Document NXENYp0RnGJZZ5OQGwKJ7qEV

Wacker Chemicals (USA), Inc. 50 Locust Avenue New Canaan. CT 06840 Phone (?03) 966 9999 TWX 643 444 FAX 203 972 0041 August 13, 1990 Mr. Merv Baldwin Conoco, Inc. P.O. Box 37 Westlake, LA 70669 Re: Updated Material Safety Data Sheet fMsnfi) Product: Dibutyl ether Dear Mr. Baldwin: Enclosed please find our updated Material Safety Data Sheet (MSDS) for the above mentioned product. We ask that you study this MSDS to become aware of any product hazards and to provide this information to all personnel who are involved with our product. Your outdated MSDS should be destroyed. Thank you for your continued interest in Wacker products. If you have any questions regarding health, safety or handling issues of our products, please do not hesitate to contact us at any time. SLJ/cac end. cc: Alex Patel Houston, TX Organic Intermediates sal 009678 MATERIAL SAFETY DATA SHEET DURA-GAUD AEROSOL RASE : 01 (006339*0157P -E0021638-S014 )|OATE OF ISSUE J 1 a/13/89 j SUREPSEOe ! 09/01/8 SECTION 1 - GENERAL INFORMATION CHEMICAL NAME ft SYNONYMS N/A TRADE NAME ft SYNONYMS OURA'GARD AEROSOL CHEMICAL FAMILY AEROSOL WAX/SOLVENT FORMULA X <'-MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP. ADDRESS (NUMBER. STREET. CITY. STATE ft ZIP CODE) BOX 1S2170 IRVING. TEXAS 75015 PREPARED ev; KEVIN UHL/T.S. CHEMIST I PRODUCT CODE NUMBER || EMERGENCY TELEPHONE NUMBER 5014 2 14-436-130 t SECTION II' HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) | HAZARD ALIPHATIC PETROLEUM DISTILLATE combust. | TLV* lOOPPM 1 ISOPROPANOL MORPHOLINE FLAM. FLAM. 400PPM 20PPM - SEE SECTION XIII PROPANE JSOBUTANE ASPHYXIANT FLAMM. N/E N/E | PEL- i CAS* 375MG/M3 1 64742-88-7 4O0PpM 20PPM 67-63-0 110-91-8 1000PPM N/E 74-98-6 75-28-5 DURA-CARD ASRCSOL SECTION IIA - N0N-HA2ARD0US INGREDIENTS PAGE : 02 NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY * 409363-5030P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) j320 f . i SPEC GRAVITY (H20-1) :0.8? VAPOR PRESSURE (MM HG). !1 o VAPOR DENSITY (AIR-1) i6.o 1 COLOR ! ODOR TAN SOLVENT ODOR PH * 100% J9 I CLARITY TRANSPARENT PERCENT. VOLATILE BY VOLUME <*) SOLUBILITY IN WATER Jso I i EVAPORATION RATE 1 (BU AC - 1 ) ! NEGLIGIBLE lO.OB \ VISCOSITY i NON-VISCOUS SECTION IV FIRE AND EXPLOSION HAZARD FLASH POINT (METHOO no f. c.o.e. EXTINGUISHING MEDIA X<-- FOAM USED ) ALCOHOL * <- -FCAM j FLAMMABLE LIMITS 1 XC--CC2 DRY X<-CHEMICAL l!n/, a LE1WATER X<--$PRAY 1 , UEL *n/a <--OTHER SPECIAL FIRE FIGHTING PROCEDURES EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL- WEAR PROPER PROTECTIVE CLOTHING INCLUDING A MCSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE-EXPOSED CONTAINERS WITH WATER. UNUSUAL FIRE ft EXPLOSION HAZARDS VAPORS ARE HEAVIER THAN AIR AND MAY ACCUMULATE IN LOW AREAS OR AREAS INADEQUATELY VENTtLATEO. VAPORS MAY ALSO TRAVEL ALONG THE GROUND TO BE IGNITED AT LOCATIONS DISTANT FROM THE HANDLING SITE. LEVEL 3 AEROSOL <NFPA 306) NFPA HAZARD RATING ( O-1 NS1GNIFI CANT; 1-SLIGHT;2-MOOERATE;3-HIGH;4-EXTREME): 2 ^--HEALTH 2 <--f LAMMABILITY O <--REAtTIVITV <--SPe6lAL sal 000009679 G S 1 58 PURA-GARD AEROSOL SECTION V - HEALTH HAZARD DATA PAGE : 03 THRESHOLD LIMIT value : NOT established FOR MIXTURE. SEE SECTION 11 . EFFECTS OF OVEREXPOSURE - ACUTE - {SHORT TERM EXPOSURE) CAN LEAD TO CENTRAL NERVOUS SYSTEM DEPRESSION WITH EFFECTS OF HEAOACHE. DIZZINESS, NAUSEA, AND LOSS OF CONSCIOUSNESS. EVE IRftITANT,OEFATS SKIN WHICH CAN LEAD TO IRRITATION. INHALATION MAY BE SLIGHTLY IRRITATING TO MUCOUS MEMBRANE. INGESTION MAY RESULT IN VOMITING. ASPIRATION MUST BE AVOIDED TO AVOID PNEUMONITIS. CHRONIC - (LONG TERM EXPOSURE) MARKED IRRITATION OF SKIN AND EYE UPON CHRONIC OVEREXPOSURE AS WELL AS LIVER AND KI ONEY DAMAGE TARGET ORGANS: LIVER AND KIDNEY. PRIMARY ROUTE OF ENTRY: X<-- INHALATION INGESTION X<-- ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION : REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH WATER FOR IS MINUTES WHILE HOLDING EYELIDS OPEN. ATTENTION. GET MEDICAL SKIN CONTACT; WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING ANO SHOES: DO MOT REUSE UNTIL CLEANEO. IF PERSI5TENT IRRITATION OCCURS. GET MEDICAL ATTENTION. INGESTION : 00 NOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY. KEEP HEAO 8EL0W HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS- GET MEOICAL ATTENTION M/A NOTES TO PHYSICIAN SECTION VI * TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTEO AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: 1ARC <--YES NTP X<--NO <--YES OSHA X<-"NO <-*YES ACGIH X<--NO <--YS OTHER X<--NO <--YES X<--NO MORPHOLINE LDSO-RAT 105OMG/KG 2. JHL-RAT 12.0OOPPM/8HR 2. ALIPHATIC PETROLEUM DISTILLATE (CONTINUED) SECTION VI DURA-SARD AEROSOL TOXICITY INFORMATION PAGE UNK-MAN LDLO: 1176MG/KG 2. ORL-RAT LDSO: 28 G/KG 2. ORL-RBT LDSO: 28 G/KG 2. THIS INGREDIENT MAY CONTAIN CONTAMINANTS WHICH ARE LISTEO BY CALIFORNIA PROPOSITION 65 AS CARCINOGENS. ISOPROPANCl ORL-MAS: LDLO &600MG/KG 2. IHL-HMN: TCLO AOOPPM 2. EYE-HMN 20 PPM 2. ORL-HMN TDLO 16,710 MG/KG CNS 2. SECTION VII - REACTIVITY DATA OA STABILITY |X< -- STABLE t' N/A <--UN$TABL | CONDITIONS TO AV010 ` -- INCOMPATIBILITY (MATERIALS TO AVOID) OPEN FLAME. STRONG OXIDIZERS HAZARDOUS DECOMPOSITION PROOUCTS CARBON MONOXIDE AND OXIDES OF NITROGEN POSSIBLE HAZARDOUS WILL NOT X < - -OCCUR MAY <--OCCUR CONDITIONS TO AVOIO POLYMERIZAT I ON N/A SECTION VII] SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASEO OR SPILLED ELIMINATE ALL SOURCES OF IGNITION. TAKE UP WITH ABSDRBANT AND PLACE IN LABELED CONTAINER FCR DISPOSAL. DO NOT FLUSH TO 5EWER. WASTE 01SP0SAL METHOO PLACE IN A OISPOSAL FACILITY APPROVEO UNDER RCRA REGULATIONS FOR HAZARDOUS WASTE USE NON-LEAKING CONTAINERS. SEAL TIGHTLY AND LABEL PROPERLY. NEUTRALIZING AGENT N/A $AL 000>6a0 OUR*-BAHD AEROSOL SECTION IX - SPECIAL PROTECTION INFORMATIOPAQE : OS REQUIRED VENTILATION GENERAL EXHAUST IS ADEQUATE UNDER NORMAL CIRCUMSTANCES. RESPIRATORY PROTECTION TYPICAL USE DOES NOT REOUIRED RESPIRATORS- HOWEVER. IN EMERGENCY SITUATIONS WHERE EXPOSURE EXCEEDS OSHA'S STANDARDS: 50QPPM/SAF/SCBAF PROTECTIVE GLOVES PVA GLOVES OR EQUIVALENT IF REPEATED OR PROLONGED EXPSOURE OCCURS. EYE PROTECTION CHEMICAL GOGGLES SHOULD BE WORN DEPENDING UPON SEVERITY of exposure OTHER PROTECTION N/A GS 1 58 SECTION X - STORAGE AND HANOLING INFORMATION STORAGE TEMPERATURE [ INDOOR 120 F. <--MAX 32 F.<--MIN [ X [HEATED ! PRECAUTIONS TO BE TAKEN IN HANDLING A STORING STORE AT MODERATE TEMPERATURES. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILOREN. READ ENTIRE LABEL BEFORE USING. [REFRIGERATED! OUTDOOR ] |x SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C . A.S NUMBER UPPER X LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING RECUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND RE AUTHOR IZAT 1 ON ACT CF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEA85 UNDER UPPER X LIMIT. ENO USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PROOUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED ANO LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH A$ FERTILIZERS ANO HERBICIDES). OR THE PROOUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. DURA-GARD AEROSOL SECTION XIX - TRANSPORTATION (FOR FUTURE USE) PAGE : 06 APPLICABLE REGULATIONS <--49 CFR <-- IMCO SHIPPING NAME HAZARD*CLASS..................... " LABELS UNIT CONTAINER DOT SPS CONTAINER AEROSOL PROPELLANT{S) <--TARlFF 6 O <--IATA C--MILITARY AIR (AFR 71-4) ' I ID NUMBER J REPORT QTY [ LIMITED QTY [ NET EXPLOSIVE WT. SECTION XIII - REFERENCES 1. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2ND EDITION. ACGIH, 1985. 2. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. INGREDIENT PERCENTAGE IS A TRADE SECRET; MASS. TRADE SECRET NUMBER THE INFORMATION CONTAINED HEREIN IS BASED CN DATA CONSIDERED ACCURATE IN LIGHT CF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OP IMPLIED REGARDING THE ACCURACY CF THIS DATA OR THE RESULTS TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH COR*. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDEO USE, STORAGE. OR DISPOSAL OF THE PRODUCT. SAL 000009681