Document NeN9xgqaRLENQp664zN8XamBw

The Law Office of Received feb o 7 1991 ^eitscM y?. Robson, ^ft.TL ^.T). Attorneys at Law .rschel L. Hobson J. Keith Hyde Nick C. E. LcBleu February 5, 1991 RECEIVED Mr. Frank Parker 304 Magnolia Boulevard Magnolia, Texas 77355 Legal Assistants Warriene Flatt Brenda Jenkins, C.L.A. -- RE: RAY WING, ET UX vs. SHELL OIL COMPANY, ET AL; CAUSE NO. B134,406/ IN THE 60TH JUDICIAL DISTRICT COURT OF JEFFERSON COUNTY, TEXAS; OUR FILE NO. WR1231-0 Dear Frank: Please find enclosed additional Material Safety Data Sheets for your review in the above-referenced matter. Please let me know if you have any questions in this regard. /JKH/wf/dm 2190 Harrison / Beaumont. Texas 77701 / (409) 838-6410 / Fax (409) 838-6084 (conocd) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267. Ponca City. OR 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have Indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dibromlde (106-93-4) A potential mutagen and tumorlgen. Ethylene dichloride (107-06-2) A potential mutagen and tumorlgen. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Bronze or red clear liquid; Gasoline odor. Boiling Range (F) 85-437 Specific- Gravity (H20-1) Vapor Pressure (mmHg)@68F 275-475 X Volatile (by volume) Solubility in Water Insoluble 0,70-0.77 100 IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However* the kidney effects were not seen in similar studies involving guinea pigs* dogs* or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point* 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant Increased incidence of skin tumors. The product may cause irritation to eyes* lungs* or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. listed as Carcinogen or Potential Carcinogen by: NTP Ho 1ARC Ho OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Vash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration.: Ingestion: If this material la. swallowed, -do-not induce vomiting. If'vertftting begins* lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 U.S. DEPARTMENT OF LABOR Occupational Safety zr.4 Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Heatth Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915,1916, 1917) SECTION 1 MANUFACTURER'S NAME CONOCO INC. AD0RESS (Number, Street City, Stale, and ZIP Cobe) 1000 South Pine Street, Ponca City, OK 74603 EMERGENCY TELEPHONE NO. (405) 767-3456 CHEMICAL NAME AND SYNONYMS Automotive Leaded Gasoline CHEMICAL FAMILY Mixed petroleum hydrocarbons. FORMULA TRADE NAME AND SYNONYMS CONOCO REGULAR GASOLINE SECTION II --HAZARDOUS INGREDIENTS Recent studies with laboratory animals have shown that gasoline vapors can cause kidnev damage and cancer in Tats and liver cancer in mice. Aromatic Hydrocarbons Benzene * Lead (as lead alkyls') 10-35% LT 5% 0.1% BOILING POINT (T) VAPOR PRESSURE (mm Hg) VAPOR DENSITY (AIR 1| SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION 111--PHYSICAL DATA RVP, psia Approx. 85-434 10-15 3.5 ' SPECIFIC GRAVITY PERCENT, VOLATILE BY VOLUME (%) E( VAPORAwTIOaNteRArTE .u A. pprox. - Insoluble Bronze or red clear liquid - gasoline odor. SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (MatTod UMd) ____________ Mav he as low as -SO*?. - -TCC. EXTINGUISHING MEDIA Foam, Carbon Dioxide, Dry Chemical FLAMMABLE LIMITS Lei 1 . A%i SPECIAL FIREFIGHTING PROCEDURES Use water spray to disperse vapors and protect personnel 0.70-0.77 100 2+ Uel 7.6* UNUSUAL FIRE AND EXPLOSION HAZARDS Highly flammable. Moderate explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on reveree tide) Form 0SHA-20 Rev. Mav 72 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATIOH Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc, Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Cheratrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dibromide (106-93-4) A potential mutagen and tumorigen. Ethylene dichloride (107-06-2) A potential mutagen and tumorigen. Physical Effect Properties: Product/Mix ture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA______________________________________________________________ _ Appearance and Odor: Bronze 6f red clear liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) 0.70-0.77 Vapor Pressure (mmHg)at 68F 75-475 % Volatile (by volume) 100 Solubility in Water Insoluble IV. REACTIVITY DATAStable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. October 17, 1985 r g. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 PFL: 7.6' Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid* Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool* If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (HFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 yI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203- Placard: Flammable. D.O.T. Label: Not Flammable. OSHA Label: CAUTION: Minimize exposure. This product contains benzene, lead, ethylene dibromide, ethylene dichloride, and certain hydrocarbons which are potentially toxic or carcinogenic. , . - If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. TII. HEALTH HAZARD INFORMATION__________________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. October 17, 1985 VII, HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. "emergency and first aid procedures Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. "" Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. ir*tiPeathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II. SPILL. LEAK AND DISPOSAL PROCEDURES_________________________________________________________ RCRA HAZARDOUS WASTE: Yes X Mo In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists. Other Protective Equipment: Coveralls should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION______________________ Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dlbromlde (106-93-4) A potential mutagen and tumorigen. Ethylene dichloride (107-06-2) A potential mutagen and tumorigen. Physical Effect Properties: Product/Mix ture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA + ** Appearance and Odor: Bronze or red clear liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. December 11, 1985 V. FIRE AND EXPLOSION HAZARD DATA LFL: 1,3 UFLs 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Vater may be Ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATIONHAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene, lead, ethylene dlbromlde, ethylene dichlorlde, and certain hydrocarbons which are potentially toxic or carcinogenic... , -- If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. December 11, 1985 11. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been Included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If-overexposure occurs, remove individual to fresh air. IT"^fereathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 11, 1985 XI. SPILL, LEAK AND DISPOSAL PROCBDPKES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists. Other Protective Equipment: Coveralls should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 11, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IPEMTIFICATKW Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 II. OSHA HAZARD VETERM1NATION CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Cheratrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and paraffinic hydrocarbons;- e.g., toluene, hexane, etc.) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PW5ICAL VATA ' Appearance and Odor: Bronze or red clear liquid: gasoline odor. Boiling Range (F) 85-437 Specific Gravity (Ha0~l) Vapor Pressure (mmHg) < 68 F 275-475 X Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IW. REACTIVITY PATA Stable,: X Unstable,: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue dieposure to "afr. ` V. Fine AW EXPLOSION HAZARD PATA IFL-* 1,3 UFI? 776 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. January 9, 1987/GASC0120 V. FIRE AND EXPLOSION HAZARD DATA lcontinued) Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA1 CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGEVOT HAZARD CLASS-' VlammabU Uouid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION:' Minimize exposure. This product may contain benzene, which may be toxic to blood and blood-forming tissues or cause cancer. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Flammable Liquid. VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm TVA: 500 ppm STEL Ceiling Value Not Established Du Pont AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rats and mice have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. January 9, 1987/GASC0120 VII. HEALTH HAZARD INFORMATION lcontinued) Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. A few studies have indicated that workers exposed many years to high concentrations of ben2ene have a slightly higher incidence of leukemia. can also be toxic to the blood and blood-forming tissues. Benzene The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No 05HA? No VIII. BMEKGBNCV AM) FIRST AID PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Vash exposed skin thoroughly with soap and water. If Irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending, on quantity of material ingested. -- January 9, 1987/GASC0120 IX. SPILL. LEAK AMP DISPOSAL PROCEDURES____________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is flammable. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. x. PKEcmioum measures Respiratory Protection: Use appropriate NIOSH-approved respiratory protection where atmospheric concentrations may exceed acceptable exposure limits. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Chemically resistant such as neoprene or NBR as needed to minimize skin contact. Eye Protection: Face shield for sprays/mists. Other Protective Equipment: Coveralls or other protective apparel should be worn if splashing is probable. Soiled clothing should be removed and laundered. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 9, 1967/GASC0120 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. 0SHA HAZARD DETERMINATION Hazardous Ingredients: Hydrocarbons (Aromatic and paraffinic hydrocarbons; e.g., toluene, hexane, etc.) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL VATA Appearance and Odor: Bronze or red clear liquid: gasoline odor. Boiling Range (F) 85-437 Specific Gravity (H*0=1) . Vapor Pressure (mmHg) @ 68 F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY VATAStable.: X Unstable.: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to ai,r.. V. FIRE AND EXPLOSION HAZARD DATA LFL-* US UFL? 7.6 Flash Point (Method used): As low as -50F (TCC) Autoianition Temperature NFPA: 536-853F Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. August 28, 1987/GASC0120 V. FIRE AMP EXPLOSION /MZARP PATA (consumed) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other'toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AMD STORAGE VOT HAZARD CLASS: HasmabU UquII~ Precautions To Be Taken In Handling And Storing: Product Is Class I A Flammable Liquid per NFPA Code No. 30-1984, Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION: Minimize exposure. This product may contain benzene, which may be toxic to blood and blood-forming tissues or cause cancer. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Flammable Liquid. WII. HEALTH HAZARD If/FORMATZOAf PEL Not Established TLV 300 ppm TWA; 500 ppm STEL Ceiling Value Not Established Du Pont AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. August 28, 1987/GASC0120 VJJ. HEALTH HAZARD INFORMATION {conUnuidl Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rats or mice have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. can also be toxic to the blood and blood-forming tissues. Benzene The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No (/HI. EMERGENCY AND FIRST AIV PROCEDURES ~ Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, admiij^gter artificial resuscitatioh. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. August 28, 1987/GASC0120 IX- SPILL. LEAK AA/P DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is flammable. Appropriate precautions should be taken. Contain spill immediately in smallest area possible* Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use appropriate NIOSH-approved respiratory protection where atmospheric concentrations may exceed acceptable exposure limits. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards'and explosive mixtures. Protective Gloves: Chemically resistant such as neoprene or NBR as needed to minimize skin contact. Eye Protection: Face shield for sprays/mists. Other Protective Equipment: Coveralls or other protective apparel should be worn if splashing is probable. Soiled clothing should be removed and laundered. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. Bonding^shall be provided when transferring product between metal containers. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0120 Occupational Safety and Health Administrator! --MATERIAL SAFETY DATA SHEET Required under USOL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916. 1917) SECTION 1 MANUFACTURER'S NAME CONOCO INC." ` EMERGENCY TELEPHONE NO. (405) 767-3456 AOORESS (Number. Stmt, City, Star*, and BP Cod*) 1000 South Pine Street, Ponca City, OK 74603 CHEMICAL NAME AND SYNONYMS . . ; _ ----------AUt"6hi6^IVe 'Unl^aHed Gasoline* CHEMICAL FAMILY Mixed petroleum hydrocarbons. FORMULA TRADE NAME AND SYNONYMS CONOCO UNLEADED GASOLINE SECTION II--HAZARDOUS INGREDIENTS Recent studies with laboratory animals have shown that gasoline vapors can cause kidney damage and cancer in rats and liver cancer in mice. ,, Aromatic Hydrocarbons 10-35% Benzene -- ------------------ ---- . LT 5% t . -..................- BOILING POINT (T) VAPOR PRESSURE (mm Hq) VAPOR OENSfTY (AIR-1) SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION HI--PHYSICAL DATA RVP, psia Approx. Insolubles. 85-434 10-15 3.5 -- SPECIFIC GRAVITY (Hrf)-!) PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE Jyater_-u Approx. Water white to straw vellow - gasoline odor. --------- 0.70-0.77 100 2+ SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT Us*d) Mav be as Tow as -50F. - *TCC EXTINGUISHING MEDIA __;_Foam, Carbon Dioxide, Dry Chemical FLAMMA8LE UMITS La! 1 d* SPECIAL FIREFIGHTING PROCEDURES ........ " Use water spray to disperse vapors and protect personnel. - - -- ----...... -- - -- 7 - .----- v-^-v ---------------- UNUSUAL FIRE ANO EXPLOSION HAZARDS Highly flammable. Moderate explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on rtvrw aid*) Form OSHA-20 R*v. May 73 SECTION V -- HtALTH HAZARD DATA THRESHOLD UMlT VALUE Approx 100-200 ppm in air. LD50(oral)= 18.75 ml/kg (rat). EFFECTS OF OVEREXPOSURE __Marked vertigo. incoordination.___In severe cases: convulsions. coma, asphyxia. EMERGENCY AND FIRST AID PROCEDURES Wash exposed areas with water: artificial respiration if needed. For ingestion. olive oil may be given to retard absorption. Do not induce vomiting. Medical treatment is symtoraatic and should be administered prompt STABILITY UNSTABLE SECTION VI --REACTIVITY DATA CONOlTIONS TO AVOID STABLE X INCOMPATABILITY (Mottrit/s to ovoid) Oxidizing materials , heat, flame. HAZARDOUS DECOMPOSITION PRODUCTS_ CO may be formed from incomplete combustion. HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR X Undue exposure to air. . SECTION VII--SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Clean up promptly by vacuum or absorption in clay or earth. Vapors are a health and gyplnsinn hararH WASTE DISPOSAL METHOD Controlled burning with great caution. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. SECTION VIII--SPECIAL PROTECTION INFORMATION RESPIRATORUY sPeROTaECirTIOmN <aSsakadtovMr>ani yd, rocarb, on a,bsor,b.ing respirator. VENTILATION LS5^iS^s^!rking hazards and explosive raixt MECHANICAL (Gonartt/) OTHER Adeouate to meet recommended concentrations PROTECnvE GLOVES ,, .... EYE PROTECTION ,, ,. ., ,, .. Rubber - as needed to avoid skin contact.) Goggles or face shield for sprays/mists ^o^e^^veVEc?otiurfg should be worn. Soiled clothing should be removed laundered. SECTION IX--SPECIAL PRECAUTIONS PRECALUJS^S TO^E TAI^p^MI^HANpLjNg^NJ^TI^R|N*^^p^^^^_ storage tanks, pumps, lines. OTHER PRECAUTIONS ______Use explosion proof equipment. Vapors are heavier than air. PAGE (2) GPO 934*110 Form 0SHA*20 fUv. May 72 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION______________________ Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: ~ (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A feu studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (HaOsI) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0*77 J00 IV. REACTIVITY DATA ______________________ ___________ Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from-incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA ~ LFLi 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 1985/GASC0140 . fire AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used_to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician Immediately. Wash thoroughly with so^p and water after contact. Flammable Liquid. Til, HEALTH HAZARD INFORMATION____________________________ PEL Not Established TLV 300 ppm "Gasoline" Celling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have-not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye Irritation, rabbits: Non-Irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities In newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. BffiRGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Vash exposed skin thoroughly with soap and water. If Irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated-leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 y, Ir II. SPILL, LEAK AND DISPOSAL PROCEDURES_________________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials* Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES__________________________________ : ______________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. '*Z The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 (ieonoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause lcldney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have Indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class 1 A Flammable Liquid per NFPA Code No. 30-1984, III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; Gasoline odor. Bolling Range (*F) 85-437 Specific Gravity (Ha0-1) Vapor Pressure (mmHg)@68F 275-475 Z Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATALFLt 1.3UFL: 7.6 Flash Point (Method used): As low as -50"F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. February 19, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. Label: Flammable liquid. VII. HEALTH HAZARD INFORMATION PEL None TLV 300 ppm Celling Value None AEL None Prlmary Route<6) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point. 120-700*F) caused a low incidence of.tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: Mo mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic .studies: Negative Reproductive toxicity: Mo abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP Mo IARC Mo OSHA Mo VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure oqpurs, remove individual to fresh air. IfJ?Jresthing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Mote to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. ~ The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 14.10/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Beg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid: gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H2Os1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 222 IV. REACTIVITY DATA _____ Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. ' Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. October 17, 1985 V. FIRE ASP EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product Is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and wate..r after *- contact. - Flammable Liquid. VII. HEALTH HAZARD INFORMATION______________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry; Inhalation, skin. October 17, 1985 VII, HEALTH HAZARD INFORMATION (continued) i Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to Ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EHERGENCX AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. _ ' - ': Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II. SPILL. LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated Items including contaminated soil and place in proper containers for disposal. Avoid washing,'draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET --BPHMWTiifiw --Hi^na-- I. MATERIAL IDESflFICATION Name: Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia* Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H^sl) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Vater Insoluble 70-0.77 100 IV* REACTIVITY DATA - _________ ;________ Stables X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from^^ incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. IN FIRE AND EXPLOSION HAZARD DATA LFLs 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) ~~ Special Fire Fighting Procedures: Water nay be ineffective to extinguish, but water should be used to keep fire-exposed containers cool* If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak* Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may ,, contain carbon monoxide, carbon dioxide and other toxic materials* Do not enter enclosed or confined space without proper protective equipment including respirator protection.' National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 I.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If Ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. v VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen In similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. December 12, 1985 yiirHEALTO HAZARD XBFORMATIOB (continued) House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxlc studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material's swallowed, do not induce vomiting. If^ppiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately In smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated Items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES_________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. t. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985 (conoco) MATERIAL SAFETY DATA SHEET BBanBHSBHBBHBBi I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid: gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H^si) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 J00 IV. REACTIVITY DATA ____________________ _Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLs 1.3 UFL: 7-6 ~ Flash Point (Method used): As low as -50F (TCC) Handle and store In accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 198jf/GASC0l40 y. FIRE AMD EXPLOSION HAZARD DATA Tcontlnued) ~ -- Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If Ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 11. HEALTH HAZARD INFORMATION____________ - : PEL Not Established TLV 300 ppm "Gasoline" Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 ?II. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No fill. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clpthing before reuse. Extremely contaminated.-leather shoes should be discarded. Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material Ingested. January 17, 1986/GASC0140 t II, SPILL, LEAK AHD DISPOSAL FROCEDDRES RCRA HAZARDOUS WASTE: Yes X No ___________ _________________________ In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES ________ ;_________ ________ . _____________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or If splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 Occupational Safety and Health Administrator) --MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916,1917) SECTION 1 MANUFACTURER'S NAME CONOCO INC." ~ EMERGENCY TELEPHONE NO. (405) 767-3456 AOORESS (Number, Street, City, Stan, and ZIP Code} 1000 South Pine Street, Ponca City, OK 74603 CHEMICAL NAME AND SYNONYMS ,; . Automotive Unleaded gasoline CHEMICAL FAMILY Mixed petroleum hydrocarbons. FORMULA TRADE NAME ANO SYNONYMS CONOCO UNLEADED GASOLINE* " SECTION II--HAZARDOUS INGREDIENTS Recent studies with laboratory animals have shewn that gasoline vapors can cause kidnev damaee and cancer in rats and liver cancer in mice. Aromatic Hydrocarbons 10-35% Benzene ................. ..... - LT 5% 1-__________________ ___________________________________ - ' BOILING POINT (T) VAPOR PRESSURE (mm Ha) VAPOR OENSTTY (AIR-1) SOLUBILITY IN WATER APPEARANCE ANO ODOR SECTION III--PHYSICAL DATA RVP, psia Approx. 85-434 10-15 3.5 SPECIFIC GRAVITY (H01) PERCENT. VOLATILE BY VOLUME (%) <EVAPORAWTIOaNteRTATE Approx. Insoluble Water white to straw yellow - zasoline odor. -------- -0.70-0.77 100 2+ SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method UMd) - Mav be as low as -50F. - -TCC EXTINGUISHING MEDIA ____;_Foam, Carbon Dioxide, Dry Chemical FLAMMABLE LIMITS - 1 SPECIAL FIREFIGHTING PROCEDURES Use water spray to disperse vapors and protect personnel. - --- -- * -- -* * * Lrt . .. U< 7.6% - . - ,--r rr-- - - UNUSUAL FIRE ANO EXPLOSION HAZARDS Highly flammable. Moderate-explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on reverse skis) Form OSHA-20 Rev. May 72 ) SECTION V--HEALTH HAZARD DATA THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE Approx. 100-200 ppm in air. LD50(oral)= 18.75'ml/kg (rat) Marked vertigo. incoordination.. In.severe cases:.cpnvulsions coma, asphyxia. EMERGENCY AND FiRST AID PROCEDURES Wash exposed areas with water* artificial respiration if needed. For ingestion, olive oil may be given to retard absorption. Do not induce vomiting. Medical treatment is symtomatic and should be administered prompt STABILITY UNSTABLE SECTION VI--REACTIVITY DATA CONDITIONS TO AVOID STABLE X INCOMPATABIUTY (Matantis to ovoid) Oxidizing materials , heat, flame. HAZARDOUS DECOMPOSITION PRODUCTS. CO may be formed from incomplete combustion. HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOIO WILL NOT OCCUR X Undue exposure to aix. * SECTION VII--SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Clean up promptly by vacuum or absorption in clay or earth. health and pvplna-irm hfl7flrri WASTE DISPOSAL METHOD Vapors are a Controlled burning with great caution. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. SECTION VIII --SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION fSpacifv %p9) , , , ,. . Use air mask or hydrocarbon absorbing respirator. VENTILATION ^SSSilf^l^rking hazards and explosive mixt ^|g.AL MECHANICAL (Gormftl) OTHER Adeauate to meet recommended conc.ent.Tati ons. PROTECTIVE GLOVES , .... Rubber - as needed to avoid skin contact. or face shield for sprays/mists CPr^e^Ti^Vc?ot5mig should be worn. Soiled clothing should be removed & laundered. SECTION IX--SPECIAL PRECAUTIONS RRECAHj^NSToj^TAi^NMi^^iNpugg^j^TjRM^^p^^^ storage tanks, pumps, lines. OTHER PRECAUTIONS ______Use explosion proof equipment. Vapors are heavier than air. PAGE (2) GPO 934-1 tO Form OSHA-20 Rv. May 72 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have Indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA* * * IV. V. Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 JjOO IV. REACTIVITY DATA _______________________ _________ Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from,^SPfimplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLs 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 1985/GASC0140 V. FIRE ASP EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. . ~ Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least * 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203- Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION____________________________ PEL Not Established TLV 300 ppm "Gasoline* Celling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 VII. HEALTH HAZARD IKFORHATIOH (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors* However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have-not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AMD FIRST AID PROCEDURES " " - ~ Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Nash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated, leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 IX. SPILL, LEAK ASP DISPOSAL PROCEDURES : RCRA HAZARDOUS WASTE: Yes X No , In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES ______________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product /Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; Gasoline odor. Boiling Range (F) 85-437 Specific Gravity (Hz0-1) Vapor Pressure (mmHg)@68F 275-475"" X Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATA_________________ Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from Incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATALFL: 1.3UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. February 19, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA)HAZARD RATING HAZARD IDENTIFICATION_______________________ Least - 0 Slight - 1 Health 1 Fire 3 Reactivity 0 High - 3 Extreme - 4 Moderate - 2 VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. Label: Flammable liquid. VII. HEALTH HAZARD INFORMATION PEL None TLV'300 ppm Celling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. - Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low Incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: Mo mortality at dose of 5 ml/kg Slight Irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxlc-studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure qccurs, remove, individual to fresh air. If<*l&eathlng stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 1 ) <f IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL safety data sheet I. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline/Premium Unleaded Gasoline Conoco Product Code: 1420/1200 Synonyms: Automotive Unleaded Casollne Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267 Ponca Cltyy OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver# skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA__________ Appearance and Odor: Red liquid; gasoline odor. Bolling Range (Deg.F) ^5-437~ Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 _ ,% Volatile (by volume) Solubility in Water Insoluble 70-0.77 IpO IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. f~. FIRE "AND EXPLOSION HAZARD DATA ~ IFLt 1.3 PFL: 6.0 Lash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. V. FIRE ASP EXPLOSION HAZARD DATA (continued) ; Special Fire Fighting Procedures: Water may be ineffective to extinguish* but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. Hatlonal Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 VI.TRANSPORTATION AMD STORAGEDOT HAZARD CLASS; Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. . Hash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established*' A EL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. April 25, 1986/GASC0130 VIlT HEALTH HAZARD INFORMATION (continued) House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product nay cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: Ho mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Mon-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical - attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is' swallowed!, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC0130 daKH II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No % In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES_______________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. *i'r The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. April 25, 1986/GASC0130 (conocoi) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals Benzene (71-43*2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Bolling Range (Deg.F) 85-437 Specific Gravity (H?0s1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility In Water Insoluble 0*70-0.77 100 IV. REACTIVITX DATA Stable: Z Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. ., - - Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLi 1.3 UFLs 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. October 17, 1985 V. FIRE AMD EXPLOSION HAZARD DATA (continued) ______________ _ Special Fire Fighting Procedures: Water nay be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION_______________ PEL Not Established TLV 300 ppm - Celling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. October 17, 1985 m. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure; Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Hash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II. SPILL, LEAK ASP DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No ________ : _________ ___________ _ In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing,'draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as Incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES ;_______________________________________________________ ___________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing Is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline/Premium Unleaded Gasoline Conoco Product Code: 1420/1200 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: F. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mix ture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA* * Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H?0=1> Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA Stable: I Unstable: * - ''5 Hazardous Decomposition Products: Carbon monoxide may be formed from Incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. 7. FIRE AND EXPLOSION HAZARD DATA LFlT; 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 25, 1986/GASC0130 TII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute; Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical - attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material JLs swallowed,, do not Induce vomiting. If-juaniting begins, lower victim's fifead in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC0130 (conoco) MATERIAL SAFETY DATA SHEET - ':& I. MATERIAL IDENTIFICATION Name: Naphtha Conoco Product Code: 1509 Synonyms: Petroleum Naphtha; Full Range Straight Run Naphtha Chemical Family: Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Registry No.: 64741-42-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000) II. HAZARDOUS INGREDIENTS________ Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. A few studies have shown that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Colorless to yellow liquid; petroleum naphtha odor. Boiling Range # F -4 to 430 Specific Gravity (H20=1) 0.7 Vapor Pressure (mmHg), 100 F 500 % Volatile (by volume) 100 Vapor Density (Air=1) * >1 Solubility in Water Insoluble IV. REACTIVITY DATA_________________________________ __________ Stable: I Onstable: Hazardous Decomposition Products: Normal combustion forms carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions To Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V.T FIRE iND EXPLOSION HAZARD DATA Flash Point (Method used): Below room temperature Autoignition Temperature: Approx. 450q F LFL: 1 OFL; ~S November 19, 1985 CAS Registry No.: 64741-42-0 V. FIRE AND EXPLOSION HAZARD DATA (Continued) Handle and store In accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective, but water should be used keep fire-exposed containers cool. If a leak or spill has not Ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire_2__ Reactivity_0__ Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable Liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid, per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Naphtha, Flammable Liquid, UN 2553 Placard: Flammable D.O.T. Label: Flammable liquid OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting- Call a physician Immedlatelj^Wash thoroughly with soap and water after contact. Flammable. VII. HEALTH HAZARD INFORMATION _____________________________ PEL Not Established TLV 300 ppm; 900 mg/m3 (Gasoline) Celling Value Not Established AEL Not Established Primary Routes of Entry: Skin, inhalation. November 19, 1985 CAS Registry Mo.: 64741-42-0 VII, HEALTH HAZARD INFORMATION (continued) ___________ Signs and Symptoms of Exposure/Medical Conditions Aggravated By Exposure: No adverse health effect has been identified specifically for this product. Health effect information frsra animal and human studies has been included on related materials, even tnough health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700 F) caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No_ I ARC No_ OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. If exposed to hot oil, immediately cool with cold water. Do not attempt to remove oil but continue to cool exposed areas with cold packs angj^eek medical assistance immediately.*-' Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. November 19, 1985 CAS Registry No.: 64741-42-0 II. SPILL, LEAK AMD DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case Of Spill Or Leak: Protect from ignition. Contain spill immediately In smallest area possible, being careful to avoid potential ignition sources. Recover as much of the product as possible by such methods as vacuuming, using explosion-proof equipment, followed by use of.absorbent materials. Remove contaminated items including contaminated soli and place In proper container for disposal. The area may be washed down with water, as needed, but steps should be taken to avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material by such methods as controlled incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES _______ ___ Respiratory Protection: None required except under unusual circumstances such as described in Section V. Ventilation: Normal shop ventilation. Mechanical In confined space or where vapors may become high. Protective Gloves: Impervious. Eye Protection: Safety glasses with side shields. Chemical goggles if splashing is probable. Other Protective Equipment: Coverall with long sleeves if splashing Is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. November 19, 1985 U.S. DEPARTMENT OF LA80R Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Perm OMB No. 44-JUM7 Required under USOL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916. 1917) SECTION 1 manufacturer's name EMERGENCY TELEPHONE NO. __________ Conoco Jnc.______ _______ ' ADDRESS (Xumbtr. Street, City. Slate. *nd ZIP Code) 10f)0 South Pine. Ponca Citv. OK 74603 (4051 767-3456 CHEMICAL NAME ANO SYNONYMS CToRnAoDcEoNANMoE. AN1 DdSiYeNsOeNYlFMSue_l CHEMICAL FAMILY __________Mixed .petroleum hydrocarbons FOAMUUk SECTION II - HAZARDOUS INGREDIENTS NONE '- ~ ' * SECTION III - PHYSICAL DATA>: OILING POINT (*F.) VAPOR PRESSURE (mm Mf.) .. 330-350 2 a VAPOR OCNSITV (AIR* 11 5.2 SOLUBILITY IN WATER Insoluble appearance ano oooR^jear> paraffinic odor SPECIFIC GRAVITY PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE 1 -11 0.81 ,v Nil NA SECTION IV - FIRE AND EXPLOSION HAZARD DATA PLASH POINT (MtttlOd UM4) - _,, 135-150F. (0C) FLAMMABLE LIMITS Lai LNI 075------------- -------------2r8-- Foam, Carbon Dioxide, dTy chemical, water spray. -- ----- SPECIAL FIRE FIGHTING PROCEDURES Nrme . ,, - ----------. - ............. UNUSUAL FIRE AND EXPLOSION HAZARDS , .. Handle and store m accordance with NFPA procedure for Class II Flammable Liquid. PAGE (1) (Continued on rrvana dda) Form OSHA*20 Kn. Mae 91 -SECTION V - HEALTH HAZARO DATA THftCSMOLO LIMIT VALUE , ____________________________Ap-dtox. 100-300 ppm estimated, EPPECTS OP OVEREXPOSURE Skin fdrying of skin); Inhalation malfunction) (central nervous system Wash exposed areas with water, artificial respiration if needed. For ingestion, olive oil may be given to retard absorption. Induced vomiting is questioned. Medical treatment is symptomatic and should be administered promptly. STABILITY UNSTABLE SECTION VI - REACTIVITY DATA . CONDITIONS TO AVOID STABLE _x_____ INCOMPATA0ILITY (MfttmU tO 8V0td) Oxidizing materials, HAZARDOUS DECOMPOSITION PROOOCTS heat, flame. HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR * CONDITIONS TO AVOiO X SECTION VII * SPILL OR LEAK PROCEDURES STEPS TO ~SE TAKENIN CASE MATERIAL IS BECM0 OH SPIUL-CO ~ TJ/Tl 1 our WPPA ("nd* Clean up promptly py vacuum or absorption in clay or earth. Follow nfpa. Loae No. 30-1969 for Class II Flammable Liquid. - .________________________ WContrln^Su^xng. Storage for professional disposal- Avoid drainage to a sewer unless specifically designed to handle. SECTION VIII . SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION tfprf/v fVMtr . ~ ' ' - .. tia Pir turrIt or hydrocarbon absorbing respirator for sprays or mists. VENTILATION LOCAL EXHAUST SPECIAL MECHANICAL OTHER Normal, venti lation____________________________ PROTECTIVE GLOVES CVC PROTECTION Rubber as needed to avoid skin contact. Reauired for sprays and mists. OTHER PROTECTIVE EQUIPMENT Reouired only und. er unusua,l circums^tances of ^ex,pinocsnurrfel . SECTION IX - SPECIAL PRECAUTIONS ------ gay!" Keep away from flame or heat equipment ^accordance with NFPA Code No. 50-1969 for Class II Flammable Liquid. . PACE (2) e **. Form OSHA-20 . My fS (ssnoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Froduct Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor.___________________________________ Boiling Range (F) 330-572 Specific Gravity (H201) 0.81 Vapor Pressure (mmHg) ,68F 2_______ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidijting material?, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 5 Flash Point (Method used): 115* F min. (TCC) Autoignition Temperature: 475-500* F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. February 19, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V~, FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION_______________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate VI. TRANSPORTATION AND STORAGE___________ ______________DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Deecriptlon: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION ' ` PEL 500 ppm (petroleum distillates) TLV None Celling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. February 1, 1985 CAS Registry No.: Mixture; 64742-38-7 8008-20-6, 64742-81-0 VII. HEALTH HAZARD INFORMATION (continued)_________________ __________________________________ Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low Incidence of tumors. Studies of petroleum workers have not shown a significant increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated Clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary severs. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves; Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name; No* 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney In laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (*F) 330-572 Specific Gravity (H201) Vapor Pressure (mmHg),68"F 2________ % Volatile (by volume) Solubility in Water Insoluble OTbT Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials% heat, flame. - Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA ____________________ LFL: 0.5________ UFL: 5 Flash Point (Method used): 115* F min. (TCC) Autoignition Temperature: 475-500" F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. July 25, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not Ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA)HAZARD RATING HAZARD IDENTIFICATION_______________________ Least - 0 Slight - 1 Health 0 Fire 2 Reactivity 0 High - 3 Extreme - 4 Moderate - 2 VI. TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product Is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. July 25, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxlclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII, EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. July 25, 1985 9 l CAS Registry No*: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. July 25, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Kane: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA________________________________ Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHTSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor._______________________________ Boiling Range (Deg.F) 330-572 Specific Gravity (HgOsI) 0.81 Vapor Pressure (mmHg),68F 2_______ % Volatile (by volume) Nil Solubility in Hater Insoluble IV. REACTIVITY DATAStable: 1 Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Hill not occur. ?. FIRE AND EXPLOSION HAZARD DATALFL: 0.5UFL: 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liauid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None ^^-AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been Identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 Til. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No mi. EMERGENCE AND FIRST AID PROCEDORES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physiciaiu^. 'C ' ' Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 II. SPILL, LEAK AND DISPOSAL PROCEDPRES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. /. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (Deg.F) 330-572 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68F 2_______ % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA- i- ^.......................... ' ____________ Stable: I Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLs 0.5 OFLs 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. October 17, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 y. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection ARencv (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. 0SHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartaiented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. October 17, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 11. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors.. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant Increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No fill, EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If Irritation persists, consult a physician. Launder contaminated clbthing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 IX. SPILL, LEAK ASP DISPOSAL PROCEDURES_______________________________ _______________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoeo) MATERIAL SAFETY DATA SHEET X. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 U. OSHk HAZARD VETEmmiOH CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (8001 424-9300 (Chemtrec) Product Information No.: (4051 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA ' ~ " Appearance and Odor: Clear liquid: paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H,01) Vapor Pressure (mmHg), 68 F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil JU. REACTIVITY WA Stable* X Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND E- XPLOSION HAZARD DATA_____-__ _- __________ ~ LFL* 0.5 - ^UEU 6 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 22, 1986/GASC0210 V. FIRE AA/P EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Aaencv (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRANSPORTATION AWt> STORAGE VOT tfAZARP CLASS-* Combustible. Uouid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. ^ HAZARD INFORMATION ~~ PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. December 22, 1986/GASC0210 VII. HEALTH HAZARD INFORMATION (continued) ______________________________________________________ Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, Including weakness, dizziness, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC7 No OSHA? No mi. EMERGENCE AMP FIRST AID PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK ANV VISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes'*; X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclabie material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 22, 1986/GASC0210 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: General mechanical ventilation should be adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed when splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 22, 1986/GASC0210 (conoco) MATERIAL SAFETY DATA SHEET 1. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Nixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (8001 424-9300 (Chemtrec) Product Information No.: (4051 767-6000 II. OSHA NAZARP PETERMINATION Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H.0=1) Vapor Pressure (mmHg), 68 F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY PATAStable* X Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. -V--.-------F--IR---E----A-N--P--- EXPLOSION -; HAZA7RcD DATA ~ Flash Point (Method used): 115 F min. (TCC) LFL* 0.5 UFL? 6 Autoignition Temperature NFPA: 410F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 28, 1987/GASC0210 V. FIRE AW EXPLOSION HAZARD PATA lcontinued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Azencv (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE VCT HA1ARV CLASS! Combustible lieu-id Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Combustible. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. t/n. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. August 28, 1987/GASC0210 VII. HEALTH HAZARD INFORMATION fcontinued) , Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC7 No 0SHA7 No VIII. EMERGENCE AW FIRST AIV PROCEVURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention* Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL. LEAK ANV DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. August 28, 1987/GASC0210 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: General mechanical ventilation should be adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed when splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0210 U.S. DEPARTMENT OF LABO Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Approved OMB No. 44.13*7 Required under USDL Safety and Health Regulation! for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION I MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. Douglas Oil Company of California (714) 540-1111 address (Number, Street, City, Slate, end ZIP Code) 316Q Airway Avenue^CoBtaMesa. California 92626 CHEMICAL NAME AND SYNONYMS CHEMICAL KAMILV Mixed Hydrocarbons TRADE NAME AND SYNONYMS DO CAL 141 (02 Diesel Fuel & Fumaic a 0 FORMULA SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS % TLV (Unltil ALLOYS AND METALLIC COATINGS FIGMENTS BASE METAL CATALYST ALLOYS VEHICLE SOLVENTS * ADDITIVES METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR OASES TLV % (Units) TLV % (Units) SECTION III - PHYSICAL DATA O.UNG POINT <>.) Tn<Mfll VAPOR PRESSURE (mm Hf.) VAPOR DENSITY (AIR-1) 360 1 mm. 6 SPECIFIC GRAVITY (H^O-l) PERCENT, VOLATILE BY VOLUME {%) EVAPORATION RATE ( - ----------- .... -1) SOLUBILITY IN WATER __ Insol. appearance AND ODOR clear or Llt,ht Yellow Llnuid - Aromatic Odor 0.855 Nil NA SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) 3U It -- lOU Ut EXTINGUISHING MEDIA Foam. Carbon Dioxide. SPECIAL FIRE FIGHTING PROCEDURES None FLAMMABLE LIMITS Dry Chemical. Water Spray Lei 0.4 ....... Up! TTT UNUSUAL FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Class XI Flammable Liquid. PAGE (1) (Continued on reverse side) Form OSHA-20 Rtv. May 71 SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE ` 100-500 com estimated Skin fdrvine of skin): Inhalation (central nervous system malfunction). EMERGENCY ANO FIRST AIO PROCEDURES Wash exposed areas with waters artificial respiration if needed.___Forineestion. olive oil hiot he given t-n retard ahRftrnHfln. Induced vomiting is Questioned. Medical treatment is symptomatic. & _ should. he_ administered promptly. * SECTION VI - REACTIVITY DATA STABILITY UNSTABLE . , CONDITIONS TO AVOID STABLE X INCOMPATABIUTV {Materials to ovoid) ____________________________________ Oxidizing Materials. HAZARDOUS DECOMPOSITION PHOOUCTS Heat. Flame HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OH SPILLED Clean up promptly bv vacuum or absorption in clav or earth. Follow NFPA -Co-da_Eb^_30-1969 for Claes IT Flammable Tinned.__________ __ '____________ _____________ WASTE DISPOSAL METHOD .. Controlled burning. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY protection (SpecifV type) Use air mask or hydrocarbon absorbing respirator for snrav VENTILATION LOCAL EXHAUST SPECIAL MECHANICAL Normal vent Hating OTHER PROTECTIVE GLOVES Rubber as needed to avoid skin contact EVE PROTECTION Required for sprays OTHER PROTECTIVE EQUIPMENT Required under unusual ri.rrnmstanres nr ovpeWenre or mists _ -------- SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDUING AND STORING ____ ____ _ __________ Store outdoors in ventilated area. Keep away from flame or heat equipment._______________ _______________________ OTHER PRECAUTIONS ______________________ In accordance vith NFPA Code No. 30-TQfiQ for Class TT Flammable Liquid. ( PAGE (2) CFO I 90.940 Form OSHA-20 Km, May 72 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil Conoco Product Code: 4142/3510 Synonyms: Fungible All-Purpose Fuel Oil 45 Cetane Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class 11 Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellov liquid; Aromatic odor.__________________ Bolling Range <*F) 350-680 Specific "Gravity <H20-1) 0T86 Vapor Pressure (mmHg),68F 1 % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA _____ LFL: 0.4 UFL; 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500* F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Bo not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (HFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code Ho. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, Ho. 2, combustible liquid, HA 1993 (as appropriate). Placard: Combustible* (Hot required on packages 110 gallons or less). Label: Hone. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorised. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Hone Celling Value Hone Primary Route(s) of Exposure/Entry: Inhalation, skin. AEL Hone Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Ho adverse health effect has been,Identified specifically for-th&s product. Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. February 19, 1985 VIX. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSRA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure, occurs, remove Individual to fresh air^ ,JC.breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed If splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoeo) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil Conoco Product Code: 3503/3510/4142/4182 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties Product/Mixture: Class IT Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellow liquid; Aromatic odor.__________ _______ Boiling Range (F) 350-680 Specific Gravity (H20**1) 0.85-0.93 Vapor Pressure (mmHg),68F _1________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. /*: * -. ... ' T. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. May 15, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Tire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials,. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary Route(s) of Exposure/Entry: Inhalation, skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been Included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. May 15, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause Irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye Irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalatlon: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. May 15, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. T, PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing Is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SFECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. May 15, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Fumace Oil Conoco Product Code: 3510/4142 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OR 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellow liquid; Aromatic odor. Boiling Range (*F) 350-680 Specific Gravity (H20*1) Vapor Pressure (mmHg),68*F 1________ % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500* F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. July 12, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued!) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION_______________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate - VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmentled tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary Route(s) of Exposure/Entry: Inhalation, skin. AEL None Signs and Symptoms of Expo?ure/Medlcal Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. July 12, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700?) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: Ko mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately.consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. July 12, 1985 t IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as Incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES* * Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. * - The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. July 12, 1985 fcanoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name; No. 2 Diesel Fuel/Furnace Oil/Furnace Oil LP Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid os per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellow liquid; Aromatic odor. Boiling Range (*F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg),68F J.__ Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: WJ.il not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4________ UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 29, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class IX Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary Route(s) of Exposure/Entry: Inhalation, skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by ExposuA-; No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. August 29, 1985 VII, HEALTH HAZARD INFORMATION (continued) House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700*F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Bata from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No 05HA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. August 29, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as Incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 29, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/Furnace Oil LP Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267* Ponca City, OK 74603 Transportation Emergency No.: <800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Ef-Ce^t Properties: None. HAZARD DATA Not'applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHXSICAL DATA Appearance and Odor: -Clear or light yellow liquid; Aromatic odor._____________ ________ Boiling Range (Deg.F) 350-680 Specific Gravity (H20=1) 0~.~85-0.93 Vapor Pressure (mmHg),68F 1________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: I Unstables Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. T. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 4, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxidet carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA)HAZARD RATING HAZARD IDENTIFICATION_____________________ Least - 0 Slight - 1 Health 0 Fire 2 Reactivity 0 High - 3 Extreme - 4 Moderate - 2 VI.TRANSPORTATION AMD STORAGE ' DOT HAZARD CLASS; Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible4 (Not required on packages 110 gallons or less). Label: None. 4 Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. 11. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Celling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 4, 1985 VII. HEALTH HAZARD INFORMATION (continued) House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to Ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median^let-hal dose, rat oral: 9 ml/kg' ` ~ Skin toxicity, rabbits: Ho mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Hash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X Wo In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Dispos^L.Hethod: Recycle as much of ..the recoverable>yproduct as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANT LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 (conoco) MATERIAL SAFETY DATA SHEET 9 I. KAT55UAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/Furnace Oil LP Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Mnaufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determtaabion: Health Effect Properties: None. HAZARD DATA '' Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHXSICAL DATA Appearance and Odor: Clear or light yellow liquid; aromatic odor. Boiling Range (Deg.F) 350-o80 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68F 1_______ % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IT. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ? FIRS AND EXPLOSION HAZARD DATA IJLS 0.4 UFLa 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 17, 1985 ? FIRE ASP EXPLOSION HAZARD DATA (continued) -~ Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 _ VI.TRANSPORTATION AND STORAGE HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 - y-- '>f DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. ?II. HEALTH HAZARD INFORMATION; PEL 500 ppm (petroleum distillates) I^^ TLV Not Established =- Celling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen In similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 17* 1985 fll, HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel,..funded by the American-Petroleum Institute: - -- Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities In newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AMD FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II, SPILL. LEAK AHD DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself sis possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste DisposaJJjethod: Recycle as much of the recoverable*product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAPTIONARY MEASURES ; ________ __________________ ; Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Mnaufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHXSICAL DATA - Appearance and Odor: Clear or light yellow liquid; aromatic odor. Bolling Range (Deg.F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg)t 68F J_______ % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV, REACTIVITY DATAStable: I Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. . FIRE AND EXPLOSION HAZARD DATA ' LFLrO.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not Ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. January 31, 1986/GASC0220 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least * 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liauid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established- AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. January 31, 1986/GASC0220 11. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye Irritation, rabbits: Non-irritating' Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen -or Potential Carcinogen by: NTP No IARC No OSHA No 7III. EMERGENCY AND FIRST AID PROCEDORES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material *5 swallowed,'do not induce vomiting. If'tfdmltlng begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 31, 1986/GASC0220 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids-by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. *: The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 31, 1986/GASC0220 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIA! IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Registry No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. 0SHA HAZARD DETERMINATION Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. HI. PHYSICAL DATA Appearance and Odor: Clear or lizht yellow liquid; aromatic odor. Boiling Range (F) 350-660 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68 F 1 % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY VATA ___________________ Stable.: X Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. EIRE AND EWLOSm HAZARD VATA___________________________ LEU 0.4 UH* 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 22, 1986/GASC0220 V. FIRE ANP EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION ANO STORAGE POT HAZARD CLASS: Combustible. Uouid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:' Minimize exposure. Use in well-ventilated area. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim*s head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. December 22, 1986/GASC0220 m. HEALTH tfAZARP INFORMATION (continued)___________ House skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP7 No IARC7 No OSHA? No mi* EMERGENCY AW FIRST AW PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove Individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPIU. LEAK MW VISPOSkL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No /,* - - - In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 22, 1986/GASC0220 X. PRECAUTIONARY MEASURED Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 22, 1986/GASC0220 I fconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IVEMinCATION Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 ii. osha hazard venmmiOH CAS Registry No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: `Clear or light yellow liquid: aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68 FI % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY PATAStables X Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AW EXPLOSION HAZARD PATA_______________________LVL* 0.4________UFL* 6 Flash Point (Method used): 130 F min* (TCC) Autoignition Temperatures^475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 23, 1986/GASC0220 V. FIRE AND EXPLOSION HAZARD DATA (continued)___________________________________ ______________ Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS- Combustible, Uould Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:' Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 23, 1986/GASC0220 m. HEALTH HAZARP INFORMATION {continued)____________ House skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may csuse pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No 0SHA7 No mi. EMERGENCE AMP FIRST Alt? PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, IEAK ANP VXSPOSAL PRQCEVURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 23, 1986/GASC0220 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 23, 1986/GASC0220 | (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IPEttrXFICATlOA/ Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3504/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 IX. OSHA HAZARD DETERMINATION ~~ CAS Registry No.: Mixture Transportation Emergency No.: (8001 424-9300 (Chemtrec) Product Information No.: (4051 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. XXX. PHYSICAL DATA Appearance and Odor:'Clear or light yellow liquid: aromatic odor. Boiling Range (F) 350-680 Specific Gravity (Ha0=l) Vapor Pressure (mmHg), 68 F ,1 % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil XV. REACTIVITY PATA____________ ______________ Stable,'- X UnitabU'- Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V7~ FIR^Af/P EXPLOSION HAZARD PATA LfU 0.4 UVU 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperaturej^ftXS-SOO0 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. May 29, 1987/GASC0220 -<kUeJL Sh U1 V. FIRE AMD EXPLOSION HAZARD VATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AWD STORAGE POT HAZARD CLASS: CombuvtibU UotUd Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:' Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION _________________________________________________________________ PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. May 29, 1987/GASC0220 Vll. HEALTH HAZARD INFORMATION IconUnu&d) Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No WIT. EMERGENCY ANP FIRST AIP PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material Ingested. IX. SPILL, LEAK ANP DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. May 29, 1987/GASC0220 X. PRECAtSTIOHARV MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. May 29, 1987/GASC0220 t Cconoco) MATERIAL SAFETY DATA SHEET i. material iVEmncAnou Name: No. 2 Diesel Fuel/Fumace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3504/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74603 CAS Registry No.: Mixture Transportation Emergency No.: (8001 424-9300 (Chemtrec) Product Information No.: (4051 767-6000 71, OSHAHAIARV DETERMINATION Hazardous Ingredients: ... - '>/ Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSI CAL VATA ADDearance and Odor: -Clear or lieht vellow liauid: aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H^O5*!) Vapor Pressure (mmHg), 68 F 1 % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY VATA Stable* X Unstable! Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE ANP EXPLOSION HAZARD DATA LFU 0.4 U?U 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature NFPA: 494F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 28, 1987/GASC0220 V. FIRE AW EXPLOSION HAZARD DATA fcontinued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2. Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRAWSPORTATIObi AW STORAGE DOT HAZARD CLASS: Combustible, timid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: ' Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. August 28, 1987/GASC0220 VII. HEALTH HAZARD INFORMATION iconUnuzd)_ Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC7 No OSHA? No VIII. EMERGENCE AW FIRST ATP PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL. LEAK ANP VISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. August 28, 1987/GASC0220 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or othe,r protective^ppparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0220 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 11. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 12Q-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If ..overexposure occurs, remove individual to fresh air. -I&fhreathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 II. SPILL, LEAK AND DISPOSAL PROCEDURES_______________________________________________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 (csnoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Paraffinic and isoparaffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H20-1) Vapor Pressure (mmHg),68*F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials,'heat, flame. Hazardous Polymerization: Will not occur. - V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored In accordance with NFPA procedures for Class 11 Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION_______________________ HAZARD RATING Health 0 Fire 2 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI, TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route (a) of Exposurey'Entry: Skin,, inhalation. -- <***.< Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect Information from animal or human studies has been Included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low Incidence of-tumors. Studies of petroleum workers have not shown a significant Increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats, listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contamlnate4._^eather shoes should be discarded Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim*s head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 U.S. L PARTMENT OF LABOR C jpational Safety and Health Administn. >n MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION 1 MANUFACTURER'S NAME CONOCO INC. ADDRESS (Notnbaf. Straat, City. State, and ZIP Coda) 1000 South Pine, Ponca City, OK 74603 CHEMICAL NAME AND SYNONYMS CHEMICAL FAMILY Mixed Petroleum Hydrocarbons FORMULA EMERGENCY TELEPHONE NO. (405) 767-3456 TRADE NAME AND SYNONYMS CONOCO KEROSENE SECTION II--HAZARDOUS INGREDIENTS Under current laws, rules, and regulations, this material is considered non-toxic and non-hazardous, - - eOBJNG POiN^ rF) Initial VAPOR PRESSURE (mm Hg) VAPOR OENSfTY (AIR -1) SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION III--PHYSICAL DATA 330-3S0 2 5.2 , SPECIFIC GRAVTTY (HjO 1) PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE --------------------------------1) Insoluble Clear, paraffinic odor. *^HPO,T ,.<, U, SECTION IV--FIRE AND EXPLOSION HAZARQ DATA 135_ls0oF- (coc) FLAMMABLE LIMITS EXTINGUISHING MEDIA Foam, dry chemical, caTbon dioxide, water spray. SPECIAL FIREFIGHTING PROCEDURES None LM 0.5 0.81 Nil NA Uel 2.8 UNUSUAL FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA Procedures for Class II Flammable Liquid. PACE (1) (Continued on rivim side) FormOSHA-20 Rev. May 72 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor. Boiling Range (Deg.F) 330-572 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68F 2_______ % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA_______________ ____________________________ Stable: I Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. /`k, - ' ' V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored In accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use Hater spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 17, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 V, FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION . HAZARD RATING Health 0 Fire 2 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223* Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSKA Label: Combustible Liquid. Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. 11. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Routes of Expcsure/Eiiry: Skin, "Irihalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been Identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 17, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause Irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. .Inbreathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 CAS Registry No.: Mixture, 6117212-38-7, 8008-20-6 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267* Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA _________________________________________________ Appearance and Odor: Clear liquid, paraffinic odor._______________________________ Boiling Range (Deg.F) 330-572 Specific Gravity^H20=1) 6.81 Vapor Pressure (mmHg),68F 2_______ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: I Unstable; Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 ?. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA). HAZARD IDENTIFICATION_____________________ HAZARD RATING Health 0 Fire 2 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 ?1. TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been 'iffdluded on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 11. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No 7III. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If ..overexposure jaccurs, remove individual to fresh air. - Lf^breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES_____________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. u.- The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Paraffinic and isoparaffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (Ha0l) Vapor Pressure (mmHg),68cF 2_______ X Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. . Conditions to Avoid: Oxidizing materials, * heat, flame. * Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500"F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 CAS Registry No.: Mixture 64742-38-7, 8008-20-6 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Skin, inhalation. -- Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant Increased incidence of skin tumors* The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxlcity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No 1ARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated closing before reuse. Extremely contamlnated.Aeather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim*s head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture 64742-38-7, 8008-20-6 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 U.s. L APARTMENT OF LABOR C .pational Safety and Health Administrc >n MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915. 1916, 1917) SECTION 1 MANUFACTURER'S NAME CONOCO INC. ADDRESS (Numoar, Stnet, City, Slat*, and ZIP Coda) 1000 South Pine, Ponca City, OK 74603 CHEMICAL NAME ANO SYNONYMS CHEMICAL FAMILY Mixed Petroleum Hydrocarbons FORMULA EMERGENCY TELEPHONE NO. (405) 767-3456 TRADE NAME AND SYNONYMS CONOCO KEROSENE SECTION 11--HAZARDOUS INGREDIENTS Under current laws, rules, and regulations, this material is considered non-toxic and non-hazardous. - BOIUNG POINT rF) initial VAPOR PRESSURE (mm HqJ VAPOR OENSITY (AIR -1) SOLUBILITY IN WATER - appearance and odor SECTION III--PHYSICAL DATA 330-350 2 5.2 SPECIFIC GRAVTTY <H,01) PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE l------------------------------- -11 Insoluble' Clear, paraffinic odor. 0.S1 Nil NA ----wgsje.1.-1 SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (MtmoO UMd) 135-150F. (COC) FLAMMABLE LIMITS EXTINGUISHING MEDIA Foam, dry chemical, carbon dioxide, water spray. SPECIAL FIREFIGHTING PROCEDURES None LI 0.5 Uel 2.8 UNUSUAL FIRE ANO EXPLOSION HAZAROS Handle and store in accordance with NFPA Procedures for Class II Flammable Liquid. PAGE (1) (Continued on r*vfM Form OSHA-20 R*v. May 72 y (conoco) MATERIAL SAFETY DATA SHEET I MATERIAL IDENTIFICATION___________ Name: Super Unleaded Gasoline/Premlum Unleaded Gasoline Conoco Product Code: 1420/1200 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71*43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA___________________________________________ Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EIPLOSIOK HAZARDDATA LFL: 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 25, 1986/GASC0130 V, FIRE ASP EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA)"GLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203- Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. . Wash thoroughly with soap and water after contact. Flammable Liquid. 11. HEALTH HAZARD INFORMATION ____________________ __; PEL Not Established TLV 300 ppm ' Ceiling Value Not Established AEL Not Established - *-4J**^^** Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. April 25, 1986/GASC0130 VII, wealth HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute; Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical - attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material i^s. swallowed, do.not induce vomiting. If'vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC0130 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak; Contain spill immediately In smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES : Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESISCT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. April 25, 1986/GASC0130 fconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Codes 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Keg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS_____________________ HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney In laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mix ture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 5-437 Specific Gravity (H20=1) 0.70-0.77 Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) J00 Solubility in Water Insoluble IV. REACTIVITY DATA Stable: Z Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store In accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 198!jfs/GASC0140 V. FIRE AND EIPLOSIOH HAZARD DATA (continued) ~" Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable llauid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If Ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. t<r VII. HEALTH HAZARD INFORMATION_______________ . PEL Not Established TLV 300 ppra "Gasoline" Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 Til. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen In similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 II. SPILL. LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No ___________ ____ In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES _________________ _______________ _______________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or If splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO* January 17, 1986/GASC0140 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION________________ Name: Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA o Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liould; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA _________ Stable; I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ?. FIRE AND EXPLOSION HAZARD DATA ~ IFIA T.3 PFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 f. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Hater may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool* If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Hater spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may . contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respirator*** protection.' National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liauld Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Hash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medleal Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 12, 1985 11. HEALTH HAZARD INFORMATION (continued) ____________ Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. Studies of petroleum workers have not shown a significant Increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gaspline, funded by the Amert3zTPetroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye Irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen .or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Nash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 H. SPILL, LEAK AND DISPOSAL PROCEDURES_____________________________ ___ ____________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill op Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I.__ PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IDENTIFICATION__________________ ___ Mamet Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267* Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Sftecific Gravity (HgOsI) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA _______ Stable: E Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLi 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCP Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 . FIRE AND EXPLOSION HAZARD DATA (continued) . ^ .. : Special Fire Fighting Procedures: Water may be Ineffective to extinguish, but water should be used to keep fire-exposed containers cool* If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak* Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may . contain carbon monoxide, carbon dioxide and other toxic materials* Do not enter enclosed or confined space without proper protective equipment including respirator protection; National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 ITRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately* Wash thoroughly with soap and water after contact. Flammable Liquid* 11, HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Celling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors* December 12, 1985 ?II,, health HAZARD INFORMATION (continued) House skin pointing studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye Irritation, rabbits: Non-irritating Genotoxlc studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen .or Potential Carcinogen by: NTP No IARC No OSHA No VIII. BffiRGEKCI AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Nash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestlon: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES--- RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES__________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. O. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dibromide (106-93-4) A potential mutagen and tumorigen. Ethylene dichloride (107-06-2) A potential mutagen and tumorigen. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Bronze or red clear liquid; Gasoline odor. Boiling Range (CF) 85-437 Specitic Gravity (H20-1) Vapor Pressure (mmHg)@68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant Increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration.: Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material Ingested. February 19 1985 U.S. DEPARTMENT OF LABOR Occupational Safety zr.d Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)______ SECTION 1 MANUFACTURER'S NAME CONOCO INC. ADDRESS (Number, Stmt, City, State, ana Z3P CoOe) 1000 South Pine Street, Ponca City, OK 74603 EMERGENCY TELEPHONE NO. (405) 767-3456 CHEMICAL NAME AND SYNONYMS Automotive Leaded Gasoline CHEMICAL FAMILY Mixed petroleum hydrocarbons. FORMULA TRADE NAME ANO SYNONYMS CONOCO REGULAR GASOLINE SECTION II--HAZARDOUS INGREDIENTS Recent studies with laboratory animals have shown that gasoline vapors can cause kidnev damage and cancer in rats and liver cancer in mice. Aromatic Hydrocarbons Benzene ' Lead (as lead alkyls) 10-35-6 LT l`c 0.H BOILING POINT CF) VAPOR PRESSURE (mm Hg) VAPOR DENSITY (AIR-1) SOLU81LTTY IN WATE'-< appearance and ODOR SECTION III--PHYSICAL DATA RVP , psia ApprOX. 85-434 10-15 3.5 SPECIFIC GRAVITY (HaO -1) PERCENT, VOLATILE BY VOLUME (%) (EV.APO.R.A.TITON YRATEatsrApprox. Insoluble Bronze ot red cleaT liquid - gasoline odor. SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Metfxxt Usd) ____________ Mav be as low as -50F. - TCC. EXTINGUISHING MEDIA Foam, Carbon Dioxide, Dry Chemical FLAMMABLE LIMITS LSI 1^-4% SPECIAL FIREFIGHTING PROCEDURES Use water spray to disperse vapors and protect personnel 0.70-0.77 100 2+ Usl J7-J& UNUSUAL FIRE AND EXPLOSION HAZARDS Highly flammable. Moderate explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on rsvsrss tiOs) Form OSHA-20 Rev. Mty 72 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Cheratrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dibromide (106-93-4) A potential mutagen and tumorigen. Ethylene dichloride (107-06-2) A potential mutagen and tumorigen. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Bronze or red clear liquid 1 gasoline odor. Boiling Range (Deg.F) S5-437 Specific Gravity (H20=1) Vapor Pressure (mmHg)at 68F 75-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. October 17, 1985 ?. FIRE AND EXPLOSION HAZARD DATA LFL; 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (HFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - High - 3 Extreme - 4 ?I.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Not Flammable. OSHA Label: CAUTION: Minimize exposure. This product contains benzene, lead, ethylene dibromide, ethylene dichloride, and certain hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION__________________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. October 17, 1985 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EHERGENCX ANITfIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II, SPILL, LEAK AHD DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I, PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists. Other Protective Equipment: Coveralls should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 1124-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Tetraethyl lead (78-00-2) Toxic to the nervous system, blood and blood-forming tissues, gastrointestinal tract, liver, pancreas, and kidney. Ethylene dibromide (106-93-4) A potential mutagen and tumorigen. Ethylene dichloride (107-06-2) A potential mutagen and tumorigen. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Bronze or red clear liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATAStable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. December 11, 1985 7. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 PFL: TIE Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection AgencV {NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene, lead, ethylene dibromide, ethylene dichloride, and certain hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 711. HEALTH HAZARD INFORMATION__________________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. December 11, 1985 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 11, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists. Other Protective Equipment: Coveralls should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 11, 1985 (conoeo) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION___________________________________________________ ___ Name; Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 IX. OSHA HAZARD DETERMINATION CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and paraffinic hydrocarbons;- e.g., toluene, hexane, etc.) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. mSICAL DATA Appearance and Odor: Bronze or red clear liquid; gasoline odor. Boiling Range (F) 85-437 Specific Gravity (Ha0=l) Vapor Pressure (mmffg) @ 68 F 275-475 % Volatile (by volume) Solubility in Water Insoluble ID. REACTIVITY DATAStable X UnAtabte.: 0.70-0.77 100 Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. V. FIRE AND EXPLOSION HAZARD DATA UFL* 171 UFL-- 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. January 9, 1987/GASC0120 V. FIRE MW EXPLOSION HAZARD VATA lcontinued) Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VJ .TRANSPORTATION AArt? STORAGEVOT HAZAtW CLASS? Flammable, liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION:' Minimize exposure. This product may contain benzene, which may be toxic to blood and blood-forming tissues or cause cancer. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Flammable Liquid. VII. HEALTH tfAZARP INFORMATION PEL Not Established TLV 300 ppm TVA; 500 ppm STEL Ceiling Value Not Established Du Pont AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rats and mice have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. January 9, 1987/GASC0120 VII. WEALTtf HAZARD INTONATION IconUnuddl House skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. can also be toxic to the blood and blood-forming tissues. Benzene The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No VU1. EMERGENCY AW FIRST AID PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 9 1987/GASC0120 IX> SPILL. LEAK AW VISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is flammable. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use appropriate NIOSH-approved respiratory protection where atmospheric concentrations may exceed acceptable exposure limits. Ventilation: Use adeguate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Chemically resistant such as neoprene or NBR as needed to minimize skin contact. Eye Protection: Face shield for sprays/mists. Other Protective Equipment: Coveralls or other protective apparel should be worn if splashing is probable. Soiled clothing should be removed and laundered. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 9, 1987/GASC0120 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Leaded Regular Gasoline Conoco Product Code: 1100 Synonyms: Automotive Leaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 IZ. 0SHA HAZARD DETERMINATION Hazardous Ingredients: Hydrocarbons (Aromatic and paraffinic hydrocarbons; e.g., toluene, hexane, etc.) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHVSJCALDATA Appearance and Odor: Bronze or Boiling Range (F) Vapor Pressure (mmHg) @ 68 F Solubility in Water red clear 85-437 275-475 Insoluble liquid; gasoline odor. Specific Gravity (H20=1) % Volatile (by volume) . 0.70-0.77 100 IV. REACTIVITY DATA Stable* X Unstable*' Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Incompatible Materials: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. Conditions To Avoid: Undue exposure to air. V. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL* 7.6 Flash Point (Method used): As low as -50F (TCC) Autoignition Temperature NFPA: 536-853F Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. August 28, 1987/GASC0120 V. FIRE AW EXPLOSION HA2ARV VATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION kW STORAGE VGT HAZARP CLASS- fjgjmabU Uoaid~ Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable Liquid. OSHA Label: CAUTION: Minimize exposure. This product may contain benzene, which may be toxic to blood and blood-forming tissues or cause cancer. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Flammable Liquid. VII. HEALTH HAZARD INFORMATION____________________________________ PEL Not Established TLV 300 ppm TWA; 500 ppm STEL Ceiling Value Not Established Du Pont AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. August 28, 1987/GASC0120 m. HEALTH HAZARD INFORMATION lconinue.d) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rats or mice have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. can also be toxic to the blood and blood-forming tissues. Benzene The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No VIII. EMERGENCY ANV FIRST AIP PROCEPURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. August 28, 1987/GASC0120 IX. SPILL. LEAK AW DISPOSAL PKOCBVUKtS KCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is flammable. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of. residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. T. PRECAUTIONARY MEASURES ~ Respiratory Protection: Use appropriate NIOSH-approved respiratory protection where atmospheric concentrations may exceed acceptable exposure limits. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards'and explosive mixtures. Protective Gloves: Chemically resistant such as neoprene or NBR as needed to minimize skin contact. Eye Protection: Face shield for sprays/mists. Other Protective Equipment: Coveralls or other protective apparel should be worn if splashing is probable. Soiled clothing should be removed and laundered. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. Bonding shall be provided when transferring product between metal containers. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0120 Occupational Safety and Health Administra*5nn --MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION! MANUFACTURER'S NAME CONOCO INC. ADORESS [Njmttar, Str**, City, Staia. and ZIP Coda) 1000 South Pine Street, Ponca City, OK 74603 EMERGENCY TELEPHONE NO. ' (405) 767-3456 CHEMICAL NAME AND SYNONYMS , ,i . . AufoUto'tive' Unleaded'^Gasdl'ine* CHEMICAL FAMILY Mixed petroleum hydrocarbons. FORMULA TRADE NAME ANO SYNONYMS CONOCO UNLEADED GASOLINE" " _______________________ SECTION 11--HAZARDOUS INGREDIENTS__________ Recent studies with laboratory animals have shown that gasoline vapors can cause kidney damage and cancer in rats and liver cancer in mice.______________ Aromatic Hydrocarbons Benzene 10-35% LT 5% BOIUNG POINT (*F) VAPOR PRESSURE (mm Hg) VAPOR DENSITY (AIR -1) SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION III--PHYSICAL DATA RVP, psia Approx. Insoluble 85-434 10-15 3.5 -- SPECIFIC GRAVITY (H*0-1) PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE t WateT -i) Approx. Water white to straw vellow - gasoline odor. ------ -0.70-0.77 100 2+ SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Mmod Used) Mav he as low as -50F. - -TCC EXTINGUISHING MEDIA __Foam, Carbon Dioxide, Dry Chemical FLAMMABLE LIMITS Ld< 1.4% SPECIAL FIREFIGHTING PROCEDURES Use water spray to disperse vapors and protect personnel. .. Utf 7.6% - *; UNUSUAL FIRE ANO EXPLOSION HAZARDS Highly flammable. Moderate explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on rtvors* afd) Form OSHA-20 Rv. May 73 SECTION V--HtALTH HAZARD DATA THRESHOLD UMIT VALUE EFFECTS OF OVEREXPOSURE AppTox. 100-200 ppm in air. LD50(oral)= 18.75 ml/kg (Tat). Ma-rked vertigo, incoordination.___ In severe cases: convulsions coma, asphyxia. EMERGENCY AND FIRST AI0 PROCEDURES Wash exposed areas with water; artificial respiration if needed. For ingestion, olive oil may be given to retard absorption. Do not induce vomiting. Medical treatment is symtomatic and should be administered prompt V STABILITY unstable SECTION VI -- REACTIVITY DATA CONDITIONS TO AVOIO STABLE X INCOMPATABILfTY (MatanaJs to avoid) Oxidizing materials , heat, flame. HAZARDOUS DECOMPOSITION FROOUCTS,. CO may oe formed from incomplete combustion. HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR X Undue exposure to air. # SECTION VII -- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Clean up promptly by vacuum or absorption in clay or earth. Vapors are a health and ft-yplosion hazard WASTE OISPOSAL METHOD Controlled burning with great caution. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. _____ SECTION VIII--SPECIAL PROTECTION INFORMATION RESPIRATORUY sPeROTaECirTIOmN (aSspkaatov frvpaH) yd, rocarb. on a,bsor,bi. ng respirator. VENTILATION L5$a4S^$1rking hazards and explosive mixt iffSS1*- MECHANICAL (Gantra/) OTHER Adequate to meet recommended concentrati ons. PROTECTIVE GLOVES ,. EYE PROTECTION ,, ,. ,,, ,, .. Rubber - as needed to avoid skin contact. Goggles or face shield for sprays/mists ^otec?iveVEc^t15?ng should be worn. Soiled clothing should be removed $ laundered. SECTION IX--SPECIAL PRECAUTIONS ;precautions to^Ts^an^arcpLgf/o?inefli e^uipment storage tanks, pumps , lines . OTHER PRECAUTIONS ______ Use explosion proof equipment. Vapors are heavier than air. PAGE (2) GPO 934-110 Form OSHA-20 Rav. May 72 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 11. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHTSICAL DATA Appearance and Odor: Water white to straw yellow liquid: gasoline odor. Bolling Range (Deg.F) 85-437 Specific Gravity (H20=T) Vapor Pressure (ramHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0*77 100 IV. REACTIVITY DATAStable: X Unstable; Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. VT FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 7.b Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 1985/GASC0140 7. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 71.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 711. HEALTH HAZARD INFORMATION_____________________________ PEL Not Established TLV 300 ppm "Gasoline" Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors* However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES " --" Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASCOI^O II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; Gasoline odor. Boiling Range (F) 85-437 Specific Gravity (H20"1) Vapor Pressure (mmHg)@68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATALFL: 1.3UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. February 19, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill haB not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION________________________ Health I Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate - 2 VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. Label: Flammable liquid. VII. HEALTH HAZARD INFORMATION PEL None TLV 300 ppm Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant Increased incidence of skin tumor8. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic .studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures* Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IDENTIFICATION________ __ Name: Unleaded Gasoline Conoco Product Code: 1*110/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc, Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 42*1-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0,70-0-77 _______ _ IF. REACTIVITY DATA Stable: Z Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from Incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ?. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. October 17, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued? Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 11. HEALTH HAZARD INFORMATION_____________________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. October 17* 1985 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing,'draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/raists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROH THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION_______________________ Name: Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA _____________________ ;Stable; I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from Incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE~AHD~BgLOSIOff HAZARD DATA LFL: 1.3 UFLa 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 T. FIRE ASP EXPLOSION HAZARD DATA (continued) "~ Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may . contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respirator protection.' National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate - High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If Ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. Til. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Celling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen In similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 12, 1985 11. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No 111. EMERGENCY AND FIRST AID PROCEDURES ' Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 II. SPILL, LEAK AHD DISPOSAL PROCEDURES______________ _____ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated Items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES_____________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administra+^n _MATERIAL SAFETY DATA SHEET_____ Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION! MANUFACTURER'S NAME CONOCO INC. ADDRESS (Number, Street, Gily. State, and ZIP Code) 1000 South Pine Street, Ponca City, OK 74603 EMERGENCY TELEPHONE NO. (405) 767-3456 CHEMICAL NAME AND SYNONYMS -----------Automotive UnleadedTasolihe CHEMICAL FAMILY Mixed petroleum hydrocarbons. formula TRADE NAME ANO SYNONYMS CONOCO UNLEADED GASOLINE' ______________________ SECTION II--HAZARDOUS INGREDIENTS_________ Recent studies with laboratory animals have shown that gasoline vapors can cause kidney damage and cancer in rats and liver cancer in mice._______ Aromatic Hydrocarbons Benzene 10-35% LT 5% BOILING POINT (*F) VAPOR PRESSURE (mm Hq) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION III--PHYSICAL DATA RVP, psia Approx. 85-434 10-15 3.5 SPECIFIC GRAVITY (H^O -- 1) PERCENT. VOLATILE BY VOLUME (%) tEVAPORAWTIOaNteRArTE .u Aoprox. Insoluble Water white to straw vellow - easoline odor. ----------0.70-0.77 100 2+ SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Metnod Used) Mav be as low as -50F. - -TCC EXTINGUISHING MEDIA ____Foam, Carbon Dioxide, Dry Chemical FLAMMABLE LIMITS Lei 1 4% ..... Uel 7 fi* SPECIAL FIREFIGHTING PROCEDURES Use water spray to disperse vapors and protect personnel. - -- ~~.......- -- * * "* ' - - . UNUSUAL FIRE ANO EXPLOSION HAZAROS Highly flammable. Moderate-explosion hazard. Flowing gasoline can be PAGE (1) ignited by self-generating static electricity. (Continued on revere* side) Form OSHA*20 Rev. May 73 THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE SECTION V -- HEALTH HAZARD DATA Approx. 100-200 ppm in air. LD50(oral)* 18.75-ml/kg (rat). Mot-VpH vptTtpo. incoordination. In severe cases: convulsions. coma, asphyxia. EMERGENCY AND FIRST AID PROCEDURES Wash exposed areas with water: artificial respiration if needed. For ingestion. olive oil may be given to retard absorption. Do not induce vomiting. Medical treatment is symtomatic and should be administered prompt STABILITY UNSTABLE SECTION VI--REACTIVITY DATA CONDITIONS TO AVOID STABLE X INCOMPATASIUTY (Matana/S to avoid) Oxidizing materials , heat, flame. HAZARDOUS DECOMPOSITIONPROOUCTS,. . , CO may De formed from incomplete combustion. HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR X Undue exposure to air. . SECTION VII--SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Clean up promptly by vacuum or absorption in clay or earth. Vapors are a .health and explosion Tifly.ard. WASTE DISPOSAL METHOD Controlled burning with great caution. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. SECTION VIII --SPECIAL PROTECTION INFORMATION RESPIRATORuSsPeROTaEiCrTIOmN/aSspktfciAortrvHpa)yd,rocarb, on a,bsor,bing resp.irator. VENTILATION LS?chSCHl^&king hazards and explosive mixt MECHANICAL (GanaraS) OTHER Adeauate to meet recommended concentrati ons. PROTECTIVE GLOVES EYE PROTECTION _ ,. , _ .. Rubber - as needed to avoid skin contact. Goggles or face shield for sprays/mists TOotecSv^^^otlifng should be worn. Soiled clothing should be removed laundered. ______________________ SECTION IX --SPECIAL PRECAUTIONS________________ PREWIfl^eSonf^Ts^Ean^axrcPuglsAo?iniRie^uipiIient; storage tanks, pumps, lines. OTHER PRECAUTIONS ______ Use explosion proof equipment. Vapors are heavier than air. PAGE (2) GPO 934-110 Form OSHA-20 Rev. May 72 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Kane: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 B CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II.__ HAZARDOUS INGREDIENTS ______ ________HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney In laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture! Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (HgOsI) Vapor Pressure (mraHg) at 68F 275-475 % Volatile (by volume) Solubility In Water Insoluble 0.70-0.77 U)0 IV. REACTIVITY DATA ________ ______________________ ___________ Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ?. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 7.6 ~ Flash Point (Method used): As low as -50F (TCC) Handle and store In accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 198jf/GASC0l40 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code Ho. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact* Flammable Liquid. 11. HEALTH HAZARD INFORMATION___________________ _ PEL Hot Established TLV 300 ppm "Gasoline" Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 YII. HEALTH HAZARD INFORMATION (continued)- Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No YI1I. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Vash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent voraitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 II. SPILL, LEAK ASP DISPOSAL PROCEDURES____________________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 I?. REACTIVITY DATA Stable: I Unstable; Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EIPLQ5I0H HAZARD DATA LFLs 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. January 17, 1985/GASC0140 y. FIRE AMD EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLASS; Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description; Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION_____________________________ PEL Not Established TLV 300 ppm "Gasoline" Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 VII. HEALTH HAZARD INFORMATION {continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If Irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 II, SPILL, LEAK ASP DISPOSAL PROCEDURES_______________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES__________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. Hie above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 (eonoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: III. PHYSICAL DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher Incidence of leukemia. Class 1 A Flammable Liquid per NFPA Code No. 30-1984. Appearance and Odor: Water white to straw yellow liquid; Gasoline odor. Boiling Range (F) 85-437 Specific Gravity (H20-1) Vapor Pressure (mmHg)<368F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0.77 100 IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATALFL: 1.3UFL: 7.6 Flash Point (Method used): As low as -5QF (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. February 19, 1985 V, FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool* If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. Label: Flammable liquid. VII. HEALTH HAZARD INFORMATION PEL None TLV 300 ppm Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies Involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 ( VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic*studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary severs. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET X. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline/Premium Unleaded Gasoline Conoco Product Code: 1420/1200 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.; (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid: gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ? FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 PFL; 6.0 lash Point (Method used): As low as -50F (TCC) iandle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. --Anr.i.1 iq86/CASC013Q ?7 FIRE AND EXPLOSION HAZARD DATA (continued) ________________________________ Special Fire Fighting Procedures; Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label; CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. . Wash thoroughly with soap and water after contact. Flammable Liquid. 11. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. April 25, 1986/GASC0130 N v VII. HEALTH HAZARD INFORMATION (continued? Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-7Q0F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC013Q ^Smsusn&iaanimmmmam IX. SPILL, LEAK AND DISPOSAL PROCEDURES__________________________________________________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES_____________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESi-SCT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. April 25, 1986/GASC0130 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc, Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 11. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 0.70-0-77 U)0 IV. REACTIVITY DATAStable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLi 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. October 17, 1985 V. FIRE ASP EXPLOSION HAZARD DATA (continued) ~ Special Fire Fighting Procedures; Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards; Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire 3 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable llauld Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION_____________________________ PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. October 17, 1985 VII. HEALTH HAZARD INFORMATION (continued) _______________ Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight Irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 XI. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No _________________________________________ __ In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing,'draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/ralsts or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 Cconoco) MATERIAL SAFETY DATA SHEET T. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline/Premium Unleaded Gasoline Conoco Product Code: 1*120/1200 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (^0=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0*77 100 IV. REACTIVITY DATA ~ Stables I Unstable:- Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 PFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 25, 1986/GASC0130 11. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration.. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC0130 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Naphtha Conoco Product Code: 1509 Synonyms: Petroleum Naphtha; Full Range Straight Run Naphtha Chemical Family: Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 7*1603 CAS Registry No.: 64741-42-0 Transportation Emergency No.: (800) 424*9300 (Chemtrec) Product Information No.: (405) 767-6000) II. HAZARDOUS INGREDIENTS_________ Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Benzene (71-43-2) Physical Effect Properties: Product/Mixture: HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. A few studies have shown that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Colorless to yellow liquid; petroleum naphtha odor. Bolling Range 0 F -4 to 430 Specific Gravity (H20=1) 0.7 Vapor Pressure (mmHg), 100 F 500 % Volatile (by volume) 100 Vapor Density (Air=1) >1 Solubility in Water Insoluble IV. REACTIVITY DATA ___________________________________ Stable: _X Unstable: Hazardous Decomposition Products: Normal combustion forms carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions To Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): Below room temperature Autoignition Temperature: Approx. 450 F LFL: 1DFL: 6 November 19, 1985 CAS Registry No.: 647^1-42-0 ?. FIRE AND EXPLOSION HAZARD DATA (Continued) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective, but water should be used keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire_3__ Reactivity^O__ Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 1. TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable Liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid, per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Naphtha, Flammable Liquid, UN 2553 Placard: Flammable D.O.T. Label: Flammable liquid OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable. 11. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm; 900 mg/m^ (Gasoline) Ceiling Value Not Established AEL Not Established Primary Routes of Entry: Skin, inhalation. November 19, 1985 CAS Registry No.: 6W1-42-0 711. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated By Exposure: No adverse health effect has been identified specifically for this product. Health effect information fr^ra animal and human studies has been included on related materials, even tnough health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700 F) caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No 71X1. EMERGENCY AMD FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. If exposed to hot oil, immediately cool with cold water. Do not attempt to remove oil but continue to cool exposed areas with cold packs and seek medical assistance immediately. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. November 19, 1985 CAS Registry No.: 64741-42-0 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes_X_____ No In Case Of Spill Or Leak: Protect from ignition. Contain spill immediately in smallest area possible, being careful to avoid potential ignition sources. Recover as much of the product as possible by such methods as vacuuming, using explosion-proof equipment, followed by use of.absorbent materials. Remove contaminated items including contaminated soii and place in proper container for disposal. The area may be washed down with water, as needed, but steps should be taken to avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material by such methods as controlled incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: None required except under unusual circumstances such as described in Section V. Ventilation: Normal shop ventilation. Mechanical in confined space or where vapors may become high. Protective Gloves: Impervious. Eye Protection: Safety glasses with side shields. Chemical goggles if splashing is probable. Other Protective Equipment: Coverall with long sleeves if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. November 19, 1985 r U.S. DEPARTMENT OF LABOR Form Aerf*4 OMt No. 44-Ua? Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916. 1917) SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. ___________ Conoco. Inc.____ _____ _________ _______ ________________ ______ AOORESS (Number. Street. City. State, and ZIP Codei mnn Smith Pine. Ponca Citv. OK 74603 f40S1 767-3456 CHEMICAL NAME ANQ SYNONYMS CToRnAoDcEoNANMoE. AN1 ODSYiNeOsfeCYl MFSue,l CHEMICAL FAMILY MiyaH oAtToleum hydrocarbons Formula SECTION 11 - HAZARDOUS INGREDIENTS NONE . ~ SECTION 111 - PHYSICAL DATA" BOlLtNO POINT (4F.) VAPOR PRESSURE (mifi Hf.) Tni ti n 1 VAPOR OCNSITV <AIR1> SOLUBILITY IN WATER 330-350 2 5.2 Insoluble SPECIFIC GRAVITY {M301| PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE t !) aprcarance and oooRj-^ear. paraffinic odor 0.81 Jill NA SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Matftod UMd) EXTINGUISHING MEDIA ___ ,PA#f( . 135-150 F. (COC) flammable limits Lai Uai ------ errs-- ------- 2t8-- _ ., , , ,. ______ Foam, Carbon Dioxide, dry chemical, water spray. --r-- - SPECIAL FIRE FIGHTING PROCEDURES ..... -------------------- ` Mnn a ... UNUSUAL fire ANO EXPLOSION HA2AROS Handle and store m accordance ._ with NFPA procedure for Class II Flammable Liquid. PAGE m (Continued on reverse side) Form OSHA-20 ft*v. May 71 SECTION V - HEALTH HAZARO DATA threshold limit valuC Approx. 100-300 ppm estimated, EFFECTS OF OVEREXPOSURE Skin fdrving of skin); Inhalation (central nervous system malfunction) EMERGENCY And first aid procedures . .- ,J -__________________ Wash exposed areas with water, artificial respiration if needed. For ingestion, olive oil may be given to retard absorption. Induced vomiting is questioned. Medical treatment is symptomatic and should be administered promptly. STABILITY UNSTABLE SECTION VI - REACTIVITY DATA CONDITIONS TO AVOID STABLE XIncompatability (HletencU to avoid) Oyldlzing materials. HAZAAOOUS DECOMPOSITION PRODUCTS heat, flame. HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID SECTION VII - SPILL OR LEAK PROCEDURES STECPlSeaTOn BuEpTApKrEoNmINptClAySEbyMAvTaEcRuIAulmTso^RrELaEbASsEoDrpOtRioSnPIUi-nEO c.lay____o___r___e___ar~tvh. Follow MNFWPAi CCro\Ad&e No. 30-1969 for Class II Flammable Liquid._________ W*Contjffi" fuming. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle. SECTION Vlll * SPECIAL PROTECTION INFORMATION RESPIRATORY PRO T CTin (Spcifv type) _. _____ Use air isk or hvdrocaroon absorbing respiratot for sprays or mists. VENTILATION LOCAL EXHAUST SPECIAL mechanical (Gantni) Normal ventilation OTHER PROTECTIVE GLOVES EYE PROTECTION Rubber as needed to avoid skin contact. Required for sprays and mists. OTHER PROTECTIVE EQUIPMENT - Rermired only under unusual circumstances of exposure. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO 8C TAKEN IN HANDLING AND STORING Store outdoors or in ventilatea area. Keep away from flame or heat equipment. TIn"accordance with NFPA Code No. 30-1969 for Class" II"Flammable Liquid. . PAGE (2) PO |4*IB Form OSHA-20 *. My 71 '(Conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor._____________________________________ Boiling Range (F) 330-572 Specific Gravity (H20*1) 0.81 Vapor Pressure (mmHg),68F 2________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. February 19, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 VT FIRE AND EXPLOSION HAZARD^^ATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION________________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. February 1, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxlcity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSKA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture; 64742-38-7* 8008-20-6, 64742-81-0 IX. SPILL* LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming* followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing* draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing Is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H20*1) Vapor Pressure (mmHg),68F 2________ % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. July 25, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION________________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate - VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Celling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. July 25, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant Increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Bata from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim*s head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material Ingested. July 25, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated Items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. July 25, 1985 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.O. Box 1267* Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA____________________________________ Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid; paraffinic odor._________________________________ Boiling Range (Deg.F) 330-572 Specific Gravity (H20=1) 0.81 Vapor Pressure (mmHg),68F 2________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA__________________________ LFL: 0.5_________UFL: 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V. FIRE AND EXPLOSION HAZARD DATA (continued) ~ Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. II. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 12Q-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No ?III. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture; 64742-38-7f 8008-20-6, 64742-81-0 XI. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Cloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA____________________________________ Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA - Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (Deg.F) 330-572 Specific Gravity (H20r1) Vapor Pressure (mmHg), 68F 2_______ % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA__Stable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA__________________________ LFL: 0.5_________PFL: 5 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. October 17, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health _0_ Fire 2 Reactivity _0_ HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. 05HA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been Identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. October 17, 1985 CAS Registry No.: Mixture; 64742-38-7, 8008-20-6, 64742-81-0 TII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel as funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 CAS Registry No.: Mixture; 6*1742-38-7, 8008-20-6, 64742-81-0 II. SPILL, LEAK ASP DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls needed when splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIA/. IDENTIFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. OSHk HA2ARD DETERMINATION Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30*1984. Ill. rHVSlCKL DATA ' Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H*0=1) Vapor Pressure (mmHg), 68 F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA Stable.: x Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA IFL* 0* 5 UFL? 6 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 22, 1986/GASC0210 V. FIRE AMP EXPLOSION HAZARD PATA IcowUnuzd) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Azencv (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE POT WAZARP CLASS' Combustible. Uouid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. December 22, 1986/GASC0210 VJT. HEALTH HAZARD INFORMATION (continued)_____________ Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No WTT. EMERGENCE AMP FIRST A1V PROCEDURES " Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim*s head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AHV VISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should-be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 22, 1986/GASC0210 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: General mechanical ventilation should be adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed when splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 22, 1986/GASC0210 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL 1VEHTXFICATION Name: No. 1 Diesel Fuel/No. 1 Fuel Oil Conoco Product Code: 3501/4195 Chemical Family: Mixed Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 II. OSHA HAZARD VETERM1NATION CAS Keg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6, 64742-81-0 Transportation Emergency No.: (8001 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL VATA ~~ Appearance and Odor: Clear liquid; paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (Hj0=l) Vapor Pressure (mmHg), 68 F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil W. REACTIVITY VATA Stable.' X_____ Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AVP EXPLOSION HAZARD DATA LfU 0.S (IF/,* 6 Flash Point (Method used): 115 F min. (TCC) Autoignition Temperature NFPA: 410F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 28, 1987/GASC0210 V. FIRE AND EXPLOSION HAZARD DATA l continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Azencv (NFPA) Health 0 Fire 2 Reactivity 0 VI.TRANSPORTATION ANO STORAGE HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VOT HAZARD CLASS'* CombuUlbU Uaaid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1964. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 1, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion, or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Combustible. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. August 26, 1987/GASC0210 m. HEALTH HAZARD INFORMATION (continued)_______________ , Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No mi. EMERGENCY AND FIRST AIV PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Vash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AKV DISPOSAL PROCEVURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. August 28, 1987/GASC0210 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: General mechanical ventilation should be adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or if splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed when splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0210 U.S. DEPARTMENT OF LABO Occupation*! Safety and Health Administration MATERIAL SAFETY DATA SHEET Perm Approved OMB No. 44R13I7 Required under USOL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking 129 CFR 1915. 1916. 1917) SECTION I ________________________ MANUFACTURER'S NAME EMERGENCY TELEPHONi NO. Douglas Oil Company of California___________ (714) 540-1111 address (Numbtr, Strtit, City, State. end ZIP Code) 3160 Alrvav Avenue. Costa Mesar California CHEMICAL. NAME AND SYNONYMS 92626 TRADE NAME AND SYNONYMS DOCAL 141 (ff2 Diesel Fuel & Furnats 0 chemical>amiLV Mixed Hydrocarbons FORMULA SECTION II - HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. & SOLVENTS FIGMENTS % TLV {Units) ALLOYS ANO METALLIC COATINGS BASE METAL CATALYST ALLOYS VEHICLE SOLVENTS ' ADDITIVES METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS OTHERS HAZARDOUS MIXTURES OP OTHER LIGUIOS, SOLIDS. OR OASES % TLV {Unit*} TLV % (Unite) SECTION III - PHYSICAL DATA BOILING POINT (eF.) _. __________________ Initial VAPOR PRESSURE {mm H9.) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER APPEARANCE ANO OOOR .. 36n 1 mm. 6 SPECIFIC GRAVITY (W)0-1) PERCENT. VOLATILE BY VOLUME (%) EVAPORATION RATE { .. . -------- 1) ____ IhClL*-- Clear or Light Yellow Liquid-- Aromatic Odor__________ SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method ued) 150 CC - 160 OC FLAMMABLE LIMITS EXTINGUISHING MEDIA Foam. Carbon Dioxide. Drv SPECIAL FIRE FIGHTING PROCEDURES None_____________ Chemical. Water Sdtsv Lei rt L 0.8SS mi NA Ue 'J UNUSUAL FIRE AND EXPLOSION HAZAROS Handle and store in accordance with NFPA PAGE (1) procedure for Class II Flammable Liauid. (Continued on reverse side) Form OSHA-20 Rev. May 72 THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE SECTION V - HEALTH HAZARD DATA 100-500 pnm estimated Skin (drvine of skinl: Inhalation ("central nervous system malfunction'). EMERGENCY ANO FIRST AID PROCEDURES Wash exposed areas with water: artificial resDiration if needed. For ineestion. olive oil wav be oiva-n tn r*ppard sVisnmf-lnn Tndurprf vomitioE is Questioned. Medical treatment is symptomatic & should, he administered prorrmtlv. SECTION VI - REACTIVITY DATA STABILITY UNSTABLE . CONDITIONS TO AVOID , STABLE INCOMPATABILITY (Mattrialt to avotd) X Oxidizing HAZARDOUS OECOMPOSiTION PRODUCTS Materials. Heat. Flame HAZARDOUS 1 ION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X --1 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Clean up promptly bv vacuum or absorption in clav or earth. Follow NFPA Code No. 30-1969 for Class II Flammable. Liquid.!___________________________ _______ WASTE DISPOSAL. METHOD Controlled burning. Storage for professional disposal. Avoid drainage to a sewer unless specifically designed to handle.______________________________________ SECTION VIII - SPECIAL PROTECTION INFORMATION respiratory protection (Specify type) ventilation Use air mask or hydrocarbon abi30Thing.1..?resDirator for sorav. LOCAL EXHAUST SPECIAL T'* mechanical (General) Normal ventilating OTHER PROTECTIVE GLOVES Rubber as needed to avoid skin contact EYE PROTECTION Required for sprays or mists OTHER PROTECTIVE EQUIPMENT Recnnred under unusual rirciimaranopr or Pvppripnre SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANOUNO ANO STORING __________________________________________________________ Store outdoors in ventilated area. Keep away from flame or heat equipment._______________ OTHER PRECAUTIONS _______________________In accordance with NFPA Code No. 30-1Q6Q for Plaa* TI Flammable Liquid. PAGE (2) CFO .940 Form OSHA-20 ll*. May 72 MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil Conoco Product Code: 4142/3510 Synonyms: Fungible All-Purpose Fuel Oil 45 Cetane Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellov liquid; Aromatic odor.___________________ Boiling Range (F) 350-680 Specific Gravity (H20=1) 0.86 Vapor Pressure (mmHg),68F 1________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) "Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION________________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate - VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary RouteCs) of Exposure/Entry: Inhalation, skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. February 19, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700ftF) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCKA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place In proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil Conoco Product Code: 3503/3510/4142/4182 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Froduct Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class IT Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellow liquid; Aromatic odor. Boiling Range (F) 350-680' Specific Gravity (HaO*1) Vapor Pressure (mmHg),68F ^1________ % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. May 15, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION________________________ Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 High - 3 Extreme - 4 Moderate - VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary Route(s) of Exposure/Entry: Inhalation, skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been Identified specifically for this product. Health effect information from animal or human studies has been Included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. May 15, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxiclty: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSRA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. May 15, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE. WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. May 15, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil Conoco Product Code: 3510/4142 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellov liquid; Aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg),68F 1________ % Volatile (by volume) Solubility in Water Insoluble 0.85-0,93 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not Ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. July 12, 1985 Y. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials* Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of ''empty*1 placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Celling Value None Primary Route(s) of Exposure/EntryT Inhalation, skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. July 12, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 tnl/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity.: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. July 12, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X, PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. July 12, 1985 (conGco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION_____________________________ Name: No. 2 Diesel Fuel/Furnace Oil/Furnace Oil LP Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.; (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Petroleum Hydrocarbons (Aromatic) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA__ Appearance and Odor: Clear or light yellow liquid; Aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg),68F J.________ X Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 29, 1985 V. FIRE AND EXPLOSION HAZARD DATA (continued)____________ Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None Primary Route(s) of Exposure/Entry: Inhalation* skin. AEL None Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. August 29, 1985 VII, HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. August 29, 1985 IX, SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 29, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/Furnace Oil LP Conoco Product Code: 3503/3510/4142/4 198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: <800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: -Clear or light yellow liquid; Aromatic odor.______________ ________ Boiling Range (Deg.F) 350-680 Vapor Pressure (mmHg),68F J________ Specific Gravity (H20=1) % Volatile (by volume) 0.85-0.93 Nil Solubility in Water Insoluble I?. REACTIVITY DATAStable: I Unstable; Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ?. FIRE AND EXPLOSION HAZARD DATA LFLt 0.4 UFL; 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F________ Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 4, 1985 y. FIRE AMD EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liauid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 4, 1985 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen`or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCI AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent voraitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method; Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 V (Conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace 011/Furnace Oil LP Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Mnaufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 IX. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear or light yellow liquid; aromatic odor. Boiling Range (Deg.F) 350-o80 Specific Gravity (HgOrl) Vapor Pressure (mmHg), 68F j________ % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil If. REACTIVITY DATA Stable: I Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. f. FIRE AND EXPLOSION HAZARD DATA LFL: 0.4 UTLs 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 17, 1985 y. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible Uauid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible11 (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty11 placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Celling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 17, 1985 fll. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to Ingredients in this product, caused a low incidence of skin tumors* Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits: Non-irritating Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCT AND FIRST AID PS r,i RES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 II. SPILL, LEAK ASP DISPOSAL PROCEDURES_______________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES ________ : - ____________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Marne: Mo. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Familv: Mixed Hydrocarbons Mnaufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information Mo.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA - Appearance and Odor: Clear or light vellow liquid; aromatic odor. Boiling Range (Deg.F) 350-680 Vapor Pressure (mmHg), 68F 1 Specific Gravity (H20=1) % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATA Stable: Z Unstable: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. T. FIRE AND EXPLOSION" HAZARD DATA LFL: 0.4 UFL: 6 Flash Point (Method used): 130 min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. January 31 * 1986/GASC0220 T. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993^ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. January 31, 1986/GASC0220 gII."HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic diesel fuel, funded by the American Petroleum Institute: Median lethal dose, rat oral: 9 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Extremely irritating to skin Eye irritation, rabbits; Non-irritating' Genotoxicity: Negative in mutagenic assays Positive chromosomal damage Reproductive toxicity: No abnormalities in newborn rats Listed as Carcinogen -or Potential Carcinogen by: NTP No IARC No OSHA No 7III. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 31 1986/GASC0220 II. SPILL, LEAK AND DISPOSAL PROCEDURES HCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls needed if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 31, 1986/GASC0220 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIA! IDENTIFICATION Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 II. 0SHA HAZARD DETERMINATION CAS Registry No.: Mixture Transportation Emergency No.: (BOO) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor:'Clear or lieht vellow liquid; aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68 F 1 % Volatile (by volume) Solubility in Water Insoluble 0.85-0.93 Nil IV. REACTIVITY DATA Stable.* X Un-Stable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LPL: 0.4 (ffU 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 22, 1986/GASC0220 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivitv 0 VI.TRANSPORTATION AHD STORAGE HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 DOT HAZARD ClASS* Combu&Uble. Uould Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:` Minimize exposure. Use in well-ventilated area. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. m, HEALTH HAIMW INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 22, 1986/6ASC0220 VII. HEALTH HA.IA.KV INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP7 No IARC? No OSHA? No VIII. EMERGENCY AND FIRST ATP PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL. LEAK AND VISPOSM PROCEDURES_________________________________________________________ RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 22, 1986/GASC0220 X- PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 22, 1986/GASC0220 fconoco) MATERIAL SAFETY DATA SHEET I. MATERIA/, JVENTlflCATlOH Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74603 1I.~ 0SHA HAZARD DETERMINATION CAS Registry No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL PATA Appearance and Odor: 'Clear or Boiling Range (F) Vapor Pressure (mmHg), 68 F Solubility in Water lixht yellow 350-680 1 Insoluble liauid; aromatic odor. Specific Gravity (H*0=1) % Volatile (by volume) 0.85-0.93 Nil IV. REACTIVITY DATA Stable.: x Un&table.* Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL; 0,4 UFl-' 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. December 23, 1986/GASC0220 V. EIRE AW EXPLOSION HAZARD DATA (continued] Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE VOT HAZARD CLASS Combustible liouid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:- Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Vti. HEALTH HAZARD INFORMATION " PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 23, 1986/GASC0220 UH. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No VliT. EMERGENCY AW FIRST AID PPOCEVURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IxV~SPULt LEAK AVP VISPOSAL PROCEVURES RCRA HAZARDOUS WASTE: Yes X No ______ In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. December 23, 1986/GASC0220 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 23, 1986/GASC0220 (conoeo) MATERIAL SAFETY DATA SHEET J. MATERIAL IPCAffTFICATIW Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3504/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 ii. osha f/AzARp vsremmm CAS Registry No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. III. PHYSICAL PATA Appearance and Odor:-Clear or light yellow liquid; aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68 F 1 % Volatile (by volume) Solubility in Water Insoluble IV. REACTIVITY PATAStable.: X Unstable,: 0.85-0.93 Nil Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. vr fire m explosion hazako vata iflj 0.4 ~ an: 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature: 475-500 F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. May 29, 1987/GASC0220 k1 V. FIRE AND EXPLOSION HAZARD PATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 VI.TRANSPORTATION AND STORAGE HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 DOT HAZARD CLASS: Combustible liouid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION:' Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. Use in poorly ventilated area may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. VII. HEALTH HAZARD INFORMATION PEL 500 ppid (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that some petroleum distillates have caused kidney damage and kidney or liver tumors. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. May 29, 1987/GASC0220 VIJ. HEALTH HAZARD INFORMATION (continued)___________________________ __ Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia or central nervous system depression, including weakness, dizziness, unconsciousness or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No yin. EMERGEA/CY AMV FIRST AID PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK DISPOSAL PROCEVURtS RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. May 29, 1987/GASC0220 X, PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. May 29, 1987/GASC0220 (conoco) MATERIAL SAFETY DATA SHEET I, MATERIAL IPEAfTIFICATIOftf Name: No. 2 Diesel Fuel/Furnace Oil/ Furnace Oil LP/No. 2 Fuel Oil Conoco Product Code: 3503/3504/3510/4142/4198 Chemical Family: Mixed Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Registry No.: Mixture Transportation Emergency No.: (800 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. OSHA HKZMW VBTEmimiOH Hazardous Ingredients: Hydrocarbons (Aromatic and Paraffinic Hydrocarbons) Physical Effect Properties: Product/Mixture: Class II Combustible Liquid as per NFPA Code No. 30-1984. I/I. PHVSICM DATA Appearance and Odor: -Clear or light yellow liquid; aromatic odor. Boiling Range (F) 350-680 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68 F 1 % Volatile (by volume) Solubility in Water Insoluble 0,85-0.93 Nil It/. REACTIVITY VATAStable.: X Unstable.: Hazardous Decomposition Products: Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AMD EXPLOSION tfAZARP PATA 1F1-' 0.4 UFU 6 Flash Point (Method used): 130 F min. (TCC) Autoignition Temperature NFPA: 494F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. August 28, 1987/GASC0220 V. FIRE AND EXPLOSION HAZARD DATA (continued)_______________________ Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS-* Combustible, liQuid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Diesel fuel, combustible liquid, NA 1993/ Fuel Oil, No. 2, combustible liquid, NA 1993 (as appropriate). Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: CAUTION: ' Minimize exposure. Product contains hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. The product may also be toxic to the liver and kidney. The use in poorly ventilated areas may cause dizziness, weakness, confusion or unconsciousness. Aspiration into the lungs may cause pneumonia. FIRST AID: If swallowed, do not induce vomiting. Avoid ignition sources. Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. m. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established Du Pont AEL Not Established Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. August 28, 1987/GASC0220 m. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a distillation range of 120-700 F, and which are similar to ingredients in this product, caused a low-moderate incidence of skin tumors. This animal data should be interpreted cautiously since these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, skin, or lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Is Product Listed as Carcinogen or Potential Carcinogen by: NTP7 No IARC? No OSHA? No VlliV EMERGENCY AM) FIRST AIV PROCEDURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and seek medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. See Section X for Precautionary Measures. Inhalation: Remove individual to fresh air. If breathing stops, administer artificial resuscitation. Seek medical attention. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Seek medical attention. Never give anything by mouth to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. .SPia. LEAK AMV DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: This material is combustible. Appropriate precautions should be taken. Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. August 28, 1987/GASC0220 X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil spray or mists. Ventilation: General mechanical ventilation is normally adequate. Protective Gloves: Chemically resistant gloves such as vinyl, neoprene or NBR to minimize skin contact. Eye Protection: Face shield recommended when exposed to oil sprays or mists or when splashing is probable. Other Protective Equipment: Coveralls or other protective apparel needed if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded Maintenance Procedures: Avoid all ignition sources until the contaminated storage container is isolated and clear of all flammable and toxic vapor concentrations. Use adequate ventilation to remove vapor from container. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. August 28, 1987/GASC0220 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 fll. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 rag/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIH7 "EMERGENCY and first aid procedures Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Paraffinic and isoparaffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor._____________________________________ Boiling Range (F) 330-572 Specific Gravity (H20"1) 0,81 Vapor Pressure (mmHg),68F 2________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: X Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Flash Point (Method used): 1150F min. (TCC) Autoignition Temperature; 475-500*F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 CAS Registry No,: Mixture 64742-38-7, 8008-20-6 V, FIRE AND~EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Nne Ceiling Value None AEL None Primary Route(s) of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been Included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed akin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's bead in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as Incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 U.S. I APARTMENT OF LABOR C ipational Safety and Health Administn >n MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION I MANUFACTURER'S NAME CONOCO INC. ADDRESS (Number, Street, City, State, and ZIP Code) 1000 South Pine, Ponca City, OK 74603 CHEMICAL NAME AND SYNONYMS CHEMICAL FAMILY Mixed Petroleum Hydrocarbons FORMULA EMERGENCY TELEPHONE NO. (405) 767-3456 TRAOE NAME ANO SYNONYMS CONOCO KEROSENE SECTION II --HAZARDOUS INGREDIENTS Under current laws, rules, and regulations, this material is considered non-toxic and non-hazardous. - boiling point r*F) initial VAPOR PRESSURE (mm Hq) VAPOR OENSfTY (AIR-1) SOLUBILITY IN WATER APPEARANCE ANO ODOR SECTION III --PHYSICAL DATA 330-350 2 5.2 SPECIFIC GRAVITY (H,01) PERCENT, VOLATILE 8Y VOLUME (%) EVAPORATION RATE < -1) Insoluble Clear, paraffinic odor. FLASH POINT (Method Used) SECTION IV--FIRE AND EXPLOSION HAZARD DATA 135-150F. (COC) FLAMMABLE UMiTS EXTINGUISHING MEDIA Foam, dry chemical, carbon dioxide, water spray SPECIAL FIREFIGHTING PROCEDURES None Lei 0.5 0.81 Nil NA Uet 2.8 UNUSUAL FIRE ANO EXPLOSION HAZARDS Handle and store in accordance with NFPA Procedures for Class II Flammable Liquid. PAGE (1) (Continued on revere* side) Form OSHA-20 Rev. May 72 Ccoooco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 7*1603 CAS Reg. No.: Mixture; major components may be some combination of 647*12-38-7, 8008-20-6 Transportation Emergency No.: (8QQ) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor. Boiling Range (Deg.F) 330-572 Specific Gravity (H20=1) Vapor Pressure (mmHg), 68F 2_______ % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil I?, REACTIVITY DATAStable: I Unstable; Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 OFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 17, 1985 CAS Registry No.: Mixture, 6W2-38-7, 8008-20-6 V. FIRE AND EXPLOSION HAZARD DATA (continued) ~ Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION HAZARD RATING Health 0 Fire 2 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - M VI.TRANSPORTATION AND STORAGE DOT HAZARD CUSS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-198M. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). D.O.T. Label: None. OSHA Label: Combustible Liquid. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 17, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No I ARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Nash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove Individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 17, 1985 CAS Registry Mo.: Mixture, 64742-38-7, 8008-20-6 II. SPILL, LEAK AMD DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE; Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES_________________________________________________________________ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 17, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: None. HAZARD DATA Not applicable. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor._________________________________ Bolling Range (Deg.F) 330-572 Specific Gravity (HgOsI) 0.81 Vapor Pressure (mmHg),68F 2________ % Volatile (by volume) Nil Solubility in Water Insoluble IV. REACTIVITY DATAStable: I Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLs 0.5 UFL: 6 Flash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without, proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) "~ HAZARD IDENTIFICATION_____________________ HAZARD RATING Health 0 __ Fire 2 Reactivity 0 Least - 0 Slight - 1 Moderate - " High - 3 Extreme - 4 ?I.TRANSPORTATION AND STORAGEDOT HAZARD CLASS: Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV Not Established Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. October 4, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 HI. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No Till. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. October 4, 1985 CAS Registry No.: Mixture, 647^2-38-7, 8008-20-6 II. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated Items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. October 4, 1985 (ccnoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Kerosene Conoco Product Code: 4300 Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture; major components may be some combination of 64742-38-7, 8008-20-6 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Paraffinic and isoparaffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Physical Effect Properties: Product/Mixture: Class II Combustible Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Clear liquid, paraffinic odor. Boiling Range (F) 330-572 Specific Gravity (H20-1) Vapor Pressure (mmHg),68F 2 % Volatile (by volume) Solubility in Water Insoluble 0.81 Nil IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Combustion can produce carbon dioxide. Incomplete combustion may produce carbon monoxide. . Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 0.5 UFL: 6 Plash Point (Method used): 115F min. (TCC) Autoignition Temperature: 475-500F Handle and stored in accordance with NFPA procedures for Class II Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. February 19, 1985 CAS Registry No.: Mixture* 64742-38-7, 8008-20-6 V. FIRE AND EXPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Bo not enter enclosed or confined space without proper protective equipment Including respiratory protection. National Fire Protection Agency (NFPA) HAZARD IDENTIFICATION Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRANSPORTATION AND STORAGEDOT HAZARD CLASS? Combustible liquid Precautions To Be Taken In Handling And Storing: Product is Class II Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Kerosene, combustible liquid, UN 1223. Placard: Combustible* (Not required on packages 110 gallons or less). Label: None. * Flammable placard may be substituted on a cargo tank, portable tank, or compartmented tank car. Use of "empty" placard not authorized. VII. HEALTH HAZARD INFORMATION PEL 500 ppm (petroleum distillates) TLV None Ceiling Value None AEL None Primary Route(s) of ExposureTEntry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect has been identified specifically for this product. Health effect Information from animal or human studies has been included on related materials, even though health experts may disagree as to the significance of this data. Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant Increases of kidney damage nor kidney or liver tumors. February 19, 1985 CAS Registry No,: Mixture, 64742-38-7, 8008-20-6 VII, HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates (boiling point, 120-700*F) caused a low incidence of tumors. Studies of petroleum workers have not shown a significant increased incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic kerosene, funded by American Petroleum Institute: Oral toxicity, rat: No mortality at a dose of 5 g/kg. Skin toxicity, rabbits: No mortality at a dose of 2 g/kg. Severe irritation (24-hour occlusion) Eye Irritation, rabbits: Minimal irritation. Inhalation toxicity, rats: No mortality at a concentration of 5.2 mg/1 for 4 hours. Genotoxicity: Negative. Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. February 19, 1985 CAS Registry No.: Mixture, 64742-38-7, 8008-20-6 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items Including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator when exposed to oil sprays or mists. Ventilation: Normal ventilation. Protective Gloves: Impervious gloves as needed to avoid skin contact. Eye Protection: Chemical goggles required when exposed to sprays and mists or if splashing is probable. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. February 19, 1985 U.s. L APARTMENT OF LABOR C ipational Safety and Health Administr.. ,n MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)_______ SECTION 1 MANUFACTURER'S NAME CONOCO INC. AOORESS (Number, Street, City, Stale, and ZIP Code) 1000 South Pine, Ponca City, OK 74603 CHEMICAL NAME ANO SYNONYMS CHEMICAL FAMILY Mixed Petroleum Hydrocarbons FORMULA EMERGENCY TELEPHONE NO. (4050 767-3456 TRADE NAME ANO SYNONYMS CONOCO KEROSENE SECTION II --HAZARDOUS INGREDIENTS Under current laws, rules, and regulations, this material is considered non-toxic and non-hazardous. BOILING PCIN-CF) Initial VAPOR PRESSURE (mm Hq> VAPOR DENSITY (AIR -1) SOLUBILITY IN WATER APPEARANCE ANO ODOR SECTION III--PHYSICAL DATA 330-350 2 5.2 SPECIFIC GRAVITY (H,0-1) PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE < -1) Insoluble Clear, paraffinic odor. FLASH PONT (MeffvXl Used) SECTION IV--FIRE AND EXPLOSION HAZARD DATA 135-150F. cCOC) FLAMMABLE LIMITS EXTINGUISHING MEDIA Foam, dry chemical, carbon dioxide, water spray. SPECIAL FIREFIGHTING PROCEDURES None ' Lei 0.5 0.S1 Nil NA Ue< 2.8 UNUSUAL FIRE ANO EXPLOSION HAZARDS Handle and store in accordance with NFPA Procedures for Class II Flammable Liquid. PAGE (t) (Continued on reverse side) Form OSHA-30 Rev. May 72 (conoco) MATERIAL SAFETY DATA SHEET T. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline/Premium Unleaded Gasoline Conoco Product Code: 1420/1200 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc* Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to blood elements and bone marrow. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 5-437 Specific Gravity (H?0=1) Vapor Pressure (romHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 I?. REACTIVITY DATA___________________________________________ Stable: I Unstable; Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION"HAZARD DATA " LFLi 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 25, 1986/GASC0130 V. FIRE AND EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate - High - 3 Extreme - 4 VI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. . Wash thoroughly with soap and water after contact. Flammable Liquid. VII. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. April 25, 1986/GASC0130 VII. HEALTH HAZARD INFORMATION (continued) Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The relative signifi cance of this to human health is uncertain since the petroleum distillates were not washed from the treatment site and the resulting skin irritation may play a role in the tumorigenic response. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. April 25, 1986/GASC0130 XI, SPILL, LEAK ASP DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as ouch of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data Is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESI2CT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. April 25, 1986/GASC0130 cConoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION________ ___ Name: Unleaded Gasoline Conoco Product Code: 1410/1411 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mix ture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Water white to straw yellow liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (HgOsI) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility In Water Insoluble 0.70-0.77 K)0 IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Condition to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 7.6 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Ip January 17, 198|7GASC0140 y. ~ FIRE AHD EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) Health 1 Fire_2_ Reactivity Q HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 yI.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not Induce vomiting. Call a physician Immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. ?II. HEALTH HAZARD INFORMATION_____________. PEL Not Established TLV 300 ppm "Gasoline11 Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. January 17, 1986/GASC0140 VII. HEALTH HAZARD INFORMATION (continued) Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight Irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen or Potential Carcinogen by: NTP No fill. EMERGENCY AND FIRST AID PROCEDURES ' ~ IARC No OSHA No >. =. "" Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If Irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head In an effort to prevent voraitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. January 17, 1986/GASC0140 II. SPILLt LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes X No ___________ _ In Case of Spill or Leak: Contain spill Immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place In proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES ______________________________ ____ Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. January 17, 1986/GASC0140 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney in laboratory animals. Benzene (71-43-2) A few studies have Indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHISICAL DATA Appearance and Odor: Red liquid; fgasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H?0=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0.77 100 IT. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from incomplete combustion. Conditions to Avoid: Oxidizing materials, heat. flame. Hazardous Polymerization: Will not occur. T. FIRE AND EXPLOSION HAZARD DATA LFL: 1.3 UFL: 6.0 Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 ." FIRE AHP ETPLOSIOM HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may . contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respirator protection. National Fire Protection Agency (NFPA) CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate - High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Flammable liquid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203* Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 11. HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin* Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 12, 1985 YII. HEALTH HAZARD INFORMATION (continued) _________________ Mouse skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low incidence of skin tumors. Studies of petroleum workers have not shown a significant increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen .or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If Irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material Is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomltus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 IX. SPILL, LEAK AND DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes__ X__ No In Case of Spill or Leak: Contain spill immediately in smallest area possible* Recover as much of the product Itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or If splashing Is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for Informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Super Unleaded Gasoline Conoco Product Code: 1420 Synonyms: Automotive Unleaded Gasoline Chemical Family: Mixed Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P. 0. Box 1267, Ponca City, OK 74603 CAS Reg. No.: Mixture Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS______________________ HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin, and kidney In laboratory animals. Benzene (71-43-2) A few studies have Indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Class I A Flammable Liquid per NFPA Code No. 30-1984. III. PHTS1CAL DATA Appearance and Odor: Red liquid; gasoline odor. Boiling Range (Deg.F) 85-437 Specific Gravity (H20=1) Vapor Pressure (mmHg) at 68F 275-475 % Volatile (by volume) Solubility in Water Insoluble 70-0>77 100 I?. REACTIVITY DATA _________________ ______________ Stable: I Unstable: Hazardous Decomposition Products: Carbon monoxide may be formed from Incomplete combustion. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AND EXPLOSION HAZARD DATA LFLs 1.3 UFLs 6.0~ Flash Point (Method used): As low as -50F (TCC) Handle and store in accordance with NFPA procedure for Class I A Flammable Liquid. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. December 12, 1985 . FIRE ASP EXPLOSION HAZARD DATA (continued) Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not Ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure* Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may . contain carbon monoxide, carbon dioxide and other toxic materials* Do not enter enclosed or confined space without proper protective equipment Including respirator protection*' National Fire Protection Agency (NFPA^CLASSIFICATION Health 1 Fire 3 Reactivity 0 Least - 0 HAZARD RATING Slight - 1 Moderate - High - 3 Extreme - 4 1.TRANSPORTATION AND STORAGE DOT HAZARD CLkSSi Flammable llouid Precautions To Be Taken In Handling And Storing: Product is Class I A Flammable Liquid per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Gasoline, flammable liquid, UN 1203. Placard: Flammable. D.O.T. Label: Flammable liquid. OSHA Label: CAUTION: Minimize exposure. This product contains benzene and certain other hydrocarbons which are potentially toxic or carcinogenic. If ingested, do not Induce vomiting. Call a physician immediately. Wash thoroughly with soap and water after contact. Flammable Liquid. 11, HEALTH HAZARD INFORMATION PEL Not Established TLV 300 ppm Ceiling Value Not Established AEL Not Established Primary Routes of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with rodents have shown that petroleum distillates have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. December 12, 1985 k ?II, ^m.th HJ^A^ IHFORMATICW (continued) ~ House skin painting studies have shown that unrefined petroleum distillates having a boiling point of 120-700F, and which are similar to ingredients in this product, caused a low Incidence of skin tumors. Studies of petroleum workers have not shown a significant increased Incidence of skin tumors. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Data from animal studies with a generic unleaded gasoline, funded by the American Petroleum Institute: Median lethal dose, rat oral: 18.8 ml/kg Skin toxicity, rabbits: No mortality at dose of 5 ml/kg Slight Irritation to skin. Eye irritation, rabbits: Non-irritating Genotoxic studies: Negative Reproductive toxicity: No abnormalities in newborn rats. Listed as Carcinogen .or Potential Carcinogen by: NTP No IARC Mo OSHA No 111. EMERGENCY AND FIRST AID PROCEDURES: .. Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Nash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. December 12, 1985 II. SPILL, LEAK AND DISPOSAL PROCEDURES; RCRA HAZARDOUS WASTE: Yes X No In Case of Spill or Leak: Contain spill immediately in smallest area possible. Recover as much of the product itself as possible by such methods as vacuuming, followed by soaking up of residual fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper containers for disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material as a RCRA hazardous waste by such methods as incineration, complying with federal, state and local regulations, I. PRECAUTIONARY MEASURES Respiratory Protection: Use air mask or hydrocarbon absorbing respirator. Ventilation: Use adequate ventilation to meet recommended concentrations. Avoid sparking hazards and explosive mixtures. Protective Gloves: Impervious as needed to avoid skin contact. Eye Protection: Goggles or face shield for sprays/mists or if splashing is probable. Other Protective Equipment: Protective clothing should be worn. Soiled clothing should be removed and laundered. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR AMY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. December 12, 1985