Document NGz7DLVO1m3kMwnO9RvY1kEzy

Cconoco) Interoffice Communication >* ..........V.&Jifl i-t-y To Distribution^ .rf t' From Tom Grumbles Date November 2, 1982 Subject MATERIAL SAFETY DATA SHEETS J*." Enclosed is a draft MSDS for CA-514 and a draft MSDS for Cresylic Acids in general. CA-514 is a high-volume blend that warrants a single sheet. However, after discussions with several of you 1 feel the remaining blends can be handled with a single sheet. (An USDS jhea already, been prepared fdr CA-510.) Please review these sheets and return comments to me by November 17. Thomas G. Grumbles ajo Enclosure Distribution: Bill Broddle Hank Pitera George Haberman Chuck Muth Dr. Drumwright Bill Groves Joe Ledvina Michele Malloy Susan Litzau _* i. ipu-27 MATERIAL SAFETY DATA SHEET C noco Chemicals 5 Graanway Plaza East P.O.B x 2197 Houston, Taxaa 77001 1. PRODUCT IDENTIFICATION MANUFACTURER'S NAME Conoco Chemicals Company ADDRESS 191 Doremus Avenue, Newark, Nj TRADE NAME SYNONYMS Conoco CA- 514 Cresylic Acid REGULAR TELEPHONE NO. (201) 344-3800 EMERGENCY TELEPHONE NO. (318) 491-5142 2. HAZARDOUS INGREDIENTS I MATERIAL OR COMPONENT % 2/4, 2/3, 2/5 Xylenols and Trlmethylphenols <28 HAZARD DATA < 2,6 Xylenol o-Cresol 37 ^36 3. PHYSICAL DATA BOILING POINT (F) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR 376-441 ----------------------------- 1 SPECIFIC GRAVITY(H20=1) 1.028 PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( Butyl Acetate = 1) 17 Trace MaTING POINT 7 F Sweet Tarry Odor; Liquid 4. FIRE AND EXPLOSION DATA FLASH POINT (TEST METHOD) ,,, ,, 0, OKA 210 F PM AUTOIGNITION TEMPERATURE FLAMMABLE LIMITS IN AIR. % BY VOL LOWER UPPER EXTINGUISHING MEDIA Water (fog or spray), foam, dry chemical, or CO2. SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL HRE AND EXPLOSION HAZARD This product is combustible. Wear self-contained breathing apparatus and full protective clothing. Cool tank with water if exposed to fire. Emits toxic fumes when heated. 5. HEALTH HAZARD INFORMATION FIRST AID Immediately begin flushing with large amounts of water and continue at least EYES: for 15 minutes while transporting for emergency medical attention. SKIN: Remove contaminated clothing. Immediately flush with large amounts of water, then wash affected areas with soap and water. Isopropanol can be used to further remove phenol^. Seek medical attention as soon as possible. INHALATION: Remove from exposure. Administer O2, by nasal cannulae if available. Administer artificial respiration if breathing has stopped. Seek immediate medical attention. Drink large amounts ot water or weak sodium bicarbonate solution. Do not induce INGESTION; vomiting, if spontaneous vomiting occurs, precautions should be taken to avoid asDiration. Seek immediate medical attention. NATURE OF HAZARD EYES: Causes severe burns. SKIN: Causes severe burns. Readily absorbed through the skin resulting in systemic toxicity. Skin exposures can be fatal. INHALATION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea, and vomiting. INGESTION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea, and vomiting. CNS depression may occur. EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Local skin burns. - ^ .. ; 'TV '* . CHRONIC OVEREXPOSURE: Dermatitis and chronic poisoning affectirig'tfi^teritriP nervous system, liver, and kidnev. THRESHOLD LIMIT VALUE (TLV) None established for this specific compound. Recommended: ACGIH 1981 TLV for cresol (and isomers) 5.0 ppm (22 mg/m3) 8-hour, time-weighted average (skin). TOXICITY DATA SKIN CONTACT* This specific product has not been tested for its toxic properties. How- ever' c*?ta on a s'm'*ar product, plus literature data on individual constit uents, indicate moderate acute oral and dermal toxicity and severecorrosive contact irritation. EYE CONTACT: See above. INHALATION: See above. INGESTION: See above. SPECIAL PRECAUTIONS: 6. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY Not applicable. INCOMPATIBILITY Alkali metals. HAZARDOUS DECOMPOSITION PRODUCTS Not applicable. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur. VENTILATION REQUIREMENTS Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL): Full face organic vapor cartridge or supplied air for high concentrations. EYE: Chemical safety goggles or face shield with goggles. GLOVES: Use rubber gloves to prevent skin contact, OTHER CLOTHING AND EQUIPMENT: Aprons, boots, etc. should be used where needed to prevent skin contact. Full slicker suit may be required where exposure is likely. ------------------------------------------------------------------------------------------------------------------ yEW-2^4735 9. SPECIAL PRECAUTIONS HAZARD CLASSIFICATION INFORMATION IMCO HAZARD CLASS AND NUMBER Class 8.0 US DOT CLASSIFICATION DOT: Corrosive UN NUMBER 1760 EEC DANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBER EEC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 1300-71-6 Xylenols 95-48-7 0-cresol TRANSPORTATION AND STORAGE HAZARD WASTE NO. U054 USUAL SHIPPING CONTAINERS Tank Cars, Tank Trucks, Drums ELECTROSTATIC ACCUMULATION HAZARD STORACE7TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LOADING/UNLOADING TEMPERATURE VISCOSITY AT LOADING/ UNLOADING TEMPERATURE HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE Stainless Steel Glass Lined Heresite Lined Carbon Steel--for short periods if kept dry. UNSUITABLE Brass and Copper--cause rapid discoloration. THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPUH) FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR IN|URY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. MARCH 1982 UEV-2747 CH-180 conoco MATERIAL SAFETY DATA SHEET C n c Chemicals 5 Greenway Plaza East H ust n, Texas 77001 1. PRODUCT IDENTIFICATION MANUFACTURER'S NAME Conoco Chemicals Company ADDRESS 191 Doremus Avenue, Newark, NJ TRADE NAME SYNONYMS ConOCO Cre3yllc Acid Cresylic Acid REGULAR TELEPHONE NO. (201) 344-3800 EMERGENCY TELEPHONE NO. (318) 491-5142 2. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT This product is a mixture of phenol, cresol, xylenol isomers, and tri-methyl phenols % HAZARD DATA 3. PHYSICAL DATA BOILING POINT (F) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR 360F-455F SPECIFIC GRAVITY(H]0 =1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( Butyl Arefate = 1) Trace MaTING POINT Sweet Tarry Odor; Liquid 1.01-1.04 17 4. FIRE AND EXPLOSION DATA FLASH POINT (TEST METHOD) > 17 ? F PM 1 172 AUTCMGNmON TEMPERATURE FLAMMABLE LIMITS IN AIR. % BY VOL LOWER UPPER EXTINGUISHING MEDIA SPECIAL HRE FIGHTING PROCEDURES UNUSUAL HRE AND EXPLOSION HAZARD Water (fog or spray), foam, dry chemical, or C02. This product is combustible. Wear self-contained breathing apparatus and full protective clothing. Cool tank with water if exposed to fire. Emits toxic fumes when heated. 5. HEALTH HAZARD INFORMATION FIRST AID Immediately begin flushing with large amounts of water and continue at least EYES: for 15 minutes while transporting for emergency medical attention, SKIN: Remove contaminated clothing. Immediately flush with large amounts of water, then wash affected areas with soap and water. Isopropanol can be used to further remove phenol^. Seek medical attention as soon as possible. inhai ATION- Remove from exposure. Administer O2, by nasal cannulae if available. inhalaiiuin: Administer artificial respiration if breathing has stopped. Seek immediate medical attention. Drink large amounts of water or weak sodium bicarbonate solution Do not induce INGESTION: vomiting. If spontaneous vomiting occurs, precautions should be taken to avoid ______________________ aspiration. Seek immediate medical attention. NATURE OF HAZARD EYES: Causes severe burns. SKIN: Causes severe burns. Readily absorbed through the skin resulting in systemic toxicity. Skin exposures can be fatal. INHALATION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea, and vomiting. INGESTION: Corrosive. Causes burning of mouth and throat, abdominal pain, nausea, and vomiting. CNS depression may occur. , EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Local skin burns. CHRONIC OVEREXPOSURE: Dermatitis and chronic poisoning affecting the central nervous system, liver, and kidney.__________________ THRESHOLD LIMIT VALUE (TLV) None established for this specific compound. Recommended: ACGIH 1981 TLV for cresol (and isomers) 5.0 ppm (22 mg/m3) 8-hour, time-weighted average (skin). TOXICITY DATA cviki mwTAfT. kin LUNiAi.1: This specific product has not been tested for its toxic properties. How- ever' ^ata on a sim'*ar product, plus literature data on individual constituents, indicate moderate acute oral and dermal toxicity and severecorrosive contact irritation. EYE CONTACT: See above. INHALATION: See above. INGESTION: See above. SPECIAL PRECAUTIONS: yEV-274"1 o. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY Not applicable. INCOMPATIBILITY Alkali metals.________________________ HAZARDOUS DECOMPOSITION PRODUCTS Not applicable. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur. 7. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Ventilate area. Sawdust, vermiculite, or sand may be used to absorb the spill. Pick up mechanically. Use personal protective equipment as appropriate. NEUTRALIZING CHEMICALS 2 to 5 percent solution of sodium hydroxide. WASTE DISPOSAL METHOD i Biological oxidation landfill or incineration according to established federal procedures. 8. SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS Ensure that ventilation is adequate to maintain concentration in air less than 5 ppm. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT________________ RESPIRATORY (SPECIFY IN DETAIL): Full face organic vapor cartridge or supplied air for high concentrations. EYE: Chemical safety goggles or face shield with goggles. GLOVES: Use rubber gloves to prevent skin contact. OTHER CLOTHING AND EQUIPMENT: Aprons, boots, etc. should be used where needed to prevent skin contact. Full slicker suit may be required where exposur is likely. VEV-274739 9. SPECIAL PRECAUTIONS HAZARD CLASSIFICATION INFORMATION IMCO HAZARD CLASS AND NUMBER Class 8.0 US DOT CLASSIFICATION DOT: Corrosive UN NUMBER 1760 EEC DANGEROUS SUBSTANCE CLASSIHCATION ADR CLASS NUMBER EEC SPECIAL RISKS AND SAFETY ADVICE | CAS NUMBER 1300-71-6 Xylenols 108-95-2 Phenoli HAZARD WASTE NO. 1319-77-3 cresols 26998-80-1 trinn thyl phenols TRANSPORTATION AND STORAGE U054 USUAL SHIPPING CONTAINERS Tank Cars, Tank Trucks, Drums ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LOADING/UNLOADING TEMPERATURE VISCOSITY AT LOADING/ UNLOADING TEMPERATURE HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE Stainless Steel Glass Lined Heresite Lined Carbon Steel--for short periods if kept dry. UNSUITABLE Brass and Copper--cause rapid discoloration. THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMACE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. MARCH 1M2 .<E'v'-2747' CH-1M