Document NZ5OV5Oe6Og9pNEZVwEV7MQ8
AXYS METHOD MLA-031 Rev 01
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F orm 1A/2
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PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample C ol taction:
22-NOV-2004 12:20
Lab Ham*: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
W ATER
Semple Receipt Date: Extraction Date: Analysis Date:
25-NOV-20Q4 02-Dec-2004 03-Dec-2004
T in : 20:37:58
Extract Volume (mL):
2
Injection Volume (pL): 10.0
Dilution Factor:
N/A
Project Name:
NSA
Lab Sample ID:
L7411-1 (A)
Sample Size:
500 mL
Initial Calibration Date:
O3-D0C-2OO4
Instrument IO:
LC-M S/M S
LC Column ID:
D iscovery C18
Sample Datafile:
PFS4G_110S23
Blank Data Filename:
PFS4G JI10S20
Cal. Ver. Data Filename: P F S 4 G J1 0 S 1 3
Concentration Unite:
ng/mL
COMPOUND
LAB FLAG *
CONC FOUND1
DETECTION LIMIT
RETENTION
TIME
PFPaA
PFHxA PFHpA PFOA PFNA PFDA PFtinA PFDoA PFTA PFBS PFHxS PFOS
0.433 0.207 0.011 0.036
U U U U U
0.013
U U
0.0085 0.0026 0.0017 0.0016 0.0003 0.0005
0.0001 0.0002 0.0002 0.D116
0.0061 0.0005
3.32 4.32 6.20 7.32
5.16
LABELED COMPOUND C13-PFD A
LAB FLAG '
SPIKE CONC.
(ng)
500
CONC. FOUND
("fl)
47,0
R (%) *
RETENTION TIME
94.0
8.77
(1) U = not detected (2) Concentrations are instrument and lab blank corrected.
{3} R (%) = Percent recovery
144t1_PFD1_2.nl*, SS
Approved by:.
Q A/QC Chem ist
1f-05*2005 dd-mm-yyyy
$ ] $ AXYS ANALYTICAL SERVICES LTD M . BOX M il, IMS KIUS ID. WIST, SIDNET I.C, UKttXVei 3S* IEI (I5D 6551100 FXX 12501 (S5-SII
AXYS METHOD MUUJ31 Rev 01
PFOS_si_D2
Forra 1AI2
PERFLUORIMATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
22-Nov-2004 12:20
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
WATER
Sample Receipt Date:
2S-NOV-2004
Extraction Date:
02-Dec-2004
Project Name: Lab Sampla ID: Sample Size: Initial Calibration Data: Instrument ID:
NIA WG14411-104
499 O3-D0C-2OO4
r
LC-MSIMS
Analyst* Date:
03-Dec-20M
Time: 20.19:16
L C Column ID:
Discovery C1&
Extract Volume (mL|:
2
Sample Datafile;
PFS4G_11QS2Z
Injection Volume (pL): Dilution F e d o r
10.0 WA
Blank Data Filename: Cal. Ver. Data Filename:
PFS4GJ10S20 PFS4GJ10S13
Concentration Unita :
nglmL
COMPOUND
LAB FLAG1
CONC FOUND1
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
0.389
0.210 0.011 0.036 U u u u u 0.018 u u
0.0107 0.0030 0.0016 0.0014 0.0002 0.0007 0.0002 0.0002 0.0001 0.0131 0.0067 0.0003
3.32 4.32 6.20 7.32
6.13
LABELED COMPOUND C1S-PFDA
LAB FLAG'
SPIKE CONC.
("0)
50.0
CONC. FOUND
(ng)
47.6
R(%)*
RETENTION TIME
95.6
8.77
(1) U = not detected (2) Concentrations are Instrument and lab blank corrected. (3) R (%) = Percent recovery
14411_PFDt_2.XlS. S4
Approved by:
QA/QC Chem ist
11-05-2005
dd-nw-yyyy
^^ A X Y S A N A L Y T I C A L S E R V I C E S L T D F.O. BOXm i. 2W5 MILLSHI. WEST, SIDNEY, I.C., CANADAVBl 1S lit (3SWiSS-SfM FAX(2501 6SS-5JI!
9!
AXY3 METHOD MLA-031 Rev 01
PFQ S_S1_D 2
FTM PERFLUORINATED SURFACTANT ANALYSIS REPORT
CU EN T IO:
Semple C oltaction:
224tov-2004 13:25123
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Matrix:
WATER
Sample Receipt Date:
25-NOV-2Q04
Extraction Date:
02-Dec-2004
Analysis Date:
03-DSC-2004
Extract Volume (mL):
2
Injection Volume (pL); 10.0
Dilution Factor.
N/A
Time: 20:56:42
Lab Sample ID:
L7411-2
Sampie Size:
500 mL
initial Calibration Date:
0340et>2004
Instrument ID:
LC-MS/MS
LC Column ID:
Discovery C18
Sample Datafile:
PFS4G110S24
Blank Data Filename:
PFS4GJ10S20
Cat. Ver. Data Filename: P F S 4 G J1 0 S 1 3
Concentration Units :
ng/mL
COMPOUND
LAS FLAG'
CONC FOUND*
DETECTION UMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA
PFTA PFBS PFHxS pros
0.415 0.163 0.010 0.036 u u u u
u 0.020
u u
0.0110 0.0023 0.0020 0.0018 0.0002 0.0004 0.0001 0.0001 0.0002 0.0124 0.0065 0.0006
3.32 4.32 6.20 7.32
5.16
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(no)
50.0
CONC. FOUND
(no)
47.6
R[%)*
RETENTION TIME
95.2
8.77
(1) II = not detected (2) Concentrations are instalm ent end lab blank corrected.
(3) R {%} = Percent recovery
I4*11_F"FDU2.xU .S 6
Approved by:
O A/QC Chem ist
11-05-2005 *JJWn-vyyy
,)][,AXYS ANALYTICAL SERVICES LTD f.O BOt 71' 5. 7045 MILLS ID, W5T. StDHtT, VI.. (ANMt V31 3S8 m 175D>15MBOO FU (750) 655-5B11
72.
AXYS METHOD MLA-031 Rev 01
pros s i 02
Fon* 1A/2
"~
PERFLUORINATED SURFACTANT ANALYSIS REPORT1
CLIENT ID:
Sample Coltectkm:
22-NOV-2004 14:10
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix: Sample Receipt Date: Extraction Data:
WATER 25-NOV-2004 02-Dec-2004
Analysis Date:
03-Dec-2004
Time: 21:15:28
Extract Volum e (mL):
2
Injection Volume (pL): 10.0
Dilution Factor:
N/A
Project Name:
N2A
Lab Sample ID:
L7411-3
Sample Size:
500 n
Initial C alibration Date:
03-Dec-2004
Instrument ID:
LC-MS/MS
L C Column ID:
Discovery C16
Sample Detaflla:
PFS4G_110S25
Blank Data Filename:
PFS4G_110S20
Cal. Var. Data Filename: PFS4G_110S13
Concentration Units :
ng/mL
COMPOUND
LAB FLAG'
CONC FOUND*
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA
PFHpA PFOA PFNA PFDA PFUnA PFOoA PFTA PFBS PFHxS PFOS
U 0.005
U u U u u u u u u u
0.0093 0.0008 0.0007 0.0006 0.0003 0.0004 0.0002 0.0001 0.0001 0.0045 0.0023 0.0002
4.32
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(ngj
50.0
CONC. FOUND
(ng>
55.6
R(%)
RETENTION TIME
111 8.77
(1) U = not detected {2) Concentrations are instrument and lab blank corrected.
<3) R (%} = Percent recovery
14411_PFD1_2.lS*. S7
Approved by:_
QA/QC Chem ist
11-06-200S dd-mm-yyyv
0)^(0 / X X Y S A N A L Y T I C A L S E R V I C E S L T D f.O. BOX2219, 045Milts10. tttSF, SIMP. S C . C i u m r a l i s rii St i5 seooI U (2501 S IS S I !
AXYS METHOD MLA-031 Rev 01
PFOS_sl_EC
Form 1AO
PERFLUOR1HATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
22-NOV-2004 15:00
Lab Name: AXYS ANALYTICAL SERVICES
Project Name;
N/A
Contract No.:
4191
Lab Sample ID:
L7411-4
Matrix:
WATER
Sample Size:
501 r
Sample Receipt Date:
25-NOV-2004
Initial Calibration Data:
03-Dec-2004
Extraction Date:
02-Dec-2004
Instrument ID:
LC-MS/MS
Analysis Dale:
03-DeC-2004
Time: 21:34:10
L C Column ID;
Discovery C18
Extract Volume lmL|:
2
Sample Datafile;
PFS4G_110S2B
Inlection Volum e (pL): 10.0
Blank Data Fllenama:
PFS4GJ10S20
Dilution F actor
N/A
Cal. Ver Data Fllenama: P F S 4 G J1 0 S 1 3
Concentration U n its:
ng/mL
COMPOUND
LAB FLAG 1
CONC FOUND1
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
0.365
0.156 0.006
0.021 U U u u u u u
0.0067 0-0034 0.0009 0.0010 0.0001 0.0005 0.0002 0.0002 0.0002 0.0131 0 0069 0.0007
3.32 4.28 6.20 7.32
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
!"9)
50.0
CONC. FOUND
|ng)
46.2
R (%) *
RETENTION TIME
92.4
6.77
(1) U = not detected (2) Concentrations are instrument and lab blank corrected. (3) R /%}= Percent recovery
14411_PFD1_2 xl*. SB
Approved by:.
Q A/Q C Chem ist
it-os-ados dd-mnvyyyy
4* AXYS ANALYTICAL SERVICES LTD P.O. BOX 21 ?, !0IS JUS ID. WEST. 9NEY, I.C., UMIM VM 3SB TIL (250) iSS-StOC fU I7SD1 &&-5811
fy
AXYS METHOD MLAOJ1 Rev 01
PFOS_St DS
Forni 1A/2
" PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
22-Nov-2004 15:55
LabName: AXYS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
L7411-5
Matrix:
WATER
Sample Size:
503
Samp) Receipt Dete: Extraction Date: Analysis Date: Extract Volume (mL):
25-NOV-2004 02-Dec-2004 03-Dec-2004 2
Time: 21:52:54
Initial Calibration Dale: Instrument ID: L C Column ID: Sample Datafile:
03-Dec-2004 LC-MS/MS Discovery C1B PFS4G11DS27
Injection Volume (pL): 10.0
Blank Data Filename:
PFS4G_110S20
Dilution Factor:
N/A
Cal. Ver. Data Filename: PFS4G_110S13
Concentration Unite :
ng/mL
COMPOUND
LAB FLAG'
CONG FOUND *
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
0.079 0.035 0.001 0.004 U u u u u u u u
0.0087 0.0020 0.0006 0.0012 0.0002 0.0008 0.0002 0.0001 0.0001 0,0075 0.0038 0.0002
3.36 4.32 6.20 7.36
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(ng)
50.0
CONC. FOUND
(f>0)
48.2
R(%)>
RETENTION TIME
96.4
8.77
(1 ) U = not detected (2) Concentrations are instrument and lab blank corrected.
(3) R (%) = Percent recovery
14411_PFD1_2.xls.S9
Approved by:
QA/QC Chem ist
11-05-2005 dd-mm-yyyy
0 AXYS ANALYTICAL S E R V I C E S LTD P.O.IM2219,?W5HILLS1WEST,SiWY.BC.CMDtVl3SCTH(2016555100FM(250)55-5B1'
fs
AXYS METHOD MLA-031 Rv 01
PFOS_Si 02
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
22-NOV-2004 11:15
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
WATER
Project Name: Lab Sample ID: Sample Size:
N/A L7411-8 499
n
Sample Receipt Date:
25-NOV-2004
Initial Calibration Data:
03-Dec-2004
Extraction Data:
02-Dec-2004
Instrument ID:
LC-MS/MS
Analysis Data:
03-Dec-2004
Time: 22:11:38
L C Column ID:
Discovery C IS
Extract Volum e (mL):
2
Sample Datafile:
PFS4G_110S28
Injection Volume (pLj: 10.0
Blank Data Filename:
P F S 4 G _ 1 10S20
Dilution Factor:
N/A
Cel. Ver. Data Filename: PFS4G_11QS13
Concentration U nits:
ng/mL
COMPOUND
LAB FLAG'
CONC FOUND >
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
0.024
0.013 U
0.003 u u u u u u u u
0.0049 0.0011 0.0005 0.0007 0.0002 0.0003 0.0001 0.0002 0.0002 0.0026 0.0016 0.0006
3.32 4.32
7.36
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(ng>
50.0
CONC. FOUND
("Bl
52.8
RW
RETENTION TIME
106 8.77
(1) U = not detected
(2) Concentrations are instrument and lab blank corrected. (3) R (%) = Percent recovery
1M11_PFD1_2.*U, S1D
A p proved by:.
QA/QC Chemist
11.05-200$
dd-mnvyyyy
}][>A x v s a n a l y t i c a l S E R V I C E S L T D pc.m nir, ms a m msi s m t ti., urna* rat3msoshwofi2sj-mii
%
AXYS METHOD MLA-031 Rev 01
pfos_s i _d2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sample ID:
Matrix:
WATER
Sample Size:
Sam ple Receipt Date:
25-NOV-2004
Initial Calibration Date:
Extraction Date:
02-Dec-2004
Instrument ID:
Analysis Date:
03-Dec-2004
Time: 22.30:31
LC Column ID:
Extract Volume (mLJ:
2
Sample Datafile:
Injection Volume (pL): 10.0
Blank Data Filename:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration Units :
ng/mL
CLIENT ID:
24-Nov-2004 14:09 N/A L7411-7 502 r 03-Dec-2004 LC-MS/MS Discovery C18 PFS4G_110529 PFS4G_110S20 PFS4G_110S13
COMPOUND
LAB FLAG '
CONC FOUND'
DETECTION UMIT
RETENTION TIME
PFPeA PFHxA PFHpA PF0A PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
U 0.0061 U 0.0009 U 0.0005
u 0.0003 u 0.0003 u 0.0004 u 0.0002 u 0.0002 U 0.0001 u 0.0014 u 0.0010 u 0.0006
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(n0)
50.0
CONC. FOUND
(no)
51.4
R W RETENTION TIME
103 8.77
(1 ) U = not detected (2) Concentrations are instrument and lab blank corrected. (3) R (%) = Percent recovery
14411_PF0l_2.ds, S I I
Approved by:
Q A/Q C Chem ist
11-06-2005 dO-mm-yyyy
^]((9A X Y S A N A L Y T I C A L S E R V I C E S LT D PO.BO2I9,204SNUISII.WEST,SIOffiT.H.LUMMVSUSTtl2S0)5-5800FUI2M)5S-5B11
77
AXYS METHOD MLA-031 Rev 01
pfo sjSI dz
Form 1AI2
' PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
24-NOV-2004 14:50
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sampla ID:
L7411-8
Matrix:
WATER
Sample Size:
500 n
Sample Receipt Date:
25-NOV-2004
Initial Calibration Date:
03-DOC-2004
Extraction Date:
02-Dec-2004
Instrument ID:
LC-MS/MS
Analysis Date:
03-0ec-2004
Time: 22:49:13
LC Column ID:
Discovery C18
Extract Volume (mL):
2
Sample Datafile;
PFS4G110S30
Injection Volume (pL>: 10.0
Blank Data Filename:
PFS4GJI1QS20
Dilution Factor
KIA
Cal. Ver. Data Filename: PFS4G_110S13
Concentration Units :
ng/mL
COMPOUND
LAB FLAG1
CONC FOUND *
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA
PFBS PFHxS PFOS
U 0.0068 u 0.0009 u 0.0002 u 0.0004 u 0.0002 u 0.0006 u 0.0001
u 0.0002 u 0.0001 u 0.0027 u 0.0018 u 0.0009
LABELED COMPOUND C13-PFDA
LAB FLAG1
SPIKE CONC.
(ng>
50.0
CONC. FOUND
(nfl>
50.4
R(%)>
RETENTION TIME
101 8.77
(1) U = not detected (2) Concentrations are instrum ent and lab blank corrected. (3) R (%) = Percent recovery
111_PFD1_2jd*. S12
Approved by:.
J Z . QA/QC Chemist
1 t -05-2005 dd-mm-yyyy
A X Y S / V f " 4 / * U - Y T I C I A . L S E R V I C E S L T D r.o. BOX22U, 2045 US IB. SI. SlWt, I.C., CMUDUVil 3Stm (50) (55'SiOD TAX(250) 455-5011
AXYS METHOD MLA-031 Rev 01
PFOS_5i_t
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
24-NOV-2004 15:20
Lab Name: A X YS ANALYTICAL SERVICES
Project Name:
MIA
Contract No.:
4191
Lab Sample ID:
L7411-9
Matrix: Sample Receipt Date: Extraction Date:
W ATER 25-NOV-2004 02-DCC-2004
Sample Size: Initial Calibration Data: Inatrumant ID:
499 0 3 -D ec-20 04 LC-M S/M S
n
Analysis Date:
03-Dec-2004
Tim e: 23:07:57
L C Column ID:
D iscovery C1B
Extract Volume (mL):
2
Sample Datafile:
PFS4GJI10S31
Injection Volume (pL): 10.0
Blank Data Filename:
PFS4G J10S20
Dilution Factor:
N/A
Cal. Ver. Data Filename: PFS4G _110S13
Concentration Units :
ng/mL
COMPOUND
LAB FLAG'
CONC FOUND 1
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFTA PFBS PFHxS PFOS
U 0.0162 u 0.0009 u 0.0005 u 0.0004 u 0.0003 u 0.0006 u 0,0001 u 0.0002 u 0.0002 u 0.0020 u 0.0013 u 0.0007
LABELED COMPOUND C13-PFDA
LAB FLAG'
SPIKE CONC.
(ng)
50.0
CONC. FOUND
(ngl
55.1
R(%)>
RETENTION TIME
110 8.77
(1) U = not detected (2) Concentrations are instrument and lab blank corrected. (3) R (%) = Percent recovery
144tt_PFD1_2.Xl. S13
Approved by.
Q A/Q C Chem ist
11-05-2005 dd-cnm-yyyy
e)][5 A X Y 5 / M V | / \ L V T I O \ U S E R V I C E S L T D ro. BO* ??!, 204S Milts ID WESI. SIDNtT, B.L, UMM VBL 3S8 lit (2501 (S5 S8M X (250) 555S11
