Document NKXbmJwK6Z6bedEV05BV9ZJE
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)
SECTION 1
i
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
Richard Klinger Inc.________ ______
(5!3) 498-1181 : _
ADDRESS IXumber. Street. City. State, and ZIP Code)
2350 Campbell Road____ Sidney. Ohio__ 45365
CHEMICAL NAME ANO SYNONYMS
TRAOE NAME ANO SYNONYMS
Compressed Rubber Bonded Asbestos Sheet Packing ._Klineer_K-62_ Black.
chemical family
FORMULA
j
Mixture of SBR Rubber and Asbestos________ _____________ n/a____________________ ____________
SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS
%
TLV (Units!
ALLOYS AND METALLIC COATINGS
pigments
CATALYST
Carbon Black
0.52I
1-5
I.SMp/M3
N/A
BASE METAL ALLOYS
VEHICLE SOLVENTS ADOITIVES
N/A N/A. N/A
METALLIC COATINGS
FILLER METAL PLUS COATING OR CORE FLUX
OTHERS
others
_ _N/A_
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES
%
j
1 S
;
TLV (Units!
N/A N/A N/A N/A N/A
14
TLV (Units)
O1
t--.
1
Chrvsotile Asbestos CAS #.1332-2 1-4 Stvrene Butadiene. Polymer CAS #9003-55-8 Carbon Black CAS #1333-86-4
- Two fibers/cc greater than 5 um in length.
-Jb___
___ ... .
81 15 _12___
__ 1% 3.5Mg/M-
#2 - No TLV established.
SECTION III - PHYSICAL DATA
BOILING POINT (F.)
VAPOR PRESSURE (mm Hg.J
VAPOR DENSITY (AIR=I)
Decomnoses N/A N/A
SPECIFIC GRAVITY (H:0*1)
PERCENT, VOLATILE BY VOLUME {%)
EVAPORATION RATE
(. - ....
=1)
SOLUBILITY IN WATER
Insoluble
appearance and odor Black with white spots.
1.65-1.85, .. NL/A_____
N/A .
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash point (Method used)
N/A
flammable limits
N/A
Lei
Uel
EXTINGUISHING MEOIA
Water, Carbon Dioxide, Dry Powder, or Foam.______________________________________
SPECIAL FIRE FIGHTING PROCEDURES
_
i
Firefighters should use self-contained breathing equipment and eve protection for
the rubber fumes._______________________________________________________ _________________________
UNUSUAL FIRE AND EXPLOSION HAZARDS
The rubber, once ignited mav need extra cooling to prevent reignition.
UTEX 000305
PAGE (1)
(Continued on reverse side)
' Form OSHA-20
Rev. Mjy 72
2-
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE (TLV) - Asbestos - 8 hour TWA (Time Weighted Average) o 2
fibers/cc greater than 5 um in length.
j
EFFECTS OF OVEREXPOSURE - The material in its finished form presents no known health hazard. A chronic health hazard may be created if further processing of the sheet allows asbestos fibers to be released into the atmosphere. Injhalation of free asbestos fiber over a long period of time can cause lung disorders, including asbestosis, pleural plaque, lung cancer, and mesothelioma.
I SECTION VI - REACTIVITY DATA
STABILITY - The material has infinite storage stability.
'
INCOMPATABILITY - Strong oxidizers, strong acids, or bases. . HAZARDOUS DECOMPOSITION PRODUCTS - Burning rubber (See Seccioj IV), and free asbestos
(See Section V).
HAZARDOUS POLMERIZATION will not occur.
SECTION VII - SPILL OR LEAK PROCEDURES iI
STEFS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Dust from sheet should be treated as free asbestos. Secure area and clean up using HEPA-filtered vacuum, or wet sweep. DO NOT clean up in a method that generates dust into atmosphere.
WASTE DISPOSAL METHOD - Bury in solid landfill as required by:29 CFR 1910.1001 (N)(2).
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - None required where local controls ensure negligible asbestos dust released into atmosphere. Where local controls not adequate, use respirator approved pursuant to 29.CFR 1910.1001 (D)(2). See section IXl- Special Precautions.
VENTILATION - Where dust producing processes are used, local ventilation, air filtra: and good work hygiene must be used to ensure negligible asbestos dust released to atmosphere.
EYE PROTECTION - None required for normal use.
OTHER PROTECTIVE EQUIPMENT - None required for normal handling or fitting of gaskets. Where gasket removal involves scraping, wire brushing, or other potential dust pro ducing operations; local ventilation, air filtration, good work hygiene, and where applicable, wetting down should be used to ensure negligible asbestos dust released atmosphere.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - In the manufacture of Klinger com pressed asbestos sheet packing, the asbestos is encapsulated into the sheet by a rubber matrix. In normaL handling of sheet and cut gaskets, no significant release of asbestos dust occurs. In the production of cut gaskets; local ventilation, air filtration, and good work hygiene must be used where the production process may release fibers into the workplace. The material must not be drilled, sawed, ground, sanded, or subjected to any other dust producing process without the necessary equvrment required to ensure that released fibers are contained.
UTEX 000306
SECTION X - DATE AND SOURCE OF INFORMATION
DATE - November 20, 1985 NAME - Derek Coomber.
p-n<;ident ISSUE #85-01
SECTION V HEALTH HAZARD DATA
THRtihOUD LIMIT VALUE
N/A (See IX Below)
EFFECTS OF OVEREXPOSURE
E.. TENCY AND FIRST AIO PROCEDURES
X
\
\
'SSSKMUSStSSr
STABILITY
UNSTABLE
SECTION VI - REACTIVITY DATA
CONDITIONS TO AVOID
STABLE INCOMPATABILITY (Materials to avoid)
X
HAZARDOUS DECOMPOSITION PRODUCTS
Infinite Storage stability j Strong Oxidizers/Acids/Alkalis
HAZARDOUS POLYMERIZATION
MAY OCCUR
WILL NOT OCCUR f
CONDITIONS TO AVOID
X
f
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO 8 TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
N/A
WASTE OISPOSAL METHOD Sanitary landfill in accordance with State and Federal Regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory protection (Specify type)
VENTILATION
LOCAL EXHAUST
None
required
SPECIAL
mechanical (General)
OTHER
PROTECTIVE GLOVES
None required
EYE PROTECTION
None required
OTHER PROTECTIVE EQUIPMENT
Special precaution not needed in normal handling or fitting of sheet
TX hfilow)
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
drilled, sawed, sanded.
ground or subiected to any other dust producing process, dust level other precautions nofc to exceed 10 MG/M . (Nuisance Dust)
PAGE (2)
GPO I 34*1 tO
Form OSHA-20
My 72
UTEX 000308