Document NQzXbede6YYLO2XJGDz2wL6D
STLS F. V F, R N TRENT
STL Chicago 2417 Bond Street University Park, IL 60456
Tel: 70S 534 5200 Fax: 70S 534 5211 www.stl-inc.com
SEVERN T T LABORATORIES ANALYTICAL REPORT
JOB NUMBER : .232881
prepared Fcr;
weston Solutions, inc 140 Weston Way B u i l d i n g 5-2.
West C h e s t e r , PA 193 80-14.99
Projcot :Confidential D e c a t u r PC I n v e s t 1g ation
Atte n t i o n : Jai Kesari
Date; 13/30/2004
Signature Name ; Ri chaif C . itfright Title: Project Manager E-Mail: rwright@sti-inc.com
This Report Contains
Icoders in Environmental Testing
STL Chicago 2417 Bond Street University Park, IL 60466
PHONE : (708) 534-5200 FAX. , ; (708) 534-5211..
) Pages
Severn Trent Lahnratnries, Inc.
WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION
JOB# 232881
Data Summary................................................................1 Chain of Custody..........................................................15 Case Narrative............................................................. 20 Raw Data...................................................................... 22
STL Chicago is part of Severn Trent Laboratories, Inc.
s A M RLE INFO R M A T I0 N ...... nsfa-
Job Number. 232801 Customer... Weston Solutions, Inc. Attn...... Jai Kesari
Project Number........ : 20004891
Customer Project ID___ : CONFIDENTIAL DECATUR Project Description.... : Confidential Decatur - FC Investigation
Laboratory Sample ID
Customer sample id
232881-1
DF14-SB-137R--005
232881-2
DF14-SBC-137R-0-0000
232881-3
DF14-SBC-137R-0-0050
232881-4
DF14-8EC-137R-0-CH00
232881-5
DF14-SBC-137R-0-0150
232881-6
DF14-SB-137R-0-0180
232881-7
DF14-S8-136R-0-0050
232881-8
DF14-SB-136R-0-0290
' Sample Matrix
Soil Soi l soi 1 soi 1 soi 1 Sai 1 Soil Soi 1
"''"Date Sarip-led;.
12/15/2004 12/15/2004 12/15/2004 12/15/2004 12/15/2004 12/15/2004 12/15/2004 12/15/2004
Time
.Date
. ..Time
Samp ted.' Received . ,.; Received1
09:05
12/17/2004
10:00
09:00
12/17/2004
10:00
09:15
12/17/2004
10:00
09:30
12/17/2004
10:00
09:45
12/17/2004
10:00
09:50
12/17/2004
10:00
15:05
12/17/2004
10:00
16:30
12/17/2004
10:00
Page 1
r* - 1
STL Chicago is part of Severn Trent Laboratori es, [ne.
a j Job Nimber: 232S81 \ i ..........------ ------------------------------J CUSTOMER: Weston Solutions, Inc. .
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
DF14-SB-137R-0-005 12/15/2004 09:05
Soil
TEST HETHCC :
PARAMETER/ T S.T DESCRIPt [ON
Method
% Solids Determination % Sol ids, Solid % Moisture, Solid
Lloyd Kahn
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
N
LABORATORY
TEST
RESULTS
PROJECT:' CONFIDENTIAL DECATUR '
Laboratory Sample ID: 232881-1 Date Received....... : 12/17/2004 Time Received....... : 10:00
Date:12/30/2004 ATTM: Jai Kesari
SAMPLE RESULT 0 FLAGS
80.9 19.1
1500
-m o l -
0.10 0.10
93
RL DItUfION UNITS ' BATCH DT OATE/TiME TECH
0.10 0.10
'1 h
13B07 13S007
12/27/04 1232 da j 12/27/04 1232 da j
360 mg/Kg 13ST54 [12/28/04 1023 els
n Description = Dry Wgt.
Page 2
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Nuidber: 232BB1
CUSTOMER: Weston Solutions, Irte. .:
Customer Sample ID: D F14 -SB C-137R-0-0000 Date Sampled..... : 12/15/20G4 Time Sampled..... : 09:00 Sample Matrix.... : So; l
TEST METHOD Method
Lloyd Kahn
PAEAKETER/TEST PESERIPTIOIt
% Solida Determi nation % Solida, Solid % Moiature, Solid
Total Organic Carbon (Soils) TOC Average PupLicates, SoLid
n
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL &ECATUR:! !
Laboratory Sample ID: 2328B1-2 Date Received...... : 12/17/2004 Time Received...... : 10:00
Date:12/30/2004 ATTN: Jai (Cesari
-
SAMPLE RESULT : FLAGS
82.1 17.9
2900
MOL 96
oo
'. r i
0.10 0.10
DILUTION
1 1
UNITS BATCH DT DATE/TIME :TECH
1 % 138007 12/27/04 1236 daj % 13B007 !12/27/04 1236 daj
370 1
mg/Kg 13B154
12/28/04 1055 c La
i i________________
* ln DescriPt ion = Dry Ugt.
1
Page 3
____ i
STL Chicago is part of Severn Trent Laboratories, [no.
Job Humber: 232831
CUSTOMER-: Weston:Solutions , Inc.
.
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
0 F14-SEC-13 7R-0-005 0 12/15/2004 09:15
Soi l
TEST METHOD.
:PARAMEfE R/EST DESCRIPTtOH
Method
% Solids Determination % Solids, Sol id
Moisture, Solid
Lloyd Jtahn
Total Organic Carbon CSoils> TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJECT: CONFEDERI AL DECATUR
.
Laboratory Sample ID 232B1-3 Date Received...... 12/17/2004 Time Received...... 10:00
D a t e : 12/30/2004 ATTN: Jai Ke.sar.i
SAMPLE RESULT Q ECAG5
79.4 20.6
1600
MDL
0.10 0.10
97
RL DILUTION UNITS T BATCH DT DATE/TIME TECH
0.10 0.10
138007 133007
12/27/04 1239 daj 12/27/04 1239 da j
330
mg/Kg 133154
.12/23/04 1106 c la
* [n Description = Dry Wgt.
Page 4
STL Chicago is part of Severn Trent Laboratories, ine.
1/5
* In Description = Dry Wgt.
Page 5
STL Chicago is part of Severn Trent Laboratories, Inc.
j
i Job Number: 232881
| CUSTOMER: Weston SoLutions,. Inc.
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
D F14-SE C-137R-0-D150 12/15/2004 09:45 Sal l
TEST/METHOD'
PARAMETER/TEST ;DESCR1PT1OH
Method
7 Solids Determination % Solids, Solid
% Moisture, Solid
Lloyd Kahn
Total Organic Carbon CSoiLs) TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
'PROJECT : CONFIDENT TAL DECATUR
'' '
Laboratory Sample ID 232881-5 Date Received...... 12/17/2004 Time Received...... 10:00
Date:12/30/2004 ATTN :. .Jai [Cesari
:
SAMPLE1RESULT! 0 [FLAGS
71.5 28.5
1500
MOL:
0.10 0.10
92
Rb DILUTION UNITS: :BATCH. DT DATE/TIME TECH
0.10 0.10
M :i
138007 138007
12/27/04 1243 da j 12/27/04 1243 daj
360
mg/Kg 138154
12/28/04 1204 els
* In Description = Dry Ugt.
Page 6
STL Chicago is part of Severn Trent Laboratories, Inc.
j Job Number: 232881
; CUSTOMER':- Wes t'on So lut ions P tnc.
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
DF14-SB-137ft-0-0180 12/15/2004 09:50 Soi L
TEST METHOD-
PARAMETE R/TEST :E ESCRIPTION
Method
% Solids Determination % Solids, Solid
l% Moisture, Sol id
f Lloyd Kahn iTotal Organic Carbon (Soils) :TOC Average Duplicates, Solid
>
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR.
Laboratory Sample ID 232881- Date Received...... 12/17/2004 Time Received...... 10:00
Date:12/30/2004 ATTN:.- Jai Jiesari
SAMPLE RESULT
TLAGS.
73.8 26.2
1400
L
0.10 0.10
94
RL DILUTION wars BATCH DT DATE/TIME TECH !
0.10 0.10
138007 138007
12/27/04 1245 daj 12/27/04 1245 da j
370
mg/Kg ^133154
"12/28/04 1220 els
* In Description = Dry Ugt.
Page 7
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232881
CUSTOMER::Weston Solutions , Inc.
Customer Sample ID: D F14-SB-13*R-0-0050 Date Sampled..... : 12/15/2004 Time Sampled..... : 15:05 Samp Le Matrix.... : Soi L
TEST METHOD Method
Lloyd Kahn
PARAHETER/TEST DESCRIPTION
% Solids Determination % Solids, Sol id % Moisture, Solid
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
00
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR '
Laboratory Sample ID: 232881-7 Date Received...... : 12/17/2004 Time Received...... : 10:00
Date:12/30/2004 ATTN:- Ji Ksari
: SAMPLE-RESULT pi FLAGS
84.2 15.8
] l
3600
MOL
0.1D 0.10
96
..R L .
DILUTION UNITS BATCH DT DATE/TIME TECH
0.10 0.10
h .1
%
138007
12/27/04 1247 daj
% t138007 12/27/04 1247 daj
370 1
mg/Kg 136154
12/28/04 1240 els
* In Description = Dry Wgt.
Page S
i
STL Chicago is part of Severn Trent Laboratories, Inc.
* In Description = Dry Ugt.
Page 9
STL Chicago is part of Severn Trent Laboratories, lncr
Job Number: 232881
LABORATORY
CHRONICLE
Date: 12/30/2004
CUSTOMER: Weston !Solutions, Inc.
Lab ID: 232881-1 METHOD
Method
EDD Lloyd Kahn
Client ID: DF14-SB-137R-0-0050 DESCRIPTION % Solids Determination Electronic Data Deliverable Total Organic Carbon (Soils)
Lab ID: 232881-2 METHOD
Method Lloyd Kahh
Client ID: DF14-SBC-137R-0-000 DESCRIPTION % Solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-3 METHOD
Method Lloyd Kahn
Client ID: DF14-SBC-137R--0050
DESCRIPTION % Solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-4 METHOD
Method Lloyd Kahn
Client ID: DF14-5BC-137R-0-0100 DESCRIPTION
% Solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-5 METHOD
Method
Lloyd Kahn
Client ID: DF14-SBC-137R-0-0150
DESCRIPTION Y, Solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-6 METHOD
Method Lloyd Kahn
Client ID: DF14-SB-137R-0-0180 DESCRIPTION % Solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-7 METHOD
Method Lloyd Kahn
Client ID: DF14-SE-136R--05Q DESCRIPTION % solids Determination Total Organic Carbon (Soils)
Lab ID: 232881-8 METHOD
Method Lloyd Kahn
Client ID: DF14-SB-136R-0-0290 DESCRIPTION % So Lids Determination Total Organic Carbon (Soils)
PROJECT' CONFIDENTIAL DECATUR
;;ATTN:- Jai Kesari
Date Reevd; 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #($)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1232
1
1 138154 138154
12/28/2004 1023
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #(5>
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1236
1 138154 138154
12/28/2004 1055
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #<S)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1239
1 138154 138154
12/28/2004 1106
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1241
1 138154 138154
12/28/2004 1136
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #<S)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1243
1 138154 138154
12/28/2004 1204
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #CS)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1245
1 138154 138154
12/28/2004 1220
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1247
1 138154 138154
12/28/2004 1240
DILUTION
Date Reevd: 12/17/2004 Sample Date: 12/15/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 138007 138007
12/27/2004 1249
1 138154 138154
12/28/2004 1254
DILUTION
Page 10
10
Job Number.: 232881 CUSTOMER-: W.eston Solutions, Inc.
QUALITY C0 N T R 0 L RESULTS PROJECT: CONFIDENTIAL DECATUR
Report Date.: 12/30/2004 ATTN: Jai Kesari ................
1,,,1-I l!l\v lFLvUa
M
Batch... .
v nann?
.Method Dcscription !% 'Sol ids 'D etermi nation ..' '
......... Equipment Code;!. :
Parameter......... :'% Moisture......................
:daj Test Code. : jSMOl ST
OC Lab ID MT 32331-1
Reagent
Units %
QC Result 18.90000
QC Result True Value
.... 19,10000
7
Orig. Value R 5.0
QC Calc. F * Limits
Date Time 12/27/2004 1234
Test'-Method....... : Method '..... ............
Method Desc ription.: % Sol ids Determinst ion
Parameter......... : % Solids
....
Batch-.::......... ; 13807 .
Equipment Code....:
..... .....
Analyst... daj Test Code. KSOLI0 .
QC Lab ID
Reagent
MB 138007-001 MO 232881-1
Units
% %
QC Result
QC Result
0.1000 U 81.10000
True Value
Orig. Value 30.90000
QC Calc. F * Limits 0.2 R 5.0
Date Time
12/27/2004 1230 12/27/2004 1234
\ Test Method......... : .Lloyd Kahn
.. .
.Method Desc ription. : Total Organic Carbon CSoils)
Parameter......... : Organic Carbon, Tot.<T0C)
QC Lab ID
Reagent
Uni ts
ICV 138154-002 I4LSTTC2 MB 138154-003
LCS 138154-004 IOOFSTLK3 LCD 138154-005 I00FSTLK3
mg/Kg mg/Kg mg/Kg mg/Kg
QC Result
QC Result
1871.70
32.00 U
3267.58
5758.06
3267.58
CCV 138154-016 I04LSTTC2 mg/Kg
CCB 138154-017
mg/Kg
1880.20 32.00 u
........
138154. .
Equipment Code. .. : T0C4
Analyst...: els Test Code,: TOC
True Value 2000.00
4730.00 4780.00
2000.00
Orig. Value QC Calc. F * Limi ts
Date Time
94
165.70 184.84
U 68 U 120
55 94
% 85-115
% 53-140 % 53-140 * R 30 % 85-115
12/28/2004 0946 12/28/2004 0950 12/28/2004 1004 12/28/2004 1016
12/28/2004 1305 12/28/2004 1308
Test Method.
oyd Kahn
Method Descn pt ion.: To tal Organi c Carboh (Sol Is)
Parameter... . * * , ; :. TOC Average Dupl icates '
QC Lab ID
MS 232881-1 MSD 232881-1
Reagent
Units
I00FSTLK3 mg/Kg 100FSTLK3 mg/Kg
QC Result
3054.88 3050.32
QC Result 3054.88
Equipment Code
138154 TC4
Analyst...''''fe'tfi' Test Code. : TOCV2
True Value
Orig. Va Lue
1492.59 1492.59
QC Calc. F A Limits
93 % 53-140 84 % 53-140 10 R 30
Date Time
12/28/2004 1039 12/28/2004 1047
Page 11
* %-% REC, R=RPDr A^ABS Diff., D=% Diff.
11
Q U A L I T Y A SS U R A N C E M E T H o D E
' * e f e- r e hi
S: A N D N O T S .
. .Report Date; 12/3072004
REPORT COMMENTS 1) ALL pages of this report are integral parts of the analytical data. Therefore, this report should
be reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for
landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting Limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(s) meet the requirements of NELAC, Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on Laboratory receipt.
Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated limit. < Not detected at or above the reporting Limit. J Result is less than the RL, but greater than or equal to the method detection limit. B ResuLt is less than the CRDL/RL, but greater than or equal to the IDL/MPL, S ResuLt was determined by the Method of Standard Additions. F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection limit. Inorganic Flags (Flag Column)
ICV,CCV,ICB,CCB,ISA,ISB.CRI,CRA,MRL: Instrument related GC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control Limits. + MSA correlation coefficient is Less than 0.995. 4 MS, MSD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control Limits are not applicable. E SD: Serial diLution exceeds the control Limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting Limit or had a negative instrument reading lower than the absolute value of the reporting limit. N MS, MSD: Spike recovery exceeds the upper or Lower controL Limits* W AS(GFAA) Post-digestioh spike was outside 85-115% controL Limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated Limit. ND Compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/M5. Y The chromatographic response resembles a typical fuel pattern. 1 The chromatographic response does not resemble a typical fuel pattern. E ResuLt exceeded calibration range, secondary diLution required. F AFCEE:Result is an estimated value below the reporting Limit or a tentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MsD, Surrogate: Batch QC exceeds the upper or lowercontrol limits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds anaLyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two vaLues is reported when the % difference between the results of two GC columns is
Page 12
Q U A L I T Y ASSI) R A N C E M E T H O D S R E F E R E N C E S AND NOTS Report D a t e :12/3/204
greater than 25%.
Abbreviations
AS Post Digestion Spike (GFAA Samples - See Note 1 below)
Batch Designation given to identify a specific extraction, digestion,preparation set, oranalysis set
CAP Capillary Column CCE Continuing Calibration Blank
CCV Continuing Calibration Verification
CF Confirmation analysis of original
C1 Confirmation analysis of Al or Dl
C2 Confirmation analysis of A2 or D2
C3 Confirmation analysis of A3 or D3
CRA Low Level standard Check - GFAA; Mercury
CRI Low Level Standard Check - ICP
CV Calibration Verification Standard
Dil Fac Dilution Factor - Secondary dilution analysis
D1 Di Lution 1
D2 Di Lution 2
D3 Dilution 3
DLFac Detection Limit Factor
DSH Distilled Standard - High Level
DSL Distilled Standard - Low Level
DSM Distilled Standard - Medium Level
EB1 Extraction Blank 1
EB2 Extraction Blank 2
EB3 DI Blank
ELC Method Extracted LCS
ELD Method Extracted LCD
ICAL
Initial calibration
ICE Initial Calibration BLank
ICV Initial Calibration Verification
IDL Instrument Detection Limit
ISA Interference Check Sample A - ICAP
ISB Interference Check Sample B - ICAP
Job No. The first six digits of the sample ID which refers to a specific clieht, project and sample group
Lab ID An 8 number unique laboratory identification
LCD Laboratory control Standard Duplicate
LCS Laboratory Control Standard with reagent grade water or amatrix freefrom theanalyte ofinterest
MB Method BLank or (PB) Preparation BLank
MD Method Duplicate
MDL Method Detection Limit
MLE Medium Level Extraction BLank
MRL Method Reporting Limit Standard
MSA Method of standard Additions
MS Matrix Spike
MSD Matrix Spike Duplicate
ND Not Detected
PREPF Preparation factor used by the Laboratory's Information Management System CL IMS >
PDS Post Digestion Spike (ICAP)
RA Re-analysis of originaL
Al Re-ahalysis of D1
A2 Re-analysis of D2
A3 Re-analysis of D3
RD Re-extract ion of dilution
RE Re-extraction of original
RC Re-extract ion Confirmation
RL Reporting Limit
RPD Relative Percent Difference of duplicate (unrounded) analyses
RRF Relative Response Factor
RT Retention Time
Page 13
Q U A L I T Y A S S U R A N C E MET.HODS R E F E R E N C E S A N D N O T'-.E^S". Report Date; 12/30/2004
RTU Retention Time Window Sample ID A 9 digit number unique for each sample, the first
six digits are referred as the job nunber
SCB Seeded Control Blank
sb SeriaL DiLutian (Calculated when sample concentration exceeds 50 times the MDL)
UCB Unsccdcd Control Blank
SSV Second Source Verification standard
SLCS
Solid Laboratory Control Standard(LCS)
PHD pH Calibration Check LCSP pH Laboratory Control Sample
LCDP
pH Laboratory Control Sample Duplicate
HOPH
pH Sample Duplicate
NDFP
Flashpoint Sample Duplicate
LCFP
Flashpoint LCS
G1 Gelex Check Standard Range 0-1
G2 Gelex Check Standard Range 1-10
G3 Gel ex Check Standard Range 10-100
G4 Gelex Check Standard Range 100"1000
Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "SM added to the current
abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA)
Note 2; The MD calculates an absolute difference (A) when the sample concentration is Less than 5 times the
reporting Limit. The control Limit is represented as +/- the RL.
Page 14
14
CHAIN OF CUSTODY
15
CHAIN OF CUSTODY/ANALYSIS REQUEST FORM
Severn Trent Laboratories
T: 708-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE j of /
PROJECT INFORMATION Client: Weston Solutions, Inc.
1460 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari email: lkesari@westonsolutions.com
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
ANALYSES REQUESTED
Sampler:
T Frinak, A Murphy
P.O. #: Quotation #:
SAMPLE ANALYSIS
ExyUMS #
I
J8T1 Si s Jter
Client Sample Identification
DF14 SB 137R 0 0050
DF14 SBC 137R 0 0 0 0 0
DF14 SBC 137R
0050
DF14 SBC 137R
0100
DF14 SBC 137R
0150
DF14 SB 137R
0180
DF14 SB 137R
0100
DF14 SB 136R
0050
DF14 SB 136R 0 0290
DF14 SB 136R 2 0290
Collection Col lection
Date
Time
oO. co ZO
15- Dec-04 9:05
15-Dec-04 9:00
X
15-Dec-04 9:15
15-Dec-04 9:30
X
15-Dec-04 9:45
15-Dec-04 9:50 X
15-Dec-04 9:15 X
15-Dec-04 15:05 X
15-Dec-04 16:30 X
15-Dec-04 16:35 X
Sample
Matrix
SOIL SOJL SOIL SOIL SOIL SOJL WATER SOIL SOIL WATER
Comments
15-13 FBGS 18-20 FBGS
X
X X PROJECT REQUIREMENTS
Results Deadline:
Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other:
<
Sample Lot#:
*2 . %% [
STL Chicago Internal Sample Custody Transfer Record
Client:
CUT
Sample No. /- F
Analysis
/! lit
Relinquished by: Received by;
7^ L / ^ ~
\ k r
0
Date
Time
Comments
/oA t/aty ? ! >
CH-22-t 1-O01/C-1 /99
rpjsckl
Job Sample Receipt Checklist Report
Job Number.: 232881
Locatioh.: 57222 Check List Number.: 1
Description.:
Customer Job ID.....:
Job Check List Date.: 12/17/2004
Project Number.: 20004891 Project Description.: Confidential Decatur FC Investigation
Customer...... : Weston Solutions, Inc.
Contact.: Jai Kesari
Questions ?
(Y/N) Comments
V2
Date of the Report..: 12/30/2004 Project Manager.... : rew
Chain-of-Custody Present?....................... . Y
Were samples dropped off at or picked up by STL? . N
Custody seal on shipping container?............. . Y
...If "yes", custody seal intact?............... . Y
Custody seals on sample containers?............. . N
...If "yes", custody seal intact?...............
Samples iced?.................................
Y
Temperature of cooler acceptable? {4 deg C +/ 2). Y
Samples received intact (good condition)?...... . Y
VoLatiLe samples acceptable? (no headspace)....
Correct containers used?... .................... . Y
Adequate sample volume provided?................ . Y
Samples preserved correctly?................ .
.Y
Samples received within holding-time?___ ....... . Y
Agreement between CQC and sample Labels?....... . Y
Radioactivity at or below background levels?.... . Y
A Sample Discrepancy Report (SDR) was needed?___ . Y
If samples were shipped was there an air bill #?. . Y
Sample Custodian Signaturc/Date.......... ..... . Y
Page 1
18
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CASE NARRATIVE
Client: Job #:
STL Chicago Wet Chemistry Case Narrative
Weston Solutions, Tnc, 232881
Date Rec'd: 12/17/04
1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method.
The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average of the sample bums is reported.
2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis.
3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria.
4. The method blank was less than the reporting limit.
5. The LCSs were within acceptance limits, although the RPD between the LCS and LCD was high, at 55%.
6. Duplicate matrix spikes were done on sample 232881-1 and both were within acceptance limits, as was the RPD between them. Please see the Quality Control Results pages for additional detail.
7. The second burn o f sample 232881-3 was high compared with the first bum. It was repeated and found to be an outlier. It is included in the raw data. The reported average TOC for that sample is 1600 mg/kg. The result from the discounted bum was 5200 mg/kg.
Wet Chemistry Section Manager
21
RAW DATA
*** RUH LOG
***
(V2 )
12/29/04 13:00
Total Organic Carbon (Soils) Method Coda.. : TOCS Batch Code... : 138154
SAMPLE: Grp Po$ Saffple ID
11 12 13 14
___ICAL_I04LSTTC1_ ___ ICV_IQ4LSTTC2_ ___MB__
__ LC5_100FSTLK3_3
15
16
___LCD_I00FSTLK3_3 2 3 2 8 8 1 J _ S ___
status...-.- : RVWD Batch Date.. : 12/28/04
Batch Time.- : 1220
User Name___ QC Code..... Calc Code....
TOCS
Location Code..: 57222 Equipment Code. : TOC4 Irrport Code.... :
TEST CODE
T TT T T T T T T T T T T O O C C C I 1I
C cC cC C C S S S C C C
2 3 4 A A A 2 A S sS
VVV 234
V 2A
22
Di lution
TEST P0S
Date / Tima
1 2 3 4 5 67 111 2 2 2 7 8 9 0 12
0000
0
12/28/04 0946 0
12/28/04 0950 0
12/28/04 1004 0 12/28/04 1016 ik
12/28/04 1023
0
17
232881_1_S_MS_I0 0 FSTLK3_6
12/28/04 1039
0
18
232881_1_S_MSDJ0QFSTLK3_6
12/28/04 1047
0
19
1 10
1 11
1 12
232881_2_S___ 2 3 2 8 8 1 ___ 232881 4 S 232881_5_S___
12/28/04 1055 12/28/04 1106 12/28/04 1136 12/28/04 1204
0 0 0 0
1 13 232881_6_5___
12/28/04 1220
0
1 14 232881 7_S___
12/28/04 1240
0
1 15 232881_8_S___
12/28/04 1254
0
1 16 1 17
___ CCV_I04LSTTC2_ ___CCB__
12/28/04 1305 0 12/28/04 1308 0
1 18 233Q25_9_S___
Page 1
23
*** QC SLimary
***
<V2 >
Total Organic Carbon (Soils)
Method code,.: TOCS Ketch Code...: 130154 Status...... : RVUti
Batch Date... 12/28/04 Batch Tinte,.. 1220 User Name.,,, els
QC Code.
TOCS
CaLc Code..... : TOCS
Locatioh Code..: 57222
Grp Smp SampLe ID
Pos Test Result
Known
Original
1 2 ___ICV_I04LSTTC2_
1 TOC 1871.70 2000
1 3 ___MB__
1 TOC -2.67
1 4 ___LCS_I00FSTLK3^3
1 TOC 3267.58 4780
-2.67
15
LCD I00FSTLK3 3
1 TOC 5758.06 4780
-2.67
1 7 232881_1_S_MSJ00F5TLK3_
1 a 232B81_1_S_M5D_I00FSTLK3_6 1 16 ___CCV_I04LSTTC2_
5 T0CAV2 3054.88 5 T0CAV2 3050.32 1 TOC 1880.20
2000
1492.59 1492.59
1 17 ___CCB__
1 TOC
3.05
Report Date: 12/29/04 13:01
Equipment Code.: TOC4 Infwrt Code..,,:
Alternate QC Res 94
F QC Res
F
3267.58 3054.88
68 120 93 84 94
55 * 10
Page 1
24
RAU TEST DATA
***
(V2 )
Total Organic Carbon (Soi Le)
Method Code. .: TOCS Batch Code *.: 138154
Status___
RVWD
Batch Date...: 12/28/04 Batch Time__ : 1220 User Name--- : cls
SAMPLE:
Grp Pos SampLe ID
11
ICAL I4LSTC1
12
ICV I04LSTTCZ
13
MB
14
LCS I0FSTLK3 3
15
LCD I00FSTLK3 3
1 6 232881 1 S
1 7 232881 1 S MS IQQFSTLK3 6
1 8 232881 1 S MSD I00FSTLK3 6
1 9 232881 2 S
1 10 232881 3 S
1 11 232881 4 S
1 12 232881 5 S
1 13 232881 6 S
1 14 232881 7 S
1 15 232881 8 S
1 16
CCV IQ4.STTC2
1 17
CCB
1 18 233025 9 S
QC Code... Cale Code. Location Code..: 57222
Dilution
TOC mg/Kg
TOC2 mg/Kg
Report Date: 12/29/04 13:01
Equipment Code.: TOC4 Import Code Itili
TOC3 mg/Kg
TOC4 mg/Kg
TOCAVH mg/Kg
1871.70 -2.67 3267.58 5758.06 1384.17 3054,88
3050.32 2909.92 1618.28 1296.59 1334.96 1482.71 3707.80 1247.76 1880,20 -3.05
1601.01
2834.76 1495.12 1540,31 1580.54 1308.71 3397,89 1021.76
1492.59 3054.88 3050.32 2872.34 1556.70 1418.45 1457.75 1395.71 3552.85 1134.76
Page 1
25
*** RAU TEST DATA
(V2 )
Totl Organic Carbon (Soi Ls)
Method Code. : TOCS
Batch Coda.., : 133154
Status
: RVWD
Batch Date...: 12/28/04 Batch Time...: 1220 User Name___ : cLs
SAMPLE
Grp Pos Sanple ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS I0DFSTLK3 3
15
LCD I00FSTLK3 3
1 6 232881 1 S
1 7 232881 1 S MS I00FSTLK 6
1 8 232881 1 S MSD IQ0FSTLK3 6
1 9 232881 2 S"
1 10 232881 3 S
1 11 232881 4 5
1 12 232881 5 S
1 13 232881 6 S
1 14 232881 7 S
1 15 232881 8 S
1 16
CCV I04LSTTC2
1 17
CCB
1 18 233025 9 S
QC Code...
. TOCS
Cale Code. ___ : TOCS
Location Code..: 57222
Dilution
TOCAV3 mg/Kg
TOCAV4 mg/Kg
Report Date: 12/29/04 13:01
Equipment Code.: TOC4 Import Code ___ :
TOCR1 ug
TOCR2 ug
T0CR3 ug
93.5850 -0.4265 100.9681 159.4982 72.3923 181.1542 164.7172 172.2670 90.9472 69.4972 76.8937 81.2524 198.3675 40.8019 94.0099 -0.4885
93.0186
136.0685 74.3075 89.6460 84.4006 70.6701 181.4474 36.0681
Page 2
26
RAU TEST DATA
(V2 >
Total Organic Carbon (Soils)
Method Code..: TOCS
Batch Coda . ; 138154
Status___
RVWD
Batch Date...: 12/28/04 Batch Time...: 1220
User Name,,,.: cls
SAMPLE :
Grp Pos Sanple ID
11 12 13
14 15
16
17
18 19 1 10
1 11 1 12 1 13
1 14 1 15
1 16 1 17
1 18
ICAL I04LSTTC1 ICV I04LSTTC2 MB LCS I00FSTLK3 3 LCD I00FSTLK3 3 232881 1 S 232881 1 S MS I00FSTLK3 6 232881 1 S MSD IOOFSTLK3 6 232881 2 S 232881 3 S 232881 4 S 232881 5 S 232881 6 S 232881 7 S 232881 8 S
CCV I04LSTTC2 CCS 233025 9 S
QC Code,...
. TOCS
Cale Coda,
TOCS
Location Code..: 57222
Dilution
T0CR4 ug
UT1 s
Report Data: 12/29/04 13:01 Equipment Coda,: TC4 Inport Code..,.:
UT2 WT3 UT4
99g
0.05 0.16 0.0309 0.0277 0.0523 0.0593 0.0540 0.0592 0.0562 0.0536 0.0576 0.0548 0.0535 0.0327 0.05 0.16 0.0534
0.0581
0.0480 0.0497 0.0582 0,0534 0.0540 0.0534 0.0353
Page 3
27
** RAU TEST DATA
Total Organic Carbon (Soils)
Method Code.,; TOCS
Batch Code .,, : 138154
Status___
RVUD
Batch Date...: 12/28/04 Batch Time...: 1220 User Name___ : cls
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS IQFSTU3 3
15
LCD I00FSTLK3 3
1 6 232881 1 S
1 7 232881 1 S MS IQQFSTLK3 6
1 8 232881 1 S HSD I00FSTLK3 6
1 9 232881 2 S
1 10 232881 3 $
1 11 232881 4 S
1 12 232881 5 S
1 13 232881 6 S
1 14 232881 7 S
1 15 232881 S S
1 16
CCV I04LSTTC2
1 17
CCB
1 IS 233025 9 S
C Code... Cale Code. --- , TOCS Location Code..: 57222
Di luti on
DI FAC N/A
TCS mg/Kg
3.2000 1.0000 5.1780 5.7762 2.8986 2.6981 2.9630 2.9851 3.0217 2.6623 2.8829 2.9412 2.9935 4.7059 3.2000 1.0000 2.9963
(V2 )
Report Date: 12/29/04 13:01
Equipment Code.: TOC4 Import Code ___ :
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
Page 4
28
Calibration Report Print Date/Time: 2G04/12/21 7:53:52
Cal. Curve ID:
SOILCURVE
Created:
12/t 3/2004 13:36
Calibration Factor (m): 9.841e+04
Y Intercept (b): -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message Date &
Raw Data ug C ugC
Time
0 ugram C
-8891 0.000 2.451 No Sample Det 12/13/2004 11:24
10ugramC
911065 10.000 11.800
12/13/200411:42
20 ugram C 1853385 20.000 21.375
12/13/200411:48
40 ugram C 3745719 40.000 40.605
12/13/200412:04
120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/200412:28
200 ugram C 18654032 200.000 192.099
12/13/2004 12:46
300 ugram C 29462156 300.000 301.928
12/13/200412:59
400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/2004 13:19
Detailed Analysis Report Print Date/Time: 2004/12/28 13:34:53
Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12280041
/
Timestamp: 12/28/2004 09:46
Sample Type: Cal. Verification ^
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 93.5850 93.5850 8959410 1768 2 767 293
Sample ID: tCB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename; 12280947
Timestamp: 12/28/2004 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integra on Baseline Baseline Time
1 -0.4265 -0.4265 -16207 2.086 1.864 120
Last Message: No Sample Detected
Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12280959
Timestamp: 12/28/204 10:04 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 100.9681 100,9681 9961871 2.084 3.083 267
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281011
Timestamp: 12/28/2004/i0:16 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time
1 159.4982 159.4982 15721718 3.087 4.085 269
SamplelD: 232881-1 Method: boat
Cai. Curve: SOILCURVE Operatorio: CAROL
Mode: TC Filename: 12281019
Timestamp: 12/28/2 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 72.3923 72.3923 7149769 2.869 3.866 242
Sample ID: 232881-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TO
Filename: 12281024 Timestamp: 12/28/200410:30
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 93.0186 93.0186 9179569 2.638 3.636 272
Sample ID: 232881-1ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281033 ,
Timestamp: 12/28/^004 10:39y Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 181,1542 181.1542 17852856 3.518 4.517 281
= x = ;s= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = s= s= = 3 ;3 ;ssi3 i3 3 s j3 :;
Sample ID: 23288t-1msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12281041
Timestamp: 12/28/204 10:47^
Sample Type: Sample /
\
Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time
1 164.7172 164.7172 16235315 2.976 3.974 326
Sample ID: 232881-2 Method: boat
Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12281050
x
Timestamp: 12/28/2064 10:55
Sample Type: Sample /
Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time
1 172.2670 172.2670 16978274 2.817 3,816 278
Sample ID: 232881-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode; TC Filename: 12281056
Timestamp: 12/28/2004 11.01 Sample Type; Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 136.0685 136.0685 13416044
2.873 3.871 275
:====a(i^Xi
31
= = = = ff= = = = = = q t = = = = = = 3 E E = = = = = = S S ^ = = = lE C = = = = D t= = = ffa a iK = = ? S = ? = = = = ^ V = = = = ^ :S E :S n IC S t? = =
Sample ID: 232881-3 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281101
Timestamp: 12/28/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 90,9472 90,9472 8975732 2,914 3,911 251
=E SiaSE?Slitit B=at==Xi=Xc==========================
Sample ID: 232881-3
Mode: TC
Method: boat
p Filename: 12281117
Cal. Curve: SOILCURVE / Operator ID: CAROL y J]
, Timestamp: 12/28/2004 11:23 Sample Type: Sample
f cnv' Rep # ppm C ug C^ Raw Data Beginning Ending Integration
\ Baseline Baseline Time
1 265.0371 265.0371 26107632 1.901 2.901 357
Sample ID: 232881-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281131 /
Timestamp: 12/28/2004 11:36 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 69.4972 69.4972 6864870 1.957 2.956 265
Sample ID: 232881-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281141
Timestamp: 12/28/200411:47 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 896460 89.6460 8847678 2.017 3.014 294
L K ir;sai:rH f5iiSiE SH t
Sample ID: 232881-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281150
Timestamp: 12/28/2004 11:55 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 74.3075 74.3075 7338247
2.088 3.086 262
32
Sample ID: 232881-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281158 j
Timestamp: 12/28/2004 12:04
Sample Type: Sample `
Rep # ppm C ug C Raw Data Beginning Ending ihtegr^tion^ Baseline Baseline Time
1 76.8937 76.8937 7592745 2.097 3.093 274
Sample ID: 232881-5
Mode: TC
Method: boat
Filename: 12281208
Cal. Curve: SOILCURVE
Timestamp: 12/28/2004 12:13
Operator ID: CAROL
Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 84.4006 84.4006 8331489 2.258 3.255 258
Sample ID: 232881-6
Mode: TC
Method: boat
Filename: 12281215
y
Cal. Curve: SOILCURVE
Timestamp: 12/28/200412:20
Operator ID: CAROL
Sample Type: Sample /
/
Rep # ppm C ug C Raw Data Beginning Ending \nte Igration
Baseline Baseline Time
1 81.2524 81.2524 8021685 2.368 3.365 274
Sample ID: 232881-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281228
Timestamp: 12/28/2004 12:33 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 70.6701 70.6701 6980297 2.053 3.053 259
Sample ID: 232881-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281234
Timestamp: 12/28/2004 12:40 Sample Type: Sample y
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 198.3675 198.3675 19546788
2.351 3.350 340
Sample ID: 232881-7
Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281241
Timestamp: 12/28/2004 12:46 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 181.4474 181.4474 17881712 2.792 3.789 294
Sample ID: 232881-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281249
Timestamp: 12/28/2pct4 12:54 Sample Type: Sam ple/
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 40.8019 40.8019 4041016 2.313 3.306 236 = = = = = = = = = = = = = = = = = = = = = = = 9 = - f f i ; = ! ! 3E E r = = = 2= 3= = = = 3= = = = = =
Sample ID: 232881-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281255
Timestamp: 12/28/2004 12:59 Sample Type: Sample
Rep# ppmC ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 36.0681 36.0681 3575164 2.940 3.939 219
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12281300
^
Timestamp: 12/28/2004 13:05
Sample Type: Cal. Verification
^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 94.0099 94.0099 9001224 2.161 3.160 278
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12281306
Timestamp: 12/28/! >0413:08 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0,4885 -0.4885 -22308 2.506 2.232 120
Last Message: No Sample Detected
:=;ss
34
STL Chicago
Page No...
115
TOC in Soils
Book No
Method: Lloyd Kahn
Instrument Phoenix 8000 fTOC4)
LabNet Batch: / 3 P /W
Calculation:
Date of Standard Curve. / / 1 3
TOC (mg/kg) ug C / grams sample
Book#3 7 ^ Faoc# ^ ^
MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample
MS, MSD Observed (mg/kg) * ug C / grams sample
MS, MSD Ree. 3 fobserved ma/ko - ave, sample result fma/koll x 100
known concentration in mg/kg
Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve) >11-4tre t
Stock II (ICV/CCV) x g y ^ r r - c
LCS Source iPSPOttfUt-y LCS True Value
Ik. Acceptance Range 3~
Sam ple ID:
'ZC&Au
Sam ple W eight (g)
o .o r o, /
ugC - 7. y-2< r-
C om m ente:
L-Pty, LO U
X ti& tl- /
i/ '/
0 Zoq /. X l n o> .o
7 . O < r i V
- .f ^ A-5/7 o. ^ H O
~ 2 - O, o r 9 ^ -- O-" o , n y & o
a.
e>\ ( j r r n :
(y t Ci *r ? C
Z r
" 7 5 ( 37-23 \
Q 3,oid / 1?! , / r y z
/y fz , *7 ._
/G Y
.! I l \ocne t ' X . 6L<tr?o, m x 9^/0^?/ n
".
/A
-V a o<r?z.
_____ ^
^ V O, 0 ^9 7 - < , 7 9?C -< r n~ T T 7 - _ . o r r p ' ^ W f7
- 7 _ 0, O r v T "Z _ 0)^0 5 T 5 ^
<2. ^ 3 3 - 7
7 9 ^ r r ? o .......... 7T J f T Y^MoOC
Y f -2.<rJy
7(7. t f ? c /
/1 Y y i7 r
/ff, Ir i
l/, ?o/9
tfiCO' 2'<ot- ^ 3
Prep Analyst 0 * 7 A nalvsty ^ S S -^
db*
Date: * /* * Data: //zP-,fy_
Reviewed by:
Date: f a M
T
Tl
V3
.5
i
35
Page No.:
_____J _. _J . U
TOC fn Soils
Book No.: 'J 7 r- ~
Method: Lloyd Kahn
Instrument Phoenix 8000 (TOC4)
LabNet Batch:________ ____
Calculation*;
Date of Standard Curve:
TOC{mg/kg) ug C / grams sample
Book # ________ Page #_
MS, MSO Known Cone, (mg/kg) * 100 ug C / grams sample
MS, MSD Observed (mg/kg) * ug C / grams sample
MS, MSD R*c. [observed mo/ko - avc. sample result fma/kcll x 100
known concentration in mg/kg
Standard Traceability; (Note; Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve)
Stock II (ICV/CCV)
LCS Source ID
LCS True Value
Acceptance Range,
Sample ID:
Sample Weight (g)
ugC
r&rl'V' ,o
ecV
a> fb
3 y.fe/
f % d&r? M 7F^<r
2-33Q3-\ a, cfli
fa f<n 7
-1 A < ? n /
-to ?. ofXj ^fO , O <r 23T
.7,2, 9^
~ti~ --rS^W-- _ - h Ot d>c*r^
- It y i n, O n t o
Tf.rCx 2L379 K^r?
-- 12l 0 , 0 *13 9' lio, ^ 7
- /3> .3Y7 , _ J - : O - o.*o h m
_ a ,o y q ,\~
o,o y 9 - T 0. 0 l(
a a o???" -'L otoft
- X 0~_J~^ . r r Z . x_Q < 3 3
O-O r Y 7
X^jy % so t( btnof.
* 5 '-nr m, oaf! itcrfi) y?, roto r; < /er i
Comments;
Prep A n aiyst/ f / ^
Date:
/o ;ot-~
Analyst:
Date:
Reviewed by:.
Date:
CHI-2M24SS/B-0a0l
