Personnel Monitoring As shown in Attachments 1 to 3, the results of three years of studies, all exposure levels were well below the TLV ceiling limit. Based on the results of these studies, sampling for caustic this year was not deemed necessary. Area Surveys The areas with the highest potential of caustic exposure at present are: the iron cell area, the centrifuge (CF-1) seal areas, and the recirculation pump packing areas. Plans are in effect for 1987 to improve the iron cell area and practically eliminate all caustic exposure. Chlor-Alkali II will be implementing a seal modification on their centrifuge in 1987. If this modification works, then the Caustic Plant will also Implement the seal modification. Plans for 1987 also include mechanical seals in place of packing for the recirculation pumps. At minimum, the causes for packing leaks are being investigated. Hydrochloric Acid Exposure Evaluation Sampling Method and Guidelines The AC^IH Threshold Limit Value for hydrochloric acid is a 5 ppm or a 7 mg/in ceiling. The threshold limit value is the time-weighted average concentration for a normal 8-hour workday and a 40-hour workweek to which all workers may be repeatedly exposed without adverse effect. However, the ceiling is the concentration that should not be exceeded during any part of the working exposure. TBS 4/3/87:mls 0fo936 DO ^ ad CO^F"1 Page 3 Hydrochloric Acid Exposure Evaluation Sampling Methpd and Guidelines (cont'd) Since hydrochloric acid is used in a batch process, the sample is taken as an area sample whenever the iron cells are being acidized. The air was tested for hydrochloric acid by using the impinger method over a 3-hour sampling period. Area Monitoring The only area with the potential for hydrochloric acid exposure is the iron cell area. When acidizing the iron cells, the hydrochloric acid is routed to open trenches. A survey was not done this year because this is a known high exposure area and is the only area possible for HC1 exposure. Presently, when the iron cells are acidized, an announce ment is made in the block to clear the area until the acidizing is com pleted, and it is usually done on the night shift to reduce potential exposures. Plans for 1987 include process design improvements to the iron cell area which will completely contain the acid in a piping system. These improvements will provide a more controlled means of containing HC1 in the block limits and then releasing it as needed. Also, new hoods will be placed on the iron cells that will aid in re ducing acid exposure. Full face masks are required when acidizing the iron cells. Noise Exposure Evaluation Method and Guidelines An Edmont Sound Level Meter type S2A was used to measure employees' exposure to noise and was also used as a sound level meter to measure area noise levels. The sound meter meets all current requirements established by U.S. government agencies. All noise measurements were made using an 80 and 90 dB(A) threshold level and a 90 dB(A) criterion level. The threshold is the level that noise must exceed to be in cluded in the dose calculation and the criterion is the decibel level that will yield a 100 percent dose in eight hours. The 90 dB(A) cri terion level is an OSHA regulation, but the Louisiana Division cri terion level is 85 dB(A). To obtain this dose level, multiply the allowable exposure limit by two. The sound meter was calibrated with an approved acoustical calibrator, the Edmont Sound Calibrator model 60-535, before and after all measurements were made. Personnel Monitoring Since ear protection is required to be worn in all high noise areas (above 85 db(A)) of the plant, the noise doses that were detected were potential doses. The potential doses are those the operators would have been exposed to if hearing protection was not worn. A noise survey was not performed this year because of the results of the previous years' studies and since no process changes were made. TBS 4/3/87:ml 106939 C0^.TDErnttal Page 4 Noise Exposure Evaluation Personnel Monitoring (cont'd) In 1980t three samples were run on each job classification and showed that all jobs were within the allowable limits. A 1982 study revealed that all samples were within allowable limits. Six samples were taken each in the evaporator and finishing areas for the SOT classification and four for the 0T classification in the loading area. In 1983, four samples were caught: Two in the finishing area and two in the loading area. All samples showed minimum exposure. In 1984, only one sample from the finishing end exceeded the allowable limits. Personnel monitoring was not performed in 1985. Data from these previous studies are available in Attachments 1 to 6. The average potential exposure from 1980 to 1985 has been 22%. Area Surveys Area noise levels were measured over the previous six years as seen in the appendix. The high noise areas (greater than 90 dBA) are the evaporator area: E-201, E-202, E-203, E-204A, HE204: the air compressor area: AC-301: and the river water pumps P71A, P71B, P71C, and P71D. All of the high noise areas listed above are designated ear protection areas. The perimeters of these areas are posted with high noise warning signs. All employees are informed of these areas annually in the safety meetings. Sample Strategy Future Plan Hazard Caustic TyP-e Personnel // Samples 16 Quarter 4 th Comments Before and after work on iron cells HC1 Area 4 4th Before and after work on iron cells Noise Personnel/ Area 16 3rd Identify source of noise TBS 4/3/87:mls DO 106940 C0NFXDFNTIA1 Page 5 Accomplishments in 1986 1. A high level alarm was installed on T-203, the hot salt settler tank, to prevent 50% caustic from overflowing over the top of the tank. 2. Two leaking iron cells were completely changed out with two brand new cells. The old cells were so badly corroded, they were scrapped. 3. The ejector on the iron cell venture scrubber is regularly cleaned to improve the efficiency of capturing all mists and vapors. 4. An overhead carbon steel steam line, that sometimes has caustic in it, was replaced with nickel pipe. The carbon steel line kept leaking, but the nickel piping will be a permanent repair. 5. Condensate is now being used instead of brine in the salt column to reduce corrosion. 6. The drain on the steam line to the evaporator evacuation system is routed to the ground to reduce the potential for exposure to steam/ condensate. 7. The use of a new kind of impact wrench reduces physical strain on the operators loading cars. 8. The vent on T-204, the salt settler, was modified to reduce expo sure to caustic mist. 9. Sections of the carbon steel brine line was replaced with lined pipe as a permanent solution to leaks in the line. 10. The monogoggle area was extended past the parking lot to the front office. This area is marked by a big yellow line. 11. Operators are required to wear a full slicker suit and face shield when opening pumps to reduce exposure to caustic. 12. The valve handles were repositioned on C-202, plug valves were in stalled in place of gate valves on T-205 for better handling, pump platforms were Installed in the evaporator area. All of the above were done to reduce physical strain. Goals for 1987 , 1. The iron cell area will be improved to reduce caustic and hydro chloric acid exposures. 2. The pumps to T-205 will be relocated so that the pumps can be ac cessed if T-205 overflows. The pumps are located directly under neath T-205 and they must be accessible to stop the further over flowing. Relocation of the pumps will also make them more reliable. TBS 4/3/87:mls DO 106941 CQNFTDETNTTAI Page 6 Goals for 1987 (cont'd) 3. The Installation of demister pads on T-204, T-205 and D-205 vents will catch caustic vapors leaving the vents. 4. The best method to stop recirculation pump packing leaks will re duce exposure of operators to any caustic leaking through the packing. 5. The evaluation of a seal modification on the centrifuge at ChlorAlkali II will determine if the modification will be used on Caustic's centrifuge. TBS 4/3/87:mls 106942 CONFIDENTIAL December 31* 1980 ATTACY\rf\ f^T L All Caustic Plant Personnel ENVIRONMENTAL HEALTH SURVEYS FOR NOISE AND AMMONIA AND CAUSTIC IN THE AIR Belov is a summary of the surveys vhich were conducted during the month of December. The ammonia samples are area samples which were-run for three hours at a time. Eight different samples were caught. The TLV for ammonia-is 18 mg/m^. The lowest sample caught was .367 mg/m3 while the highest one was A.Ill mg/m^. The caustic samples were personnel samples run for one hour periods. The TLV for caustic is 2 mg/m3. Three samples were caught on each classification. SS OS SOT - Finishing SOT - Evaporator OT High .034 .023 .016 .034 .023 Low .006 .010 <.004 .009 .021 The noise results are expressed as a percentage with 100' being the maximum allowable eight hour exposure without any hearing protection. Three samples were caught on each classification. SS OS SOT - Finishing SOT - Evaporator OT High 7 21 15 28 17 Low 1 1 2 22 14 As you can see, all of our jobs and areas within the allowable limits. -If you have any questions about these surveys, please see me. Please sign and date this letter and return to me. w/ B. J. Prescott Environmental Health Representative lne I have read, this letter ____ ^ ___________________ _____ _____________ Please sign and date and return to me. DO 106943 CONFIDENTIAL FILLED IN BY_ ~t& 77to - PLANT Cjh/mc IHCHIU'CMT TfJL * LOYEE EXPOSURE SUMMARY QUARTER ^rud YEAR / 9 8*0 BLOCK C/tuST?c.STRESS MINIMAL DETECTABLE LIMIT AND UNIT DO 1 0 6 9 4 4 CO NFIDENTIAL PERSONNEL AREA EXCURSION JOB CLASS orr- AREA/ TASK OT SOT OS ss iBt Fw*irf * *PT. TWA NO. SAMPLE EQ. BASIS SAMPLES AVG. HIGH DURATION Y\fiWL YW YlBAH- tm r 3 3 3 .o/7 .oo~7 .Gib 3 .&(ff .ah NO. SAMPLES LAB TECH CLER. * INSTR LABORER i SUMMER EXCUR. NO. AVG. HIGH DURATION SAMPLES AVG. HIGH i il CONT MAINT NON-OS SPEC. SECUR. MATL CONT 1 LOADING T/C CLNG KCRS/NON OP AREA SAMP Vno jc> ** * 1 * .g, t%sc'a'yf FILLED IN BY PLANT Ca-usTi C ATTACHMZHT -to B> EMPLOYEE EXPOSURE SUMMARY QUARTER S/2 cl % (jon-%60^ BLOCK / MINIMAL DETECTABLE STRESS f\/AfS LIMIT AND UNIT YEAR l3M PERSONNEL AREA EXCURSION JOB CLASS AREA/ TASK OTT OT SOT RVfir? OS SS 6Sfrn(j 1 H" *PT. EO. s TWA BASIS s S' & NO. SAMPLES 3 3 X 3 AVG. /$ n S' 7 SAMPLE HIGH DURATION n, 2l 7 ts* NO. SAMPLES EXCUR. NO. AVG. HIGH DURATION SAMPLES AVG. HIGH \ LAB TECH * CLER. INSTR LABORER SUMMER CONT MAINT NON-OS SPEC. t SECUR. KATL CONT i * LOADINC T/C CLNG * MGRS/NON OP - area samp fun' tr^ \ u) Y a ) c-t 5 1 1 , ATTAClVNACMT 1982 INDUSTRIAL HYGIENE SAMPLE RESULTS Hazard Noise VV II II II II II II II II II II II II II II II II IteGH ii i ii it ii it ii ti ii it it ii it ii ii . ii Ammonia 11 II HC1 Classification Sample (%) Area Comments SOT 11 It II 11 II II II II II II II II OT II II It II SOT II II II II 11 II II It II It 11 OT II I II II SOT Area 11 II 28 Evaporators 64 17 37 89 10 29 16 19 13 5 5 5 5 11 1 1 1 .016 /& 11 II II II II II Finishing 11 II II II II Loading II 11 11 II 1 Evaporators .015 .01 .01 .01 .017 .01 .01 .01 .028 .01 .01 .011 .015 .01 .01 wJ-01 It II II Finishing II II It II It Finishing Loading II 11 II It (120 min) 1.7ppm (125 min)111.Oppm (120 min) 4.2ppm (180 min) 0.8ppm (180 min) 24.4ppm Finishing Purification II Upwind Downwind 100% is equal to an 8 hr. TWA of 90 dba Sample duration 6-8 hrs. TLV * 2mg/m Ceiling Sample duration 6-8 hrs. TLV=2mg/m Ceiling TLV25ppm (v/v) 0SHA 8h T.W.A.-35ppm (v/v) 3 TLV-5 ppm or 7mg/m ceiling. 00 106947 CONFIDENTIAL Attach 3 1/5/83 ALL CAUSTIC PLANT PERSONNEL INDUSTRIAL HYGIENE SAMPLES AND RESULTS FOR FOURTH QUARTER OF 1982 CAUSTIC - TLV is 2 mg/m3 Four samples caught. ,, Evaporator area (2) both less than 0.01 mg/gi . Finishing area (2) both less than 0.01 mg/m , NOISE - TLV is 85 dBA for eight (8) hours. If operator stayed eight (8) hours in 85 dBA area, sample results would read 100%. Four samples were caught. Finishing area (2) both 5%. Loading area (2) both 1%. Industrial Hygiene Representative mis The industrial hygiene samples and the results, for the fourth quarter of 1982 have been discussed with me. PLEASE SIGN AND DATE 00 106948 confidential JUNE 25,1984 ATTACMM feMT -*t 4- ALL CAUSTIC PLANT PERSONNEL BELOW'IS A SUMMARY OF THE SURVEY WHICH WAS CONDUCTED DURING THE WEEK OF JUNE 18, 1984. THE SAMPLES ARE GIVEN AN A PERCENT OF 100. EXAMPLE - IF AN OPERATOR WAS EXPOSED TO 90 dBA FOR EIGHT(8) HOURS, THE SAMPLE WOULD READ 100%. IF THE OPERATOR WAS EXPOSED TO 90 dBA FOR FOUR (4) HOURS, THE SAMPLE WOULD READ 50%. EVAP. AREA FINISHING END IOADER SHIFT SUPV 76% 29% 0% 15% 0% 109% 26% 36% 0% 51% 55% SAM BOUDREAUX SAFETY/TRAINING/ENVIRONMENTAL no 106^50 confidential ^TTACMMEOr 4*4 CAUSTIC PLANT NOISE SURVEY JUliE 19&4 8KE WOULD LUCE TO GET A H01SE SAMPLE FOR A DURATION OF WEAR THE DOSIMETER FOR THE DURATION OF THE TEST. HOURS. PLEASE TIME CARTRIDGE DATE START STOP NUMBER ms 026<mn * | f-'/f' , , /v (FRONT) */ E.O.T. (,-n ms oi/ 03 59 3 rft / f+ . / O.S. (BACK) S.O.T. (FRONT) S.O.T. kit ObOV Ifco kit Oloo nilco o53o-/? 3. o<i O /g 37 l/l/ ^ *? -5 O.T. i-/y 3000 o$3& *ht. &x. . (BACK) / E.O.T. Cso cooo (, 3 7^ f) O.T. 'oOo O'Vo 030 97 NAME * RESULT |5?0 W ?6f. fact: OCmlL^ les^g- tho/aas ri8?a *2.4% 7+-C v/-9 A '/a 51* **. J1 JfigA. <f )OoU>eo ua f4 0% 0% 10 9g 75& IfaZE'OT_______ l(*% / / / / S SAM BOUDREAUX SAFETY/TRAINING DO 106951 DONFIDfr/vriA/ Attach mt CAUSTIC PLANT NOISE SURVEY JUNE 1984 WE WOULD LIKE TO GET A NOISE SAMPLE FOR A DURATION OF WEAR THE DOSIMETER FOR THE DURATION OF THE TEST. HOURS. PLEASE TIME CARTRIDGE DATE START STOP NUMBER NAME RESULT (FRONT) S.O.T. aaflL (BACK) S.O.T. (FRONT) S.O.T. O.T. (BACK) S.O.T. O.T. km o-n/tj Dtyi tatty l?oo )$0D mo /S' 3? fv/ *39 2,7/Z/df<r 36 -& Qf/cht'd'Cllrtty {(J/orf*/ ) ^ SAM BOUDREAUX SAFETY/TRAINING DO 106952 CONFIDENTIAL AttachMthir #5 g. 8.. cj i/5~ coMpieTeb a t^ofs<p (m T(+ CauspV pC^nT; '=b*(i*n $ R-lj 5c~(ZS&RSt ATTAcIAGO is '774-E R loth- T&e /j(P(SG /"?/?vfsr C< a.jD(F/2-L/sv.D . S/6m$ co Ul &<G PuT Ujp / AJ ( AAfc AJ <5 /T-/2-- /--CV 7"V/2c j & Lf T~ Cr OC-/L>-^ c5 /U<? tO G&~-Ps TO f><P ?9-ts/4r2G' &F TfrS Ri?cacC>rr s9-/Z~ey9-5 /}svD UJ&&/Z- ~/-M?// J-T /ZA/u& p/?oTcT*& *J /9S Qut/2Si>. *^TCn^ ^3\ 4Jl<4 f^O/SC? frfltflS 1 - flc. 3a f Z- 00 0<r<7 3 V-^-i "`o V- P 7,1 f 'a i'- (Z **-> pu*if>s 6 ~ c C. u $(Ai$ f/vip-fcli uljQSAJtti- "7 ' f * P-7^r'p z AaZfi'ts /6 *- e - "2*W 4 ^ ,is^ DO 106954 CONFTDFNTrAL. CfiU6,fL >1 o' /IFH wb / \ r*. w * * \ hioise SURVEY AttachSA 2.05 ] 3 00 89 ?r fo 9 &*/#) ss ' 93- <97 T)Ov*J M 0? ^2^4<rMp'<~? ?3 ^ <9/ F ROklT OFFICE. 4 a FtnuirJ&s I|0 DBA DO 106955 CONFIDENTIAL I AREA ~B Moise suRsiev Arr^CHKAtor **= I *4 c5c CAus'i't $<f5,ooo *t 5 Ttrirt < i *- 'VP# <0 vUitvO AIL iW' DBA DO 106956 CONFIDENTIAL j I ' lcI( IJr * it n ? Ih m j IID ? 1* Mhil m1 1I} i Jt l(Ut ) Mi r il tl fl No\se suRMev AREA C a. attach wtur 4i se FllB F* l ID 6S F-tllA F-EI1C. s'-e-8</ ChucTic "0** JfP# o/#C> T-e.i ) 'k8 [ t-^8 555 ? k ( 9n/sn Ti -e^ T^MICTRUCIC LoADIklb BAC TAnJVl CAR. LOAD) Mb R>OL kLU i4 DBk ______________ ^ Dovj ., V4 DO 106959 CONFIDENTIAL MUI l fvvnirlOiOn tl' tf ( ltfiWut hilHHl fti Mcail 0( tliiclti {I ( Ct AK.c.n /-v Attach tAfcWT #6 N'Qi-SE SURVJE^ JL. *W- /a -/t'-f'S' g'a. L M. JC &L i3l 1/e-j.vtP, tf 2. Jr?> Ik Fromt off ice DeuJ All DO 106961 CONFTDFNTIAl (N ALL DBA ! i I AREA fl__________ I go-- __________ _ kmcMAeuT* fee i i t it#/Ac, /D?r jzi i2L| TKvnCTHOC c LoADIklb RACK, TAhJK. CAR. LOADING R.ACK M.L ______ _X Dovj \si DO 106964 CONFIDENTIAL 1ST Area 5 %3z ( HE.-EJ'S ~) <// i i 1 i i 1 DO 10696^ CONFIDENT IAI. 1 AR FA fl 7(, FllB f- ana f F*IIA F-BI1C )j& h iM i- ll I i I I hi :il u Tl'iViK-rtICCKI . LoAbnJb RAC*C TAMk. CAR. LOAtrJl> X DOVJ Kj DO 106968 CONFTDfTNTIAl ^____________ p0viJ N1 I 7#7#GSFtlAVE BATON ROUGE. LA 70608 4 Q*~> DOW CHEMICAL COMPANY Plaquetnine, Louisiana January 23, 1987 One (1) filter cassette sample was received at West-Paine Laboratories, Incorporated January 6, 1987 for the analysis of asbestos content. This sample was analyzed by scanning electron microscopy (SEM) at a magnification of 2,000X to determine the size and quantity of fibers present. Each fiber observed was identified using energy dispersive x-ray spectrometer (EDS) analysis according to NIOSH method 7402. The result of this analysis is listed on the attached data sheet. r> Microscopy Laboratory Supervisor ^WEST-PAIN E Ja&oycLtoxijeA inc. M 797 GSRI AVE. BATON ROUGE, LA 70820 SAMPLE ID: 07413 This sample could not be quantified due to the high concentration of fiberous and non-fiberous organic material present. Four (4) photomicrographs were taken for illustration. A log for these pictures is provided below. Cl) Secondary electron image at 500X showing several large and small organic fibers. A high concentration of non-fiberous organic and inorganic particles are also present. (2) Backscattered electron image at 500X showing the same field as shown in photo #1. Inorganic particles exhibit high contrast bright images. Organic particles exhibit low contrast subdued images. (3) and (4) Secondary electron images at 2000X showning two fields of organic fibers. / DO 106971 CONFIDENTIAL / I i i C0O0NFl0IDfeEMNTTTIAALl 4 * / ;l D0 106973 confidential 4 OB-Aua-86 7i19 FM 2n O M S-*. nOi o 2H vj 2> Worksheet: (17) HH INVENTORY Rfdloni A1..E17 IHA2ARD0US MATERIAL 1 1 |ACETIC ACID |ACETONE | ACETYLENE > (AMMONIUM HYDROXIDE, >12% AND <44% AMMONIA |AMMONIUM FLUORIDE 1 AMMONIDH ACETATE |ARGON, COMPRESSED 1 BORIC ACID 1 CARBON DIOXIDE 1 CHLOROFORM 1 COFFER CHLORIDE IF001- RCRA HASTE NUMBER (FERRIC CHLORIDE SOLUTION (FERRIC CHLORIDE, SOLID IHELIUM, COMPRESSED 1HYDROCHLORIC ACID 1ISOFROFANOL (LEAD NITRATE (LITHIUM CHROMATE IMERCURIC THIOCYANATE 1 HEP CURIC IODIDE 1 METHYL ALCOHOL (HETHYL ISOBUTYL KETONE 1 NICKEL (NICKEL SULFATE INITRIC ACID, >40% (NITROGEN, COMPRESSED I0IL: LUBRICATING I0IL: MOTOR 1 OXYGEN, COMPRESSED (PAINT RELATED MATERIALS )FETROLEUM ETHER (FHENOL (POTASSIUM CHROMATE IFOTASSIUM IODIDE (PROPANE (3ILVER NITRATE 1 SODIUM CHLORATE 1 SODIUM HYDROXIDE, DRY SOLID 1 SODIUM HYDROXIDE, LIQUID |SULFURIC ACID ITHIOCLYCOLIC ACID |TOLUENE 1 ZINC CNLORIDE SOLUTION 1A1 B 11 1! 1 1X 1 1X t 1X I 1X t !X 1 tX 1 1X 11 1 1X 1 1X 1 1X 11 1 1X 1 1X 1 1X 1 (X 1 1X 1 1X 11 11 1 1X 1 1X !1 1X1 11 tX1 X 1 1X 1 1X 1 1X 1 1X 1 1X t 1X 1X1X i 1X 11 1 1X 1 1X 1 1X 1 1X 1 (X 1X1 X 1 1X 1 1X 1 1X . ' /' ?'' / ' I ,, ' f 1 rJ ' Fao*! 1- 1 lfl-Au<J-H6 7(19 PH lorkaheet t (17) HH INVENTORY Redloni F1..H47 c1ni 'l I 1t X 1X1 X1 X1 !xI XtxI X tx I X 1 xI 11 1x( x1 X 1xI X1XI X1 \ X xI X1xj 1 X1XI 1X( X1X1 X1 1 X1 1 1XI X1XI X1XI X1 1 11 X1 XI I1 1X1 1 X1 ( I1 1I X1 X( X 1 X1 1x1 Ix1 X1xI 1X1 X1xI X1x X1xI 11 X1xI X 1X1 i 1 j t 1 CODE AAC ACT ACE AMH AFR AAT BAC CDO CRF CPC FCL FCL HCL I FA LNT MID MAL MIK NAC OLB OHT FHN FCH FT I PRP SVN 5DC SHD SHD SPA TOL ZCL t QUANTITY 1 11 11 | 91 | 6001 | 2601 | B31 ( 2| | 11 1 350 1 ) 21 ) 901 | 16| | 11 1 1200) | 1! | 2| | 30| | 150001 | 41 | 1] | 401 1 1) ( 11 ( 141 ) 4| 1 11 1 11 | 1B4( 1 7641 | 5000( | 501 1 5601 | 360) 1 St | 11 | 11 | 4| ( 30| | 231 | 2| | 5| | 500000001 | 131 ] 4| | 4| | 11 COHHENTS 1 LAB | LAB LAB LAB LAB LAB LAB | j | | | | 25500 MAX LAB LAB LAB LAB LAB LAB LAB LAB LAB 7300 MAX | | | ( ( ( | ( | I | LAB LAB LAB LAB t | | I LAB | LAB | LAB | 120000000 MAX | LAB ( LAB | LAB | LAB | Pad* 1-2 / DO 1 0 6 9 7 5 C O N F ID E N T IA L . /m SAFETY & LOSS PREVENTION STANDARD - S-310 HEARING CONSERVATION & NOISE CONTROL Scope: The purpose of this Standard Is to define permissible levels of exposure to noise in the Louisiana Division of The Dow Chemical Company In order to prevent noise Induced hearing loss. 1. Essential Requirements of Hearing Conservation Programs A. Baseline audiogram for all employees. B. Definition of high noise level work areas. C. Monitoring of noise exposures for employees working In high noise level areas. D. Follow-up audiometric testing as part of the annual physical exam program. E. Education of personnel in the consequences of exposure to excessive noise levels. F. Maintain a written noise abatement program for all high noise level areas. 2. Permissible Exposure LlmltB A. The permissible exposure to continuous noise shall not exceed an eight hour time-weighted average of 85 dB(A), with a doubling rate of 5 dB(A), which means that the allowable exposure time doubles with each 5 dB(A) reduction in noise level. (1) Steady State Noise - Single Level Permitted Sound Pressure Levels Versus Duration of Exposure Sound Level dB(A) ` Duration Per Day ___ Hours 85 8 90 4 95 2 100 1 105 1/2 110 1/4 115* 1/8 *No exposure to Continuous or Intermittent in excess of 115 dB(A). (2) Impulse or Impact Noise Exposure to Impulse or impact noifee shall not exceed a peak sound pressure level of 140 dB(A). DO 106976 CONFIDENTIA HEARIBG CONSERVATION & NOISE CONTROL - S-310 Page 2 3. Responsibilities A. Plant Superintendent - Must maintain a written noise abatement program intended to prevent excessive noise exposure which can result in hearing loss among his employees. An abatement program shall consist of one or all of three possible methods of control: personal protective equipment, administrative, and engineering depending on feasibility. B. Industrial Hygiene Representative - Will conduct the annual noise surveys in all areas, personnel monitoring, and additional surveys as needed in problem areas. He must also maintain necessary records of area and personnel monitoring as well as signed documentation of employee education and training. C. Industrial Hygiene Department - Is responsible for keeping supervision informed of present and proposed noise regulations, supplying technical guidance as needed, and continually monitoring the division program to assure that the division remains within Dow, State and Federal government regulations. D. Medical Department - Will provide the audiometric evaluation services and documentation thereof. Medical is also responsible for determining employee's capabilities to use various types of hearing protectors. 4. Sound Monitoring Equipment A. All instrumentation used for noise measurements within the Louisiana -t Division must conform to the American National Standard specifications. (1) Sound Level Meters - Meet ANSI SI.4-1976. (2) Audiodosimeters - Meet ANSI SI.25-1978 with an operating range of 85-120 dB. B. Instruments available in the Louisiana Division include several types of sound level measuring instruments and approved audio dosimeters. For details in proper instrumentation use and availability contact the Industrial Hygiene Department. i t C. Calibration - An approved acoustical calibrator is necessary to verify accuracy of the instruments used. All equipment must be calibrated before and after measurements are made. A signed notation confirming calibration must be made on all data recorded. 5. Employee Education * The education portion of the hearing conservation and noise control program shall include the following: A. Employees who can potentially be overexposed to noise will be informed annually of the consequences of overexposure to noise and the precautions required to protect their hearing. ^0 106977 conftoenttai. HEARING CONSERVATION & NOISE CONTROL - S-310 Page 3 Dgram I t in 1 isist 1. sonal g on toise s as s of i of sion Bf ylng 1: sion m and * Ices K for I ring I ana ard of pes rs. the B. Employees who work in high noise areas will be informed of the results of the annual noise survey. C. Employees who are required to use personal protective equipment because of high noise levels will be trained in the proper use and care of the devices. 6. Control Measures A. Engineering controls shall be used whenever feasible to meet the acceptable noise exposure limit. B. Until engineering controls are Installed or deemed not feasible two types of control measures are available.' (1) acceptable noise exposure levels< (2) equipment (i.e., ear muffs) may be authorized for the employees. The plant/department is responsible for furnishing equipment and enforcing use. 7. Warning % A. A caution sign shall be at entrance and around the periphery of areas where the noise levels exceed 90 dB(A). The sign must include the following: WARNING NOISE AREA MAY CAUSE HEARING LOSS USE PROPER EAR PROTECTION B. All signs shall be in accordance with OSHA's regulations for "CAUTION" signs - black letters on yellow background. Yellow sign blanks are available in the division Stock Department. -fy :ed :ng am ed he DO 106978 CONFIDENTIAL CONTRACTOR EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: CONTRACTOR: __ SUBJECTS COVERED: PLANT: _S^5Xi^__X.____ Cov^wiM isj \ ciet^ ^0 EMPLOYEES ATTENDING INSTRUCTOR Cor.crsctcr /% i tO/lc< I fflcoA'^c <? 73zSL7 \'.\V /l/> //-/ . pe/j-'Us T&}r rps U N\e- o fr\ C. b-^< DO 106979 CONFIDENTIAL DOW EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: 5'T-Vfto SUEJECTS COVERED: PLANT: (k\*^ ^ ^ INSTRUCTOR: y>SL EMPLOYEES ATTENDING: Name Classification f.S. Z.J.T, S o<r~ &5 fT c?Z Master No. 4S/& Os #3*?/ H3ais1 m o?j 43 W VJ30?/ _D i06980 CNrrDIENTrAL DOW EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: SUBJECTS COVERED: OS\\f PLANT: _S INSTRUCTOR EMPLOYEES ATTENDING: _NN aitttee_______________________Classif ication M.&-1 bh/'t-j C__ So <Z<pT yij CSrM^ 1't f?. ~Th c Ti Master_N o. 3 30^ y t -* f- DO 106981 CONFIDENTIAL. DOW EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: __ PLANT: SUBJECTS COVERED: Wfv'^'U rJ u ffrwivi INSTRUCTOR licuil., _____ EMPLOYEES ATTENDING Name / > ^u^Jl V ' ^/r- Classification o. s. ^ 5. O5 $>'O-) . 5- s. S v7~ oS SOT <P* __ Master No.___ "a 3 \i ? t~ ^3 2 3 ft? y?p>' i'7 lj 333^$ if 3 o86^f /r-?/<f-2.^ 4/J0 f93T~ &33 *4/7 //J ^^ r,0 1.069S? CONFtOFMTTAV.. DOW EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: ------------3-- r-H--i-l- SUBJECTS COVERED: PLANT: P^p fj ^ L+'!Xrt>cI INSTRUCTOR: ^*0.' 6&Ab,^ EMPLOYEES ATTENDING: Name Classification 03 . Serf __Master No. ^53Z37 ~ V335"7^. V 3 3(^/7^ 2-Y JOlh^^r^ <r.5. oT S-tf.7- Gn l>p h <y 3 ^/ 7.2</$/'?'? f y3 o f s1 s i r* 733/y 7 i/ ? o s 7 5 Do J06983 CONFIDENTTA! DOW EMPLOYEE TRAINING DOCUMENTATION RECORD DATE: SUBJECTS COVERED: PLANT: INSTRUCTO><X^l EMPLOYEES ATTENDING: Name Classification ~$CT Master No.t~ 'tf? 3 eS /' 106934 CONFrDTNTrAL