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AR 226 - 0869 ACUTE TOXICITY TO FISH (MUMMICHOG) TEST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a componentof FC-780. (1Octanesulfonic acid) (CAS # 2795-393). Remarks: The 3M production lot number was not available. The test sample is FC-780. Current information indicates it is a mixture of 0.5% PFOS, 14% diethylene glycol butyl ether, 76.95% water, 5.5% urea, 1.0% Sultone foamer, 1.15% sodium octyl sulfate, 0.8% polyoxyethylene monooctylphenyl ether, 0.05% sodium lauryl sulfate, and 0.05% tolyltriazole. The following summary applies to a mixture with incompletely characterized concentrationsof impurities. Data may not accurately reflect the toxicity of the fluorochemical componentofthe test sample. METHOD: Method: Not given Type: Acute static GYeLaPr:coNmopleted: Not given. Species: Fundulus heteroclitus Supplier: Not given. AEnxaploystiucrael pmeorniiotdo:ri9n6g-:hoNuorts given. Test organism age: Not given. Statistical methods: Not given. Test conditions: Dilution water: Not given. Dilution water chemistry: Not given. Lighting: Not given. Stock andtestsolution preparation: Notgiven. Exposure vessels: Not given. `Number of replicates: Not given. Number of daphnids per replicate: Not given. Number of concentrations: Not given. Water chemistry during the study: Not given. RESULTS ---- Nominal concentrations: Not given. Element values: 96-hour LC50 = >5000 mg/L 002495 Element values based on nominal concentrations. Remarks: Testing was conducted on a mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. CONCLUSIONS The 96-hour LCs, for FC-780 was >5000 mg/L. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 De AVAQUALITY cm. Reliability: Kiimisch ranking = 4. Values are from a summary sheet only -- raw data not found. Study lacks description and recordsofthe method followed. There is no characterizationofthe test substance purity and the study lacks analytical confirmation of the amount of fiuorochemical proportion in the solution. REFERENCES Test was conducted by the Naval Research Laboratory, Fire Supression Section, Washington, D.C., 1977. OTHER Last changed: 6/26/00. 002496 EEnnvviirroonnmmeennttaall LEanbgoirnaetsorriyng and Pollution Control 3P0O0BBouxsh33A3v3e1nue St Paul MNss133 Teimesio COMMERCIAL CHEMICALS DIVISION 3M BRAND COMMERCIAL'#GCR-A7D8E0 AFEF 6% CONCENTRATE DESCRIPTION: Fire extinguishing agent. APPEARANCE: Clear amber liquid. COMPOSITION: . Percent by Weight Diethylene glycol monobutyl ether water(Butyl Carbitol) OFrlguaonriocalispuhraftaicctanstusrfactants Urea u s 77 o <56 USAGE: pFaCr-t7s80FCis-78e0m)plotyoedextaitngaui6s%hlefvierles (ie.ngv.o,lvi9n4gpalritqsuidwatfeurelstoan6d other liquid organic compounds. AQUATIC TOXICITY: Test Organism 96-Br. LCso FC-780 C(oEmumnodnuluMsummhiectheorgocloirtuKsi)lle Fish 5,000 mg/1 BIODEGRADATION: * CRhaetmiiocaolf OTxwyegnetny-DDaeymanBdioc(hCeOmD)ical Oxygen Oxygen Demand Demand t(oB0CDh2e0m/CiOcDa)l 0.32 g/g 0.98 * ASsectrieopno,rteWdashbiyngtthoen,NavDaC.l Research Laboratory, Fire Suppression Oute 6/11/82 (Supersedes 1/8/80) These data ae intended for the use ofa person auliiedto evaluate environmental dat. ATiltesraattuermeainntfso,rmtaetcihonincwaelbienlfioervmeattioonbeanedlarbelceo,bmmuetntdhaetaicocnusraccoyn,tcaoimnepdlehteerneienssaroeroaf apgapneiracl naaotbupriaertalincdtulayarrecbiarsceudmsotnanlacbeosriastnoorty gteusatsror aonwtso,edr.egSuMlatmionsaannodrk reuplreesseentas tion that the customer's use and disposal of the product will comply with al applicable environmental \ fom ros wo \ 002497