Document NXovMGMDoQoX17DkBn0xKojQ

Gasket System 3000 AF3000/GR3000/UF3000 Contents 1 General 1.1 Introduction 1.2 Scope 2 Safety 2.1 Warnings and symbols 2.2 Safety instructions 3 Transport and storage 4 Construction 6 Installation of the gaskets 6.1 General instructions 6.2 Installation of the agitator nozzle gasket type WTR 7 Gasket packing using the UF3000 filler material for gasket types WKT and WKTV 7.1 Construction and properties of the system 7.2 Installation and packing procedure 7.3 Storage and transport of the UF3000 filler material 7.4 Standard consumption values 7.5 Processing notes 7.6 Installation and packing of a gasket with UF3000 8 Starting up new gaskets 9 Maintenance 10 Health and safety at work 11 Faults: causes and correction 12 Related documents Annex 1 UF3000 Safety data sheet Annex 2 Certificate of conformity with TA Luft (Clean Air Act) Annex 3 Certificate of conformity with TA Luft (Clean Air Act) Annex 4 Certificate of conformity FDA Title 21 177.1550 Operating Instructions & Safety Data Sheet conforms to Regulation (EC) No. 1907/2006 (REACH) 316-12e Gasket System 3000 AF3000/GR3000/UF3000 1 General 1.1 Introduction The gaskets may only be installed, commissioned and serviced by authorized technical personnel in machine /plant construction and in strict compli ance with the present instructions as well as the valid standards and provisions. The failure to observe these instructions - no matter whether intentionally or negligently - releases the manufacturer from all liability and warranty claims. The present operating instructions are designed to familiarize users with the gaskets and their use. The operating instructions should be available to the operating and maintenance personnel and should be read and understood prior to any assembly and maintenance work. By knowing the present operating instructions, you can avoid damages to the gasket system and achieve a faultless operation. The figures and data contained in the present operating instructions are subject to change and further development. The latest edition will always supersede all previous ones. 1.2 Scope The gasket system 3000 is used for sealing glasslined flange connections on reactors and storage tanks and for pipelines. The gasket system should only be used within its admissible operating conditions. 2 Safety The safety instructions refer exclusively to the scope of delivery. Please also note the safety instructions valid for your reactor/system and the liquids to be sealed. 2.1 Warnings and symbols In the operating instructions, the danger symbol is used to draw your attention to especially important information. m Compliance with these man datory instructions helps to avoid personal injury and damage to property. m2.2 Safety instructions Please note the following instruc tions: Do not practice any working methods which may endanger safety. In the case of malfunctions, the reactor/system shall be immedia tely stopped and protected against unauthorized restart! Malfunctions shall be immediately corrected! If the gaskets are worn or defective, leakage may occur. This leakage may cause risks to your plant as well as to man and the environment. Therefore, you should ensure regu lar inspections and suitable pro tection and collection facilities, if necessary. Hot system elements need to be protected against accidental con tact. Ensure a safe, environmentally sound disposal of operating and auxiliary substances and replace ment parts in accordance with the valid regulations. PTFE or fluorocarbon caoutchouk may never be burnt or ignited because they produce highly toxic vapors. If fluorocarbon caoutchouk was nevertheless burnt, you have to wear protective gloves because of the possible presence of hydrofluo ric acid. Please note that hydrofluoric acid attacks glasslined surfaces very strongly. 3 Transport and storage In order to guarantee an as-new condition of the gaskets, maintain the following storage conditions: n dry and dust-free n gaskets should be preferably stored in a lying position. If suspended for storage, provide large supporting area. n Do not use standing storage. n steady temperature and ventilation n protection against direct influences of heat and ultra-violet light 2 Pfaudler GmbH Gasket System 3000 AF3000/GR3000/UF3000 4 Construction In addition to the general demands on gaskets for glasslined apparatus (resistance to chemicals and temperature, leakage proofness and elasticity), the capability of the gaskets of being adjusted to the properties of the glasslined flange surfaces is of special importance. Pfaudler supplies special gaskets for all glasslined apparatus and systems. The gasket system consists of the following components: n PTFE envelope chemically modified polytetrafluor ethylene with excellent chemical, thermal and dielectric properties, tested with a stabilized DC voltage of 7000 V in accordance with the GKV guidelines. FDA approval under Title 2, Code of Federal Regulations #177.1550. n Corrugated ring austenitic stainless steel characterized by high chemical resistance to aggressive substances. n Gasket insert AF3000: asbestos-free soft material based on viton-bound aramid fibers. GR3000: high-quality, adhesive-free, bound expanded graphite. n PTFE internal envelope and UF3000 filler material for gasket types WKT and WKTV. Discoloration of the PTFE envelope during operation has no influence on its functional properties. Important: We recommend using only Pfaudler approved gasket systems in combi nation with glasslined flange con nections. Other gaskets might put the entire system at a risk. WT Corrugated ring, PTFE envelope WKT Corrugated ring, UF3000 filler material, PTFE envelope, PTFE internal envelope WKTG Like WKT, but the PTFE envelope is impermeable to diffusion thanks to its 3 mm wall thickness WKTV Corrugated ring, UF3000 filler material, PTFE envelope for vacuum application, PTFE internal envelope WTR Corrugated ring, PTFE envelope with wedge-shaped insert specifically for agitator nozzles WT WT conductive Tab Figure 1 Gasket shapes and explanation of abbreviations 5 Technical data Table 1 Temperature range Conventional gaskets Compressibility 35 - 45 % Resilience min. 20 % WT conductive Compressibility Surface resistivity Temperature Pressure Surface pressure vu when installed Surface pressure vu when installed 35 - 45 % <109 at 23 C and 50% rel. humidity -60/+230 C 40 bar 8 N/mm2 60 N/mm2 Insert material Gasket type WT, WKT, WKTV, WTR, WKTG AF3000 GR3000 Temperature in gasket sealing area [C] -60/+230 -60/+230 Table 2 Pressure Gasket type WT, WKT, WKTV, WTR, WKTG Diameter* DN 25 . . . DN 150 DN 200 . . . DN 800 DN 1000 . . . DN 1200 DN 1400 . . . DN 2000 DN 2200 max. pressure [bar] 40 25 16 10 6 *The larger dimension is to be used with respect to the pressure on oval gaskets. Pfaudler GmbH 33 Gasket System 3000 AF3000/GR3000/UF3000 6 Installation of the gaskets 6.1 General instructions The gaskets should always be placed on dry, clean sealing surfaces. Tighten all screwed connections evenly with the prescribed torque. m For the proper torques, please refer to Operating Instructions 318 or the assembly drawing. The gasket types with a corrugated ring are equipped with holding brackets. If a used gasket is installed, its original position can be restored by this feature. Furthermore, the gaskets no longer slip off from inclined nozzles. For manhole covers, the holding brackets are shifted and clamped in below the circumferential VA ring. For assembly and reactor covers, the holding brackets are fastened to the profiled ring using grooved drive studs. 6.2 Installation of the agitator nozzle gasket type WTR The WTR gasket design was specifically developed to compensate for inclinations of agitator nozzles. The gasket is equipped with two wedge-shaped inserts. By turning the inserts against each other, the gasket thickness can be modified. Thus, an inclination of the agitator nozzle can be compensated. The required total thickness of the gasket is obtained by installing an additional gasket insert, if necessary. When not pressed, the asbestos-free gasket should be 2.5 to 3.0 mm higher than the distance between the glass surfaces of the agitator nozzle and the intermediate flange when mounted (refer to Fig. 3). When tightened with the prescribed torque, the gasket will thus be prestressed to the extent necessary to ensure proper functioning. 6.2.1 Installation on agitator nozzles without leveling ring The distance between the top edge of the agitator support and the glass surface of the agitator nozzle is 20 mm when delivered from the factory (measured at the highest point of the agitator nozzle). The chamber size is reduced to 5 mm by the offset of the intermediate flange. 1 Reactor top head or assembly cover 2 Agitator nozzle 3 Split flange for fastening the intermediate flange (for agitator nozzles size DN 250 or more) 4 Agitator support Figure 2 Before installing the intermediate flange 4 max. 12,0 - 12,5 7,5 - 8,0 1 Agitator nozzle 2 Agitator support 3 Intermediate flange 4 Top edge of agitator support Figure 3 Procedure: t Place WTR gasket on the nozzle. t Ensure a horizontal alignment on all sides of the gasket by turning one of the gasket inserts in the upper side of the gasket. Use a water level to measure levelness in two directions at an angle of 90. t Measure the distance from the upper edge of the agitator support in several locations around the gasket's perimeter. The distance should be identical in all points and should be 12.0 - 12.5 mm in order to achieve the necessary compression of the gasket. t If the value measured is greater, insert an additional (plane) gasket insert of suitable thickness. Gasket inserts will be attached to spare part order. t Put the intermediate flange in place and tighten it with the prescribed torque. 4 Pfaudler GmbH 6.2.2 Installation on agitator nozzles with a leveling ring For agitator nozzles sized DN 250 or more, the two-piece, wedge-shaped leveling ring is adjusted on the agitator nozzle already in the factory and pinned down. The support area is orthogonal to the agitator shaft. When replacing a complete cover and nozzle of a reactor with an assembly cover (series CE, E, DG), the leveling ring must be readjusted. Please call a service technician for performing this type of work. Gasket installation procedure: t Measure dimension z = distance be- tween the glassed surface on the bottom side of the intermediate flange and the support area of the leveling ring; z may be ne gative if the glassed surface is above the level of the support area. t Determine dimension a in 4 to 6 points. a is the distance between the leveling ring and the glassed surface of the agitator nozzle. The sum of a and z is the chamber size y available to the gasket when compressed. t Place WTR gasket on the nozzle. t Ensure a horizontal alignment on all sides of the gasket by turning one of the gasket inserts in the upper side of the gasket (water level). t Measure the height of the gasket in several locations around the gasket's perimeter. The height should be identical in all points and should be y +2.5 mm to y +3.0 mm in order to achieve the necessary compression of the gasket. t If the gasket height is lower, insert an additional (plane) gasket insert of suitable thickness. Gasket inserts will be attached to spare part order. t Put the intermediate flange in place and tighten it with the prescribed torque. 2,5 - 3,0 1 Agitator nozzle 2 Leveling ring 3 Agitator support Figure 4 Pfaudler GmbH Gasket System 3000 AF3000/GR3000/UF3000 5 Gasket System 3000 AF3000/GR3000/UF3000 7 Gasket packing using the UF3000 filler material for gasket types WKT and WKTV 7.1 Construction and properties of the system PTFE is extremely resistant to chemicals. It is furthermore characterized by high thermal resistance and strength within a broad temperature range. It is only attacked by molten alkalis and fluorine at high temperatures. Together with the corrugated ring, the gasket inserts form a strong, elastic combination which prevents the gasket from being pushed out even at high internal pressures or from being drawn in if a vacuum is present. The system has been matched to the special features of the glassed flange surfaces. The two-component UF3000 filler material is pressed out of the double cartridge using the specially provided compressed air gun CP3000 and mixed in a spray nozzle that functions as a static mixer. The UF3000 is automatically shaped to optimally fit all surface tolerances and differences in shape of the flange surfaces. When cured, it forms a stable, highly solid filler material. After curing, the gasket has the same elasticity at all points around its perimeter. Bending stress in the glasslined flange as a consequence of dif- 1 PTFE envelope 2 Corrugated ring 3 Gasket inserts 4 PTFE internal envelope 5 UF3000 filler material Figure 5 Principle of UF3000 with shapes WKT/ WKT V ferent setting behaviors around the flange peri-meter cannot occur. Contrary to soft filler materials, UF3000 ensures that once the gasket fit is reached, it does not change even at different pressures or temperatures. The mechanical skills for properly applying the filler material are easy to learn. Nevertheless, we recommend attending a training course by a service technician on location or at Pfaudler's in Schwetzingen. Contrary to packings consisting of ground or cut fitting pieces the quality of which largely depends on the workmanship of the fitter, the gasket can be optimally adjusted to the glasslined flange faces when observing the handling instructions. m In order to avoid damages to the PTFE envelope of the gasket (Fig. 5, item 1) by the filler material, the WKT and WKTV gaskets have a special PTFE internal envelope. Therefore, the filler material should only be injected into the PTFE inter nal envelope (Fig. 5, item 4) provided for this purpose. 3 2a 2 1 1 Air gun 2 Double cartridge 2a Closure cap 3 Static mixer Figure 6 CP3000 air gun 7.2 Installation and packing procedure The installation of the gasket and the application of the UF3000 packing require very few tools and appliances: n CP3000 air gun, part no. 021 936n UF3000 double cartridge with static mixer, part no. 021 937(the static mixer may also be ordered separately by specifying part no. 021 937M) n customary water bucket n customary thermometer for water bath, min. measuring range 30 . . . 50 C Technical features of the CP3000 air gun n Air connection, internal thread 1/4". A highly flexible pressure hose DN 6 or 1/4" must be used. n Compressed air supply max. 8 bar n Max. operating pressure of the air gun 6 bar (can be adjusted on pressure regulator) n Sound level < 83 dBA n For explosion protection, refer to Annex 3, EC Declaration of Conformity m Risk of getting hands or fin gers squeezed in between the feed pistons and the housing. When the safety device is intact and has not been manipulated, the feed pistons can be moved back and forth by the air pressure with the double cartridge installed only. Cut off the air supply to put the air gun out of operation or clean it. If it is necessary to clean the inter nal shell, the feed pistons may be moved manually. The air gun may only be operated if a water separator/oiler is fitted to the air connection. Do not alter or remove the pressure controller. Only Pfaudler original spare parts may be used for re placement. 6 Pfaudler GmbH Gasket System 3000 AF3000/GR3000/UF3000 The air gun shall be checked for any defects or damages and should only be used if in perfect condition. Damaged air guns should be taken out of service immediately and send to Pfaudler for repair. Do not try to modify or repair the air gun. The air gun hose should be positioned in a way to avoid any tripping or tangling. Take care when connecting and disconnecting the air gun hose. All users and people nearby must wear safety glasses. The user also has to wear gloves. Please handle and store the air gun with care. The air gun or the static mixer must not be pointed at people or animals when ready for use. 7.3 Storage and transport of the UF3000 filler material Shelf life: refer to label print Storage temperature: +2 . . . 40 C Transport temperature: Short-term deviations from the storage temperature are possible. m Dry storage: After reusing close the cartridge again, it is dura ble for 6 months. 7.4 Standard consumption values UF3000 is sufficient for a gasket perimeter of approx. 1 m, but any residues remaining in the last double cartridge opened may be reused. For this purpose, simply remove the static mixer and close the double cartridge again. A used static mixer must be disposed of because once mixed, the material cures inside the mixer. The series of pictures (refer to Section 7.6) is used to describe the proper use by the example of a main flange gasket. Number of double cartridges = gasket diameter D in meters x = 0.5 x 3.14 = 1.57 Double cartridges Figure 7 Consumption shown by the example of a gasket size DN 500 7.5 Processing notes Temperature of the filler material n The temperature of the UF3000 filler material should be 40 10 C when injecting the material. 50 50 40 40 30 30 n At higher temperatures, injection becomes easier, and the curing process is accelerated. n If the temperature of the filler material is below 30 C, it should be warmed before use. This is done most efficiently by immersing the double cartridge into a bucket of hot water for approx. 30 min. n If the specified temperature is exceeded, the mixed filler material cures very quickly. n Temperatures lower than the desired temperatures prevent a smooth injection due to the high viscosity of the material. Table 3 UF3000 curing time Ambient temperature [C] 5 15 25 Curing time [h] approx. 7 approx. 4 approx. 2 Ambient temperature n The curing time of the UF3000 two- component filler material depends on the ambient temperature. n At especially low ambient temperatures (< 5 C), it is easily possible to cure the UF3000 filler material within a few minutes with the help of the apparatus heating system. When curing, the temperature at the gasket should not exceed 60 C. m Only the static mixer provid ed may be used. The static mixer must not be modified Only the outer tip may be cut off in order to reach a broader applica tion area. The remaining intact mix er field ensures faultless mixing even without the tip. As the filler material AF3000 cures quickly, it is advisable to place the agitator inside the reactor already before injecting the gasket and lowering the cover of a two-piece reactor. The filler material must be allowed to cure without being disturbed. However, you may start setting up the drive or connecting the piping, for example, while the material cures. Of course, our service technicians are also available on request for all works described. Pfaudler GmbH 7 Gasket System 3000 AF3000/GR3000/UF3000 7.6 Installation and packing of a gasket with UF3000 3 1 4 1 5 CP3000 air gun control elements 2 1 Trigger 2 Retraction of pistons 3 Cartridge ejector 4 Pressure regulator 5 Compressed air port 2 Placing cover in position on a trial basis. Use intermediate layer to protect the glass! Estimate gap width in order to determine the necessary quantity of UF3000. 3 The temperature of the UF3000 filler material should be 40 10 C when injecting the material. Warm up the filler material, if necessary (refer to Section 7.5). 4 Insert double cartridge into the half-shell of the air gun, note that the larger cartridge must be on top. 8 Pfaudler GmbH Gasket System 3000 AF3000/GR3000/UF3000 5 Unscrew cap from double cartridge . . . 7 6 . . . and screw on static mixer until it is firm. Connect compressed air to the air gun. Press trigger on air gun. The ejection speed can be adjusted at the pressure regulator (Fig. 1, item 4). m Excessive pressure may lead to extreme contamination of the air gun in the area of the feed pistons (especially if the double cartridge has not been prewarmed), because the components of the filler material may emerge backwards through the cartridge piston due to the ram pressure on the static mixer. The UF3000 filler material is injected evenly corresponding to the estimated sealing gap width until the internal envelope is completely filled. It is advisable to use a support to inject the filler material into the suspended gasket. Pfaudler GmbH 9 Gasket System 3000 AF3000/GR3000/UF3000 8 Gaskets with a large, unwieldy diameter can also be injected with filler material while lying on the actual reactor flange. In order to remove the double cartridge from the air gun, first move the feed pistons backward by operating the red button (Fig. 1, item 2), and then press the ejection mechanism (Fig. 1, item 3). If several double cartridges are needed to fill a gasket, one static mixer may be used for all cartridges. When the gasket has been filled, remove the last cartridge from the air gun and isolate the air supply. Open, but not totally empty double cartridges may be closed with the cap and reused later. m For the disposal of the used static mixers and the double cartridges, refer to Section 10. 9 Put the gasket filled with UF3000 in place and slowly lower the cover. Caution: Place large covers down lightly due to their inherent weight and secure them in this position with a hoist until the filler material has finished curing. 10 Shaping and position control are achieved with the help of individual clamps. The position of the cover can still be influenced in this way. 10 Pfaudler GmbH Gasket System 3000 AF3000/GR3000/UF3000 11 The excess filler material is pressed out and can be cut off once it has lost its sticky properties. The thickness of the filler material should be 2 mm around the entire flange perimeter. When the filler material has totally cured, apply the clamps one by one. 12 Finally tighten the clamps several times one by one with the prescribed torque. Before performing this step, you must ensure that the filler material can no longer be deformed plastically. In order to close the cartridge again 13 To close the double cartridge again, please use original, unscrewed cat (pic. 5). Dry storage: After re-using close the cartridge again, it is durable for 6 months (Chapter 7.3). Pfaudler GmbH 11 Gasket System 3000 AF3OOO/GR3OOO/UF3OOO 8 Starting up new gaskets Even when packed with UF3000, the reliability and useful life of the gasket during operation will depend decisively on the start-up procedure for the reactor after the gasket has been replaced. It is necessary to re-tighten the clamps several times during the start-up phase in order to compensate for the settling amount of the new gasket -- by the way, this is independent of the filler material. However, with the help of UF3000, you can achieve that the gasket settles faster and more evenly. The following method has proven its worth in practice: v When the clamps have been tightened with the nominal torque, a pressure test with water must be performed. Afterwards, correct the clamp tightening torque while the reactor is de-pressurized. For the maximum permitted tightening torques of the flange connections, please refer to Operating Instructions 318. v Then perform a second pressure test with water. For this purpose, heat up the reactor to its operating temperature and keep it at this temperature for approx. 12 to 16 hours. Then re-tighten the clamps to their nominal torque while the reactor is de-pressurized and at ambient temperature. v Now the apparatus can be started up. It is advisable to check the tightening torques of the clamps after the first, second and approx. tenth batch. If necessary, re-tighten the clamps with the nominal torque. A gasket that has been started up according to these instructions will justify the efforts by a long useful life and high operational reliability. We recommend providing a splash protection (e.g. sleeve) around flange connections. 9 Maintenance Once it has been installed, the gasket is practically maintenance-free. An occasional visual inspection of the exposed part of the PTFE envelope in the reactor for mechanical damages and the outer perimeter of the gasket for signs of leaks will be sufficient (use leak detection spray, if necessary). The tightening torques of the clamps should be checked every six months in the course of apparatus maintenance (refer to Operating Instructions 318). 10 Health and safety at work AL Please note the detailed instructions and information concerning the UF3OOO filler material given in the material safety data sheet (Annex 1). When both components of the filler material have been mixed and cured, the material is neutral and does not pose and risks to health or the environment. 11 Faults: causes and correction If you notice a leak, check the prescribed torque at the de-pressurized reactor at ambient temperature and re-tighten the clamps, if necessary. It may be necessary to observe additional, specific safety measures. If the leakage of the gasket system cannot be corrected by these measures, the gasket must be replaced. Again, take all specific precautions that might be necessary. 12 Related documents Material safety data sheet for UF3000 filler material (in Annex) Operating instructions 318, Tighten- ing torques for bolts on Pfaudler apparatuses Technical Information No. 651 Optional: CP3000 Service KitCP 3000 (TNr. 021 375). Ask for more information. Chemical Resistance of PTFE TI 951 12 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : PFAUDLER UF 3000 A Unique Formula Identifier (UFI) : AYG3-E0EV-800A-8QC6 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Epoxy constituents 1.3 Details of the supplier of the safety data sheet Company Address Telephone Telefax Huntsman Advanced Materials (Europe)BVBA Everslaan 45 3078 Everberg Belgium +41 61 299 20 41 +41 61 299 20 40 E-mail address of person responsible for the SDS @huntsman.com 1.4 Emergency telephone number Emergency telephone number : Berlin: 0049 30 19 24 0 & 0049 30 30 68 6 7 11 Bonn: 0049 228 19 27 0 & 0049 228 28 7 3 32 11 Erfurt: 0049 361 73 07 30 Freiburg: 0049 761 16 24 0 Gottingen: 0049 51 19 24 0 & 0049 551 38 31 80 Homburg: 0049 6841 19 24 0 Mainz: 0049 6131 19 24 0 & 0049 6131 23 24 66 Munchen: 0049 89 19 24 0 Nurnberg: 0049 911 39 8 2 45 1 EUROPE: France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Skin irritation, Category 2 H315: Causes skin irritation. Pfaudler GmbH 13 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Serious eye damage, Category 1 Skin sensitisation, Category 1 Chronic aquatic toxicity, Category 2 H318: Causes serious eye damage. H317: May cause an allergic skin reaction. H411: Toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : H315 H317 H318 H411 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Toxic to aquatic life with long lasting effects. : Prevention: P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P391 Collect spillage. Hazardous components which must be listed on the label: Phenol, polymer with formaldehyde, glycidyl ether Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE) 1,4-Bis(2,3-epoxypropoxy)butane 2-Propenoic acid, reaction products with dipentaerythritol EUH205 Additional Labelling: Contains epoxy constituents. May produce an allergic reaction. 14 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Toxicological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical name Phenol, polymer with formaldehyde, glycidyl ether CAS-No. EC-No. Index-No. Registration number 28064-14-4 Polymer Formaldehyde, oligomeric reaction products with 1-chloro2,3-epoxypropane and phenol (BPFDGE) 1,4-Bis(2,3epoxypropoxy)butane 01-2119454392-40 2425-79-8 219-371-7 603-072-00-7 01-2119494060-45 2-Propenoic acid, reaction products with dipentaerythritol 1384855-91-7 01-2119980666-22 For explanation of abbreviations see section 16. Classification Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411 Skin Irrit. 2; H315 Skin Sens. 1; H317 Aquatic Chronic 2; H411 Acute Tox. 4; H302 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Chronic 3; H412 Concent ration (% w/w) >= 25 < 30 >= 2,5 < 10 >= 3 - < 10 Acute toxicity estimate Acute dermal toxicity: 1 100 mg/kg Eye Irrit. 2; H319 Skin Sens. 1A; H317 Aquatic Chronic 3; H412 >= 2,5 < 10 Pfaudler GmbH 15 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Treat symptomatically. Get medical attention if symptoms occur. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing If potential for exposure exists refer to Section 8 for specific personal protective equipment. Avoid inhalation, ingestion and contact with skin and eyes. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If inhaled In case of skin contact : Call a physician or poison control centre immediately. If inhaled, remove to fresh air. Get medical attention if symptoms occur. : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2 Most important symptoms and effects, both acute and delayed None known. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. 16 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : Exercise caution when using a high volume water jet as it may scatter and spread fire 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Carbon oxides 5.3 Advice for firefighters Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary. Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Refer to protective measures listed in sections 7 and 8. 6.2 Environmental precautions Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pfaudler GmbH 17 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal considerations see section 13., See Section 1 for emergency contact information., For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitisation of susceptible persons. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Advice on protection against : Normal measures for preventive fire protection. fire and explosion Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Keep in properly labelled containers. Advice on common storage : For incompatible materials please refer to Section 10 of this SDS. Storage class (TRGS 510) : 10, Combustible liquids Further information on storage stability : Stable under normal conditions. Recommended storage temperature : 2 - 40 C 7.3 Specific end use(s) Specific use(s) : No data available 18 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 SECTION 8: Exposure controls/personal protection 8.1 Control parameters Contains no substances with occupational exposure limit values. Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006: Substance name 1,4-Bis(2,3epoxypropoxy)butane End Use Workers Exposure routes Inhalation Potential health effects Long-term systemic effects Workers Dermal Long-term systemic effects Consumers Consumers Inhalation Dermal Long-term systemic effects Long-term systemic effects Consumers Oral Long-term systemic effects Value 4,7 mg/m3 6,66 mg/kg bw/day 1,16 mg/m3 3,33 mg/kg bw/day 0,33 mg/kg bw/day Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006: Substance name 1,4-Bis(2,3-epoxypropoxy)butane Environmental Compartment Fresh water Value 0,024 mg/l Remarks: Assessment Factors Marine water 0,002 mg/l Assessment Factors Sewage treatment plant Assessment Factors 100 mg/l Fresh water sediment Equilibrium method 0,084 mg/kg dry weight (d.w.) Marine sediment Equilibrium method 0,008 mg/kg dry weight (d.w.) Soil Equilibrium method 0,003 mg/kg dry weight (d.w.) Oral Siloxanes and Silicones, di-Me, reaction products with silica Fresh water sediment Assessment Factors 0,028 mg/kg > 100 mg/kg Soil Assessment Factors 23 mg/kg Pfaudler GmbH 19 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 8.2 Exposure controls Personal protective equipment Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Hand protection Remarks : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. The suitability for a specific workplace should be discussed with the producers of the protective gloves. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Respiratory protection : W A R N I N G ! This product contains quartz, which has been classified by IARC as carcinogenic for humans (Group 1), and which can cause silicosis and lung cancer following exposure to respirable dust. It is therefore important to take particular care to avoid inhalation exposure when mechanically processing cured material (e.g. grinding, sanding, sawing). SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical state : paste Colour : beige Odour : slight Odour Threshold : No data is available on the product itself. pH : substance/mixture is non-soluble (in water) Melting point/freezing point Boiling point Flash point Evaporation rate Flammability (solid, gas) Burning rate : No data is available on the product itself. : > 200 C : > 200 C Method: Pensky-Martens closed cup, closed cup : No data is available on the product itself. : No data is available on the product itself. : No data is available on the product itself. 20 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Upper explosion limit / Upper flammability limit : No data is available on the product itself. Lower explosion limit / Lower flammability limit : No data is available on the product itself. Vapour pressure : < 0,002 hPa (20 C) Relative vapour density : No data is available on the product itself. Relative density : No data is available on the product itself. Density : 1,65 g/cm3 (40 C) Solubility(ies) Water solubility : practically insoluble (20 C) Solubility in other solvents Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity, dynamic Explosive properties Oxidizing properties : No data is available on the product itself. : No data is available on the product itself. : No data is available on the product itself. : > 200 C : 200 000 - 400 000 mPa.s (40 C) : No data is available on the product itself. : No data is available on the product itself. 9.2 Other information No data available SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : No hazards to be specially mentioned. 10.4 Conditions to avoid Conditions to avoid : None known. 10.5 Incompatible materials Pfaudler GmbH 21 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Materials to avoid : None known. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 10.6 Hazardous decomposition products No hazardous decomposition products are known. SECTION 11: Toxicological information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Acute oral toxicity - Product : Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method Acute inhalation toxicity Product : Acute toxicity estimate : > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute dermal toxicity Product : Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method Acute toxicity (other routes of : No data available administration) Skin corrosion/irritation Components: Phenol, polymer with formaldehyde, glycidyl ether: Species: Rabbit Method: OECD Test Guideline 404 Result: Irritating to skin. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Species: Rabbit Method: OECD Test Guideline 404 Result: Irritating to skin. 1,4-Bis(2,3-epoxypropoxy)butane: Species: Rabbit Method: OECD Test Guideline 404 Result: Skin irritation GLP: yes 2-Propenoic acid, reaction products with dipentaerythritol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Serious eye damage/eye irritation Components: 22 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Phenol, polymer with formaldehyde, glycidyl ether: Species: Rabbit Method: OECD Test Guideline 405 Result: Irritating to eyes. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Species: Rabbit Method: OECD Test Guideline 405 Result: No eye irritation 1,4-Bis(2,3-epoxypropoxy)butane: Species: Rabbit Assessment: Risk of serious damage to eyes. Method: OECD Test Guideline 405 GLP: yes 2-Propenoic acid, reaction products with dipentaerythritol: Species: Rabbit Method: OECD Test Guideline 405 Result: Eye irritation Respiratory or skin sensitisation Components: Phenol, polymer with formaldehyde, glycidyl ether: Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: May cause sensitisation by skin contact. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: May cause sensitisation by skin contact. 1,4-Bis(2,3-epoxypropoxy)butane: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. GLP: yes 2-Propenoic acid, reaction products with dipentaerythritol: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: The product is a skin sensitiser, sub-category 1A. Components: 1,4-Bis(2,3-epoxypropoxy)butane: Pfaudler GmbH 23 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Assessment: Harmful if inhaled. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Germ cell mutagenicity Components: Phenol, polymer with formaldehyde, glycidyl ether: Genotoxicity in vitro : Metabolic activation: with and without metabolic activation Result: positive : Concentration: 0 - 5000 ug/plate Metabolic activation: with and without metabolic activation Result: positive Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Genotoxicity in vitro : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: positive : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive 1,4-Bis(2,3-epoxypropoxy)butane: Genotoxicity in vitro : Test Type: reverse mutation assay Concentration: 10 - 5000 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive GLP: yes Remarks: Not classified due to data which are conclusive although insufficient for classification. : Test Type: Chromosome aberration test in vitro Test system: Chinese hamster lung cells Concentration: 1 - 100 g/L Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: positive GLP: yes Remarks: Not classified due to data which are conclusive although insufficient for classification. : Test Type: In vitro mammalian cell gene mutation test 24 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive GLP: no Remarks: Not classified due to data which are conclusive although insufficient for classification. 2-Propenoic acid, reaction products with dipentaerythritol: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella tryphimurium and E. coli Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Components: Phenol, polymer with formaldehyde, glycidyl ether: Genotoxicity in vivo : Cell type: Germ Application Route: Oral Result: negative Cell type: Somatic Application Route: Oral Dose: 0 - 5000 mg/kg Result: negative Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Genotoxicity in vivo : Cell type: Somatic Application Route: Oral Exposure time: 48 h Dose: 2000 mg/kg Method: OECD Test Guideline 474 Result: negative Cell type: Somatic Application Route: Oral Dose: 2000 mg/kg Method: OECD Test Guideline 486 Result: negative 1,4-Bis(2,3-epoxypropoxy)butane: Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse (male) Cell type: Somatic Application Route: Oral Exposure time: 4 d Dose: 187.5 - 750 mg/kg Pfaudler GmbH 25 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Method: OECD Test Guideline 474 Result: negative GLP: yes Test Type: unscheduled DNA synthesis assay Test species: Rat Cell type: Liver cells Application Route: Oral Method: OECD Test Guideline 486 Result: negative 2-Propenoic acid, reaction products with dipentaerythritol: Genotoxicity in vivo : Test Type: Micronucleus test Test species: Mouse (male and female) Method: OECD Test Guideline 474 Result: negative Components: 1,4-Bis(2,3-epoxypropoxy)butane: Germ cell mutagenicity- : Weight of evidence does not support classification as a germ Assessment cell mutagen., Animal testing did not show any mutagenic effects. Carcinogenicity Components: Phenol, polymer with formaldehyde, glycidyl ether: Species: Rat, male and female Application Route: Oral Exposure time: 24 month(s) Dose: 15 mg/kg Frequency of Treatment: 7 daily Method: OECD Test Guideline 453 Result: negative Species: Mouse, male Application Route: Dermal Exposure time: 24 month(s) Dose: .1 mg/kg Frequency of Treatment: 3 daily Method: OECD Test Guideline 453 Result: negative Species: Rat, female Application Route: Dermal Exposure time: 24 month(s) Dose: 1 mg/kg Frequency of Treatment: 5 daily Method: OECD Test Guideline 453 Result: negative 26 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 2-Propenoic acid, reaction products with dipentaerythritol: Species: Rat, male and female Application Route: inhalation (vapour) Dose: 0, 12.8, 32 or 80 ppm 12,8 ppm Method: OECD Test Guideline 451 Carcinogenicity Assessment : No data available Reproductive toxicity Components: Phenol, polymer with formaldehyde, glycidyl ether: Effects on fertility : Species: Rat, male and female Application Route: Oral Method: OECD Test Guideline 416 Result: No effects on fertility and early embryonic development were detected. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Species: Rat, male and female Application Route: Oral Method: OECD Test Guideline 416 Result: No effects on fertility and early embryonic development were detected. Components: Phenol, polymer with formaldehyde, glycidyl ether: Effects on foetal : Species: Rabbit, female development Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 30 mg/kg body weight Result: No teratogenic effects Species: Rabbit, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 60 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 180 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Species: Rabbit, female Pfaudler GmbH 27 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 30 mg/kg body weight Result: No teratogenic effects 1,4-Bis(2,3-epoxypropoxy)butane: Test Type: Pre-natal Species: Rat, female Application Route: Oral Dose: 0/30/100/300 mg/kg bw/day Duration of Single Treatment: 17 d General Toxicity Maternal: No observed adverse effect level: 300 mg/kg body weight Developmental Toxicity: No observed adverse effect level: 300 mg/kg body weight Method: OECD Test Guideline 414 GLP: yes Remarks: Information given is based on data obtained from similar substances. Reproductive toxicity Assessment : No data available STOT - single exposure No data available STOT - repeated exposure No data available Repeated dose toxicity Components: Phenol, polymer with formaldehyde, glycidyl ether: Species: Rat, male and female NOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 14 WeeksNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male and female NOEL: 10 mg/kg Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity Species: Mouse, male NOAEL: 100 mg/kg Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 3 d Method: Subchronic toxicity Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): 28 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Species: Rat, male and female NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 13 WeeksNumber of exposures: 7 d Method: Subchronic toxicity 1,4-Bis(2,3-epoxypropoxy)butane: Species: Rat, male and female NOAEL: 200 mg/kg Application Route: Oral Exposure time: 28 dNumber of exposures: daily Dose: 25, 100, 200, 400 mg/kg Method: Subacute toxicity Species: Rat, male and female NOAEL: 263 mg/kg Application Route: Oral Exposure time: 90 hNumber of exposures: daily Dose: 0,30,100,300 mg/kg bw/day Method: OECD Test Guideline 408 GLP: yes Remarks: Information given is based on data obtained from similar substances. Components: 1,4-Bis(2,3-epoxypropoxy)butane: Repeated dose toxicity - : Harmful if inhaled. Assessment Aspiration toxicity No data available 11.2 Information on other hazards Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Experience with human exposure General Information: No data available Inhalation: No data available Skin contact: No data available Pfaudler GmbH 29 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Eye contact: No data available Ingestion: No data available SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Toxicology, Metabolism, Distribution No data available Neurological effects No data available Further information Ingestion: No data available SECTION 12: Ecological information 12.1 Toxicity Components: Phenol, polymer with formaldehyde, glycidyl ether: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1,5 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 1,7 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202 EC50 (Daphnia magna (Water flea)): 2,7 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Toxicity to algae/aquatic plants : EC50 (Selenastrum capricornutum (green algae)): 9,4 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Toxicity to microorganisms : IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water 30 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : GLP: yes : NOEC: 0,3 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211 Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Toxicity to fish : LC50 (Fish): 2,54 mg/l Exposure time: 96 h Method: Calculation method Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 2,55 mg/l Exposure time: 48 h Method: Calculation method Toxicity to algae/aquatic plants : EC50 (Selenastrum capricornutum (green algae)): 1,8 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201 Toxicity to microorganisms : IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0,3 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211 Remarks: Information given is based on data obtained from similar substances. 1,4-Bis(2,3-epoxypropoxy)butane: Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): 24 mg/l End point: mortality Exposure time: 96 h Test Type: static test Analytical monitoring: no Test substance: Fresh water Method: OECD Test Guideline 203 GLP: no Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 75 mg/l End point: Immobilization Exposure time: 24 h Test Type: static test Analytical monitoring: no Test substance: Fresh water Pfaudler GmbH 31 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Method: OECD Test Guideline 202 GLP: no Toxicity to algae/aquatic plants : EL50 (Pseudokirchneriella subcapitata (green algae)): > 160 mg/l Exposure time: 72 h Test Type: static test Analytical monitoring: yes Test substance: Fresh water Method: OECD Test Guideline 201 GLP: yes NOELR (Pseudokirchneriella subcapitata (green algae)): 40 mg/l Exposure time: 72 h Test Type: static test Analytical monitoring: yes Test substance: Fresh water Method: OECD Test Guideline 201 GLP: yes Toxicity to microorganisms : IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Analytical monitoring: no Test substance: Fresh water Method: OECD Test Guideline 209 GLP: no 2-Propenoic acid, reaction products with dipentaerythritol: Toxicity to fish : LL50 (Cyprinus carpio (Carp)): 13 mg/l Exposure time: 96 h Test Type: static test Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 18 mg/l Exposure time: 48 h Test Type: static test Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EL50 (Pseudokirchneriella subcapitata (green algae)): > 100 mg/l Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 GLP: yes 12.2 Persistence and degradability Components: Phenol, polymer with formaldehyde, glycidyl ether: Biodegradability : Inoculum: Sewage (STP effluent) Concentration: 20 mg/l Result: Not readily biodegradable. 32 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301F Stability in water : Degradation half life (DT50): 4,83 d (25 C) pH: 4 Method: OECD Test Guideline 111 Remarks: Fresh water Degradation half life (DT50): 7,1 d (25 C) pH: 9 Method: OECD Test Guideline 111 Remarks: Fresh water Degradation half life (DT50): 3,58 d (25 C) pH: 7 Method: OECD Test Guideline 111 Remarks: Fresh water Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Biodegradability : Inoculum: activated sludge Concentration: 3 mg/l Result: Not biodegradable Biodegradation: ca. 0 % Exposure time: 28 d Method: Directive 67/548/EEC Annex V, C.4.E. 1,4-Bis(2,3-epoxypropoxy)butane: Biodegradability : Test Type: aerobic Inoculum: activated sludge Concentration: 20 mg/l Result: Not readily biodegradable. Biodegradation: 43 % Exposure time: 28 d Method: OECD Test Guideline 301F GLP: yes Test Type: aerobic Inoculum: Sewage (STP effluent) Concentration: 20 mg/l Result: Not readily biodegradable. Biodegradation: 38 % Related to: Dissolved organic carbon (DOC) Exposure time: 28 d Method: OECD Test Guideline 301E GLP: no 2-Propenoic acid, reaction products with dipentaerythritol: Biodegradability : Test Type: aerobic Inoculum: activated sludge Concentration: 18 mg/l Result: Not biodegradable Biodegradation: 0 % Pfaudler GmbH 33 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Exposure time: 28 d Method: OECD Test Guideline 301B 12.3 Bioaccumulative potential Components: Phenol, polymer with formaldehyde, glycidyl ether: Bioaccumulation : Bioconcentration factor (BCF): 31 Remarks: Does not bioaccumulate. Partition coefficient: noctanol/water : log Pow: 3,242 (25 C) pH: 7,1 Method: OECD Test Guideline 117 Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Bioaccumulation : Species: Fish Bioconcentration factor (BCF): 150 Remarks: Does not bioaccumulate. Partition coefficient: noctanol/water : log Pow: 2,7 - 3,6 Method: OECD Test Guideline 117 1,4-Bis(2,3-epoxypropoxy)butane: Partition coefficient: n- : log Pow: -0,269 (25 C) octanol/water pH: 6,7 Method: OECD Test Guideline 117 GLP: yes 12.4 Mobility in soil Components: Phenol, polymer with formaldehyde, glycidyl ether: Distribution among : Koc: 445 environmental compartments Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (BPFDGE): Distribution among : Koc: 4460 environmental compartments Method: OECD Test Guideline 121 1,4-Bis(2,3-epoxypropoxy)butane: Distribution among : Koc: 12,59 environmental compartments Method: OECD Test Guideline 121 12.5 Results of PBT and vPvB assessment Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.. 34 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long lasting effects. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of contents/ container to an approved waste disposal plant. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information IATA 14.1 UN number or ID number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) : UN 3082 : Environmentally hazardous substance, liquid, n.o.s. (EPOXY RESIN) : 9 : III : Miscellaneous : 964 : 964 IMDG Pfaudler GmbH 35 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 14.1 UN number or ID : UN 3082 number 14.2 UN proper shipping : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, name N.O.S. (EPOXY RESIN) 14.3 Transport hazard : 9 class(es) 14.4 Packing group : III Labels : 9 EmS Code : F-A, S-F 14.5 Environmental hazards Marine pollutant : yes ADR 14.1 UN number or ID : UN 3082 number 14.2 UN proper shipping : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, name N.O.S. (EPOXY RESIN) 14.3 Transport hazard : 9 class(es) 14.4 Packing group : III Labels : 9 14.5 Environmental hazards Environmentally hazardous : yes RID 14.1 UN number or ID : UN 3082 number 14.2 UN proper shipping : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, name N.O.S. (EPOXY RESIN) 14.3 Transport hazard : 9 class(es) 14.4 Packing group : III Labels : 9 14.5 Environmental hazards Environmentally hazardous : yes 14.7 Maritime transport in bulk according to IMO instruments Not applicable for product as supplied. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACH - List of substances subject to authorisation (Annex XIV) : Not applicable REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). 36 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. E2 ENVIRONMENTAL HAZARDS Water contaminating class (Germany) : WGK 2 obviously hazardous to water Classification according to AwSV, Annex 1 (5.2) TA Luft List (Germany) : Total dust: Not applicable : Inorganic substances in powdered form: Not applicable : Inorganic substances in vapour or gaseous form: Not applicable : Organic Substances: Not applicable : Carcinogenic substances: Not applicable : Mutagenic: Not applicable : Toxic to reproduction: Not applicable Other regulations: Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable. The components of this product are reported in the following inventories: DSL : This product contains one or several components listed in the Canadian NDSL. AIIC : On the inventory, or in compliance with the inventory NZIoC : Not in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory Pfaudler GmbH 37 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 TSCA : All substances listed as active on the TSCA inventory Inventories AICS (Australia), AIIC (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (United States of America (USA)) 15.2 Chemical safety assessment Chemical Safety Assessments for all substances in this product are either Complete or Not applicable. SECTION 16: Other information Full text of H-Statements H302 H312 H315 H317 H318 H319 H332 H411 H412 : Harmful if swallowed. : Harmful in contact with skin. : Causes skin irritation. : May cause an allergic skin reaction. : Causes serious eye damage. : Causes serious eye irritation. : Harmful if inhaled. : Toxic to aquatic life with long lasting effects. : Harmful to aquatic life with long lasting effects. Full text of other abbreviations Acute Tox. : Aquatic Chronic : Eye Dam. : Eye Irrit. : Skin Irrit. : Skin Sens. : Acute toxicity Chronic aquatic toxicity Serious eye damage Eye irritation Skin irritation Skin sensitisation Further information Classification of the mixture: Classification procedure: Skin Irrit. 2 H315 Calculation method Eye Dam. 1 H318 Calculation method Skin Sens. 1 H317 Calculation method Aquatic Chronic 2 H411 Calculation method The information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. 38 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 A Version 1.1 Revision Date: 18.03.2021 SDS Number: 400001010475 Annex 1 UF3000 Safety data sheet Date of last issue: 11.05.2015 Date of first issue: 11.05.2015 Print Date 29.06.2021 THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users. The trademarks above are the property of Huntsman Corporation or an affiliate thereof. NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. Pfaudler GmbH 39 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : PFAUDLER UF 3000 B Unique Formula Identifier (UFI) : NPU3-P0QG-J006-XD68 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Hardener 1.3 Details of the supplier of the safety data sheet Company Address Telephone Telefax Huntsman Advanced Materials (Europe)BVBA Everslaan 45 3078 Everberg Belgium +41 61 299 20 41 +41 61 299 20 40 E-mail address of person responsible for the SDS @huntsman.com 1.4 Emergency telephone number Emergency telephone number : Berlin: 0049 30 19 24 0 & 0049 30 30 68 6 7 11 Bonn: 0049 228 19 27 0 & 0049 228 28 7 3 32 11 Erfurt: 0049 361 73 07 30 Freiburg: 0049 761 16 24 0 Gottingen: 0049 51 19 24 0 & 0049 551 38 31 80 Homburg: 0049 6841 19 24 0 Mainz: 0049 6131 19 24 0 & 0049 6131 23 24 66 Munchen: 0049 89 19 24 0 Nurnberg: 0049 911 39 8 2 45 1 EUROPE: France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 H332: Harmful if inhaled. 40 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Annex 1 UF3000 Safety data sheet Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Skin corrosion, Sub-category 1B Serious eye damage, Category 1 Skin sensitisation, Category 1 Reproductive toxicity, Category 1B Chronic aquatic toxicity, Category 2 H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage. H317: May cause an allergic skin reaction. H360F: May damage fertility. H411: Toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : H314 H317 H332 H360F H411 Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful if inhaled. May damage fertility. Toxic to aquatic life with long lasting effects. : Prevention: P201 Obtain special instructions before use. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage. Hazardous components which must be listed on the label: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction Pfaudler GmbH 41 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 2,2'-Iminodi(ethylamine) Amines, polyethylenepoly-, pentaethylenehexamine fraction 4,4'-Isopropylidenediphenol Additional Labelling: Restricted to professional users. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: This substance/mixture contains components considered to have endocrine disrupting properties for environment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Toxicological information: This substance/mixture contains components considered to have endocrine disrupting properties affecting human health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical name Reaction products of fatty acid dimers and trimers, C18 (unsaturated), alkyl and fatty acids, C18 (unsaturated) alkyl with amines,, polyethylenepoly-, triethylenetetramine fraction, 2,2'-Iminodi(ethylamine) CAS-No. EC-No. Index-No. Registration number Not Assigned 01-2119972322-40 111-40-0 203-865-4 612-058-00-X 01-2119473793-27 Amines, polyethylenepoly-, pentaethylenehexamine fraction Not Assigned 01-2119485826-22 42 Classification Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1A; H317 Aquatic Chronic 2; H411 Concent ration (% w/w) >= 10 < 20 Acute Tox. 4; H302 Acute Tox. 2; H330 Acute Tox. 4; H312 Skin Corr. 1B; H314 Eye Dam. 1; H318 Skin Sens. 1; H317 STOT SE 3; H335 (Respiratory system) Acute Tox. 4; H302 Acute Tox. 4; H312 Skin Corr. 1B; H314 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Acute 1; H400 >= 5 - < 10 >= 5 - < 10 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Aquatic Chronic 1; H410 M-Factor (Acute aquatic toxicity): 1 M-Factor (Chronic aquatic toxicity): 1 4,4'-Isopropylidenediphenol 80-05-7 201-245-8 604-030-00-0 01-2119457856-23 Eye Dam. 1; H318 Skin Sens. 1; H317 Repr. 1B; H360F STOT SE 3; H335 (Respiratory system) Aquatic Chronic 2; H411 >= 3 - < 10 For explanation of abbreviations see section 16. M-Factor (Chronic aquatic toxicity): 1 SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Treat symptomatically. Get medical attention if symptoms occur. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing If potential for exposure exists refer to Section 8 for specific personal protective equipment. Avoid inhalation, ingestion and contact with skin and eyes. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If inhaled : Consult a physician after significant exposure. If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. Pfaudler GmbH 43 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2 Most important symptoms and effects, both acute and delayed None known. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : Exercise caution when using a high volume water jet as it may scatter and spread fire 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. 5.3 Advice for firefighters Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary. Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 44 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Annex 1 UF3000 Safety data sheet Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Refer to protective measures listed in sections 7 and 8. 6.2 Environmental precautions Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal considerations see section 13., See Section 1 for emergency contact information., For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitisation of susceptible persons. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Advice on protection against : Normal measures for preventive fire protection. fire and explosion Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : Keep container tightly closed in a dry and well-ventilated Pfaudler GmbH 45 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 areas and containers place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in properly labelled containers. Advice on common storage : For incompatible materials please refer to Section 10 of this SDS. Storage class (TRGS 510) : 6.1C, Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects Recommended storage temperature : 2 - 40 C Further information on storage stability : Stable under normal conditions. 7.3 Specific end use(s) Specific use(s) : No data available SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components 4,4'Isopropylidenediph enol Peak-limit: excursion factor (category) Further information Further information CAS-No. 80-05-7 1;(I) Value type (Form of exposure) AGW (Inhalable fraction) Control parameters 5 mg/m3 Basis DE TRGS 900 When there is compliance with the OEL and biological tolerance values, there is no risk of harming the unborn child TWA (inhalable 2 mg/m3 2017/164/EU fraction) Indicative Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006: Substance name End Use 2,2'-iminodiethylamine Workers Exposure routes Inhalation Potential health effects Long-term systemic effects Workers Workers Workers Inhalation Inhalation Inhalation Acute systemic effects Long-term local effects Acute local effects Workers Dermal Long-term systemic effects Value 15,4 mg/m3 92,1 mg/m3 0,87 mg/m3 2,6 mg/m3 11,4 mg/kg 46 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Workers Consumers Consumers Consumers Consumers 3,6,9,12tetraazatetradecameth ylenediamine Workers Workers Workers Workers Workers Consumers Consumers Consumers Consumers Consumers Consumers Consumers 2,2'Iminodi(ethylamine) Consumers Workers Workers Workers Workers Workers Workers Dermal Inhalation Inhalation Dermal Dermal Inhalation Dermal Dermal Dermal Inhalation Dermal Inhalation Oral Dermal Dermal Inhalation Oral Dermal Inhalation Inhalation Inhalation Inhalation Dermal Dermal Long-term local effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Systemic effects, Long-term exposure Systemic effects, Long-term exposure Local effects, Longterm exposure Local effects, Longterm exposure Systemic effects, Short-term exposure Systemic effects, Long-term exposure Systemic effects, Short-term exposure Systemic effects, Short-term exposure Local effects, Shortterm exposure Systemic effects, Short-term exposure Systemic effects, Long-term exposure Systemic effects, Long-term exposure Local effects, Longterm exposure Long-term systemic effects Acute systemic effects Long-term local effects Acute local effects Long-term systemic effects Long-term local bw/day 1,1 mg/cm2 4,6 mg/m3 27,5 mg/m3 4,88 mg/kg bw/day 4,88 mg/kg bw/day 1,59 mg/m3 0,91 mg/kg bw/day 1,59 mg/cm2 0,44 mg/cm2 8550 mg/m3 4 mg/kg bw/day 2542 mg/m3 32 mg/kg bw/day 1,59 mg/cm2 13 mg/kg bw/day 0,46 mg/m3 0,65 mg/kg bw/day 0,68 mg/cm2 15,4 mg/m3 92,1 mg/m3 0,87 mg/m3 2,6 mg/m3 11,4 mg/kg bw/day 1,1 mg/cm2 Pfaudler GmbH 47 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Consumers Consumers Consumers Consumers Inhalation Inhalation Dermal Dermal effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects 4,6 mg/m3 27,5 mg/m3 4,88 mg/kg bw/day 4,88 mg/kg bw/day Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006: Substance name 2,2'-iminodiethylamine Environmental Compartment Fresh water Value 0,56 mg/l Freshwater - intermittent 0,32 mg/l Fresh water sediment 1072 mg/kg dry weight (d.w.) Marine water 0,056 mg/l Marine sediment 107,2 mg/kg dry weight (d.w.) Sewage treatment plant 6 mg/l Soil 7,97 mg/kg dry weight (d.w.) Siloxanes and silicones, di-Me, reaction products with silica Fresh water sediment > 100 mg/kg Remarks: Assessment Factors Soil 23 mg/kg Assessment Factors 3,6,9,12tetraazatetradecamethylenediami ne Fresh water Assessment Factors 2,5 g/l Marine water Assessment Factors 2,5 g/l Freshwater - intermittent Assessment Factors 25 g/l Fresh water sediment Equilibrium method 0,22 mg/kg Marine sediment Equilibrium method 0,14 mg/kg Soil Equilibrium method 0,18 mg/kg 48 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Sewage treatment plant Secondary Poisoning Assessment Factors 2,2'-Iminodi(ethylamine) Fresh water Freshwater - intermittent Fresh water sediment Marine water Marine sediment Sewage treatment plant Soil Siloxanes and Silicones, di-Me, reaction products with silica Fresh water sediment Assessment Factors Soil Assessment Factors 1,64 mg/l 0,29 mg/kg 0,56 mg/l 0,32 mg/l 1072 mg/kg dry weight (d.w.) 0,056 mg/l 107,2 mg/kg dry weight (d.w.) 6 mg/l 7,97 mg/kg dry weight (d.w.) > 100 mg/kg 23 mg/kg 8.2 Exposure controls Personal protective equipment Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Hand protection Material Break through time : butyl-rubber : >8h Material : Solvent-resistant gloves (butyl-rubber) Material Break through time : Nitrile rubber : 10 - 480 min Remarks Skin and body protection Respiratory protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : W A R N I N G ! This product contains quartz, which has Pfaudler GmbH 49 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 been classified by IARC as carcinogenic for humans (Group 1), and which can cause silicosis and lung cancer following exposure to respirable dust. It is therefore important to take particular care to avoid inhalation exposure when mechanically processing cured material (e.g. grinding, sanding, sawing). SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical state : paste Colour : black Odour : amine-like Odour Threshold : No data is available on the product itself. pH : No data is available on the product itself. Melting point/freezing point : No data is available on the product itself. Boiling point : > 200 C Flash point : > 100 C Method: Pensky-Martens closed cup, closed cup Evaporation rate : No data is available on the product itself. Flammability (solid, gas) : No data is available on the product itself. Burning rate : No data is available on the product itself. Upper explosion limit / Upper flammability limit : No data is available on the product itself. Lower explosion limit / Lower flammability limit : No data is available on the product itself. Vapour pressure : < 0,5 hPa (20 C) Relative vapour density : No data is available on the product itself. Relative density : No data is available on the product itself. Density : 1,85 g/cm3 (25 C) Solubility(ies) Water solubility : partly soluble (20 C) Solubility in other solvents : No data is available on the product itself. Partition coefficient: n- : No data is available on the product itself. 50 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 octanol/water Auto-ignition temperature : No data is available on the product itself. Decomposition temperature : > 200 C Viscosity Viscosity, dynamic : 400 000 - 600 000 mPa.s (40 C) Explosive properties : No data is available on the product itself. Oxidizing properties : No data is available on the product itself. 9.2 Other information No data available SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : No hazards to be specially mentioned. 10.4 Conditions to avoid Conditions to avoid : None known. 10.5 Incompatible materials Materials to avoid : None known. 10.6 Hazardous decomposition products Carbon oxides Nitrogen oxides (NOx) Burning produces noxious and toxic fumes. No hazardous decomposition products are known. SECTION 11: Toxicological information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Acute oral toxicity - Product : Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method Acute inhalation toxicity Product : Acute toxicity estimate : 2,65 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Pfaudler GmbH 51 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Acute dermal toxicity Product : Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method Acute toxicity (other routes of : No data available administration) Skin corrosion/irritation Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Species: human skin Assessment: May cause eye and skin irritation. Method: OECD Test Guideline 431 Result: May cause eye and skin irritation. Species: human skin Assessment: Irritant Method: OECD Test Guideline 439 Result: Irritating to skin. 2,2'-Iminodi(ethylamine): Species: Rabbit Assessment: Causes burns. Result: Causes burns. Amines, polyethylenepoly-, pentaethylenehexamine fraction: Species: Rabbit Method: OECD Test Guideline 404 Result: Corrosive after 3 minutes to 1 hour of exposure 4,4'-Isopropylidenediphenol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Serious eye damage/eye irritation Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Species: Rabbit Method: OECD Test Guideline 405 Result: Corrosive 2,2'-Iminodi(ethylamine): Species: Rabbit Assessment: Corrosive Result: Corrosive 52 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Amines, polyethylenepoly-, pentaethylenehexamine fraction: Species: Rabbit Assessment: Severe eye irritation Method: OECD Test Guideline 405 Result: Severe eye irritation Species: Rabbit Assessment: Corrosive Result: Corrosive 4,4'-Isopropylidenediphenol: Species: Rabbit Method: OECD Test Guideline 405 Result: Irreversible effects on the eye Respiratory or skin sensitisation Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: The product is a skin sensitiser, sub-category 1A. 2,2'-Iminodi(ethylamine): Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: May cause sensitisation by skin contact. Remarks: Causes sensitisation. Exposure routes: Respiratory Tract Species: Mouse Result: Does not cause respiratory sensitisation. Amines, polyethylenepoly-, pentaethylenehexamine fraction: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. 4,4'-Isopropylidenediphenol: Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: Does not cause skin sensitisation. Exposure routes: Skin Species: Humans Assessment: May cause sensitisation by skin contact. Result: Causes sensitisation. Assessment: No data available Pfaudler GmbH 53 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Germ cell mutagenicity Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Genotoxicity in vitro : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative : Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 487 Result: negative Amines, polyethylenepoly-, pentaethylenehexamine fraction: Genotoxicity in vitro : Concentration: 16.7 - 1670 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive : Concentration: .01 - 3 mg/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive : Concentration: .03 - 5 mg/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive : Concentration: .1 - 200 g/L Metabolic activation: negative Method: OECD Test Guideline 482 Result: negative : Metabolic activation: negative Method: OECD Test Guideline 482 Result: negative : Concentration: .2 - .8 mg/ml Metabolic activation: with and without metabolic activation 54 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Method: OECD Test Guideline 479 Result: positive : Concentration: .02 - 10 g/kg Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: Not classified due to inconclusive data. : Concentration: 0 - 8 mg/kg Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive : Concentration: 0 - 4 mg/kg Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: positive : Concentration: 0 - 10 mg/kg Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: positive 4,4'-Isopropylidenediphenol: Genotoxicity in vitro : Metabolic activation: with and without metabolic activation Result: negative Components: 2,2'-Iminodi(ethylamine): Genotoxicity in vivo : Cell type: Somatic Application Route: Oral Dose: 85 - 850 mg/kg Method: OECD Test Guideline 474 Result: negative Application Route: Oral Result: negative Amines, polyethylenepoly-, pentaethylenehexamine fraction: Genotoxicity in vivo : Application Route: Oral Dose: 2300 - 1400 ppm Method: OECD Test Guideline 477 Result: negative Application Route: Intraperitoneal injection Pfaudler GmbH 55 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Dose: 185 - 600 mg/kg Method: OECD Test Guideline 474 Result: negative Application Route: Intraperitoneal injection Dose: 150 mg/kg Method: OECD Test Guideline 474 Result: negative 4,4'-Isopropylidenediphenol: Genotoxicity in vivo : Method: OECD Test Guideline 474 Result: negative Germ cell mutagenicityAssessment : No data available Carcinogenicity Components: 2,2'-Iminodi(ethylamine): Species: Mouse, male Application Route: Dermal Dose: 56.3 mg/kg Frequency of Treatment: 3 daily Result: negative Amines, polyethylenepoly-, pentaethylenehexamine fraction: Species: Mouse, male Application Route: Dermal Exposure time: 104 weeks Dose: ca 16.8 mg/kg Frequency of Treatment: 3 daily Method: OECD Test Guideline 451 Result: positive Species: Mouse, male Application Route: Dermal Exposure time: 24 month(s) Dose: 1.25 mg/kg Frequency of Treatment: 3 daily Method: OECD Test Guideline 451 Result: negative 4,4'-Isopropylidenediphenol: Species: Rat, male and female Application Route: Oral Exposure time: 103 weeks Frequency of Treatment: 7 daily Result: negative Carcinogenicity Assessment : No data available 56 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Annex 1 UF3000 Safety data sheet Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Reproductive toxicity Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Effects on fertility : Species: Rat, male and female Application Route: Oral Method: OECD Test Guideline 422 Result: Animal testing did not show any effects on fertility. 2,2'-Iminodi(ethylamine): Species: Rat, male and female Application Route: Oral General Toxicity - Parent: No observed adverse effect level: 30 mg/kg wet weight Method: OECD Test Guideline 421 4,4'-Isopropylidenediphenol: Species: Rat, male and female Application Route: Oral Method: OECD Test Guideline 416 Result: Embryotoxic effects and adverse effects on the offspring were detected. Components: 2,2'-Iminodi(ethylamine): Effects on foetal development 4,4'-Isopropylidenediphenol: : Species: Rat Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 100 mg/kg body weight Method: OECD Test Guideline 421 Result: No adverse effects Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: < 160 mg/kg body weight Method: OECD Test Guideline 416 Result: No teratogenic effects Components: 4,4'-Isopropylidenediphenol: Reproductive toxicity Assessment : Clear evidence of adverse effects on sexual function and fertility, based on animal experiments. STOT - single exposure Components: 2,2'-Iminodi(ethylamine): Target Organs: Respiratory Tract Pfaudler GmbH 57 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Assessment: May cause respiratory irritation. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 4,4'-Isopropylidenediphenol: Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation. STOT - repeated exposure No data available Repeated dose toxicity Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Species: Rat, male and female NOAEL: 1000 mg/kg Application Route: Ingestion Exposure time: 6 WeeksNumber of exposures: 7 d Method: Subacute toxicity 2,2'-Iminodi(ethylamine): Species: Rat, male and female NOEC: 70 - 80 Application Route: Ingestion Test atmosphere: vapour Exposure time: 360 hNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male and female NOAEL: 114 Application Route: Skin contact Exposure time: 9 600 hNumber of exposures: 6 d Method: Chronic toxicity Amines, polyethylenepoly-, pentaethylenehexamine fraction: Species: Rat, female NOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 26 WeeksNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male LOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 26 WeeksNumber of exposures: 7 d Method: Subchronic toxicity 4,4'-Isopropylidenediphenol: Species: Dog, male and female NOEC: 75 mg/kg, 10 Application Route: Ingestion 58 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Test atmosphere: dust/mist Exposure time: 2 160 hNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male and female LOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 672 hNumber of exposures: 7 d Method: Subchronic toxicity Repeated dose toxicity Assessment : No data available Aspiration toxicity No data available 11.2 Information on other hazards Endocrine disrupting properties Product: Assessment : This substance/mixture contains components considered to have endocrine disrupting properties affecting human health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Experience with human exposure General Information: No data available Inhalation: No data available Skin contact: No data available Eye contact: No data available Ingestion: No data available Toxicology, Metabolism, Distribution No data available Neurological effects No data available Pfaudler GmbH 59 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Further information Ingestion: No data available SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 SECTION 12: Ecological information 12.1 Toxicity Components: Reaction products of fatty acid dimers and trimers, C18 (unsaturated) alkyl and fatty acids, C18 (unsaturated) alkyl with amines, polyethylenepoly-, triethylenetetramine fraction : Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): 7,07 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 5,18 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EC50 (Selenastrum capricornutum (green algae)): 2,43 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201 Toxicity to microorganisms : EC50 (activated sludge): 421 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 209 2,2'-Iminodi(ethylamine): Toxicity to fish : LC50 : 430 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 64,6 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: Regulation (EC) No. 440/2008, Annex, C.2 EC50 (Daphnia magna (Water flea)): 16 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water 60 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Method: DIN 38412 Toxicity to algae/aquatic plants : EbC50 (Selenastrum capricornutum (green algae)): 1 164 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOEC: 10 mg/l Exposure time: 28 d Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 210 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 5,6 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.20 Toxicity to soil dwelling organisms : EC50: > 1 000 mg/kg Exposure time: 56 d Species: Eisenia fetida (earthworms) Method: OECD Test Guideline 222 Ecotoxicology Assessment Acute aquatic toxicity : This product has no known ecotoxicological effects. Amines, polyethylenepoly-, pentaethylenehexamine fraction: Toxicity to fish : LC50 (Poecilia reticulata (guppy)): .18 g/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 17,5 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.2. Toxicity to algae/aquatic plants : EbC50 (Selenastrum capricornutum (green algae)): 0,7 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201 ErC50 (Selenastrum capricornutum (green algae)): 1,7 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201 Pfaudler GmbH 61 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 M-Factor (Acute aquatic : 1 toxicity) Toxicity to microorganisms : EC50 (No information available.): 1 600 mg/l Exposure time: 0,5 h Test Type: static test Test substance: Fresh water EC50 (No information available.): 164 mg/l Exposure time: 2 h Test Type: static test Test substance: Fresh water Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : EC10: 1,9 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 202 M-Factor (Chronic aquatic toxicity) 4,4'-Isopropylidenediphenol: Toxicity to fish : 1 : LC50 (Oncorhynchus mykiss (rainbow trout)): 7,5 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 : 3,9 - 10,2 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic plants (Ceriodaphnia dubia (Water flea)): : EC50 (Selenastrum capricornutum (green algae)): 2,5 - 3,1 mg/l Exposure time: 96 h Toxicity to fish (Chronic toxicity) : NOEC: 0,016 mg/l Exposure time: 444 d Species: Pimephales promelas (fathead minnow) Test Type: flow-through test Test substance: Fresh water Method: Fish Life Cycle Toxicity Remarks: Toxic to aquatic organisms. M-Factor (Chronic aquatic toxicity) Ecotoxicology Assessment Chronic aquatic toxicity : 1 : Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability Components: 2,2'-Iminodi(ethylamine): Biodegradability : Inoculum: activated sludge Result: Readily biodegradable. Biodegradation: 87 % 62 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Exposure time: 21 d Method: OECD Test Guideline 301D Photodegradation : Test Type: Air Rate constant: 500000 Degradation (direct photolysis): 50 % Amines, polyethylenepoly-, pentaethylenehexamine fraction: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 162 d Method: OECD Test Guideline 301D 4,4'-Isopropylidenediphenol: Biodegradability : Result: Not readily biodegradable. Biodegradation: 1 - 2 % Exposure time: 28 d 12.3 Bioaccumulative potential Components: 2,2'-Iminodi(ethylamine): Bioaccumulation : Species: Cyprinus carpio (Carp) Exposure time: 42 d Bioconcentration factor (BCF): 0,3 - 6,3 Test substance: Fresh water Method: flow-through test Remarks: Bioaccumulation is unlikely. Partition coefficient: noctanol/water : log Pow: -1,58 (20 C) pH: 7 Amines, polyethylenepoly-, pentaethylenehexamine fraction: Partition coefficient: n- : log Pow: -3,67 octanol/water 12.4 Mobility in soil Components: 2,2'-Iminodi(ethylamine): Distribution among environmental compartments : Koc: 19111 12.5 Results of PBT and vPvB assessment Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.. 12.6 Endocrine disrupting properties Product: Assessment : This substance/mixture contains components considered to have endocrine disrupting properties for environment , Pfaudler GmbH 63 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. 12.7 Other adverse effects Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long lasting effects. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of contents/ container to an approved waste disposal plant. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information IATA 14.1 UN number or ID number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) : UN 2735 : Amines, liquid, corrosive, n.o.s. (DIETHYLENETRIAMINE, PENTAETHYLENE HEXAMINE) : 8 : II : Corrosive : 855 : 851 IMDG 14.1 UN number or ID number 14.2 UN proper shipping name : UN 2735 : AMINES, LIQUID, CORROSIVE, N.O.S. 64 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 (DIETHYLENETRIAMINE, PENTAETHYLENE HEXAMINE) 14.3 Transport hazard : 8 class(es) 14.4 Packing group : II Labels : 8 EmS Code : F-A, S-B 14.5 Environmental hazards Marine pollutant : yes ADR 14.1 UN number or ID : UN 2735 number 14.2 UN proper shipping : AMINES, LIQUID, CORROSIVE, N.O.S. name (DIETHYLENETRIAMINE, PENTAETHYLENE HEXAMINE) 14.3 Transport hazard : 8 class(es) 14.4 Packing group : II Labels : 8 14.5 Environmental hazards Environmentally hazardous : yes RID 14.1 UN number or ID : UN 2735 number 14.2 UN proper shipping : AMINES, LIQUID, CORROSIVE, N.O.S. name (DIETHYLENETRIAMINE, PENTAETHYLENE HEXAMINE) 14.3 Transport hazard : 8 class(es) 14.4 Packing group : II Labels : 8 14.5 Environmental hazards Environmentally hazardous : no 14.7 Maritime transport in bulk according to IMO instruments Not applicable for product as supplied. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACH - List of substances subject to authorisation (Annex XIV) : Not applicable REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : bisphenol A Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. E2 ENVIRONMENTAL HAZARDS Pfaudler GmbH 65 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Water contaminating class (Germany) : WGK 3 highly hazardous to water Classification according to AwSV, Annex 1 (5.2) TA Luft List (Germany) : Total dust: Not applicable : Inorganic substances in powdered form: Not applicable : Inorganic substances in vapour or gaseous form: Not applicable : Organic Substances: portionClass 1: 6,97 % : Carcinogenic substances: Not applicable : Mutagenic: Not applicable : Toxic to reproduction: Not applicable Other regulations: The product is subject to the supply restrictions of the Ordinance on the Prohibition of Chemicals. Take note of Law on the protection of mothers at work, in education and in studies (Maternity Protection Act - MuSchG). Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable. The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AIIC : On the inventory, or in compliance with the inventory NZIoC : Not in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory 66 Pfaudler GmbH SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Annex 1 UF3000 Safety data sheet Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 TSCA : All substances listed as active on the TSCA inventory Inventories AICS (Australia), AIIC (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (United States of America (USA)) 15.2 Chemical safety assessment Chemical Safety Assessments for all substances in this product are either Complete or Not applicable. SECTION 16: Other information Full text of H-Statements H302 H312 H314 H315 H317 H318 H330 H335 H360F H400 H410 H411 : Harmful if swallowed. : Harmful in contact with skin. : Causes severe skin burns and eye damage. : Causes skin irritation. : May cause an allergic skin reaction. : Causes serious eye damage. : Fatal if inhaled. : May cause respiratory irritation. : May damage fertility. : Very toxic to aquatic life. : Very toxic to aquatic life with long lasting effects. : Toxic to aquatic life with long lasting effects. Full text of other abbreviations Acute Tox. : Aquatic Acute : Aquatic Chronic : Eye Dam. : Repr. : Skin Corr. : Skin Irrit. : Skin Sens. : STOT SE : 2017/164/EU : DE TRGS 900 : 2017/164/EU / TWA : DE TRGS 900 / AGW : Acute toxicity Short-term (acute) aquatic hazard Chronic aquatic toxicity Serious eye damage Reproductive toxicity Skin corrosion Skin irritation Skin sensitisation Specific target organ toxicity - single exposure Europe. Commission Directive 2017/164/EU establishing a fourth list of indicative occupational exposure limit values Germany. TRGS 900 - Occupational exposure limit values. Limit Value - eight hours Time Weighted Average Further information Classification of the mixture: Classification procedure: Acute Tox. 4 H332 Calculation method Skin Corr. 1B H314 Calculation method Eye Dam. 1 H318 Calculation method Pfaudler GmbH 67 Annex 1 UF3000 Safety data sheet PFAUDLER UF 3000 B Version 1.3 Revision Date: 18.03.2021 SDS Number: 400001009288 Skin Sens. 1 Repr. 1B Aquatic Chronic 2 H317 H360F H411 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Date of last issue: 03.02.2020 Date of first issue: 20.05.2015 Print Date 29.06.2021 Calculation method Calculation method Calculation method The information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users. The trademarks above are the property of Huntsman Corporation or an affiliate thereof. NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. 68 Pfaudler GmbH Annex 2 Certificate of conformity with TA Luft (Clean Air Act) Pfaudler GmbH 69 Annex 3 Certificate of conformity with TA Luft (Clean Air Act) 70 Pfaudler GmbH Annex 4 Certificate of conformity FDA Title 21 177.1550 r GMM Pfaudler Declaration of compliance with the order EN 10204 - 2.1 We herewith confirm that gasket envelopes in contact with the product are made of virginal PTFE. The asbestos free gaskets: Pfaudler AF3000/ GR3000 Gasket Types WT, WKT, WKTV, WTR and WKTG meet the requirements of the US Food and Drug Administration (FDA). They can be used in applications where the material is in contact with food. FDA Title 21 177.1550 Pfaudler GmbH pp . Michael Theilig Technical Manager Waghausel, 14.06.2022 HB009E i.V. Thorsten Ham~bsch Quality Manager Pfaudler GmbH Louis-Schuler-StraRe 1 68753 Waghausel, Deutschland T: +49 (0) 7254 9212-0 I E: @pfaudler.com I W: www.gmmpfaudler.com PFAUDLER Glass-Llned Technology NORMAG Lob & Process Gig.. MAVAG Filtration & Drying MIXION Mixing Technology INTERSEAL EQUILLOY . Equipment EDLON me Flooropolyrners Pfaudler GmbH 71 The information provided in this documentation corresponds to the state of the art at the time of printing. It is published in good faith. However, we will accept no warranty claims based on the information provided in this documentation. We reserve the right to include improvements, amendments and new findings in this documentation without prior notice. The actual design of products may deviate from the information contained in the calatoge if technical alterations and product improvements so require. The proposal made by Pfaudler for a concrete application will be binding in such cases. The present documentation is made available free of charge to our customers and other interested parties. The right to print or copy this documentation, or any parts thereof, or to convert the same into electronic form shall be subject to our written permission. All rights reserved by us. Pfaudler GmbH Louis-Schuler-Strae 1 68753 Waghusel, Germany Phone: +49 (0) 7254 9212-0 www.gmmpfaudler.com