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, AR226-0432 CORNINGHazleton MUTAGENICITY TEST WITH : T-6564 IN THE SALMOMNUETLALATI-OENSCAHSESRAICYHWIIATCHOALICMOANMFMIARLMIAATNO-RMYIACSRSOASYOME REVERSE FINAL REPORT AUTHOR mrs :. Timothy E. Lawlor, MA. [F. dg Foi ag : PERFORMINGLABORATORY Ue= Smrrie Coming Hazleton Inc. (CHV) Vi9e2w00,LVeiersgbiunriag P2i1k8e2 oT LABORATORYPROJECTID CHV Study No.: 17750-0-409R SUBMITTTEDO . BuiSltdPiangu3lM2,2M0Co.Nr3p5o.5r03a2t1i43o4nM-1C0e0n0ter STUDYCOMPLETIONDATE September 13, 1996 i CHV Study Nos 17750.0-409% Lof34 i 0232 CORNING Hazleton : QUALITY ASSURANCE STATEMENT STUDY TITLE: S`aAslsmaoynewiltlha-aECsocnhfeirrimcahtioarycoAlssMaaym.malian-Microsome Reverse Mutation ASSAY NO: 177500-409R PROTOCOLNO.: 409R, Edition 4, Modified for 3M Quality Assurance inspections ofthe study and reviewofthe final repor: ofthe above referenced. : project were conducted according to the Standard Operating Proceduresofthe Quality Assurance Unit and according to the general requirementsofthe appropriate Good Laboratory Practice ; regulations. Findingsfromthe inspections and final report review were reported to management ? and to the study director on th following dates: Scoring Plates - 06/28/96 0628/9 Draft Report Review - 08/29/96 0873019 Final Report Review -09/13/96 0911319 P. Conley C. Orantes C.Orantes { iy Assurance Unit Date Refeas3/e51d i CHV Study No.: 17750-0-409R 2 C0033 CORNING Hazleton STUDY COMPLIANCE AND CERTIFICATION `fTohrethsbtuydtyhweaFsoocdonadnudctDerduignAcdommipnliisatnrcaetiwoint(hFtDhAe)GoiondTitLlaebo2r1aotfotrhyePrUaSct.icCeordeegouflFateidoenrsaals set Regulations Part 55, issued December 22, 1978, (effective June 20, 1975) with any applicable `amendments. There were no deviations from the aforementioned regulations or the signed protocol that would affect the integrityofthe study or the interpretationofthe test results. The raw data have been reviewed by the Study Director, who certifies that the evaluationofthe test adretsiicglen aasnpdreevsaelnutaetdiohnerceriitnerriea.presents an appropriate conclusion within the contextofthe study : Study Director: ;! 2 ee BTaicmtoetrihayl EM.obgLejnwleors,iMs.A. Genetic and Cellular Toricology -13-7 Study Completion Date : CHV Study No.: 17750-0-409R. 1 i 3 . 00234 CORNINGHazleton ; TAOFBCOLNTENETS Page No. Lo SUMMARY Loonie J} I STUDYINFORMATION oot T . HL MATERIALS ANDMETHODS oui ceil 9) IV. REAS NDU CONCL LUSIT ONSS .....oouniiiiniiiinniiieiiicniin 28 V. DATATABLES ....................... wrreanssvesssrne 27 CHV Study No.: 17750-0409R : 4 C6035 [I CORNING Hazleton SECTION I. SUMMARY : INTRODUCTION AND CONCLUSIONS x CHV Study No.: 17750-0409R i 5 00236 : SUMMARY `CORNINGHazleton A. Introduction mutagenic sctiAvtihy in trheequSeasltmoofneSlMlaC-orEpxocrhaetriicohni,acCoolmliMnagmmHaazllieatnonMnicc.roinsvoemsteigRaetveedrTs-e6564 for mMeuttaabtoilointeAssfsorytwheiitrhaCiolnyfiteomitndourcye Arsevseyr.se Tmhuitsataisosnasyaetvtahluahtiestditdiene(lcotcuaslinethaengdeonrofmse of `specific Salmonella typhimurium tester strains and at the tryptophan locus in an Escherichia coli tester strain both in the presence and absenceofan exogenous metabolic activation system of `mammalian microsomal enzymes derived from AroclorTM.induced rat liver (9). The doses tested inthe mutagenicity assay were selected basedonthe resus of a dose rangefinding study using tester strains TA100 and WP2uvrA and ten dosesoftest article ranging from 5,000 to 6.67 ug per plate, one plate per dose, both in the presence and absence of S9 mix. i The teste sais used in the mtageicy assy wee Slmonele tphimurm ste sins ii ccTooAnn9cd8uu,rcrtTeeAndt1w0vi0eth,hicTilAev1ea5n3ddo5s,peosTsAoi1fi5ve3es7tc,oanatnnridollsEsicsnhibenorgtihhchtiehae cplorlaeitseteesnspcteeerradsntodrsaaeib.nsWeTPnh2ceeudvoorfsASe.s9 emTsihtxeeadalswosenargyewwiatsh r5e,s0u0l0t,so3f,3t30e, i1,i00l0;m3u3t3a,geannidci1t0y0susgapererpleatceoinnbfoitmhetdhienparnesienndceepeannddenatbseexnpceeriomefn9t.mix. The B. Conclusions : CMuotraptoiroantiAosns'ytTehswteitarhreisaeulClt,osonTff6ti5hm6ea4oS,ardlymdoAnnseostlclyaaui-snEedsaicchpetortishctahitiv,aeuncidnoeclrrie/taMhseaemcimnoanhldeiianonun-msMobifecrrtohosifosmrseuecRvyeev,retrss1e per plateofanyofthe tester strains either in the presence or absenceof microsomal enzymes `prepared from AroclorTM-induced rat liver (S9). . CHV Study Nos 177500409 J 6 00237 | CORNINGHazleton SECTION II. STUDY INFORMATION ; CHV Study Nos 177500405 : 7 00238 CORNING Hazleton STUDY INFORMATION A Sponsor: 3M Corporation B. TestAicle: TL6156647 Fet0isx 1 Physical Description: clear colorless liquid 2 Date Received: 05/30/96 3: c TypeofAssay:MiSatlamtonoenllAas-sEascyhweirtihchCioancfoilrimMaarmomrayliAasns-eMicrosome Reverse : 1. Protocol Number: CHV Protocol 409R, Editio4n 2 CHV Suudy Number: 177500-409R D. SudyDues 1 Study Iniation Date: o0ams . 2 Experimental SanDae: ozs 5. Experimental Teminaton Date: 08279 : E. Study Supervisory Personnel Study Director: Timothy E. Lawlor, MA : Laboratory Supervisor: Michael S. Mecchi, B.S. i CHY Study No: 1775004058 ! 5 00239 4 `CO RNI NG Hazleton SECTION IIL. MATERIALS AND METHODS : CHV Study No.: 17750-0-409R i 9 00240 ' CORNING Hazleton i MATERIALS AND METHODS Ames efTahle(e1x9p7e5r)iamnedntGarlemeantearniadlsM,umrieetlho1d9s7a6n)d procedures are based on those described by MATERIALS A. TesterStraing 1 Solmonella nphimurium auxotrophs TA98, TAI"0T0h,e tTeAsIteSr3sSt,aiannsduTsAedISw3e7reasthdeeSsaclrimboendelblyaAtmypehsimeurraliu1m97h5is)t.idiTnhee specific genotypesofthese stains are show in Teble TABLEL TESTERSTRAINGENOTYPES hisG46 isCI076 hisD30S2 LPS Repair R Factor TAISIS TALS da wed . | T_A--I00 TASS da wr WR Imnutaadtdiiotnisonwthoicahmuetnahtainocneithtehir sheinsstiitdiivnietyopoersoon,methmeutteasgteernitcracnomspcoounntdaisn.tTwhoeadrfdaitwoanlallmutation lreispuolptosliynsatchcehlaorsisdoefboanrreioerftthhae feonrzmysmethserseusrpfoancseibolftehfeobratchteersiyanlthceeslilswolflp,arToheftrheesulting cell wall ! dienfgicsiyesntceymisnc(irce.asbeesnpzeor(mae)apbyirleintey)ttohacterwtoaiunldcloastsheesrowfiscehbeemeixccallusdseudchbyasatnhoosremaclonitnatiancitncgellawrgaell Tsyhsetesmecwohnidcmhutgraetaitolny,aednehlaentcieosntohfetsheensiwtvirvBitygoefnet,herseseulsttsraiinnsadefiscoimeentmuDtNagAenesx.cisSiionnceretphaeir1B. . dveilteatmiionnbeixotteinndfsorthgrroouwgthhth bio gene,al ofth tester stains containing this deletion require the :; thStersaeinnssiTtiAv9i8tyoanfdthTeAs1e0s0taailnsso0constoamien mthuetaRg-efnasc.torTphleasmmeicdh,apnKiMs1m0b1y,wwhhiicchhtfhuisrtphlearsimnicdreases DinNcrAearseepsasiernpsiotliyvmiteyratsoemcutoamgpelnesxhiansvobleveendswuigtghesthteedmitosmbaetcbhye-mroedpiafiyiprnogceasns.existing bacterial } CHV Study No.: 17750-0409R 10 00241 CORNINGHazleton : hTiessttiedrinsetrianidnsepTeAn9d8enacned(pTrAo1toSt3r7opahrye)rbeyvefrrtaemdesfhriofmt hmiusttaigdeinnes.depTeAn1dSe3nSceis(aruevxeorttreodphbyy)btaose ssuubbssttiittuuttiioonn mmuuttaatgieonnss and TAI00 i reverted by mutagens which cause both frameshifis and base 2. Escherichiacoli described by Green andThMeurtieestler(1s9t7r6a)i.n used was the tryptophan auxotroph WP2uvrA as Idnefaidcdiietnicoynwthoiachmuetnahtainocneisnitthsesetnrsyipttiovipthyantoospoermoen,muthteagteenstiecr sctormapinouconndtsa.inTshaisuvdrefAicDiNenAcyreaplaliorws trheemostvreaitnhteodsahmoawgeednhpaanrtcoefdtmhuetaDbiNliAtymsoilnecceutlheeawnvdraAccruerpaaitrelsyyrsetpeamirwiotualfdtenrwoarrmdasl.ly act 10 : TiensdteepresntdreanicneW(Pp2ruotvortrAopishyr)evbeyrtbeadsefrsoubmsttrityupttioopnhamuntdaegpenesn.dence (auxotrophy) to tryptophan . 3. SoofuTesrtercStraeins a Salmonella typhimurium Dr. Bruce Ames, `The tester strains Deparmentof Biochemistry, in use at CHV were received directly UniversityofCalifornia, Berkeley. from b. Escherichia coli National Collection ofIndustriTahleBatcetseterrias,trTaoirn,reWyP2ReusveraAr,chinStuasteioant,CScHoVtlawnads(rUencietievdedKfirnogmdotmhe) 4. StooftherTesatergStraeins : a Frozen Permanent Stocks ovemight cultures, adding DMFSrOoz(e0n.p09ermmUa/nmelnotfstcoulctkusrew)earendprferpeaerziendgbsymaglrlowailinqguoftrsesh (5-1.5 mb at 5-70C. - CHV Study No.: 17750-0409R 1 C0042 : CORNING Hazleton : b. Master Plates Master plates were prepared by sreaking exch ester sain from a Ifyrpozheinm upreirumma,neanntexsctoecsks onto ofhis minimal agar tidine, and bi appropriately supplemented with 1) otin, and for tester strains TA98 and for Salmonella TA100, ampicillin (25 g/ml), to ensure the stable maintenanceofthe pKM101 plasmid; and 2) for E5s2c3herCi.chia coli, an excessoftryptophan. Tester strain master plates were stored at 5. PrepoafOrveranigthtCiuloturnes + Inoculation by transferring a colony from tOhveeranpiprgohptricualtteurmeasstfeorr pulsaeteintoalal testing procedures were flask containing culture inoculated medium. Inoculated flasks were placed in a shakerfincubator which was programmed to begin operation : (shaking, 125 25 rpm; incubation, 37 + 2C) so that the overnight cultures were in log phase or i late log phase when turbidity monitoring began. } b. Harvest To ensure that cultures were harvested in late log phase, the length of incubation was determined by spectrophotometric monitoringofculture turbidity. Cultures t`rwearneshmairtvaenscteed(%oTnc)eraeapdriendgeotnermsipneecdtrtuorpbhiodtiotmyewtaers.reTahcihsedtaarsgedtettuerrbmiidniteyd ebnysuarpeesrtcheanttcultures } : O`whevareveregrrreeoamcwohnveed(dsatafdtreionomsniaitrnyyo)cufcbuaaltttiuloreneasswtmh0ae.ny5 Xetxhhe1i0tbairtcgeedltelc%srpTeearswemadlssarenendasictthihevadittatytnhedcwsuelortmueerpemsluahcaaegvdeenatnso.5t&oCvu3elrtCgu.rreoswn. 6. ConfoifTmestmerSaimitnGeinootypnes Tester sran cultures were checked for the following genetic markers on * `the dayoftheir use in the mutagenicity assay: ! a Salmonella typhimurium 1) ofa Wall Mutation The presenceofthe 1/2 wall mutation was confirmed bs demonstrationofthe sensitivity ofthe culture to crystal violet. An aliquotofan overnight 1 CHV Study No.: 17750-0-409R 12 0243 CORNING Hazleton ; sceunlstiutrieoviftyedaicshksctornatianiwnainsgo1ve0rilsgidofocnrtyostpallavtisolceotnwtaaisniandgdesdel.ecSteinvseitmievditiyawaansd daenmaonntisbuiaottiecd by inbibitionof bacterial growth in a zone immediately surrounding th disk 2) PKMIO! Plasmid Refactor tester stains TA98 and TAI100 by dem"oTnhsetprraetsieonnocfeorfestihsetapnKcMeI1to01amppilcaislmliind.wAsncaolnifquiortmeofdafnor aonvteirbniiogthict sceunlstiutrievoiftycdaicshk sctornatianiwnainsgo1v0erilaidofaomnptiocpillaltiesnwcaonstaadindiendg.slReecstiisvteanmceedwiaasand an demonstrated by bacterial growth inthe zone immediately sumounding the disk. 3) Characteristic Number of Spontancous Reverants !i i v1e0h0iculleacloinqturootlssotfthahtearceulcthuareraacltonegriwsi"otThfhetthmheeaarpenpsrpnoeupcmrtibisveteresovtfershaipiconlnewteaornneesodeulesemcortneivsveetramtteandetidsab.pyerplplaattiengin the i b Escherichia coli 1) Characteristic Number of Spontaneous Revertans ; vehiclecontrolsthat are characteristic"oTfhtehmeereasnpencutmibveersotfrsaipnosnwtearneeoduesmorenvsetratatnetds bpyerppllaattiengin the 100 ul aliquots ofthe WP2uvrA culture along with the appropriate vehicle on selective media : 7. TesterStainMedia a Curing Broth :: `Vogel-Bonner salt solution(Vo"gTheelabnotdhBuosnender0, g19r5o6w)osvuepmpilgehmtenctueltdurweistohf2t.h5e%t(eswtievr)sOuxsoinisdwas Nutrient Broth No. 2 (dry power). : bo AgarPlaes 0Bo.n2n%e(rwmhi)nigmluaclomseediumE (VBoogteltoamndagBaorr(n2e5r,mi19p5e6r),1s5uxpp1l0e0memnetmepdewtiithdis1h.)5%wa(sw/Vvo)gaegla-r and CHV Study No.: 177500409 I i i 00z4a4 CORNINGHazleton : . Overlay Agar for Selection of Revertants 0.5% NaCl (wiv) and was sup`pOlveermleanyte(dopw)itahga1r0wmalsopfre1p)a0r.e5dmwiMthhi0s.t7id%inaeg/abrio(twi/nvs)oaluntdion per 100 agar mflorasgealrecftoirosnoefletcrtyiopntoofphhiasntirdeivenretarnetvse.rtaWnthse, norS29) 0.5 mix mM was trreyqupitroepdh,a2n.s0omlultiofotnhpeer 100 ml of swuapspaldemdeendtteodttheopsaugpaprlweamesnutseedditonptahgearov(e0r.l5aym.loHfowwaetveerr,pewrh2enmiSo9fsmuipxpwlaesmennotterdeqtuoipreadg,arw)ataenrd `tehnesruerseudltthiangtt2h.e5fmiinaloftdoiplaugtaesd asunpdpalmeimneontaecdidtospupapglaermweanst ucsoencdefnotrratthieoonvserrleamya.inTehdisthdeilsuatmioenboth in the presence and absenceof$9 mix. : 5 Kireelli jon Misture (SMG 1. SHOomogenate i; Molecular Toxicology,LIinvce.s, mAincnarpoosloimsa,lMeDnzy2m14e0s1(,SB9ahtocmho0g6e4n2at(e3)9.w5emregopfurpcrhoatseeidn fperromml) and : : DBaatwclhey06r4a6tst(h4a3t.4hamdgobfeepnroitnejienctpeedr(im.pl.)).wiTthhe AhroomcogleonraTMte12w5a4s(p2r0e0pmargepdefrrmolm minalceoSmproaig)uaet- 500 mg/kg as described by Ames ef al, 1975, 2. S9Mix : procedure. The S9 mix`TchoenSta9imneidxtwhaescpormeppoanreendtismmineddiicaatteeldyinprTieobrl0e Itls use in any experimental : HO `TABLE 59MIX COMPONENTS 070ml i 012M5NMaHG,lPucOo,s/eN-a6;-pHhPoOs,p,haptHe 7.4 010m 002ml : 0.10M NADP 0.825M KCUO.2M MgCl, 004ml 0.04 ml 1 i 59 Homogenate o1.l00omml CHV Study No.: 17750-0409. { 1 ! 0024s5 sy CORNING Hazleton C Contrals 1. VehicleConyols absenceof $9 mix. Vehicle controls were The vehicle control was plated for al plated, using tester strains both in the presence and a 50 ul aliquotofvehicle (equal to the `temsatexrismruaminalainqduoato5f0t0esutl aarltiiqculoetdiolfuSti9onmiplxat(ewdh),enalnoencgeswsiatrhy)2, 1o0n0swelleacltiiqvueoatgaorft.he appropriate : 2. PositiveConurals stains plated concurren"tTlhye cwoimtbhitnhaetaisosnasyofaproesiintdiivceatceodntirnoTlas,blaecLtIivation condition and tester ) i "TTesAtBerLE POSITIVECONTROLS Cone :: STiAmSiSn S9+Mix Po2saimtiinvoeaCnotnhtrraoclene pe2rg5lmatge TA% ~ 2mnitrofluorene TAI0 + 2-aminoanthracene 100g 25ug TAO TAIS}S + sodium azide 2-aminoanthracene 20g 25g TAIS3S TAIS}7 + sodiumazde 2-aminoanthracenc 2250p1gg :. TAI? - ICRISI 204g WP2orA + 2-aminoanthracene 250g WP2ivrA _-_ d-nitroquinoline-N-oxide 1.0 ug a Source and Grade of Positive Control Articles purity 2 97.5% 2-nitrofluoren2e-(amCiAnSoa#n6t0h7v-a5c7e-n8e),(AClAdSri#c6h1C3-h1e3m-i8c)a,lSCiog.m,apuCrhietmyi9c8a%l;Csoo,dium i aPzoildyesc(iCenAcSes#2I6n6c2,8p-u2r2i-t8y)>,9S5i%gamnadChSeimgimcaalChCeom.icpuarlitCyo>,p9u8r%i;tyIC9R8-%1;914-n(iCtArSoq#ui1n7o0l7i-n4e5--N0-)o.xide (CAS #56-57-5), Sigma Chemical Co., purity >99%. : CHV Study No.: 17750-0-409R. : is 00246 CORNING Hazleton 3. Sterilite Conrols a TestAnicle : by plating a 50 ul aliquot (heTshaememovsotlucmoneceunsterdatiendthteesatsasratyi)cloendisleulteicotnivweaasgacrh.ecked for sterility bo s9Mix : agar The $9 mixwascheckedforsterility by plating 0.5 mi on selective METHODS ; A. DoseRangefindingStudy i determined in o"rTdheergtrooawltlhoiwntkihbisteolreycetfifoenoctf(acpyptrootpoxriicaittey)doofsetshtotebset taetsitledeitnotthheemtuesttagseynsitceimtywas + assay. 1. Desi : and WP2uvrA both in t`Thheepdroesseenrcaengaenfdinadbisnegncsetoufdy$w9asmipxe.rfToernmeddosuessionfg tteesstearrstticrlaeinwseTrAe1t0es0ted actonocneentprlaattieopneor dfosem.eg Tphereptaetset.articlewas checked for cytotoxicity up toa maximum a Rationale .: is generally representative of tThhateocbysteortvoxeidciotnytohftohtehetretteasrtteirclsetroabisnseravneddboencatuessteerofsaTAiIn0T0'AsI00 ) : rceoamdpialryadtiivsecleymehdigfhrnomumrboeutrionfesepxopnetrainmeenotuaslrveavreirattainotns.pTerheplEastc,hegrriacdahtiiaocnsoolftecsyttoetsoxaiicnity can be a`nWdP2tuhuvsr,Aa ddoiefsfenroenttproasnsgeesosftchyet1otaoxwiacliltmyumtaatyiobne tohbastertvheedS.alAmlosnoe,lltahetcyypthoitomxuirciiutmy istnrdauicnsedhabvye& tmeisxt. anTihelreefiontrhe,eptrhiessewnocueldofre$q9uimriexthmaaydivfafreyregnreeasttlyafrrtioclmetdhoasteorbasnegrevsedbeintetshteedaibnsetnhceeof $9 `mutagenicity assay based on the presence or absenceofthe S9 mix. CHV Study No.: 17750.0409R 16 00247 CORNING Hazleton : 2. EvaluationoftheDoseRangefindingStudy pesplate and/or by a thCiyntnoitnogriocridtiysiaspdpeetaercatnacbeloefathaedbeaccrteearsiaelibnatchekgnruomubnedrloafwnr.everaant colonies 3. SelectionoftheMaximumDosefo theMutagenicityAssy a NoCyotoxicity Observed the highest dose level oftest aSriincleunsoecdyitnottohxeicmiuttyagweansicoibtsyerasvseadyiwnathsetdhoessearmaengaesftihnadtitnegssttedudiyn, the rangefinding study. B. Mutagenicity Assay : I. Design : `TAIS37, and WP2uvr`AThbeoatshsianywthaepsrepsenecearndusafibnsgeontceseotrefrstSrm9aiminxse.TAFSdiSv,e TdoAs1e0s0o,ftTeAstISa3rtSi,cle w`weerree tseeslteecdteadlboansgewditohntthheearpepsruolptrioafttehevedhoisceleraanndgepfoisnidtiinvge csotnutdryo.ls.TheThreesduolsseosfofttheesitntairatlicle mutagenicity assay were confirmed in an independent experiment. 3 2. FreandqRouuteoefAdnminicstatyion incorporation methodol"TohgeytoerstiegrinsatlrlayindsewscerriebeedxpboyseAdmetostehrael (te1st9a7rt5i)cleanvdiaMtahreopnlaatned Ames m(1u9t8a3g)e.nsT.hiIsnmtehethpoldatoeloigncyorhpaosrbaetieonnsmheotwhnotdoodeltoecgttyh2,wtiedtearrtaincgleeo, tfhcltaesssteesrosftrcahienmaincdalthe S9 pmliaxt.(wFhoelrleoawpipnrgopirnicautbea)twioenreatc3o7mb+i2nedC ifnormo4l8t+en8ahgra,rrewvheircthanwtacsoloovneirelsaiwderoentcoouanmtiend.imaAlllagar : doses ofthe test article, the vehicle controls and the positive controls were pated in triplicate. i C. PlatingProcedures `mutagenicity as`sTahye.se procedures were used in both the dose rangefinding study and the i CHV Study No.: 17750-0-409R 17 00248 CORNINGHazleton Each plate was labeled with a code which identified the test atcle, test phase, ester strain, `iamcmteivdaitaitonelcyonpdriitiooon atnhdeidroussee level. The S9 mix and dilutionsofthe test article were prepared v`iWahseand5d9edm1i0x.2w.a5smlnoofrmeoqulitreend,se1l0ec0tipvleotfeosptaegrars(trmaaiinntaanidne0d autl4of5v=eh2icCl)e. ofWhteestnaSrt9icmleixdowsaes required, S00 ul of $9 mix, 100 plof testerstrain and 50 ulofvehicleortestarticle dose was `added t0 2.0 mlofmolten selective top agar. After the required components had been added, the `mixture was vortexed and overlaid onto the surfaceof25 ml ofminimal bottom agar contained in 215 x 100mmpetri dish. After the overlay had solidified, the plates were inverted and ailnicquuobta.ted for 48 + 8 hr at 37 + 2C. Positive control articles were plated using a 50 pl plating : D. ScotrheiPlnatges Plates which were not evaluated immediately following the incubation period : `were held at 5 + evaluation could 3C until such take place. time that colony counting and bacterial background lawn 1. BaBcteariolckgrLaownuEvalnuatdion evidenceofcytotoxicit`yThaencdotnedsittairotniocflethpreecbiapcitteartie.al Ebvaicdkegnrcoeuonfdcyltaowtnoxwiacsiteyvawlausatsecdorfoerd relative 10 the vehicle control plate and was recorded along with the revertant counts for all plates at that i dMoesteholdevselSeocntitohne. data tables using the code system presented at the endofthe Materials and 2 CountingRevertantColonies The numberofrevertant colonies per plate for the vehicle controls and all i plates containing test article were counted manually. The numberofrevertant colonies per plate for the positive controls were counted by automated colony counter with the exceptionof the : ``pwohsiicthivweecroentcrooulnstfeodr mteasntuearlsltryain WP2uvrA in the absence of $9 mix, in Experiment 17750-B1, E. AnshsisofData were calculated.FoTrhalelrreespullitcsatoeftphleatsiengcsa,lctuhleamtieoansnarreeveprrieasnetnstpeedripnltaatebualnardfthoermstianntdhaerdDdaetvaiation Tables Sectionoftis report. i CHV Study No.: 17750-0-409R. 3 i 18 i 00249 tL . CORNING Hazleton EVALUATION OF TEST RESULTS Before assay data were evaluated, the criteria for a valid assay had to be met. A. CriFotrAeVarlidiAssaay `The following criteriawereused to determine a valid assay: . 1. TesterSwainlotegrity Salmonella typhimurium a ofa Wall Mutation !: cultures exhibited sensitivity `To demonstrate to crystal violet the presenceofthe rf wall mutation, tester strain } b. pKMIOI Plasmid 3 culturesofteste srains TA`aTonddeTmAo1ns0t0raetxehitbhietperderseesnicsetoanfctehteo Ra-mfpaiccitlolripnlasmid, pKMI01, . Characteristic NumberofSpontaneous Reverunts ; cultures exhibited a characteris`tTiocdneummobnsetroraftestphoenrteaqnueioruesmreenvterftoanhtispteirdipnlea,ttehwehteesnteprlastureadinalong : } wwietrhetahsefvoelhliowcsl:e under selective conditions. The acceptable ranges for the mean vehicle controls ) TASS 8-60 TAI00 60-240 : TASS 4. 4s TASS? 2.25 ! 2. TestorSuainlnvegrity : Escherichia coli 2 Characteristic NumberofSpontancous Reveruants ; culture exhibiteda To characteristic nduemmobnesrtorfatsepothnetarneeqouuisrermeevnetrtoanrtstrpyeprtpolpahtaen,whtheentepsltaetredstarlaionng CHV Study No.: 17750-0-409R 19 i C0250 CORNINGHazleton `cwointthrotlhse wveahsicletou4n0derrevseerlteacnttisvepceornpdaittei.ons. The acceptable range for the WP2uvrA mean vehicle 3. Tester StusinCultureDensity To demonstrate that appropriate numbers ofbacteria are plated, the density `aoftatregsetterlsetvrealioncfutlutrubriedsitwyerdeemgornesattrearttehdantoo rpreoqduuacletcou0l.t5urxes1w0itbhacatdeernisaipteyr mland/or had greater than or reached equal to 0.5 x 10 bacteria per ml. 4. PositiveControlValues a Positive Control Values inthe AbsenceofS9 Mix To demonstrate that the tester strains were capableofidentifying a i: 3`-mfuotladgeinn,crtehaesmeeoavnervtahleuemeofena pvoasliuteivoeftchoentrvoelhifcolreacorenstpoelctfiovrettheasttesrtasitnr.ain exhibited at least a : b. Positive Control Values in the Presenceof S9 Mix ' (9 Mix Integrity) To demonstrate thatthe S9 mix was capableofmetabolizing a : topefrstothemreutsvateaghiiecnnlietnoctiohtnestmrpourlteasfegonercnteihoacftfttohiremn(.Ss)9,mtihex meexhainbivtaeldueaotfletahsteapo-sfiotlivdeicnocnrteraosleofvoreratrheespmecetainvevalue mutagen. i An acceptable positive control in the presence of S9 mix for a specific strain was evaluated as `having demonstrated both the integrityofthe S9 mix and the abilityofthe tester strain to detect a Ss. Cooicity MN A minimumofthree non-toxic doses were required to evaluate assay data. B. CrFiorAtPoseitirveReispoanse were evaluateda`Oncfeoltlhoewsc:riteria foar valid assay had been met, responses observed in the assay CHV Study No.: 17750-0409R ; 2 00251 CORNINGHazleton i 1. TesterStrainsTA98,TAL00.andWP2ipvrA 2-fold increase in the mFeoarnarteevsetratnaincislepteor bpeatceoonfsaiderleeadstpoosniteiovfet,hiet sheadtetsoteprrostdruaciensaotvleerastthae : mreevaerntarnetvserptearntpslapteerhpaldatteoobftehaeccapopmrpoapnriieatdebvyehaidcloesecornetrsoplo.nsTehtiosiinnccrreeaassiengincotnhceemnteraantinounmsobfetrhoef test ance. 2. TesorSuainsTALSISandTALSYT 3-fold increase inthe mFeoarnarteevsetratnainctlsepetorbpleacteonosiafderleedastpoosniteiovfet,hiet sheatdesttoeprrsotrdauicnesaotvleerastthae rmeevaerntarnetvserptearntpslapteerhpaldatteoofbtehaeccapopmrpoapnriieatdebvyehaidcloesecornetsroplo.nsTehtiosiinnccrreeaassiengincotnhceemnteraantinounmsobfetrhoef test aricle. i RECORDS TO BE MAINTAINED Athlilsrsatwuddyatwai,ldobceuamrecnhtiavteidoni,n trheecosrtdosr,agtehefparcoitliotceoslo,fanCdortnhienfginHaazrleeptorotngIenn.erfaoteadtalseaastreosnueltyoefar fmoalyloewliencg tsoubhmaivsestihoenoaffotrheemefnitniaorneepdormtat(e0rtihaelsSproetnasionre.d iAnfttheer tshteoroangee yfaecairlipteiresioodf,CtohemiSpnognsor HSapzolnestoorn Inc. for an additional periodoftime or sent to a storage faciliy designated by the REFERENCES Ames, BwiNth.Jth.eMScaCiamnonn,ealnlda/EM.amYmamaalsiaakni-.MicMreotshoomdes MfuortadgeetneictciintgycTeasrtc.inoMguetnastiaonndRmeusteaagrecnhs i 1347-364 (1975), 1 Brusick,AnD.eJv,alVu.aFt.ioSnimomfotnhe,EHsSch.erRiocsheinakrcoalniz,WPV.2A.anRdayW,Pa2nudvRr.AS.reSvtearffsoermd.utation assay. Mutation Research 76:169-190(1980). 3 Green, MMuHtaLt.ioannRdesWe.aJr.cMhur3i8e:l3.-32M.ut(1a9g7e6n).testing using ip" reversion in Escherichia coli CHV Study No.: 17750-0409R 21 7 C0052 CORNINGHazleton Maron, D.M., and B. Ames. Revised methods for the Salmonella Mutagenicity Test. Mutation Research 113:173-215 (1983). Vogel, HprJop.eratnieds.D.JM..BiBooln.neCrh.emA.c2et1y8l:o9m7i-t1h0i6na(s19e5o6f)E . coli: Partialpurificationand some CHV Study No.: 17750-0-409R : 2 00253 CORNING Hazleton i BB ACTEA RIALCKGLR AWNO EVALU UATN IONCD ODE "mTihcerocsocnodpiitciaolnolyf(tuhseinbgaackdgirsoseucntdinbgacmtiecriraolscaowpen)ifoervianlduiactaetdiobnosothfmcayctrootsocxopiitcyalalnydatnedst article i precipitate as follows: CODE DEFINITION CHARACTOFEBRACIKGSROTUNIDLCAWSN 1 Nomal Ahealthy microcolony lawn. 2 RSleidguhcleyd Ainncorieacseesibn lthtehsiinzneionfgothfethmeicmrioccroolcoonlioensycolmapwnaraenddoanthe vehicle control plate. : 3 MRoeddeurcaetdely Aincmraeraskeedintthhiennsiinzgeoofftthhee mmiiccrrooccaolloonniyeslacwonmapnardeadnto the vehicle contol plate i:: 4 ERexdruecmeedly iAncnreexatsreeimnetthheisninzieongfotfhtehemimcircotcoocloolnioensycloamwpnaarneddaon the velicle contol plate 5 Awsem A complete lackofany microcolony lawn. 6 OPrbescicpuitradteby eTvhaelubaatcekdgdruoeuntdo bmaicctreorsiaclopliacwnancdalnonromtabceroascccoupraitcelteyst article precipitate. i. Efvolildoewnicnegopfremcaicpritoastceocpoidcetetsottahreticcoledeprnecuimpbitearteusoendtthoeepvlaaltuesaties trheecocrodnedditbiyonadoditfthionboafctkhgeround bacterial Taw. SPriecgihpiistc Nhootwiecveearb,lethmeapcrreocsipciotpaitce pdroeecsipniottatienfolnuetnhceeplaautteo,mated countingof the plate { mp MProedceirpiattaete wTohueladmionutnertfeorfemwaictrhoasucotpoimcatperdecciopuintattiengo,ntthhuesprleaqtueiring the plate to be i hand counted. hp HPreeciapitte pTlhaetelamragkeeasmtohuenrteoqufimraecdrhoasncdopciocunptriecnigpidtifaftiecuolnt the Ewxhaimcphleh:ad4tmopbewcoouulndteidndmiacnautaaplllyatdeueobtsoetrhveemdatrokheadvaeamnoeuxnttorefmmealcyrorsecduocpeidc beasctkagrrtioculned lawn precipiae. : CHY Study No: 17750-0409R FS) . 00254 CORNING Hazleton 1 SECTION IV. RESULTS AND CONCLUSIONS i . CHV Study No.: 17750-0409R : : 2 00255 Bi CORNINGHazleton RESULTS A. TestArticle Handling (CHY Lots 347,Th3e49t,esatnadrt3ic5l2e), Tw6a5s6u4s,edwaasstshteorveehdiactler.ooAmtt1e0m0pemrgaptuerrem.lD,ewihoniiczhewdawsattehre most canoinccleentrreamtaeidnteodacksdoilluuttiioonnipnrealplasreudc,cetehdeitnegstdairltuitciloenfsoprrmeepadraedclfeoarr,thceolmourtleasgsensiocluittiyona.ssTayhe test B. DRosaengefindiStnudgy the dose rangefDinodsiensgtsobetutdeysctoenddiucnttehdeomnuttahgetneistciatrtyicalsesauysiwnegrteessteelrescrteadinbsasTeAdIo0n0tahnedresults of `arWtiPcl2ei, rfAroimn5b,o0t0h0tthoe6p.r6e7seungcepearnpdlaatbes,ewnecereofteSs9temdiaxnd(otnhee prleastuletpsearrdeopser)e.senTteend dinosTeasblofetses1tand t 2t.heTphreesseendcaetaorwaebrseegnecneeorfatSe9d minixExapseerviimdeenntce1d77b5y0-aA1n.ormNaol bcyatcoktgorxiocuintdy lwaawsnoabnsdernvoeddeicnreeiatsheerin : the numberofrevertant per pate. C. MutagenicityAssay `These data were"TgheenmeurtaatgeedniinciEtxypaesrsiamyenrtessul1t7s7f5o0r-TB-1,65167475a0r-Cp1r,esaenndte1d7i7n50T-aDbI.le3sThtehdraotuaghr7.e : pgrreosuepnt(eTdabalsesme4a,6n,raenvder7t)aansndpears pilnadtievi+dusatlanpdlaarted dceovuinattsi(oTnafbolresea3c,h5,traenadtm7e)nt and control "`Tmhuetargeesnuilctisotyftashseayd.osTehreandgoesfeisntdeisntgedstwuedryew5e,r0e00u,s3e,d3t3o0,se1l,e0c0t0f,iv3e33d,osaensdt1o0b0eiegspteerd ipnlattheein both the presence and absence of S9 mix, : aIsnstahye, iEnxitpiearlimmuetnatge1n7ic7i5t0y-Ca1ss(ayT,abElxepse5rainmednt6),17al7l5d0a-tBaIwe(Traeblaecsce3ptaanbdle4)a, annnddo ipnotshieticvoenfinicrrmeaatsoesr.y :i ipnretsheenncuemobrearbosfenrceevoerftaSn9tsmipxe.s pIlnatEexwpeerreimoebnster1v7e7d5w0i-tChl,anaynoofnt-hdeosteesrteesrpSoanisinvsee5i.t0h-efrolidn the : `iTncArIeSa3s7e wihnitchehadbisdennoctemoefeS9thmiexc.ritFeroiratfhoirs repaossiotnitveestreerssptornasien wTaAsISo3bs7erwvaesdrweitteshteedstinetshterain absenceof $9 mix in Experiment 17750-DI. : InunmEbexrpoefrriemveentrt1a7n7t5s0-pDeIr l(aTtaeblwee7r)e, aolblsdeartvaedwewriethactceestpetrabslreaiannTd AaLndS?noipnotshietivaebsiennccreeaosfes in the $9 mix. i All criteria for a valid study were met. 1 CHV Study No.: 17750-0-409R 25 | G00256 1. `CORNING Hazleton CONCLUSIONS . A`TshsearyeswuiltthsoaftCohnefSiarlmmaotnoerlylAas-sEasycihnedriicchaitathcaotl,iu/nMdaemrmtahleicaonn-dMiiticornossoofmtehiRsevsetrusdye,M3uMt.ation `pCeorrppolrataetoiofna'snyteosfttarhteicltee,stTe-r6s5t6ra4i,nsdieditnhoetr icnautshee aprpeosseintciveeoirnacbrseaesneceionfthmeicnruomsboemraolfernezvyemrteasnts prepared fromAroclorTM induced rat liver (59) i CHV Study No.: 17750-04098. i 2% 600257 i. CORNING Hazleton SECTION V. DATA TABLES CHV Study No.: 17750-0-409R s 27 00258 `CORNINGHazleton naa 1 nose avcrFIOIG StoDy Teor AnriouE 1: T6564 JE -- Date FATED: 12-30n-96 VENIGLE: Detentzed wares Dare coma: 18-30n-96 - Tatoo RpvERTANS IR LATE vermin i emETorn e Eo I h TeFmAe J mSE e :]| Test(sA0rospsel)cie es 1 106 s 78 1 n \ 10.0 1 s os s : ww33.3 112220 1A 107s8 1\ 100 us : " A : ss 16 3 us s : wr = : os \ 1000 so A w : : e sos0s0 w 1ue2 r .\ r wo .3 ] E ST im BEEOUeSeS. JD IEE, : CHV Study No.: 17750-0-409R : 28 00259 1. i oz 2 i CORNING Hazleton ! . Teer samscaz 1: Tesen DOSE RANGEFINDING STUDY memo 0 1730-01 Date ELATED: 12-3ume96 VENIGLE: Detontsed vase _-- Date comzD: 10-sume96 "ruck neveRzaves pn pate paseuae ECTr rine tEie n raTe in v suLaraomse eon-- . si 10 3 2 : :i Tees Aoreic 1s : P : : 10.0 2 : u : i wr33.3 16 1 5 3 16 1 = 3 ; 100 ws 1 3 w : 0 : .. ; w To 3 2 : : 1000 s : " : : ss0 u : . : ; _--3000 10 : s : : CHV Study No.: 17750-0-409R i 29 00260 1. CORNINGHazleton |4 MUTAGENICITnYasAeSSA3Y TNDIVIDUAL PLATE CREoSnUeLsTS TEST ARTICLE ID: T-6364 peEneNT 10: 1750-81 DATE PLATED: 20-Jun-96 DATE COUNTED: 28-3un-96 ------------ VEHICLE: Detonized vater PLATING ALIQUOT: 50 41 TE NEJ J SE BEa i a wrmr pra _-- FEL) "1's arson cotucas 3 = mederataly casscnt i CHV Study No.: 17750-0-409R i : 30 c00261 CORNINGHazleton i MUTAGENICITTYanAzSSA4Y RESULTS `Story TEST ARTICLE ID: T-6364 : EXPERIMENT TD: 1775031 DATE PLATED: 20-Jun-96 DATE COUNTED: 28-Jun-96 VEHICLE: Deionized vater PLATING ALIQUOT: 50 pl eee eee. em me we am oan wen --_--_----_ 7 =5 Gnianyprecipoidseasse CHV Study No.: 17750-0-409R. wp5= sfatunrate precipitate [ER sSetadovynpcyaptease 31 : 00262 ; CORNINGHazleton j MUTTARGOEINVIICoIUaTAYLoAPeLSASTA5SY CREoSuUvLsTS Test ARTIcuz To: T-esed exert 1: 17750-C1 DATE PLATED: 25-3u1-96 VEHICLE: Deionized vater DATE COUNTED: 30-9u1-96. 31-Jul-56 FLATING ALtauor: 50 41 -- ee ------ san au -_ one _-- 1: Te PSIeIeIr D53 apience hane L domTaine 1a0 npupmae BS TR nE ie 3Te1a0niy r eventr 3I= p sR eerse uates. i CHV Study No.: 17750-0409R ; 32 00263 : CORNINGHazleton ::: MUTAGENICITTYamALSzSA6Y RESULTS StuRy TEST ARTICLE ID: T-6564 : EXPERIMENT ID: 17750-C1 DATE PLATED: 25-Jul-96 DATE COUNTED: 30-3u1-96, 31-3u1-96 _--m-- VEHICLE: Defonized vater PLATING ALIQUOT: 50 p1 ram ue wie a sum wen i or arses wow moe wos [a I nos : : _-- ms CII Te Th sam ee Ti ATi "1's artery ravens sL edeeseI pracpitase 3 = woderasaly redsent 2 taryerseMcasiunpe)e 1 CHVStudy No.: 17750-0409R 33 00264 `CORNINGHazleton none AEAC icshs7 A Efe ras Anmscas mo: 7-364 . xen 1: 1775001 DATE PLATED: 25-hug96 VEUICLE: Detontzed vater ceDAT--E co-- nrTED--: 27-- -hug---96 ----------Fu--t A--uiau-- ors --50 4-- 1 ------ nwa A FEE i ------ SIE i pes 38 re CHV Study No. 177500405 34 C0265