Document NGyBo0N7Lv1VBb1a3vL7LMqZg

PAGE 1 I MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION PLASTICS & ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 EMERGENCY PHONE NUMBERS. SAFETY/HEALTH. (914) 347-4700 AFTER HOURS . (800) 334-9481 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME). TINUVIN P FAMILY/CHEMICAL NAME. 2-( 2'-HYDROXY-5'-METHYLPHENYL)BENZOTRIAZOLE CAS REG. NO. 2440-22-4 PRODUCT TYPE. UV ABSORBER IMPORTANT. PLEASE NOTE-. REVISION 05 - SECTION VI REVISED. XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X x FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X x ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THE WIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE AND EFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX HAZARD STATEMENT . xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. x X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx SECTION II-HAZARDOUS INGREDIENTS NONE KNOWN TINUVIN P DO 087093 CONFIDENTIAL PAGE ` 2 SECTION III-PHYSICAL DATA APPEARANCE. YELLOW GRANULES ODOR. ODORLESS. BOILING POINT. NOT APPLICABLE. MELTING POINT. 128-132C DECOMPOSITION TEMPERATURE. >2Z0C. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. <0.2 `4 VAPOR DENSITY: NOT APPLICABLE. VAPOR PRESSURE. AT 60C, CA. 1.1 X 10C-6) SOLUBILITY IN WATER: AT 25C, INSOLUBLE PH. NOT APPLICABLE. SPECIFIC GRAVITY. CA. 1.4 (H20 = 1) CMM HG) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 401F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER: NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER: NOT DETERMINED. EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS. DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. SECTION V-REACTIVITY DATA STABILITY. STABLE. INCOMPATIBILITY: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES. HAZARDOUS POLYMERIZATION: TINUVIN P DO 08709A PAGE 3 WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE. DERMAL, INGESTION, AND INHALATION. THRESHOLD LIMIT VALUE. NONE ESTABLISHED. ORAL LD50. (RATS) >10,000 MG/KGj (MICE) >5000 MG/KG DERMAL LD50 > (RABBITS) >1000 MG/KG SKIN IRRITATION. (RABBITS) NON-IRRITATING. PHOTOTOXICITY. (HUMANS) NO PHOTOTOXICITY NOTED IN 10 SUBJECTS. EYE IRRITATION. (RABBITS) MINIMAL (DRAIZE SCORE 1.7/110) SENSITIZATION. RIPT (HUMANS) NO SENSITIZATION NOTED. THERE ARE SOME LITERATURE REFERENCES INDICATING SENSITIZATION REACTIONS BY PEOPLE EXPOSED TO COSMETIC FORMULATIONS CONTAINING THIS CHEMICAL. TO OUR KNOWLEDGE, SUCH REACTIONS HAVE NOT OCCURRED DURING INDUSTRIAL USAGE. INHALATION LC50. (RATS) >163 MG/L AIR FOR A 1.2-HOUR DUST EXPOSURE. TERATOGENICITY: SEGMENT II (RATS, MICE). NO EVIDENCE OF TERATOGENIC OR EMBRYOTOXIC EFFECTS. MUTAGENICITY. AMES TEST: NEGATIVE NUCLEUS ANOMALY TEST (CHINESE HAMSTER). NO EVIDENCE OF MUTAGENIC EFFECTS. SUBCHRONIC ORAL FEEDING STUDIES. DURING A 90-DAY FEEDING STUDY IN RATS, TOXIC ALTERATIONS WERE PRODUCED IN THE KIDNEY AND LIVER AT THE HIGHER DOSE LEVELS, WITH A NO OBSERVABLE EFFECT LEVEL (NOEL) OF 145-162 MG/KG/DAY. SIGNS AND SYMPTOMS OF EXPOSURE-ACUTE. NO IDENTIFIED HEALTH EFFECTS. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC. NO EXPECTED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. NONE KNOWN. EMERGENCY AND FIRST AID PROCEDURES-EYES. FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN. WASH WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION. IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION. TINUVIN P 087095 C0NFrDFNT'TAL PAGE ' 4 REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER WASH CONTAMINATED CLOTHING PRIOR TO REUSE. ________________________ SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES* PREWET MATERIAL WITH WATER TO AVOID DUST FORMATION. SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. WASTE DISPOSAL METHODS* DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATION* LOCAL EXHAUST RECOMMENDED, MECHANICAL EXHAUST ACCEPTABLE. PROTECTIVE GLOVES* WEAR IMPERVIOUS GLOVES AS A STANDARD HANDLING PRACTICE. EYE PROTECTION: IN CASES WHERE THERE IS LIKELIHOOD OF EYE CONTACT, WEAR CHEMICAL GOGGLES. RESPIRATORY PROTECTION: USE NIOSH APPROVED DUST MASK, IF REQUIRED. OTHER PROTECTIVE EQUIPMENT* WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HANDLING PRECAUTIONS* IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, HANDLE WITH CARE AND AVOID UNNECESSARY PERSONAL CONTACT. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST. USE ONLY WITH ADEQUATE VENTILATION . FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENE* WASH THOROUGHLY AFTER HANDLING. SECTION X- REGULATORY INFORMATION DOT CLASS: NOT REGULATED. DOT NUMBER: NONE. RCRA STATUS: NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). CERCLA STATUS: NOT LISTED. TINUVIN P DO 087096 CONFIDENTIAL 'PAGE * 5 TSCA INVENTORY STATUS: CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. ISSUE DATE: 06/13/86 REVISION: OSC FOR FURTHER INFORMATION, PLEASE CONTACT: BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. TINUVIN P DO 087097 CONFIDENTIAL PAGE 1 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (91A) 785-2000 1 | EMERGENCY PHONE NUMBER. 1 1 (800) 888-8372 1 1 1 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME). TINUVIN 770 FAMILY/CHEMICAL NAME. BIS(2,2,6,6-TETRAMETHYL-A-PIPERIDYL)SEBACATE PRODUCT TYPE. HINDERED AMINE LIGHT STABILIZER (HALS) IMPORTANT. PLEASE NOTE. REVISION 10 - SECTION IX REVISED. xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X X FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THEWIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx HAZARD STATEMENT . xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX SECTION II-HAZARD0U5 INGREDIENTS ___________________________ SPECIFIC CHEMICAL NAME. BIS(2,2,6,6-TETRAMETHYL-A-PIPERIDINYL)DECANEDIOATE CAS REG. NO. 52829-07-9 TINUVIN 770 DO 087098 CONFIDENTIAL PAGE 2 COMMON NAME) TINUVIN 770 PERCENTi PRODUCT PER SE WAS TESTED EXPOSURE LIMITS: OSHA PEL. NONE ESTABLISHED ACGIH TLV: NONE ESTABLISHED CIBA-GEIGY INTERNAL. TWA 0.1 MG/CU. M. CARCINOGENICITY. THIS CHEMICAL IS NOT CONSIDERED TO BE CARCINOGENIC BY NTP, IARC OR OSHA. ______________ SECTION III-PHYSICAL DATA ________________________ APPEARANCE. WHITE TO OFF-WHITE POWDER. ODOR. NO DISCERNABLE ODOR. BOILING POINT. NOT DETERMINED. MELTING POINT. 81-86C DECOMPOSITION TEMPERATURE. >220C. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. < 0.5'/.. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE. AT 20C, CA. 1 X 10(-10) (MM HG) SOLUBILITY IN WATER. AT 25C, INSOLUBLE PH. NOT DETERMINED, BUT MODERATELY BASIC. SPECIFIC GRAVITY. CA. 1.05 (H20 = 1) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. >302F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER. NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. NFPA CODE. NONE. EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: THE PRODUCT CAN FORM AN EXPLOSIVE DUST/AIR MIXTURE. AVOID TINUVIN 770 DO 087099 CONFTDFNTTAL PAGE 3 DUST FORMATION AND CONTROL IGNITION SOURCES; EMPLOY GROUNDING, VENTING AND EXPLOSION RELIEF PROVISIONS IN ACCORD WITH ACCEPTED ENGINEERING PRACTICES IN PROCESS OPERATIONS CAP ABLE OF GENERATING DUST AND/OR STATIC ELECTRICITY. SECTION V-REACTIVITY DATA STABILITY STABLE. INCOMPATIBILITY! NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS! THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES. HAZARDOUS POLYMERIZATION! WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE! DERMAL, INGESTION, AND INHALATION. ORAL LD50: (RATS) 3700 MG/KG DERMAL LD50i (RABBITS) >3100 MG/KG SKIN IRRITATION! (RABBITS) MINIMAL (DRAIZE SCORE 0.5/8) EYE IRRITATION! (RABBITS) SEVERE (DRAIZE SCORE 52.3/110; 77.7/110, WITH CORNEAL CLOUDING PERSISTING AT 7 DAYS) SENSITIZATION! (GUINEA PIGS) NOT A SENSITIZER. RIPT (HUMANS) PRIMARY SKIN IRRITANT WHEN APPLIED NEAT. INHALATION LC50i (RATS) >0.96 MG/L AIR FOR A 4-HOUR DUST EXPOSURE WITH ESSENTIALLY ALL PARTICLES >10 MICRONS. MUTAGENICITY! AMES TEST: NEGATIVE SIGNS AND SYMPTOMS OF EXPOSURE-ACUTEi WARNING!! CAUSES SEVERE EYE IRRITATION; MAY CAUSE SKIN IRRITATION. MAY BE IRRITATING TO NASAL MEMBRANES AND RESPIRATORY TRACT. MAY LEAVE BITTER METALLIC TASTE IN MOUTH. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC< NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE! SKIN CONDITIONS. EMERGENCY AND FIRST AID PROCEDURES-EYESi IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKINi PROMPTLY WASH WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION: TINUVIN 770 DO 087100 confidential PAGE A IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATIONi REMOVE TO FRESH AIR. IF DIFFICULTY IN BREATHING, GIVE ARTIFICIAL RESPIRATION AND OXYGEN AS NECESSARY. EMERGENCY AND FIRST AID PROCEDURES-OTHERi WASH CONTAMINATED CLOTHING PRIOR TO REUSE. ________________________ SECTION VII-SPILL OR LEAK PROCEDURES ___ SPILL PROCEDURES: SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. THOROUGHLY FLUSH RESIDUE WITH WATER. WASTE DISPOSAL METHODS< INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD. (MODIFIED OECD SCREENING TEST): PARTIALLY BUT NOT READILY BIODEGRADABLE SEWAGE BACTERIAL TOXICITY: INHIBITORY CONCENTRATION ON THE RESPIRATION OF AEROBIC WASTE WATER BACTERIAi IC20 APPROXIMATELY 100 PPM; IC50, IC80 >100 PPM FISH TOXICITY: BLUEGILL, LC50 96H: A.A PPM RAINBOW TROUT, LC50 96 H: 13 PPM SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATION: USE LOCAL EXHAUST. PROTECTIVE GLOVES: WEAR GLOVES AS A STANDARD HANDLING PROCEDURE. EYE PROTECTION: WEAR CHEMICAL GOGGLES. RESPIRATORY PROTECTION: USE NIOSH APPROVED DUST MASK. AT HIGH TEMPERATURES, USE AN APPROVED RESPIRATOR FOR ORGANIC VAPORS, IF REQUIRED. OTHER PROTECTIVE EQUIPMENT: WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HMIS CODE: HEALTH : 3 FIRE = 1 REACTIVITY : HANDLING PRECAUTIONS: DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT INHALE DUST OR HEATED VAPORS. DO NOT TASTE OR SWALLOW. USE ONLY WITH ADEQUATE VENTILATION. DO NOT CAUSE DUSTING DURING HANDLING. HANDLE AS A MODERATE TO STRONG BASE. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: 0 TINUVIN 770 00 087101 CONFTOFNTTA| PAGE 5 KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENEi WASH THOROUGHLY AFTER HANDLING. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME< NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) 49 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASSi NONE. DOT NUMBER* NONE. RCRA STATUS* NOT A HAZARDOUS WASTE UNDER RCRA (AO CFR 261). CERCLA STATUS* NOT LISTED. SARA/TITLE III - TOXIC CHEMICALS LIST* THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 313 (40 CFR 372). TSCA INVENTORY STATUS. CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65* THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATION* THIS PRODUCT CONTAINS THE FOLLOWING * CHEMICAL NAME * BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDYL)SEBACATE CAS NUMBER * 528Z9-07-9 xxx PENNSYLVANIA RIGHT-TO-KNOW ACT. THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME . CAS NUMBER COMMON NAME . * COMMENTS * DECANEDIOIC ACID, BIS(2,2,6,6-TETRAMETHYL-4PIPERIDINYL) ESTER 52829-07-9 BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDYL) SEBACATE; INUVIN 770 NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. xxx T TINUVIN 770 DO 087102 CONFIDENTIAL PAGE 6 V ISSUE DATE. 0A/05/90 REVISION. 11C FOR FURTHER INFORMATION, PLEASE CONTACT. BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. TINUVIN 770 DO 087103 CONFIDENTIAL f PAGE 1 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION PLASTICS 8 ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 EMERGENCY PHONE NUMBERSi SAFETY/HEALTH. (914) 347-4700 AFTER HOURS < (800) 334-9481 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME): TINUVIN 765 FAMILY/CHEMICAL NAME: BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)SEBACATE, PRODUCT TYPE: HINDERED AMINE LIGHT STABILIZER IMPORTANT: MIXTURE PLEASE NOTE: REVISION 04 - SECTION VI REVISED. xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X * FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X * SPECIFICALLY INTENDED. BECAUSE OF THEWIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx HAZARD STATEMENT : xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS X * CHEMICAL UNDER THAT STANDARD. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX SECTION II-HAZARDOUS INGREDIENTS THE PRECISE COMPOSITION OF THIS MIXTURE IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE WILL BE PROVIDED TO TINUVIN 765 DO 0871,04 CONFTDFNTIAI PAGE 2 A PHYSICIAN OR NURSE IN THE EVENT OF A MEDICAL EMERGENCY. SPECIFIC CHEMICAL NAME-. BISCl,2,Z,6,6-PENTAMETHYL-4-PIPERIDINYL) SEBACATE, CAS REG. NO. 41556-26-7 COMMON NAMEi TINUVIN 765 MAJOR COMPONENT EXPOSURE LIMITS* OSHA PEL* NONE ESTABLISHED ACGIH TLVs NONE ESTABLISHED CARCINOGENICITY* THIS CHEMICAL IS NOT CONSIDERED TO BE CARCINOGENIC BY NTP, IARC, OR OSHA. COMMON NAME* TINUVIN 765 MINOR COMPONENT EXPOSURE LIMITS* OSHA PEL* NONE ESTABLISHED ACGIH TLV* NONE ESTABLISHED CARCINOGENICITY* THIS CHEMICAL IS NOT CONSIDERED TO BE CARCINOGENIC BY NTP, IARC, OR OSHA. ____________________ SECTION III-PHYSICAL DATA ____________________ APPEARANCE* PALE YELLOW VISCOUS LIQUID. ODOR* NO DISCERNABLE ODOR. BOILING POINT* NOT DETERMINED. MELTING POINT* <20C DECOMPOSITION TEMPERATURE* >325C EVAPORATION RATE* NOT APPLICABLE. PERCENT VOLATILE: NEGLIGIBLE. VAPOR DENSITY: NOT APPLICABLE. VAPOR PRESSURE* NOT DETERMINED. SOLUBILITY IN WATER* AT 25C, INSOLUBLE PH* NOT APPLICABLE. SPECIFIC GRAVITY: CA. 1.0 (H20 = 1) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT* 189F (PENSKY-MARTENS) COMBUSTIBLE LIQUID. FLAMMABLE LIMITS IN AIR-LOWER* NOT DETERMINED. TINUVIN 765 DO 087105 CONFIDENTIAL PAGE 3 FLAMMABLE LIMITS IN AIR-UPPER: NOT DETERMINED. NFPA CODEi NONE. EXTINGUISHING MEDIAi CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ____________________ SECTION V-REACTIVITY DATA STABILITY: STABLE. INCOMPATIBILITY: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE: DERMAL. ORAL LD50: (RATS) 3125 MG/KG SKIN IRRITATION: (RABBITS) MINIMAL (DRAIZE SCORE 0.47/8) EYE IRRITATION: (RABBITS) NON-IRRITATING. SENSITIZATION: (GUINEA PIGS) STRONG SKIN SENSITIZING POTENTIAL, WITH 20/20 ANIMALS SENSITIZED IN EPIDERMAL CHALLENGE. MUTAGENICITY: AMES TEST: NEGATIVE SIGNS AND SYMPTOMS OF EXPOSURE-ACUTE: WARNING! MAY CAUSE SKIN SENSITIZATION OR OTHER ALLERGIC RESPONSES. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC: NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ALLERGY, ECZEMA. EMERGENCY AND FIRST AID PROCEDURES-EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN: PROMPTLY REMOVE FROM SKIN WITH DRY CLOTH FOLLOWED BY THOROUGH WASHING WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION: IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET TINUVIN 765 DO 087106 CONFIDENTIAL PAGE A MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION: REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHERi PROMPTLY REMOVE AND WASH CONTAMINATED CLOTHING PRIOR TO REUSE. SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES! ABSORB ONTO SAND OR OTHER ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. WASTE DISPOSAL METHODSi DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS; INCINERATION RECOMMENDED. EFFLUENT DATA-BOD: OECD SCREENING TEST 301Ei PARTIALLY BIODEGRADABLE BIOACCUMULATIONi JAPANESE MITI TEST: LOW ACCUMULATION FACTOR. FISH TOXICITY: BLUEGILL, LC50 96 Hi 0.97 PPM (DYNAMIC TEST) RAINBOW TROUT, LC50 96 H: 7.9 PPM (STATIC TEST) INVERTEBRATE TOXICITY: DAPHNIA MAGNA, EC50 48 H: 20 PPM SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL EXHAUST RECOMMENDED. PROTECTIVE GLOVES: NEAR RUBBER OR PLASTIC GLOVES. EYE PROTECTION! WEAR CHEMICAL GOGGLES IF EYE CONTACT IS POSSIBLE. RESPIRATORY PROTECTION: AT HIGH TEMPERATURES, USE NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS, IF REQUIRED. OTHER PROTECTIVE EQUIPMENT: WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HANDLING PRECAUTIONS! DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT INHALE MISTS OR HEATED VAPORS. DO NOT TASTE OR SWALLOW. USE WITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS! KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENE: WASH THOROUGHLY AFTER HANDLING. TINUVIN 765 DO 087107 CONFIDENTIAL PAGE 5 SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME) COMBUSTIBLE LIQUID, N.O.S. (NOT APPLICABLE IN CONTAINERS HAVING A RATED CAPACITY OF 110 GALLONS OR LESS.) DOT CLASSi COMBUSTIBLE LIQUID. DOT NUMBER. NA 1993 RCRA STATUS; NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). CERCLA STATUS; NOT LISTED. TSCA INVENTORY STATUS; CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. ISSUE DATE; 06/13/86 REVISION; 04C FOR FURTHER INFORMATION, PLEASE CONTACT; BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. TINUVIN 765 DO 0871.08 CONFTDFNTIAl face: Jl Hate r i a l safety data sheet TRAJ)E NAME '. TINUVIN 326 CIBA-CEICY CORPORATION PLASTICS & ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (914) 347-4700 FAHtLY/NAME : 2- (3 ' -TERT-BUTYL-2 1 HYDROXY-5 1 METHYLPHENYL >'5-CHL0R0BENZOTRIAZOL E PRODUCT TYPE: UV ABSORBER ulaical data : APFEARAHCE AND ODOR: PALE YELLOW P0WDER . 0b0Ri...ESS DECO HP 0 SIT10 N T E H P E R A T.J R E : f 320C MELTING POINT. I S'" i *t `i P h i 0 E N I V 0 i... A TIL d.05% MAX, SPECIFIC GRAVITY: CA, i.32 (H20 - 1) SOLUBILITY IN WATER: AT 25C, INSOLUBLE VAPOR PRESSURE: A)' 20 C, CA, 5,6 X 10<-9> <MM HG) I'E AfjfD EXPLOSION HAZARD DATA : "XTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER HIST, "IRE ! FIG H TIN G P R 0 C E D ij R E S - S P E CIA L : USE SELF-CONTAINED BREATHING APPARATUS, :N US UAL FIRE AND EXPLOSION HAZARDS: DECOMPOSITION AND COMBUSTION PRODUCTS HAY BE TOXIC. TINUVJN 326 DO 087109 CONFIDENTIAL I REACTIVITY DATA : STABILITY: STABLE! HAZARDOUS DECOMPOSITION PRODUCTS: BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES AND CHLORINE COMPOUNDS. HAZARDOUS POLYMERIZATION: WILL.. NOT OCCUR. HEALTH HAZARD DATA : THRESHOLD LIMIT VALUE: i NONE ESTABLISHED ORAL. LD3G: (MICE 5: RATS) >3000 MG/KG DERMAL LD30: ! (RATS) >2000 MG/KG SKIN IRRIGATION: tRATS) FOR A 6-DAY PER WEEK 4 WEEK APPLICATION OF 0.4 OF A 5% SUSPENSION, THERE WAS NO LOCAL IRRITATION OR SYSTEMIC TOXICITY. EYE IRRITATION (RABBITS) MINIMAl <DRAIZE SCORE <i/1i0) NSITIZATION: R1PT (HUMANS) NOT AN IRRITANT OR SENSITIZER AT i 0.3% IN DMP. INHALATION LX50: : (Ri-.TS) >0.27 ilG/L AIR FOR A 4HOUR DUST EXPOSURE EMERGENCY AND FIRST AID PROCEDURES--EYES: ' FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. ' CALL A PHYSICIAN. E [i E R G E N C Y A N D FIR S T AID P R 0 C E D U R E S - S K IN . : WASH WITH MILD SOAP AND WATER, EMERGENCY AND FIRST AID PROCEDURES -INGESTION:' IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. INDUCE VOMITING. CALL A PHYSICIAN. EMERGENCY AND FIRST AID PROCEDURES INHALATION: REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER: ` WASH CONTAMINATED CLOTHING PRIOR TO REUSE. ML SPILL OR LEAK PROCEDURES : SPILL PROCEDURES: SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR : DISPOSAL, WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. ! THOROUGHLY FLUSH RESIDUE WITH WATER. W A S1" E DIS P 0 S A L M E T H 0 D S : BURY OR INCINERATE IN APPROVED SITE OR FACILITY IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. : TINUVIN 326 DO 087110 CONFIDENTS . 4: PAG!" 3 v A RA STATUS: NOT A HAZARDOUS WASTE." UNDER RCRA (40 CFR 261)* SPECIAL PROTECTION INFORMATION : ! VENTILATION: i use: local exhaust* PROTECTIVE GLOVES: ; WEAR GLOVES AS A STANDARD HANDLING PROCEDURE* EYE PROTECTION: S WEAR SAFETY GLASSES OR GOGGLES* RESPIRATORY PROTECTION: USE NIOSH APPROVED DUST MASK, IF REQUIRED. SPECIAL PRECAUTIONS : HiANDi... ING , SHIPPING AND ST0RING PRECAUTIONS : . IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, HANDLE WITH CARE AND AVOID UNNECESSARY PERSONAL CONTACT* AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST* KEEP CONTAINER CLOSED WHEN NOT IN USE AND DURING TRANSPORT. USE ONLY WITH ADEQUATE VENTILATION. WASH AFTER HANDLING, AND BEFORE EATING, DRINKING OR SMOKING* ' FOR INDUSTRIAL USE ONLY* ISSUE DATE: A7/26/3C FOR' FURTHER INFORHAVION, PLEASE CONTACT: BRUCE SCHWEHMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT, HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMP!..] ED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN * TINUVIN 326 DO 087111 CONFIDENTIAL page' I` i M A TER l A L SAFETY D A T A S H E E T 1 CIBA-GEIGY CORPORATION mi PLASTICS & ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (914) 347-470 TRADE NAME: jlNUVIN 327 FALflLY/NAME : ; 2 < 3'5 ' -DI-TERT-BUTYL-2 ' --HYDROXYPHENYL >-5CHLOROBENZQTRIAZOLE PRODUCT TYPE: UV ABSORBER PH ,.... Ic;Al... DATA ! APPEARANCE AND ODOR; ! PALE YELLDU POWDER. ODORLESS DECOMPOSITION TEMPERATURE: j >220t MELTIMO POINT: i54-1 ESC PERCENT VOLATILE. . <*5 SPECIFIC GRAVITY: : CA. 1 * 26 ( H20 - i) SOLUBILITY IN WATER: i AT 25 C, INSOLUBLE VAPOR PRESSURE: i AT 2C, CA 8*2 X 1 (-9) (MM FIRE AND EXPLOSION HAZARD DATA HG) FLASH POINT: : 4I53F (MARKUSSON) EXTINGUISHING MEDIA: ! CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER EIR E FIG H TING P R 0 C E D U R E S - SPECIAL.: : USE JELF- C0NT AINED BRE ATHING APP AR ATUS . ' USUAL FIRE AND EXPLOSION HAZARDS: MIST * TINUVIN 327 00 087112 CONFIDENTIAL PAtjE DECOMPOSITION AND COMBUSTION PRODUCTS' MAY BE TOXIC, REACTIVITY DATA : STABILITY: ! STABLE HAZARDOUS DECOMPOSITION PRODUCTS: BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES AND CHLORINE COMPOUNDS, HAZARDOUS POLYMERI2ATION: ; WILL NOT OCCUR, HEALTH HAZARD DATA : ! THRESHOLD LIMIT VALUE: ! NONE ESTABLISHED ORAL LDSv): | HI ATS, MICE) >5000 MG/KG SKIN IRRITATION: < RABBITS) NONE v BRAIZE SCORE 0/8} <RATS) 5% SUSPENSION IN GUM ARABIC APPLIED DAILY FDR 4 WEEKS RESULTED IN NO ,...GCAL IRRITATION OR SYSTEMIC TOXIC EFFECTS, EYE IRRITATION: (R A BEITS) N0Nu IDR AIZ E S C 0 R E 0/110) ' ' \ S I i j L A T10 N RIPT 'sHUMANS) NOT A PRIMARY IRRITANT OR SENSITIZER WHEN APPLIED TO 55 SUBJECTS AS A 0.5% MIXTURE IN DHP , ONE | SUBJECT SHOWED A RESPONSE CHARACTERISTIC OF THAT PRODUCED - A F A"TIG UIH G A G E N T , INHALATION LC50 (RATS) >0.75 MG/L AIR FOR A 4-HOUR EXPOSURE . WITH APPROX, 88% OF PARTICLES <7 MICRONS EH REGENCY AND FIRST AID PROCEDURES-EYES: PLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, CALL A PUT SI ClAw* EMERGENCY AND FIRST AID PROCEDURES-Si< IN: 1 WASH WITH MILD SOAP AND WATER, EMERGENCY AND FIRST AID PROCEDURES-INGESTION: i IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. INDUCE VOMITING, CALL A PHYSICIAN, EMERGENCY AND FIRST AID PROCEDURES-INHALATION: 5 REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES--OTHER: ; WASH CONTAMINATED CLOTHING PRIOR TO REUSE, BY SPIiLi... OR LEAK PROCEDURES . SPILL PROCEDURES. i SWEEP DR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR ; DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. : THOROUGHLY FLUSH RESIDUE WITH WATER, : 7INUVIN 327 DO 087113 CONFIDENTIAL f PAGE ; T E DI S P 0 S A L i'i E T H 01) S : " BURY OR INCINERATE IN APPROVED SITE OR FACILITY IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ItCRA STATUS: NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). SPECIAL PROTECTION INFORMATION : VENTILATION: USE LOCAL EXHAUST FOR DUSTY USE CONDITIONS. PROTECTIVE GLOVES: . WEAR GLOVES AS A STANDARD HANDLING PROCEDURE. EYE PROTECTION: WEAR SAFETY GLASSES OR GOGGLES. RESPIRATORY PROTECTION: USE NIOSH APPROVED DUST MASK, IF REQUIRED. SPECIAL PRECAUTIONS ; i HANDLING, SHIPPING AND STORING PRECAUTIONS: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE. HANDLE WITH ^ CARE AND AVOID UNNECESSARY PERSONAL CONTACT. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. : AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST. KEEP CONTAINER CLOSED WHEN NOT IN USE AND DURING TRANSPORT. USE ONLY WITH ADEQUATE VENTILATION. : WASH AFTER HANDLING, AND BEFORE EATING, DRINKING OR SMOKING. ! FOR INDUSTRIAL USE ONLY. ISSUE DATE: 0 7/26/03 FORI FURTHER INFORMATION, PLEASE CONTACT: BRUCE SCHWEMMER I THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY i: IN|D EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. TINUVIN 327 DO 087114 CONFIDENTIAL