Document NGZg2eeD5jw3NkGQopzyda46R
AR226-3588
ANALYTICAL REPORT
E . I . DuPont Project : APFO Analysis
(FAY) Fayetteville, NC Sampling 11/05 LBIO-65332
7035-504461-772000 Release STL17459
Lot # : D5K230384
p . 81
STL
STL Denve r 4955 Yarrow Street Arvada, CO 80002 Tel : 303 736 0100 Fax: 303 431 7171 www.stl-inc.co m
rn -.,
rr;
~
Michael Aucoin ADQM AP Services, CRG DuPont
Barley Mill Plaza Bldg 27 Lancaster Pike & Route 14 1
Wilmington, DE 1980 5
Severn Trent Laboratories, Inc ./STL Denver
4/ail eRuz Project Manager
November 30, 2005 Revised Case Narrative January 26, 2006
Leaders in Environmental Testing
Severn Trent Laboratories, Inc.
p . 82
Tabie Of' Contents
Standard Deliverables with Supporting Documentation'
Report Contents Number of Pages
Standard Deliverables
p(TarhtesCoofyt_hefrsSLteatrtiedraarnddDtehleivReerpaborl'teC'podv:e&rgpea:g'7e7aiirserceopn~s*itdres'rrend'~innrtpefgertael ,,... . unless all pages indicated in this Table of Contents are included.)
Table of Content s Case Narrative Executive Summary - Detection Highlights Methods Summary Method/Analyst Summary Lot Sample Summary Analy tical Results
~ QC Data Association Summary Chain-of-Custody
Supporting Documentation
(Note: A onepage "Description of Supporting Documentation" is provided at the beginning of this section) .
Volatile GC/MS
Check below when supporting
documentation is present
Semivolatile GC/MS Volatile GC
~ Semivolatile G C
LCMS or HPLC /
Metals
,
General Chemistry
Subcontracted Data
STL Denver L:\PM\PMs\Forms\toc expanded .doc
D5K230384
p . 83
Case Narrative D5K230384
The results included in this report have been reviewed for compliance with the Laboratory Quality Manual . All results have been found to meet all requirements of NELAC an d any exceptions are noted below .
This report shall not be reproduced except in full, without the written approval of the laboratory or sponsor . Dilution factors and footnotes have been provided on each datasheet to assist in the interpretation of the results .
Sample Arrival and Receipt
The three aqueous samples and one field blank presented in this report were received at the STL Denver laboratory at a temperature of 3 .9C on November 23, 2005 .
Standards
Analytical standards were prepared using the acid form of the compound perfluorooctanoic acid (PFOA) . The concentrations are converted to express the concentration in round numbers as the ammonium salt ammonium perfluooctanoate (APFO) so that results can be reported as both PFOA and APFO.
A di-carbon-13 labeled perfluorooctanoic acid, [1,2-di-11C] was introduced at the extraction step and was used as an internal standard for quantitation of APFO and PFOA.
Sample Extraction and Analysis
The samples presented in this report were analyzed for the target analyte by STL Denver's SOP DENLC-0 0 12A. The samples were tested unspiked only as insufficient sample volume was available to test the samples in duplicate and spiked with the target analyte .
For water samples a 250 mL aliquot of each sample is acidified with 1 mL of 6N HCl solution and it is extracted using solid phase extraction technique with methanol conditioned C 18 cartridges . Each sample is spiked with the internal standard, prior to extraction . After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol . The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS .
The target analyte is separated from other components on a high-performance liquid chromatography (HPLC) C18 column with a mobile phase mixture of water containing 0 .1% formic acid and methanol . The mass spectrometer detector is operated in the electrospray (ESI) negative ion mode . The instrument is calibrated at 6 concentration levels (1, 2, 5, 10, 20, and 50 ug/L) . The target analyte is detected as the perfluorooctanoate anion with the parent ion of 413 amu. The daughter ions used for analysis by LC/MS/MS are at 369 and 219 amu . The ratio of the peak areas to the two ions must be 20% of the ion ratios in the mid-point ICAL for qualitative identification . Sample results are quantitated using the internal standard method .
Tunine and Calibration
The instrument is tuned with a solution of the target analyte such that mass assignments are within 0 .5 amu of the daughter ions . The instrument is calibrated with six concentration levels from 1 ug/L to 50 ug/L . Linear regression (y=ax+b) was used with a correlation coefficient >_0 .990 .
STL
Denver
2
y
D5K23038 4
p . 84
Following initial calibration (ICAL), an initial calibration blank (ICB) is tested, which consists of methanol spiked with the surrogate . The result for the target analyte must be less than the limit of detection (LOD = 0 .002 ug/L for waters) to proceed .
Next an initial calibration verification (ICV) standard is tested . This is a mid-level concentration standard from a different vendor from the ICAL standard . The ICV must be within 80-120% of the true value .
The quantitation limit verification standard (LOQ = 0 .01 ug/L for waters) is a standard from the same source as the ICAL tested run at the LOQ level to determine accuracy near the detection limit . This recovery must be within 80-120% .
Continuing calibration verification (CCV) standards are tested every 10 injections and are from the same source as the ICAL and are at mid-level concentration . The recovery of the CCVs must be 80-120% or recalibration is necessary.
A closing calibration of the six standards is also done to verify instrument drift and to verify the correlation coefficient. The recoveries of the 2, 10, and 50 ug/L standards must be 80-120% .
Method OC Samples
The Method Blank is processed reagent water spiked with internal standard and prepared with each batch of 20 samples of the same matrix . All samples in the batch are processed at the same time and with the same reagents . The method blank must be less than the LOD or associated batch samples must be reextracted and reanalyzed .
Each batch is prepared with a low- and a mid-level concentration spike Laboratory Control Samples (LCS) . The recoveries of these samples must be within 70-130% or associated batch samples must be reextracted and reanalyzed. If the recovery is biased high and samples are non-detect, results can be reported without re-extraction .
Calculations
1 . Sample Result Calculation
For internal standard quantitation, APFO Response = area of APFO / area of APFO 1,2-di"C
Concentration in waters, ug(L =(C,, V~/(Vo) Where : C,,, = Concentration measured in sample extract from the target analyte response (ng/mL) V, = Volume of total extract (mL ) Vo = Volume of water extracted (mL )
If results are to be reported as ammonium perfluorooctanoate (APFO), in addition to PFOA, a multiplier of 1 .0406 is applied to sample results to correct for the molecular weight differences between PFOA and APFO . This adjustment can also be made during the preparation of the standards used for calibration .
STL
Denver
3
D5K230384
p . 85
2 . Percent Recovery Calculation
Spike Recovery = (SsR-SR)/(SA)x100% Where : SSR = Spike sample result SR = Sample resul t SA = Spike added
3 . Relative Percent Difference Calculation
RPD = (SR - DR)/(1/2(SR-DR))x100
Where : SR = Sample result DR = Duplicate result
PFOAJAPFO Analysis Anomalies
No anomalies were noted .
Revision
The report was revised 12/28/05 to report results to the LOD (recorded as the 1VIDL in the report) and the LOQ (recorded as the RL in the report) . The revision on 1/20/06 is to include the documentation on the LOD/LOQ determination, which follows the an alytical report. The raw data is included in thi s submission . On 1/26/06 the case narrative was revised to remove references to APFN .
STL
Denver
4
p . 86
f0,~
11t~ O .~+ m 0~ p C C
.'_ f'
O
cdr
ca
O O > m
m
~
O O O U .,,m., .~ C
75
U m U C ~ (l1
O L Y
m
. .~ C9 Q
C) m CO
m J E 'p cy E ~Q .0 l0 .
O_ C m m p t]
C') m O O O O V~
L
CD
C~
-1 C O O O O m~ m U m
O
~ LY
flm
=
J
f0
u .
.L..
CO~C C O
-p
mL
V m
C
tmLC
>
C
m m m C U tn . m a 7~ C m O
oo w .+O~
7O. ra
CY z z z
::S ~ E yL0
y~p N C
m mJ
y
0 0 aj
= C
C
. .~mmccco
015-S
~ 0 .2
m C mJ
~ c ~
m
m
.+ m ~0 C1
m33
o mn 00' mc~Xm a~o.~
w aa z z z ~O
Eco ~N
75 ~ w o
-0 p
~
C
ONy -
7 V O
5
~
m
cj II (6
. ~ U m m cm ; .m.
cc
0 0
~ (a ~O N
C
7 mmOJ d
A m~
W
m
m
m m mm
CD Cl)
>
-`-
'? amCD
n E :3
~
co
aw m
m,,t.o ,
m7v=---=0m Lo I I
ccE
co CJc m
m10d~mom Oo~
o
N ~ ~~ p . o ~'C a u
J ~ ~~~~~0mc~oma~~~v
Z` U ~ ~Z 3_ a
V~ y} } } }
Wfn F~1
LL LL LI. lQL
.- N M d'
c N o y mYd~ o
il$HllH m 3~ ~ m
LU
c 2 co E~ E m
0
Uo
_0 2 OZd O- co m m = ~O a>
z z
0G m G J~ cC
~ C!~
mm
E 'OE
Uc)a z=
STL
Denver
5
METHODS
Y
D5K230384
p . 87
PARAMETER'
ANALYTICAL PREPARATION METHOD METHOD
LC/MS/MS, PFOA DEN -LC-001 2
Refeiences :
DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure .
STL
Denver
6
p . 88
METHOD / ANALYST SUARVIARY .
D5R230384
ANALYTICAL
ANALYST
METHOD
ANALYST
ID
DEN -LC-0012 Steve Cowling 008738
References' :
DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure .
STL
Denver
7
p . 89
SAWLE SUAEMLARY
D5K230384
SAMPLED SAMP WO # SAMPLE# CLIENT SAMPLE ID DATE TIME
HQW31 HQW32 HQW34 HQW35
001 FAY-D-4328MLR 11/16/05 002 FAY-D-6999PED 11/16/05 003 FAY-K-FBLK-1 11/16/05 004 FAY-D=53I'StCAR 11/16/05
13 :10 14 :13 15 :20 13 :51
NOTE(S) : - The analytical results of the samples listed above are presented on the following pages . - All calculations are performed before rounding to avoid round-off erro rs in calculated results . - Results noted as 'ND' were not detected at or above the stated limit . - This report must not be reproduced, except in fiill, without the written app ro val of the laborato ry. - Results for the following parameters are never reported on a dry weight basis : color, corrosivi ty , density , flashpoint, ignitability , layers, odor, paint filter test, pH, porosity pressure, reactivity , redox potential, specific gravity , spot tests, solids, solubility , temperature, viscosity, and weight.
STL
Denver
g
P . 90
S .I . Dupont De Nemours and Co
Client Sample ID : FAY-D-4328MUR ..
HPLC
Lot-Sample # . . . : D5K230384-001 Date Sampled . . . : 11/16/05 13 :10 Prep Date . . . . . . : 11/28/05 Prep Batch # . . . : 5329125 Dilution Factor : 1
Work Order #- . . : HQW311AA Date Received . . : 11/23/0 5 Analysis Date . . : 11/29/05 Analysis Time . . : 18 :43
Matrix . . . . . . . . . :
1K'et:T'iod. . . . . . . . . DEN -LC=O0-I2"
WATER
REPORTING
PARAMETER RESULT LIMIT UNITS MDL
PFOA
0 .010 0 .010 ug/L 0 .0020
Ammonium
0 .011 0 . .010 ug/L 0 .0020
Perfluorooctanoa.te (APFO)
PERCENT RECOVERY SURROGATE RECOVERY LIMITS 13C2 80 (50 - 200 )
STL
Denver
g
P . 91
E . 1 . Dupont De Nemours and Co
Client Sample ID : FAY-D-6999PED
HPLC
Lot-Sample # . . . : D5K230384-002 Work Order #- . . : HQW321AA
Date Sampled . : . :- : 11/16/05 14 :13 Date Received . . : 11/23/0 5
Prep Date . . . . . . : 11/28/05
Analysis Date . . : 11/29/05
Prep Batch # . . . : 5329125
Analysis Time . . : 18 :47
Dilution Factor : 1
Met~od:-------- I7EN"'-DC-UO'IZ'-
Matrix . . . . . . . . . : WATER
REPORTING
PARAMETER RESULT LIMIT UNITS MDL
PFOA
ND
0 .010 ug/L 0 .0020
Ammonium
ND
0 .010 ug/L 0 .0020
Perfluorooctanoate (APFO)
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
13C2
76
( 50 - 200 )
STL
Denver
10
p . 92
E .I . Dupont De Nemours and Co Client Sample ID : FAY-R-FBLK-1
HPLC
Lot-Sample # . . . : D5K230384-003 Date Sampled . . . : 11/16/05 15 :20 Prep Date . . . . . . : 11/28/05 Prep Batch # . . . : 5329125 Dilution Factor : 1
Work Order # . . . : HQW341AA Date Received . . : 11/23/0 5 Analysis Date . . : 11/29/05 Analysis Time . . : 18 :52
Matrix . . . . . . . . . : WATER
Method'." . . . . . . . . : DEN- -LC= Cr0IZ"
REPORTING
PARAMETER RESULT LIMIT UNITS MDL
PFOA
ND
0 .010 ug/L 0 .0020
Ammonium
ND
0 .010 ug/L 0 .0020
Perfluorooctanoate (APFO)
PERCENT RECOVERY SURROGATE RECOVERY LIMITS 13C2 80 (50 - 200 )
STL
Denver
11
p . 93
E .I . Dupont De Nemours and Co
Client Sample ID : FAY-D-5319KAR
HPLC
Lot-Sample # . . . : D5K230384-004 Date Sampled . . . : 11/16/05 13 :57 Prep Date . . . . . . : 11/28/05 Prep Batch # . . . : 5329125 Dilution Factor : 1
Work Order # . . . : Date Received . . : Analysis Date . . : Analysis Time . . :
Method . . . . . . . . . :
HQW351AA 11/23/0 5 11/29/05 18 :56
DEN -LC-0012
Matrix . . . . . . . . . : WATER
REPORTING
PARAMETER RESULT LIMIT UNITS MDL
PFOA
0 .0051 J 0 .011 ug/L 0 .0020
Ammonium
0 .0053 J 0 .011 ug/L 0 .0020
Perfluorooctanoate (APFO)
SURROGATE 13C2
PERCENT RECOVERY RECOVERY LIMITS
89 (50 - 200)
NOTE ( S ) : J Esdmated resah. Result is lea than RL.
STL
Denver
12
p . 94
QC DATA ASSOCIATION
Y
D5K230384
Sample Preparation and Analysis Control Numbers
ANALYTICAL LEACH PRE P SAMPLE# MATRIX METHOD BATCH # BATCH # MS RUN#
001 WATER DEN -LC-0012 5329125 5329070 002 WATER DEN -LC-0012 5329125 5329070 003 WATER DEN -LC-0012 5329125 5329070 004 WATER DEN -LC-0012 5329125 532907 0
STL
Denver
13
p . 95
METHOD BLANK REPORT
HPLC
Client Lot # . . . : D5K230384 Work Order # . . . : HQXPR1AA Matrix . . . . . . . . . : WATER MB Lot-Sample # : R5K250000-125
Analysis Dilution
Date . . : 11/29/05 Factor : 1
Prep Date . . . . . . : 11/28/05 Prep Batch # . . . : 532912 5
Analysis
Time . . : 18 :30
REPORTING
PARAME TER RESULT LIMIT UNITS
PFOA
ND
0 .010 ug/L
Ammonium
ND
0 .010 ug/L
Perfluorooctanoate (APFO)
DEN DEN
METHOD -LC-0012 -LC-0012
SURROGATE 13C2
PERCENT RECOVERY
RECOVERY LIMITS
80
( 50 - 200)
NOTE(S) : Calculations are performed before rounding to avoid round off errors in calculated results.
STL
Denver
14
p . 96
LABORATORY CONTROL SAMPLE DATA REPORT
HPLC
Client Lot # . . . : D5K230384
Work Order # . . . : HQXPR1AC
LCS Lot-Sample# : R5K250000-12 5
Prep Date . . . . . . : 11/28/05
Analysis Date . . : 11/29/05
Prep Batch # .- . : 5329125 Analysis Time . . : 18 :34
Dilution Factor : 1
Matrix . . . . . . . . . : WATER
SPIKE MEASURED
PERCENT
PARAMETER AMOUNT AMOUNT UNITS RECOVERY METHOD
Ammonium
0 .208
Perfluorooctanoate (APFO)
0 .211
ug/L
101
DEN - LC-0012
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
13C2
86
(50
-
200)
NOTS (S ) : Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters
STL
Denver
15
p. 97
;
.
..
LABORATORY CONTROL SAMPLE DATA REPORT
HPLC
Client Lot # . . . : D5K230384
Work Order # . . . : HQXPRIAD
LCS Lot-Sample# : R5K250000-12 5
Prep Date . . . . . . : 11/28/05 Prep Batch # . . . : 5329125 Dilution Factor : 1
Analysis Date . . : 11/29/05 Analysis Time . . : 18 :39
Matrix . . . . . . . . . : WATER
SPIKE MEASURED
PARAMETER AMOUNT AMOUNT UNITS
A""vn' ium
0 .0208 0 .0212
Perfluorooctanoate (APFO)
PERCENT RECOVERY METHOD
ug/L 102
DEN - LC-0012
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
13C2
79
( 50 - 200)
NOTg ( S ) : Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters
STL
Denver
16
x
n N ~ E ~; O
p . 98
X
n x o ~p'
N :~w~ ~ ~ rr
rM
0
T
1~ r~
w oc
3 rr
13
r r z a
BP
~
~
N
?LnM m
;-0
0
o LM
3
f
v
'o'
rtT
o
-IM X
te a~a
[wj
CA
p
Q
7 = W
\ h ~ 0 3~ (
~~ ~
c
p z ~
n n
Grab p,
Pl. c O O. O
Composite
p, ~ rt
`. ~
o Number of ~ Containers
v ~ S'a ^
H O Z '^
cra
Ns Vw
3 O
0:P.0"a;a "n
~
OQ
.
a ~ o ~ ~ x Sco ~ .
s v Cox o
Z
W) PI
:A' ~- ~
a 3 vo r~ ~ `M
~ o O ~
e
VI
z
r
Q c -
-%
>
~
3
y
A
qQ ~ (D
I~
\
oT
I
uuuuuu ~ ~ ~ ~ ~c ~
. ~ D A E,_
- LA
`
.
p Da Da D D N c o Ci c w G o/
a OR a a
n
- t.
p
SU 0
n o
<
LA
0 M O
~
~-
~ (D II
~
3
^
Q
o ~
i a s ID
~
~ f
'iW V~
c
C'S
STL
Denver
17
STL Denver
Sample Receiving Checklist
Lot # : Date/Time Received : ///"5 /03d
Company Name & Sampling Site:
f//~ZYJI'J~ //
PM to Complete This Section : Yes Residual chlorine check required:u
Quote # :
Special Instructi ons :
N Yes No ~ Quarantined : u u
P . 99
Time Zone : EDT/EST CDT/CST ' MDT/MST PDT/PST OTHER
Unpacking, Checks :
Cooler #(s) : ~
Temperatures (C) : ~ N/A Yes No - Initials u2' u 1 . Cooler seals intact? (N/A if hand delivered) If no, document on CUR.
,Z' u 2. Chain of custody present? If no, document on CUR .
u ;2r 3 . Bottles broken and/or are leaking? If yes, document on CUR.
u ~ 4- Multiphasic samples obvious? If yes, document on CUR-
C) 5 . Proper container & preserv atives used? (ref. Attachment D of SOPr DEN-QA-0003) If no, document on CUR.
,21' u u 6 . pH of all samples checked and meet re quirements? If no, document on CUR .
,Er u
7. Sufficient volume provided for all analysis requested? (ref Attachment D of SOP# DEN-QA-0003) If no, document on CUR, and contact PM before proceeding .
~ u 8 . Did chain of custody a gree with labels ID and samples received? If no, document on CUR.
,E~I u u 9 . Were VOA samples without headspace? If no, document on CUR-
C2 u 10 . Were VOA vials preserved? Preservative uHCl u 4y 2 C u Sodium Thiosulfate u Ascorbic Acid u ?f 11 . Did samples require preserv ation with sodium thiosulfate ?
,Zr u u 12 . If yes to #11, did the samples contain residual chlorine? If yes, document on CUR0 u 13 . Sediment present in dissolved/filtered bottles? If yes, document on CUR-
0u
~u u ~rd
14 . Is sufficient volume provided for c li ent requested MS, MSD or matrix dupli cates? If no, document on CUR, and
contact PM before proceedin g -
~.~------
15 . Receipt date(s) > 48 hours past the collection date(s~ . - es, no ify PA/PM-
16 . Are analyses with short holding times requested?
----------------
u ~ 17 . Was a quick Turn Around (TAT) requested?
STLP1)k&-FP6-'1 . 1e ReceivinglSample Receiving Cbecklist 12 13 04 revision
12/13/04 18
STL Denve r
Sample Receiving Checklist
p . 100
Lot #
Login Checks :
Initials
N/.4
Yes
No
~
~u
18 . Sufficient volume provided for a ll analysis requested? (ref. Attachment D of SOP# DEN-QA-0003) If no , document on CUR, and contact PM before proceeding.
u u
19 . Is sufficient volume provided for client requested MS, MSD or matrix duplicates? If no, document on CUR, and contact PM before proceeding.
. 2r u 20 . Did the chain of custody includes "received by" and "relinquished" by signatures, dates, and times? u J~ u 21 . Were special log in instruc ti ons read and followed ?
0 u 22 : Were AFCEE metals logged for refrigerated storage ?
u 23 . Were tests logged checked against the COC? Which samples were confirmed?
u u 24 . Was a Rush form completed for quick TAT ?
.~ u u 25 . Was a Sho rt Hold form completed for any sho rt holds?
u ~ 26 . Is "Strict ICOC" required?
27 . Were special archiving instructions indicated in the General Comments? If so, what we re they?
A U
4pro /
Labeling and Storage Checks :
~]--0 u Zr~- u u 3~'-u
u u u u u . C3
28 . Was the subcontract COC signed and sent with samples to bottle prep ? 29 . Were sample labels double-checked by a second person? 30. Were sample bottles and COC double checked for dissolved/ filtered metals by a second person? 31 . Did the sample ID, Date, and Time from label match what was logged ? 32 . Were stickers for special archiving instructions affixed to each box and to the ICOC? See #27 33 . Were AFCEE metals stored refrigerated? 34. Were "Strict ICOC" copies given to satellite storage areas ?
Initials -~-
Document any problems or discrepancies and the actions taken to resolve them on a Condition Upon Receipt Anomaly Report (CUR) .
\QA\Forms\Sample Receiving\Sample Receiving Checklist 12 13 04 revision 12/13/04
STL
Denver
19
Lot Number: 'b5K 2.303fS4
Vl g "sUlll; 1JiLLiI itCVlCVY 1 C111 p 1'sLL C
Client : " arnt
Analytical Due Date :
p . 101 ~d-1dOS
Sample Numbers : !- y
PA/PM : Reviewed by/Date : JA i I - 10. o
Method :
Fpfa
Batch #: 5 3 a c 't l a 5
Calibration Issues : YES NO ICAL/ICV/CCV (NCM#04- _
Den-Std. 1 DCS CLP Form -8 / 6-8
AFCEE form s
1 : Holding Time: All samples were prepped and analyzed within the method-specific holding time requirements .
Samples in this lot were extracted and/or analyzed beyond the required hold-time . (NCM#04-
2 : Method Blan k
(
All criteria were met for the method blank .
Criteria for method blank were not met . (NCM#04
3: LCS/LCSD All spike recoveries and RPD data met method QC criteria
Recoveries and/or RPDs failed method QC criteria. (NCM#04-_ 4: MS/MSD
All spike recoveries and RPD data met method QC criteria
Recoveries and/or RPDs failed method QC criteria . (NCM#04-
Recoveries diluted out .
No MS/MSD . (NCM#04- $3S 4 )
5: Sample Data No issues with sample data.
The automated formula printed on the quantitation report was checked and is accurate .
Sample(s) had surrogate failures . (NCM#04
Sample(s) had ISTD failures . (NCM#04-
Sample(s) were analyzed at a dilution due to target compounds .
Sample(s) were analyzed at a dilution due to final extract volume/ starting volume extracted . (NCM#04-
Sample(s) were analyzed at a dilution due to non-target matrix . (NCM#04-
6: Based on review of chromatograms for sample(s)
, it is my opinion that the evident
interferences are potentially causing false positive/negative results . Date Analyst
7 : Comment s
STL
Denver
20
p . 102
LOD/LOQ Determination
STL
Denver
21
p . 103
Blank 10-Sep-20 0
13 :55 :00
pf35i1018 Sm (Mn, 2x2) MRM of 5 Channels ES-
0.48
412 .8 > 368 .7
62
1 .52e3
Area
.
.
1
,
..
40
Time
0 .20 0 .40 O .fiO 0 .80 1 .00 1 .20 1 .40 1 .60 1 .80 2 .0 0
STL
Denver
22
p . 104
0 .1 ppb 10-Sep-20 0
13 :52 :0
pf35i1017 Sm (Mn, 2x2) MRM of 5 Channels ES-
0 .48
412 .8> 368 .7
81
1 .60e 3
Area
1 .3 7 79
167
h.
35
Tim e
0 .20 0 .40 0 .60 0 .80 1 .00 1 .20 1 .40 1 .60 1 .80 2 .00
STL
Denver
23
p . 105
So corr '
~ LO o 0, t v
~
. L06Z
~~
o . Do'
~ AL
x ~ s = ,~ ~ `~- .
r se~ l
LO~ ,IVo A ~ r~ ~'~
.
.
.
,
.
. ..
STL
Denver
24
TITLE From Page No .
.
.
y~ ,
Book .
Project No. No .
p . 106 .
~-j ,
~, zo~~ol :l~_ "
.. ,__ .
I Y-0 V,
qIIl
1
' .: I i~4 f nm-~~
-
'
;
.
} . _ i . . . .- . . . . ._ ._. ._ .. . ; . .
._ _ . _ _ _ . ~_ - . y_ . ,_ ,-
i
~~
~~I; ~. co f ;~L~ ;~ 1 i AR--6-
;._ ;_~~~~~1~ ! - .~ .__ ; . . -
~ 2. 9JL .r~. .2. . :-._~ i~. ~. .~
-~ - ~ . ~ ; : . _.C . . ~ f -~: , ; ~ - : " '~-
.-- - . ., ._
~
. . _.
~
1
: . . _---i .- ~-- . _.F. .:. . . . ._ .
. ._ . . . .: . , ; . .--- :-- : ._ _ _ _ . ~ _. .
fy
~ ~ i ~i ~ ~ ~ ~ ' ~ ~ ' ~ '
. . ~_ ~ ! , ~ ~
ii " ~ _~
----
h-L ~~td : . ~~~e,.~__~_~, _-~~_~_;, ..-~._ ~ . - : . . . . . . ., .
,
. . ._ . .- -- . . . _ . ~__-. '_-1- -
. ..
. . . _ . : . . -'+ -
, , - - . . ._
~ , !
.
~
. - ' _-~-- j; . ' ---- f -- -
, _. -
. _ . ._ ._.. . : :.. . i . . i_ - . i . .. ._ , . .- . .1 ._- '.- .-_ . .. _ . _ . ~_ . _i _-. .- " __ _. - : .. .. ._i .. _ i~ . _ . .
. ._ _
, ' ~
. __
. I ' ,
.
~
. ' , ,
.
. . . _ . _ . _ , . . .. .._ . . .. . . .__ .
. _..
: .
.
..
.
.
. . ..
,
.
.
. _ _ _-. . . . -. . . ! _ . . . ._ ._ .~-- --" - - - - --' - ~ - I . . .
:. , . .,; .~ .. . .-.. .
. :.
. .
. .
, .
.~ . . i
. . _. , ~ . . _
_ .. . .
_ . .~ .
.
~ . :. .,
. ~~~ ~
.
.
. . ~ . ~ . .
' . . . .. ~._.-.. _ ..
: .
... ~. _ - . .. . . ._._ .,.. . . _ , - .. ~;
; ~_ . . .: .. . _. . . . .. . . _. . _ , . .._ . . .. . ~ _ ,
.
,
.
~
,
. . . a ._ . . .~ . ._ . . . I_ ._ . . .. .
. . -
- -
.
.- ._
.
,
.
~
~
.
. ..
. . . . . . _ . . ... . .~ . . . . .' _ : . . .~ . . . .~ . _ ._ _ i . . . ~ .
..
.
..
..~
;~`:.
.
.~. .
..: .. i ..
. _. .
" _. ..~ :. .
. ._ .. ' . ,
.
.
'
. ~:
.
i
:i
. , . . .: , , . .
: . . . ..
.. ._ . .
~ . .._,_ . . ~
, .. . . .
.
.
.
.
.
. _ . _ -_ _ _ _ -
, . . . . . . . . . . , . . . . .i . .,_~
.. _ _
.
._
. _ ._ ._ ..
, . . ._ .-
.
.
.
.
i'
~.
:
.__
.
.
~
. ~.
:
, . .<
-7"
._;_I' _ f . . ~.
.
I ..
' r ._ _ I . ~- __ ._ _ . ._ r- _..-~r---~ - ~ -. _ -- -' - ~ ' -
.
~ .. .
~ ._-
`-
:, -
. .. .
~
~
. . . ._ .._
. . :
,
-
~ ~ ~"--- i---'
. . .. ._.
'
~
,
.-_~-:__ . _ . ' - ~ _ . .
~ - - - ._ -----~ -~----~--i ?-- - - F f--- , . . -
. , :, .
, .e : .. :
. . - .
: - -- --: - ".-- --. ~ --- -
---
~ _.
. . ._. .
+ +
s~ .. ; .. , . ., .
~
"~
,
_
. - - - r--- --- - ----- - . i. . - -- ------
. a.:~.. ,~.,. y. . . . . . . . . ' ,:. _ . . .
..
. : .: . i .~ . i. . . . ~._ .
. ._
. ~
. ~
,
..
.
: ,
.- !
;
. ~ - ~ ~
. '
.
. I I
Witnessed & Understood by me, Date Invented by:
:;:To Pa e No . Date
/~ ~ .~05
~ ~i(r+" ' r6 A S'I' Denver
Recorded y :
p . 107
LC/MS
Supporting Documentatio n
Sample Sequence, Chromatograms/Mass Spectr a
STL
Lot ID: 71 5 K 2 3o3gq Client :_~crn Method: ~ Fo(Associated Samples: I ' j Batch #(s): 5 3 a4 I a5
I certify that, to the best of my knowledge, the attached package represents a complete and accurate copy of the original data .
Signature/Date :
. t! . 3 0- oS'
STL
Denver
26
p . 108
LC/MS SEMIVOLATIL E ORGANIC EXTRACTION
LOG SHEET S
STL
Denver
27
Ln ai
Sd
O ri C~j
'
\
\
\
\
\
N\
N\
kO
l0 l0 lD
kO
4%0
''4 t0
\
'
r-1
r1
.~ ~i r1 ri \ri \rI
0~
V'
N u1 U
f0
\
\
.-1
\ .1
ri
ri rl
O r-I
1.!
\
?.U t+1 rry
riO O O
ro~,) 0 0
.N
\
\
\
O\
O\
H
14 ri
H
H-1
ri rl
.~
H
11
11
1-1
lI
H
r1
f~1 n1 t+1 f
.
.
.
. rHi .
eH-1 .
4.7 ,~~, ~ H GD ri
t0 .i
y
AE+ ~
004
r1
A
d~ V V~ V~ di r-I ~ 'I di
E,F
.~-4
~ ~ ~
~nQ o+ m rn
al
H H~
.~~~
m
clot
a% a,
00
ro~'v ~
; O O NN Ha
.i 'C1 U .i U \\ at' o J m
14
r+N E ~ 1-4
4) 4J aJ Au +~~
AOV :3 O
.
1-4 V rn d)
O o
O 0
.
O O O 00 HO
0 .
0 .
0
0
0
d,~ V 0
ro U o~~ ~d~d aU 0 o r.
oa ) (d 4) M uaoam
04
IIIII
N
~ o 0 0 0 0 0 0
4141
. +
Il1
I
m0 0
H
w
v
a
w
w
w
w
p . 109
~ E- *at ~* ~ x
H w Ls L1
M
x *
E p~7
x x x x x
x
0 0 0 0 0 0
E ~ E ~ ~
MW 4)
# M C![~~, N
Ix
1.3
I O
to E)
~ i !~ Fi t i! n ~ ai
z 1
~
~i
~
IZi
* RI * Ila~~ 04
~~~]i
o 0 0 0 0
a Zi ~
0 0
Od~ alil
A C1 + ~
tq
N N N H o 0
N N N N
0 0 0 0
0
0 11 H
H I r t~ l~ l~ I~ r r
E
r
U E ,
z
H a a a
E C+ E' u ro w \O a E 1 0
E E 0 0
a a a a ~n E E E E a 0 0 0 o W
SN+ ~ m,i O > Q) Lri A
z E+
~n
(7 u~ ~ ~n a1 in ~ ui O in ~ in
H3 1!1 {fl Ui 1+1 If1
In
Ift
N 4) d)
N N N N N N N
v ,,x 'a E
a
a0 SL
0
~x
> x {.' k Q0
H a a Wa w
a W
a
a a
w w
aw
b+ a~ O 4) - .+ E E+ N E~ E F E E ~i
OU3 ) + 4 + FC ~ FC RC ~ FC ~
.7
0
3~ ,o~ ~ 3 3 3 3 3 3 3 rj
Ix
~IrmUia
~
uWp
V O k a-)
in in in in
Ln
in in
E
x
~
szj` c
E OOUrA UW
41
x lP
x l~ 1
x IfA ~
x la~ l
x ~ Q Px n
O 1+ r. 041 O u
EyWC I r PO
~ ~I a
.11 4) (0 .0 0
00Hk 1
ScOnutriAm ~
0
o
a
0i w ~ ~~(nJ A A A A
~
N 1aO -a ~ i.
u U W u ri rl
. C W r-I -+ rd 0
46
W a
a H w ~ N
(n
u,
L,
rn -14
bl~e C a E .+ o 0 0
0
N
in N N ,a
.+ .+ ro .A 8 O > q ~ o 0 0 0
.+ , i U
H CJ
U
N p~ .irt0 co 0
~
i
~
~
p
x
m > .a u~ .] h \ ~ w I
.r 1
.10 ~ o o~ o~C
a aoi aoi
Cot Cot 014
o1
oi
5 ~ H W m rl M rl
M 4
rn'i O
o~ O rl ~ ,.a
>4 WD+D+I D+I O ~ aA oi oi .7I h o v~ a4 cn r ~ ri N c~
oi w
ron inf
oi o f Ln 01 in PI
oi m Oi o
q
a ~ I~INaI ~I e ~ ~ oa a~ a a A~ LO
ap~d a l
in
uw
in
in in in
o a3
0
0 oU
Nd J%d ca
0
UA
~
.7W N N N N
0
O Oa
~ F(d.' U0A 1x-
~
u
w
0 A. fI ~
H H 11
~AI \ \ \
0 0
\ \ \
O 3
\O
E
co
fI~ U E
L~ \ ~
H N
r1 r-i
0 0 0 .3
N O
0
0
> -e H H in cq
Ln cA vi W in W
U) ca
t> 1
0 0
0
a a~'' I o c aa ~z ~' z z ~z u ~ 0 y~
z
~ o ~
H al m w MW M~ mW Mw
uicn in to 0 0 (nw Mw a
~ aw
>~, u ~ ww NE NE ~ NE NE NE ~E ' W >+ ~ I I K
0
d rl o
r-4 O
HO
14 0
HO r1 o ri O
z
n II
a w
u
PS
r-I U
r-4 U
r-I U
r-I U
r-I U
HU
r-I U
0
aw
STL
Denver
28
p . 110
M 2: M E co w
w
H U A E~
STL
Denver
29
p . 111
LC/MS SEMIVOLATIL E INSTRUMENT RUN LO G
STL
Denver
30
p . 112
Sample List Repo rt
MassLynx 4 .0 SP4,525
Sample List : C :tMassLynx\PFOA .PRO1SampleDBlpf35k29(4).SPL Page 1 of 2 Last Modified : Wednesday, November 30, 2005 7 :39 :38 AM Mountain Standard Tim e
Printed : Wednesday, November 30, 2005 7 :47 :24 AM Mountain Standard Time Page Position (1, 1)
File Name Sample ID File Text Sample Type PFOA Ng/L or kg APFO NglL or kg Bottl e
1 pf35k2972 919 .59 .1 Blank Blank 0 0 1 :1,A
2 pf35k2973 919 .59 .2 0 .2 pg/L
Standard 0 .2 0 .208 1 :1,B
3 pf35k2974 919.59 .3 0.5 pg/L Standard 0 .5 0 .520 1 :1,C
4 pf35k2975 919 .59 .4 1 pg/L
Standard 1 1 .041 1 :1,D
5 pf35k2976 919 .59 .5 2 pg/L
Standard 2 2 .082 1 :1,E
6 pf35k2977 919 .59 .6 5 pg/L
Standard 5 5 .205 1 :1,F
7 pf35k2978 919 .59 .7 10 pg/L
Standard 10 10 .411 1 :2,A
8 pf35k2979 919 .59 .8 20 pg/L
Standard 20 20 .821 1 :2,B
9 pf35k2980 919 .59 .1 Blank Blank 0 0 1 :1,A
10 pf35k2981 919 .59 .9 2 pg/L ICV QC 2 2 .082 1 :2,C
11 pf35k2982 919 .59 .2 0.2 pg/L
QC 0 .2 0 .208 1 :1,B
12 pf35k2983 HQXPR1AA R5K250000-125 MB Blank 0 0 2 :1,A
13 pf35k2984 HQXPR1AC R5K250000-125 LCS QC 0 .2 0.208 2 :1,B
14 pf35k2985 HQXPR1AD R5K250000-125 LCS QC 0 .02 0.0208 2 :1,C
15 pf35k2986 HQW311AA D5K230384-1 Analyte 0 0 2 :1,D
16 pf35k2987 HQW321AA D5K230384-2 Analyte 0 0 2 :1,E
17 pf35k2988 HQW341AA D5K230384-3 Analyte 0 0 2 :1,F
18 pf35k2989 HQW351AA D5K230384-4 Analyte 0 0 2 :2,A
19 pf35k2990 919 .59 .1 Blank Blank 0 0 1 :1,A
20 pf35k2991 919 .59 .2 0.2 pg/L
Standard 0 .2 0.208 1 :1,B
21 pf35k2992 919 .59 .3 0.5 pg/L
Standard 0 .5 0.520 1 :1,C
22 pf35k2993 919 .59 .4 1 pg/L
Standard 1 1 .041 1 :1,D
23 pf35k2994 919 .59 .5 2 pg/L
Standard 2 2 .082 1 :1,E
24 pf35k2995 919 .59 .6 5 pg/L
Standard 5 5 .205 1 :1,F
25 pf35k2996 919 .59 .7 10 pg/L
Standard 10 10 .411 1 :2,A
26 pf35k2997 919 .59 .8 20 pg/L
Standard 20 20 .821 1 :2, B
STL
Denver
31
p . 113
Sample List Report
MassLynx 4 .0 SP4,52 5
Sample List : C :1MassLynxIPFOA .PRO1SampleDB\pf35k29(4) .SPL Last Modified : Wednesday, November 30, 2005 7 :39 :38 AM Mountain Standard Time
Page 2 of 2
Printed: Wednesday, November 30, 2005 7 :47 :24 AM Mountain Standard Time Page Position (2, 1)
Extract mL Sample mL or g Dilution Inject Volume MS Tune File Inlet File MS Fil e
1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5.000000 250 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 250 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 250 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 251 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 250 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 251 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 5 .000000 233 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20 .000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFOS 1 .000000 1 .000000 1 .000000 20.000000 PFOA PFOA2 PFO S
STL
Denver
32
p . 114
LC/MS SEMIVOLATILE STANDARD DATA
STL
Denver
33
p . 115
d
o
Uo
o
! ~
~
O ~
Q
N i O
I
O
O
-0 (p Z
~
QC
V
CO
O)
0
N U~
UC-))
fl- * ,~-
d CcOOvQa L Q ~ ~ rn v o
A.
o Io
o
X -X
Q C W
2
cf)
N
O C p~p C ~
~+
4~j 0o
~E C Q
$ S~nn CO~ ~
R ~1 >>
C
C 0 Z N C _
c6 11, - O U + N N N ~ ~
41 N
N
A ~ C O Gj O
OO
a
u
CS
+~
O
O
~2
O 0 (0 O 7
i ~ a U~ a U U U~ U
~
STL
Denver
34
S
u
f i
t
~
,
W
p . 116 0
0 N
e,,,
r
r
Q 0 r.
-o ca Z
Q c U)
~
C p
YN
C/) ~-
U-
co))cf
a
(O
iio~Q 'O N
a~
~r
, +L~pw( ~
W 0 C)(* CX
a a ~ O 2 c75 a. C c~ (6 , cm
ass E~ Ep
t & ` a EyajC~
e u s N O U a'~ N
Y u?. ~~i
u
C C
p .0 (Z O,U_ "m E
(n Q~
&o 3C UUU~ U
co co 4-
N 00 CD ~
N
U) C Q~?-
(D
m
N
C5
a
STL
Denver
35
g
p X
(I
p . 117 -
U
UO~
0
0
) co
O
O
co
O
~
M a
~ ~
o
0
il~ N
am)
` V N o~Q`
~
Q00~v_)
.~
~o ~
oo ja co o E
& ~ool aCj~ _~
i~wifC L
W
m
N U.
i iisz v~ w 3~ ua~
lili co ~ M~' ./
C NN
. O O y~ O
O O
O O O O
a)
O M
~ O
O
e- - O COCo
L
U
d co
w
~ O
O N
O
~
p ~
STL
Denver
36
p . 118 c 0 Uo o
~
W O
V ~
0
O r
N 0
z
t
~- (p C
LO d) (~
00 Q Y o~ ~
Z
+ XO i N 0 cm LO CD ~ .C-. ce)
(D
rL CD N CO O p O C)
LLct o CD Q i+^~
I
N Oa
a O~ x
~oo
2 C5 U.)
Wx
C
O
,"m
c
a
CY)
LQG .il .~y IIII O O CQ y, O
~ p PIY1
Y
p^
4nn 0 0
Ytl
U-
a-
~
LO C ; ,^ y
E,V L w ` T `
N
Cc; K
Z7i
O
C~ ~ O
ZO
O UCLN CD
n
co 60
C O
N
ii $g 7 OO- C
~~ ~~~
a .U
(L9
O
a
O
O
a
0 0 U0 U Q)
STL
Denver
37
p . 119
i ae
O
to
LL O O
W
N o ~' t
E
~
A F-
>
O
Z r. c6 Oo
Cl)
N N ~ N O
'tt T7 C N
N
N
UE,
C%j
o
=
v co
LL N~ Mp Q > .~ n a)
a)
Z 0 O ~ R
X It
~
o a)
o,
CV)
N
1~
N
N
N !0 Q~ M
O in u . Cr6-cco) ctoi r6~ m co md 00 ~ C N 'jQCc'S c~ a E
n.
> A
A
7= , cq
, ~
o
N X~ c~ X~ M tp
N O N O
O O
~
~ o
O N NM OE N ~nj Cl) vN N
CE /)
N
E
N
O O e-
r ~
n n ~
_
C)
to LO
O 0)
N
Nww .
(O (~ ~oo a
ry A m Qf a % N a
Y w rv
4 n C Y7 LL ~ ^ 0 N 2
PU- ~6 0 ~ (p ~
p~ N~ N Q
r(Di~a F.. .
9n MY/ n mt~i ~n n ~
>
O
^ O
O
A~ Co
0
QrIJIJIJlY C C C
'ga~ :
Zi ~ N
O C N f) ~.. O ~
. ..~" N x o a n 0 N o
04 It x O O N
~mC m r~ ) mm O
ri .3 .4
N ~ a
I & ~~~
~ o
w
G~ON
N
E 0
N
M
C14 N
E o co
'0
N
. a ;a
Mwmrno
o
gr
o..
~ 1 ~B i
3 I~ u ~p5 u~uY ~ c a da m r1 y o
an C~ Y Y
~~ae~-~M - IO N Cl) aw + m C! a
!p~~ o
%
s
~ 7Fn<aw
. rv .
g
ip.
z
STL Denver 38
p . 120
N
U*) Ln O 00 f0
O N LL h~ 4)
:10 ti Z
A
o
H
0
N X c+) N
N~
CP
O
O N
E `N M
of~N
NZ
a N, CV) %
i
a
N N'~'
Lico~0
N 0 Q
E
> nO
0r Z
O ~
AN
.-. c~
-v
N
O O
o
N
cn ~ ~
M
N C) pf to
N V
~CO! CL
LOn WN) ~ V- I- N~
Ca V N ~1! Q
% O
N M co
L UO - CO(~ O Qj E
. . m f'~ aD .~1
> A AM ~ $NrvOrv
0 r "R
C)
W ~ Moooo
z
N
O
N
O
o
N~'
M
N X X
N ON CO~ CO
O~ ~ CC~~
C E ~ ~ G~ ~
N 1'~i A A L~
~ 9am~na
M
M
OS o)
O J! ~ w
g
0 4 N M l[) lfl M "
)
rt y Q VI YL
/O ~
Yi
s
tn Lo 1f! N O N N~ I~iQ ~N ~M li^ aO Mi ~Q
o,
o, a .y .-1 .y bNCV
pg
mro~vo
o ry ry
v
r . A. vA
o
M
> h A A
0
oO 0 CO O NNrvrv
~ No C?o N o 0 o
M ~-
M
X~ C~ V
o
N
O
Q
N
NN
O P~N N
CO ) n N ~ N _ Q LO
N
aaa
a
a
E C)
i '~ ~u + aM ui s M f/) r. ~!! S E) ~
b
'' c S i a J N
2R ci O
O
m
w i ~ i1~ o0 o Z~
~7 ~ ~~r uf ~A
O~ c~j % U') .Ai ~~ l"~ Q
04 mrlZ .7h all Zf . tiQ CD
Y Y 1oo.9 o cLj M a ae a o` Q / .~N,w
s
STL
Denver
39
^ ~
O) C) LLoi
co
*1
N ; OV A ~
O
co
z
(3)
N N CN (R co
Q)
E
CO)
N
^ V/
M
C1 ~ N
p . 121
~ O O a
Ln me
cc
O LA ~ LJ ..~~
co
Q
;
n co
0
O
Z ^~
N X N
CF
C~ C
~ ~
M
N
;
O
u CD
~ Lq Y
~ , %
I - M cc
~ I,- CO N
LL LL c6 M ~
N~ N Q O M Q
A
A
Z N 00
co
o
~ tlm+ +r
N
E
~amo~m
~ _. . .ne
~ poo~o
(n) _ r' M
a
N
X~ N
X~ N
O Q
d a)
00 C-4
~O)~ N ~ O ?~
a
E
O O
M C)
rn
~G
01
N
O
=0 ~ N etmmm .
/~
O
O
PO
i
~/ M
% M % , M1
V~ CL CL
.
M o i1
N
-f~M N
N. M N
O IA LL ap !Q ~
LL O N 2)
u' M
E
N Q C07 ~ a F-
C
00 04
O cCoq cri ~ .
ha~~~
..~aaaaaau
0000
CV)
8 ~
N
%~(o 0. o o'
I{
O .in p
M~
O
'E :
N O N O ^.^.'^.^.
!1
O
~
N
C
N
N
00
~~~ ~~~
~
N N Hmmo~.o
o E Eo
u
i
u
n
a
~
~ppp" S~ Iryry a
JM T V,
~
'y
CD
Do 4 ~ O
~
N ~6~.Omp
y ~YU O (
Oh
LO
n
CV)
n
s
~~
~
C
~
..
~
STL
Denver
40
-
Ln C14 -rnco c
aOc~ ~ 0 1"
E
N
A Na
~
Q ti O e- CO
O
?
tcy N N )R ~
N M Cy
p . 122
t CW) f) a
N
~ a
'Rt Co ONIioi a)
M n cp6 Q
Z~ 1~ ap
N
X
Ea)
O M
N N
c~l)
.--- p
~
O
+ ~
m In Y
ce) r CY)
(-. M co
r I~ ~ f9 !v~ivroivv
O N LL . ap N~ ti aD rN d ~ Foooo
N~ (4 C.1
A
0
dO
Z
04
M 0 `" _ .n o m nnP +
n oooo
O 00 O ~ .y .. o{ ..
O N C7 ~-. r-
N
X ~ M
C) N Co ~~
N C C
N
~ A N A A A
MAAAA
LC)
Ul)
v
~
~
s
Z
tq Y
Y
LO LO U)
j
~O r o M,,o ~o ~
mm .7"
. ~ ro
~ ro~~ a Q
in 04 r r- M M
O N IL ap ~N
lL ap tN ~
m 3 O Q cD e~ N~ N ? ^ I-Q
~
p
, HN YY1
n
m O~ o
O
nin
O
n Z
~ a~a ti i ~
^ ~ oa~aa
co O cqr N O 0
N M~.~
v c~ c
p ~ 1 1 S 1
m .. .. .+ .+
M
,
I M
1 'oio o
sa
i N O N O e .e v
O
p
CO co
,
~~~
r
nnNN
N
~
N
P
co U') o ~~~
MP PP P
P
P
P
p
~
V-
I o usu :
#
Y
g
I
i
~
~
o
u
~+
i Q ..~i o i Pt~ a
N
d i u .~ w 1 Jt ~ Q) Q)
m
C14 M~ ~w$ g i
` ew n ~ t Ln
Y
Lf) .y ~ ~! ~ R g y i O a Q~ ~ l!7 p l[~ Va - Cn V) s ~O
o .ro ~ p r ow s . i oi,
~o .,rvn .
a
~
41 STL Denver
, N
a
~
r
O
Mm
LL Q) 2
Go
:$ <
~
O LO n
I Z T- c o - a
N NNt~ .
E
M oN
(En co Lq F-
L0n) C,4 -0 0 S M :N CD a
LO M oo v UW- ci
M
a) r-
0~
4 Irl
N X~
N C 0cC?too0
CE
p
Q FE '> o
f")
p . 123
0 LO
ow Sr CV) % O u
CM 0) a
r
~
s O. nN
{ O-0 LL pp LL d ~ BaP~o
N~ N M Q Cn 0) - Q
> 1A AN
A
Z r co O N O
PO~ O
o .'NON
04 x~
x
Cl p)N $
N p N
O
N gp A 2 2 ~M N~O~i~
M
E E G C
~/~
O
O
N O =oom r
omo,n /~
~ y a+ o . r
(0
r co
VI eeV
=~
0
Y c) e)
~
% C L V,) % , . N M
~ !
w .r .. . . . f~ K P P P~D
{ x w , ev N~ O a
~
tid fp
? ~ { O -e LL O 0.- ~ LL co N `)
I1 ii N T- rMQ McQ o H E
N
~N~! N n wAn
~ aaaa
{ f0n /N N
O
WN O O c W O o Q S?
p dddd 3 ~1~
~cC o z CV N OiNNNN
bn'co :
.~.
r
Ce) .1 r-
M
~ ~ o V 3~3~ :
'o%o o
N X X
N ON
~NP P
M
~
04 M co
~O N EN co O p PP N
MaaPP
"~
I iisus
to
CO
P ` ~ ~ T f C
~N
N
cm $ g
Y Y oo
C.+~ o B~ 6~ ~{ Q~
Ln
C7 ln ~ mamo .
i .
a ~' a S~ ~ ~O 4M,, IO
s,~~..n v
!O ~M iA as~~ 0
d i~F N C1 a Q ~
~
STL
Denver
42
e a r MI m
'
NOA _a Z o0 ~
00 ^ ~
N XMO~ N cp
~ o
M
p . 124
Q1
~~1
O
y~
~f~7
%
~ N O~ a
I~ co
O r LL Qj N`)
C#) CO "t
N o "~ o a > A c
2O~ co
N x
N<1
N ~
`
~ CD
Tr
T
E o
M
N
o
N
CD
C*4
n Z CV)
Ln C) CL
ti Tticr) m CD U- c6 Q) Q
tLiL 0v 6 G C J2 o 0
e o v r
N M N l() Qco Q E
P P ~ P
}-
. .. m~n r v
r v o m
> A LO
A
0 CO O 00 0 ~monm
ZNO N
fM Cl) ~
N [V d' C14 q
* N p N p
s
CO N ~00 N
r^
^
O r~O Q
~
T
~
O~Pwf P
1~ ~m0em
T
.a
p
I,
Ap i
J N Al.
~! ~/~ ~ P
Lf! Q) Q
o.
s
aLL-10~6
C7 N
(D Q)
LL
I,- d' CO
c6 C}~ '2
N O N Ln Q M QO Q ~
er. m. m. .m. ~a
P
P~
F
w
SY1 L Y1
N
mf1 ~1'1 rI
g. .
X x
{III >
O
Z
~A.~
^
w
~ 0 00
CV tV ~T Cri XIt c~ v
p bbb b O ~S 11 1
ri
N OO N QO u- 1u
G ~ P P
OPO
O
~
~
N
i > a
~CO Lo
D C N ~ O~) N ~
N
u
C/) p cn
s
U
t
t
r
T
r
p~
g
..
r/ .i
O to ~ o ti w N ^ w ~
m0 ~ ~ ~ w
JinC o ~
., w .w w n a _~
~ N
~
) R V C
O
6
m
M~ ~ g ~~ 3 ~ u~ os Ch cn ln o T LA o O zasa a
u
a~
;A oA A a .7. ~ ~O
HM M k
In CD fl- n
~O
s
..r~n ~
a N
..
STL
Denver
43
p . 125
p
W
a O d' LL
r 0) 1- co Qj M~
N ~ ~ N Q
H
> O0 c9
0
CV
o' N
) N " N
{
E
00
J ~ 0)
Im LA y
{
a
o Z~ Or
lCfV))
0 /0
rO a
J ~f~d ~C { LL a) N
o
CD
A co a Z
N x N
co(p co
(En
co
N
O ~
O Ln
S
N
Y Lo
I
O
aoCDeo~ - -w %
V) to't LL C6 Q
N7
4) a)
G .nvn
U- CO CD
. ..~
CD
~
CV) ~ mmm~
> A A 0)
~ .rin~ .aa
Z N Q N O o
(W1 ~ M
N X
X
N
O
N
O
O
p
OD cli $ N
E
co
J ~ ~
cmO in Y
tn
(h
ry~ CD d
cor*-
LO ,GN K~ am aa m m ~
M %
. . . ..rv
d.
s
LL c6 4) 2
lL I T C
a $ ~ ~ Q Q
G
qp ~ N
2Y1 MN Yf
aln ;v n
O
N ~ CV) p) ~ F~aa J
>
A
A
q
0 r 00 0 co
Obb b
O p1nY~
Z (V
O nj cn M
a n n CY) X It X V
N N O ~`~`r r
$ Qa
CD
E '"~
N -O0D) N
O E -~
O Ja N N
N
Haaaa
O
C)
? ~ a ..i '` it ~ ~ q
r
00
/T
co
/T
fp ~.
q
M
= a % j . .n~ . i .~ , ~ i{ o
Y1
3
v,
v,
`'
N
N
O~ Y Y ~~~`d o
-- . LA LO O nsw a
,.
STL
Denver
44
p . 126
3
qi u ai
O 'qatln Q
N
A O~ O
O
? 00O M
N X M LO N(D C N
O
0
N
E
00
J CR
Y
oe- LCOl) ;-c4 C! a
M ! - 'cr c0
OCDT- LL Oj a~o 2
0 O /0
E
{ >N , n `) ao ~
zO r- CO)
~, N N X ~ N 00
O Q
E~~
Cc
CD
N
o0
. LO 0
..
/0
M
N M ~-
I -- d' N P, LO (C
C e- LL ap 4)
LL ap
NN Q
o Q
O R
3!
v,n u, m~o
> A N
N 00 Z
n
VC ) n O j' O ONN "
N
X~
X~
r
N o O
N O O
0) M 04 0) . . p~ O) ~ ~ N OE ~~
'^ Q'^ Q i~i
N 0 ~" .M .
v v o .~a
0)
f T
Y
a
in N~ /~
r-rrl
LO
O
C V - .. ~ G~F
nNV~ a
VY ~/1' ../ M a
O O s
oHtnnmi
aN~
N
X LO M co N. LO fC
O e~ LL ap N'm
L L Q
a 3 ~ON N NaO C~ ,,co) iQ 2 E ~J
~
A 04
> O oc o 0 o a" o z~ 0 }i
N/N N ~~
Q
O
~000 0
~mo~au~
n z N N mNNNN
mV
. ~ - Cf)
M
, IT
~~o~ 04
o~ . 0
mmm m
T i .l T,0.1 O
a
~
C Q C Q N N Y1 N
. ..~ M ~N-0) ' ~ - M N O M mNm
y
AA
w A as
~.3. Y ~ wo
E
U)
N
E
N
Q
~
J co ~
f~
C
N
1 1 f) Y
N O-~ Y a - m o r~ .o
~
m
A~ n % Q
.
W
m N v'
h
6
$
F
~+
~
STL
Denver
45
p . 127
r
- E r
~v
O
~
~ . ..
A
,
cp
N ~
z
co
r)
N
`~
N N O
~ O O
N
O
CO
E
O
T- CO
{ Y~N Lq O LO
a
ID
/O
co CD
LL
N~ cD ~ Q n
O 1- o
E 0
z N x
N 00 co
O N
N
CO N CD N
CY
0
c~i %
M_
_
N O~ LL ap N~
V.-
N N Q
_
LL
C
o
r-
:
0
0
C
o
0)
u
T co C - 7 Q ~o~ry
>
Ar'.n`
A ~ ~(OON
0
W O ~ O O p p~
?,~ c~)
~ N N d y
N N
C co
ON Q C
C'4 0) N
v
o
wa N ~a
E
E
U)
{
r OQ)
co 0)
Y~
y C6 . Y
0
LO cr)
q n m CD
KPPa~D
to ., .
1! % co
c~, -.
..
,,aM
s
~n~n n
In CM T-- r~r- w -t- M Co W
O It lLON ( .D
u"0O 0 2
N E
> N M~Q ~
F-
N
A
A
m
n~
N
~
N
R
O~
Z
~
O
~
O
fl
O
tl!
tl
N
N
O M
o,ommmm
ty~ X V
0.co N O N
~
0
~
C
~
111Y1N
P P P P 1fl
{ ~~ N O N
N
PPPP
g l i i>
8 $$
o usua
{
s~
N
$
v
EN
(n = oO
co c o ~ P ~
~
E~N
~
H a`~.caa
O~ O
o
$
ti
.. .w
.~
~Y~YU
~~ ~5~3 k
CO) n = ~ ~ Y r ~ ,-j O M
~ ~O ~ O w W n VI ~ % N a ~ % s w
6 r 0 srr
i .rNrn ~
~,
~
STL
Denver
46
~
(D m m
OoLL Q 0) CD
N~N Z
A > cp co
CO
p co
N xM 0 0
N CO
O Cl1
E V ~
J ~ Y
!
M
a N O w '
C) .- r.- -t to O O LL Qj 4) 2 O co NN 17
co >0 co~
Z
qlt
oo
Q
E
O CO
N
a?
Cf)
o
N O
p . 128
~ ` YI Y
uo p Zr M /O
O
; NC~ a
- t-- cr) cC
t~ t0
O O U- C6 Q) 2 ULO I~1
O r
N N
N ~ P
N Q c~
WMCP O
~ oor o
H e~i
> NA N V~ 0 'r, co Z N
N X It
g W A r V~ ~ o o . ~N
N CM M
N N
00 O 00
M
d M p a? fc~r)
E O E NO
(~
CV ~.
.2 2 2
{NN~ ~
c o_W ~W
. !
O N N 0 ~ V! LO o M LO
M. o r~o
.~~
~
w
P
w
V
V) IO . N
p N C~ a a
s
P
N
O O LL C6 4) N LL ap 4) ~
N r NNQ MOOO. Q
N
~
.~aaa
mo~o o ( inin
4na~
.r
0 > pp ~ O N C '' Da Oa eo }ao ~i
n r
Z CV ~ N O mNNrvN
~ ~ ~e-.F
C7 r
M
! ~(PA~'1 YI
O M C N
.
\\
X V Jl ~
a o oar ro CV O N O w o t :'1
O
N UI Y1 JI
C OO pp N C CO co CO NwPw P
M
N
O ~ N
O
wPPP ~ o
i c u :u z
;
O
~ gM ~ JL~ 1 N~ M N 1f~
oy
V~ CY) oT o~
~ ~~^ ; _ , Y
M
1
co
rrrrrrTj
r-
N
~
9
u ~Q O
rY
cy;Lo cn LO I w~ 6~ A~ i N O VI ~
r
~~
4
y
y
I Yp R ~Q M Y p~
~
a . V Z ~ M O tiIO N
I r O r~ . Y . O
aa ms~sti a
M ~ r
:~ :
V~
c N Cl- ~
C a"
.
s
O n IO O
~ ~ ~{
STL
Denver
47
p . 129
~ !
a
ao 0) 00
OM LL 6 o ~
6
N
~!N n
> cp
ca
a)
Z
1
C)
~
....
!
N
CV N
O N
U)
N
J N co
O
C?
!
!
! y
!`
z~ C~
N :OQ~ a
%
C)
C C O ML Qj~N
N O m !' Q N n o6
000
Z
-
E
CO 0 r)
N X
N
N
M
E
0
N
CV N co
ZN Y Nr
~
%
) C
Lf) 00 r- 1~ Nm r f~ c7 M
O M LL ap 't- 2 LL ap Na) O~ r M Q CD ~
Q N M > A ^ 04
O
Z
N
CR
C~j N~t
0 co
~N - V.-
04 '9t
OO
C'7
~ ~
o m a
O O O ~ N JC NNON 000~
t
N
co
~
v
E ! J N C/)
04 CC)
N
M N
~
OE ~ U)
s C?
co N
a Aa
AA AaA
O ~van 'ir~Na
~
N
in ~ N
Z ~Y
N ~ 'Y
CD N
% r
p
C o. a s m
~cmmm E . ..v .y o aao e
%
.. .. ..N
U) 00
CO
O e~f ~i .~N
LL ~ ~ ~
I po OiN A N Q N~P CN ') ia
~
e
~
~ aik1~~N N
>
wAn
0~
0
o ~ N P PP P
Y
O
gYYY
c
Z N
04 0 N moooo cr)
C~
C~
N O N QO NNrvrv
i ~n ~n a+ ~ ~ w wD
~ s$
~
S v~ ~ r
c N 0,
E
co ~ N
r
Hamm m
O
! I~~~ ;gw !~~r ! ;`n " N co r N cno r
N
3'O 04 co ~ o~o
.o
.
! a~ ~Z~~~n; k! ~~ a 0 N n % a0 !
~q
r
S
~
STL
Denver
48
p . 130
4 '
0
t1~ O T o ~t
y
N LL. p
r'
O
A
Lo
N
CD
O
O
N M O CY)
N
N~ rn
nj
N
O
E N N co-
i
CA M C tq !~
m CD m O Tnl-- er c0
O N LL aj 4,)
O< C., 40 MAV7
O
%
O op
z
N
~
N
r
-0) ~
ET N
O rO
Y CS O Y
~ r vM.
%
I-
~
E
O
cY)
N
T
u
TI~GO ~9 TI~M M O cV LL pp o~ tL ~ 0 L a~) N o N N a M TNQ
A
00) coj
7r
C
^T
A
T
qO Co N
M ^T
a O C7
N x~ N
OO
N
OO
.. oo q
o o
oo
e
r
co
E
N~ Nrn O CEo
N
I~RA~
~ O O
T OO
T
~
z ~ C YLoh % Y N ~~ ~ %o coom crcr w..
a r m ` ~e0CD-rMa a
s
ON tTi~o ~ u~ aMi Co (D
R a
N ~ NocTva E
8 4
mOn~n
A
T
A
r O O
co
YJCt Y O ~G C
N `~ a .o0~ai
"+
z ~
N ~ N ~ mmmmm
T M^T
M
C~
It
!~o~ N io O N o
~
~
~ ~p : o O L~
p 2
2
v
T
N
O N 2rO~j
N
O v N ~ G O M w q C q w
F
O
ui s UG ) C o~
.+
e~
, ~s
O V w r~
C0)) m!~
s M M ~I ~ y~ ~
T ,~ Sr
T
~
g
m
wi ! ~ O Qm ~~~ Ln
I 3~ ~~33 d ~~ : m O
% Lo 'o
n N a
~ o ~
00
Xy~yy
~.
STL
Denver
49
p . 131
0) 04 m LLi (LU
.O A ~ tp
O 00
? O N4
N N X 0ON OND
E
a) E f
r)
N o
_,! N rn
Y o 0)
Ncf) O Q~ a
l(')
NI- oI-~ - coM~
co
Q ~~
>
AO
0 ~ co
N N O
.~
E
0 Cf)
~
O
N
f
cm
c Ci N
N
~ooon a.
%
t~- M CC
Y N .-1 OD P
O LLcp~ 2 LL CpM ~ ~ B .~o P
P P ~P
N ~ N > A
a CO < A (~j
F-
. . ~mu
u~o
ao
amPmO
n
0 C Z N
r
0 co
Jt .~ti ON O O O O M O
N r)
N N d N~ z
x OO N
$
,
C 0)
E
O
cn
C o~~~N~N
coc
i.~na a
CD E p mm , N
rvnom
JN~ O)
S ~ a {
GN~O
~ tf) c~ c) V rCO~ a
N
.
LO M mmmm P P O. b
%
. . .;N
C.
s
^ cr) co O~ LL c6 c O LL ~ N C~~i ~
N M
MNQ~N Q
~m~uu~ m
m P
t > A A aa O a Daya aa
0 0 0 co
e N N NN
n
Z
N
N
co
oa/ o
N X~ C~ ~t
a ~ oio
N o ~ ~i C NP O O CC V O n fP
o $
~l 2 .1
$
~(O
E
N ~ ~N
It
N
O
r~
O
E
: .P,
MPPP P
~ V i U~
i
(n
(n
0
00~
as ` N //~~ O
O
~
m
m~ M M ~ N ~ ~,
N
.pw~ Q~~~g n
V~ .7iJry
N r~ ,
o VI
to
M Q.
ce)
U' )
% M % M
0.
s
!N !!! !
STL
Denver
50
p . 132
-0 W r-0) co co
o a) CD
W
IT, Np U- ~
E
A r. > O
~ o
`V)
N
N~ N~
C-
O N
E
O
U)
C
l (n
%
a
E LM tO O T- LL 0 co M
N O M Q ~
> ^
O oo
z
d
O
~ ~ N X
co
N
O
00 M N
~ dE
MN
o
0)
u
Cy ~Y
~ t[f r Lo
% O
C O) a
p n u v n
1-- co tC r 1- CO CC
O
V-
LL
00 LO
cfl
~
IL
p
(2
(,D
E
o+nm om
NQ M c D ~ ~ Q
> A A Q1
"'LO N 0 N O o0000
M~ r' Cn N N~ 04 '
O N VNXO ~ co N co
f~ So~ 0)
E 0E
N Q rn~o n
P ~ n r
CV N
= M 0) ooi
Co N
N
p
Z
Y
Y
a 1A % O , CV)
x P N 0~ a a
Cmmm v
P P P O
s
o a
n Y Y1 Yf
5O O O
1 m lV 0$~
96
to L
OoT: ii ~ c~OC (0 LL N. 0 ~ 4)
~p ~ U') Q cp CO Q E
N NI~
~
ha`aa
'
A~
/\
O
AQ M
Q O
O o1 3 1
Qm
/ 0 OD f1 P~ ~ MI C N Y1 Y1 U l
A~ Z (y (~ O moooo
N C" X X
a ~ ra ae r
i~~~n
ro t/N o O o N O O O 7~
~ ~iv+ ~
cC CO N I .- N P
^
C~~
MPPP P
P Ti ~ S~ G E Q~
O
E
s m a
N
c1 rn
rn
~
m~
4 U . N
4
N
`
i~~ ~~~ oao o S V U5 U')
: o~ n /o a io
S 6 0 7~ lh a ~~ :
"~
N . .ro~ .
P e,
O
~e
~
w co C
STL
Denver
51
n
M co M
~ ~
~
N~u-a~iM ~
0~
AN cp
Z V-
04 N x
NfC nj M
Vi N
E
p
p . 133
~ ~ ~
_j
C))
N
%
N
>
~~ti~ CO
ca (Do i') N
A co
0 r co
?
a ~-E
0
N
N
o
2C 00 8
N
(n r
M
N
cn
Z
% O u
!
r
r O~ Z
f - Cn m
U- c
4)
N
co O Q
c! LL
A~
A~ O o
CO 0
O O 0 JyC
CV
N_
n~n m
.+~aorv o m
o .-i o 0
4 N X'~ M X'1
M 0
CV O N O O O
co CY) CD ti N~ Qj OD
N saa$n
~ E OO UE ~ )CYVI)
~ O) Q)
O O(~
O
O
iao.~o~
0
U.)
Y kmmm~
Lo e Lt 0 ~
0 ~ . CV) CY) %
.. .. ^i r.
r' CA Q Q
~
?^ r~O ~ LL. L N L~
a g p
0 l o ooi n ig n
~rS :
~
, r N N MQ N M~a
Z O O
O O r O
O 0 RN
N
N M - f'7
a ao aaa
.~ . .
! 2n~n
:
N
X
X~
ai~an n N O N O eve~
oiYo o 0 O Nomm
otlo
o
~+~ ~
; : rn^ rn ~An 04 co n
b
5 O~
p
E OE O S 7l m
I ~~ \I ~~
1i T P O. O
u ~F t~ n f!~ ~(/~
O
M
)(Y
Y w .1 X~ a~
~
! ~ N N ~ 0 ~ ~ ~
a J ly CV
M
eoo
Sa m, 3~M~u J~ Ao,
:F
V. a CD
a
,%
~
n
..
STL
Denver
52
Lo C14 - 0) co m
0 V- LL oi^ 2?
N 6 A r~ a
E
O T- 0 0 ?
o
NCD
O O 04
E
C/)
ww Z!~ V) NM a
0 T- LVL- oNi cv No~
>~ ~ A cc)
,Na
~
~
0 D o
?
c,i
N
N O
N co 0) U-)
E''
0
O
N
Y
U.)
0
O
CV)
~0
N Q~
V- L L 6 N
O
c^h` t^0`
~
NQ! NNa
06 r1,- I ~
11
~rn
cA9`
`
a
C
E
P P O
~mn
>
AN A
O ~mPno
z 0 N 00 O ON co O o, .on
N `~ "IT
(rJ
`~.-. I
t
-
(~)
as
N O N O
(M CO
(~ C pp Co
04
E o E r' N 0 =~~ . ~ ~ ~ 4? N.
, /~~/~ N ~!I
Y1
P
VJ
O,
vI r
~
0 r
Lm
0) C)
to N 7,73 Y IIIII
o~tmmmm
w CM aj Ln N l1) e- P P P e
m Z V.- V % CY) %
.. .y .. r
x a ! N0 a a
s
Ln CM o T- ti~ a ^ ~oa~i~
o NC; NNa
~
A N
o~o >
O~v n Q V-
Co
CO i oto ~ a~i Mrna E
A 0 co
O
~ ~(
f
Zi N O N N Xq, ~ X~
~ M
.+,~~~ yiii
me.o.Hr
E 6n e~v
w nrn
v r
N
O
N
O
^'^'^^
o n l~o en
n o A~ O O ~r~~ . . . v, CO N co ~ N P P P P
M Q'
c) ^ Lf,
NPPPP
E o E N
o
Lo o> q
u3us
s f/)
.
~
9 f/) ~
~
N
N
l A 3 a9u~ m
Lc) N U ) a % a ~n wA a e. N M
.o
.r .
STL
Denver
p . 134 53
p . 135
~.
c~ 0) It c9 d O M LL Qj f~
N N M rn- V7
Z V"Cf(q 00 ~
Qy
O ~
N N (D rn N
o
i
N
{
E
O
{ J M r0 n )
0 ~ Ln !~
SO M %
r W lO ) C.
~ O
Q1 e- f~ et l9
ODMllajc~~ NM ~M Q
E
{
0 ~ Ro 0
z
O
~ ~ C'f)
N
04 ~
Xcv
o
CFco~ ~i
a? c E o
o,
LO ~ ~ CD rn
d MZ O O
an Q1 a
Oor~u.~~~ u-~~~ E aa~a M r- ti (h co ~~(9 0 o v n
NN
'
CN LnQ .A /\ Y'
cf) oC) Q
A
It
p .TN O YmON ~lOO .rY
Z C O r opN O O C co j O o .o~
N
.-.~ C~ - T-
X
N
O
X N
co O~i c~p N
n
{ ~ ~ O ~
~
M
wp
N
`~LAA
Y
w
_j Q) _ to
~
n Ln M
~
0) 0)
N
Y ~ L 1 o
~I O/~
LO
r M
a
~
O~
s
. ..
~rnaav
o~ O M e~~ry M
LL pp N N LL ap 1 `7 a)
NeMi N
6
CN iao 1-
I
c[! 'a' ~~ .a .a
0 Z
CO N
O
00 O az N ri ch
~o%o
N X~
o~
N
O
X N
O
P~~P
J
M O~ wy O
g ~ ZZZI U 72 ZY
..
O ~~~
E O~~~ N- p~j. In
CO
N
MTPaC
~
~
O~~
O
~
w
LO
O
n
mM MM w ~~
J ) N Q Q N) ~ m ^
1q Y
~o
p ~ ! ~~ y{ ay' ~ LO u
~
~-
LO
~
W g r ~ O M ~ a ~ Q. ~4 m .7 S 3h a ZF + ~ ~
/O Q
sO ~ .n n
O
..
a ~
STL
Denver
54
CO rrn q, m
oOO I~ ' Q)
NN A NQ F-
~
N
cD
Z ~ ~ O
O
N
U*) co
c%4 co C14
O
o, )
N
N
~ (p
rn
0 LO O aQ ~- w
~
O
v o o - ~ ~i ~
N N co > A co
% ca O
Q
F-
0 00
z
~ ~..~
-
N X~
Q
Ch
N 00 o
N
Q? O
p . 136
A, CD 0)
~ a I- NL[)
Q
Io
O
u
-000 co
0 O 0 LL apO G) 2
ti (q YmmPrP~ P n.
cLlL!h CO~ a)E~wmm o
N N n~ Q ^~ Q
~
p
m
Q CO
0 co
z nj O N O O
P O KPr nr~n P^~ P'
N !
Cr)
t X I
N
ON
O 9 CF 0)
V) s
U')
NN N
! c ~ ~ C r- M ~ ooo~o
( E n tn 0 G ~ ~ ~~.. . . ... r^
A
M N
gnnn mn a
m
~ 0)
0)
!
tMin
Y Y ~aam ~o
LO
Lf) m
Qo O P P P . rvI
toe-rO -O O va
s
ry~' C~ a
w~
nl
LO 00 ~
Co o LL ~p
^
~
,V
LL Co ~ a)
Oeo Q ~Q ~
N >
A
A
0) ~~r ~
s so 0 r 00
O co 0 ii
? N,- M~ C')
.. . . .
~w' n n
~ .:~^
N X X N O CV
O
rrr r
g
a ~~
U
;
P i U
N 2
E ~~-
O E
h co t ! m ~ O N
~ N
N
' ~ Oo
O
NPPPP
~
~L
~
M
M
~
1
04
y~
`+
~~ ~5~~~ k ~~
o =L
in
O
U)
ce)
o/O w
: e- C~ a a
O
~y~a
O s /C .arvr, .
~
6
S
~
ai
STL Denver 55
p . 137
O
O
* M M
T
V
L1. ~
4) 2
a
NM /~ > p~ cc
Z 'T- pcoj
E
~
N (~j (~OM C N cn
O CV
cE o O
-~ CCDR CD N ~M Y o ~. LO
CV)
O /0
:NQ) a
in in ~ I~- " f f0 (4)
(D
p M~O )
E
>M Cn~Q ~
v-
Zo
c+i
N Nv
0) " Q? Q~
C14
CO ti
t
.. gn Y eaa
W Lo
o o U
G
O
/0
,, N O! a
In Ln
t0
O M LL op 0
- 1-4 Lo LL. Co
N
o m a a
E 000 O
C5 N Q Q
>/w A N
A
b ~ooo~m
YNN~O N
a co Z Vr N O nj O oNN
~ e- Cl) .-.
CO
N XV
N OO N OO
C~cD CV co
0) ~ N ~
E ~ N O E a- N O aao .~o
J
T
QV
O. C
O N V O f~
_j 0)
C 0 N Y N .
~
O ,^
o a a r N Q~ a /
.
O
FNAND
., N O. N N V
M W) W) V? a OMI L.Q~6' m L~i~ ~N
1N cV ` 'Na
m N~ N N
> 0 ~
co
g rm g . Lm ~`
N XV
"'~ a
.0 co
O ^ ; O
~
N
N
1i i NN
X "t
40~0
0~
N
O ONO O Q i T mm O~mO m ~
$
u us
if
tE N
N C O
0)
-0)
f~ N
N
amm m IQi a e.
o,
a
~
CO Q)
O)
~
m
~ Q1 N N '
..
j
On .~.M LO
O LO
O Ia 4t0tn
S n 4 h m
Q % Q .
. .. N n .
N CD
STL
Denver
56
..
U
a ~
~d X
!
E
p . 13 8
CO Uo
c
o
04
~
~
,^
Wr
O
N 9
O
t !
~
C O
Z
L Q C
.+
~
V
J
(
0
Q
Q)
0
CV
Lo m m
C/) cm
C
" ( m U")
LL ~ Lo
fl O N
L Q M o
Zoo ! X+ - X gry~
ao~ Q0 00
LL
u af~oo a E
Q
`
~
x
W
cv
0 co E
a '$$
cc o O O
O
4(
.~
7
Q Co
J
00
co
N
N04
N
'o
O
O~
VO)
u~ o U_ (0o
"~ ~tn sl E~ a UO )
93
0000 D
8a ~S4 UUU ~ U
M
O~+' 0
NCL
C~`
N
O
.
u
m
C
,,
~
STL
Denver
57
p . 13 9
O
U x
O
N
O
00
O
CD
~
~ca oz
06
~
Q c U) w
0 N U~
u) 7
~co
c
"'
0 ~-'
LL-ao 00
00N
,Q. :
3.
a sa~~ C4)
~
co
t
o
X
C
W
X
O .Y L^L
Or~
L< L C - C
! Y /00
` nl O
O
O~~/J
C
N
^, W
E~
C~
w
u~ w w
C 0 N
4 CD c0
N O O CD d
N O N N r- ~ U e- r ~ - - 'J
0 Nc-
O
o~
U
l9
C0 .~'
Q) C
0a
N s
o ai
u"!oY UUUCoQ .'U:1
~
STL
Denver
58
p . 14 0
65
zanuaQ
ZZS
ILll19i , ypM
n~ m ;p 0 erC .n o
CD
ssn i
W W W W W W W W A ~
;o 0 r n C-0
O
T(D
~O
So% o
m N 71 3 ! w$w t'
CD ~
--0n
O
D "
J 77~11 x J
1JJ y
~
CD
W N 11 ~ ~
CD C/) N Itl w Q g
N
j
N U ~ CD
r. n CA) ? O
O
N
a ~l
W
O 411
O O
Q) O
O co O
~
1 ~I
J
03
0
0
w
09
zanuaQ
p . 14 1 Zsg
CD
(~)
0m
CD
c~ o~i o o e~ P 6
;2 CD 3
R MV
(D p N n p aXr e
N= ~ C
w.
CD `V
:~ 3 An a
!!
N
W
co
O
~ C~? b~n o
M
a05~ W~~ ~~C A
a~ C 3 'fooeo.~ 8~
cD 3
'}~ V J J yp
0 cl) O
T ~/ ~
J .~1 y
arn -' .
O
R
V/ ~uN ~%
O
3'\
~
O
U
UM
m ;o
~ A
x -, .ca .. m c G' x co o
Q-` .N .P 0-
>+ O T
:A
fD
O
CD
(D O s W
?~V W CJt
O
p
O
X
n
0 W (Np J
+
cn o
y
co
1w `-
cW0
z~ 0
7
CD
~
O
J
J ~ O
cm
O
~ O
N O
O n
0
:3
i
0
p . 142
LC/MS SEMIVOLATILE SAMPLE DATA
STL
Denver
61
p . 143
999999999099990999999C999 9 O PPO~ T PPO.P PPPPO.PPPPPP O.PO~PPPP .-1 N N N N N N N N N N N N N N N N N N N N N N N N n N .1 x Y Y x X x X x X Y X Y Y X x X X Y x X x X Y X X X V J1 1!1 ~l1 Yf N N N Y1 VI N Yl if1 U1 N 1fl N Yl lfl 1!I N Yf Y1 Y1 i(1 ~R Vl
,~nnnnnnnnnnnnnnnnnn n q tl i0 q tl q q q q q tl q tl q q q q q q q q q q tl tl tl
uoaaoaaaaaaoaaaaaaaaaaaaaag
p00000000000000000000000000 O o 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 . .400000000000000000000000000
dooooo00000000000000ooo000 0 0 000000000000000000000000
0 .~ .~ .a
..
.~ .y .~ .~
.~ .r .yooo .yo .~n .y rvrvnvi~nin n
.~
.a~ .a .y .i .~
rv N N n
,
~ ~ooooo0000000000000~0~0000 0
o O o 0 0 0 0 o O o 0 0 o O o O o 0 o p O o O o 0 0
~ u rl .-1 e1 rl .y r1 ~1 rV .-1 r1 rl YI .(1 N YI YI N Yl rl r1 rl " .1 .-1 ei .1
qM
, ,
b
nm ."b .m 00 "ul On .NO~O~ .
.
O. N.
.n .
n ..
. .
mn ..
nm ..
N~On
OOmm
n . n V~O"O 00 '1'1
.O~O .bP ."V
-
n
~ Nm V ~nmm . NO .Cm~C .~/f . .~"O . .y .n .NN :~ O U 1 m r n P O~ O O O N O O O O V I O V n n O . P m
rvnN .+rm .+ .+ooon .+oooomm~omom m .I~ON .OO~m .-IOOmNON000000"nPmmPn
I
Q11000-~00 .-I0 00 000000000 .-1 .0 .0
N
N
~+Nnn .rNY1P .0 .InONVm .Omm~~OPnnP~00 oan V~On .ONOrinn N .1n n .n~ .n~r ."V~bnnOOn ' {f000 .VNN~ryON00~'10000000 .-INN~yr
,
~O~n
nnnnnnnnnnnnnnnnnnnnnnnnnn
M
~O .-I .Im m~~On O V PO~n .~Ui .10mrl .y'GO .n00. Y1 V U1n YfNm r1~OnU1mN .~n m .1 nnOnbY1P~0 V V nnn . .OPO r . nor POUVOOm r . .Nit10C~ N .-1"rVr1 .yO .lrv""PPmPmPON .-0""""V"O i " " .1 r1 rl .-1 .1 '1 .-1 rl rl ' 1 .~ .1 '1 .-1 .-1 .-1 "
m M
ObNb .
.nT 1l~T
.H ~fl NO n O~nNPn n~10 .00 V O
e1 .C0"1f1 nn .0 P~00~ r
. V m 1fl" .`Gm
rm .Pm POYI . O nN ~OOnO~fl .O~n O
n m P m m m m m m m O O~ m m m ~ P P m m m m P
qunN .oa~N .-~Nn .aui .~nv .+inn~omnmm~o m
Y1Pr nON .r .-V . V mmri0~l1 Y1 .P NTO~YIPPP MN .n Y1mm V .N .O ."mnn"" . .~ .`D~n rN~O 4 "NNn V N yy nb~,ry
q
ry
h .+OmmmmmOOmmn . . .-V .-VYI .I .dmmmmm00
, J( q Yi00PPPPPOOP TO~P m OOOOO~O~PO~mOO
~ N N .1 .~ " '~ .V n n .'~ '~ N ~I .1 ei N N N N .-~ .~ .V 1 " n N
, p O O O O O O O O O O N O O O O O O O N1100000 ON NO NY100000
r1 ~ Y
uQ 00 n1N Ifl~~ NO 00 00~1NP ~ry
I r `4 q Y
99999'09q 9999999
y~ m
ry
~
UUM .1 OiY~~ q ~++/
u (J tl q Oy' Mp O~q Cp q+e
~m m fWA N 41 N N N 10 o V 0 d O~~ 4~tl om m m m fyA N m
. M
ow
YI Y MI Itl
.K N Yt VI N
O O O Y1n .
rvN N
O O O.. . .
V , aCO m eO 4a O~ mwo 1' v1 7 ! h ~.] a`OOOmmmm \ J
a a
--m w
.] .~ OOOnnnn ~1
i
M 0~ PI YI ~O + p n V X x C d
R"u d d
rqIX 1 3
1 5~~, d dY ~ S00ulnnn~x C d N N N N N rv N G
11~0~ 10~Dd10S
a w~~ .
. i ~7
a n a n r tl
`"Y
qN .a ~. n
ya~
q
YNY.XXXYX%qN~. fl. ~1
1 o0
~ O /7~O O I O 9 m00..-IN oN .o~"Nm~N~O ~L ~L' fNIG a m' ~G NO "Om00"NN .yN
~~O i~~
p
o
O
o
~ QY . m H
m~~~N
~Nn .~n .onm ..PN ua Nn .~nvn<o
O~ PPTPPPP
.1 .~~1 PPPPP O.PT
~fI YI J~V~ NY~Y~ Vf U1U1 Yl R .0' 1K"N . ./1 a d a s3
~(1Y1Y~NNYIU1i(1
$
.~ f
O
q u s U fq f O~ F M M P P T P P P P P P N P~= S S S S S P O.
P
P
P
P
P
P
XYxxx `.~"W J",ic `,~x`~aeXxxxxx`~Y`~' xxxx .. 7~
9
~
a
O
Faj
r7G
N
n V~fl~O ~m PO"NO~N~Cn mP O~I
n n m m m m m m m m m m O. T P O.
P
P
P
q Yw +1 I tl~ O~aO~O~PPPPPP O .PPPPPPPO~O.PPO~PP P
u~ q Y W " O Y N N N N N N N N N N rv n N N N N
NOr Nbn >q
P
m
M
.7 Y q Yf N ~fl ~fl V~ Ut Y~ N Jf ifl Yf Yl N Ut UI Yl Yl Vf .fl YV ~fl N Yf YI N VV Y
~ y ~~(7
8 q~ 8 ~~ ~ ~'V~ gq
T W w w w w W Ynd W W W W W u W 4 W W .U w W W W W W w
a a . aa a a a 6 a a a a a a a a a 6 a 6 q 6 a 6 a
" u F Y V C
y :~ ~~
~
0 . V1 .Cn mP
.a
.i POryNn .1(I .O
0{I' " ~ "NNNNNN N
.i ~ r1 ~~q~ q1"n
aYi s =
STL
Denver
62
.
(
qqqVqqqqqpqqqq99qOq9q9qqqq P P P P P P P P P P P P P P P P P P P P P P P P P P
rl n N N N N n N n rv N n N N N N N N N N N N N N
.1 X J! X X Y Y X X Y Y Y X Y Y X Y X Y X Y X X Y X Y Y a N N Y1 Vf ,fl 1(1 N Y1 N Yl N Yf Y1 ,fl Uf ,fl Yl Yf ,/1 N Yl N U1 ,fl I(1 u 1
nnn n n n nn n nn rA q A A qA A A AA 4 A AAA A A AGAA AA AA A U ~GOC10GGA6L1G 0 GG6OOGG6 GO G 6~G
0 .0 0 a O O O O O O O O O O O O O O O O o O O O
O O O O O O O O O O O O O O O O O O O O O .40000000000000000000000
Y . .. . y .. .. . : .. .. . : .. .. ~ .; ~ .. .: ., . . . . ..
O O
O o O
o O O O O OO
.: . . ..
O
pooooo00000oooooeooooo00000 o0000000000000000000000000
p .~ ., .a .+ .r .a,r .. .~ .w .aooo .~o .~n .a .i .y .y .y .. .~ .~ Y1NNY1,flN n
a
n
n
N
N
n
N
N
f~ tiQ
f
s
m
.00 . . . .70000ooooodooooo0000000000 0
s
O O o O o O o O o o O O O O O o O o o O
000000000000000000000000
.y .a .-, ., .-, '1 .y .~ .-~ Uf Uf N vl vf ,fl N ,ti .e .+ .Y .~ .~ .~ .-1
A ~ 1 yM
M
.1 .1n,OnYI Pn Nn V Nn .-IPP r
~ .~w~nr~ r ~P
.+oroomm
r~ vo .~o 00 .~ .a
n,o~o~oP . ~
~ m O P P O+ M P~ O O P r P P P P O
^
y
'~
~Y1nOrNNYIr V n V PPnP V nnOm~OPnOn 0 4 r1 r r r,n-~ ~ OOm00~OOOU10n m~Or .IP,(1
~On V OOpY1POmnOn000000 .~ nOPOnn .. .... ..... ..... .... .... ..
MO00 .-1 NNO00 .-IOOOOOOOOOOOrH 1 NO rl O y N ~ N
p . 144
o
ry nn~/~N IIfw~O r1n tlfl~m~On mN V Pnr P V O I wO n1(Im~rn0,0 .-IPOm~O r r r nY1 r 00 mN .l O
Corv V~On ~m nO .innryeinr NN'rNn V n n mOn ;000 .1rv~f1 ~ryOnOO~eI0000000 .~ rv,fl~
Nqnn n
~i
~~0 .1 .1r mnOn0 V PPn .~HI-I mm .1 .+OOr rvOP
. . . . . . . . . o m N V YI/~ 1l1nm .I VnU1mY1 .~1~ m .lrnOn V Y1P,G, 0
~ V~nn~~OwOr rnOr PONOO
.1 ~i 1 .1 m'1 N .d .1 ri M 1
P mP O n .-1 1 .1 a .y rl 0 .A '1 ei .i '1 .~ .i -1 .1
AI
"
ObN~Or rnPY1P .~Y1 n0 V PnNPnNNO
M V O .yNnry,O P,OPr V V m Nti~ .Om V OGO
YPr~m~Pm P01(1~ Onn OOnO,l10Pr O
. .... .... .
.
.... ..
r m P m m O m m m m O P m r m r P P m m m m P .1
N
.AiyAAApAn y An AAAAAA AyAy \ A A A A A A G~~ J6 ~ A A~~ A A D A A A~ A L A L
O nry rOPnN nnN Y1~Y1~G .1Yin'Om r nm N OP YIP~r ON ~ r ti~~ mm'1 ON I~Prv PPN PPP
Mry~r vlmmvvrv++mNr .y .~ .+ou~rrn~c
~
.I N m n V N
.I rl 'I N~O ~,O
.~ ry ~1 N
A
w ~ O F+ommm mmoom mrm ~ . .+v+ .yti mmmmmoo
.. O O P P P P P O O P P O P P m O O O O P P P P P O O
~ A i0
-~~~tiNN
I 111~~~
.... .... .... . .... . .. yn rm .1I n m .-1 n'1 , N Om .~ .-IN
~ M M q 0000000* o m
N O N N O O n V m
V UC 00 ryN,/1 O^ NO 00 OO .y N Uf ON
` a
\(~ A
~ A w V IQw
8~ m qqqqqqq Ma yyy M My b14444414144414 IM L O
Aq L M qNq M9 1qq ~ 4q Mq Mq
~ JI ` M A * C y q : p ~ 6 ; ~ Cu fJ p Ap A ~p0 ,[0 0 A tl ! ! ,GC ,GO
p n D MTpOsD NNNN N,N/ IVq {OddmdO<,C ~RlA mNN NNVIN
a V
Ny
mm
y M
77 7 O
~^i,, ~
~ fO NO~N O .+~ Y10~
NN .~ .i
n .y
.y
O O I Lit w PI f ~ ~ O O G rr V ~
/. m K w d w o q1 N J a M J o O o m m m m \ \ a,,1 a ~ w w J a o 0 o n n n n
.-1 a
u f .1 ddJ .4 .7~~ a dOOO0o0o PdJJ .]~~
~ ~( H vl 1 s o ~ p Y S 3~~ ~ d dJi S~u1,(InnnnY 31~ ~~ d d
~ p Qn ~ 1( ~( o C d d d 1 S O d C d d d 1 1 D ~ ~ 1 a ~ Y Y A n,n 1 3 1 ,0 S n Y Y iL Y. X Y. Y A rv,n 3 1 1 arar r a / .+ . oo .+ v,,nui,n,n,n,n .+ . . o a ~ o~o O{ O q mRi00 .-IryY1 .,mm~oa IK~ 0 0 o GmoO .~n~1'1N
n ga ~O~O
O
~YYr/4w
n
an aii~~n
+-y.+d. Nne,nvrm .+PN m
1~ $ ~d ~ m~ .+ Y ~ ,(INY~UIN,RYI,f1,flY1N~ ap'~ CpC~ ~ ~~ ~YINNJfY1Y11flJ1
o ., . . .. .. . . ... .. .. ., .. ..aa Ey {7 q N Y y P
~/~ Ay U= U= = D~ M N P P P P
P P . . . . . . . P K Y. R3 g~ N~~~~~ ~ O ~~ O
P P P P P P P T T~ S T T T P P P P P P P P
Vo
r
~4
~ .,1
.. ~
.~
UUUppp ~A M Y W
v~ I~~j a w u
~ Y~, O~~aG n r r r r r~ r mmmmmaNpmbCb aP
M C iii~~i P PPP PPPPPPPPP P
n p G Y N N N N N n N N ry ry N N N N n N N n n N N N n n N N I ~1 p X X Y X Y Y X X X X X Y Y Y Y Y Y Y
TTT ,/I~TNN,n~u1 ~,n,n,n,nN vl,n~ N,nT ~n,nvf T~u i
X
PP PPPP P Y X Y Y
PPPPPP PPP PP m
X X Y ,,
ti R ~~~~ ~I M~ y ~ n T W'~ W W W M W W w W W W W W M W W W W W W W W W , u U u W A i O O tL G 6 G G G O O q 6 G G G G 6 G O ~ 6 G 6 O ~ O
.7 ~~ ~~ ~
h
a
~U=~ VV
.-Poaa-
~n~~n .ri~ .PirOit~vNrvr~iP N
STL Denver
63
i ea a
O9O O .OO O'009'099C'O V 9 O'OC 9 V'090 0
~ q P P P P P P P P P P P P P P P P q P q P P P P P q N N rv N N N N N N N N N N N Y~ N N rv N N N N N N N
X Y Y X X X Y Y Y X Y Y X Y X Y Y Y X Y Y Y Y Y~f Y N N N N N N N N N 1 N N U t N N N N N N N N N N V I N N
,rnnnnn m mnnnnnnmmmmmmnnnmm~n
U a q a aaaa$ a a 4 a a a a a a a a 6 a a a G a
q O O o 0 o O o 0 0 0 0 0 0 0 0 0 0 0 o O o 0 0 o O o
Oooooo000000000000000000000
.~ooooo000000000000000000000
.
...
.
..
.
7 A A A A A A A A A A A A A A A A . .1 A A A A A A A A
N
Q
! booooo000000000000000000000 Mo 0 0 0 o O O o 0 0 0 0 0 o O o 0 0 0 0 0 0 0 0 0 0
OA AA rl Ar1A AA A ei OOOAO .ImA A AAA tiA A N N N N N N n N N N rv N N N
m
. . . . . . . . . . .1 0 0 0 o O O O o 0 0 0 0 o O o O
11 o O O O O O O O O O O O O O O O o O O O O O o O O O
.Oy ti~ O O O O O O O O O O O O O O O O O O O
U OA AAA AA A ti N N N W N N N A A A A A A N rl
!
yM
s
!
Y
t7oN r O r-1r+mNN+r .q+m+AN'1 N nbPP m
q+nonrAnmAVnNrNmrA+mAnA+r P
~A000dNrrNAOObmONqqnO AANNr~n
! ~ o O o 0 o q Pd O o m m r m r r m A o 0 0 0 o P P
AAAAA
A A .1 A rl AAA .1
+ mNb .~r mNA PO .OqnnbPnPNmOm N .N O .~DPA~Onr ry An~OnP+r n A .OAnNPqm
! ! ~r~ OOOA Nr rN AOObCrDO NqPnOAAN rvr b
! 1~ N O O O O O P P A O O m m r m r r m A O O O O O P P OA AA AAA A A A AA A .~A
p . 145
. mmmqr NAmm m .0 -IANrOVmPb bn A P O O P n r A N O P+ N q 0 r O+ q O N N N + r O ONIA Or APmnA NYnn V m+P m Nrvm ~oN m
. . . . . . . . . . . O A r m ry b N P~O P P n A N
NbN r NN m A~RnNmNArm Ar nOn~OVI q~0O ~O A A A A A q O r+ n O r P O N O O m+~~ N N O P p~ ~ O AN A .IPPmPm PON -1 A AY O
AArlA .1AAAAA A .1A .-I .-IAAA
Aom o O O o O
FI
O
O
ti KO
~
~y ARADAy y AR
a DA R A p A
~A~DDRDRA~G~DR~~CAA~A~A~DR ~
b A A r m n b n o .O P P n A N A m m A A b o+ N e q
R
NbNr NNOA~OmNmNIr m-IrnombNP~Cb bnn1.1 V~OPOr+nOr PONOOm .v .NNO q
q N~ 1~ A
A n I r i r I O A N A A P q m P m P~ 1 V A A A A A A O A .-I .~A AAAAA A A AA A AAA
YN
a
hmmmmmmmmmmmo .+ACremmmmmmmc K q P P P P P q q P P q P P P m m m O q q P P P P q O
A ri AA r1A .-1 AAAA .~A .i AA ANA rl AAAAAN N
\ [~ O O O O O O O O O 00 O O O O O O O O
!
o
S O O O o O O O O O O O O O O O OO
O AA
U 000
O
. . 00 o
. O OA O OA oo
3
m
" VO00'OVC 700'09OV q R L M N N M 4 M Y Y 4 M 1~ L M M M
a a i~ .I N L r l (~ (~ A(J (J ~ C C
! p NI ~ MKm N N NNN00d O
. ~ m N N N N tq N N
K
R N~! N
N
A
NN
mii O i O O
y~{ A N n V
pNoi l'~
ry
M
O
U
Aoo++ . +
Y.e Kq o J f1 h J ..1 ~~ .]ooommmm .I .]
a n a+
.+ a J o 0 o n n n n
.~ \
y - 0000 .7 Jb000000 0
I M
t P t e1 N p M
.1Y 11~ ~~ ObY ~ 1NN NnnnnY 11~ ~~ PP
p O n 6 N + I~ m 4 ~ O P d 1 1 C Q N N N N N N N C Q P P 1 1
q YYbVi LLG NN 331 tl 1NXlLYY.iLXY qNN 13 ~
%7 O O '' OOA NN l(1 NNNrI 00
40
OOANANmNO{K a N' K G G G
mOOANNI N
p O p O ~ I
m
~ ii+~~n 7,~, q ..j A INnq N~D r mA q N U ANnON .Or m
~<3g~~~ P
+
3~~ g p f1 O~{~ N P P P P P P P P P P A A A A A A A P q P P q P q P
C
~ ~
!
V
f
. . . . . . . . . .aaannnm ZZZ U n
M {~ P P P
y P
NN NNN P P P q
NN NNN
K a'
It P P P X k X
.1 3
NrNNN NNN P
N NN A
~ ,]{ QA A r~ AA A A .YA A aaa0~~~~
.~ .1 A A
U=
As
M P P P... P P P q P S S S S S S S P P P P P P P P
A~
q
P
P
P
V S
u~
d
0 .
A
~
O
'N w
N ~ N n . Nbr mPOAN m . N .Or mP0 I .~ ~ r r r r r m m m m m m m m m m n P a q q P P o.
iii~~~ P P P P P q P q q P P q P P P
N q P
m+U1~Or _ q P P P P P P P P m
wM N I n~y^ Y
NNN NN NNNN
N
~. rp
p
G
Y X Y X Y X X X X X~ Y Y Y Y X X x?t Y Y X X . Y
AA
N N N N~ N N N N N~~^~ N N N N N N N^^ N~ ,,
J!
,
2 40 --- I
~a Y : +aw C1 ~ wu .uunaww W wwvw Vaaniwwwww .+r,u~uw~w
p
.+ ~~ O U
am DG 066G06f1000qG
Y~~ R iy !
~ A Qy w~~y{ w
~p Arvn+N~Ormq
~ .l A
n ...
OF.0 mY .7 i 3 h G I U O6 K K U
m nrvvNb .~ .rNNNrv Nvr
GG~GOG44G
~OG
~`
STL
Denver
64
,.
.
6'OR79'C40 V COO04090 V OOC9717Q'77
P P P w P P P P P P P P P P P P P P P P P P P P P P
rl N N N N N N N N N N N N N N rv N N N N N N N N N N N
XXXXXXXXXXXXXX XXXXXXXXX XXX
, ~yNN~l1 NNNNNNNNYIN NNNNN NNYIN N~/IN N
--------------- ~
04O0 q~094 ~04O~OUOi7 itl tl
Sam," G G O C O 6 G O G G 6 G G G ~ L1 G 6 O ~
tl O O O O O O O o O O O O O O o O O O O O O O O O o O , Y O O O O O O O O O O 00 G O C O O O O O O O O O O O O
, , ~ M ~. .,. .,. ~~~. ...~ ~.: .. .,~.. ~ ... .: . . ....~ '.. ~~ ., , , Occccoocco cccccccocoocoo o
,
N
, QoOOOOOOOOOOOOOOOOOOOOOOOO o
4 O o 0 0 0 0 o O o 0 0 0 0 o O o 0 0 o O o 0 0 0 0 0
N
O ~ 1 H .~ .~ .1 .i .-1 .d .~ .a O O O .a O .i n .-1 .^~ .i .i .~ .1 .~ .+
N
N
N
Nn
N N N N N NN
p . 146
m
.7 0 0 0 0 o O O O O o O O o O O O O o O O O O o O O o
~ ' . . . . ------------- ,
(400
O
O
0000000000 000 000 000 0O O O O O O O O'O S o O O O O O O O O O O O O O O O O O
Url rl ~IA A rl .1 .I .-I NN
, ,
1
OrN
w . . . O
r N b O V m n N b Nn
Nn_NrPb nr PIPbnnP
Or .IP b r mmNn _ N m OPP O PmP .i .0001
.ipm r V N .-1 PN OrNN Pbn .ab ~NmN 1 NP O OOPnNNN
N V OOmP-~P tiN O NOPOIn N
11 00~N V OP NO O OOONYf00
G y .y
1
N
v
}
,
PPAIPnr ON N ~PPnP m
r_v~oPNr om
.~ ~NNmrem
o .~noNn~ ro 0 o .ano~onb
oooo .ano 00 0 000 o .+n~o
n n n n in n n n n n n n n n n n n n n n n n n n n n
~ Yb1.OIrNIrrNm Nn mb.n IbO~b 1 P ~1PmnYt.1-1Nr.01m .~ mrn.-1O.n~bbNOP_NOOP.O }~ ~Onnn_bPOr V nOrPOIflOOm V_ V Y1NOP ~ -1 .Y -~ .~ 1 O .-1 N 1 ~ P P m P m P O N y ti~'~ "~ "~ O "
w u
e
, ~~ N
,
~
i 2cAa22c 22 2 cn2nd2 a
~ r
~ pPmrPti/f On ~ Nr b Ob~Y
f 1 N n O P m
m
m .i m
.~n r
r
r
P_ N n .i n r .P-1 n r
A
{~ M
ap Z
~ F
nNnnnnYl n Yf ~ NNnnnNN
s
~p~Ob~ObY~O Ob bb~Obb~Ob
I1 N N N N N N N N N N N N N N N N N
1~II~~ ~000000 00 oNO 0000000 ~ ~ H ~ N o 0 o O O O N N N O O o o O
r ~p 00 .-1 NY1 ~~ NO 00 00 .9 NNO yr
,
w y o u . m M M q k M M M Y Y M N g4 4 M Y M
~ ~ C n~ % ~M 8 5~~~~~~~5 (JU 5 f~(~ x 'yq ~t xeG 99595~$ ~
q PI ~ y mNMN W N W m YIO~OOOC~ ~[~SfONwNNNNN 10 at - m Ab
,
m
Y N
m
m OgO O I.~r
+~
N N N
N 'N y'y .'~"~Nn V
"'JJJ
ON ON n~ Daryn .~ ~ M o0o V V__
xeKw ~ w 11 ~ \ .~ ao0ommmm
.] a
y
an+sv i .w 1 Y
u ~a ooonnnn ~
.~a
QQ .1 .i`1 ~~ \ Qo 00 00 0o Q Q .7 .1 ..1 ~~
y ~ w~iw m O K
.IX S 1~~ ~ Q QJ~ SNNNnn nn .1( 1 5~~~ P O
~1 N _ N QC QQ Q3 Sq Q NNNNNNN C QQQ'~ 1
S ~7 `" q 8 O N v1 1 S S y S N ~C i6 ~L Y X Y Y r N N S S S
I ,L 6 r 4r r I{ O /~(O O
I q .Y I m Yup sm s m0 0 .-INN 0 .I0 N.I-O 1 N O NJ S1'IK NN CNO NC ~O (1O.101 00 i NN0.-10 N
p o p O o
.I r
m
4
~ JT~,!!!.. n n a,,n O ,,Nn_Nbrm .~P N$SL) 4f t~!Nnvin~or m
Q
.y .1 .yt <~ ~NC ~S~ PPPP PPPP
p = p N ~ r Y ~ I N J N IN N N N PP N PN P P q PPp:OC .N_NNN NNNNJ~ N
w . X X~~~~ aa
a Y Y P P P.. ......M
. . . . .~
..~ I ~ q On .. .y .~n .+ .~ .r .~ .~ ..dd d
U Us m ~M FIPPPPPPPPPPP 7li ~S
Q!
O A
U
S SPPPPPPPP
.y
s
M U T
+q
. E V ( N O ~ Nn _ NOr mP0'1 Nn
0
YM r1 (
(~
r r r r r r r r m m m 0 m m
.. ~1 q T .. PPP PPPPPPPP PP PPP PPP PPPP PP P
w M _ 0 O M~ N N N N N N N N N N N N N N
.~ I M
X~]l~XXXX XXX XX XXYYYXXXXYXX Y
ya p! N N N N N N N N ~(1 N N,, N N N N~^ N N N N N^
V ~(Ibr m POtiNn _N~Or y m m 0 m P P P P P P P P m
~i Yp . (
O~{
~O U
O ~ .Y1 +{~ ay
~w`+wwwwnuWwwWWaniwwwni+wniwwwWwww w
u MA g i GG0,66G4i060.OGOGOGG G D.GOG6G
y O ~i wA q
2~a m~~~n
:~ ~p
i-~Nn _Nbr mP0-~Nn . NNNMr-~n_N b N
d uuCURiV "'"'~'~~ N NNN
6G
r
STL
Denver
65
p . 147
rn cooL 0o ~
o
r-- a-)
It
~ MA N
{
Z
cot CY)
d~
.- . '
N `~
E T- M CV
00
N
Ci NN
co rn
OO N
a N
=a
LO % co
LO CO
N 0 o LL~a~mil Q
E
CV)
O cq M z
~ A
a M
If
, N
co
E''
O
N
NM
T pC ~
y
~ IL C%4
LO
LO W
,. O) M
OO O LL ap LL ~
0 V-
CO
Q ~y M N M F ~oo ~
coo
OR
O
co
O "ooom
?
M
M
N N
r.-N
E ~ co
X O N N
o CO nj
N8
8
a
r M coo d' 0)
M
o rn
Y
o U-)
% M co
2 a a
r--~rn % s
n n o vro ..
p 6n~.
loco O O tL c6
~LL~ ~ rnQ E
rr~.n:
NQ
CV
(o
o000
A Co
n oooo
~ n r O y 0 ^ r ~ zS y OD Y tn C 1 ) v G cr ov C a r ) C v
n lc
g ~~r
N
(V coNM ~ ~ M ~caonc X~ N ' 04X V
aio%o o N N 0
a .~ .~ ..
n
m ~l $
n
n C co
E
NC m 0t 0 i1I~ px~ xx
rN - o Ni SS S
N aa~y o
E o ~
-1
.. ~ i I q O
e- /~/
ma w ~~~ a N V /
0N)
~~ ~~~ i A~
I~~ ~~~~n~ a f a~ u a ll'l% LO M LO n
< ~C ~C ~a~a ~ ~ ae a a a
:o tirMV ~1
STL
Denver
66
p . 148
O O M LL O
N M A
~
I OV- ao ri N o
N
M
N U?
E C N
N
E
a0
O 0
ic
o n
m U9 00 ')
a f0
OO M LL aj D `) E
N M M~ a
>
A
ZO
op
~
~ N C
o ch
N M
N
NE ~ ~
aY
LO
L]
%
0
1- Crl co lC
M LL c6 0 2
LL O a) ~
N~ Q M~Q ~ oa o
,A
bN O '
'
~
A Y' J~ tOV N V
O W c o 0
00
MOO m
ZV- N O N O o
M , Cl) a
N N
8CV N a er (a V
N
Tj
a
=
. Y ~~m o ~m ~ a
U')
r- U')
. ..
a
%
Cl) C.
%s
to 14 r- 1-- co ca ~ 1- '-Cr co
?~ O M LL ap (D d
LL ap 40) m
~ nuin n
m ry~ ry ^
N M > A
zO T-
No O ~ Q 0 co f- Q 0 1- Fooc 0o
A o000
co
O
~ ~y~
/~ ~J ~MU N
y~
0 co
CV ~ N
Q
NN
N
N iGKX Y
% a: i a
(Y)
I ~n~n v~ ~ N X X ~
G N ~ I
N O N
I ~ ~~5~ ~ 1 N ~
usiis
:
U)
N N xxxk aoca a
co ( )3
ovaa v
.NSSSS
cn
0) 0) m!~
M V I N ry
"' m
a ~ r-r
~ ,~~~g
up
u~u
n ~ a
t7
~~p
f'rJ .+roln %
i p d a ~ m ~ .,+7y! i, Jy h S 0 I Z N F ~ I
~
~
~
~
. fl
~
a~aa
;
+C <
STL
Denver
67
p . 149
O `-m `n
O O u. aj
N
E
A
! > o0 0
Z
co
A o
~ (Y) ~
N N N N N
N
N
Q E CF)
p
a LO
a N~ -rj o LM O CO
=a
r ~--t <C 0 0 li Qj c G i G) E NM M Q
000 0 O
Z ~
~
M
N
N
N
E cO
V- Lo
O
Ix
O
aY LO
4 = a
%
Lo 0 r f ~ f~ t 9 r t- Mm m a ~
O N M O LLN COQ ~~ ~~ V' O ~ D- ~Q~~ (D ~ oo 1
> A ^ 8oa~
Z co C) co
0 ooo~
~ - r M r N Nq 04 '9
M
t N O N O
LtA o -N 0)1 N0
N
. c
Er O E
Cl)
tA
~
Q)
-- co - CO co o a~ t~ c ? o LO ~ cf)
' a = a Q
a~
M N Q 1.1
` U- C6 'i0-
O O
C6 ^'
r1 . I
N I.L
W
^,
a N % s
` ` w
o0 . . .. .. .. : ..
. .1 '1 .r1
N M N M LO a oo o
O ~ O O ' > I~
, mo ~O O
0 W
O
W
Aco.~'n` Q
~ ry N ry ry ~Y iLYY.
a~ai
Z N O N O m a~'cza~
a~ ~ M r'
M
4 A~3n : N X
o o O N N
0 Q W Q . 0 Q Q
.9
a
a
~
Q~ a xxm aa
& I~ ;~ $ Q? U-) N~ N 9 9
4
r
~
~O
q ~a o
~ E pE~
p
u i u s
~
s
~i
O o ma oIm L c co ) r
U c O ')o
r
N
d N N
~R va1- l
oi o L oo M / CV 4a 0 ae.
1 Q ~ a. . ..
2ra ms~~n ~ i aN ::
_
STL
Denver
~p
68
o r O r O N LL. Qj co
A
00
N
X 04
N
SC'4
~ E 1-
o
p . 150
cOU~~
Nv ~ O O r
MM~
LO co a tA (J r) % co ~ G 2 0-
tn c o r v m ~ O O Nti0) t0 E N M nN a
> 0 ~ O ~ ?
N X
N
r ln
E
M co00
~cY M LO ~o
O
W) 00 rf-- r) m O N LL ap O~
N ~ N
>
A
0
00
Z ~ CV
LrLfa~p-
(0r))
W N
CNI
a M
A
N
~oo
O co~ C Qoom !
O
N
C7 ~ r C'7 a
N
X~
$
N O N
C C
~
Nc 4 2
v~ O
O N
~A~ A
{iT, ? ::: O O
00
M C',
C14
a
- MClc) % N ~ %
.. .,,
n p C= n a
s
Ya
:.
0
r N. Cf) cc r I~ M(0 CD O CV li- ap~O LL~ (D CD
~
CV Q M N Q
~
F
n
n
n
n
A
AN
mR3n S
gmnSv
.ni
O V- co o c o Z N N maaa a
I -r Ce)
` ~~n n N X~ X~
ol 1 96 o
N
N
d
04
C14
N
E .- ,^ 00
oo
VJ
r
~~~ 3 O Iry o ~ ~ w I JC I1
CD ! co ,
~ 00
~
m w .` "i ~17 M M N
G a =a - i ~ ~~~y~ ~ 40 ~~ 3~ O O LO
Y~M ri tl
4 3(f9 CY N M
d4 m y.]!Z~hy 4 i ~
10 /~
s
i4C . 4 .r~4.
g
STL
Denver
w
69
p . 151
I
co cm oou- 6c6
f~ 00
N n
cri
Z O TQ - C~ O O Nc,)
~
N C~ N
N
CD
E
p C+)
O O
V E ) CO
CO) N~ O~
N
N C%j O
(0 :0= Q
rf.- et CO
~
Oto LL 6 Q) G ~
co
> A 04
0 co
z
v
-r
N X`t
N
o
N)
C
N
N Eoo~
CO
co
r
N
0O0
O
~ r
C)
0.c ~ =
rl~r rl~~ (I
ooInLL ~ 00
LL ~~~D E
N N fOr) Q ~-
_. . . v
> A A
.~oo
0 CD O 00 0 woon
o
Z N r C Mo cr v M O
N C~ IRt in
i N Q~N Q N Q
N N -
N 0O
N
E 0 O E
0 ~ ti I` r ti r
m
M M N coo
p00i
a s 0
Y Y oGoo~
S ~y LO N U')
CD
t in V7 Io f'7 % r N N .+
o m ^3
co
w
LL
op r
ao '^
t~ i 06
4-) _ {{NNN
N
Q N VM/
iF{mm
em~" o >A A m N~nO n O 'ZO OO M C~ ) c% o N ~
.innnn
NN N Y~
CV M CV ~ moooo
M~.r M
~ ~ . .~~
n .
n
N CD CN X~ ~ C~
anan n N p) N O N
O
. N fjoio o ~ O O Nr++
N~ O
N
U~U2 m~' s ~ w
NE
OE
O
co CO
U)
ni CV)
r
M ao ~o
M rn rn
m
I
n`~
N
N
Y Y Ioo.g 0
a a m~ 7~ ~ n 7 c.
o M Q ~ C 2 Q %
. D.Nt~d d.
u
. ~
~
STL
Denver
70
p . 152
r
r
O N
N 1Cl > 4ii
LL CQ~j U~
CN fl_ 00
A
N
co
~
Z~ I O N et co
`N~`
C M
(~
co
NO
~ ~
O
O N
y
3
a Llf~M
:G2 a
r- It cv
O N LL O N`) ~
NN C.' in Z
AM 0 1*
N X~
O cM
N N
0 co(3
cEo^ CM000
N Y ~MM Lo
LO 0 CL
LO qq~ V- t--
COD N LL dp I'.
N N
co
04
>
A
00O LL co 14-)
M A
0 OR
C) Go
? N O N O o 0 o r
a
N X It
N M X~ M
N
N
Lo O ~ O
C N N C p~
M
M
OE
Q V/
M
OI coW o M
O
W W
m N
O =nno
M
N
Y
Y
a
d
. in
lo
Cy c ?
LO
a n ~= a a
s
'~ o o m
w n a~ I~ O ~- 1 .- ~/C
ON
~
~ t~ d
CD LL c6 co LL f m ro y R~r ay o
f1 N t N !! N m c ) ~^ 4 H o & m m . . .
> A
A
~ O
00
Crj
Q
co
On~nn~n O IV fV fV IV
r
IG
OG
1G
iC
a MO
N ~
~ O CV
Q mcooo
M
N M N
x
~f o itj o o O O O
S n S~ n n C (~j (V
U')
M Cti ~(qV L~o
e : :e
$ ~ iiius
~
i i~.~ ~ ~~
9y ~ 8y~r $ M I~~
0 M Q cn
i{
1A
~
E
~
If
CO h
~ co ~- 00
Q
Q
M N
N
na o~~ Y
U) Y
U,,~a
% M CV)
~
_ ao~~ o % . .rnV
o ~
STL
Denver
71
ou~ .U-,) m-
; ^
-
-1 E
O pp
N U N')
0
N 04
C
N
O co
O N
Q
00
co) M
3/ N
~A Y V
M
%
M
~
tn 04 r- co
oCD ~ to ~ ~
N~ Lo
M ti
lid
~ OD
z ~
O M
N
x
N
cp Mo
W a cE l) CD coo
N
O CV
0
R
EtACY M % o
N ~G= a
to
N o> co r~ M CO
C D N LL c6 ~ m M~ LL 0 6 m~) E
F-
' ~ A oomo
0
^N
Z O~ O 04 O cOVO oomo
N
V W
c It M h M
x O~ N Oq
rn 04 ~ NNLo 4 waa~ ~
E O O ~f~1V mN .~
Q'^ ff1 0 r ~ O Q V' V /
O ! ~
~
= p
n
MN 3M: Y N
Y
N
o
In CY M % T- M
0=
Q
fl.
o P
%M ~
P P 0
ov oPa
e- N O N N. M(C ry~,,
E ~
~
... .
~ ~n~n no
, N ~Ni MQ v ~~ov 0a v
F F n n n n
>
A
AN
z 0 OD
0 00 0
~KKrY
CV CV ~ mooao
.- . M .-~ N)
c~
CIO 0
O
anan n
O
N
O
OO
N
N
~
.i .
i!1
JI N
C C> N N N
, C~ Lo .w ..N ~ Hmmsm
E
I Woo co
.~
oe
g : ? ~a c
co
co) N
E
co
N
w~ .i g ~~ Y( oa o~ /3y tU') )
V M
~~ m~3$3$ w ~~ ~= o.
U') %
Lo
M
ia~~em
% Sa~aa
STL
Denver
p. 153
72