Document Ne6za240nmLyDO5jY4gJJ9Zpb

TOM FRANCIS CONLEY CASTING SUPPLY CO 124 MAPLE ST WARWICK, RI. 02888 June 8, 2012 DEAR TOM FRANCIS, Enclosed please find the Material Safety Data Sheet (MSDS) for the material listed below. Either you recently purchased this product from us, and/or we are furnishing this MSDS as required by the "Annual Notification Procedures under Section 313 of Title m". Product Name: TALC IMP BC IMP 1820L We thank you for your order and hope we may continue to merit serving your future requirements. Very truly yours, Frank McGonigle Frank McGonigle Manager Technical Information Brenntag Specialties, Inc. PLAINTIFFS EXHIBIT CAM-172 Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 Material Safety Data Sheet Version: 8.0 Revision date: June 23, 2011 Stf0ft:;i^-hehiiii'Prduetand Gompany fctentificatfon Product name: Cimpact 550C Compacted Cimpact 550 Densified Cimpact 610C Compacted Cimpact 610 Densified Cim pact 710 Powder Cim pact 710 Densified Cimpact 710 RC Cimpact 710 R Densified Cim pact 710 C Compacted EZ Flow imperial 1820L BC imperial 1821L BC Imperial 1822L BC Imperial 1824L BC Imperial 1825L FCC/BC Imperial 1886L BC Imperial 1888L BC Imperial 1889L BC Imperial ACM Imperial RMA________ Jetfine 1H Luzenac 8230 Powder Steasilk 5CH Steasilk 5AH Stellar 410 Powder Stellar 420 Powder Stellar 510 Powder Stellar EX Powder Stellar SO CAS Registry Number: 14807 96-6 Product use: Functional mineral for use in paper, paints, ceramics, plastics, personal care, etc. Chemical Formula: 3M g0*4Si02*H20 Chemical Name: Hydrous magnesium silicate Synonyms: Talc, Soapstone, Steatite Chemical Family: Silicate Manufacturer Company name Address Tel: Fax: E-mail: Luzenac America Inc 17509 Van Road Houston, TX 77049 USA +1 281-272-7200 +1 281-456-7816 msds.americas@luzenac.com Emergency telephone number: +1 303 623 5716 .x . / :-i Talc is a natural association of talc, chlorite, dolomite and magnesite. Main constituents Talc Chlorite Dolomite Magnesite EINECS 238-877-9 215-285-9 240-4-44-2 208-915-9 CAS. 14807-96-6 1318-59-8 16389-88-1 546-93-0 A m ount (%) >96 <3 <1 <1 V 8.0 For more information visit www luzenac com 06/28/2011 - p 1/7 TX UC PRODUCTS NA EN IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express assHN^LiNJ^kihty the accuracy or completeness of the information. The Buyer assumes all responsibility7 any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 M aterial Safety Data Sheet Emergency Overview: Under normal conditions of use, this product is not expected to create any unusual emergency hazard. This product is NOT flammable, NOT reactive, NOT explosive, has No flash point, and poses no special hazards in the presence of fire. Potential Health Effects Route of Exposure: Inhalation is the primary route of exposure Inhalation: Acute: Exposure to a large concentration of air-borne dust of this material may cause mechanical irritation of the mucous membranes and respiratory tract. Chronic: Repeated and prolonged exposure to large amount of talc dust might induce a mild pneumoconiosis. This is caused by lung overload exposure, a non specific particle effect, rather than a specific intrinsic fibrogenic activity of talc. Skin Contact: Acute: Direct contact may cause dryness or mild irritation if an allergic predisposition exists Chronic: Prolonged contact may cause dryness of skin or mild irritation if an allergic predisposition exists Eye Contact: Acute: Direct contact with dust may cause mechanical irritation of the eyes Chronic: Repeated exposure may cause conjunctive inflammation Ingestion: Acute: This material is considered to be harmless and inert when ingested. C hronic: Repeated ingestion of large doses of talc for 13 and 10 successive days by rabbits and mice revealed negative teratogenic and carcinogenic results. Section 4 ;: First-aid Measures Eye contact: Rinse with copious quantities of water for at least 15 minutes and seek medical attention if irritation persists. Skin contact: No special first aid measures necessary. Inhalation: No special first aid measures. Remove to fresh air and get medical attention in case of serious respiratory problems. Ingestion: No first aid measures required. Extinguishing media: All extinguishing media can be used. Special hazards arising from the substance or m ixture: The product is not flammable, combustible or explosive. No hazardous thermal decomposition. Advice fo r fire-fighters: No specific fire-fighting protection is required. Use an extinguishing agent suitable for the surrounding fire. V 8.0 06/28/2011 - p 2 T / TX UC PRODUCTS NA EN For more information visit www.luzenac.com IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility W any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 Mms r? vycsrii n M aterial Safety Data Sheet ---- Personal precautions, protective equipm ent and emergency procedures: Avoid airborne dust generation. If the generation of dust is likely, personal protective equipment should be worn in compliance with national legislation. Environmental precautions: No special requirements. Contain spillage and clean up as indicated below. Methods and material fo r containm ent and cleaning up: Dry product should be cleaned with a shovel or vacuum cleaner while wearing personal protective equipment in compliance with national legislation. Washing the floor with water is not recommended since it may cause the floor to become slippery. However, if talc is already wet, and only in this case, the floor should be thoroughly flushed with water to remove all slipperiness. Talc is not considered a hazardous waste as defined by the US EPA RCRA (40 CFR 261) regulations. Observe all applicable federal, state and local regulations when handling, storing or disposing of this substance. S c t j n Handling ;r: Precautions fo r safe handing: Avoid airborne dust generation. Provide appropriate exhaust ventilation at places where airborne dust is generated, in case of Insufficient ventilation, wear suitable respiratory protective equipment. Handle packaged products carefully to prevent accidental bursting. If you require advice on safe handling techniques, please contact your supplier. C onditions fo r safe storage: Keep the product dry and In closed containers. filiMIfiilillSiilililiM Control parameters: Follow workplace regulatory exposure limits for all types of airborne dust (e.g. total dust, respirable dust, and respirable crystalline silica dust). In the U S., the Occupational Exposure Limit (OEL) for talc containing no asbestos fibers and less than 1% crystalline silica is 2 mg/m3 respirable fraction (ACGIH) measured as an 8 hours TWA (Time Weighted Average). The OSHA exposure limit for talc Is 20 mppcf Permissible Exposure Limit (PEL) TWA. For the equivalent limits in other countries, please consult a competent occupational hygienist or the local regulatory authority. Engineering controls: Minimise airborne dust generation. Use process enclosures, local exhaust ventilation or other engineering controls to keep airborne levels below specified exposure limits. If user operations generate dust, use ventilation to keep exposure to airborne particles below the exposure limit. Apply organisational measures, e.g. by isolating personnel from dusty areas. Remove and wash soiled clothing. Personal protection: Eye protection: Wear safety glasses with side-shields in circumstances where there is a risk of dust generation which could lead to mechanical irritation of the eye. Skin protection: No specific requirement. For hands, see below Hand protection: Protective gloves are not necessary but recommended for those prone to skin irritation or dryness. Respiratory protection: In case of overexposure to airborne dust concentrations, wear respiratory protective equipment that complies with the requirements of national legislation. V 8.0 For more information visit www.luzenac.com 06/28/2011 --p 3/7 TX UC PRODUCTS NA EN IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility 1M1W. llliyM W JM IM l any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 M aterial Safety Data Sheet Sij&tpM: sii t':'tTji;:C Pro:jprtifSy Information on basic physical and chemical properties Appearance: White, off white to light grey powder. Odour: Odourless pH: 9 - 9.5 (10% slurry in water) M elting point: >130CTC Flam mability (solid, gas): Not flammable. Relative density: 2.7 - 2.8 g/cm3 S o lu b ility : S olubility In water: Negligible Solubility in hydrofluoric acid: Yes D ecom position temperature: >1000C Explosivity: Not explosive rigao.:';, :A **? Reactivity: inert, not reactive Chemical stability: Chemically stable. Possibility of hazardous reactions: No hazardous reaction. Conditions to avoid: None. Incom patible m aterials: None known. Hazardous decom position products: None. Section 11. TdxicdlogicaUnformation NIOSH registry number: WW2710000 SAX to xicity evaluation: THR: Not available Carcinogenic Status: (ARC: In 2006, IARC concluded that inhaled talc not containing asbestos or asbestiform fibers is not classifiable as a human carcinogen (Group 3). iARC: in 2006, IARC ruled that there is limited evidence that the use of talc-based body powder for perineal dusting is a possible risk factor for ovarian cancer (Group 2B). This is not a route of exposure relevant to workers and applies only to one specific use of talc. OSHA: Not listed V 8.0 For more information visit www.luzenac.com 06/28/2011 - p 4/7 TX UC PRODUCTS NA EN IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 M aterial Safety Data Sheet ACGIH: A4 - not classified as a human carcinogen WHMIS: Class D-2A NTP: Not listed. A 2-year inhalation study demonstrated clear evidence of carcinogenic activity in female rats at exposure levels of 18 mg/m3. Some evidence of carcinogenic activity was observed in male rats at the same level. No evidence of carcinogenic activity was found in mice (NTP TR-421). Tum origenic Data TCLo: ihl-rat 11 mg/m3/1Y-1 TDLo: imp-rat 200 mg/kg Other Toxicity Data: Skin and eye irritation data: skn-hmn 300 ug/3D-l MLD Teratogenicity (reproductive effects data): Repeated ingestion of large doses of talc for 13 and 10 successive days by rabbits and mice revealed negative teratogenic and carcinogenic results Mutation Data: Not available Toxicity: No data are available on this product. No specific adverse effects known. Persistence and degradability: No data are available on this product. Product is an inorganic substance and therefore is not considered biodegradable. Other adverse effects: No specific adverse effects known. Waste disposal inform ation: Talc is not considered a hazardous waste as defined by the US EPA RCRA (40 CFR 261) regulations. Observe all applicable federal, state and local regulations when handling, storing or disposing of this substance. Disposal guidelines: Where possible, recycling is preferable to disposal. Recycling and disposal of packaging should be carried out by an authorized waste management company. Recycling and disposal of packaging should be carried out in compliance with local regulations. Responsibility for proper waste disposal lies with the owner of the waste. tJljjit 14. T ra n sp o rt In form ation US Department of Transportation (DOT): No classification assigned Canadian Transportation o f Dangerous Goods: No classification assigned Land Transport - ADR/RiD: No classification assigned A ir Transport --IATA/ICAO: No classification assigned M aritime Transport - IMDG: No classification assigned Harmonized T ariff Code: Talc - crushed or powdered. 2526.20.00 (stat suffix 00) EPA TSCA 12(B) Export N otification: Not listed V 8.0 For more information visit www.luzenac.com 06/28/2011 - p 5/7 TX UC PRODUCTS NA EN IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility w a d i y i,TM ,y ii a iM M J . liny any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 M aterial Safety Data Sheet y g ,-y.; Chemical inventories: The following inventories have been investigated as to the publicly available portion of the lists: MINERAL Talc Chlorite Dolomite Magnesite CAS No. 14807-96-6 1318-59-8 16389-88-1 546-93-0 EINECS (EU) 238-877-9 215-285-9 240-440-2 208-915-9 AICS (Australia) Yes No Yes Yes CEPA (DSLTNDSL) (Canada) Yes (DSL) Yes* (DSL) Yes (DSL) Yes (DSL) KEC1 Korean Gazette No. (Korea) KE-32773 KE-05489 KE-13036 KE-22686 ENCS/ISHUMITI (Japan) Yes* Yes* Yes* Yes MINERAL Talc Chlorite Dolomite Magnesite IECSC (China) Yes Yes Yes Yes PiCCS (Philippines) Yes Yes Yes Yes TSCA (USA) Yes Yes* Yes Yes Swiss ID No. (Switzerland) G-6939 Not listed G-8431 G-7477 NZloC (New Zealand) Yes Yes Yes Yes Yes*: There exists a broad category for naturally occurring chemicals, so these minerals are covered by definition, but not specifically listed. Other Pertinent Classifications/Regulations: California PROP 65 Status: talc not listed State Right-To-Know: Talc listed in IL, MA, NJ, PA, FL Clean A ir A ct - Ozone depleting chem icals (ODC): None CONEG Approved Packaging: Yes National Fire Protection Association (NFPA) Ratings (0-4 scale): Health = 0 Fire = 0 Reactivity = 0 National Paint and Coating Association (NPCA) --Hazardous Material Identification System (HMIS) Health: 1* (chronic potential) Flammability: 0 Physical: 0 Personal protection: dust respirator, gasses or goggles, gloves l i sau References and sources: 1. Baan, R, Straif K, Secretan B, Ghissassi FE and Cogliano V. (2006), On behalf of the WHO International Agency tor Research on cancer Monograph Working Group. Carcinogenicity of carbon black, titanium dioxide and talc. The Lancet Oncology. 7:295-296. 2. Wild, P.; "Lung cancer risk and talc not containing asbestiform fibers: a review of the epidemiological evidence". Occup. Environ. Med. 2006; 63, 4-9. V 8.0 06/28/2011 - p 6/7 TX UC PRODUCTS NA EN For more information visit www.iuzenac.com IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale. Product#: 332889 Name: TALC IMP BC IMP 1820L Desc: IMP1820L.50.BG From: BRENNTAG SPECIALTIES INC. To: CONLEY CASTING SUPPLY CO Friday, June 08, 2012 r*!ai**w*xX*i M aterial Safety Data Sheet 3. Cohrssen, B. and Powell C.H. (2001). Talc. In Patty's Toxicology, 5th ed., Bingham, E., Cohrssen, B., and Powell, C.H., eds., John Wiley & Sons, Inc. NY. pp. 519-538. 4. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Vol. 42. Silica and some silicates pp. 185-224, International Agency for Research on Cancer, Lyon, France, 1987,1 vol., 289 p. 5. WILD, P. et coll; ,,Effects of talc dust on respiratory health: results of a longitudinal survey of 378 French and Austrian talc workers", Occup. Environ. Med. 2008; 65, 261-267. 6. USEPA 1992. Health Assessment Document for Talc, Environmental Criteria and Assessment Office, Office of Health and Environmental Assessment, U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA 600/8-91/217, March 1992. Glossary ACGIH - American Conference of Governmental industrial Hygienists IARC - International Agency for Research on Cancer IATA - International Air Transport Association ICAO - International Civil Aviation Organisation IMDG - International Maritime Dangerous Goods NIOSH - National Institute of Occupational Safety and Health NTP - National Toxicological Program OSHA - Occupational Safety and Health Association OEL - Occupational Exposure Limit PEL - Permissible Exposure Limit RID/ADR --The European Agreements Concerning the International Carriage of Dangerous Goods by Rail (RID) and by Road (ADR) TLV --Threshold Limit Value TWA - Time Weighted Average WHMIS - Workplace Hazardous Materials Information System (Canada) Revisions Version 8 .0 - re-added product Imperial 1889L BC DISCLAIMER Luzenac America, inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. LUZENAC AMERICA, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, LUZENAC AMERICA, INC, WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. ISSUED BY Product Stewardship Department Luzenac America, Inc. Tel: +1 303-713-5000 V 8.0 For more information visit www.luzenac.com 06/28/2011 - p 7/7 TX UC PRODUCTS NA EN IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, express or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer assumes all responsibility wnTSTfflwpr any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale.