Document NmBZqVOdyN13VZjrr0b0YZnD

Conoco Chemicals Company A Oivrnon of Conoco tnc. 5 Groonway Plaza Ea*t P.0 Box 2197 Houston. TX 77001 August 31, 1981 Mr. Leslie Lee Exxon Chemicals P.O. Box 241 Baton, Rouge 70805 Dear Leslie: Per your request, enclosed is a Material Safety Data Sheet for Conoco Chemicals Piperylene Concentrate. Please feel free to contact me if you have further questions. Sincerely, Industrial Hygiene ajo Enclosure MATERIAL SAFETY DATA SHEET iconocoj Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 K - vPROnUCriDEKnHCOTOK MANUFACTURER'S NAME Conoco Chemicals Company REGULAR TELEPHONE NO. 713/965-5010 EMERGENCY TELEPHONE NO. 318/491-5070 ADDRESS Chocolate Bayou Operations, P.O. Box 2917, Alvin, TX 77511 TRADE NAME Piperylene Concentrate SYNONYMS Mixed Cc; Hydrocarbons " HflZflRDDUSINGHHHEHIS?: MATERIAL OR COMPONENT % HAZARD DATA Cis & Trans piperylene Isoprene C^dienedimers Benzene Z-30 <7 15 <2 90IUNG POINT (f.) VAPOR PRE5URE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR ;THYSICALDflnt,~;Jv; 106 12.5 psia @ 100? 2.4 SPECIFIC GRAVITY (Hi) = 1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATT ( -1) negligible MELTING POINT Colorless liquid - strong sweet odor 0.70 1002 FLASH POINT (TEST METHOD) Below 0J (TCC) FLAMMABLE LIMITS IN AIR. % 9Y VOL u AUTOIGNITJON TEMPERATURE LOWER 1.5 UPPER 7.5 EXTINGUISHING MEDIA CO 2 dry chemical, water fog CCR 0000018*? 3 SPECIAL FIRE RGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION U(l7ftDn Cool surface of exposed tanks with water spray. Self-contained breathing apparatus should be worn. Do not attempt to extinguish flames due to possibility of explosion and reignition._________________ Hazardous flammable liquid. Contact with oxidizers may cause fire and explosion. Exposure to air form oerixides. FIRST AID EYES: SKIN: Flush with copious amounts of water for at least 15 minutes. Seek medical aid. Wash with non-abrasive soap. Flush with copious amounts of water. Remove from exposure. If breathing has stopped, administer arti INHALATION: ficial respiration or oxygen and cardio-pulmonary resuscitation if indicated. Seek medical aid. INGESTION: Do not induce vomiting. Administer 2-4 oz. of vegetable oil or olive Oil and gggk nierHral__aid ._____________________________________________________ NATURE OF HAZARD EYES: Irritation may result with exposure to high vapor concentrations nr Hnitid . SKIN: Repeated contact may cause dermatitis. This material may be absorbed through the skin in toxic amounts. tract INHALATION: Nose, throat and upper respiratory/irritation may occur. Chronic exposure can lead to CNS depression and systemic toxicity. INGESTION: Systemic toxicity may occur. lungs, pnuemonia may occur. If material is aspirated into the EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Irritation eyes, nose, throat and upper respiratory tract. Dizziness and CNS depression. CHRONIC OVEREXPOSURE: Systemic toaclcty ^ result. THRESHOLD LIMIT VALUE (TLV) None established: 1,000 ppm TLV is recommended. TOXICITY OATA SKIN CONTACT: Rabbit Dermal LD50: >7,940 mg/kg Skin irritation score of 0 (maximum of 8) EYE CONTACT: Rye irritation score of 14 (maximum of 110) CCR oooon. INHALATION: This material contains small amounts of benzene which is a suspect leukemogen. INGESTION: Rat oral LD50: 10,400 mg/kg SPECIAL PRECAUTIONS: CONDITIONS CONTRIBUTING TO INSTABILITY ^jsaaaiBifa Presence of heat, oxygen, water, acecylide-fomring metals. *9i INCOMPATIBILITY Air; oxidizing agents, water, caustics, amines, halogenated compounds, alcohols, glycol ethers, phenols, ammonia, halogens, ether, acid anhydrides. HAZARDOUS DECOMPOSITION PRODUCTS May form peroxides and unstable polymers upon explosion. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION All sources of heat, sparks, and exposure to air. STEPS TO BE TAXEN IF MATERIAL IS RELEASED OR SPILLED Eliminate all ignition sources. Evacuate area. If possible eliminate leak source. Prevent liquid from entering sewers or low areas. Increase ventilation if indicated. NEUTRALIZING CHEMICALS WASTE DISPOSAL METHOO Vapors should be vented to a burning flare. If vapor must be vented to atmosphere insure dissipation of gas below it's LEL. Liquids should be incinerated. VENTILATION REQUIREMENTS This product should be used only with adequate ventilation, Mechanical ventilation is recommended. 'SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL!: Organic vapor cannister or air-supplied respirators. EYE; Chemical goggles and face shield should be worn when handling this product. GLOVES: Impervious gloves should be worn. are suitable materials. Butyl rubber and polyvinyl alcohol OCR 000001895 OTHER CLOTHING AND EQUIPMENT: Other impervious clothing may be required if contact is possible. ik . - i- 11MC0 HAZARD CLASS AMD NUMBER 3.1 UN NUMBER 1993 ADR CUSS NUMBER CAS NUMBER sPBaALPREcainioNS^: US DOT CLASSIFICATION Flammable Liquid SC DANGEROUS SUBSTANCE CLASSIFICATION SC SPECIAL RISKS AND SAFETY ADVICE USUAL SHIPPING CONTAINERS STORAGE TRANSPORT TEMPERATURE ELECTROSTATIC ACCUMULATION HAZARD STORAGE-TRANSPORT PRESSURE LOAOING/UNLQAQIHG TEMPERATURE VISCOSITY AT LOADINGAJNLDADING TEMPERATURE . p^y*mi'?&4J'sS HANDLING AND STORAGE MATERIALS' AND COATINGS SUITABLE UNSUITABLE Steel ! The above data is baaed on tasa and experience wrncfi Conoco believes reliable and are suootied ter informational ourocsea ontv. Conoco disclaims any fiaoility tor damage or injury wmch results from tne use of the aoove data and nothing contained therein snail constitute a guar* antes. WARRANTY OF MERCHANTABILITY. or representation (including freedom from oaient liability) by Conoco with resoect to the oaa. the product desorbed. or their use ter any soecfic ouroose. even it that ourpcse is known to Conoco. Conoco assumes no resoonsioiitty ter injury to Buyer or third persons pronmaiety caused by the product if reasoned# safety measures are not adhered to as stipulated m the data sheet. CCR 0000018 96