Document NejMMNmK04X0YZwVz2wqNzGwg

Material Safety ^Ss.'&T 4Data Sheet ../-.;' ** - ' Partr>burg '"Talaphona Witt , .t0*4345411 Virginia -.. V rMtoi .. Aof^Wamcr Otemkals ^n.>-jr,.'.'. -7 - 1 WESTON TNPP/WESTON 399/WESTON 399B * November 1, 1986 MSDSNa. CS-0019-6A The following information has been compiled from currant source* which are believed to be accurate and reliable. Since it ie not possible to anticipate all condition* under which thit information and the subject product* wilt be used, it should not be assumed that all acceptable safety measures are defined, or that other additional procedures may not be required under individual circumstances. User should insure that the information is relevant to each particular condition or application. Borg-Warner Chemicals, Inc. makes no war ranty, either express or implied, including merchantability and fitness. Lr fit V***!* " tp;l-*:- ; - ' * . r 1. !",'}*'''1i> .G*' 2. yg'k'- E?*fcX $S.Vt,-'.V 3. PRODUCT IDENTIFICATION .. BRAND NAME.............. WESTON TNPP/WESTON 399*/WESTON 399B* COMMON NAMES.......... tris-nonylphenol phosphite .. CHEMICAL .NAME.... phosphorous acid, tris-nonylphenyl ester .. CAS NUMBER............. 26523-78-4 . . FORMULA.................... C45 H69 03 P .. DOT HAZARDCLASS, not classified * WESTON 399/WESTON 399B contain less than 1.0% by wt. triisopropanolamine (TIPA). HAZARDOUS INGREDIENTS CHEMICAL NAME nonylphenol COMMON NAME nonylphenol CAS NUMBER 25154-52-3 PHYSICAL AND CHEMICAL PROPERTIES STATE..................... MELTING POINT.. BOILING POINT.. VAPOR PRESSURE. VAPOR DENSITY.. SPECIFIC GRAVITY WATER SOLUBILITY pH............ ODOR------ straw-colored liquid unknown unknown 5 mmHg 0 437F (225C) 23.8 (air = 1) 0.980-0.992 0 25C/15.5C insoluble not applicable mild PHYSICAL HAZARD INFORMATION FLASH POINT TNPP: 405F (207C) PMCC 399/399B: 385F (196C) PMCC LOWER FLAMMABLE LIMIT., unknown UPPER FLAMMABLE LIMIT., unknown AUTO IGNITION TEMP.......... unknown EXTINGUISHING MEDIA------ Dry chemical, C02, foam, water spray FORM 1B85-REV 9 IS Jyts .... :%- ` \-'. - .Tt- -^.nr rfarhi-iTirr* iffr <l CS-0019-6A Page 2 PHYSICAL HAZARD INFORMATION (CONTINUED) REACTIVITY............................ Can hydrolyze in the presence of water. INCOMPATABILITIES............ Acids, oxidizers, water. Mixing with other chemicals should be done only under the supervision of qualified individuals. CONDITIONS TO AVOID____Do not store above 150F (66C). Do not heat above flash point. HAZARDOUS DECOMPOSITION PRODUCTS : Hydrolyzed by moisture with the production of phosphorous acid and nonylphenol. Phosphine is a possible byproduct of hydrolysis at elevated temperatures. PYROPHORIC. . no EXPLOSIVE... no FLAMMABLE... no COMBUSTIBLE. no .. OXIDIZER-----.. PEROXIDE-----.. COMPRESSED GAS................... no no no HEALTH HAZARD INFORMATION .. PRECAUTIONARY INFORMATION............. Avoid skin and eye contact. Use with adequate ventilation. .. SYMPTOMS OF OVEREXPOSURE................. * Acute: Repeated and prolonged skin exposure may cause mild irritation. * Chronic: Subchronic (90-day) and long term (2-year) ingestion studies with tris-nonylphenyl phosphite indicate no toxic effects. .. RESTRICTIVE MEDICAL CONDITIONS., unknown .. PRIMARY ROUTES OF EXPOSURE............ INHALATION.............. unlikely, unless heated SKIN ABSORPTION., unknown INGESTION................. unlikely SKIN AND EYE CONTACT..................... yes i r^mx- k wjz / J'' Do 085347 CONFIDENTIAL `*"*-*fc*r- -^- fryytfl '.**',u^ni_-viffW>iiyjW'# * jf*. * ** . ; -^<'*. ** *. v ^ -- , y> ,'.*...{/ i|*>-sfl ,, / * * '*<<, > - , K,*-3/.i4 7 y 4a . '* - ~ "-!`">T*"' : J*' ;t,v'?%MS` ~V, ;. ,j!??:??77' -r;-,.ft-i k.:h i-.-ife.i^S'f;;f '- - .. f. -m '. -' iffJ 5r '> *JE- -_- -', '* t ^ '`^*- f'v* r i v- - .- n , ** iw' `*X *f fiA-W.--1- r 5. HEALTH HAZARD INFORMATION (CONTINUED) .fr*' S&XS^' -' Ji jL.; < r foiWft ^T -* t*'* " i^T rMfriik Wr#i<gfe|y .*&i V CS-0019-6A Page 3 .V rS* ' K!$K?'^&^&Tj; :> iji-'tfr-** *> j&"-',' h TOXICITY INFORMATION.......................... * Acute oral LD50 (rat) = 19.5g/kg Acute inhalation LC50 (rats) > 2mg/L Acute dermal LD50 (rabbits) > 200mg/kg D.O.T. Corrosivity: Non-Corrosive Found to be a primary skin irritant when applied repeatedly to the skin of rabbits. * A ninety day feeding study in weanling rats produced kidney damage at 5% of the diet but no effect at the 0.2% and 1.0% levels. * .Studies in rats fed 0.1%, 0.3%, 1.0% tiisnonylphenyl phosphite in the diet for 2 years showed no significant compound related abnormalities including cholinesterase depression. * A two year chronic study in dogs showed no effects at 0.1%, 0.3%, and 1.0% of the diet. * A multigeneration reproductive study in rats fed at 50, 167, and 500 mg/kg showed only slight effects (reduced food uptake efficiency at the high dose). i ;n -i-V? 5 FIRST AID PROCEDURES 1'1 INGESTION: If person is conscious, give large amounts of water to drink. Keep person warm and quiet. Get medical attention immediately. ,-> if INHALATION: Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep the affected person warm and at rest. Get medical attention immediately. SKIN CONTACT: Immediately wash with soap and water. If irritation develops, obtain medical attention. Remove contaminated clothing immediately, wash before reuse. Remove and discard contaminated shoes. as-sascW * ' ir>v-v EYE CONTACT: Immediately wash with large amounts of water, keeping the lids open. Get medical attention immediately. Contact lenses should not be worn when working with this material. 1,1 I .iJ!WWPI'iWpiWXi| ji'WPKjUUlU * !! |.lj'l' ^ ^Sfi'afw' Do 08534S1 CONFIDENTIAL .. EXPOSURE LIMITS OSHA PEL.... not regulated TLV................... not listed OTHERS............ unknown .. CARCINOGENIC OSHA REGULATED........................................ not regulated NATIONAL TOXICOLOGY PROGRAM.......... not tested INTERNATIONAL AGENCY FOR RESEARCH ON CANCER..................... not listed t- 6. PRECAUTIONS FOR SAFE HANDLING AND STORAGE Store in a cool, dry area, away from heat, spark or flame. Avoid skin and eye contact. Wash hands after handling. Wear proper personal protective equipment. .. SPILLS/LEAKS/RELEASES ft? ``"P"!4** WORKPLACE RELEASE: Absorb on inert sorbent. Shovel into drums. Remaining material may be emulsified with soap and water and absorbed on additional sorbent. Disposal must be in accordance with federal, state, and local regulations. f-k SOIL RELEASE: Do not flush to sewer. Water causes hydrolysis. Scoop up contaminated soil and place in dry drums. Dispose of as laws and regulations allow. rrr4*"-'-1 r- WATER RELEASE: Since phosphites can hydrolyze, notification of the governing agency may be appropriate. Phosphorous acid and nonylphenol may be released. The by-product nonylphenol is acutely toxic to fish. The 96 hr. LD50 is o.l5 mg/1 for fat head minnows. Releases of large amounts should be reported to the appropriate agencies. l f r? AIR RELEASE: Unlikely to be released to the air because of low volatility. __ 7*-'* % o .6 PRECAUTIONS FOR SAFE HANDLING AND STORAGE (CONTINUED) RCRA WASTE NUMBER: not applicable REPORTABLE QUANTITY (PER EPA): not applicable 7. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT .. VENTILATION: Recommended; sufficient to control vapors and odors. .. PERSONAL PROTECTIVE EQUIPMENT DEGREE OF EXPOSUREEYE SKIN RESPIRATORY OTHERS I CLOSED SYSTEM (REMOTE) A II OCCASIONAL (INFREQUENT) A III REPEATED & PROLONGED B IV SPILLS (GROSS CONTACT) B A A A B none none A A none B BC BD ~ -A. s... F,,,`, RESPIRATORY PROTECTION: NIOSH approved organic vapor cartridges. GLOVES: Impervious, such as rubber or plastic. ' ' ` " ' KEY FOR PERSONAL PROTECTIVE EQUIPMENT EYE A SAFETY GLASSES B CHEMICAL GOGGLES C GAS TIGHT GOGGLES OTHERS SKIN A ORDINARY WORK CLOTHES B IMPERVIOUS CLOTHING C IMPERVIOUS AND GAS TIGHT RESPIRATORY PROTECTION A HALF MASK W/CARTRIDGE B FULL FACE W/CANNISTER C FULL FACE W/SUPPLIED AIR unk = UNKNOWN n.a. = NOT APPLICABLE > = GREATER THAN < = LESS THAN A FACESHIELD B GLOVES C APRON D BOOTS r -`r s- - r'.v, DO 085350 CONFIDENTIAL ,hi .w.-v&hL-'7 CS-0019-6A Page 6 FOR ADDITIONAL INFORMATION TELEPHONE------ 304-296-2554 or if no answer 304-863-7480 DATE OF ISSUE 10/25/85 DATE REVISED 11/1/86 REPLACES CS-0019-5A rr SE fs ; 'V'- >V a: -r `-t -i- - -- .- o ^Material Safety' -`Borg-Worntr intrnotlonot P#rkrfburg Chemicals, ...C**nt*r W#i ^Datasheet ^ - Jn--.1* , . r ,* v 26102 Tflfphon* *04 424-5411 BorgWamer Chemicals L V. WESTON TNPP/WESTON 399/WESTON 399B October 25, 1985 CS-0019-5A MSDSNs. The following Information hat btin compiled from current aourcet which are believed to be accurate and reliable. Since It I* not poaalble to anticipate alt conditions under which thia Information and the aubfeef product* will be uaad, It ahould not be aaaumed that all acceptable aafety measure* are defined, or that other additional procedures may not be required under Individual circumstances. User should Insure that the information it relevant to each particular condition or application. Borg-Wamer Chemical*, Inc. makes no war ranty, either express or implied, Including merchantability and fitness. 1. PRODUCT IDENTIFICATION .. BRAND NAME.............. WESTON TNPP/WESTON 399*/WESTON 3998^ .. COMMON NAMES..........tris-nonylphenol phosphite .. CHEMICAL NAME.... phosphorous acid, tris-nonylphenyl ester . . CAS NUMBER.............. 26523-78-4 .. FORMULA..................... C45 H69 03 P .. DOT HAZARD CLASS, not classified * WESTON 399/WESTON 399B contain less than 1.0% by wt. triisopropanolamine (TIPA). .2 HAZARDOUS INGREDIENTS CHEMICAL NAME nonylphenol COMMON NAME nonylphenol CAS NUMBER 25154-52-3 3. PHYSICAL AND CHEMICAL PROPERTIES STATE....................................... MELTING POINT..................... BOILING POINT..................... VAPOR PRESSURE................... VAPOR DENSITY..................... SPECIFIC GRAVITY.............. WATER SOLUBILITY.............. pH.............................................. ODOR.......................................... straw-colored liquid unk unk 5 mmHg @ 437 F (225 C) 23.8 (air * 1) _ _ 0.980-0.992 @ 25C/15.5 C insoluble n. a. mild PHYSICAL HAZARD INFORMATION FLASH POINT TNPP: 405F (207C) PMCC 399/399B: 385F (196C) PMCC LOWER FLAMMABLE LIMIT., unk UPPER FLAMMABLE LIMIT., unk AUTO IGNITION TEMP..........unk EXTINGUISHING MEDIA.... Dry chemical, C02, foam, water spray `-v. ,t,' |T * 1 f V . i .k . ~t ' . = - ^5% j*V . r,'..'.j ,. -'tiV- i, Tr'iF: FORM iaas REV9/85 ,V-"DO 08S3W _v<."A"i-'^HV-"** r?- REACTIVITY............................. Can hydrolyze in the presence of water. INCOMPATABILITIES............ Acids, oxidizers, water. Mixing with other chemicals should be done only under the supervision of qualified individuals. '-V . -r- - - . i^V^Vo: CONDITIONS TO AVOID____ Do not store above 150F (66c). Do not heat above flash point. HAZARDOUS DECOMPOSITION PRODUCTS : Hydrolyzed by moisture with the production of phosphorous acid and nonylphenol. *"" ' " r. .. PYROPHORIC., no .. EXPLOSIVE... no .. FLAMMABLE... no .. COMBUSTIBLE, no .. OXIDIZER____ .. PEROXIDE____ .. COMPRESSED GAS................... no no no 5. HEALTH HAZARD INFORMATION .. PRECAUTIONARY INFORMATION.............. Avoid skin and eye contact. Use with adequate ventilation. " s+'-t i. kyy:P,^" .. SYMPTOMS OF OVEREXPOSURE................. * Acute: Repeated and prolonged skin exposure may cause mild irritation. * Chronic: Subchronic (90-day) and long term (2-year) ingestion studies with tris-nonylphenyl phosphite indicate no toxic effects. F-* RESTRICTIVE MEDICAL CONDITIONS., unknown PRIMARY ROUTES OF EXPOSURE............ INHALATION.............. unlikely, unless heated SKIN ABSORPTION., unk INGESTION................. unlikely SKIN AND EYE CONTACT...................... yes TOXICITY INFORMATION. * Acute oral LD50 (rat) = 19.5g/kg * Acute inhalation LC50 (rats) > 2mg/L * Acute dermal LD50 (rabbits) > 200mg/kg * D.O.T. Corrosivity: Non-Corrosive * Found to be a primary skin irritant when applied repeatedly to the skin of rabbits. * A ninety day feeding study in weanling rats produced kidney damage at 5% of the diet but no effect at the h i- 0.2% and 1.0% levels. * Studies in rats fed 0.1%, 0.3%, 1.0% trisnonylphenyl phosphite in the diet for 2 years showed no significant compound related abnormalities including cholinesterase depression. * A two year chronic study in dogs showed no effects at 0.1%, 0.3%, and 1.0% of the diet. $ * A multigeneration reproductive study in rats fed at 50, 167, and 500 mg/kg showed only slight effects (reduced food uptake efficiency at the high dose). FIRST AID PROCEDURES INGESTION: If person is conscious, give large amounts of water to drink. Keep person warm and quiet. Get medical attention immediately. INHALATION: Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep the affected person warm and at rest. Get medical attention immediately. \ SKIN CONTACT: Immediately wash with soap and water. If irritation develops, obtain medical attention. Remove contaminated clothing immediately, wash before reuse. Remove and discard contaminated shoes. EYE CONTACT: Immediately wash with large amounts of water, keeping the lids open. Get medical attention immediately. Contact lenses should not be worn when working with this material. 00 085354 confidential i r [ r it S f>,; -- 'S'-' fS? OSHA PEL.... not regulated TLV................... not listed OTHERS............... unk .. CARCINOGENIC OSHA REGULATED........................................ not regulated NATIONAL TOXICOLOGY PROGRAM.......... not tested INTERNATIONAL AGENCY FOR RESEARCH ON CANCER..................... not listed 6. PRECAUTIONS FOR SAFE HANDLING AND STORAGE Store in a cool, dry area, away from heat, spark or flame. Avoid skin and eye contact. Wash hands after handling. Wear proper personal protective equipment. . . SPILLS/LEAKS/RELEASES WORKPLACE RELEASE: Absorb on inert sorbent. Shovel into drums. Remaining material may be emulsified with soap and water and absorbed on additional sorbent. Disposal must be in accordance with federal, state, and local regulations. SOIL RELEASE: Do not flush to sewer. Water causes hydrolysis. Scoop up contaminated soil and place in dry drums. Dispose of as laws and regulations allow. WATER RELEASE: since phosphites can hydrolyze, notification of the governing agency may be appropriate. Phosphorous acid and nonylphenol may be released. The by-product nonylphenolis acutely toxic to fish. The 96 hr. LD50 is 0.15 mg/1 for fat head minnows. Releases of large amounts should be reported to the appropriate agencies. ? -J< i AIR RELEASE: Unlikely to be released to the air because of low volatility. ct-j DO 085355 CONFIDENTIAl .v.iLc- r ; # t~ *#sS'iJTi&i* *?.'! ^r*J.r=iT"jT-Ttj (JF' *{?%' . 6. l i CS-0019-5A Page 5 PRECAUTIONS FOR SAFE HANDLING AND STORAGE (CONTINUED) RCRA WASTE NUMBER: n.a. REPORTABLE QUANTITY (PER EPA): n.a. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT .. VENTILATION: Recommended; sufficient to control vapors and odors. .. PERSONAL PROTECTIVE EQUIPMENT DEGREE OF EXPOSUREEYE SKIN RESPIRATORY OTHERS I CLOSED SYSTEM (REMOTE) A II OCCASIONAL (INFREQUENT) A III REPEATED & PROLONGED B IV SPILLS (GROSS CONTACT) B A A A B none none A A none B BC BD RESPIRATORY PROTECTION: NIOSH approved organic vapor cartridges. GLOVES: Impervious, such as rubber or plastic. ` `f .r&ft*,: - KEY FOR PERSONAL PROTECTIVE EQUIPMENT EYE A SAFETY GLASSES OTHERS A*- FACESHIELD B CHEMICAL GOGGLES B GLOVES l C GAS TIGHT GOGGLES C APRON D BOOTS SKIN A ORDINARY WORK CLOTHES B IMPERVIOUS CLOTHING C IMPERVIOUS AND GAS TIGHT i RESPIRATORY PROTECTION f A HALF MASK W/CARTRIDGE B FULL FACE W/CANNISTER C FULL FACE W/SUPPLIED AIR in. A*' f fv-V? S* - ' CS-0019-5A Page 6 FOR ADDITIONAL INFORMATION TELEPHONE____ 304-296-2554 or if no answer 304-863-7480 DATE OF ISSUE 10/25/85 DATE REVISED n.a. REPLACES CA-303C CA-305A I > >:&*/ /" V>*t' fe ' 'Hr , V ^ J--" `