Document NGrK9nn4kYn702a3xZ5862aJV

Qn [iCrteeteh it Anr at: Reporter RCSummary Antepeak Name Pron 5p.r13a0zpro [sora Pros? scrros [oronz Pron z Pros2 | PFDoA 2 5.130FD0A pPeeraenrs [ar expects ea Voted? ce ssa | own [rmwass | |w ame[|m woow || osza woaw |mse| I sas | ve o ost weas | we ww ssa ww ors enen wee | wweo | 2I00 om | | a7ess | 163950 No 0.28 [eras [ee[we | oa | emsernewe |woenaswn |w| aosm | 2 Page 2700202 LS Gumeia Analytical Services PrCinrteead:ted14w/i0t2h/A2n0a1l0y6s:t4R1:p0o0rtPeHr `Quantitative Peak rg A x 413P.0F1O6A8T.00a o Baseline o Missed Review TE |= A zl 411730C3-7P2FO0A08 | oBaselnecMssed PFC 5.0ppb = I TM = A io I I 463.P0E14N1A9.T0 0a 4661.03/C42-3P.0FNADa | Baseline oMissed | Baseline: Missed . Lo | = I I I" tool 499.P0F18O0S.01 Da Baseline Missed | 5031.30C1-80P.F0OS0.a oBaselinecMssed | 513.0P/F46O9A.10 0a cBaselinec Missed | oBa5s1e15l30iCn4-e7P0oF0OMAiDsased wap woes wan2g ig - i] HE 5 iz4 563P0FU5R1A801 Da Baseline o Missed | 51635C02-7P0F0UA0a Baseline cMssed | 509p.F0/O8S00T 0a Baselines Missed | 50133,0C/-8P0F.0OSDa cBaseline c Missed A io i = i al ul _ = a I 6130P/F5D6O9A01 0a Baseline o Missed | 615103/C1-P6F3D0OA0a Baseline cMssed | 663P.E06T1A9.100a cBaselnecMissed | 61153.C0-/P1F6DO90A.a0 Baselinec Missed o 7 i ih : ul 713.P0F6T6E9A.10 0a Baseline c Missed | 61135C.-0PF1D609DA.a c Baseline o Missed O Before O After Page 28 of 242 238 3 olumbia AnalyticalServices- PriCnrteead:ted14w0it2h/2A0na1l0yB6i:4R1e:p0o0rPteMr TL lon Ratio Confirmation T= = = fEd i=bol i [3 oT PFC 5.0ppb ]7 =7 JE og Se-- i : 413P0F/3O6A9200a 4630PF2N1A9200a BaseclMiisnseed | BaselaMiisnseed | 499P.F0O99S020a Baseline cMissed| 513P.F02O62A80.a0 cBaseline Missed | Wrong Peak Wong Peak Wrong Peak Wong Peak | wl 3| 4 J i 4 El i i= ofls oo "3 oo 563P0F/U2R6A902 Da 509P.0F/O99S.20 Da BaWsreloinnegcPMesasked | oBa<sWerloinnegcPMeiasksed | { 613.P0F/D16O9A.02 0a 563P0/F16T920 Da BaWsreloinneg PMeiasksed| BaWserloinnegcPMeiasksed 71P3F0T/O1A62900a BasWerlionnegoPMeiasksed 0 Before 0After Page 29 of 242 259 /4 Columbia 3 AnalyticalServices" PrCinrteeadt:ed14w/i0t2h2A2n0a1l0y/s6t:4R1:b0o0rtPeHr PDraotjaecFtile 0Ev2a0n8'1s05P\rCeaclLioonPgFwCifs Acquisition Method _PFCiinelexLdoanmg ARelsguolrtitThamblUesed 208105 ampsong 195 nteliuan Instrument Name __API 5000 [SAcaqmuipstNioanmDeate | 7P8E7C20T10op65502 PIL I cova a6] `Acquisition Method _| PFCKnelex_donagm EC SampleType [Siang Dion Factor [100 | | SeamepleeCoPe mmegnt |-- -- ---- -- -- -- ee|eWei-- gntiovoum-- eJoo--e-- ee | Results Summary Analyte |Anayie RT Anais | ExpCons| Gale-Cone vo Name | (Expected Area | _(ngiml) | (ng/ml) 1360.36) | 13PFOA | 3016300| 1452100| ooo| 10200| 102 | No [P|r22as@ets| raceeva| awsrano| zstose|o tom| osm | toe = 13C.PFOS | 6896700| 8043100 tow |1|0 No | |Proar 3.34(3.34|) 13C-PFDA | 2127100 | 2332600 10.000 10.400 104 No | | runes 4.12(4.06) | 13C-PFUNA| 172090 1784200 10.000 | 11.000 10 | No PFDS1 | 4.12410) | 13C-PFOS 6895700 | 8526300 10.000 1080 | 108 | No PFDOA1 | 4764.63| 13CPFDOA | 225140 | 1336800 | 10000 | 11400 | 114 | No 529|5131CP4FD)OA | 225140 | 92540 | 10000 | 1700 | 17 | No PFTen1 | 574674 | 19CPFDOA|25140| Tino | 0000 | tise | 11s | Me 7 Aa = 2 rune Pa30ogf2e42 200 RCSummary Create win Analy}Reporter [s_1sc_prua | PFOA2 [prosz Er asm 0 | 33434 349340 No 412610 | 27ees00 | No wn 0.15 0.32 | 4 SAnoaulymtbiicazl Services" PrCirneteadted14w0it2h12An0a1l0ys6:f4R7B:p0o0rtPeIr : A 2 A E A Quantitative Peak Review :5 7 PFC 10ppb ] =----2m ca4s13e.Pi0F1nO16Ac91.a0s08ed | cB4a11s37eCl0-n3Pa7cF2MO0iA0sased | cBa4s6e3lP0iEn4Ne1cA9h01M0isased | |e rs 7 once Fi:d |:Cl EHi l CBa4s9e9Pi0Fn8Oe0oS.M01i0sases | cBa15s03e3Ci.-n0Pe1Fc0MO0iSDsased | B5a1s3ePl.i0Fn4eD6A91.hi0sased | B4a6s1e83l.iC0n-e4Pc2F0NMAiDsased le 2cl B5a1s51e.3l0iC4n-7eP0oF.0OMAi0sased : i il i Ba5s6elP2iF0nU5eN1Ac901Ma0ase | cB15a63s5Ce.0l-1nP2eF7c0U.MR0iAs0saes | oBa5s99eP.lF0nD8eS0c.10hi0sased | oped pen lms Bas50e1e 3i3.Cn0-e8Po0e F0GMSDisased L|C bioCf Lj=ll lioo CB6e1i3Pi0Fn1D5eO6Ac910as0aed | cB6a1s15e3lC0-n1Pe6Fc9Dt00iAs0saed | cB6a6s3e.Pi0E6n1Te9cA.M1is0s8ed | Ba6s1e15l30iC/n-1eP6F9D0MOiA0sased Ba7se1lP2iF0nT6ee6oA9TM0is0sed | B6as11e35lCi0-neP1Fc6DMO9iDAs0ased 0 Before O After 22 Page 320f 242 3 Columbia AnalyticalServices CrweithAanalty R7eepordter Printed: 1410212010 6:41.00PM fon Ratio Confirmation Ea] |=: a [i da PFC 10ppb 5i oT = cla fiLo 4 41B3a.0Ps3F6eO9cAl.2M0ii0snaseed | B4a63.sP01eF2N1lc8A.MZi0i0snsaeed | B4a99s.P0eF9Ol9So20iMiDnsaseed|<B5a13sP,0Fe1O2l.6AM9ii0s0nsaeed = Wrong Peak = Wrong Peak Wrong Peak Wrong Peak 0r i4 i ae fi 5 A i. ul bo 563P.0F12U69A.20 Da Baseline oMissed | 595P.F0D9S920 0a oBaselinecMissed | 613P0F/D1G60A02 0a Baseline Missed| 663.P0/E16T9.Z0 Da BaseliMinsseed WrongPeak WrongPeak < WrongPeak Wrong Peak i she f-- 71P3F0T/E1A62090a BasWerlionnegoPMeiasksed O Before 0 After Pa33ogf2e42 23 a`AS nalyts icalServices casi alig$ns Printed: 14/02/2010 6:41:00 PM Rweeorno totes T CImoeocmaT immoand [[SA Riemcusttic oomnwtsaaso sTFaSmPEs aCneToto0to o7n7sumr [So[smmSecoto~mm~eiroiusioiie Results Summary A p|Anorwmisoed nmaeton SToacmtoelvrTvoeims [s 5 m| TE wmowvobE re [om | Nrarmoeri | rans| (Expected) | ciohrer | oBAme| dAoreean | oo(ng/mL) | sew (ng/mL) | 92(%) | tooe! | fr[soronsts |am | a eros|s rsseo| evions| vont | smasn| nero 2000 woo | [=| rome |3 | 0| FFoorroasn1it [aaana||ssoia crorroosm||wteoin|| vmooon|| mmomm || wsom || m5r5 || nwee | oroont ort | | are| smn| cero| eros zen [ro | | aes wm | mom |waeo ||w9wo|wwe | error sear | ceroms| mem| wm| wwe | am | w; | we A LLievsers - ore sraz 8ASnahlyutimcaal Services PrCinrteead:ted14w1i0t2h7A20n1a0ly5s:t4R1p:0o0rtPeArL RCSummary Anat pe ame |e T RT(Epecte| d) Area Modified? = E CrCews| froSisc_prva S_130.P70S [romers {rrorosos oraz | smweamn || wmeew || wmos | 232259) No | 050 | | aanmoen||we|eeww | aaws | aemaans |wweew||w ww m|| [amen| wm | we | oz pa35gof2e42 2s 4 5olmbie AnalyticalServices Quantitative Peak Review Fa I-f Ed : A iE .- = iI Created with Analyspt.R1e0porter Printed: 14/02120106:41:00 PM PFC 20ppb Nl Im i7 413P0/F1O6A9.100a 41137C0-3P7F2O0A08 463.P0E1N41A9T.00a 461830C1-42P3F0RADa cBaseltnieon2c Missed | oBaselnnigeoMssed | R oBasm elneoMssed | -c Baselineeo aMissed i= i i - [Coll ii=oll 499P.0F/O80S.T0 Da 50133.0C/.8P0F.0OS0a 513.P0/F4O69A.10 Da 511530C4-7P0F0OADa cn Baseliy e Missed | oBasebluionneac M2is ssed | oBasetlainnegc Missed | c Basetgline o Miassed ol Lo il 3 |! i ic |A 563.P0R/5U19B.A0 T 0a 1635C.0-/2P7F0.U0NA0a 599P.F0O80S0T Da 50133.0C/-8P0.F0GSDa --cBVaseclioneac Mipesgsed | LoBmaselinec Missed | s Baseo liney cMissed | Baselionenao Missed - po I i i3 E io 613P0F1O5O6A90TDa 61153.C0-1P6F9D.O0A0a 662.P0E61T6A. 10a 61135C-0P1F6GO9DAa0 Baseline Missed | Baseline Missed | oBaselinecMissed | Baseline: Missed i il 713.P0F/T66E9A.0 0a 61153.C0-/P1F6Do90A.a0 < Baseline c Missed| c Baselinec Missed 0 Before O After Page 36 of 262 208  Soham Analytical Services PriCnrteead:ted14v1i0th2:A2n0a1l0y's8tp:4R11e1p0o0rtPeAAr | i lonRatio Confirmation |: Lh F wt \ 7 PFC 5 20ppb - Lfool Pi Aa - EEoC : ) fA _ B4a1s2e.Pl0iFn0Oe8A5.20Mi0s8sed | cB4a6s2e.Pl0Fn2N1eA8c.20Mi0ssed | oBa4s9e5Pl.iF0nO9eS8c20Mi0sased | oc B5a1se2Pli0Fn2OeA629M0is0sed Wiong Peak Wrong Peak Wrong Peak = Wiong Peak 2 i 3 ah 2 oof ls : | + EY i! sz | | 5B6a3seP0lFi2nU6eRc9A0M2i0sased | cBa5s9s9Pi0Rn1OeS9c820M0is8sed | oBa6s1e3Pl0Fi1Dn1eO6o3AM02i0sased | Ba6se6l2Pi0nFe/1cT26M8i0s08sed = Wrong Peak Wrong Peak =Wiong Peak Wrong Peak i i B7a1seP3lFi0nT/ee1R62M8i0s0sed <Wiong Peak 0 Before 0 After Page 37of 242 7 5 Slumbia Analytical ServicesTM PCirneeadt:ed1w4i0t2h/2A0n1a0ly5s:P4R1b:0o0rtPetr PDraotjaeFcitle E ca081omCaR lLongwi Acquisition Method _PFCiinetex.doanmg RAlegsoraitThamblUesed TtetTiaSuan erLon Instrument Name __AP1 5000 [AScaqmupilseiiNonaDamtee] PFC Sop ectonval [5 | [SAcaqmuipsilteiodn Method [|iPoFwsCzersoidnameiex||DSLwawmopolnnefTyagpcetr [|iaonders || (Semp| ieComment|Weiohttovomme Joo | FRneasyuilets|SuAmndmiaerRyT | Hse Evp Cane Gale Gor | Ress Y N[amero|(tEnaxpsecc1taede)| 1sicleerson| msezon| rsArseea0 | saw (ng/mL) | ssw (ng/mL) | 1(%) | mneer Prost |2|3 13cpros|s evsseun | sooo| som | sow | 1m | no [PPrFuOnAaTt || 3a3x3z3e.o3n4))| 13c-PFDA | 1938900| 10412000| sSoo.0o0n0 || ssoasno || 10012 | wNoo Pros1 | saz | vsceros |seo|sme | som | soem | wr | ne PFOOAT | 476853| 1SCPFOOA| 227as0 | Goosano| soo | sso | 97 | No | sa|s 1cPrs oon | zz | sae|so | wso| o se | ne | PFTeAT | 573674| 130PFO0A soon |sa | w 102 | we fa = ="Le (iC Page 3801242 218 [Gambia nalytical Services IRC Summary - PrCinrteead:ted14w/i0t2h/A2n01a0l'y6:4d1d:o0r0tPeAr ProAz = fos one [rons S_13CPFUNA PFDOA 2 5_13C.PFDoA tare |mos| soNo o| 236 [TM zas 2a) 031 ] | was |wee|e| em | aw |wwe |e| aw ewem | wom |e| ew 413405) 163690 No | 002 476460) wm |No| 035 1 475460) 0.04 | Pa39gof2e42 209 4 Solumbia Analytical Services" Quantitative Peak Review = TE = TE ii: i b== TE ij= Created with Analystp1Re4porter Printed: 14/02/2010 6:41:00 PM PFC 50ppb =7 ia i 413.0P/F16O9A.01 Da 411730C3P7F2O0R02 463.P0F1N41A9T.00a fcBgaseig ne Missed | e oBaseg ineoMissa ed | b cBasy elneoMassed | = cl | +A =A i. =i | 499P.F0O80S07 Da 0133.0C/.8P0F.0OS0a 513.P0/F4O69A.10 Da | cBaseinecMissed | cBaselinecMssed | oBaselineoMissed | 461830C-1P4F2NDA3a0 oBatseolinnge ooMaissed == | | 511530C4.7P0F0OADa oBaseine o Missed i i 1 hz: ai 56P3F0U/5R1A9T0 0a 15635C0.2P7F0U0nADa 5P09F.0S800TDa 50103008P0F0O0S8 | cBatseiimne Missed | T oBaselg necMssed | cBaselnbeocnMissed | o-c Baselineo2Missed | hEz: io|x |2wf 3IE] 613P0F1D5O6A910Da 615.103/C1-6P9F.B0oDAa 663.P0E6T1A9.100a 61135C0-1PF1B6o09Aa0 cBaselrneiolMiessed | oBaseglnez oMissed | oBaselineoMissed | cBaseline o Missed box il 713.0P/F6T6E9A.01 0a 61153.C0-/P1F6D090A.0a c Baseline c Missed | c Baseline o Missed 0 Before O After Page 40 of 242 250 5 lamb Analytical Services Rovichieivs on 4 Created with Analys#&orter TonRatio Confirmation PFC 50ppD rb 2] Lo [[- El5 A A 3pe A wRe a mraoin in || iwptar)sy | coomrimieie | otsevirnomsesons re ee py a -: i he L iC EDe iC Bs I pot ot 4I 5 F aRsPmFyUNa eA,2 n | sn r ofPaRnOsy Sn a2os | cwe oiPmFmiDs mAii2osn|| cseoiPpFnTas GiAt2osi - 1 LSp idLPoFrTeBA eAa2co, O Before O After ergot or2e2 2 4 Solumbia AnalyticalServices- Created withAnalys?1Re6porter Printed: 14/02/2010 6:41:00 PM Project DataFile E0v2a0n8'1s05PrCoajleLcosngPFwCifs Acquisition Method _PFChinetexLdoanmg Result Table AlgorithmUsed 208108amplesLong intetiuan 196 Instrument Name __API 5000 [SampleName PFC 20pm 1G [injectonvia 5 [Ac`AqcuqiusiisittiioonnDMaettehod_[|2/P8F/C2K0i1n07e3te0x5L4doPanMmg______| ISnajmecptlieonTVyopleume ually Cortral [Samed [towsarny [DutonFactor [100 | (SampleComment|[WeighttoVolume [006 | Results Summary_ [ANnaamtyeie ||A(nEsxlpeyceteRdT) TAaretae | EpgCmo)ne|| Ca(negiGmto)re|| Acc0u)racy| yeas | [Pruas | 23342| 1ocprna| 2sa|ssasos0t000| 20000 | 19s00 PFOS1 | 235253)| 13C-PFOS | 6969700| 15447000 | 20.000 20.800 104 No | PFOA1 | 3330.34| 13CPFDA | 368300| 4333800 | 20000 | 20800 | 104 | No [Prost [42610| 1acpros | essoroo| 1s7r7o0|0 zoom | zosw0 |10s| ne PFDOA1 |476663)| 13c-PFD0|A 2173s0| 2671400 | 20000 | 22600 | 13 | ho PFTeA1 | 5.74(6.74)| 13PFDoA| 217090| 1043200 | zo000 |1e|a st0 |w0 o| 7 A4 ll Ee Lrralic Pa45ogf2e42 252  Golumbia ] Analytical Services PriCnrteeadt:ed14w1i0t2h1A2n0a1l0y5s:P4R1U:p0o0rPteMr RSC ummary ww srac pron ww we] [ores |awaw |wom | we | ow] S_13C-PF00A Pra | emsasn |am| mno o | we | wT ve Pa47gof2e62 253 8 SAnoalluymtibciaal Services PrGinrteead:ted14v/i0t2h/A2n0a1l0y6s:P4R1i:b0o0rtPeHrA Quantitative Peak Review 5a = LC boi= ii- PFC 20ppb ICV Im TT 4 - i:A it3~! 413P0F/1O6A9T00a 41173.C0-53P7F2O0A02 463P0E4N1A901 Da 4618.30C1.2P3F.N0ADa cBasenliiannec Missed | oBasewliinpeoMpesased | oBaselnenycMssed | p oBaselig ne o Missed : Lc 5 zl =] i i3 i 499P.F0O80S01 Da 50133.C0-8P0F0OSDa 513P0F4O6A9T0 Da 5151.304C7-0P.0FDADa Basweloinme Mpieassed | oBaselienecyMissed | <oBiaselnecMissed | BaselWiangeec Mizeassed i:= Elzl j |= Ic3 A 563P.0F/U5R1A9.10 Da 56153.C0-2P7F0U0nADa 599.P0F1D80S.01 0a 50133.001-3P0.F0OSDa cBaselinec Missed | Baseline: Missed | Baseline cMissed | Baseline Missed 3 IE i iE a cl - a 613P0FD5O6A901 Da 611530C/-1P6F9D0oADa 66P3F0T/6G1A9T0 Da 61135C0-/PF1D60D3Aa0 h cBasely inec Missed | S cBasely necMissed | oBaseiionnecMissed | Baseline Missed i fn. 713.0P/F6T6e9A.T0 0a = Baseline c Missed | a 611530-/P1F6D90A.Da0 Baseline Missed O Before O After Page 48 of 242 254 8CoSluombiia services: PrCirneea.ted14w0i2h72An0a1l0y6s:#41B.0o0rPeHrA on Ratio Confirmation i Cp = # ERI] |= a \ Ba4s1e3l.Pi0F3n8Oe8A.c2Mi0s8sed| o B4a6s2ePl.i0En2Ne1Ao.2M0i0s0s8ed WrongPeak WrongPeak 4 Pde =| ol ee PFC 20ppb ICV fmt LTof) A LC7 | BE | Bas4e0l5Pi0Fn5eO5So02M0isased| B5a1s3e.Pl0iF2nDe6c8A.20Mi0sased =Wiong Peak =Wrong Peak El - io ap fs Ba5se6l3Pi0Fn2Ue6R6AM0i2s0sed | Ba50s8.P0eF99O.lo0S2iMi0nsaseed | c6B12aP0Fs/O1Geo6A9Mi20is0ns8eed | Ba6s6e3lP0i/nF1e6T9M02i0sased Wiong Pea Wiong Peak Wiong Peak Wong Peak TT oe B7as1ePl3Fi0nTee1cA62M8i0s08sed : Wrongpeak O Before 0 After Page 4901262 255 ao n4 te CAS anomall:uymtibciaalServicWresanat PSRequeeitioon ianattehod P2T920r10Ci306n4T2team Ra edorunm Nsanmde pr Evans pessoarres eqssin smion___y=0.108x+ 000604 0a.n009 Created with Analyt porter Printed: 15/02/2010 2:34:00 PM nAPi336n0 os [ames [w wes [m we [owween] T To e e me w w [Te we e w[ewe ee wwe |e Co Tn me [wo | we | hen] | | _ i i ~~7 ,4 i __rd 'q rd ! 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Lust aoer268 i 3 Columbia AnalyticalServices" Created with Analy Alporter Printed: 15/02/20102:34:00 PM InAtnearlnyatleSNtaamndea:rd AcaquisFiiteion Date PArcoqjueicstitionMethod Regression Equation: TPrsPcopAr1oa 2S9E2T0O10Ca3:S06o:r42 AM PEvFaCnK'isPnreotjeecxtSshidPoaFrCmts AlRgeosruinthTmabiUesed Instrument Name = 0.00x-5+8 0.002(c=M0e.a9n878 ICnRteBtiTQuOaSnamplesSHonean db AP15000 os Tv om Ts Nnaa | hNaan Cs wEee Te me | hNeann[haNan 0 To ww we wa a [a TT eee es Na | Nan | 3 + : _ 3 7 w rd IHEE i3 ~~ __ iaii 7<7~~ 8 _ a > iq 7 A CT5suiee Page 201245 27 8Columbia Analytical Services Created with AnalytReporter Printed: 15/02/2010 2:34:00 PM iAnntaelmyatleSNtaamndea:re PTrsaospr1 rs ATcaqtuaisFiiteion Date Z291E201C0 3C:06A:42 RAoMw APcrqoujiecstition Method EvPaFCnK'isnPetreoxjSehcotrstPdFaCms ARlegsuolrtitThamblUesed TIRntGeBlTiQOuSaanmplesShoredt db Instrument Name API 5000 Regression Equation: =-0.00191 x"2 + ean 0.x+3-05 .0064 25(r = 0.9989) / : _-- CC T sT s 0 wTe omr whaenn |nwaen]] C 0 m eems miw [ wween | wa Cs we wer [na] wav] 3 ! _ | _-- yohi'' 1i p1i . iAl rd of pred _ oTpd | rd adoe E=Fne Page 301245 258 Columbia RE services PrCinrteead:ted15w1i0t2h7A2n01a0l2y:3R4:p0o0rPeMr AInntaelrynatle SNtaamneda:rd Tata Fie AAccqquuiissiittiioonn MDaettehod Project PTarCtPF1 H TET Ca ho P29F1C2K01i0nt30e6x:S42hdoAarMmt Evan's ProjectsPFCs Result Table CZORTOSampiesShonedi db AInlsgtorruimtehnmtUNsaemde AIPnItl5i0G0u0an Regression Equation: =-0.000377 x"2 + 0.1M0ex8an+ 0.00572(r = 0.9988 - ! or 3 0 er Nan aN | [es 1 + 1 049 [es NaN Nan i [we er Rr en Nan [s see a ee [NaN | wen [02 1777 ] 11088516 Te108 NNaany NNaaNN 50 1 1 50.50 1 101 NaN NaN it ; _--_ 7 i _-- El 7 4 pr 3y ~~ i1 d3 ~~ LE _ | i 5 3 rd 7 7 Fae sto Pag4e of 245 259 5 lamin Analytical Services- PrCirnteeadt:ed15w/i0t2h:A2n0a1f02t:H3e4p.o0r0tPeMr AInntaelrynatleSNtaanmdea:rc: P1IHCPAF1 A ATcaqtauiFsiteion Date T2E13E2T01O0Ca3:S0h6:o4r2 AwiMl APrcoqjueicstition Method PEvFaCnK'sinPeotjeecxsSPhdFoarCmts ARelsguolrtitThamblUesed nZteBiQTuOaSnamplesShonedn ab Instrument Name AP1 5000 Regression Equation: = 1.090008 2. 0.0x 000802828(r= 0.9988) [er e:s ]e C 1 T [om d ew ||_e _e xoe94 || hNear eNn[| eN hneN ]| s sew hear] Cw] wm wha an i 50 [+[s [dg e |Nvs | nN] |) P= oe :| ~~ 7 | re__ 1 i1 Pr _ aol LL rd J ~~ 7 Ad= 2057 Page 5 of 245 20 4Columbia AnalyticalServices" Crate in AnaBorer Printed: 15/02/2010 2:34:00PM aAnaare toanms:: oorhs o f ww"nke i rEoEsmda pmT mmrenithname orT 50% Pree Euan roarsercs ER, yr SNE Se er Exp Conc gmt) | #orVatues| cuchtingmt) --oosr [+ : |e oow eT|e e eo n |eNaNh |min w | --wT TTsee e T Tw w weenn[wewe | 2 i wee wweNw[iw J| oe ~ |3| __ | _-- i ~~ i ps 1 : ; 7 ol yd lteter . Ap eTse Poouras i" 4 Golam AnalyticalServices PrGine.r15we0it2h/Aa2n0a1n0tfi2i.S3eB4e0p0odrPenr PDratoapeFtile cvzaosrts0CParSoHRoarRtPwrCi RIenssutrlutmTeanbtleName cAP2Io5s010o0SamplesShoreadbt [S[amAplecNaqDmaetueTi|2Bs920t103i66o. nA `Acquisition Injection Via Method| PFCKinetexShdoarmt Tiectonvolme [5 DiWleuitgihotntFoaVcototrume[[010000 Ea TN Results Summary EN Freeni | norma| 0Jomam0 || wa | | wo | [Prat cera | 0 | saaean| sos Na | we | mst | worms | 0 Jomem| 0 | wa | we | [Simoes | wceron| 0 owen] srceron | ween | 0 |owamm| 0| wa " u% l 7L5ust Pagofe24s5 a2 [kta Analytical ServicesTM PriCnrteeadt:ed15w/i0t2h1A2n0a1l0y2:3F4l.p0o0rPteMr (re IRC Summary [prreaz fPrroasm?a [rons [mom |e Jo Rg oT oo0@en | 0 | No | ooo ro o0m00e4.2n6)|o 0 Nw o |o wowm || e we | em | wm | we|emem| ow | [soma omen|0| wo|owns | | Pa10g0f2e65 203 PASColumbia AnalyticalServices Created with Anais Reporter Printed: 15/02/20102:34:00PM Frontera AS 2 = bg k 5 Tn 3 Quantitative Peak Review ha i 3 ih If 1B J i icol, adWL ch21mp3rr0e1a6ci9iT0i0i0o | oi21su7m0c/cE1lR72Ei0As0eas | | od2m63ar0ie2ee1c0dh0e00is | ob3u11a535rc7e0po0Fy.A0iaes i=z5Spin ilies 26p6r0e0S00T 0a ie Baseline o Missed [1 d Llo| t ilki:wJl = A A-|] JR rh oh "Bl Sabi wooiposi0s0s -Baseline c Missed || 31P3R0H2A80100 | se Baseline o Missed 411530C5-7P0F0IA00 pe Baselince Missed id) Wa A Jlli = 4 En hull teih 1th 3 Bn Heir | Zid brit ik | Wit] 3P63E,0R160T.00a oBssoine Missed | cB3a11s3a5i.n0po7Fo0N0is0saed |[cSma3s9e6l0s n8e0c0M0i8sed | oBa40sw3l0on/re1i0o5iM0sis0saed STNTCo NE Lb RE I7 Ey1B - ILRGT ENE ' Lh J Mid Td ll Thai oB4as3s31i.i08n10e03oMss0sed | ca5s1wi5n0oc4o70ln0s0s0ed || | 5s1sE0c4PTr0o00nn oBasoineoNisssd | 51T50a/c4e70i0oDAa o Sasol oased O Before O After Page 1101 245 280 4CoAnlaulymtbiicaal Services Created withAnalyhFSporer Printed: 15/02/2010 2:34:00 PM lon Ratio Confirmation B Ei 3lmtorr i C|l [|] EIE 3 i |- | Let, | oB2a1si3Pi0rn1ge6ic5sh0i0g8eed | o2B6ops3br0ien2cei1o02M0ss8ed | oBa2s68ep.lr0ne0es8o0sM0s0sed | o B5a1se3Pl0in1e1Ho60Mi0s8sed Wrong peak ons Peak Wong Peak Teitons Peak == 7 7 FodLeT==| 36P30H5A16208 Baseline Missed 0 Wrong Peak =dblbol|e bth 36P60H8S50208 SS_i1E3ocMFT0r0o0nn Baseline o Missed Wrong Peak o Baseline c Missed 0 Wrong Peak NA Baseline c Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. O Before OJ After Page 120125 285 5 Golmbia AnalyticalServices PCrreeates15i0n22A0n1a0ifp5s3.30R4e0p0orter DPartoapeFtile EcznrBtoCasha Acausiion Method _PrCKnetexShdaomr AEgorthNm Used ntlicuan instrument ame __AP15000 [SAacqmuiseitRioanmMeethod T|P2P0CF2C0oi100npe50e03xS5hAd2oarr [(SsaammpplleeCodmment | |Lowsza% SC EampTleETypea|E-- SRandars -- |DwieiognhtFoavcteowrme [[ 000 100]| [NFRaremaseiuslts|SuAtmnmsayerRyT| tsname [isms F[rR00e STaOOr || loemGyove || Rena| oer [r|avanscatn | tscerea |aw|ososmso| ow | oo |w|r we| PrPent | 360060| CRRA | 45ati0| iiss [prost | wasn| worms [som| om |om |oes | sw |wo| PripA1| 620|t6ac2om9a |as|s zsi|oomn| om | ss | ne S| emeon| vceron |me| wm|ww| im | ws | vo | Soc [Tess| rce|rmoamne| arsion w| 4,0WW Zpeis]te Page 1201245 266 BE server ren IRC Summary rn | ve| cocoa | owen | ww | we | am] Columbia aO Analytical Services Created with Analypst32Reporter Printed: 150272010 2.3400 PM oT Quantitative Peak ; Review 7 iE PFC 0T .10pps b iiz= 1 ii: TiE s. IElE bBo) JE 21p2r0/a1n68T0 08 oBaseineo Missed | 2017a.1c7P2E0A08 oBaselnocMissed | 2P63e0p21a90 0a oBeselneo Missed | 311530C2.1P0F0TADa oBaseline o Missed br rea dig > lig: iz i il = i a be Bf 203p0r8e0s0i02 03w0o1s0f3i0s0a cBalseilienccsMissed | cBaisieolinecMissed =3 =a ial I || 313p0r28a9008 311350022F7T0A00a 1| oBaseoinnegoMissed | oSalisoenoM:iisnseed i=zl 3= Is = mPregi Be A Pr] he] A eos i oB3a6s3e0i/n16e9o.0MiDsased | oB3au1se5l0mn2e7cp0M0i0s8sed | || oBa3s9, 9e.l0n6e0o.M0s0asea | =B4a0s3.e01lo0Mi3iD.sna0seed 3IE! ji 22 ,iE 2 =i 3 Lb] 4S0_3108/01-0P3F0HDSa Baseline o Missed le) 511530C4-7PF0D0A00 || oBaselinec Missed | Af 5s1_510s4c7p0r0o0n8 Baseline o Missed Sh 511530C4-7P0F0OADa Baseline Missed. 0 Before O After Pa15g012e45 268 0Columbia Analytical Services Created with Analy?Foborter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation - 76 i-E 2- ER PFC 0.10ppb LwZ-] de hEwe] 2 2. Ba2s1eP2l0Fi/nE1eA6920Mi0s8sed | o2B6os3eP0iF2nP1ee0oAM02i0s8sed | Bas2e9l9Pi0rn5eEc9S02M0i8ssed| o B3as1ePl3iH0ne1Ao1M290is0ased Wrong Posk =Wrong Pek = Wong Posk = Wiong Peak -- = 2 = E-- LI -- hshE fj opel i z2 Brie 3P63.r031A0.20 209p.r0/i9S0.2008 Ss1_5.103407F07000Aa Baseline Missed c Baseline c Missed Baseline o Missed NG PFBWAraonndg PPeFaPkA G0 nt ave qWuraolinfgyiPngefaok Wranstors Wrong Peak Na Baseline c Missed Wrong Peak 0 Before 0 After Page 16 0r 245 260 3 Gale AnalyticalServices" m Crotee d win Ai nttpi34en oner FCReraqoumFieltieonHeinot_ SrE2r0ou1Rn0aCaraTommotSreaim [SempreRams TorF0e1a0sSmeas AR [s`AacmqupisliteiosnMethod ||tPcFiiCsKznaesloexSdhaorry [Samplecomment | AIRoneogTreutmtemantsNeadme _AnG pr e500uS 5 ES EecTonVar -- [SDaimdpiolneFTaycpteor |[S100tandard|| | Weignttovolame foo] Results Summary [Rparnoeat | sas| nose |as |amm es| oso | nogemsty || sm || twee|| preent | as0aan| cern[assim| miso| om | os | ww | wo [[rprrmoast |t_s[osareaaa||n cwoormrmmas |[assaroromn||ssnoems|| 0asmo ||ooms|| wwm || wwo | [revert | sau|arcomrona | soon| oom | aso |or | wor | ne| wS pir:se|esavme || wvooerorn||mwmeeses|| man |om| meron| oo | oa | % | am | ws | ro ne Bion | reece| nceron [a[ss ss s | to ov| a0 |w|o wo| 30 SAE Zs CAT 21 0 8CSooluumtbia services: on IRC Summary prea2 am 1.26 (1.27) PrCinrteeadt:ed15w/i0th21A2n0a1l0y2:3F4:p0o0rtPeMr | _ 238600 [ No we] raz srcpra Tonem |wea| wn caw |me | w ow | wm LESCosleumrbviaices: Created with Analyps.t36Reporter Printed: 15/02/20102:34.00PM Quantitative Peak Review =T 7" i: ]- oi o vegan Be] 213.P0F/1B6A9.T0 Da 211730C1-7PF2B0A00 -cBaseline42ac Missed | oBaselinneyeMissed PFC 0.5ppb = =r El IsE c3 360 i: = =| EE 2630PF2P1e9A01 0a 31135C0-2PF7H0A0a | oBasewlingeoMissed | Baseliangeec Missed = zi IE = ol] i 33 [=: I=1 PFBS 1 GBa2s9e9l.i0n/e80o.0MiDsased 0 re bo b== PRHDA 1 B36a3o.s0/eg16lc9p.Mei0iasDnsaeed 180-PFHS | oB4a0s3e.l0i/n10e3o.M0iDsased eg = fo3 13C-PFHXA | Ba31s5i0e2ol7o0eMi0i0sn8seed PFHYXA | |i oB3a1s3e.l0i/n26e9c.M0iDssaed I = Ii=n | PHS 1 || cBa39os9w.ie0n/8glo0M.izi0aDsnaseed 13C-PFHXA | Ba3s1e5l.i0/n2e70c.0MiDsased Treen Zl hsi 180-PFHS | cB4ao03s.n0e/g10lo3.Mi0i0snsaeed ix: i:zg lli=: )y [3 3bt] A 3 |A 3 A 456_3.108100-3.FFhDsa 5113500.4P7F0D0ADa 5s1_01437C-0F0DDAa 5151.30C4.70P.FDADa Baseline oMissed | cBaselinecMissed | cBaselinecMissed | oBaseinec Missed 0 Before O After Page 19 of 245 272 < columbia Analytical Services Created ih Analy3Re7porter Printed: 1510212010 2:34:00 PM lon Ratio = = Confirmation Pep i- LZ i =3 = PFC 5 0.5ppb ew | A3 Ts of e 3 _---- o 21P3r0E16A920 0a Baseline oMissed | 263.P0F2P1e5.A020a cBaselinechissed | o2Ba0s8e0pi8rn5eec.sM20i0s8sed | oSa3s1e3Pl.Ri0n1He1Ac9.2M0i0sased Wrong Peak Wrong Peak Wrong Peak = Wiang Peak |i JJ--w-- i=loco ff3T 3 T pitt deed | 3 363P0F3H1pA9020 30P9.H09S9020a SS5_01437CP0F0D0Aa Baseline o Missed Baseline c Missed Baseline 0 Missed NB PFEWAraonndg PPFePakeA Ga nol have qWuraollnyginPgeaokn Tarsiions. Wrong Peak NA Baseline o Missed Wrong Peak 0 Before O After Page 20 of 245 an 7 Columbia AnalyticalServices* Casein sna5.3p8ater Printed: 15/02/20102:34:00PM oRFareaumteirteontenod_prSSoraansnsPsooruRateEan nNA torruimoenUasmeed__ 4m6o1n30o [[AEcqmuisstitoanmbeateT]reguezoaiomssezo eL nviaEr --T-- ---------- [[`SAcmquspislitoeioln M>me--th--podf||rloPuFeCsxnzceiiecxoShormidammen[Soa[lmWuiptgelhneteToayVcpiaeourrme [1 S[anda00000] ]| prRnerlsTounlts Stum[mfmiaa Rnrgy||rvscvea ernen[|aseomso| w[e0mo| C[aERamE |t c[ORoee|[AAts oes|| wor| prreat | sso| vcr|rwmara| wo| am | | wo| [pPrroas1t || saastuss[| socooron[|assaoo||sssusioe || 1amm || ateosr|| wwosr|| wwee|| [rro[spmea| scwmmun| ssseoo| wm |tan| wos | ss | wo prs | ssmess| opens| serio| swam| wo | wm | wes | wo [SSSi|ae sae| vorron | am| mous| roo | [Teas | voeron | memo| memo |am| tos eo | | we | wo| wo | ne A 7 ue page2101245 LS services Greated vithAnalysfRSporter IRC Summary reas Prrenz - waa |wwe| we | we [ssoaso aware Too puss| emem | wen wo oar sie oem |eww| ne ED 8 Selmi . AnalyticalServices" Created with Analys4t 0Reporter Printed: 1510222010 2:34:00 PM TT Quantitative Peak ReviT ew ET PFC 1.0ppb 5 ig i: Ei i 3 2 = zl ob2a1s3eP0lr1n8ae9ci.TM0i0s8sed | oB2as7we0lC1nHe72BM0iAs0s8ed ||| Ba2se6lp3i0nee2e1os6M0is0sed | o/B3a11se35l0n0e527o75M0i0sa0sed :i=2 3zl fbil- oin preA si re wopA dis L | peAw fel 19CA PiTiR oBai 2s9e0i8nge0c0M0s8sed | :oB4a0se3oi0n1gs0c3i0i0s8ied || =ob3as1o3l0oi5e6rc5M0i0ss0ed| 7oS3es1e5i0ne3ss7tMi0isa0sed o | = = I ml oB3a6s3Ps,0iR/n1Ae6c0T0Ms0saed | 51c5e02l7i00a08 oBuseinsciisies | l= I= 2 -l - ||| 33r80s8d000 oBaselmonMssed | 403106701.05P.FiSDa obscoeMinsseed |i2 EiE l E0E i2 cB4aSs_0o1i18n00e-0oPMF0iHs0Ssed | oB5a1s15i3nC0o-4Po7FM0DiA0ss0ed | | oBSaS1s_5s1.i30nC4e-7oP0MF0iDa0Ased | oB5a1s15l3.nC0-e4P7oF00DMAiDsased O Before OJ After Page 23.1245 ars 3 SAnoalluymtibciaal Services" PriCnrteead:ted15w/i0t2h1A2n0a1l0ys2t:p34R4e1:p0o0rPteMr fonT RatiT o ConfirmationTER p PFC 1.0ppb = Eitg3 - i | == pEeIt oo [i == of Tl sm 213p0/rB1E6Ae920 Da | rr | We | 263P0F2Pa1A902 Da 209.P0r/e99s.?0 Da 313P0F11H90202 | <Baseine Missed | Baseline oMissed | cBaselinecMissed | oBaseinec Missed | Wrong Peak 0 Wrong Peak Wrong Peak Wrong Peak | Tse wt ---- [---- i. | i= 8 =: Tits Ba3s6e3lP.i0Fn1H3e1G9A.20Mi0sased | o Ba3s0e9P.l0iH/n9e9I.02MDisased | oB5aSs1_e5l10i3n4Ce7PcF0MD0iAs0seg | NG. Wrong Peak PFBA and PFPA do nol Wrong Peak have qualifying on transiions. Wrong Peak O Before 0After NA BasWerionnegoPMeiasksed Page 26 of 245 277 LS [SSAnRservices Createa win Anal$pi4t2egorer Printed 1502/32340010P0i FDraotgaeeFtle G2E0a81r0sCaPlrSahoRrPtRwiCs Acquistion Method _prCkinoexshon dam ARlgeosruitThambUlseed OntIlEiOcuSaAnTHeSSRoredt Instrument Name__API 5000 [[RScaaumipstaomnestsI T|aPF2057054 GLGTA [eT conT var-- ES T-- Es [EsaCmpTlec-- oment1 T DviisgohinwFavceor m Tro] -Results Summary Ftarmaeis | pray| stem [sam| FPraeis E[xSpCOoRne | GTeeGoo|TAAccra| er [proonr | sna | com|siounr |mao| soo|sm| |e [rroat |ssvan| comma| w|so mo| sw | sm | or | wa | rSsEt | essmmeeasnn|| wrsoorrrmosn | s|worwo|| zsemreo|| stoon || soww | oTmr we|e [S3icc roses| scoron|mown| own| on | woo | ow] we 5 20" Page 2501245 ors EEAnalyticalServices IRC Summary | Analyte Peak Name RT (Expected)TT SeAre~ a Modified? CoalncuRlaattieod Perna | Prez PFHpA 2 saaan| mo w | em | amen| 6.22(6.22) wo 2709700 || Nwoe on2.88 4CAonlaulymtbiicaalServices- Createdwith AnalypsatsReporter Printed: 15/02/2010 2:34:00 PM BE 2 7 7 Quantitative Peak Review 5 7 il4 i 3= 2130P/F1B6A9T0 Da oBaseinecMisses | 21137C0-1P7F2B0A0a cBaselneclissed ny 7 usogpea bBo E |3 rl '3 CBa2s5e0P.i0nF/eB3S0.MT0i0sased | oB4a0s31e,80i01n-1c0Po3F.MH0iSs0saed oe ol na Toe = = [3 J = 3 PFC 5.0ppb =5 faa iE=ll | 263P0F2P1e8A0T 0a oBaseinecMissed | Ba3s11el35iCn0-e2PF7MHi0DAs0ased | conn ia h=d =3 fo El | | Ba51sP3eR0Hn2A6cA9M10s0s8ed| o3B115a30C/s-2Pe7c0FMl0FiAsDnsaeed EE ana Bs =o Ih ix HDA 1 13C-PFTKA oB3a6s3e.0l/n1e69c.0MiDsased | oB3a1s5.e0i/n27e0c.M0sDsaed i3 i-= PHC 1 180-PFHS I| oBa39s9e.i0n/8e0c.0MiDsased | oB403a.0s/1e0o3l.M0iiDsnsaeed - cf |- i 4S0_3.1081010-3P.F0H0Sa Baseline o Missed $1153.C0-4P7F0O0ADa | 5S1_5.1031C7.0P.F0D0Aa oBaseline o Missed | o Baseline o Missed 0 Before O After $1153.C0-47P0F0OADa Baseline o Missed Page 27 or245 280 LCE olumS bia services: Createdwith Analyspt.4R5eporter Printed: 15/02/2010 2:34:00PM i i CT Tm lon Ratio Confirmation - 4 fie H T PFC q 5.0ppb po ds 213P0F1E1A62900 oBaseline oMissed| 263P,E01P2E1R920 0a oBaselinec Missed | 208P.r0e9s9?0 Da o Baseline Missed | 313P0F11H9A20 0a Baselineo Missed oWrong Peak o Wrong Peak Wrong Peak Wrong Peak Tea] = . i: oes i= Hepdnide 363P.R03H1G9A.02 0a 309P.0E1H98I.S20a oBaseline Missed | Baseline Missed | 5s1_3.1034C70F.F0D0Aa Baseline Missed | NA BaseolMiisnseed Wrong Peak Wrong Peak 5Wrong Peak Wrong Peak NE. PFOA and PFPeA da nol have qualifying on Fansiions. O Before OJ After Page 28 of 265 Ey Columbia PAY vPv R PrCirnteeadt:ed15w/i0t2h1A20n10a2n:3p4o.0r0tPeMr DPartojaeFcitle 0Ew2a0n8'1s0CParloSjheocritswPiRfCs Acquisition Method _PFCKinetexShort dam ARlegsourlitthTamblUesed G20 OSampesShaReddb nteliQuan Instrument Name__AP! 5000 [SAacmaupilseiNioanmbeate | 2P0F2C001069TITAN I nectonvial 1-- 6 Acquisition Method |PFCrneioxShdaorry [sampled [Lowszese [[SDaitmwpiloenFTaycpetor [[s1i0an0aas || SampleComment ||Weghtovowme joc | Results Summary NAanmateyie | AonnaalnyteRT|_oveme[oan [| ArAaiFyie | E[xpSCoRne | GaleiCmone || Accuracy ty | Mo PrPeAt | 2.60.60,| 19C-P|F4Hs2X74A00 | Soz1e00 | 1000 | tie |116 | mo [Prost | 42626| 180pFHs | 2676500| sssttoo | 10.00 no | [rat | sate y [Prpat | 6.22629) | 13C-P|FasH27aa00a| 1st3t0|0 10.00 No | [Prrxs1 | 6262)| 160PFHs| 267650|0 3163300 | 1000 | 1080 |108| No sSeso. |[osvean| tsceron |T mero| eee |t|e ten| 3 | wo S5 r3cc: [e | rs aceroa n| as sso|T zesao | 1m | 100 w [| Al! ustae Pa20gof2e45 22 5 Simin Analytical Services* R Cre weinsAri ta0s.4e7radter IRC Summary fv en ame TT rear| T rT nT | am | TTnes] mew | ouw ter a TCTalcue rleanatoedn] e oerenz mem [wee |we| 00 res: am | wen | ve | om Pranz sean |we| re ws [orvoz mew | wm | we | we ai owen | wom [ow | em | s< _isnocrrronna mom |wwwow[|owv [em om ] 2s page or24s PASACnoalluymtbiciaalServicesTM `Quantitative Peak 5= ReviT ew T bz3 | Hi 3 El = 213p0r11e6a9T0 0a Baseline Missed 21w7o0e4i7a2n00 Baseline c Missed CriethAanalty Bepordter Printed: 15/02/20102:34:00 PM 5 PFC 1=0ppb % bo= =| i| = | 263p0re2e1k9t008 | c Baseline o Missed 31153002.7P0F.A00a Baseline c Missed i- 4 E3 : iI:=! El-= 209P.0r/a8s0.00a o Baseline o Missed | 40s0e0o1p0f3i0s08 || oBaselnecMissed | 313P02R60A.00a oBaselneo Missed | 31153,0C2-7P0F.0TADa Baseline Missed gy pany | Chine, ig El i h El a] 4 2) I= l= -! Ar] FEHR 3630/1690 0a soeAfiea r]| 31502700 0a A eed] 305.0100 0a = 180-FiS 403.01103.00a oBaseline Missed | Baseline cMissed | o Baseline oMissed | Baseline Missed ol = i3 Ll i: i= i El 3 Il |= A oB4aS6_s31e081i01n-0eP3oF0sH0sSaed | oB5a1s51e.3l0C4n-7eP0cF.OM0As0saed | oBSaSis_5e10i34nCTe-0cP.iF0iDsDAsaed | oB51a15.3s0C4-e7Po0lF.MO0iiADsnaseed O Before O After Pag3e1of 245 284 4 lamba AnalyticalServices* Created with Analyspt.4R9eporter Printed: 15/0212010 2:34.00 PM Ton Ratio Confirmation PFC 10ppb, . Tw Tw = = i 332 oh =3Fe ph"ou: . Be 5 sh 2130P/F1E6A920 0a oBaseline c Missed | 263,P0r2P1e9A02 Da Baseline Missed | 209.P0/r0e9s.0?0 Baseline Missed | 31P30R/H1A21D9a0 o Baseline o Missed Wrong Peak = Wrong Peak Wrong Peak Wrong Peak wm |. bo he = i - oh Yr izzl | Tepito 363P.F0H1O3A1.2Da Baseline oMissed | 309P.0F/H99Y.S0 20a Baseline o Missed | 5S1_3.1034C70P.F0D0Aa Baseline c Missed | ) NA Baseline o Missed = Wrong Peak o Wrong Peak Wrong Peak Wrong Peak NE PFBA and PFE do not have qualiying fon Fransiions. O Before 0 After Page 3201 245 25 3 Goma AnalyticalServices rCttriilsneAntsttsy teBoorgoeird DAFraeaiiteion ait_ rrrGraunccFearsEhoTnaSm AR nofrutmteTnmtusNeadme_ 4mT 91a50i0O 0n SS [SampleName Aeasistion Hed TPF9C20270 5 [SSaammpple Comment Toszor I ET TT ES -- -- Weia gnioveame f-- oo] Results Summary [Namn e: a||iA(nEelapbees eeRg|yT |S"gpa sae| AnPalRyis || ExCpoCnoyn || Calme. yCone| ts | Me? [werpentr||woaassnznm||amcosroerna|| aawaerwoon|| zweineo||mmeoso||maorov|| wwmm ||nNoo|| ros1 | aasaan| sores | aan | teens| mm | weo |on| we | Prat | mean| cera| aw| mmo |mao |me| wm | No| (rripnt|sazean | worrua|aso| was | mm | ao | m2 | w vrs1 | eam|weorsms | amo| teow| moo | tear | wm | no | SEO riaan| wopron| sere| aoo | ta |os | e wm | no SB anaes| viceron | sso| mom| 1m | 1m | wo| fo Ae Eets o [S---- 2 PASColumbia AnalyticalServices" Printed: 15/02/2010 2:34:00 PM IRC Summary [ Anatte peak name Pron [pras2 RT (Expected) -- EE Wodited? CfaonlRcautiloated 125428) sr11000 No iz 4Anaollyutmicbaila ServicesTM Prcinrteead:ted15vi0t2h12A0n1a0ly2:3B4p:a00rPtedr 2] 3 % Quantitative Peak 7 Review ga iz I - " cB2a1s3eP0iFn1Be6Ao30M1i0sased | oBwas71ea3iiCn-rePzMFoBiAossned | - 2 Bg PFC 2o0pps b |. i= !- - ||| a9P0FaP1A90108 oBaselineoMissed | B3a11s35C0e-7PloF2HM7iXiD0Asn0aseed bo kd i 2 of ij l=Cl Ir zl= i 20p3r08o0.s0 0a oBasdanegoMiisnea seed = |= 3P63F0H/p16A910 Da Baseline o Missed 1) 631 3 =pi 450_3108100-350FH0Sa c Baseline c Missed w0o1r0d3s00| || 913p0r20i0008 | oBaseineTY Missed i | oBases linoc Missed = be Ion=t JIt = | 31135C0-2P7F00HA0a oBaseinecMissed | oBa3s0e9Ei,iH0n8e0c,10Mi0s2sed FREE A. ka li po~ Iie 51w5c04e7O00ADa |S 5115.C047O0.0A0a Baseline c Missed | 0 Baseline o Missed 31"5a07C27E0i0ADa | BasaenlogMiisnseed = i=3 | o B4a0s31e.8l0i01n-1e0Po3F.H0MSiDsased J a - i |J 51153004.7P0F0OADa Baseline o Missed 0 Before OI After Page 35 of 245 258 4 ASnoalluymtibciaal Services" Created with Analyspt5R3eporter Printed: 15/0212010 2:34.00 PA 3 = db] Ton Ratio Confirmation Tm TE PFC 20ppb 7 7 iz (i i | == I|rH | ui ) { e heeede : 213P0F/1E6A920 Da 2P63F0P2E1A902 Da 269.P0/r9e9.s0?Da 31P30F/1A21900a oBaseWliionnegcPMeiasksed | BaseWlionneg PMeiasksed | BaseWlrionnegcPMeiasksed | BaseWlrionneg PMeiasksed a] 4 T i1 t he Sar hf Tipe 3P63F0H3p1A90202 399P.E09H0.S02Da 5s1_51.30CF4F7O0DA0a oBaseWlrionnegcPMeiasksed | BaseWliionnegoPMeiasksed | oBaseline oMissed Wiong Peak | NB_PFBA and PFPeA do nol have qualiying fon Iransiions O Before OJ After NA Baseline Missed Wiong Peak Page 36 of 245 289 Columbia LE SE services: PrCintedr: 1w5ei/0t2h/Aa2n0a10tt2y:3B4ep:o0r0dtPeMr DPraotjaeFcitle E0v2a0n8'1s0PCarioSjhSocrSPwFiCfS Acquisition Method _PFGKinetexShort dam ARlegsourlittThamblUesed GIZte0l5iTQ0uSaanmplesShonedl db Instrument Name __AP1 5000 [SampleName]25P7F2C0S1o0pp3241 AM [neeccttioonnvvioallume [1 5 s]| Acquisition Method | PFCHinetexSdhaorrn [Samplel> | Lvsz856 SampleType Standard [DionFactor [100 | [Samp| leComment |Weighttovoume [ooo | Results Summary | ANnamaeis || A(nxapieyciieoRqyT| 'SName | save | An"aRieryie|| ExnpgmCbo)ne|| Ca(loegmCba)ne||Acecuracy| Mo PFPeA1 | 3.59360, | 13C-PFHXA| 475|322118040000| S000 | 4880 | 8 | No Pres Prat || e2suze| savaan| 180pFHS| crews| 2676100| aso| sestaom | nasow| sooo sme | sero |ma ||dwo o || wn Noo|| PrHpA1 | 6206.29 |19CPF|H476X31A00| sosoton| sooo | soo|101 | Ne Pris1 | 69|2166 0PF. HS |9267260| ateds0o0| S000 |somo| 102 | Mo [i50g5o0r Toamean| 1sceron| sss|resrstuenn| 100 083 EIEN sS1e3c: [7a1ass| taceron | aaron wo | 10 | Ne 4 Ct5e 26 Pa37gof2e45 200 Lakme AnalyticalServices nCosot ssans 0So.5s5eEr:a ee IRC Summary vanes ween | ww | ours oa rans reer em | meme ET E|eRae ET ] [reese [mam wPrina z z] weawraenn || eww | ammeewn || owwo | ven eaw | Pri 2 + scrron omen| www | w wom | www | we | os ae | S_13C-PFHxA 5.31(5.30) I 4753100 No 0.22 [-- 4AGnaollymtbiciaal Services PrCirneca:ted15w0it2h72A0n1a0ly25t3.45R,6o00pePMr Quantitative Peak Review : =: = 2=Sl 7 0 = 1 a Ca2s13aP0lF1e6B8Ao.v10i0t8eed | oB2a11s37eC0l-1nP7eF2oBM0As0s8ed bipoozol iE o3l A be A - e2s6eo9P0rv8ai0ss010s8es i | cB0as31ei08l01n-g0cPoF5nHt0Si0.s8sed A. be i -l i= CB2a6o3pi0/nr1e6oi9M0a0saed |oSes3e1w5lo0nr2ef7ct0Ma0in0s8sed PFC 50ppb I =- = , ==! 537 rl il | = | cB2s6se3Pi0FnP2ee1cA9t01h0s8sed | Ba3se11l53i0Cn2eP7F0HMX0iA0s8sed wl - i 2 7 f=| A iA |||| cB3a1s3Pe0iH2ne6Ao0M0|s0s8ed | og M B31a153C0e s-2P7cF0FeM0XiADslsaed IbE ii= = =3 | | o3Be9s5ep0ln2ee0sd0Mi0s8sed| oBa4s01e3el00n1eroF0MR3is0s0sed E : | 2 Satin 40301103.0Ds siisoei00ba I= || 5o15m047d00n08 o 51p5047y0008 oBaseine ovissed | oBaselineoMssed | cOsseinecMissed | Baseline o Missed 0 Before OJ After Page 3901245 202 8 Aonlaulymtbiicaal Services" Created with Analyspt5R7eporter Printed: 15/0212010 2:34:00 PM fon Ratio Confirmation TE TE lo TS ifJ '-4 Loz. fxdes PFC 50ppb -7 "00a 213.P0/r1E6A8.20 0a 263P0E2P19E02Da 209.P0r1E99S.?0 Da 31P3F0H/K1A12900a cBasWerloinngeoPMeasksed | oBasWerionnegoMPieasksed | oBasWeloinngecPMeiasksed| cBasWerionnegoPMeiasksed [-- po] ye ho ek = Isl I =f I~ | Tip ide 363P0F13H1R9A.02 Da 39P9.H09S002Da 5S1_51.034C7F0F0D0Aa NA B5asWerlionneg0PMeiasksed | BasWeilionneg5PMeiasksed | BasWerlionnegoPMeiasksed | BasWerlionneg5PMeiasksed NB. PFBA and PFPA do not have qualifying on ransiions O Before OJ After Page 40 of 245 203 LColR umbia servicer PrCnreeda:ted15w0i2n2A0n1al0ys2pt:.3R4se:8p0o0rtPeMr DAFacrtqouaieFsriietion Method c_TaPaoFCsnrtsioniecPtaerixsoShhRoorrettridCatSm [SampleName Acquisition Method |TPP0FF0CG1HZ0noe5t01e1exA VShdrart [[SSaammppeicoomme | Tomsa7 ARlegsourirtThambUiseed CInEetOiGSusn Shae [ Instre ument c Name_t[5APo I 5T 000nvar T Sample Type | Guaity Gono! DwieioohntiFoavctaohrume [J1o0o0 || FReasuylts |SuAmrmaasrRyT Trae | Ep Cone |Ga Cone| Aceuraey Nparmoeat | vara (Expected)| roeron hidiiind | somo 18 Ape | ssw|mom| Area (ng/mL) am(ng/mL) | (t%e)s | hoMod? [rorapesnt || e56r10a.z6n0|| 1w3ocPrFHeA |sdsaaes00||wsmeeasseonn ||m0a0o|| m22a3o0 || w1o1r2 || ntoo | [PorHrxAnT | | 5w9a2v6a.z3n0|| n 1CPFRc xA||sseaammo|| smeemo|| 0mo0o | 2060 | 103 | oNo | [Pret |astasn| tops| easun| esis| m0 | wm | we | to sw Ss5c5 || Toran| wsorron|ss |smno | am | eo | wo | wo 1 v ofI} Ziste 2.0 Page 4501245 20 Columbia 4 Analytical Services Creesvin sts.5r0 or Printed: 15/02/2010 2:34.00 PH IRC Summary rae ess Perroanne [pres [rrronz Prrisnz scr [ercrma wren | we [eat--|--goon smwaamm|| wweoem || wvee ||ovvee | mam | mmo | smo|w|m wo| ws C[Coewaesne || wewmow || wwoe |[vvee|| mam | we | we | ne | swe | wm | we | | i Pagesor2es Lm AnalyticalServices cts So Created win Analybpt6R0eporter Quantitative Peak Review | 7 1 J 7 | Hz c2l13ap.i0r1r1ei68o].N0iDnaeed| co2m1o7l0n0o72c0M0s8ed BF 7 ings gr PFC T= 20ppb ICV - = 1 = ||| ca2s6e3mi02nn1o9M0i0s8sed| oB311a53s0e25o7lMA0ians0seed | ~ ie in i= iz i1 i= ca2s0s0Pi0re8o0so0iMs0saed | oBaawswealonoiescs0MDasssed || | cB2as1a3pi0ne2e6cw0i0i0s8sed | Ba3se11l53i0n02e7Fc0T0MAiDsased 3 = | El Lo he J is ci3m6J3i0no/1c6el90iz0aes | cosir msroepe0c0h0ian || c3o96m08m00i08e | o401u308100s370SDta re TR Trees 7 on sods idi B4a0s3e.l0i/n1e0c3.0MiDsased Toon Eli Ba5s1e5l.i0/n4e70.0MiDsased | sawsion iE 2 || c B5a1s5e.l0i/n4e70o.0MiDsased Tscoon i: i o B5a1s5e.l0i/n4e70o.0MiDsased 0 Before O After Page 4701245 256 8AnSaollyutmibciaalServices p61 PrCinrteead:ted15w0it2h/2A0na1l0ys2t:3R4e:p0o0rPteMr fon Ratio Confirmation Tw Tee 0bm.i | i Wl oa PFC 20ppb ICV. J IN zl eee a1. "oss _ 213.P0r/1E6A9.20 0a 2P63F0P2e1A9020a 209P0F/E9S9020a 31P3F0H/1K21A08a0 BaseWlrionnegcPMeiasksed | oBaWseoinnegcPMeiasksed | oBasWerloinnegcPMeiasksed | oBasWerionnegoPMeiasksed T =r TT biol L a eh BE 2 - Potopsduite 363.P01F3H1p0A.02 0a 309P.0H/9S9.200a GBaseline o Missed| o Baseline o Missed | 5S1_5130C4P7F0DaA0 Baseline c Missed | Wrong Peak Wrong Peak Wrong Peak NB PFA and PFPeA do nol have qualiying on ransiions 0 Before OI After NA BasWeloinnego PMeiasksed Pa48gof2e45 207 PASACnoallyutmibciaal Services PrCinrteead:ted14w/i0t2h/A2n0a1l0y6s:P4A1d:o00rtPeMr RFOeraaouisFiiteion eho GE _rposraOmuR Cnaioonngtowainmt [Sample ame [PZFoC0tT0og1c2o55 [Somes tPcruCsrnzeetsstong dam [Semplecomment| RRooretomeUsed G mlicumS n R nswumentName 415000 FTiocjVoiec[t5onvotame| [weightiovouume[000 | RFeasuelts SuRmosmiaer#7y re ET CHC Rr| Nbarmoent ||1(3Ex7pe0c1te3d)8| tscrron|sero| mAoreaan| sngoimmLe) || (tnge/amlm) | o(s%) | fo vent | 2avas| racer| ziooroo| seman| wow | maw | 8 | to bros1| zssas|s sscrros|wo |vwan mwo| moo | temo| mn | no |oPreon |[seartezsi||et1ssoccernrrou,nm|| z sso|| r azmxoraom | mam maw | IKwws | | we PFDS 1 Toromat | arson| 4124.10) | r13Cs-PcFOrS |r|a7os24s0o0o0n0| 1s4m8e4r2e0e0||0 mow 20.000 | mae 18.400 || 9s2s | Nwo o| Perrraantt || 5s7z6s6i7t6e)||1150aProcon||ezzrer|o| wssoeoaosnooo|| mmaaww || wwaoaw || wses || nwoe || A AF piel! Page zor262 200 5AnaulymtbiicaalServices" ISRCummary PrCirnteeadt:ed14w1i0t2h7A20n1a0ly6:s4P1R:b0o0rtPeMr s_130PF0S amesy | prove| amew| mow | No | eww | wm | we | ve | [rams swam | en | ve | we] [Ferrors Comwesn|se| m we| ve | Pa43gof2e42 299 aS CAonlaulymtbiciaal Services Created with Analyst.Rdporter Printed: 14/02/2010 6:41:00 PM = Quantitative Peak --% Review - = PFC 20ppb =CCV i La i. i bo i -L 413P0R1O6X8T008 _aseine cMissed | 41173.C0.3PF7O2A00 oBaseline o Missed | 462P0N41A901 0a Bassin classed| 46123.C0.4P7F3N0ADa Saseline c Missed :: iic iES i: bw o zl pu om4ei0Pn3Fe0Oo8nS0i10s0ses | oBa5s10o33iCn0-eP6cF0tOi0Ss0sed | cB5a1s3eP0iFn4Oe8c3AM.Ti0s0saed | cB5a1s15e30iCn4-e7Po0F0OMAiDsased ime es lee i i | il i 1 CL CL i 5P6E3U0A5A10T 0a _Bastine Mise | 56153c0.2P7F0U0M0Aa cBaselinechissed | 5P6r0O8S0T00 Baseline cMssed | 50133.00.66070GS0a Baselineo Missed Po i |- io 6P12r0O5O6A9T0 0a Gassing oviseed | 611530C/.1P6F9B0oA0a Baseline olised | 662P0E6T1910 0a cBaselnec Missed | c 611530C/.16P9F.B0oADa aseciMnisseed 3 a 7P13E0T6e6R9T00a Saseinec Massed | c B6a1s1e53lC0i.n1Pe6Fc3G0oMiA0s8sed 0 Before O After Pa44gof2e42 00 Columbia LS Ru services PrCinrteeadt:ed14w/i0t2h/A2n0a1l0ys6t:4R1o:0n0 ePnM Ton Ratio Confirmation PFC 20ppb CCV TT i:piz 136 ]| A fo- a - I\ EEr 2 -3 --f da 413.0P1F3O69A.20Da 4630P1F2N1A920 Da 499.P0F/9O9S.20 Da 513P.F0O2A629.0a0 BaseWlrionnegcPMeiasksed | cBasWeionnegoPMeiasksed | BaseWloinnegoPMeiasksed | Bas<eWloinneg PMeiasksed 1T 5~ =3 aE= - alts he = A 2 il dts ul ol sie o 563P.0F1U26R9A.02 Da 509.P0R/O99S.20 Da 613P0F/O1G6A902 0a 663.P0F/T16I9A.20 Da BaseWlrionnegcPMeiasksed | cBasWerloinnegcPeMaiks.sed | BaseWlrionnegoPMeiasksed | BaseWlrionnegcPMeiasksed . 5)i 713.P0F/T16e9A.20 0a BasWelrionneg@PMeiasksed O Before 0 After Page 45 of 242 301 4Columbia AnalyticalServices~ Created with Analyspt.6R6eporter Printed: 15/02/2010 2:34:00PM Project DataFile E0v2a0n8'1s0IPCraoijeSchiosrPwFiCs Acquisition Method _PFCKinstexShort dam AlRgeosrulitthTambUlseed ~~ 2In0e8liTq0uSaanmpiesShoriedi ab Instrument Name __AP! 5000 [SampleName | 2P7F2C02100ppb5C1O5V1. AM [inIjnjeeccttiioonnVVoiallume [5 | [AcquSisitaion Mmethopd lLoewszser [SampleComment | | Weightto Votoms[000 | Results Summary [[pTEraoEtnet | | Annaatyise aRT|R ceren|T EsTss| Arai swarm | ooo l|lm ire Clos ne|rse sd| wo | [pr|raesasto| 13cerrea|4sssooo|ssas|s20o000| 1900 | 55 | No Pros1 |ama|wozrmes|zesioo| esseooo| mmo | no | st | we Fr1 |sane| tosens | resi| samo| moo|mao | mn | ne S80: s3c- 4 Wos Juste Pa41gof2e65 02 CrweitaAnalty Reapodrer IRC Summary [Anatpeaktams -- | RUEpRT) | AresWo|amear| oRete rns Coven|osm | | we [oor imum| ome[ww| 1AnQalluymtibciaalServices Created ith Analyps.t6R8eporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review = Come o 7 bIE" i3 pl I 1 Ex IIh~e7 | PFC 20ppb CCV = 537 bJ 3= zl cB2a1s3eP0lF1nB6eA0o.1M0i0sased | oB2as71e03l1Cn-7ePo2FM0BiA0s2sed ||i oB2a6se3PiF0nP2ee1cA90M1i0s8sed | B3a11s530Ce2-P7lcF0HM0iXiADsnsaeed congpea SEL ee slim cl it ] i p il 209P0R/8B0S.100a 4013800-1P0F3H0S.08 oBaselnoc Missed | oBaselnecMssed so = If = [= |- x || 313P0H2Y6A90| 08 311530C2-7P0F0HADa | oBassinecMissed| oBaseolMiisnseed Lt = Fo = 553P0R/1H6p9A.0| 0a 31153C0-2P7F0H0XA0a coymyes | moim les IE 3 =: 3 = 4s0_3.108/01.0F37.0H0Sa 51135C0.4P7F0D0ADa oBaselnec Missed | oBaselnecMssed : cl | ra El I| 30P9.F0H8G001 4031.8001-10P3F.H0SDa |=osseoogt2i2aoe | loSiensnieesr Ba iwf |= = 5s1_51034c7-0F0DDAa 511530C4-7P0F0OADa | oBaseinooMissed | oBaseo Mlisnseed 0 Before O After Page 43of 245 04 Columbia BR services fon Ratio Confirmation wT IE lfi+l= Li l: 21P3F01E6A9.20 Da BaWsreloinnegcPMeiasksed 263P.0F1P21e9R.20 Da BasWerlionnegcPMeiasksed sl | Ae I. | I Created with AnalystR5e9porter Printed: 15/02/2010 2:34:00 PM PFC 20ppb CCV = = h4| t|e ff3 2 Lap | 20P9F.0E19S9.20 0a BasWerloinngcePMeiasksed 3P13F0H1I1A802 Da 1 BWasoelninge cPMeiasksed || A.1 i bi Tings ane 363P0F/H3p1A902 Da oBaseinecMissed | 309P.F0/H9X9.S02Da oBaselineoMissed | 5S1_51034C7P0F0DDAa oBaseline Missed| NA BaseolMiisnseed Wiong Peak Wrong Peak. Wrong Peak = Wrong Peak. NB PFBA and PFPeA do nol have qualfying fon ransitons 0 BeforeCJAfter Page 44 of 245 05 p10 :+ Ae"ZguSomneiOmetcazVi 5$ ZSSaenaoniioorrraseas 7+ SSSeeenonvoorrerecass 35 SSSeeemmmumiisnnc BW 2 IdEemsuE roos i8S a Immmoaz0 iroir @To FmZeoomnm0siI 252 ZSseeeam0ommniins %I% SSGeememviooonmnsem 725 GJFeeooaoios0msmm S%o GFDeeemaaiivooimmonzn TS3i5 eSDeoeoimmommasen TXGNaR0On0o00nT $ 2DD9oom00mo0m G SGDueoomnbnoorssm is DoDeaommooirraisEe &s9 oDDooemontne SS S F DDeemmOooss S 5% TDoZ eoonarn SEE$A Dremgis PostenIISFamEplCeNOatme iSSPPPICCCiOSagGmmm TSSrPiiPCciiCunme aS7P7oE0wC2eS0an5p0ao nCCOyV K2mKIoi0m00eaNi10am0n2 LKsSSIi0O0o0MmaS1e1Ua0G0n8 4sD8iKnKIaemOsIioNaNn 5SSHKGiISOINaIG0IrTONE SSKKIIIOXSST0Io0OlTsS SxiKToiIoowoIniio0o1nn7 G 6GiKKaaS0G0GeeO sdmed GGoak KKIOORMGSOAO 62315KKKIQI0N0000S40SS0300.0003 2aIKKkiIIoowRwmSenn0oon0ns 2I mKiK koomI snon 3B30S1lKKiio0o0oasw0ee6n0o0a1n0s 35u5KKKiiIo0ow00ew8ee8n8e.oo0i1ns3 K33xaiaoIaomweenOoornys 305kK0iloim0msee0nno0sntms 6c Kamt m: 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PFPFrrCCCHuuimnneeeetiteoesniLgoddooananamgngn 2CC0oO8BB1i0im0SSSaaammpmlpeeesssotennoggnwiuegtlt FFErrrcccuuunnnseemtmeiioeonmngggdasannn CDCoeonieiaimSSSaaammmepeessnooonnnggpuueeettt bbErrrcccuuunnneeemrmiiaoennngggusoaeennm CCCoBmeiiiSSSaaammmggaeeeninoononggnuuttt PFrrrCkOunienmiioerongagnaagmnm 0GD2En0u0ib1SI0a9OumSadameomseleoeLLnoopnngugwtuttt FrbPorrucmmuenemetidsootnnggodoonaaamgnn GDCEooOeeiTiaSOSa0ammSrdeaessmooolnnngwgeweuLttt bFPrroCuunreetmegok nogdeaamnn CCOo2em0iiNSSOaaDmmSegasemonenoLgnowsniugttt FFcrrorcummeodmecoeomnnnggdueaaamnn C0C2eo0i0oe1S0ia0mSSraeamspmoenorngnLeugoenntg SerccoueiengpeenlScmeeSamseosnsewt 208 1S ves o21u0rF02si00 SZpirisisairtoo0o ZZfnrasereeiei0) 7fsrse0eos ZpSor0so3s5ee0s0 ZBnaaomoo STSritosee ZTSiossrsooon ZZSsoasr2nse0es0 rZSaoeroes 2eS50o0d0e00 f=metoeid rSrsasoa00 ZSpeioerido EZSs0e0v0e ZSSaortieae ZZSaooiredo STSeooe 2EE50r02i390o00n0 fpridest Zc Sh Ev Zl p71 +3AeaSsmaoaoooiniOoonaaa0ses Via Posten 21PSaErCpOlaTNmamse 3 wmode PCOS APPcEPqrCruCOsuuMhmomrnmeSaMmnetGathtnooddtduarmnm F0i00N2220a000m980DeICC0HaSCSrHreStvrwNultttt is Pas A0v0e0(0co0uor Toess00 35 SSDmeaaoomrroioacesones 7 Semism iSSPhPrrCooiSTooommsms Trica PPPrrrCoOuuuommeeSmmShShananttddoaaannn 0002290009MC1OK0CCSHHNSStNhwwaweltlrl PrCkmmmnotam GSTOCHSw TSZoaesrrxia0 reo +S DGsmammaoiiomosaossri" 1 aemonses rP7 rHcEiECIooImMsCCOOUV 1 KIO 001 PPPFrCPrCrCkkCkmnumeeetemmmmSsShhnharerotttdodrdaaaamtnnn C0G0E222B000I8980O10SC0CaHCHmaSgSStehNoasawtrStttlreritt 3SS2aa5zs7e5as0co00 "enaa0 5Te SSSemeaoaenrrsors is ammoiorae K22Ki1io00oo010t.090o00104 5K100091.005 PPPEPGFEEkCnkanCGtemmnhKSdcdaraaammttm GG0GE2EES0OO8TBDBTI0Sa0aSSmapnamegmseepSssrSrSsrthewuehreltt S"`raaesenas0oe0 prey 7is mSmeoamrorrae e000 i66cK1i0ao0ot0o9oi1!11o0000n88 6 Kiooo011008 PPSPFEErGCkCnkhaurinamamrmSamnthadoceaaaatnnmm C0CDO2CBB0BGO0I1OSSDSaaSampammemoosReSseshSSaarrtoett Shet `"`sr2s2omz00 ira n3 Z maSmasaimioosssnnz 5 Semen 55027 KKKiiioooooooo00o11o110010111031 SE Kloo10t13 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Pekaanm 02010Samper "zn Ee7s7 isto 307 i HH if1 Emil PANNA ET U i FR e el | 2 ERR EE DFE RRSENENINERERERRARNRNY EE i NAVA i2 L SELle RRfe]ERfEeRlLlsGS2 SZ BlEEEEEIEERIEERIEEEEEREER SER T| f :| 31 1) i 3 ES3 v 3 Pls itl lll 2: I: ryEs 22 FL] ndi 2 sit |: fl1e2e2s8 ||2B :IRE }| a. EI le H l: EEE EEE EEE |e . $$2s HJlaasdst ylo] d gif i 5 shila S51. [ENNNSSSIEARSANRRRRRREERESRRN B3 eis 1x asa i : sHiH iF idllaiiaiesist |8i IA TTRE HAE EB lEEEEFEREEEEEEREEEEENAN 1331 3 $1 BELLE b Efloisizs [0B)s EL PRREOLERL BRL LLL 3 BREE EER, FEEL EE i i GiSBR ELLERERREERRRERREEGRIEREREERLERL elL]s 1i 3 rli)l. 525L3A EEE EERRRREERREpREE)El"[F" aa( s 2(0 2): 5 EaE a LH RREEEEER LA IE EE z 25. SE i= f Sz Ss i g 3, 21] $25 5222 252 ji: B 21 .3IH E p.7 3 i. 2 3i 93 l RY REER! | sl! a | ) 2 wo EMelTl8ielgedd|a:3 LN ona Analytical Services p75 Koran as x S ---- February 22, 2010 Analytical Report for Service Request No: K1000968 David Anderson `Camp Dresser & McKee, Incorporated 325 John Knox Road Building M, Suite 100 Tallahassee, FL. 32303 RE: Baron & Budd, P.C./95779-75319 Dear David: Enclosed are the results of the samples submitted to our laboratory on February 03, 2010. For your reference, these analyses have been assigned our service request number K1000968. Analyses were performed according to our laboratory's NELAP-approved quality assurance program. The test results meet requirementsofthe current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.caslab.com. All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. Please call if you have any questions. My extension is 3281. You may also contact me via Email at PDivvela@caslab.com. Respectfully submitted, Columbia Analytical Services, Inc. Project Chemist PD/afs Page 1 of 405" ASTM AA CARB CAS Number CEC CFU DEC DEQ DHS DOE DOH EPA ELAP Gc Gems LUFT M MeL MDL MPN MRL NA Ne NCASI ND NIOSH PQL RCRA SM TPH [3 Acronyms p.76 American Society for Testing and Materials American Association for Laboratory Accreditation California Air Resources Board Chemical Abstract Service registry Number Chiorofluorocarbon Colony-Forming Unit DepartmentofEnvironmental Conservation DepartmentofEnvironmental Quality DepartmentofHealth Services DepartmentofEcology Departmentof Health U.S. Environmental Protection Agency Environmental Laboratory Accreditation Program Gas Chromatography Gas Chromatography/Mass Spectrometry Leaking Underground Fuel Tank Modified Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. Method Detection Limit Most Probable Number Method Reporting Limit Not Applicable Not Calculated National Councilofthe Paper Industry for Air and Stream Improvement Not Detected National Institute for Occupational Safety and Health Practical Quantitation Limit Resource Conservation and Recovery Act Selected lon Monitoring Total Petroleum Hydrocarbons "Trace level is the concentration of an analyte that is less than the PQL but greater thanor equal to the MDL. 2 Inorganic Data Qualifiers p77 + Theron moti, Secv ermine, TThheceomne weit fcioedsteetspolciciabole.tShndcomen utree.ve et gist iv he spl sl dnd by dhe E TDhOeDroomriNtEsLmACcatme.ssnbest he eo sid the ment bron ge 3 TT hereh swnasny clye afrl,aewtamtsmsodttdcecid(tiNdoen-hdeeqkru) ottisngbteMvRLAMeDL. eDOcDo.nGSiUs2] dint:d Aorawiycnve so dteed nd pari es ho LOD oe. ead by te pct Te Toc MKUMDoLrLOIiLoOaiDed def mus ference X Sewcoeommive Q Sec surmive, Oneor morsquiy contd ir ws sie he nis. Metals Data Qualifiers Theconto tnterie ictpcb.Sccn ate. 3 Therein om veOtwu decuitid he utionrng. BE Theperce icefohese don was renethan 10%, nici possible tis nrc in he ple. M Theepicnesecion precisionwastmet. TheMart Sie sample recovery s awithin one i. Secsamie U1 TTheheeprycdwusloeyweedetoerr,bmtinwabsysthtMeeethcotd o(SNatadnedtAed) sdo(irSeAsh)e MELMOL DdODcodmiins oti:d fArniytnwa.sntdct nd gor 4 hn heLODor dein yhrjc The AW Theposition siefor rmceAlysis uofottis, we sslborne is ss an 50% pike TheMRUMDL or LOGOiclested a mais nese X Scocmmonmive. + Thecore coefcintfor MSA i sh055. Q Seecusmaive. Oneormorgui como iciwos uti eit Thereminmute Sec ermine, Organic Dats Qualifies Theconvl crn is otplicable. Sescasesave A Atel deniedcomponed, sopetdsolcondensin prodoct. B TDhOeDaourNcELwAaC fsoanddiedhe soci methodakta eve ti gc uv te ssp els dndby Theme wsqu confinedwio ngOCA eben, ptrcobyi compn ut s, orave. D Theron enlis fom iin. Theres n cutesmnbcs he lo xceddBenentcabin ge J Theron noth ve ttvuected cutie he union ng. IN Thesisrspive.The sli ws ete died,bu confirmation epi snotpeormed. sTyHeEd eHPiLCcofinmatieortn as exceeded. Th hivepestifs grt tha 0%betwee he ov. U1 TDOoDsLaSHwassionlne:d oArm,ibttewowssonttdd ete (Nnt da deped otcs)avhheheMRLIODMDL.1dein y he rjc The eTchteiMoRnLMOLsbrLiOcGoOriDicilnewte ac htop err. QA SSoeocamseesmamriavee.Oveormor etyond eri was utd heirs Additional Petroleus Hydrocarbon Specific Qualifiers FE Thechronic gerpiat afesl ches ie ssi patiote cali sandr. LL rThetchmorunoomf oghepmoilteshweeigsh cloarstes thl,ptecaprnods,notdhelio atten indice te presseof HL eThercrmomomitgubpiac iagopllfaeweisgphceornessiissbatpethecctsrronduc,sibdetdh. hinpor bcs hepres of O TThhechronmumngtapohicpF ica fnoftgbg hherssampppe leieresoet oulfe pil,be tdoprsl ond otce lcihnghei aprmeoinnaealnydhaercoe con 2 Ttthhe ceuipcat hdSoraegseottiomeouhetrcnealbgienppsrlht.eidc. 3 p78 Columbia Analytical Services, Inc. State Certifications,KeAlcscor,edWitAations, and Licenses Program Number | UST-040 AZ0339 [Aransas - DEQ [mse | [ColoadoDPEE [- 1 [[ Fawaipon | Tdaho DHW. rr [ManeDHS__ JwLaAo05m0s0s10 | WA3S 1 [NewMexicoED_ [- | [W[ eUSsotuhathihnDCOgaHir.oolniC DnaODEHEC l1a 6C1O0L02U s] `Wisconsin DNR | 998386840 `Wyoming (EPA Region8) - slLe --S~TN-- - a p79 Case Narrative 5 p80 COLUMBIA ANALYTICAL SERVICES, INC. CPnionhd:aive C0o3m0T031MNi100 n Se, Sec Requestos KIopes CASE NARRATIVE F et r steinoowanom er tnh oaktritin. TWeoe8sapiroemtaetbt--es--atmi--eoln S I e ety waee samples wee sid for saysa t ColumbianaAnaslytwSerie es becween 020310 andA024/:10. erfurinatd Sloe Acids and Peuoinated Carboste Acs by HPLCIMS E -- twE-- am premeord{10-S1e3oCEowcaBnoewnAciTdaitFioeldMSl,nnkd2,BBrroosnosnonR"aRna'w,DMWS&waAsveoryuRiaw'. i tama . Be na e ah ston go ts 2a salto fae hO e covey of Peelsoron{1.2:34-e E C4] tance sid. 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Seexlie 1H1]HT0 D T f2ii:hlhs g 84% SR : l Toe 5 TT Hshly iiHi 1 a FH < a 5 {om a wd] yTr RRLTEO. |HHH [1] HHH: Soke A G4 ' 3: Ho w S ahoyol11]HHA &fels 5 z H[1]TTT] FfHe 1 5<iiillllS ] n]ss HHE E H BE --3[Sih1lar:-- i B AT110E TLIEE5455| 3ly 3 qs LL 4 Ig [23] I1T]TEEEES i iFoohls S5E; se Bi f IT| = T] 81 E=i34t 23 i 3 ln 1 1 4784 [2 dE 1] bipl fl Jit, F 80 | cd F Sg n |: T 9 il >SB FL Fosfi i6 atiriatse y ||a se vas Sf HEHHH0 iH Nl3 Bo H i i= e o & [] H iif RN = 4 = s 6 s i SyH n HE[=<][] ik EN T o S Sitio, Hh HE 5 E n f i =8 = ET fsap 1s 2 : =--~ ll sol)e a i sl g3:3 = 5 Hi Hi 8 81a :: Xs5s - 2 I Hi 2 So S TReNea <2 Nl 5 f i C] in d: igols8 is Ie uy H e <Zins b TT|]I] [][I] [ 3H:iie i23 5 : El 2 3 Ly B [ ]1 i a |I 7i | i g=f, = la | % n 11 R2i(Re14d953394]4 | 2 iSRTelei )i B eHsadgizgd|leB i s l 54 3 CHT<o 1I2T5~ C[1]1HEE : i, inl 3}fl 2 0 n gi l 2E y J Els 3 NiEE A|i ` ffiinltinHE i 2 i a 9 HH hE 3 36 gEc s ! 3! 3m _o o L R Cooler Receipt and Preservation Form p85 Client Project; Received: Opened: Servis Request K10 (V0 J Lo f/ Vl sy Pitre. Sievers Ta | Samverpe olseestia (TDD UPS bHL Z Cowier HandDeivered 2 Semerprecliveedin (rl) Cor, Box Bwelope Other wm 3 Weemsotveslcnceder? NA EE Tr --71 2.1 | p| 2H TE [=p2[03 gp [Tr [25 7 277 xe] Cre qrTyg[Tx] 7. Packing materialused. Inserts GEEEEI>BubbleWrap GelPacks QWETTEE Sleeves Other Lm 58.. DWiedrelclubstootdyspaapveersipnrgopoerdlycofinldlietdioountu(innbkr,okseing)n?ed,eItc)n? diihecalaebteloew. 10. Wereall ample bescompete (.canalysis, preservation, ic)? 11. Did lfsamplelabelsandtgs agreewithcustody papas? Inicte major discrepancnitehsetable onpog2e 12. Were appropriseabndvooltumels eeseliveod onrtsheeitsninedicsatsed? 13. Were hepfpreserved bes GeSOGENSOP) escive at hespreepi? Indicaabebtloew 14. WereVOA vas recived without headspace? nic i hetbe elo: 8:NxAa xN xa x NA x NA x (SA YN a Tm Sea eel rr EE EE icin Somes Sonata nite] on | mongers" | RES |e [ Lr r rrr r rr r r rr rrr rrr rr rrrrrr [rrr TTT [T rT r Notes, Discrepancies, & Resolutions: 12 Page 1of EEL ETE]TRE on i] CoorlnersReceisptvanndevaPnrses servaytionaFiorm pry Client /Project. chm Service Request K10__CO 7, 5 Ressived:__2 [3/15 Opened [3/0 By Lr 1. Samverpsrelciveedvsia? Mail (FGETS UPS 2 Samrsprclheedin Cle) COT Bos DHL PDX Courier mele Other Hand Delivered na 3 Weeasodvieioncooen? NA N ifyesbowmaryand whe Jad Ifpresent,werecustodysealsinact? ~ presen,wertheysignedand ded? >x 0 [asp [ey Ee [egToe [27 Cr [1] 7 acingmtr rsBEEre Fs les Or 7] 8. 5. DWiedraelclubsteodsypaapveersipnrgopoeordlycfoinldlietdioonut((binrko, ksiegnne?d,ec tc)? a nthet fablee belo, Na N NA oN 10. Were il sampleaescomple.snl,preston, cio? 11. Did lamp bl20 gs te wihcustody pes? dct mordiscrnpealnecniges2 NA ) 12. Wereappropriatebotlescontsiners andvolumesreceivedfo th tests indicated? Na oN 13. 14. WWeerreetVheOpAHv-apsrreecseievbreodlvwtlieetdsho(usteehSesOdsGpEcNe?SOIP)nrecdeiivniedhaecttthaaeleatpbperelopor.iatepH? Indinihectabalebteleow (3 @ YvxN 15. WasCI2Resnegive? vn Notes, Discrepancies, & Resolutions:ee ese --e -- _--_-- -_-- _-- -_-- eeaa---------------- --_---- BN Page1 of p.68 Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPCL/MS 14 Client: Project: Sample Matrix: Sample Name: Lab Code: AnalyticalReport B`Caamp&rDrBoeusdnsde,&rP.MCc/K9e5e7,79I-n7co5r3p1o9rated (CDM) Water FieldBlank 2 K1000968-001 p89 SeDravtieceCoRlelqeucetsetd:: 2K/120/01009068800 Date Received: 2/3/10 UBnaistiss:: nNgA. Perfluorinated Sulfonic Analytical Method: PFOA Prep Method: Method Analyte Name PPerefliuooror-notrnidetcaenoricdacoiscdand oc Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannceicSuAlfcoindate: PerfluorodecanoicAcid PPeerrfflluuoorroohdeopdteacnaoniociAccAicdid Perfluorohexanesulfonate: PePrefrlfulouroroonhoenxaanncoiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorroopoecnttaanniocicAAcciidd PerfluoroundecanoicAcid Result Q NUD ND U ND U 047] ND U ND U NNDD UU 019) 023] ND U 018 J ND U 033) ND U Acids and Perfluorinated CarboxylicAcidsby HPLC/MS MRL MDL 30 0% 50 09s SO 0029 50 on 50 0095 50 048 5S0O 0008BsL SO 0030 50 on 50 on 50 0046 SO 006 50 on 50 13 Dilution Factor Date Extracted T Wun 120 1 2810 L810 1 M0 1 10 I1 228100 1 2810 I 2810 1810 1 2810 1 210 I 810 1 810 Date Analyzed ToT 29/1000:10 29101055 29101035 29M000:10 29/1000:10 2299/0101000:5150 29101055 29101035 291000:10 291000:10 29100010 29101055 29/1000:10 Extraction Lot TO 105653 105653 105653 105653 105653 110055665533 105653 105653 105653 105653 105653 105653 105653 Analysis Lot Note HT 190530 190530 190530 190530 190530 119900553300 190530 190530 190530 190530 190530 190530 190530 Surrogate Name %Rec Control Limits Date Analyzed Q Note EE Perfluoro-n-{1,2,3,4-13C4] butanoic acid 7" 50-10 2T 09710T10:55 PPeerflluuoorroo--nn{{11,,22-,1334C-21]3dCe4c)aoncotiacnaociciadcid 9 100 50-10 50-150 2091000:10 29100010 PePrefrlfulouroor-on-n--{{11,,22--1133CC22]]dhoedxeacnaoniociaccAicdid 7 2) 50-150 50-150 29710 10:55 2971000:10 SPeordfiluumopro-en-r{1f,2l-1u3Co2Jr4un1od3e0-c4a)n1oai-cct{aAnce1isud.lfo2ns3te 748% S150 50-150 29100000 291000:10 Sodium perfluoro-1-hexane[1802]sulfonate: 0-150 20910 10:55 -- Co-m_m--ents: -_-- Pred223101337 a UU ummm Fama SupaRetemce. 100000ev800 15 CPlrioejnetc:t: Sample Matrix: Sample Name: Lab Code: AnalyticalReport Ba`Craomnp D&rBeusdsde,&rP.MCc9K5eTe7,9I-n7c5or3p1o9rated (CDM) Water University Parkviay "Raw" KI1000968-002 p.90 Service Request: Date Collected: K1000968 2/2/100812 Date Received: 2/3/10 Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS. Analytical Method: PFOA Prep Method: ~~ Method - AnPearloyotreo-Nnatmeetra_dec__an_o a_cid_. Perfluoro-n-ridecancicacid Perfluorobutanesulfonate PPeerrlfluuoorroobduetcaannoeicSuAlcfiodrate Perfluorodecanoic Acid PPeerrfflluuoorroohdeopdteacnaoniociAccAicidd Perfluorohexancsulfonate PePrefrlfulouroroohneoxnaanncoiiccAAcciidd Perfluorooctanesulforate PePrefrlfulourooroopcetnatnacniociAccAicdid Perfluoroundecanoic Acid Rest @ NU ND U 012 0N1D81U ND U ND U 001182 JJ 0351 ND U 031) ND U 025 J ND U Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Analyzed Lot Lot Note 30 046 50 095 50 009 5500 0o0l5r5 50 048 50 085 5500 000080L 50 on 50 on 50 004 50 0066 50 oll 50 13 1 1 2/810 2810 2500018 29100013 10% 105653 190530 190530 1 2810 2901104 105653 190530 11 228/0100 29101104 20000:18 105653 105653 190530 190530 1 2810 2/9/1000:8 105653 190530 1 1 2810 28N0 29000018 29001104 103653 105653 190530 190530 1 2/810 2901104 105653 19030 T2810 1 U8I0 29101104 29100018 105653 105653 150530 190530 1 2810 29000018 10653 19030 1 1 2/810 U8I0 2/9/000018 2901104 103653 105653 190530 190530 1 U8I0 29100018 105653 190530 SuPSreurrrfrologvgoaarttoee-nNN{aa1mm,2ee,3_4,5_-13_C5]_no_man_oic_aci_d _ PPeerrfflluuoorroo--nn--{{11,.22,,33,,44--1133CC44]]obcuttaannooiiccaacciidd PPeerrfflluuoorroo--nn-{{11,,22--1133CC22]]dehecxaannooiiccaacciidd PPeerrfflluuoorroo--nn--{{11,,22--1133CC22}Jduonddeeccaannooiicc AAcciidd Sodium pefloro-1{1.2,3,4-13C4]ccanesulfonate Sodium perfluoro-1-hexane(1802]sulfonate 7%RReecc sns 100 @ 5545 60 7 Control Date m0Li1mi5st0s A29Aw 7na0l0yd 0ze7d89Q TNoFte 550014550 229910000101:1084 50150 50050 297100018 29101104 5500005500 2299//11000000::1188 5045 5045 29/1000:18 29/10 1:04 Comments: _e VPrieod2S 2310 n 1337 ir -_ mm _ _ Femin 16 Sipe Rlerms 0B 000 Client: Project: SampleMatrix: SLaambpCloedeN:ame: Ansytca Report BCaarmonp &DBruded,&sP.MsCc.Ke9e5er7,79I-n7c5or3p1o9rated (CDM) Water KUn1i0v0e0rs9i6t8y.0Pa0r3kway "Treated" had SeDravtieceCRoelqleucetsetd::2/K21/001009068522 Date Received: 2/3/10 Units: Basis: nglL NA Perfuorinated Sulfonic Acids and Perfluorinated Carbosyic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name PPerelulouroo-rn-ornidceacadnoeiccaacnisdoacd Perluorobutanesulfonate PPeerrfflluuoorroobduetcaannaeiScuAlcfoindate Perfluorodecanoic Acid PPeerrfflluuoorroohdeopdteacnacniccicAcAicdid Perflvorohexancsulfonate PePrelruflouroornoohnexaanncoiicc AAcciidd Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaoniocicAAcciidd PerfluoroundecanicAcid Realt MRL MDL ND ND U U 050 0% oss 013 J 50 009 055 018 1 50 SO on 0095 ND U SO 048 NNDD UU 5500 0o0sSsL 018 J 50 000 ND U ND U so 50 on on 036) 50 008 ND 014 U 5$0000o6n NU 50 13 Dilution Date Factor Extracted T12W80h 0 1 uI0 I 1 uSN0 u8M0 1 210 T1 28u1$M00 1 u$N0 I I UI0 2810 1 B10 1 I 2810 UI0 I U810 Date Analyzed Extraction Lot AnaLloytsisNote 2T9100 0025010 065301w 90530T 29101114 10563 190530 229910000100215 105653 105653 190530 190530 29100025 105653 150530 229S100I00L2I5 110055665533 190530 190530 2901014 105653 190530 229010000101215e 105653 105653 190530 190530 29100025 105653 10530 229910010101245 105653 108653 190530 190530 29100025 105653 190530 Surrogate Name %Rec Control Limits Date Analysed Q Note PPeerrflluloiroo-rno-{n1{,12,2334.1341C.34]50-bumtaonmoincoaccsided 8U%o 305101530 0 0Ww1moswm PPeerrfflluuoorroo--nn--{{11,22.-31,34C-21)3Cd4e]caoncotiacnoaiccidcid % 100 50-10 5010 22997110000002255 PPeerrlfulouroor-on--n{{11,,22--1133CC22]JdhoedxeacnaoniccicacAicdid 7 49 50-50 sas 22900000112154 SPeordfolumopreor-lni-c{r1o,12--(113.C223Ju4n-d1e3c0an)ooiccanAecmiidfonste 463 1+ sS0d1s0 229910000002255 Sodium perfluoro-1-hexane{1802}sulfonate 7 S050 2901114 a Com_--ments: _-- NPriemed2t231i013m 37 pi Fom1a Sosa Toot 7 Client: Project: Sample Matrix: SampleName: Lab Code: AnalyticalReport `CampDresser & McKee, Incorporated (CDM) Baron &Budd,P.C/95779-75319 Water McCory"Raw" K1000968-004 p.92 S`eDravtiecCeolRleeqcuteesdt:: 2K/120/01009068348. DateReceived: 2/3/10 BUansitiss:: NngAlL Perfluorinated Sulfonic Acids and Perflorinated Carboxylic Acids by HPLCIMS Analytical Method: Prep Method: PFOA Method -- AnPearlfyotoeroN-animcetradecanor 3d Perfluoro-n-trdecancicacid Perfliorobutancsulfonate PPeerrfflluuoorroobduetcaannoeicSuAlfcoindate: Perfluorodecanoic Acid Perfluorododecancic Acid PPeerrfflluuoorroohheexpatnaensouilcfAocniatde PePrefrlfulouroorohneoxnaanncoiiccAAcciidd Perfluorooctanesulforate PePrelrufolurooroocpteantnacniociAccAicdid Perfluoroundecancic Acid Result Q No U ND U 035 J 0421 ND U ND U ND U 0147631 117 ND 095 JU 05828 1 ND U MRL MDL Diluon Factor Date Extracted Date Analyzed Extraction Lot Analysis Lot Note 30 04 50 095 1 1 50 009 1 50 oll 50 0095 1 1 50 048 1 50 085 1 5500 0000S0L 11 50 oil 1 550000o4n6 11 5500 0o0l6l6 I1 50 13 1 Z/I0 2/810 20700033 29100033 10565 103653 190530 190530 28N0 2901123 105653 190530 210 28N0 29101123 29100033 105653 105653 190530 190530 28N0 2/9/1003 105653 190530 2810 28M0 29100033 29101123 10653 105653 190530 190530 8/0 29001123 105653 190530 2810 29101123 10653 190530 W2/I8100 I29N10000003333 11005566533 11990053300 U2/8010 29100033 29101123 103653 10563 190530 190530 810 29100033 105653 190530 Surrogate Name Control %Rec Limits Date Anslyzed Q Note PPeerrflluuoorroo--nn{-{11.,22,,3344-,153-C143C]5b]uotamnaonicciacciadcid 658 SO01405 200200100131233 -- PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21)3dCe4c]anoocitcanaociicdacid 91200 50150 5015 2/9/100033 29100033 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]}hdeoxdaecnaonicciaccAicdid 7 36 5045 50450 29101123 29/1000:33 SPoedrifulmuopreor-lnu-o{r1o,-21-{1132C,23J4u-n1d3e0s4a]ncociacneAscaildfonste 764 5005 50450 297100033 297100033 Sodium perfluoro-1-hexane{180Z]sulfonate 5 50050 2901123 owes Prineor2a231013c3s7heAny Fem 1a SipsRt 10D 18 Client: Project: Sample Matrix: Sample Name: LabCode: Analytical Report `Camp Baron Dre&sMscKeeer, Incorporated &Budd, P.C/95779-75319 (CDM) Water McCory "Treated" K1000963-005 Ls Service Request: K1000968 Date Collected: 2/2/10 0858 Date Received: 2/3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: ~~ Method. Analyte Name, Pelioroniciadesaanodc Perfluoro-n-tridecanoicacid. Perfluorcbutanesulfonate: Perfluorobutanoic Acid `PPeerrfflluuoorrooddeeccaanneicSuAlcfiodnate PerfluorododecanoicAcid Perfluoroheptanoic Acid `Prerfleuoreohexancsulfonate Perfluorohexanoic Acid PerfluorononanoicAcid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.35 J 040 1 0121 ND U ND U 054 J 181 107 ND U 0.88 J 50 082 J ND U MRL MDL Dilution Date Factor Extracted Date Extraction Analysis Analyzed Lot Lot Note 30 0% 50 09s TZN TOOT ToS To -- 1 28N0 29100040 105653 190530 50 009 1 8N0 2901133 105653 190530 50 onl 50 0095 1 1 2810 29001133 105653 190530 U0 297100040 105653 19030 50 0a 1 810 29100040 105653 190530 50 08s 50 0081 1 1 2810 2810 29100040 2901133 105653 105653 190530 190530 500 0000 30 11 50 on 1 81I00 229910011113333 101055665533 191900553300 UBI0 2901133 105653 190530 EX 50 0046 1 1 U0 28N0 29700040 297100040 105653 105653 190530 190530 50 0066 50 onl 1 1 810 2810 29100040 29001133 105653 105653 190530 190530 50 131 2810 29/1000:40 105653 190530 Surrogate Name %Rec PPeerrfflluioorro-on--n{112,,23,.34,4.-51-31C34C]3]bumtanooicmaciandcdoic 77 6 Perfluoro-n-{1,2,3,4-13C4] octanoic acid Perfluoro-n-{1,2-13C2] decanoic acid 3 100 Perfluoro-n-{1,2-13C2] hexanoic acid Perfluoro-n-{1,2-13C2}dodecanoic Acid 7 47% ``SPoedrifulmuopreor-fnuo-r{o1-,12--{113.C223],u4n-d1e3cCa4n]ooisctaAncesiudlfonate: 49% 60 Sodium perfluoro-1-hexanc{1802]sulfonate 81 Control Date Limits Analyzed Q 30.10 2pM00040 50150 0-150 29/1011:33 2/9/1000:40 0-150 2/9/1000:40 50-150 29101133 S050 29100040 50450 50-150 29/1000:40 2/9/1000:40 50-150 29/1011:33 Note - Comments: --_-- -_-- Prlimeod2t23/i10L13:i37eAmine Uv Fom 1A SopaReamee: 1640003513rev0 19 Client: PSraojmepclte: Matrix: Sample Name: Lab Code: Analytical Report `BCaampD&rreBosusdendr,&P.MCc/K9e5e7,79I-nc7o5r3p1o9rated (CDM) Water Duravay "Raw" K1000968-006 p94 SDearvtiecCeolRleeqcuteesdt:: K1000968 2/2/100929 Date Received: 2/3/10 Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carbosylic Acids by HPLC/MS. AnParleyptiMcetahloMde:th~od~: PFOA Method Analyte Name PPerefrlluuoorroo--nn--t{reitdreacdaencoaincoaiccaicdid. Perfluorobutanesulfonate PePrefrlfulouroorboduetcaannoeicSAulcfiondate: PerfluorodecancicAcid PPeerrlfulouroroodhoedpetcaannciocicAAcciidd Perlorohexanesulfonate PePrefrlluuoorroonhoenxaannociiccAAcciidd Pefluorooctanesulfonate PePrefrlfulourooropoecnitaanncoiiccAAccidid PerfluoroundecanoicAcid Result Q NOU ND U 015 J 029 NNDD UU ND U 015 3 056 1 034 ND U 047) ND U 033 J ND U MRL MDL Dilution Date Factor Extracted Date Analysed ExtrLaocttion AnaLloytsisNote 30 0% 1 Z/I0 29000048 1055 e19e0530 50 095 50 009 1 1 2810 2810 2/9/1000:48 29M01142 103653 105653 190530 190530 50 oul 50 0095 1 1 810 2/810 20001142 29100048 105653 105653 190530 19030 50 048 1 2/810 2/9/100048 105653 190530 50 085 50 008L T2810 1 2810 290100048 29101142 105653 105653 190530 19030 50 0030 1 2810 29001142 105653 190530 50 oul 50 012 I 1 210 2800 2900114 2/9/1000.48 105653 105653 190530 19030 50 0046 1 2wI0_ 29M00048 10565 190530 50 0066 50 on 1 1 2810 210 2/1000:48 2901142 103653 105653 190530 190530 50 13 1 2810 29100048 105653 190530 SSuuPrerrrofolgguaaotrtoee-nNN{aa1m.m2ee,3,,5-13C3] noranoic acid PePrefrlfulouroor-on--n{-1{,12.2,,33,,44--1133CC44]]boucttaannooiiccaacciidd PPeerrfflluooorroo--nn-{{11,,22--1133CC22])dheexcaannoiiccaacciidd PePrefrlfulouroor-on-en{-{11,,22--1133CC221]duonddeeccaanncoiiccAAcciidd Sodium perliro41-3041){cta1nes.ulf2ors3te Sodium perfluoro-1-hexane(1802]sulfonate Control Date %RReecc mLimibts AnAnielyzred 9Q TNoFte 5 8 S010 50450 29700048 29/0112 1800 5500405500 22/99//11000000::488 &7 S50040550 2299//11000101::428 &75 5500445500 22990110000004488 85 50150 2901142 Comme- nts -- Prlinoe 2S2u3t1i0n1r35a7pAyer Fem1A Sth 000000 20 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Regert `BCaarmopnD&rBuedd,s&PMs.cCK/e9e5er7,79I-n7co5r3p1o9rated (CDM) Water Dunaway "Treated" K1000968.007 p.95 Service Request: K1000968 DDaatteeCoRlelceecitveedd:: 22//32//11000939 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Analytical Method: PFOA Prep Method: Method Analyte Name PePrefllluoiroor-no-nt-ritdeeicanndceiccaacniaodsicd Perflvorobutancsulfonate PePrefrlfulouorroodbeuctaannoeiSculAfcoindate Perfluorodecancic Acid PPeerfflluuoorroohdeopdteacnacniccicAAcicdid Perluorohexanesulfonate: PePrelruflouroorhoenxonaannooiiccAAcciidd Perflvorooctanesulfonate. PePrefrlfulourorooopcetnatnaoniocicAcAicdid PerfluoroundecanoicAcid Rest Q ND U 0N1D4 JU 015 J ND U ND U ND U 0093 J 055 1 033 ND U 0381 0N1D8 U1 ND U Acids and MRL 50 5500 50 50 50 50 50 50 50 50 50 5500 50 Perfluorinated Carboxylic Acidsby HPLC/MS MDL Dilution Factor Date Extracted Date Anahzed 046 1 095 1 790 uWI0 0029 1 810 on 0095 I 1 UBI0 280 048 1 R10 085 0081 1 1 2WI0 UI0 0030 1 810 ol on 1210 I B10 0046 1280 0o0ul6 11 2288100 13 1 2/810 2900035 2299100001013552 29101152 2000:55 29000:55 29100055 29M01LS2 29M01152 29001152 29100055 29M000:55 290000:55 29I0ILS2 297100055 Extraction Lot 1065 110055665533 105653 105653 10653 105653 105653 105653 103653 10553 105653 103653 108653 108653 Analysis Lat Note 00 119900553300 190530 190530 190530 190530 19030 190530 190530 190530 10530 190530 190530 190530 SurrogateName PPeerrfflluuoorroo--nn-{{11,,22,,33,.44-,153-C134C]3b]utnoarnmoaincoraeciadcid. PPeerrlluuoorroo--nn--[{11.,22-,1334C-21]3Cd4e]caoncotiacnoaiccidacid PPeerfflluuoorroo--nn--{{11,,22--1133CC22]JhdeoxdaecnaonicciaccAicdid PSeosdfiluumopreor-lnu-o{r1o-,12--(113,C223u,n4-d1e3cCa4n]coiccaAncesiudlonate Sodiumperfluoro-1-hexane[ 1802]sulfonate. %Rec 7 5%80 100 65 366 7s 7 Control Limits 30-130 55001405 50150 50150 5500-4150 5045 5045 Date Analyzed Q 297100055 220911001010:5552 29100055 29101152 2299110000005555 29/1000:55 2901152 Note -- -- Comments: _-- _9-- m9mB09090TT90U0U0U0Um_ Pilnoa s22e31r01s337 cen Fema Serbo 00035120000 21 Client: PSraojmepclte: Matrix: Sample Name: Lab Code: AnslyticalReport BaCramopnD&Bruded,s&PM.scC/Ke9e5er7,79I-n7co5r3p1o9rated (CDM) Water LKiIl1l0i0an09"6R8a.w0"08 p.% SeDrvaitceeCoRlelqeucetsetd:: K1000963 2/2/10 1004 DateReceived: 2/3/10 Units: ngll Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated CarboxylicAcidsby HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name PPeerrfllluuoorroo--nn--ttreitdreacdaencoaincoaicci3d6 Perlluorobutancsulfonate. PPeerrflluuoorroobduetcaannoeiScuAlcfiondate PerfluorodecanoicAcid PPeerrflllvuoorroohdeopdteacnaonicciAccAicdid Perfluorohexancsulfonate PPeerrfflluuoorroonhoenxaannociiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuorroopoecnttaanncoiiccAAcciidd PerfluoroundecanoicAcid Ret@ No U ND U 193 207 002660 3J ND U 26911 47) 061373 82 N5D1 U MRL MDL 50 50 04 09s 50 0020 50 onl 5500 0004985 50 08s 5500 0000801 50 oul 5500004on6 50 0066 5500 o1n3 Dilution Date Factor Extracted AnaDlaytzeed ExtrLaocttion AnaLloytsisNote 1 I 2J/88I2 00 5 29100 010301010 0556655301190 0050303 1 2810 2901201 105653 190530 T2810 1 2WI0 29101201 2M/100103 103653 105653 190530 190530 1 2810 2/900103 105653 190530 I 1 2/810 2810 29700103 29M01201 105653 105653 190530 190530 1 2810 2/9M01201 105653 190530 I 1 2/10 810 20001201 29700103 105653 105653 190530 190530 1 2810 29000103 105653 190530 1 1 2810 2810 29100103 29101201 105653 105653 190530 190530 1 2800 2/9/0003 105653 190530 Surrogate Name PePfelrufolruoo-rno{-1n,{21,,23,.344,-51-31C34C]3]buntoannaonicciaccaicdid PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21)3dCe4c]aoncctiancoaicciadcid PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]hdeoxdaencaoniociacciAcdid PSeordfiluumopreor-lni-o{r1o,-21-{131C.22J3u4n1d3e0ca4n)ocicctaAnceisudlforste Sodium perfluoro-1-hexane{1802Jsulfonate Control %Rec Limits AnDaaltyzeed Q Note El " 0050 2W/10010 -- 50450 29/10 12:01 88 100 5015 5045 29/1001:03 2/1001:03 8 46 + 50450 50450 29/10 1201 29100103 4647+ 5500145500 2299/11000011:0033 8 50050 29101201 cower poreSd 2t2310r1e337am Femi Spahr 1080080) 22 Client: Project: Sample Matrix: LSaambplCoedNea:me: Analytica Report BCaarmopn D& Bruded,&sPM.scCK/ee95er7,79I-n7co5r3p1o9rated (CDM) Water KL1i0ll0i0a9n6"8T.re0a0t9ed" p97 SerDvaitceeCRoelqleucetsetd:: 2K/120/010096180.15 Date Received: 2/3/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS APnraelpytMiectahloMde:thod: PFOA Method Analyte Name PPeerlluiooron-nntcriidaedceacnaoincoaicciadcd Perfluorobutanesulfonate PPeerrflluuoorroodbeuctaanneoiSculAfcoindate. PerfluorodecanoicAcid PPeerrfflluuoorroohdeopdteacnaoniccicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroonhoenxaanncoiicc AAcciidd Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaoniocicAAcciidd PerfluoroundecanoicAcid Rest ND U_ ND U 19) 181 ND U NDU ND U 303 8 467 056 1 1 Bs N5D2 U MRL MDL 30 04 550000089s 5500000o9n5 50048 50 SO oss 008L 50000 50 50 oul on 50 0046 50 50 006 on 50 13 Dilution Date Date Factor Extracted Analyzed 1 1 JE U8I0 2HM00TTT 2910011 1 u$N0 29N0I211 1 1 UI0 28M0 229900001121011 | 810 29000011 1UUs2I8M00 22990/10201111 1 $10 29M01211 TI 28U18I00 2299010010211111 1 10 2900111 1 I 2810 U0 229910010201111 I U810_29M00111 Extraction Analysis Lot Lot Note 106 105653 TOR-- 190530 105653 190530 103653 103653 190530 190530 105653 19050 105653 105653 190530 190530 10653 190530 103653 105653 190530 190530 108653 190530 105653 103653 190530 190530 105653 190530 Surrogate Name %Rec CLoinmtirtosl PPeerrfllluioorroo-nn{-1(.12,233.,44,-51-31C34C]5b]utnaonnoaincoaicciadcid 7 7 50-150 50150 PPeerrfflluuoorroo--nn--{{11.,22,131,34C-21]3dCe4c)aoncotiacnaociciadcid 2 100 5015 50450 PePrefrlfulouroor-on--n-[{11,.22--1133CC22}]dhoedxeacnaonicciaccAicdid 4"8+ 5500415500 PSeordfliuuomrpo-en-{f1,l2-o13Cr2Jou4n-1de3c-0a4n{)oaic1ctAan.ccisu2dlfo,nst3e. 3690 + 5500015500 Sodium perfluoro-1-hexane{1802]sulfonate 8 50-150 Date Anslyzed Q ZOM0OTIT 2299701000112:1111 2209110010201111 2299M00001L0111 29100811 2910 12:11 Note -- C-om--ments: -_-- Plroa2c211k0 e13r37Arie 0U0Uumum9m909m909m0m Ramin 23 Super Reterce 1000281230 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report CampDresser& McKee, Incorporated (CDM) Baron &Budd, P.C/95779-75319 Water Bronson "Raw" K1000968-010 p.98 Service Request: Date Collected: K1000968 2/2/10 1041 Date Received: 2/3/10 UBnaistiss:: nNgAlL Perflorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS. Analytical Method: PFOA Prep Method: Method Analyte Name PePrefflluuoorroo--nn--ttreitdreacdaencoaincoaicciadcid Perfluorobuanesulfonate PerfluorobutanoicAcid PePrefrlfulourooroddeeccaannoeicSAulcfiondate: PePrefrlfuluoorroohdeopdtecaanniociAccAicdid Perfluorohexanesulfonate PPeerrfflluuoorroohneoxnaannociiccAAcciidd Perfluorooctanesulfonate PePrefrlfulouroroopoecnitaannooicicAAcciidd Perfluoroundecancic Acid Ret Q NU N4D51U 54 0N1D6 3U N7D7 U 3 1 098 1 ss 2s 13 ND U MRL $0 5500 50 5500 5500 50 50 50 50 50 50 50 Dilution Date Date Extraction Analysis MDL Factor Extracted Analyzed Lot Lot Note 046 095 1 1 2/810 2810 29000018 29/100118 105653 10653 190530 190530 0029 1 28N0 29/001220 105653 190530 oan 0095 T1U u8I0 2/810 29001220 29100118 105653 105653 190530 19030 048 1 2/810 2/9/0018 105653 190530 0008851 11 22/881100 2900018 29101220 10563 105653 190530 190530 000 1 2/810 2/9/101220 105653 190530 oll 012 1 1 810 2810 29101220 29100118 105653 10353 190530 190530 0046 1 U8I0 29000118 105653 190530 0066 on 1 1 2810 U0 29/100118 29101220 105653 105653 190530 190530 13 1 810 29100118 105653 190530 SSuurroroggaatteeNNaammee _______ Control RReec ULimmits AAnwDlaywtzee?d 9Q TNoFte PPeerrufolruoo-rno-{n1-,{21,23.34,,45-1-31C34C]5]buntoamnoaincoiacida.cid 5 7 0150 29/0088 5050 29101220 PePsefrlfulouroor-on--n{-1{,12,2,-31,34C-21]3Cd4e)cacntoaincoiaccaidcid 105 100 50150 50450 200118 29100118 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]}dhoedxeacnaoniocicacAicdid 386 5005 50150 297101220 29100118 PSeordfiluumopreor-lni-o{r1o,-21-{113.C223]4u-nd1e3c0a4n]ociccanAecsiudlfonste 4790 + 50450 5045 29/0008 2900018 Sodium perfloro-1-hexane(1802Jsulfonate 81 5045 200101220 Comments: -- ee ----------------e -- rr-- or --- Plreenta2S2t3n1s01337 Ans [I Soe Rt OO 2 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Repert (BCaamrpoD&nreBsusdedr,&PM.eCK/e95e7,79I-n7co5r3p1o9rated (CDM) Water BKr1o0n0s0o9n68".T0re1a1ted" p.99 Service Request: Date Collected: K1000968 2/2/10 1054 Date Received: 2/3/10 BUansiitss:: NngAll Perfluorinated SulfonicAcidsand Perfluorinated Carboxylic Acids by HPLC/MS APnraelpytMiectahloMde:thod: MPeFtOhAod Analyte Name PPeerrfflluuooror-on-tnr-icdiercaadnooiccaancoiidcad Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeicSuAlcfiondate Perfluorodecanic Acid Perlluorododecancic Acid PePfelrufolruoorhoehxeapntcasnouilcfoAncaitde PePrefrlfulouroorohneoxnaannooiiccAAcciidd. Perflvorooctanesulfonate PePrefrllulourooroopcetnatnacniociAccAicdid Perfluoroundecanoic Acid Ret Q MRL MDL Dilution Date Factor Extracted Date Extraction Analysis Analyzed Lot Lot Note NNDDUU_ 5500 004965 1 1 2288100 2991701000113266 1100555%3 1019055300 12 SO 029 1 uWI0 29101230 105653 190530 N9D7 U 5500 0o0n95 I1 28/1100 2299110010213260 110035665533 119900553300 ND U 50 048 | 810 29100126 105653 190530 ND U 18 50 085 50 00BL 1 1 2810 2$M0 29000126 29101230 105653 108653 190530 190530 8 50 000 1 2810 2901230 10653 10530 3 161 50 ol 50 on 12/810 I 810 29101230 297100126 105653 108653 190530 190530 8 50 0046 1 2810 29100126 105653 190530 32 5500 0o0n6 11 22/88100 22590/001021320 110058665533 119900553300 ND U 50 13 I 28N0 209100126 108653 190530 Surrogate Name %Rec CoLnimtirtosl Date Analysed Q Note PPeerrflluuoorroo-n--n({11,22,34.-1435C-41]33b]urtoamnaonicoiaccaicdid 89 " 50050 moore 50-10 29101230 PePrefrlfulouroor-on-{n1{,12,,23-143-C21)3de4c]aoncotiacnoaicciadcid 1%000 5045 5015 29100126 29100126 PPeerrfflluuoorroo--nn{{11,,22--1133CC22]]hdeoxdaencaonicciaccAicdid 8 52 5015 20101230 50150 2/1001:26 PSeordliuuomrpoe-rnf-u{o1t,o2--11-3{1C22,J3u4n-d1e3cCa4n)cciccuAnecsiudfonate 754 5500415500 29100126 2/9/100126 Sodium perfluoro-1-hexane{102)sulfonate: 9 50050 29101230 -- Comments: _-- re r ---------------------------------- Prineena22S3m1a0l1337pA Fania Spr Rene: 100m v0 25 Cleat: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report `Camp Dresse&r McKee, Incorporated (CDM) Baron & Budd,P.C/95779-75319 Water West Pensacola "Raw" K1000968.012 p.100 Service Request: DateCollected: K1000968 2/2/10 1203 DateReceived: 2/3/10 Units: ngll Basis: NA Perfluorinated SulfonicAcidsandPerfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name PPereflforuoo-nr-tornideecmandoeicaacnaiodccd Perfluorobutancsulfonate Perfluorobutanoic Acid PerfluorodecaneSulfonate: PPeerfflluuoorrooddeocdeacnaoniociAccAicdid PerfluoroheptanoicAcid Perfluorohexanesulfonate PePrefrlfulouroroohneoxnaanrcoiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorroopoecnttaanncoiiccAAccidid Perfluoroundecanic Acid. Rewlt @ MRL ND U 30 0N3D5 JU 5500 0547 50 ND U 50 NNDD UU SO50 074 3 25] 50 50 0927 063 50 50 59 50 271 087 5500 ND U 50 Dilution MDL Factor 046 1 0009s9 1I oan 1 0055 1 040885 11 008L 1 0030 1 oun 1 012 1 0041 0o0n66 I1 13 1 Date Date Extraction Extracted Analyzed Lot 2/81029100133 2/810 29M00133 105633 105653 2810 2/9/01240 105653 2810 2810 29101240 29100133 105653 10563 8281100 225901000113333101505665533 2800 2810 297101240 2901240 105653 105653 210 2800 29101240 29100133 105653 105653 2810 200133 105653 2u8I100 2299/00100214303 110055665533 28N0 2/9/100133 105653 Analysis Lot Note 190530 119900553300 190530 190530 190530 11990053300 190530 190530 190530 190530 119900553300 190530 Surrogate Name PPeerrflluuoorroo--nn-{{11,,22,,334,4,-51-31C34C]b5u]tnaonnoainccaicciadcid PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21]3dCe4c]aoncotiancoaicciadcid PPeerfflluuoorroo--nn{{11,,22--1133CC22]1hdeoxdaencoaniociaccAicdid Pe`rSuoodiruom-pne-r{l1u,o2r-o-113{C12.]2u3n4d-e13c0a4n)cicctAnccuildforate Sodium perluoro-1-18h0e2sxulafnoneat(e Control %Rec Limits 0 8 010 50150 102 50050 1"00 5500005500 A+ 44+ 50050 505 63 5045 5 50450 Date Analyzed Q 29291000010:430 297100133 2299/711001021:3430 29100033 29100033 29/100133 209/10 12:40 Note -- n_ ers: ----- pB ried22310 1337d Fama SoRp ete 10S0D 2 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Rept BCamap&rDrBoeusdnsde,&rP.MCc/K9e5e7,79I-nc7o5r3p1o9rated (CDM) Water West Pensacola "Treated" K1000968.013 p.101 Service Request: K1000968 Date Collected: 2/2/10 1214 Date Received: 2/310 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA PrepMethod: ~~ Method Analyte Name PPeerlfulouroor-on--nttertirdaedceacnanicciaccaicdid Perfluorobutanesulfonate. PePrefrlfulouorroodbeuctaannoeicSuAlcfiodnate Perfluorodecancic Acid PPeerdlluuoorroohdeopdteacnacniccicAcAicdid Perluorohexanesulfonate Perfluorohexancic Acid PePrefrlfulourooroocntoannacnsouilcfAocniatde PPeerrfflluuoorrooopcetnatnaoniocicAcAicdid PerluoroundecanoicAcid Rewlt Q NNDD UU ND U 0N2D51U ND U ND U ND U 017 3 0211 oNmDyU ND U 038 J ND U MRL MDL 0 5500 % 095 SO 0029 5500 0o0n95 50 048 50 085 50 008L 50 000 50 oun 5500 0o0n% 50 006 50 on 50 13 Dilution Date Factor Extracted Date Analyzed 11 22/88100 22090M00000L4411 1 810 29101249 11 wI0 28M0 29101249 2900141 1 2810 29000141 1 1 2810 25/100041 2810 2901249 1 280 2501249 T2910 29101249 I1 2881N00 2921910000114411 1 I 2810 29000041 210 297101249 I 210 29/100141 Extraction Lot 101055665533 105653 105653 105653 108653 105653 10653 105653 103653 11005565533 105653 105653 108653 Analysis Lot Note 11990053300 19030 190530 190530 190530 190530 190530 190530 190530 11990053300 190530 190530 190530 Surrogate Name PPeerrfulouroor-on-{n1{,12.2,.33.,44,-51-31C34C]5b]urtaonmoaincoiaecaidcd PPeerrfflluuoorroo--nn--{{11,,22-31,34C-21]3Cd4e]caancotiacnoaiccidacid PPeerrfflluuoorroo--nn--{{11,22--1133CC22]]hdoedxeacnaonicciccAicdid SoPdeirfulmuopreor-lnu{o1r,o2--1113.C223J,u4n-d1e3c0a4n)coiccanAecsiudlforate Sodium perfluoro-1-hexane{1802]sulfonate: %Rec 893 100 100 8468 + 4646 + 8 Control Date Limits Analyzed Q 5300415500 2R72I900001142419 50450 2/1001] 50450 2/100L41 5S005500 2299/110001124:419 S010 50450 2900141 29/100141 50050 201012:49 Note -- Comments: -- eee------------------e---- -- ---- e -- r -------------------- Pirleod?2S2at3i1n0s1L35a7prae Ramin Spesahance oO 27 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report `BCaampr&DBorudend,&sPM.scCK/ee9e5r7,79I-n7co5r3p1o9rated (CDM) Water WK10&00A9v6e8r-y0"1R4aw" p.102 Service Request: K1000968 Date Collected: 2/2/10 1234 Date Received: 2/3/10 Units: ng/L. Basis: NA Perfluorinated Sulfonic Acids and Perflurinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Rest @ Dilution Date MRL MDL Factor Extracted PefloraocdnteNtD U_ade50ca04n6 oi1 c 80 PPeerrfflluuoorroo-bnu-arniedseuclafnocniactaecid ND U 50 095 1 28N0 121 50 0029 1 u8N0 PerfluorobutanoicAcid LJ 50 oll T2910 PPeerrfflluuoorrooddeeccaannoeiSculAfcoindate: ND U 50 0095 1 2800 ND U 50 048 1 2/300 PPeerrflluuoorroodhoedpetcaancniocicAAcciidd ND U 50 085 1 2810 161 50 008 1 28M0 Perfluorohexanesulfonate 58 50 000 1 2800 PePrefrllulouorroonhoenxaanncoiiccAAcciidd 277 50 oun T2810 0413 50 012 1 2/800 Perfluoroocianesulfonate ss 50 0046 1 2/810 PePrefrlfulourooroocpetnatnacniociAc cAicidd a 251 50 50 006 oul 1 2810 L810 Perfluoroundecancic Acid ND U 50 13 I 28M0 Date Extraction Analysis Analyzed Lot Lot Note Z9I00T49 10565 19050 2900149 103653 190530 29101259 105653 190530 29101259 105653 190830 2900149 105653 190530 29100149 105653 190530 29100149 10553 190530 29101259 10553 190530 291012359 10553 190530 29101259 105653 190530 29100149 105653 190830 29100149 105653 190530 2/1001:49 103653 190530 290012:59 10653 190530 2900149 105653 190530 Control Date Surrogate Name %Rec Limits Analysed Q Note PPeerrfflluuoorroo--nn--{{11.,22,,33,44-,51-31C34C]3b]utnaonaoniociacciadcid % nu 0130 2910014 50450 291012:59 Perluoro-n{1,2,3,4-13C4] octanoic acid 105 5015 29100149 PePrefrlluuoorroo--nn-{{11,,22--1133CC22]]hdeecxaanncoiiccaacciidd 1800 5500415500 22/997/11001021:4599 PPeerfflluuoorroo--nn-{{11,.22--1133CC22]Jduonddeeccaannociicc AAcciidd 6 50150 29/1001:49 47+ 50050 29/100149 `Sodium perluoro-1{1.2 34-1304] ccancsulfonate 71 5005 29/100149 Sodium perfluoro-11-8h02esxulafonneat{e % 50450 2/9/1012:59 -- Comments: iPrio med22s310 1337pA Fam 1a SipsRts 10D er 28 Client: PrSoajmepclte:Matrix: LSaabmpCloedeN:ame: Ansytcal Report `BCaarmopnD&reBsusdedr,&P.MCc/K9e5e7,79I-n1c5o3rp1o9rated (CDM) Water KW1&000A9v6e8r.y0"1T5reated" p.103 Service Request: K1000968 DDaatteeCoRlelceecitveedd::22//23//1100 1245 UBnaistiss:: nNgA/L Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method. Analyte Name Rest @ Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Amlyzed Lot Lot Note PerfluorPeroflw-oronnte-tratdecrandciceacicd anoicacid Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeiSculAfcoindate Perfluorodecancic Acid PPeerrfflluuoorroohdeopdteacnaoniccicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroohneoxnaannociicc AAcdidd. Perflvorooctanesulfonate. PePrefrlfulouroroopoecnitaanncoicicAAccidid PerfluoroundecancicAcid NNDD UU 5500 004s6 1 1 24/881100 292190000113566 101503665533 191090553300 121 50 0m9 1 280 2901308 105653 190% 1] ND U 50 on 50 0095 1210 29001308 103653 190530 1 YWI0 29M00LS6 10553 190530 ND U 50 04s 1 210 29100156 105653 190530 ND U 50 oss I 2/10 297100156 103653 190530 171 59 50 0081 1 2810 2901308 105653 190530 50 003 1 2810 29101308 10653 190530 287 0473 50 on 50 on T2810 2901308 1036353 190530 I UBIO 29100156 105653 190530 59 50 0046 1 S10 9100156 105653 190530 50 261 50 006 1 810 29100136 1056353 190530 50 onl I U10 2901308 103653 190530 ND U 50 13 1 2810 29000156 105653 190530 Control Date SurrogateName %Rec Limits Anslyzed Q Note PPeerrfflluioorroo--nn--{11..2233.,44,-51-31C34C]3]buntoamnoaincoiacciadcid 501 3500-14350 2299710001135068 -- PPeerrfflluuoorroo--nn--[[11..22-31,34C-21]3Cd4e]coacntoaincoaicciadcid 107 5045 29/001:56 100 50450 29/0016 PPeerfflluuoorroo--nn--{{11,,22--1133CC22]]dhoedxeacnaoniocicacAicdid 9 50150 29/101308 42 rss) 29000156 PSeordfiluumopreor-lnu{a1o,2--1113,C22,J3u4n-d1e3cCa4n)oioccmAecsiudlonate 261 + 55005105 2299110000113366 `Sodiumperfluoro-1-hexane{ 1802]sulfonate 8 5015 29101308 Comments Pnrios22u310s137 Ret Ramin Speaker 0000S 2 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Reert BCamapr&DrBoeusdnsd,e&rP.MCc.K9e5e7,79I-nc7o5r3p1o9rated (CDM) Water KW1e0s0t09W6e8l.l0P1l6a.nt "Raw" p.104 Service Request: Date Collected: K1000968 2/2/10 1305 Date Received: 2/3/10 UBnaistiss:: NngAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acidsby HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name PPereflluboroor-no-ntr-itdeecianrciacdaceiacdadnoic Perfluorobutanesulfonate PePrefrlfulouorroodbeuctaannoeicSuAfcoindate Perfluorodecanoic Acid PPeerrflluuoorroodhoedpetcanaoniocicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroonhoenxaannooiiccAAcciidd Perfluorooctanesulfonate PePrefrlfulourooroocpetnatnacniocicAcAicdid PerfluoroundecanoicAcid Remit Q MRL MDL ND ND UU3 _ 50 0090456 11) SO 0029 076 1 030 J 50 on 500055 ND U 50 048 ND U 127 50 08s 50 0081 41) 50 0030 181 056 1 50 oun 50 012 71 50 0086 a 14 50 006 50 oul ND U 50 13 Dilution Date Factor Extracted 1 1 J28I100 1 28N0 T2910 1 2/800 1 210 I UWI0 1 2810 1 2$N0 T2910 1 2/80 1 2810 1 2810 |I 2U/88I100 Date Anmlyed Extraction Lot 229910000320047 11005565573 S018 105653 29001308 29100204 105653 105653 2/9/00204 105653 29100208 29M0INIS 105653 10553 290138 105653 29101308 29100204 10553 105653 2900204 105653 29100204 29101318 105653 10653 29100204 108653 Analysis Lot Note 119900553300 190530 190530 190530 190530 190530 19030 190530 190530 190530 190530 190530 190530 150530 Surrogate Name PPeerrfflluuoorroo--nn{-1{,12,,23,,344,-51-31C34C]5b]utnaonnoaincciacciadcd PePrefrlluuoorroo--nn-{{11,,22-,1334C-21]3Cd4e]coacntoaicnoaicciadcid PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]hdeoxdaencoainociacciAcdid PSeosdfiluumopreor-lnu-o{r1o,-21-{11.32C23J4u-n1d3ec0a4n]ociccanAccsiudlfonste Sodium perluoro-1-hexane(1802slfonate %Rec Control Limits SW 00% 7 50150 1m0n0 50150 50150 842 9+ 5500405500 4608 + 50050 5045 8 5005 Date Analyzed Q ammoozor 29101318 297100204 29/1002:04 2290110001230148 29100204 297100204 2901318 Note -- Comments: PVriionns22310 i13m3b7 eApcBern Fomia Sper Rte 0300381 10 20 Client: Project: Sample Matrix: Sample Name: Lab Code: AnalyticalReport Camp Dre&sMscKeeer, Incorporated (CDM) Baron & Budd, P.C.9S779-75319 Water West WellPlant Treated" KI000968-017 p.105 Service Request: K1000968 Date Collected: 2/2/10 1312 Date Received: 2/3/10 Units: nglL Basis: NA Perflorinated Sulfonic Acids and Perfluorinated Carboxylic Acidsby HPLCIMS Analytical Method: PFOA PrepMethod: ~~ Method Analyte Name Perflioro-n-etradecanoieacid Perfluoro-n-tridecancicacid Perflvorobutanesulforate Perfluorobutanoic Acid PerfluorodecaneSulfonate PerfluorodecancicAcid PPeerrfflluuoorroohdeopdteacnacniccicAcAicdid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluoroocianesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perflvoroundecanoic Acid Result Q NOU ND U 014 0791 017 ND U 0N1D3 JU 019 0327 ND U 0471 ND U 031 J ND U Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Avalyzed Lot Lot Note 30 04 50 095 50 009 50 oan 50 0095 50 048 5500 00088 50 000 50 oar 50 on 50 0046 50 0066 so on 50 13 1 2/800 1 2810 1 28N0 T2810 1 2810 1 2810 11 228%1i00 1 2810 T2810 1 UYI0 1 2810 1 8/10 I UI0 | U0 IWM00211 29000211 29001327 2901327 29100211 2500211 2299010001231217 29101327 29101327 297100211 29700211 29/0011 29101327 29100211 10565 10653 10653 103653 105653 105653 110065533 105653 10653 103653 105653 10565 103653 105653 190530 190530 190530 190530 190530 190530 119900853300 190530 190530 190530 190530 190530 190530 190530 Control Date SurrogateName %Rec Limits Analyzed Q Note Perluoro-n-[1,23,4,5-13C3]nomanaic cid 0150 29700201 Perfluoro-n-1,2,34-13C4]butanoic acid & S450 29001327 Perfluoro-n-1,2,3,4-13C4] octanoic acid E3 50450 29100211 Perfluoro-n-{1,2-13C2] decanoic acid 100 50450 29100211 Perfluoro-n{1,2-13C2] hexanoic acid 7 S045 29001327 Perfluoro-n{1,2-13C2Jdodecancic Acid. s1 50450 29100211 PSeordfiluumpoerrol-uno{r1o,-21--1{31C2,23J,u4n-d1e3cCa4n)coiccuAmceisidfonste 46850 S5005405 2299110000221111 Sodium perfluoro-1-hexane(1802sulfonate. 2 S015 29101327 Comments: PJ red22310 1337 Romi Saher: 100mm 3 Client: Project: Sumple Matrix: Sumple Name: Lab Code: Analytical Reart `BCaraomnp D& Bruded,&sPM.scCK/ee9e5r7,79I-nc7o5r3p1o9rated (CDM) Water KIF:0S0c0ot9t6"8R.a0w1"8 p.106 ServiceRequest: Date Collected: K1000968 2/2/10 1331 Date Received: 2/3/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated CarboxylicAcidsby HPLCMS. Analytical Method: PFOA Prep Method: Method Analyte Name. PePrfelruforlou-on-rtornid-etceanioridcaecciadncodic Perfluorobuanesulfonate PPeerrfflluuoorroobduetcaannoeiScuAlcfoindate: Perfluorodecanoic Acid PPeerrfflluuoorroobdeopdteacnaoniocicAcAicdid. Perfluorohexanesulfonate PePrefrlfulouroorohneoxnaanncoiiccAAcciidd Perfluorooctancsulfonate PePfelrulouroroopoecnttaanncoiiccAAccidid Pefluoroundecanoic Acid Rest Q 0.66 1 ND U 11) 27] 035 J ND U ND U 331 403 327211 on 58 46) ND U MRL MDL 30 046 50 09s 50 0029 50 onl 50 0095 50 048 50 oss SO 0081 50 0030 5500 o0u1n2 50 0086 50 006 50 oun 50 13 Dilution Date Factor Extracted 1 ZI0 I U8I0 1 28N0 1 20 1 2$N0 1 2800 T2810 1 SMO 1 u8M0 11 2281100 1 2810 1 2810 1 UI0 I 810 Date Amslyzed Extraction Analysis Lot Lot Note 2Z99000020139 11510055665573 2901337 103653 29001337 2900219 10553 103653 29100219 105653 20000215 2901337 105653 105653 2901337 105653 2299100010323179 10553 105653 2500219 105653 29100219 2901337 105653 105653 29100219 10653 10050 190530 190530 190530 190530 190530 190530 190530 190530 190530 190530 190530 190530 190530 190530 Surrogate Name PPeerrlfulouroor-on-{n1{,12,,23,.344,-51-31C34C]5]buntoannaaincciacciadcid PPeerrfflluuoorroo--nn-{{11,,22-,1334C-21]3Cd4e]caoncotiacnoaiccidacid PPeerrflluuoorroo--nn{-1{,1,22--1133CC22l)dhoedxeacnaoniocicacAicdid PSeofdliuuomrpoe-rnl-u{o1r,o2--11{31C.22]3u4n-d1e3cCa4n]cictcanAccsiudlforste Sodium perfluoro-1-hexane[1802Jsulfonate %Rec Control Limits 2 sam "1%07 5500005500 100 50050 2 50150 52 ae 5015 50450 66 5045 8 5045 Date Antlyzed Q Note memos 22997110001231397 2100219 29001337 29100219 2299/11000022:1199 29101337 Comments: Primoedn22a01n0 e13n37eAnsys Fania SopaRls 100m0 32 Client: PSraomjepclte:Matrix: Sample Name: Lab Code: Analytical Report `BCaarmopnDr&esBsudedr,&P.MCc/K9e5e7,79I-nc7o5r3p1o9rated (CDM) Water FK:10S0c0o9t6"8T-r0e1a9ted" p.107 SeDravtieceCoRlelqeucetsetd:: K1000968 2/2/10 1362 Date Received: 2/3/10 Units: nglL Basis: NA Perflorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCMS Analytical Method: PFOA Prep Method: Method Analyte Name Rest Q Dilution Date Date Extraction Analysis MRL MDL Factor Extracted Analyzed Lot Lot Note Perfluoro-n-{eiradecanoleacid Perfluoro-n-tridecancicacid NU 50 0% ND U 50 0s T I JU/IUI00 2259110000222266 110055665533 119900553300 Perflvorobutanesulforate 057 50 002 1 810 29101346 105653 190530 PePrelruflouroordoebuctaannecSiculAfcoindate. 261 ND U 50 on 50 0095 I 1 2WI0 E10 2299110010324266 103653 105653 190530 190530 DPferwfleuodroodoudeicadnoeiclAdcid NNDOUU 5500 o08s s s) I NUMI0 B2h910i0226 M1056e53 m190e530 PPeerrffllvuoorroohheexpatnaensouilcfoArcaited: 1312 15050 0081 000 1 1 YWI0 2wi0 229910011334466 105653 105653 190530 10530 PePrefrlfulouroroonhoenxaanncciicc AAcciidd. 207 0521 50 oil 50 on I I 210 U0 2299010010324266 105653 103653 190530 190530 PPeerrfflluuoorrooooccttaannoeiscuAfcoindate 17) 237 $500 o00e6,6 1 D 220 810 29100220 6 A10e 553 T19u0530 PePrefrlfulovroorpoeunndteacnaoniociAccAicidd 30 ND U 50 ol 50 13 I I 810 10 2299110010324266 108653 108653 190530 190530 Surrogate Name Control %Rec Limits AnaDlaytzeed Q Note PPeerrfllvuoorroo--nn--1{,12,32,3,44,-51-31C34C]3]buntoamnaoincoraeciadcid. % 3 30050 297100226 50450 2900 13:46 PPeerrfflluuoorroo--nn-{{11,,22-31,34C-21]3Cd4e]caoncotiacnoaiccidacid 100 100 50450 50150 2290/911000022:2266 PPeerrfflluuoorroo--nn-{{11,.22--1133CC22]JdhoedxeacnaoniccicacAidc.id 8 48 ov 50450 5010 2209/11000123:2466 PSeordfiluvmopreor-fnl-u(o1r,o21-.123.C32,J0u-n1d3eCcHa]ncccitcamAecsiildfonste 4684. or 550010%50 2299110000222266 `Sodium perfivoro-1-hexane(1802)sulfonate 8 50050 29N013:46 Comments: PJ red223101357 Fam 1a Sips Rte 10mOI0) 33 PCrloijeenctt:: SampleMatrix: LSaambpCloedeN:ame: vali Rept B(aCraomnp&DBruded,&sPMs.eCee9eSr,T9I1nc5o3rp1o9rated (CON) Water KFi1e0l0d0B9l6a8n-k0230 p05 SeDravtieceCoRlelqeucetsetd:: 2K/130/01009067850 DateReceived: 2/4/10 BUansiitss:: NnAg Perfluorinated Sulfonc Acids and Perfivorinated CarboxylicAcids by HPLCIMS PAnraelpyMtiectahloMde:thod: MPeFtOhAod Analyte Name PPeeuroflruoo-rno-inctirriddeoccaanonicciacciaded Perflorobutanesulonate PePerrffulouraordoebucaannoeicSAulcfiondate: Perfuorodecanci Acid PPeedrlluuoorroobdeopdteacnaoniociAccAicdid Perfivorohexanesulfonate PePerrffulouroornohaenxaannooiiccAAcciidd Perfluarocancsulfonate PPeerrfflluuoorroopoecnttaanncoiiccAAccidid PerfluoroundecanoicAcid Rest@ NNDDUU_ NOU 0N1D71U NDU NNDDUU 012 J 0N16DU1 0191 0N14DJU NOU MRL MDL Dinion Factor ExtDraatceted AnaDlaytzeed ExtraLcottion AnaLloytsisNote 5300 009%5 11 UZ8MI0 2900020354 11005566553 1T90B53H0 50 009 1 U8N0 2901356 105653 190530 5500 0O0n55 11 82/0ul00 229900010325364 1100%6S533 11990055330 50 048 1 u8N0 u9m0023s 10653 150530 5500 0008B5L 11 J28B1I0 229900010325364 1l0o3s6e5s3 119900583300 50 000 1 810 901356 10s6ss 190530 5500 0021 11 U881M00 2295000123334 1100556853) 119900553300 50 004 1 281029100234 105653 190530 55000 00066111 22/010 225900010525364 110055665533 119900553300 50 13 1 810 29000234 105653 190530 Surrogate Name %Rec CoLnitmirtosl AmDaaltyeed Q Note PPeerlluiooroo-nn-1{122.33,44-513IC4C] bumanoonioccacaided E)10 500415%0 2ae9i1m0o1o3z5s6s PPeerrlluuoorroo-nn--{{112,,23:1,34C-21)3Cd4e]caonccainccaiccidacd 11000 5500115500 22990000223344 PePrelrulouroor-on-{n1{,12,-2-1133CC22}]dhoedxeacnaonicciacAcicdid 89 500115500 2299100001233546 SPeordfiluumopreor-fn{o1r,2--1{312C,23J,u4n-d1e3cCaHn)coicanAccsildforte 823 500015500 2290000223344 Sodium perfuoro-1-18h0e2 xsualfnoneat{e 5 S150 2001356 Commons: po2n0t3B 97 AB fomia Spaitams 16000 3 cSePimrnopjl:ee:Marx: SuLambpCeodNeasme: Ana Reon CBaaWarmtoepnr DrBiuer,&PMCeSkST,I9InTc5o3rp1o9rated (CON) MKeQtUhOo0d0B6l2a0n0k6 p.108 SerDDvaaittceeRCReaeclqeueievtseatd::: KNIA000965 NA nBaissi:: nNgA. PeuorintedSolfne Acids nd Perforated Carbosylic Acids by HPLCIMS APnraelpyMteitchaodMsethod: PMeFtOhAod Analyte Name Rent@ MRL MDL DFiacoonr ExDrataeed AmDbugeed ExtrLaoction AnLeatsNoe FPeeronamarncnoitonnseseid PePueorrrosdeuctannoerSuAfcoindste PPeePutuoeorrhfdeapwtaecncaoniaccivcAAdicdcad PPeettuuoorrpheesnncourtoAcnisdc PPeetthouroornosnaanniicoAndtde PPPeeefttlhuuooorrrosopcmetdnaeancnoacrnicAecAAiccdiidd NNUU 0So oamsse 11 uwm wm0o amm ma a ow0ssss mssso aNdU 5s0o a0m1s 11 awmmi0 u29mm0m0ams 0105s65 Bsosso WNN UU DSs0U Oo 0_ ooMsms _11 1NM wwWIww m2o wm0mman owsssesssa wmveosss ainess 50 ooo 50 ou 1 1 wawwwl d2o9nmo0w0a2ss 110556s5 110s5 W6)u 0soabans 11 zumw0 wanoomn owsss mssseo aNWnUU1 s5so0o oo1mne3111 uwymeiaw0 wuwmmomowmmoousessesss bssoosssoo SurrogateName Rec CLoimrmoil ADmatied Q Noe PFF eelhootne on-1112.a 223.343-44-1513r 2TCCIHHC] abwco atoanmcmscn aicidiedd TwmFoo 0wo0aa TwomIoanOe Petar {12-13C2] decane ac www aso PPeerftluaorro-n{-1{12,-21-133CC22]cdheoxcaanoniiccacAidce 103 ono 50-150 ammonw 2/9/10 17:24. SPSoeordfmiluumoprp oe-ln-o{1,e 2-L13e2Cx20r aJu4nndCeclar 8no0oJicnnlAfco oitndsee. 6116040 50500-11155000 22211977/1010001227332:44477 Commer rrzeaido13a3) t min Sota ass ss ClPireonjtec:t: Sample Matrix, SLaambpCloedeN:ame: Antica Report CBamap&rDBoiudnde,&sPM.eeCK.erSe,TIISn-coTrSp1o39rated (CDM) Water LKaQbIC0o0n0t6r2ol00S5ample p-110 SeDravtieceCoRlelqeucetsetd:: NK1A000968 DateReceived: NA UBnaistss;: nNgA Perflorinated Sulfonic PrAneaplyMteitcahloMde:thod: MPeFtOhAod Analyte Name PPereluforoo rndmecaanncciceacaidd Peruorobuaneaulfonse PPPeeerrrfffllluuuooorrroooddbeuectcaaannnooeiiSccuAlAccoiinddate PPeerrlluuooraodhoedpeicaannoiociAccAicidd. Perforohevanceulonste PePrelurorlonoounabnoeiac nAAcodicdd Peuorocnesuforate PePreurofrolpieonrtoacnioaincAAodcidicd PerluorundecanoAciicd Rest@ T10H8 505 10073 11004 980 95025 102 916003 120 Acids and Perfuoinated Carbarylic Acids by HPLCMS MRL MDL DFialcwtioorn ExtDraatceted AmaDiavtseed ExtrLaocttion 35000905% 11 JwHEI00 m27oM0n23i40 0 1065 50 00 1 ymi0 29101715 105653 55500000090.41581 111 222888111000 222100797N11100012273:441500 11100055566655s33 550 0008081 11 uwBEII00 22910002174105 1100566553 50 000 1 uBI0_ 29101715 105653 53000 00L 11 228800 22900710012754105 1100%65s65 50 006 1 2810 217102340 103s 5500 0006611 1 2mW8I100 72900205174105 1100556563 50131 um10 2070230 105653 AnaLlaytsisNote 1199055%3 11155900505330530 110955%% 19053 11509530050 150530 11950055330 19053 Surrogate Name %Rec CoLnitmroil AmDlatyeed Q Note Fefuoron{1234s IC momneicasd 102 0-0 Immma Perfluoro-n-(1,2,3,4-13C4] butanoic acid 100 50-150 29/1017:15 Perfluoro-n-{1,2,3,4-13C4]octanoicacid 100 50-150 2/17/1023:40 Perfluoro-n-{(1,2-13C2] decanoic acid 100 50-150 2/9/10 17:15 PFeePffetlrufuloourrooor..onn---n{{-1{1.1.,222-.-111333CCC222J]ludhnoeddxeeaccnaaonnioociiaAcAiccdiidd 1020 Sudperfor H1234.130 neste 111 50500-001555000 22210/977/111000221755:441500 50.150 217102340 Sodium perfluoro-1-hexane(1802]sulfonate 9% 50-150 29110 17:15, Cone msetzoean0133m7 on Femin Standen 3 Client: PSraomjpeclte:Matrix: Sample Name: RLuanb TCyopdee:: Ansel Report BCaarmopn D& Bruded,&sPM.sCc/Ke9e5erT,19In-c7o5r3p1o9rated (CDM) Water BKrQo0n0s0o6n"2T0r-e0at1ed" Matrix Spike pot SeDrvaitceeCoRlelqeucetsetd:: K1000968 2/2/10 1054 DateReceived: 2/3/10 BUansiitss:: NngAlL Perfuorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA PrepMethod: ~~ Method Analyte Name Result Q FPeerrfflluoorroo-nn-eriirdaecdaencoaincoaccaidcd 107 107 Perfluorobutanesulfonate 11s PPeerrfflluuoorroobduetcaannoeiScuAlcfoindate 116 590 PerluorodAecicdancic 785 PPeerrfflluuoorroohdeopdteacnaonicciAccAicdid 1m 134 Perfluorohexanesulfonate 188 PPeerrfflluuoorroonhoenxaanncoiicc AAcciidd 115027 Perfluorooctancsulfonate 198 PPeerrflluuroroopoecnttaanoniociAccAicdid 7 139 Perfluoroundecanoic Acid 101 Dilution Date Date Extraction Analysis ~~ MRL MDL Factor Extracted Analyzed Lot Lot Note So 0461 50 09s 1 JI0 70535 105 19050 210 217102325 10653 190530 50 009 1 28N0 2/9/101656 105653 190530 50 oll 50 0095 1 1 2810 2810 22197110012633265 105653 105653 190530 190530 50 0481 20 217102325105653 190530 50 08s 50 008L 1 1 2810 2810 217102325 20166 103653 105653 190530 190530 50 0030 1 2810 29101656 105653 190530 5500 oounl I1 U2881100 2219701102633265 10553 10553 190530 190530 50 0046 1 810 217102325 105653 190530 50 006 50 oa 1 1 2/8/10 U%I0 291170110623365 105653 103653 190530 190530 50 131 2800217102325 105653 190530 Control Date Surrogate Name %Rec Limits Antlyzed Q Note PPeerrfflliuoorroo--nn{-1{.12.,2,33,,465--131C34]5]buntanooimc aacnidoicacd875 0050 50450 J2I9100156556 -- PPeerrffllvuoorroo--nn--{{11.,22-,1334C-21]3dCe4c]aoncotiacnaocicidacid 8 100 5050 50450 22197110012635265 PPeerrffllvuoorroo--nne-{[11,,22--1133CC22]]hdeoxdaencaonicciaccAicdid 7 6 50450 50050 221971701102635265 PSeordfiluuomrpoe-rnf-l{u1o.r2o--113{1C22,J3u4n-d1e3c0a4n]caiccaAnccsiudlforate 4886+ S500A05500 221177110022332255 Sodiumperfluoro-1-hexane{ 1802]sulfonate. 8 5005 29101656 Comments: Proeda223r101s357 Ae Fomin SipsRte. 1000 a7 ClPireojnetc:t: Sample Matrix: LSaambpCloedeN:ame: Run Type: AnalyticalReport B(aCraompnD&rBuedds,&Ps.MCe/eK9eSrsT,79I-n1co5r3p1o9rated (CDM) Water KQBr0o0n0s6on20R:a0w3" Matix Spike pz SerDvaitceeCRoelqleucetsetd:: K2/120/01009610841 DateReceived: 2310 BUanistiss:: nNAg Perfluorinated SulfoicAcidsand Perflaorinated Carboxylic Acids by HPLC/MS PAnraelpytMiectahloMde:thod: MPeFtOhAod Ansiyte Name PPeerrlluioorro-onn-ireiidnecdaenccainoaccadad [rm ---- PPeerclluuoorroodbeucaannoicSAulcfiondate: PerlvorodecanoicAcid PPeerrffluuaorroohdeopdeacnacnicciAcAccidid Perfuorohexancsulonate PPeerlluuoorroonhoenxaanncciiccAAdcidd Perfuoroocanesuforate PPeerrulouroorpoeonctaanncocicAAcciidd PerluoroundecanoicAcid Remit Q 101008 100 5104 830 111017 m 91315 C1 1110 955 MRL MDL DFialcuttioorn BrDaactieed AnaDlaytzeed ExtrLaocttion AnaLlaytsisNote 53000 009%5 11 uTsEo 2I990000020402 1103065%3 1B0H5I% 50 09 1 u8I0 29101506 10553 150530 S5000 000915 11 2w8E1I00 229510010820462 110053665533 11590055330 50 048 1 uso um0oae ose 1050 5500 0018 11 22881100 221m0l1060026a 1l0o5s6e5s3) 11990055330 50 00% 1 u810 25101806 105653 150530 5S0O0 0O1I2 11 28m100 2295110001254026 l1o0s5e6s5)3 11990055330 50 00 1 usi0 290002 10%) 190% 5500 000166 11 uu8BII00 2299110001254026 11005565533 119900553300 50 131 weno usnooear 10sess isos Surrogate Name %Rec CoLnitmritosl AwDaaltyueed Q Note PPeerffluoorno{n-1{12,23,3445-1D3C04]buanoicaciodnocaed n9 0S0a5w 2m90e016e06 PPeerllouroor-onn{{11.,22:31,34C-21]3dC4e]coactnaenacciicdacid 00 001a0 m2mo00oe PePrelrulouroor-on--n1-,12,-21-313CC22}]dhoedxeacnaoniociacAcicdid 67 S50011500 22900001026 PeSrolduiourmop-en-r{1r,o2-1{31C22j3u4n-d1e3c0a4nooicsAnceisdlfome s8t3 SS01100 229m1n0000220422 Sodium perfluoro-11-8h02eJsxulafonnaete{: 8s 5015 29001406 Commas: -_-- Pisss i137ps ot 0 VBnono romia Setar om 3 PClrioejnetc:t: Sample Matrix: Sample Name: RLaubn CToydpee:: Ansytcal Report BCaampr&DrBoeusdnsde,&rP.MCc.K/e9e5,T7I9n-c7o5r3p1o9rated (CDM) Water BKrQoIn0s0o0n6"2T0r-e0a2ted" Duplicate Matrix Spike p.113 SeDravtieceCoRlelqeucetsetd:: K1000968 2/2/10 1054 Date Received: 2/3/10 Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method:~~ Method Analyte Name FPeerrfflluwoorroo-nn-itcrtimdaecdaencoaincoaicciadcd Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannceicSuAlfcoindate. PerfluorodecanoicAcid PPeerrfflluuoorroohdeopdteacnaoniccicAcAicdid `Perfluorohexanesulfonate PePrelrfulouroorhoenoxnaannooiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorroopoecnttaannociiccAcAicdid PerfluoroundecanoicAcid Ret @ 1B 920 fre) 0115s 80 nm 120 186 138 210098 196 11300 Dilton Date Date Extraction Analysis MRL MDL Factor Extracted Analyzed Lot Lot Note 30 046 50 09 50 009 5500 0o09n5 50 048 50 08s 50 008 50 0030 50 oll 5500 0001426 50 0066 5500 o1n3l 1 1 Z10 810 2211777110022333372 1065 103653 190530 190530 1 2800 2901705 105653 190530 1T28218100 22197010012730352 11005565533 119900553300 1 2wI0 217102332 105653 190530 1 1 2810 20 22197110012730352 105633 10653 190530 190530 1 28M0 29101705 105653 190530 T2810 1 2810 1279100021730352 10653 105653 190530 190530 1 2810 7102332 105653 190530 1 I 2810 2810 1279110012730352 105653 105653 190530 190530 I 2BN0 217102332 108653 190530 Surrogate Name PePsefrluooorroo--n{{11,,22,,33.44,-51-3143C]3]buntoanmoaincoracciadcid. PePrefrlfulouroor-on--n{-1{,12,,23-143-C123)Cd4e]caoncotiacndaiccidacid PPeerrfflluuoorroo--nn--[{11,,22--1133CC22]JdhoedxeacnaoniccicaciAdc.id SPeordfiluumopreor-fnu-o{r1o,-21-{1132C,23Ju4n1d3e0c4an]ociccanAecsiudlfonste `Sodiumperfluoro-1-hexane(1802sulfonate Cantrol %Rec Limits 7 S0500050 8 100 50050 50050 87 Ey 50150 50050 5902 5500445500 ot 5005 Date Analyzed Q 2290/0102137.3078 22197110012730382 22197110012730352 221177110022333322 291017:05 Note -- Comments: Pieod2n201a0 1n337 AR 6 Fmia Sopa Rete 10010) 39 Anaya Client: Project: BaCraomnpD&rBuedd,s&PM.sCc/Ke9e5er7,79I-n7co5r3p1o9rated (CDM) Sample Matrix: ~~ Water LaSabmpCloedeN:ame: KBrQoIn0s0o0n6"2R0a0w4" Run Type: Duplicate Matrix Spike p14 SeDravtieceCoRlelqeucetsetd:: K1000968 2/2/10 1041 DateReceived: 2/3/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA Prep Method: Method Analyte Name PPeerrfluuaornoo-nn-tteriidredcoancoaincaocciadcd Perfluorobutaneslfonate PPeerrfflluuoorroobduetcaannoeiScuAlfcoirdate: PerfluorodecanoicAcid PPeerrfflluuoorroohdeopdteacnaoniccicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroonhoenxaannociiccAAcciidd Perfluorooctaneslforate: PPeerrfflluuoorroopoecnttaannocicicAAccidid Perfluoroundecancic Acid RetQ MRL MDL 845 113 30096 50 09s 108 50 0029 110 550 50 50 oul 0095 655 50 048 139 110 50 50 085 00BL 133 50 000 120 9190 50 50 oul 012 163 50 0046 m 114 50 50 0066 on us 50 13 Dilution Date Date Factor Extracted Analyzed 1 ZWI0 11 U288I100 T2910 1 1 28N0 2800 1 1 2810 2810 1 2810 T8100 1 1 2800 2810 1 1 2810 810 I 810 250000 22991M000121459 29101815 2/9/100249 2/9/00249 25100249 2901415 29101415 29001415 205100249 2/5/100249 2100249 29101415 29100249 Extraction Analysis Lot Lot Note 10% 100 110055665533 119900553300 105653 103653 190530 190530 105653 190530 105653 105653 190530 190830 105653 19030 105653 103653 190530 190530 105653 190530 105653 105653 19030 190530 10653 190530 Surrogate Name PPeerrffluuoorroo--nn{-1{,12,2,,3344,-51-31C34C]3]buntoamnoaincciacciadcid PPeerrfflluuoorroo--nn--{{11,,22-,1334C-21)3Cd4e]caoncotiacnoaiccidacid PPeerrflluuoorroo--nn{{11,,22--1133CC22]]dhoedxeacnaoniccicacAicdid SPeordfiluumoproe-rnl-u{o1r,o2--{1113.C22]3u4n1d3e0c4an)ocicctnAecsiudlfonste Sodium perfluoro-1-hexane{1802sulfonate %Rec El n 91%00 480 + 538 % 8 CoLnitmirtosl T5S000510 0 5500-115500 S50045500 5S0045500 50450 Date Analysed Q 229p1n00104z1e5y 229911000022:4499 229910010421459 2299/0100022:4499 29101415 Note -- Comments: Pirimoed2S2a3t1s013s37hen Fem1a SipeRete 10S 0 a0 CPlrioejnetc:t: Sample Matriz: QueRept p115 `BCaampDr&Broudend,s&PMsCc/KeOeSerT,IOInIcSo3rp1o9rated (CDM) SeDravtieceCoRlelqeucetsetd:: K27I20/0100968 Water DDaatteeAnRaecleyizveedd:: 2239/1100 Perfluorinated Sulfonic AcidsMaantdriPxerSfpliukoeriSnuamtemdaCrayrboxylic Acids by HPLCIMS SLaambpCloedeN:ame: BKr1o0n0s0o9n6"8R0a1w0" UBnaistiss:: NnAg. APnraelpytMiectahloMde:thod: PMeFtOhAod Sample KMQa1t0r0i0x6S2p0i.k0e3 AnPaelfyltoeoNnaimcedecsicadd Rell Result Amount %Rec ND 105 100 105 PPePreeffrlfluloourrooorboubvuttaianncdcsiueclfAoocniaadctied N4D5 0M10 l1o00%101 54 104 00 99 PPPeererfffllluiooorrnoodddeoecdceaacnnaaeniocSiuAclcoAircdaitde ~~ 0N1D6 $B5O5 Nm 1M0000 0 $85 ow PePPreefrrlflolurooorrhooebexexapanancncsciuiclcfAoAcnciaidtde 237 Imm Wome aa00 98% 10% PePrefrlfulourooroocnoannacnscuilcfoAncaitde 0s%s 915m 1000 0%9 PPPeeerrrfffliluvvooorrrooouopncedanentcoaainncicciAccAicAdicdid 3Loonl ND ess 0 10 %7 lo 9% DupliKcQaUt0e00M6a2t0ri-x04Spike Result Amount %Re 81S3 11000 38 M1008 110000 M1044 56550 110000 655 B 10 lo10 11329 1b3o 110000 11005 9108 1100 1005 2le 1100 1900 us 10 us %LimRietse RPD LRiemiDt 5$00-.1100 2 1 %30 5500-.11500 85%3 500-.1100 234 300 050--1100 233 030 5500.-11500 95%30 00.01-5100 37 3300 s50-o150 31 30 So-10 2 30 Comments: PieSs22t310a133b8 e Mari Spesummary @ Satan: oD CPlroijeenctt:: Sample Matrix: QwQC Report p.116 `BCamapDr&rBeosusdendr,&PM.eCK9eSsT,II9n-c1o5r3p1or9ated (COM) SeDravtieceCRoelqleucetsetd:: 2K21/01000968 Water DaDtateeAnRaecleyizveedd:: 223//91/010- m0 Perfluorinated Sulfon AcidsMaantdiPseSrpfilkoerSinuamtmedarCayrbosylic Acids by RPLCIMS SLaambpCloedeN:ame: KIB0r0on0s9o6n8."T0r1e1ated" PrAneaplyMtiectahloMde:thod: PMeFtOhAod Sample KQ0Ma0t0r6ix2S0p-i0ke1 AnPaalfyitoenNianmdecnscaid Remit Remit Amount %Rec ND 107100 17 PPeePrtefrlfuolourroorooubaurtniacdnesccuiacnfcoAincisadtied NZD ou07 o10w0 110}7 57 16 100 16 PPeePrrefffluluooorrnooodddoeedcceaacnnaecnccSiuAcfcoiAndcsitde ~~ NNDD 7980S N13 11000 00 7590 13 PePrelrufouroorhoehxepatnaensouilcfoAncaitde Perlluorohexanoic Acid 9BobsIs 100 U916 Im 0 us PePPreefrruffollrvuooororocootncaotnnaacnnscoiuiclcfAoAcnciaidtde 1SL 6107 1000 1W0ws @ m0 109 PePrefrlfuloorrooupnednetacnaoniocicAcAicdid N2D 900 0000 110007 UBaaistiss:: nNAg DupliKcQaItOe00M6a2t0ri-x02Spike %Rec PD Reult Amomt %Rec Limits RPD Limit 91230 110000 123 5so0o-150 1145 3% m13s 110000 0105 050-010 21 330% 6m05 1100 68 s0-o1m0 3 7% % 210 1100 212 S0.o1m0 11% % I18 1100 1800 5500-.11500 110 3300 21095 11000 1105 5500--11500 25%30 130% 110000 1528 5s0o-10 06%3% 10 100 10 sous 9 30 Comments: Fes22t3e10t13p38 aras -- a2 Sesh os PCrloijeenctt:: Sample Matrix: QuQC Report p17 CBaarmopnD&reBsusdedr,&P.MCc/K9e5e7,79I-n7co5r3p1o9rated (CDM) SeDravtieceAnRaelqyuzeesdt:: K2/I90/01009-68 Water m0 Perfluorinated Sulfonic AcLiadbs CaonndtPreorlfSluaomrpilneatSeudmCmaarbroyxylic Acids by HPLCIMS APnraelpytMiectahloMde:thod: MePtFhOoAd UBnaistiss:: NngAlL Extraction Lot: 105653 APenrafllyutoeroN-na-mteetradecanoic cid PePrefrlfulouroorbou-tna-ntrcdseuclafnooniactcacid PPeerrfflluuoorroobduetcaannoeicSuAlcfiondate PPPeeerrrfffllluuuooorrrooohddeeopcdtaeancncaoinciociAcAcciAidcdid PePrefrlfulouroorhoehxeaxannecsiuclfAocniadte PPeerrlfulourooroocntoannacnsouilcfoAncaitde PPPeeerrrlffllluuuooorrroooopucentndatenaccnaionciociAccAicAdicdid LabKQCIo0n0t0ro6l20S-a0m5ple % Rec Result Espected %Rec Limits m0o8 00m 100 18 5500.-115500 00s3 110000 19013 5500.-115500 o0s7 110000 17007 5500--11550 u10e4 110000 114064 5500--115500 B95O5 110000 89% 5500--115500 02 0 1000 11022 5500--115500 916003 110000 190%3 5500--11550 20 10 120 50-150 Comments: NPoretd2e20s1013o38k Cone LabControlSampleSummary a Sp Reenc: 00D 4 ASnoalluymtibciaal Services PriCnrteead:ted14w/i0t2h1A2n0a1l0yps6.t:141R18e:p0o0rPteMr PDraotjaecFtile Result Table 00E22v00a8n81'10s0P6Sr\aSomajpmelpcelsseLPsoFLnoCgnsgr.dwif InstrumentName __ AP)5000 [[S`AacmapuilseiNioanmbeate |2K0i2o00013088.2G:0170:38 AT [inSjaemcptiloenTVyopteame [5] [inAjceqcutiisoitniVoinaMlethod|J~ P2F1ChinetexLdo~ anmg [[WDieliugthiotntFoaVcotlourme[T1070000 | | BE |we |wa Results Summary Anais Peak [EwaI | rn | Tm Cae Cor | won| PFOS 1 |Prooat 13CPFOS | 6231700| 0.00(4.10) o | wa No | toeroo|n eo [ooouen| 0 | wna | ol zs pleted o Page 154 of262 44 Loma Analytical Services RC Summary svsperentine | npr)[es wor[SS Prige tianin ahiSttc] Rein| [sormun [[psrcees ros Fronz sr.uvmoeron maw| www | me |omaem| we | was|w | wm e |mommaomm| [vvee || ome| 0 |wo|owes [we wun |0| we | wom| Ps_rroanc2eron [pra Fries [wEaXsEn| ww |o we| o| n we | [owe [ 0 |w|owem| w [omom| wr | wo|owom| w po 155 r282 45 4AnSaollyatmibciaalServices- PriGnrteead:ted14w/i0t2h1A2n0a1l0yps6.t:142R10e:p0o0rPteMr Quantitative Peak Review K1000968-001 - . TT ry = TE Fi endl = i: A i CoE - on =! Ba4s1e3lP0i/Fn1eO6A910Mi0sased| cBa4s1e17l30iCn3-e7Pc2FO0MAi0s8sed | ling pea clue B4a6s3ePl0i/En4Ne1Ac9M10i0sased | Ba4se61l83i.Cn-e0P4F2NMDA3is.ased TH en Pe . o=l ol Fd o| ly :of Wo af Bas4e9l9.Pi0Rn/eO60Sc.10MDisased | oB5a0s3e10l3i/Cn8-e0PMFOiDSsased | B5a1s3e.l0Pi4Fn6eD9A.01MiDsased | oB5a1s1e53lCn0-e4PcF7DM00Ais0ased hy Es pe Hetamps be bof 3d 2 =A FPFrURAe T ] 63.0/519.0 Da 56153.C0-1P27Fr0Ue0naADra Bh 599.P0F/O80Sr.07eDa I 50133.00/P80Fe.O0 SDsa KcABaseline Missed | BaselinetcaMgissed | BoBaEselSnecMssed | EBaseeline u Missed - Ll gl Lo pet D I A rl, faa ee A c6B1a3Ps.Fe0iD5nO6e9cA.M1iDsased | c6B1a5s10e3/lC1i-n6Pe9Fc.D00MiADsased | o6B6a3s.e0P/lE6iT1n9Ae.c10Ms0saed | 61153C0-/P1F6D9OD.A0a oBaselne c Missed oh Ll EEOC PRY B7a1s3ePl.Fi0nT6eE6Ac90M1i0sased| o B6a1s1e35lCi0-n/eP1FoD6MO9iDAs0ased 0 Before OJ After Pa156gof2e42 4% Columbia 4 Analytical Services Created vith Analyst1R2e1porter Printed: 14/02/2010 6:41:00 PM lon Ratio Confirmation K1000968-001 joi | boa i i nd |J i Notte Ba4s1Pi3rn03gi6o920v0i8s | Ba4se6Pl3ri0nv2ea1o52V0i0esed | B4asP9erl5io0ne5s02M0i8ssed | B5a1se3lP0in2re5co020Mi0s8sed Wong Peak Wrong Peak 2 Wong Peak Wong Peak :nebtsih 3 Lpasiogpuy oJostgnMh]| So33peenbrioltes oB5a6s3ePi0Fn2Ue8N9A.2M0i0sased | oBa5s9e9PiR0nOe9S9o02Mi0s8sed | B6a1se3Pl0Fin1De8GcA920Mi0s0sed| c B6a3s0ePi1nF6eo8T2.M0is0sed Wrong Peak Wong Peak Wong Peak =Wiong Peak 71P30T/O1?6900a BaWisoneglPMieiasnkseed O Before O After Page 157 or 242 a7 5 Solumbia Analytical Services* PriCnrteead:ted15w/it0h2A1n2a0l1yp0s.t122R.23e4p0o0rPteMr DPraotjaecFtile Result Table 00E22v0a08n81'10s05PSaramopmjipeelcsessshPSoFhrCtoserdiw.ifdb Instrument Name__ API 5000 [SHameplneaNnamDeas] o rroooso 68367 m TE eAccquiiosintivoinaMetho[d|3P1FCKinelexShdoarmt [Samepcltoe TVyaporn [|U5niman----------| |wDWieluitgihotntFoaVcotlourm_eT[ 700 56]| Results Summary -- Anais Peak | Name J di_ame[sae | Anaiie RT (ExpRT) | Analyte Area GaatiemGtoyne|Moses"| roar 13CPFBA | s510a37n00| [ 126012s 7)|| wa81a38w 9 | o00w9 | wNeo PFoHrXAn1 | rroapcrrirao||n sseuveon |[ssmaena|| evows || ooems | | wwee || pat | worms | are [ames] we | ow |we] [sSrocrrrruosn || cnoerrronn |||ssTwtaeoiaea|ossinea|n| ssmno | io | Wwe-- w]| 4 ps v 2 Zzi iyiste Page 137of265 48 AnalyticalServices' CrweithAanalytbi Reepordter CSUMMary oman rir)|e [sone gs rriassen L| omum[0_ |m[|eommoo| w|| | [eros [ose | mew | we| omem | ve 49 AACnoalluytmibciaalServices Created with Analyps.t12R4eporter Printed: 15/02/2010 2:34:00 PM = 7 Quantitative Peak = Review 7 a El " Fle gw K1000968-001 1 c2o13.pm0/r1o6i9R.T0c0as | co2o1s17i3.nC01oP7Fc2Bh0Ai0saes | o2s6w3,eP0iE2nP1e9oc.Ah0]i0aaes | o31135m C0.P2F7Ye X00A0ases . ai hg - seca ving I+ - (J = | I3 i draped 20p9r.e08s00 00 Wo40t3o0sC10fA3i0sC02] || h3e13p0er26i9l008 LL311530C2A -7p0F0A0a cBaselnoeno Missed ||oBai seinoc Missed | Baselia ne Missed | o Bi asolign o Missed .~ i-] oB3a6s3eP,0lR1n1eA69cT.M0is0saed | cB5a1s1e53i0Cn2-e1cp0MF0iR0s8sed Te mre - - ia ii. 4s63_.1018100F3.F0HDsa oBaselieoMissed | oB5a1sc5ei0ne4e7c0a0Mi0s8sed E=l il' || Ba3s0ePl9ri0in8e0s0M1i0s8sed | oB40a138s00-1ep0oFl3iM0iiiS0sn8segd ] 95 thang, = - | lo.2] R| E ||| 5s1t3.a0c47A0R.o00n8 Baseline Missed | oBa5s11e3l5i00n-o4PoF7DM0AiDs0ased O Before O After Page 139of 245 50 3AnGaloyltiacamlServices" PriCnrteead:ted15w/i0t2h1A20n1a0l2yp:.3R61e:2p05o0rtPeMr fon Ratio Confirmation K1000968-001 = - = |i - d G| am Lo-= izTzl hu \ bree Bf A| eet| eee RT B2a1s3e0lP/iFn1eB6A92M0i0sased | B26a3sP0F2eP1le9oAMi02i0snaseed | B2a0s9e.l0Pi1nF9eB9Sc.0M2iDsased | Wrong Peak Wong Peak Wiong Peak = eg = - x a eh SE To hyA]i -- fF se| GB3a6s3eP.i0F/nH3e1Dc0A.0M2iDsased | Bas3e99lP.i0Fn1He99I.oS0 2Da Misse d | cBa5Ss1e_l51i30nCe4Pc7FM0DDiAs0ased | Wrong Peak Wrong Peak = Wrong Peak NE PFBA and PFPeA do nol have qualifying fon ransiions Ba31sP3e0H/l1oA21iMi9Dns0aseed Wrong Peak Tiassa NA BasWelrionnegMPiesasked 0 Before OJ After Page 140of 265 51