Document NNpRBzzkLnOmyGJ4byZekqvYV
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(i*r
/ . SHELL OIL COMPANY
SHELL CHEMICAL COMPANY
PLAINTIFF'S EXHIBIT
DEER PARK MANUFACTURING COMPLEX
SH-1628
DATE OCTOBER 9, 1975
TO DEER PARK MANUFACTURING COMPLEX ENVIRONMENTAL CONSERVATION SUPERINTENDENT
FROM
STAFF ENGINEER - ENVIRONMENTAL CONSERVATION - DEER PARK MANUFACTURING COMPLEX
SUBJECT WASTE MATERIALS GENERATED AT REFINERY
Attached is a list of various waste materials generated in the Deer Park Refinery. The wastes have been categorized as follows:
A. Granular --Spent Catalyst B. Granular - Miscellaneous C. Sludge - Oily D. Sludge - Chemical E. Solids - Chemical and Oil F. Waste Materials to Refuse
Total
228 M Lb/Year 1,498.3 M Lb/Year 10,935 M Lb/Year 1,797.5 M Lb/Year
167 M Lb/Year 20,000 M Lb/Year
34,625.8 M Lb/Year
(The materials listed in "A" through "F" are disposed of in-house except for refuse. The refuse includes refuse generated at the Chemical Plant.)
G. Waste Materials Sold H. Waste Materials Lost (Lost to
Atmosphere or Wastewater) I. Waste Materials Stored
11,278 M Lb/Year Unknown
Unknown
The quantities reported here might be improved through review of Purchasing records. This would be a considerable task. In-house disposal consists of landfill, landfarming (sludge pits), and the effluent treaters. Some of the wastes listed in "A" through "E" may be disposed of in "refuse".
fa If you need additional information, please call me.
DPMC-00983
LAM 007498
REFINERY WASTE MATERIALS
GRANULAR - SPENT CATALYST
ITEM NO. R-8
SOURCE A-E
R-10 R-ll R-15
HUD-1 A-E SR-5
CONTACT RDM
RDM RDM LRG
DESCRIPTION
QUANTITY, M LB/YR
Catalyst Ni-Co/Mo ZnO 8 to 10% S Ceramics (All Changed out 8 Mo)
30 69
7
Catalyst Ni-Mo S (Changed out 2-3 Yr)
25
Catalyst Ni-Mo (Changed out 2 Yr)
15
Catalyst (22O0cu ft/yr) SO2- Alumina (Changed out 3 Yr)
30
R-16 K-37
H-PT
Lube HT Unit
LRG CEB
Catalyst 3/8" x 1/4" Iron Oxide & Chromium (Changed Every 4 Yr)
Catalyst HDS2A Co-Mo Alumina FeS Pyrophoric (Change out Every 2 Yr)
SUBTOTAL
40
12 228
HCU -- Hydrocracking Unit LRG - L. R. Grounds RDM - R. D. Madsen A-E - Aromatics-East SR-5 - Sulfur Plant H-PT - Hydrogen Plant GF - Geart Fikkert
DPMC-00984
LAM 007499
Refinery Waste Materials
2
B. GRANULAR - MISCELLANEOUS
ITEM NO.
SOURCE
CONTACT
DESCRIPTION
QUANTITY M LB/YR
R-71
CR
KSB Spent Molecular Sieve, S & Cl
100
R-72 R-73
CR CR
KSB Alumina-Tail Gas Scrubber, Cl & S 41
KSB Filter Aid-Diatomaceous Earth-DEA
0.2
R-60
CC
AFO
Cat Spill-Turnaround, SilicaAlumina
40
R-65
LC
QCS Bauxite-Treating Clay, 9 T/Month 228
R-46
Lab
CEB Silica Gel - from Air Dryers
5
R-63
CC
AFO
Silica Gel - Air Dryer, 4.5M Lb/3 .Yr
1.5
R-69
LC
QCS Silica Gel - Air Dryer, 4M Lb/3 Yr 1.5
R-22 Tk D-340
DWL
Biosludge, Salts-Solids
50
R-55
GR
AKW
Plastic & Steel Rings, 1/2 T/3 Yr
0.3
R-51
GR
AKW CFH Rock, Ceramic, & Coke, Pyrophoric-
Lube Oil Oozes, 100M Lb/2 Yr
50
R-54
GR
AKW
Coked Mol Sieve from n-Paraffin Pyrophoric
210
R-l HCU
LRG Granular Coke with Oil-Water Pyrophoric, Sour (4 Lugger Pans Every 3 Years)
11
R-5 TC
PL Tube Coke-Dust, 7 Drums/Year
3
R-6 TC
PL Coke from Reaction Chamber (10 cu yd/2 yr)
10
CEB - Chet Beecher CERT - Cat Feed HT AKW - A. K. Washburn DHT - Dist. HT AFO - A1 Ott CC - Catalytic Cracking LC - Lube C
QCS - Curt Stanberry Lab - Lube A & B CR - Cat Reformer KSB - Ken Baird DWL - Don Lanning GR - Gas Recovery TC - Thermal Cracking PL - Pete Lanchak
OPMG-00886
LAM 007500
Refinery Waste Materials
3
B. GRANULAR - MISCELLANEOUS (Cont'd)
ITEM NO.
SOURCE
CONTACT
DESCRIPTION
R-39
Lab
CEB Coke from Exchangers & Vacuum Towers (20 T/3 Yr)
R-64
CC
AFO
Coke - Cleanout When Down 15 Lugger Pans/Year
R-52
GR
AKW
Bed Support Dist. HT, Pyrophoric 10,000 Lb/2 Years
R-30
Disp.
DBM
Oily Dirt from Inside Tank Dikes Leaks
R-19
Disp.
DBM
Rust and Dust from Kero Tanks FeS
R-58
CC
AFO
tCatalyst Fines-Silica Dust (Now to Clay Pond-Slurried with H2O)
SUBTOTAL
QUANTITY, M LB/YR
13 130
5
100 130 550 1,498.3
SLUDGE - OILY
R-17
Disp.
DRD
Crude BS&W
10,000
R-31
Dist.
GF
Sludge from Vac. Tower Filters
15
R-36
Lab.
CEB Sludge, Oily from Feed Tanks When Leak Occurs
300
R-62
CC
R-7 CC
AFO Catalyst from Feed Tanks from Recycling on Start-up
AFO Catalyst - Slurry Oil Tanks
20 100
R-67 R-68
LC LC
QCS BS & Rust - 6 or 8 Tanks
QCS Wax Spills and Sand SUBTOTAL
250
250 10,935
AW - Aromatics West RRI - Bob Ingram WA - West Alkylation JEG - John Garrison T&S - Treating & Solvents SFG - Floyd Good
DBM - Don McCants Dist. - Distilling GF - Gaert Fikkert Disp, - Dispatching DRD -r- Don Deister
DPMG-GQ986
LAM 007501
Refinery Waste Materials
4
D. SLUDGE - CHEMICAL
ITEM NO.
SOURCE
CONTACT
R-18
Disp.
DRD
R-2 HC
LRG
R-33
WA
JEG
R-35
T&S
SFG
R-56
GR
AKW
R-75
CR
KSB
R-76
CR
KSB
DESCRIPTION Leaded Sludge Triethylene Glycol Sludge H2S0<, Storage Sludge H2S0i, Storage Sludge Caustic Sludge 20% Caustic Sulfide Biotreaters 20% Caustic Carbonate
SUBTOTAL
QUANTITY. M LB/YR 60 0.5 27 60 45 550
1,100 1,797.5
SOLIDS - CHEMICAL AND OIL
R-14
Sulfur
LRG
R-25
Disp.
DWL
R-42 R-38 R-20
Lab. Lab. Disp.
CEB CEB DRD
Elemental Sulfur - Spills & Leaks 20 cu yd Annually
45
Wax Set up in Hoses - Reprocessed Through Lube C
5
Wax Chips from Clean-up
20
Asphalt Drips - 10-20 gal Drums/Week 87
Solids - Lead Contaminated Clothing, Aggregate, Dirt
SUBTOTAL
10 167
F. WASTE MATERIALS TO REFUSE
R-4, R-13, R-24
Hoses - Cargo, Steam, Air, Hydraulic,
R-26, R-4 3, R-4 9
Hydrocarbon, etc.
R-56, R-41, R-66
Tires
R-2 7, R-2 9, R-44
Containers - Drums? 5 gal, 1 gal, & smaller.
R-45, R-21
Samples, Paint, Oil, Additives, etc.
Includes Chem.
Plant & Refinery Pallets; Seals-Floating Roof Tanks: Filter
Cartridges; Outfall Collectors; Debris from
Water Front Clean-up; Trash; Garbage
TOTAL REFUSE, 50,000 cu yds/year - Estimated Weight
20,000
GRAND TOTAL
34,625.8
_________________________
2,885 M LB/MONTH
*Some drums sold for reclamation.
DPHC-00987
LAM 007502
Refinery Waste Materials
5
WASTE MATERIALS SOLD
ITEM NO.
SOURCE
CONTACT
R-70
CR
KSB
R-32
IIDU-2
GF
R-50
CFHT
AKW
R-53
DHT
R-59
CC
R-3A
T&S
R-3 HCU
AKVJ APO SFG LRG
DESCRIPTION
QUANTITY. M LB/YR
1IDS-2 Cat. Pellets (Change 4-5 Yr)
30
Catalyst (Shell 244 HT) - Co-Mo Metal Recovery, 117M lb/4 yr
30
Shell 324 Cat. Ni/Mo, Silica/ Alumina/MetaIs Recovery (400,000 lb/2 Years)
200
Shell 344 Cat. Co/Mo Alumina/ Metals Recovery, 95M lb/2 Yr
43
Spent Catalyst - 1/2 T/D, Sold as Equilibrium Catalyst, Silica/Alumina 365
Caustic - 10-14% Cresylic Acid Solid to Merichem
10,395
1/16" Extruded Catalyst: Ni-3%, Mo-11%, FI-6%, P-1%, AI2O31/16" Extruded Catalyst: Ni-4.5%, T-3%, Fl-3.5% on Al203/Si02 (Both Changed out 3 Years) 1/4" Alumina Balls
60 . 120
35
SUBTOTAL
11,278
WASTE MATERIALS RECOVERED
R-23
CC
AFO
WASTE MATERIALS LOST
R-61
CC
AFO
General Some Areas (R-40)
R-12
General Some Areas (R-7A)
Wax Spills & Drips from Tank Car Cleaning - 2 Lugger Pans/Day Reprocessed Through Lube & CC
Catalyst to Atmosphere, 1 T/D Silica-Alumina Sour Water Sump Vapor, H2S and NH3
Xylene Vapors from Xylene Spill to Sewer - Loss of Pump Suction Hydrocarbons - CD Vented to Atmos.
400
730 ?
? ?
DPMC-00988
LAM 007503
Refinery Waste Materials
6
H. WASTE MATERIALS LOST (Cont'd)
ITEM NO.
SOURCE
CONTACT
DESCRIPTION
R.-9 S&T
SFG Sulfolane (10 ppm in 120 B/D II2O) (Sulfolane 153 lb/yr) 200-300 B II2O with 1 B Sulfolane 1 or 2 times a year (Sulfolane 350 lb/yr) Kills biotreater bacteria.
R-48 AW
RRI Sulfolane Sludge (5% in Water) 500 B/3 Years on Turnaround (Sulfolane = 2900 lb/yr) Kills biotreater bacteria.
1. WASTE MATERIALS STORED
General Most Area (R-28)
R.-32
All Areas
Lumber, Ties, Piling, Telephone Poles, etc.
Insulation - Bagged & Buried Asbes tos
QUANTITY, M LB/Y
15,330 130
58
? ?
DPMC-00989
LAM 007504