Document NEMGxxQ0pLDkymOpBJBmG2DNQ

Stationary Source Sampling Report Mercury Emissions from the End Box and Hydrogen Systems PPG, Lake Charles. LA Deceiifcer, 1984 PPG Industries. Inc. Environmental Testing Group Barberton Technical Center P. 0. Box 31 Barberton, OH 44203 SL 025692 TABLE OF CONTENTS Page No. I. Introduction ...................................................................................................... 1 II. Abstract........... ................................................................................................. 1 III. Sampling Procedures*...................................................................................... 1 V. Results ................................................................................................................. 2 V. Discussion ......................................................................................................... 4 VI. Approvals ........................................................................................................... 4 APPENDICES A. Sample Location - End Box .............................................. 5 B. Sample Location - HydrogenSystem.......................................................... 8 C. Sampling and Analytical Methods ............................................................ 10 D. Sampling Parameters, FieldData and Results ..................................... 24 E. Analytical QA and Results, Emission Calculations and Chain of Custody............................................................................................ 48 F. Sampling QA ............................................................................... 55 SL 025693 I. Introduction Effective June 20, 1983, the State of Louisiana was delegated the authority to implement and enforce the National Emission Standards for Hazardous Air Pollutants (NESHAP) for stationary sources* Sections 76.18 of the Louisiana Emission Standards for Hazardous Air Pollutants (LESHAP) requires all LESHAP sources to demonstrate compliance with applicable regulations within ninety days of the effective date and yearly thereafter. This report covers mercury emissions from the end box stack and hydrogen Sroductlon at the chlor-alkall facility. Lake Charles complex during the period cember 12 and 13, 1984. Sampling procedures, quality assurance, analytical methodology, and process related data are presented. II. Abstract Stationary source sampling was performed at the chlor-alkall facility. Lake Charles complex for mercury emissions December 12 and 13, 1984. The test results showed mercury emissions ranging 26 to 72 g/day at the end box stack and <11 to 140 g/day at the hydrogen system. Testing was conducted In accordance with USEPA Test Methods 101 and 102 (40CFR61 Appendix B) with the following exceptions waived by the LESHAP Adnlnlstrator: 1) One lane of the end box stack was sampled with the nunfcer of traverse points doubled due to structural Interferences, 2) Non-Isokinetic sampling was performed at the hydrogen system due to production constraints. Testing was witnessed In part by Mr. N. Coltrln, Louisiana Department of Natural Resources, Dept, of Environmental Quality. III. Sampling Procedures A. Sample Locations 1. End Box Stack (Appendix A) Sample ports were Installed on the south and east sides of the 12" ID end box stack 10'-9" downstream and 7'-8" upstream from any point of streamline disturbances such as bends, turns, constrictions, or expansions. Revised (48FR45035) Method 1 dictates an eight point traverse (four per lane). Building interferences negated sampling the west lane. The AAnlnlstrator approved sampling the south lane only using eight traverse points Instead of four. Traverse point locations and a stack diagram are shown In Appendix A. 2. Hydrogen System (Appendix B) Routinely, the hydrogen produced at the mercury cell operation Is sold as a raw material to a local chemical plant. If sales are Interrupted for any reason, the hydrogen Is used as boiler fuel. If an upset condition occurs In the cell operation, the hydrogen could be vented through the tertiary stack. Due to the size and pressure of the Hg vent header and the potential disruption of product sales, the Administrator waived Isokinetic sampling at this source. Integrated sampling was performed at the centroid of the PuraSiv bed vent lines (8"). Hydrogen flows were calculated based upon production. A flow diagram Is shown In Appendix B. SL 025694 -2- B. Sampling Methods 1. End Box Isokinetic sanpllng was performed at each of eight traverse points located along the north-south lane of the end box stack In accordance with Method 101 (40CFR61 Appendix B) Included In this report as Appendix C. The recommended minimum sample duration of 2 hours was adhered to* 2. Hydrogen System Integrated, non-lsoklnetlc sampling was conducted for the minimum recomnended 2 hours duration at the hydrogen system utilizing a Method 102 train (Appendix C) without the pltobe assent)!y. Hydrogen under pressure was valved Into a mixing bottle from the discharge of the active PuraSlv* unit using 1/2" TFE tubing. Sampling was performed by attaching a short piece of 1/4" TFE tubing (valved) from the mixing bottle to the first Implnger. To assure positive pressure In the mixing bottle at all times, the bottle was vented through a seal pot before being discharged to the atmosphere at a safe distance from the sampling equipment. The sample train orifice discharge was also vented away from the equipment for safety purposes. Appendix B shows a sampling flow diagram. ^ C. Analytical Methodology (Appendix C) The analytical method employed for the determination of mercury followed the procedure detailed In Method 101 (40CFR61 Appendix B) Included In this report as Appendix C. IV. Results (Appendices D, E, and F) The pertinent test results are presented In the following tables. Appendix D details sampling parameters, field sampling data sheets, and calculations. Appendix E contains the analytical quality assurance and results plus chain of custody. Appendix F presents sampling quality assurance. 025695 A. End Box -3- 84EB-1 12/12/84 09:03-11:03 Stack Gas Flow Rate, Dry scfm* 2260 Sample Volume, Dry SCF 77.399 Mercury Found, ug 525 Emission Rate, g/d - 25.98 Isokinetic Sampling Rate, % 97.8 Test Mo. 84EB-2 12/12/84 13:30-15:30 2653 77.180 1450 71.80 97.8 84EB-3 12/13/84 08:10-10:10 2600 74.562 525 26.38 96.4 B. Hydrogen System Hydrogen Flow Rate, Dry scf*/day Sanple Volume, scf Mercury Found, jig Emission Rate, g/d 84PV-1 12/13/84 05:54-07:54 East Bed 6.0S6E0S Test Mo. 84PV-2 12/13/84 12:53-14:53 East Bed 6.889E06 84PV-3 12/13/84 19:53-21:53 East Bed 7.092e06 65.897 <125 <11.49 65.046 <125 13.24 73.359 1450 140.18 *Std. cubic foot at 68#F, 29.92" Hg SL 025696 -4V. Discussion PPG Industries, Lake Charles has demonstrated compliance with the Louisiana Emission Standard for Hazardous Air Pollutants. This report has been reviewed and approved by Mr. R. J. Samel son. Manager of Environmental Programs, Chemicals Group. VI. Approvals vvs -5- APPENDIX A SaRpie Location - End Box SL 025698 MERCURY CELL FUME SYSTEM SL 025699 rreuminary f ield Data PI AMT K1ALG ^At +-*r. , SAKPLNG LOCATION D DUCT DEPTH FlOa WSCEFA* MAUL TO OUTSOC OF FORT JUS* NPPLE LENGTH S7S~ DEPTH OF DUCT /z-.o" WIDTH CRCCTANCLL4R DUCT) EQUVALENT OUACTER: Ur,t~- -2*OOCEFTPHTN**WMOOTTHH __ (2< X )) ii I" I- I-: UI -l--i i B l--i--b DISTANCE FROM PORTS u^tpfau TO NEAREST FLOW -/ DISTURBANCE: rtT *0-7 STICK OUICTERS PPWfilKAM 7'-*" STACK AREA:__ (R Y *______sO-Wttfi LOCATION. OF TRAVERSE FONTS M CVOJUM STXOS 1 1 4 a.* 4 4.4 t.t m. U. 1.4 a.i U. _M_ IM IM M__ 1.4 n i.i ..P. 4.1 . IL. IM 1 1 * n.a n.a aa.a n.a u.a i*.a a.a aa.a 4.T u.a .T a.a a.a M 4.4 T.t IM 4.T M *M IM M 4 *.* aa.a u.l 11.4 IT.* MM ti.a MM a.i 4.T T.a i . at.a at.a M.a n.a n.i u.a MM u.a MM MM 4 V at,* aa.c aa.a 14.4 n.a UM MM 14.* MM . UM aa.a n.a aa.a M.a M.l I1.4 M.4 MM MM aa.a aa.a n.a *1.* IT.* n.a MM UM M.a * aa.a aa.i 11.1 41.* MM M.4 MM UM ia at.a aa.l M.a n.t 41M MM UM 11.1 :i ai.l a.a MM M.a 41M M.l M.l u aa.a MM n.i M.a a.a M.l MM :i -- aa.i a.a 1.1 Mm a.a MM i4 aa.a a.a M* mm TIM T.T It aa.i aa.a 1.* MM MM ;a IT n.a ai.a at. *.l M.l UM a.a TIM MM' l* a.a ai.a M.4 i.a IV aa.i 41.1 MM M aa.i 44M MM u MM M.1 u MM MM 11 MM M.a SL 025700 LOCATTM OF TRAVERSE FONTS N RECTUCUMA SXAOCS 7 ii* n.a mm n.i i.i >.} i* *;# *.i m. n. M.a *t.i a :r- *. it.* ia.a n.l n.l __ iiaa ii i.i> Vv..Fr Cl" ia. u.a i>.a n.a u.a n.i u.l M.a IM M.a aa.a m. i fnt..aI M.a a.i *a.a i.a M.l aa.a m.* M.a ai.t n.a ai.a MM u.a aa.a M.a n*r..i *i.a i.a ai.l n.i ai.a M.l *a.i *.* ai.i n.a 44.! U.l M.a n.a n.i M.a ii; ti.a aa.a n.l at.* at.t ^ NM MsMaIrU MIMUMUIMKl11M mMmarlUaraomCaurt a I 7* ^ . w .7r 2 foS /.2.C 7,0/ 3 /i-i x 13 4 Jl-} 9.ez 5 gji. ir.il 6 X*-u 17 7 %T / 8 %! //tl* /A.1S 9 K) < II 12 13 * 14 IS 6 17 18 19 20 21 22 23 F> 4 8- - APPEHDIX B Sample Location - Hydrogen System SL 025701 TO A * PHERE TRAIN MERCURY CELL HYDROGEN SYSTEM' APPENDIX C Sampling and Analytical Methods 025703 sl C: 11 Part *1, App. IMo 40 ProtocHoa of Environment Arrmtx B--T**t Mxtmom Mt-DmuiattiM or Puneon Owmoi ilacm Pmiii)w hut-Auui Punra--An Snwa L imWMIUr at PrtMW^-U AppUoobUUp. Thio method aopUe* to the deter* Of pHtlollAll OOMOMt Mf* r <Hf) awlMlnM from chioralball plaata other aoureaa <*a medfled la tb* n* laUoae). abort Um eorrlor-o* atnom la iht duet or atadi It priadpally olr. L3 Prtadjrf*. HrticuliM tad coaeouo Be i art withdrawn taoklactlcally Hat Um ea and eaPoctod la addle ladlna byAi After MUM dOutfon. Um toad* of a ls to 1M c Mf/mL Tba Tad by f ` tba i___ AX AroaffMfa Tba aandtlvAy of Ibla ao tba rocordar/a A IMaAhar Aaowta A1 reduce* Id i of Um IO BttlutflMQ* AX Anofpda. ICt tbAD if*4 moUr raducUoo of tbs H* (II) Ion la the of i*l A, are UI ALL IU ALA Ui. ALA aad ALIA it> apoctlaaly. LU Proto Linar, Soroalllrata or quart* llaaa toblnc. Tha taatar mar uoe a hoaUn* ayttam capable of maintaining a eaa tem perature of 120*14' C (3te*Xt* P) at the i axlt durtoe aampllnp to prevent water Moic Do not nee metal i ALS bwbiot Ft) tanplacara aonnaetad hi aartaa wtth t*ak*free around daaa fluinea or any tbnllar laak-froo nnneontamlnattne flttiacL Far the ftnL third, aad fourth kaptnem. the taab uae taapiaean that art modlflad by In* tba Up wtth a l*mm*ID (AA-bD tuba aataadtag to IX am (AS A) i bottom of tba flaaA LL4 Add Tnp. Mine Safety eiWT. uttb AAl Uoat with aMAudWd AAA iaf Cpttadar. XAO-a AAX Ptmad end bettor FaKcMama, lb old la t ifdMca--1 to coat rylfaQX AA4 Pbaaal CHaaa, to aid Miample ia> ~AA,j niaaraflmi and dnalyefn TbafoOowtneoaatpaaot la needed AAl atomic ilNffMos J^c Mftet a iMrlUtiraqalMdone, corn the optical cad daaarlbad la Sooth AAA Optical CM. Cylindrical i i wtth la Pleura 101-A wtth appradmaidy X motors of .Thai I a MJof Hp/ool (la 0.1 K ICU etaadard nbtmmd a atu of SAT ad Ht/aL A dpperofua-Al JdaaUa# SVata. A achamatle of the aapMnt train la abowa la Pleura Idl-L It la dmflar to Um Method A trala (bmbUob of Method f rafan to Pena 00 of 40 OPItl Um aawipllnr inla corutrto of tha followinc component*: 1U Proto Jfoaalt Pilot TUta, DiffmnUml Praeuro Oawp* MWirbf SpUcm. So rometer, mmd Ooa Onullr OdimiudM Saulpmcmt Soma aa Method 0. AAL AAA VOriette naailbwr. To vary Um volt*ea op Um optical coU from 0 to 4 volte. AAA Hood. For vaaUae optical adl ax- hiitfC IA.T AAA fntowwemMadUerr.iaRr oVtUaaaatotar or aquiva* lent, capahla of maaaurtne a e*e flow of IA Uten/mla. SL 025704 628 I C:12 Part 41* App. t Tltlw 40--Pf*tdl(i pf InvIrMMMl (LX) Into i 00Add 10 ml of the I KX aarf 1 ml of tho 0.1 MIC1 eM km aa i bunk (TJJ) ond 00 ml with datoniaad dfctilled Ihgmodlhr. htf--T.l fMfUm 1--iw of of thia method. taatora nlnod aad txportaocad with the to amufo relistolo rmuiu. ;be< to >10 atainlom eteel or Teflon forruloa may ho wood. Mark the probe with hMUwWut tape or by aome other method to denote the proper diotaneo Into the dad or duet far each aampllnc point. Animbli the train aa ahown in nuro 101-1. ualnc (tt noeamaryi a very Ucht eoat of alltcono praaao on all (round fiaaa Jotrna. Oreaao only the outer portion (are APTD-OST01 to avoid poaoftlUty of oontaalnation by the aUlaoni paaao Hots An empty Impincer may bo bmactad between the third Imptneor ond the dUn Aftor tho aampllnc train ha* bled, turn on and aot the probe. If apoHaaMe. at the dealrad oporatlao imwtMm. Allow time for the tampmturao to atabOlm. T.1.1 teeKCbadr Praoodaiaa. Follow the leak-check pmeeduraa outlhmd la Method , Section* 4.1A1 tPratom leak Chockk iUI T.Ut Jbrcnry IMa Oparofloa. Maw the (onaral paomduro (Ivan In Mothod . Soctlan fbr oKh run. roaord tlm dun roqulrod on a data (hoot ouch aa tha ana dwwalaniMtlM. T.U Chlrulortoa of ftiwil hilkdlt Saaao oa Method ft, Section eta ctaanup proeoduro aa aeon ae the inSrk removed from the etack at the end of tho Allow the probe to coot Whoa k eon be aafely handled, wipe aff any extemol parUoolale matter near the Up af the probe off the probe up tlphtly while the naktaf train la oooHnc Capping would create a vacuum and <kaw liquid out from the tm- <Citation <n Section 10) lor doeither Ihwfw the probe and Impincer aaeembty in a cleanup area that la dean, pretarted from the wind, and free of Hfe onwtamkmp tlen. The ambient air In laberetorlm lecatad In Um Inunadlalr ddnlty of Hc-tulnc (acmtlea la net normally free of Bs oeotamlno Uon. Inapoet tho train before and during aaaem- Treat tho aamptaMtTfollowc U1 Cbntaiacr JVO. i (Imptneor and Probel. Oainc e (raduated cylinder, mraeurt the Uquld In the first three bnpincora to 630 C: 13 Chapter I-- hvfciwimM Erelectin Aftaqr Part *1, App. within cl nL llsoocd Um rnturns of liquid pm wit (ex. M Figure 14 of Method IX This Information to neodod to calculate the mototuru oontont of tbo offluont gas. (Um only glam atone* bottlm and graduated ctlIndus that has* boon prodoanad aa tat Sec tion Til) Plaea the oontonto of th* tint thro* taaplnian Into a 1000 tal glass Miapt* Dottia. Ttktoinra that nMjn^th*|Mtoiddoof not cat into Um sample. quantitatively re cover ttao Ht (and any condensate) fnn Um TJJ MiKmx Flpet a 3-ml aliquot from the diluted sample from Til Into a MO ml volumetric flask. Add 10 ml of 0 percent UOi sad adjust th* volume to exactly MO ml wtth deionised dtotUlsd water. Them so lutions are stable for at least T1 bouts. Norm The dilution factor wtll be MO/3 for this solution. 7.4 juafyeta CUIbrste th* spectrophoto meter and rseordsr and prepare the callkratlea curve as damribsd tat Sections 0.1 to 0.4. 7.4.1 Mercury lamplsa Itepeat the proco- with appropriately stood aliquot* (tut mil of eeeh of Um diluted samples (from Section TJJ) mitO two conesculive peek betebU agree within cl pareent of their avanta eaten, Tba peak msrtauum of an aliquot (asoopt Um M aliquot) must bo pmtar than 10 pareent of the recorder fun scale. If the peek maximum of a U-aU aliquot to off Mis on the recorder, further dilute the It to alee meemm ended thet et lead ana aamplt from each stack test be chocked bp the method of atandecd eddltlona to eonfirm that matrix effects have not interfered teUMineiyda. 7.4J Cbafafner Mn i CSOtea 0*1). Weigh the Meat silica gri (er silica gal ptam tmplngarl to Um itssiml U g using a bulanen mdaatep maybe camtected In UmflehL) fnllnse brush with seep end water. Uberally ikM* wtth tap water, soak for I hour In M pvuant SMOfc and than rinse etth doMn U flam OshOrefien. temlla th* aoratlao Mctem as shown In Figure Ml-A. Set te etetet pruMuru entbejnrstlonmMjcylj flask and adjust the votamM to umatty 1000 ml wtth dstontasd dtotltted water. MO mm Hg (10 pa and use Um flowmeterteg valve and a bubble flowmeter or wet tod motor to obtain a flow rate of LSc0.1 liters/ mte through Um aeration eoll. After the flow aaHbrallon to comptot*. remove the Wafcfe|d fUteBftnr fron the tytUOL AS Optical CWf Meettap Svefem CWfbrutton. Udng a 90ml graduated cylinder, add M ml of detootoed dlsUUed water to th* bottle section of the aorstlan ceH and attach the bottle section to th* bubbler section of tbo con. Attach Um aeration can to the opti cal call; and while aerating et IJ Utera/min. determine the ---*--- variable traaaferm- of mototurekTute opUeal call and In Um M-ur o--m--u 631 SL 025706 025707 Chapter I--CnvirMUMfltat fralxlim Agency M *1* Apf B cm. ie determine the final total weight ef mercury In nanograna In the aeration oeil for cadi source ounple. Comet tor an? di lution* oiado to brine the sample In the working rmng* of the spectrophotometer. Titan coleeloto the He In pg (nj to ttoa original (elution ao foUowK CumXFJ(V,io-* S Bt 101-1 of mercury In allWank subtract- DLP.-DOutlon factor ter the : solution (bgfoie filing to the eon; u. OP..1M/* If the i TAX) V*8otuti ed for flection TA1. I0**-Conroteon factor, pg/ng. 8Aliquot setaoao added te apelleablo national amhetan standard, uaa tho average of tha moult* of all rcpetiUope. IX tiMUmMa 1. Addendum to Spidftcatlona for Indnoratar Tooting ot Federal Podlltioa. raa. NCAPC. Oocambrr X100T. X Determining Duet Conoontratlon In a Oaa Stream. A8MK Performanee Toot Code Not IT. New Tort NY. 1MT. X Drvorfcta. Howard, at aL Air Pollution Source Testing Manual Air Pollution Con trol District loo Angeloo. CA. November IMS. X Hatch. WJU and WX OU. Determinetion of Suh-Mloogram Quontltlm of Mar* airy by Atomic Absorption Spectrophoto metry. AnoL Cbm. <SMI IT. 1MX X Mark. LA Mcchenlcel tetgtoeerr Hood- book. MoQrata-HBI Book On. Inn. .Mo* York.NY.lMl. X Martin, Hebert M. Cunetructiow DetaOa ef taokineite Santee Sampling SgulpionaL DA SnelioamMdal FietaeUen Agency. He* aaorch Triangle Park. NC. PuMkntlan Re. APTD-MkL Aprt IfTL T. Weeteru PridpWaflnn Dtahten ef Jdy J Jtefeerr the Kg amlarton rate R In g/day ter cooUnuouo onoratlono Mine aquation 101-L For cyclic nratlwt eoo only the time per day each atact h In operation. The total Hg nlaalan nte from aaouiua wm bo the nun- inllacacka. WtAdMdOxlO-T R- k tv, v^xvpj MM. K-OilM *K/mm Hg for motrio uafta. ITAI H/tn. Hg for Baghah untto. xlfledlonrAn and 14A teapacUroly. XT PetenufaHno qf Cbmgfloaoa. Baeh performance toot aonolata of throe repetlUooo of tha mclkoltla toot motliod. FUr the purpose of determining cwmpHanru wtth an April Mil R.T, WA TodX and WX offerers to Stack Sam- DUM-1XI Btafe Sampling Neva. 1*TX 1LJ with HO* . APCA Paper Mo. ST-11X UWT. IX Saaltlu WA. AT. J WJT. ,A1 _ _ JtlKA*IT. IfTX IX SpodOn aaPadaralfaidmtea, PHSLIiCAFXyST:>fcj for Particulate Matter. Ms 1PU Annual of ASTM Standards Part ZX ASTM D-3-Tl. Philadelphia. PA. 1T1. IX VennarX JJX Bementary Plold Me chanics. John WUey and Sana. Inc. Me* York. 1MT. IX MltcfadL WA. and >CJL MMgett. Un proved Procedure for Determining Mercury KmlmiOM from Mercury CeU Chior-Alkali Plants. J. APCA. Ml gT4-gTT. Ady ltTX IT. Shlgehara. R-T. Adjuatmonte la the EPA Nomograph for DUferont Pitot Tube Coeffldenta end Dry Molecular Weights. Nona. M-IL October IflTX 633 025708 C: 16 Fart *1, App. I It. VoUaro. ILF. for Soiapla Ttinn InDuotef la InrtMo la OA birtronmonul Proioctloa Acme?. Trtancto rut NC Mo im TM* 40 ProtocHon of favtmwont lt. KMn, R, oad CI Uook Dm and *`t**--*-- to i OMtrte UiuunMoU. Am. Lap. paL ItTT. 30. Wator. AUoMplwrta Analyata. Ik of ACTM CUadar*. Fart *L O-llM-TL miadol- ptala. PA. IVT4. C Chop* C 634 c SL 025709 j ; r~ ? 0MF1CI MAHOMITU MVTmWTKM 101*1 ? C r 18 r ***. L636 SL 025711 C: 19 Pwfdfaa A(*ficy i/ Part il, Aff. i IM MALI BALL JOINT BOM TVPLON CTOPCOOC TO OmCALCfLL 1C/B MALI BALL JOINT WPMLNhrUM Rpn 101-X AmmIbw Si 02^lZ 3T cr 1 \ ! SL 025714 fw tw Hwi AgMcy Ftgun 101*4. Schwmlc of Mnftlofi SL 025716 APPENDIX D Sampling Parameters, Field Data and Results 05* 0:25 /Us*--/*- FIELD SAMPLING DATA - f*/<b07*O . fi-JhT */ PLANT & LOCATIONj ASSUMED: Z HiO'vZ.O T7 INOUSTMES fifty *C Pa, 1a. WG 7P. *>> DATE : nJn*! & TEST NO.: EQUIP MFC. { -P-------- METER BOX NO. &--*/ LEAK CHECKS INITIAL k FINAL YD r> 9/9# A Ha: 7 Q?> SAMP. BOX NO. OPERATOR /jf/CfA. y TRAIN: PITOT: IMP. f-* O ft ~ 7'---------- PITOBE: NOZZLE: NO. /A NO. / TYPE <7 Cp Z>- W ,^-oV ID, la. Oj?9 Ft* /?(? STACK: DIMENSIONS / *Z* AREA O 7?^ Ft* K r A P REF. /. .f*7 C FACTOR WAKE FIELD METER CHECK CuJLlZi riMt' Comm W / 2-- 3 V t 025718 k1 < t 7 dock Tlaa o -- Dir Cm Iktll. CP :t #. Pita* ar la. S.O /17 i . AM s tit a/fir. j^sr bfl* Orlflc* A Dry Cm -T&*M*....**P* Z ' for ta. Toay. f r Stack Ptom. la 1.0 5-w 18 T5 e>.o jee +s -.40 Stack Tcm* #P r 4iV 7*/ ei 44 /o 4lb .4 00 t**? 5 *** |D1 7L 8-S PSft Mu u4 tr 4?0.f7f \ *40 1>7 18 er 48 2-0 4*4 MAC .7S* w 457.8SD 1 ?o </?/? S4S ?r Hi[Lrtfp hlo ?o </y). i9o I!** 1*0 lC i.Mo |n /. f j|^ /.If bio ft, e>r PMo Si 4 Ml J7 2?? y* -O.A6 r.r79 yjIT 9/ ?.r ?^r /7 /r /./S' -To +<7.000 i.t* /. 7-Tly v ?.r 2T6 n .o Ml ,rT 45011$* l.LS_ 4S4.4aSj 0*1 6a" 4S141S- 0.^1 1.1T (At |.5D|\3d l.SolnS S\ o 1.6 *r 1.0 ^4<r 4(, 4b ......... <4u C7 7 V4I.4TT 0.17 7J" *kS,oo* fo 4Lfl.*0 oMl 018$* 0.4 3 Iff 47s.no o.8a fr ^ y# 0.J3 - t<SO lii^ i*45 1 u 1-44 1/iA `W Ins \ *58 JuA 9f 7.o ?4v Ml VoHl <*s 1* * 7M1 4t 7.* ^ST> H 48 1.0 as- -.48 UL 9 $_ (, .o ( \ C.D rVf Y7 /Dtl * i* o->1 /.L* l//S> U, 2Y? &_ riiir o (/ D: 26 Vm n *T $M NMV. cr nut At la. U "i m A `/to.fls o ?r /.to /H> \ - hu i* ir Am1i Rlur to. Aj Tv IV? ItlM. --it-- So -olr * * - . * y. - rt i/ w` 5/ tf" / ^o.fwr - ^.3S'3 Ft * (Dry)' 55- /2~T , 5Fl- **WB P* - 0.</4 "WC 5 2*f** "* 5 P* -- ?. o5 "H* Pn ba.- "H* P bAJ / "Hg Additional CoHMnts: hT ^ <^bm :t- ? :ii- S~^S^ % SL 025719 D:27 ORSAT ANALYSIS TP? MkS INDUSTRIES Tcac no. 6*4 _________ Sampl L cation E^'ljQy ^4tvc.|C Dace Analyzed by__ tA* V^T0^ Sample Type Xkj-V *<^r* ^ Volume (30 L minimum) Time (4 hrs. max. afcer sampling) Il3 . . Orsac Leak Checks(Mandatory) Before <0 After o*. Orsac Test No. 1 2 3 4 5 6 AVE. -go?. <0.o c. 0 O.o + Op as> ao-8 SQ> 0?~2o A \ fL ^ fo CO o o o -Ji2TU- 7T-7- st 025720 m . /_ Teat No. 2*j/&&-1 Plant INDUSTRIES Inplnger #1 TJ7 3 g a Silica gel 7J? / 9 g H--- TffVi Inplnger #2 gg>-7_l P7 4 > --a^.-g Total H,0 / Iapinger f55*5 8 ^3 --^ N - 75, 7 g >./ZCcS 2*?7*"T _ / 2^5 Bottle No 810017 No'. Bottle No. Gross filter wt. Avg. gross wt. Tare wt. Particulate wt. ng Gross blldwt. ng Avg. gros ng Tare w t Blank''wt. Date Tina Rel. Hun. Analyst '8 /1 /n/f4 12e>0 1222 Particulate wt. Blank wt. Weight of particulate on filter _ng Acetone Wash Beaker No. Mis used 11 Blank Beaker Mo. Gross wash wt. Avg. gross wt. Tare wt. Particulate wt. ng Gross blk wt. g 8 Avg. gross wt. ng Tare wt. g Blank wt* g ng *g ng 8 Date Tine Mis used Rel. Hun. Analyst Particulate wt. ng Blank wt. ng Weight of particulate in washmg Total particulate on filter _____________ ng Total particulate in acetone washng Total particulate Total Ha0 _____________ pd FIELD SAMPLING DATA P/2* PLANT A LOCATION ASSUMED: Z H,0>. > :Tj?*F 3 Bay (yf'A' <*Pb* ** ^ 7tf-*** --____________________ ----------------"y- ^ DATE: TEST NO.:/FVg/r-; LEAK CHECKS EQUIP.: Mva./Z^U.......... MEIEt BOX HO. */ INITIAL % FINAL ID /*. 99f A Ha: 2^CO _ SAMP. BOX NO. /?- */ TRAIN: |P* PC/..* OPERATORtfjf ______________ PITOT: IMP. PITOBE: NO. /^ NOZZLE: NO. / TYPE X Cp >-f*/ ID, In.ftJaP? Ft*/ ,-0*/ WAKE FIELD METER CHECK STACK: DIMENSIONS AREA ^ lXS'*/ Ft* 7-*/ *< 63 _c*c K r A P REF.: / <^7 C FACTOR_ Float act / / SL 025722 TUt la. Clock TIm HDattoyrC.mCF P1a0it,or1t .0 /Tp 0 5D&.U& \.ao r SoSMf \'} /> BOQ.Tpo /r l.-WS" la* .T3\4ao us 3o *a.C lea \.Xr, jlftAeS .< Vb |.oS yr /./^ r 910,010 /,/5 ,fT >13-too- /. IS 5p.i03 1*05 S5i.ii3 l. 05 Wh.md l,of 7/" jss.1 p.'l aPo $6/.*33 # 13 5ts.no 0,13 */> Hft.Lrf D,7f yr 57/-741 0.77 /oo 37H.W r^VJo. Orlflco InA 1.0 9rf Cm twTo> mM-.oamtJ u"S Com gocp Tofm. T1m1o"fm1*** _ Stock Pimto1m.0. Stock ToPm. I.8S Si 6-d 48 -0^1 6 (a t.^o nt ... Ip*V Ml lAo UA *K? *0 1<V> life L cs we 41 -OHS (c( IAO ne 6x HT \.So It* tfl 2SH_. H7 u A* 6-a a? 4? l.7o u <W U*o *54 4(a US 1. Uo 190 <4 la-d ?S4 Ml /`7.T' /z# <?r Co -o.Vo <r /*7a7 ftf 17 6< *75 /3^ 7* 4( A5 V7 /.*/ / 7/? *t7 -ft 37 /4/ in 11 255 Mf /w n 5 *t7 itf ill 11 5 3 a^s V5 *0.33 IS ;.w3 171 It *3 a5o ^//! Mi 111 10 5 3 as V.4 /. 21 1/1 1* 5.0. M* -nia /2I Hi i& 50 25{ 1L in ILL._1L 5 o iiL 0:30 vx* T-dA?o*s2.:-31C7`/79/ w Ft*(Dry) dditi nil Coainci: /.i/Tfc e>iJtb P55a fahiba- J. SJ <9? 9- - / SL 025723 * WC % P*a aPr*baa--^-- C?. 39 gl^<O.Q """wHh*ci ;5 tTa. -- _5*25"__#*H Date D:31 PARTICULATE data sheet Test No. fr*/ - 2- pun INDUSTRIES #1 h28,2 g 8.a g #2 iya.o I 1^ Imninger '3 6*5 / x wjtZi t 3 g Silica gel No. 76?. 4 _g 7___ 8 l v *___ % Total Ha0 Filter No. Bottle No. 3J 1 Blank No. (,*, 3 c.t * TC/ /CX? ______ Bottle No. ______ Gross filter wt. Avg. gr ss wt. Tare wt. Particulate wt. mx Gross blk wt. mg mg Avg. gross wt. _mg Tare wt. mg Blank wt. Date Tine Eel. Hum. Analyst i img U/ll/lt /SO*9 &2L i ja'*g* (i/ii/k mo Particulate wt. _____________ mg Blank wt. _____________ mg Height of particulate on filter mg Acetone Wash Beaker No. __________ Mis used Blank Beaker No. Mis used Gr ss wash wt. Avg. xr ss wt. Tare wt. Particulate wt. mg mg _ 8 mx g Gross blk wt. Avg. gross wt. Tare wt. Blank wt. Date Time mg mx mg B mg Rel. Hum. Analyst Particulate wt. ____________ mg Blank wt. ____________ mg Weight of particulate in wash mg Total particulate on filter T tal particulate in acetone wash Total particulate Total H>0 -------------- g --------------- g ----------------pg ml SL 025724 # 0:32 ORSAT ANALYSIS INDUSTRIES Test No. Sample Location Q- Date Aflk.r ^crJAarSlefonalyzcd bv OJ * VA^WylT Sample Type ______________________ Volume (30 L minimum) . Time (4 hra. max. after sampling). Orsat Leak Checks (Mandatory) Before Ot.__________ After ______________________ Orsat Test No. 1 2 3 4 5 6 AVE. + 0 cJQ.1 CO o o -Ji2_ n' H'Tu *3"-- a^JL^yr -? <j % n ,1& o'*5 SV 0:33 FIELD SAMPLINC DATA 3V*l0 ASSUMED: Z H,0 g lEJr MOUSTMCS _:Tt.*F 6$ P, In. WG METER BOX HO. ZP"/ LEAK CHECKS IHITIAL _Jl * D, 94,98A OPERATOR jlU _OQ_ SAMP. BOX HO. ^O,______________ PITOBE: HO. /Xf g TYPE_ c aJ></ ^ NOZZLE: NO. /____ ID, in. bJ2%it'Jdj!. TRAIH: Ml PITOT: IMP. 53 *< y HAKE / FIELD METER CHECK STACK: DIMENSIORS /?/ , AREA 0, IfS'7 Pt* FINAL 3 Ok K or A P KEF.: C FACTOR FliM Tut I*. riMt fb\t 0 <71^* T1m HMty*I.nCF Kla4t.MtlaO /T* nr LYiffao Q"71 0-845> /y> 6W.fe23 O4rif1lM -TSo i5% te. g /PI nt 4t> f*l-S4 IOC 5L0 VlUar ttmf , nf* 24 7 frtaaacak. TVflp* vrK i*W -.03 , f i a _ -- V* - Z/Tfc OA9SO x TdO.<?C^8 (;/ZpS)* o.Wco - l3L2fe*l_^**y> ddielonal Coxmiics: X tm 1 S4 X Pb - O.U h *- SI'Sl r *VC P - "HC "Hx s Pa * -- 0-03 "Ha "fc P xbx^ 2*1- U7 "Hx A : T* ToH *f i Tl 5^ SL 025727 D: 35 Dice ^7, dl.H > 125./ s ^ ^____ 8 Silica gal N .Itt 5 _g -- /I .*/ _g % PARTICULATE DATA SHEET INDUSTRIES Test No. Imoinger i^ _8 #2 "CT"_g A. 3 _JB Total HtO ___ H 1 Plant! Impinger C 1*0 13 hO/.f _____0*? -ST 8 8 8 Filter No. Bottle No. Blank No. Bottle No. Gross filter wt. Avg. gross wt. Tare wt. Particulate wt. mg mg g . g mg Gross blk wt. Avg. gross wt. Tare wt. Blank wt. Date Time B s mg /2//5//i/OY5 * * *R t2.hr/ti HOO eg ' Y Rel. Hum. Analyst V%- Particulate wt. _____________ mg Blank wt. _____________ mg Weight of particulate on filter mg Acetone Wash Beaker No. ______ __ Mis used Blank Beaker No. Mis used Gr ss wash wt. Avg. gross wt. Tare wt. Particulate wt. g Gross blk wt. eg Avg. gross wt. eg Tare wt. 8 Blank wt. Particulate wt. Blank wt. Weight of particulate in wash _*8 _*8 mg Date g mg mg "mg mg Time Rel. Hum. Analyst Total particulate on filter Total particulate in acetone wash Total particulate Total H,0 mg mg . mtt ml REMARKS: O.i 7o 9 <! A** V .i ZUiS to8> SL 025728 A.'--* *0 .<- y '& 4aoa (a**} v^~l .ISA ^ rH I JI,'KV f 0:36 Eft ORSAT ANALYSIS INDUSTRIES Test No. Sample Location Dace 1 9- " ^cruVWL&*cX-Analyzed bv M Sample Type J^eyoici) Volume (30 L minimum) Time (4 hra. max. after sampling).. Orsac Leak Checks(Mandatory) Before d>*C. After Orsac Test No. 06^ 1 2 3 4 5 6 AVE. CO? 09 CO ___H2. ni A A. 3' ** 0030 SL 025729 - 0:37 PARTICULATE HUSSIONS SMffUNS REPORT r PLANT-NAME AND ADDRESS TEST TEAM LEADER t4ff CHARLES KURYLA t TEST I 84CM TEST : 9<fp-: ( TCST 3 WEI-3 RUN WRIER ( TEST DATE 1 12/12/84 2 12/12/84 3 12/13/84 c T TIK-START TF TIIC-FINISM n NET TIIC OF TEST,MIN. r nr NET SAHPLIN6 POINTS 903 1103 120.0 S. 1338 1530 120.0 t. 810 1010 120.0 I. DN SAMPLING NOZZLE DlA., IN. o.m 0.119 0.109 CP PITOT TUBE COEFFICIENT 0.84 0.84 0.84 < PH AVERAGE ORIFICE PRESSURE 1.40 1.59 1.54 MOP. IN. H20 VN VOLUC OF DRY GAS SAHPLO 12.353 82.771 79.344 CU. FT. AT METER CONDITIONS TH AVERAGE 6AS METER TEIT 102.5 104.0 100.0 MtSTU DEGREES F VOLUME OF DRY GAS SMTIED 77.399 77.180 74.542 AT STANDARD CONDITIONS*,SCF c Ml TOTAL K2C COUECTEI IN 34.10 32.10 29.90 IMPINGERS 1 SILICA GELiH. MU' VOLUME OF HATER VAPOR 1.405 1.511 1.407 AT STANDARD COMITIONSt. SCF i PHU PERCENT MOISTURE IT VOL. 2.0 1.9 1.9 FHD MOLE FRACTION MY BAS 0.980 0.981 0.981 fco: PERCENT C02 DT VOL..IRY 0.0 1.0 0.0 ( P02 PERCENT 0? DY VOL.,HIT 20.10 20.90 20.90 PCO PERCENT CO IT VIOL..MR 0.0 0.0 0.0 PIC PERCENT 1C IT VOL.,MY 70.20 79.10 79.10 ( FUND MOLEULAR NT-DRY STK GAS 28.83 28.84 28.84 FNV MOLECULAR UT-STK GAS 28.41 28.43 28.44 PD IAROHETRIC PRESSURE* IN. H6. 29.84 29.79 29.70 V PSI STATIC PRES OF STK GAS IN. US -0.44 -0.39 -0.44 IN. ICO t \ PS STACK PRES,ADS. IN. HE. 29.804 29.741 29.448 T$ AVERAGE STACK TEIT. KB. F 45.0 45.0 44.0 IPS SO OF AVE OF SO ITS OF DELTA P S 1.0420 1.0340 0.9950 STACK GAS.IN. H20 VS AVE STK GAS VELOCITY.FFS 57.52 57.38 54.24 AS STACK AREA.FT. SORD 0.8 0.8 0.8 OS STK FlOH RATE.IRT.DSCFM 2440. 2453. 2400. QA ACTUAL STK FLOU KATl.ACFN 2710. 2704. 2451. PERI PERCENT ISOKINETIC 97.8 97.8 94.4 W 4` . -L-_. ` SL 025730 ./ I n PsJ' I l* LOCATION* 0:39 FIELD SAMPLING DATA Sb2J?,6? U4 ASSUMED: Z H.O:T..*F Pa* in. VC lUt mdusimcs . TEST HO.: r^/v- ^ LEAK CHECKS EQUIP.: MFG. iD 0.1tn! i OPERATOR _ METER BOX HO. sakp- *" /U//' ^ INITIAL k PITOT: DtP. FINAL H PITOBE: HO. >t//yW Cp__________ HAKE _ ----------- NOZZLE: NO. ID, in. Ft* ^________ FIELD METER CHECK STACK: DIMENSIONS , AREA Ft' K or A P REF.:______ C FACTOR pimc_____________________ rc n. Data Clock Dry Coo TIM Macar. CT j2_ G24Z/2. Pita* AP f- o /o Oil .Uo ?rO fltyO.OSO 7<? TiS73 OS/.flo m rt> si^ui o 0C1.1SO 4*- mm fn IH.llS 9n iO.lOo fetio /Dp //2/&^ USio iW -i co.7J *6 / v/ KS ^ f/ rf7.Ml y\ r~ 90* _> 0 *> Or&flca I Dry Cm Pom TtM At 1 Tom-* *K- -U. c to M M Aw*^ Cmm O./r 7 70 3 o.l 1H 11 .? 0.01 7: 7/ b01 71 It o1 10 11 3 j o t__ 7# 3 3 iMia* Plica* l tm. TMp. f P Stack Pimtm1s.0. Stack Tom. P o. 1 7P 0.01 tb 11 0*1 11 7? 3 3 3 o.o? 7? 7? ? o-oi H 1L \1 r Afjb V i-C u/> 7G# 75 SL 025732 L 0 o7 /7.7 9 n.rii 1 1 --------------(7/ dJ J40 -- . Xtoc - ^ r a> i / /f/= > < nt D:40 T1m #ry Su Hmc Af /r* OrifftM aa A*7 t-*.. _ _ In. - VAUW aJr w % i 1W * - Vn x Td - Ft* 5/^ Ft*<Drr) ddlclooal Coanenta: - t -- 1 *1 * i F* - iia- *- *VS V F* "b ;Fi"It Fa abiF SL 025733 ; Ta 5 Ta - **UG "h* "Ha * ? 1 JV /=v-/ Dace /yj/Z, f 8</ 0:41 PARTICULATE DATA SHEET T.,t NO. ??/ PLS--L fU 10 CJU<- tu Impinger #1 5'C-J* ^ g * Silica gel No. _______ | MJ ,,. _8 _8 _8 Impinger 12 Total H,0 O /7. 7 g l 8 Inplnger *3 <5 (0 ^ g 8 JR /oo 0*1 M ZFC/ Filter N . Bottle No. / / 2^ 3 / BlankTNtf; _ loccle No. Gross filter wt. Avg. gross wt. Tare wt. Particulate wt. mg Gross blk wt. mg mg Avg. gross wt. mg Tare wt. mg Blank wt. Rel. Hum. mg -------------- mg mg mg (*//<* no _x&&, mg Analys Particulate wt. Blank wt. Weight of particulate on filter ________ mg g mg Acetone Wash Beaker No. ___________ Mis usedBlank Beaker No. Mis used Gross wash wt. Avg. gross wt. Tare wt. Particulate wt. mg mg mg *8 __mg Gross blk wt. Avg. gross wt. Tare wt. Blank wt. _ mg mg mg mg g Date Time Rel. Hum. Analyst Particulate wt. Blank wt. Weight of particulate in wash mg mg mg Total particulate on filter _____________mg Total particulate in acetone wash mg T tal particulate mg T tal H*0 _______ P1 REMARKS: -P /Jc 02573'' SL 0:42 FIELD SAMPLING DATA /Q 2- MONIES ASSUMED * * H.sSfcl-jT,f*F________ 0 TEST NO.: MP^ Pm, in. WG LEAK CHECKS EQUIP .: MFC. METER BOX MO. 6. n9?^/j//1jld^/* ALJiUhi:-t--i---L---- SA_MP. _BOX BNOX NO. OPERATOR PITOBE : NO/^-- TYPE Cp *" NOZZLE: NO. ID. in. Ft1 STACK: DIMENSIONS . area INITIAL % TRAIN: .pots' fr/9" FINAL tOa/G. 7 PITOT: IMP. ________ ________ ________ WAKE ___ ________ ________ FIELD METER CHECK Ft* K r A P REF.:______ C FACTOR nut Tut It. at* /z s'3 i^sr Ctdock try 6u tlM Naur. r> Tfjs-t nut AP U. 1.0 /Tf Oriflea A la 1.0 Dry Taap.. *P tv*. 7F Xa. || ? /Q- /'''S' ui.ST) A oJ 7< 7* ' ^ 77 So a. on 7f ? Va t/i.nc .r?> U5.HS Jju tuns a ft n ft-.fc ? 6i97 * 3 $/ 3 1 Q,V7 $* ex 3 7ft l3iJU* 1*3- 330 1,47 R3 8* 3 Q r 01 8i 93 3 J2n_ iSiiiiwjji $.07 &t 01 ,? 0.67 Si O.i 3 0.07 8+ 83 3 PUtar taap. f Iapl*~ 1" Taap. P - Stack Stack Praaa. Tea. la l.o "w" i-1.. r J 67,*//o jlmu /?)( 41 aMig /* waTf*lTrfl AV- | */7^t / > X oo P?l>>.< * / o^ T*- A ' cjL 025735 s. jfZL^O 276 X2 J21L 7ttt: 1 > . ^ r J*'0 --7-^ * ------------- \ ******* tint. TMt It, 0:43 v* - Ft* 5/T3C x Td <s/*p=>- - Ft*{Dry) ddltlonal Ccwcati: SL 025736 5* ;fi aba- "ME Fl> "h S Fl % P abl^ ; t ;tm "WG "Ha "H *f *r Jsis wr D:44 PARTICULATE data sheet Is/*/------------ Test No. Dace f 2* P\/~7^ n sci.l___ 3 L. 0 3 Silica g 1 Lit* 8 No. ___ 8 __ IaA. 8 Impinger AIL 1#2 T3q 3 3 Total H,0 JO / 6 O. //* Filter No. Bo Blank No. Boccle No. Gross filter vt. Avg. gross vt. Tare vt. Particulate vt. mg Gross blk vt. _ s mg Avg. gross vt. mg Tare vt. mg Blank vt. Particulate vt. Blank vt. Weight of particulate on filter 8 8 mg Dace. Time Rel. Hum. Analyse . "8 U=ilalMJl* _________ _________ ms mg , L) - - "8 Acetone Wash Beaker No. __________ Mis used _ Blank Beaker No. Mis used Gross vash vt. Avg. gross vt. Tare vt. Particulate vt. 8 8 *8 . *8 mg Gross blk vt. Avg. gross vt. Tare vt. Blank vt. 8 mg mg ....... *8 mg Dace Time Rel. Hum. Analyst Particulate vt. ____________ mg Blank vt. mg Weight of particulate in vashag Total particulate on filter Total particulate in acetone vash Total particulate Total H,0 8 8 jag ml REMARKS: /A *W-mA~7 SL 025737 PLANTv4 LOCATION D:45 FIELD SAMPLING DATA ASSUMED: X H.O r j/f 7? INOUSTHIES ^T* *F_ ------------- !---------------- Pn, in. VC yjaU- TEST NO.:. JWPtS-1 EQUIP.: MFC.J&C-------- r METER BOX NO. FINAL *p6. 7fr> <___ * Hg sJ</OPERATOR us. SAMP. IOI NO. 7&- --/ LKALai no - ^-O zs*..ooi ff i` _______ -y=LJU PITOBE: NO. TYPE VAKE NOZZLE: NO. ID, in. Ft1 FIELD METER CHECK STACK: DIMENSIONS , AREA Ft* K or A P REF.: ____ C FACTOR riMc Tt a*. Bat* SL 025738 flMt Tmc , Mm d*ck Dry Om a r TiM *m. _er m OrlflM A *5.% ) 2T5 bfi** Mim ta*. kMk JP t * - ' Vb - x Td - Ft* (;/^)a Ft*(Dry) Wddltlonal Comnti: - * - ------------------------------- r i IF*- ; Pi * fi tb&* "HC Fa - **Bx ;? "i Fa aba^ SL 025739 ? Ta ; Ta "WC "h* "Ha *F Dace #1Implnger saw . __SLnPa-A_____8g Silica gel _8No. ___ (,61.0 (H^-% 0:47 PARTICULATE DATA SHEET Teat No. Pl/S Plan INDUSTRIES Implnger ____ g >-- - ^ > 8 Total H,0 77 'C* Implnger #3 SAC-I % C> ' ___8 Filter No. Bottle No. Blank No. Bottle No. Gr ss filter wt. Avg. gross wt. Tare wt. Particulate wt. mg Cross blk wt. mg mg Avg. gross wt. 8 Tare wt. mg Blank wt. Date /Tine mg mg mg mg uhs/ii mo mg Rel Particulate wt. Blank wt. Weight of particulate on filter mg eg mg Acetone Wash Beaker No. __________ Mis used ______ Blank Beaker No. _______ Mis used Gross wash wt. Avg. gross wt. Tare wt. Particulate wt. mg mg mg __mg mg Gross blk wt. Avg. gross wt. Tare wt. Blank wt. Particulate wt. Blank wt. __ Weight of particulate in wash ___ eg Date Tine mg mg mg mg 8 Rel. Hum. Analyst Total particulate on filter Total particulate in acetone wash Total particulate T tal H*0 8 8 J8 ml REMARKS: SL 2S?4o APPENDIX E Analytical QA and Results, Emission Calculations and Chain of Custody 0257*1 CHEMICALS 9 . J. P M 141 INDUSTRIES E:49 INTEROFFICE/LAKE CHARLES TO I. A. Ruryla FROM M* G- Carver DATE SUBJECT Dec. 20, 1984 Hg Analyses Attached are the results fron the analyses of the saaples obtained while stack sanpling the Mercury Cell End Box (EB) stack and the Purasieve (FORA) Unit. Also included is the calibration curve data and spiked recov ry analyses. It you have any questions concerning these data, please call, ce Attachments cc: M. W. Wood W. H. Cooper H. J. Hoenes K. s. Konoroski SL 025742 MERCURY ALYSES DATA FROM DECEMBER 12 fc 13 E:50 STANDARDIZATION Hg tactual) (ug) Hg (analyzad) (ug) i SPIKED RECOVERY .! DATA * Sample Hg spiked Hg ree. (ug) (ug) X rec 1.0 0.80 0.60 0.40 0.20 0.00 0.89 0.68 O.SS 0.38 0.18 0.00 PURA-2 EB-2 BLANK 0.88 1.02 0.00 0.88 0.97 0.00 100 95.1 -- SAMPLE ANALYSES DATA - RUN ID Hg (ug) - PURA-1 PURA-2 PURA-3 EB-1 EB-2 EB-3 < 125 < 125 1450 525 1430 525 " SL 025743 ACTUAL -VS- INSTRUMENT RDING Coleman model 00 RBADIMO ( U |) C'W'Vtt v.3/ts/7t BARBERTON TECHNICAL CENTER 1:52 V.......... f ............................................................................................ ...... .... i...........>.....\.....i.....i.....i..................................... *..... *.....*..... -i.......... *...........I...........`........... i...........I* *1--..................................... * * *J * . ........... . 4^. .......... |...........i........... ......................................... {...........*........... i........... -...........*;------- ....... . M* ,... . .....i..... i. ---*-- *''****** Xu-, s*. !3-r.7 7 - k.... J*.3? :.... ......vs^ 0^57 om c>n-*ia wv.3/is/71 lRBERTON technical center Barker! a, Ohio 3 3 4 5 * 7 l ; ) 1113 13 14 1$ H : 17 It It -30 31^33 : 33 ; 34 35 34 : 37 :> :3V : 30 : 31 :j: 'h 13 : .itr3i.tr:. 4 :::::::::: IS : r? ;e>rw j .........>* y^*i**"`>**-**f......-- *-f < **! ---} -- *!................* 4- - -- *<...... * - \9. / .......*-^*^* mok "<.......... r ........ . :% 31 3$ ' SL 025746 ***** /9:S3 J.lj.ifj Lj -#S ............V` oi /4p.fc .... CHAIN OF CUSTC RECORD bS: 3 eta SLii&>vStL,- JjJi2 4 ff / /V-/ 'S'1/,g^--g gV/V- 2-- ryC.5t^22CT z uiihed by: Wowa**/ Data/Tima ftacafwadby: tJnkklii* 7 Is I / ssiT/S Raliriquithad by: (SJt** ? PL/- *>UtX &I7Z2/Z2ZS Oata/Tima Raeatvad by: A/bwMM/ tuithad by: IStpnttyH) Crt t* uithtd by: Kbwiv^ o ro m VJ ______ JS DDaatatJ//Tima Raeaivad by: rtynnml Ralinquithad by: (S*t***n) Data/Tima Raeaivad for Laboratory by: dywim/ Data /Tima Ramarki Data / Tima Raeaivad by: (tbMiiw/ -55- APPENDIX F Sailing QA SL 2574S F:5G CALIBRATIONS * QUALITY ASSURANCE _*NRAL All measuring equipment PPG uses Is Initially calibrated before use. Equipment which can change calibration Is both checked upon return from each field use nd Is also periodically recalibrated In full. When an instrument Is found out of calibration. It Is so noted In the report and appropriate adjustments are Mde t the final results. The equipment is then repaired and recalibrated or retired as needed. Specific equipment Is handled as follows: PITOT TUBE All pitot tubes used by PPG, whether separate or attached to a saapllng probe, re calibrated using EPA geometry standards. In general, if a type "S pitot tube is assembled correctly, and positioned properly. In relation to the probe nozzle. It will have an average Cp of 0.84. As long as it Is not damaged. It should not change Its calibration. The recalibration schedule for pitot tubes is related to the physical condition and usage of the pitot tube, not a fixed time schedule. Pitot tubes are calibrated before each field use. ORY GAS 1CTER AND ORIFICE METER All PPG meter boxes are calibrated upon purchase and at least once every six months against a secondary test meter (one calibrated against a wet test meter) according to their usage history. Basic procedures are outlined In the EPA Publication No. APTD-0576. The only differences are In the choice of flow *tes used and the volumes metered at each flow rate. After each field use, :lck checks are performed to insure all changes of less than 21. These checks coopare the orifice against the dry gas meter. If greater than 21 changes cur, recalibration and repair are instituted. EPA and PPG Method 5 audit -rile s are also used In the field or at the laboratory. NOZZLES Each nozzle Is calibrated upon purchase, and thereafter whenever It becomes apparent that the nozzle has become damaged. Each nozzle is inspected upon return to laboratory from each field use. The diameter Is measured on four different axes, with the high and low readings differing by no more than 0.004 inches as a tolerance. !EWERATURE MEASURING INSTRWCNTS After each field use, the thermocouples or thermometers are calibrated against 4n ASTM precision mercury-in-glass thermometer across a wide range of temperatures. If the Initial reading Is not within 1.51 of the absolute temperature reading of the standard thermometer, the Instrument is adjusted until it Is in the acceptable range. $1 9 % F: 57 WAGMEHELIC gauges Aft r each field use, each magnehelic gauge Is calibrated against an Inclined nanometer at three different settings (low, medium, high) over the range of the individual gauges. If the readings differ more than $% from the monometer readings, the magnehellcs are recalibrated. BAROFCTER After each field use, each barometer is checked against a mercury barometer. SPUME ANALYSIS ??G Industries, Barberton Technical Center, actively participates In the EPA quality assurance audit program, i.e.. Methods 3, 5, 6, I 7, 0^1$ SV \ irroet u. itm i, ihhi m* miMtim t. f. I. HI )| IMIlltM, *ir - oc* 0 ' uxuc mui it* it* MtUHilHtTNI f V#* tnnM < lIKt tM 1 NlUfMI - IM tU Mlltllt IKMltt sitBfjii mu e,it t.nit O.Ntl, It* - (IKK *tt* .{r*.mn. D.IHI O.tIH r.tIM ti!tui.uiiftiitt .1 ... * **S *m 'ft SL 025751 I1700* NO. LfNN 0. MU ' P> ** MPK KMItlllt IOC. MlliTWt M *4701 fill * 00) tsifis* MRU! II* *1* II* ynip^f F:59 cr:? itw Minn < ii m t MuyMM IM Mill (Wit NT*t IfSMJU IUII 0.7)** 0.1)** B.7)* .UMIIK. .!*M 0.1*1* 0.7*1* UltllLUlUIUU *. :J 1*'K3 o> SL 025752 I N*1 S 5? f ' |H-f- H1 1 Ml:. METCK COX IDENTIFICATION:. prm s/a) e$3(f n &UJ/ ** .CAUIRATION MUCK IDENTIFICATION: JSLiZZ0C- in CM ain , lAKOMCTRlC fRCSSURE tl- 29.V PB 99 to. K| AFfROXIMATC now RATE IB) tot .53 ,91 /<4 P ORIFICE READING 1 AH 1 to. HjO 0. 0.4 /C 3^ CAUIRATION METER GAS VOLUME iv<,l H) METER COX METER GAS VOLUME IVi H> 4.C7V- s.i^L L.113 9/77 5.54* 7.743 4.77/ .Um4- TEMFE RATURE CAUIRATION MITER METER IOX METER INLET OUTLET W f (W) f 74 J 75.7 77 74 77 76,7 n% 77 7? 77.7 average (lit) *F 74 74.r 7^.y_ 77.5" 77. 4 INLET M *F OUTLET Hit) f AVERAGE *F 7f 96. S 7U /0&.3 /d,7 TIME W) ato. /AAA /AA /0.AA /AOA /#.AO METER IOX METER COEFFICIENT (Vi ^751 .$777 .979* 1 (OHO) 474 /.!? /tf? /.f? 7TT- 196 f TvT i *fk %/ oH AH AMf . ------------- |-- --------- 1 % fli * 4M) v*cT V|, rtrf * 4*0) 'fit v< . 410) (Ffc . *j| WHIM: AHf ORIFICE FRESSURE DIFFERENTIAL THAT CIVIC0.75lOF AIK AT TO* F AND 2I.IE totfcft OF MERCURY,in.HtO. TOlCRANCI 10.IS TT'-'i , ! 1 tTTT : r r-'T-;- i*i * / ^'9ufe 4- 6**ntple data ibcct lot calibration ol meter box gat meter againtt a calibration drv gat meter (Englith unite). i 6vvvvv*^>- 'CtJC/ CtJX&K+Hv* A-t. . tLl/S'J WC/9*V AU4^L<| 0^-l-'X. A^-^'LS' * y -5 Motor lot Hwtlfttitloi> 0M Calibrated bv; tAV\pHk^ _ jr> Dedicated OGM S Point Sol rootUr , Collbrototf by; __________ 0ete:_JLkJfe3__________ IoVIqt________ Calibration Motor Identification Tdt Poto; laroaetrlc Protiure IP^I: Afl.^1 In Hg Approilatte Flow lato (01 cfa OH flea loading (OKI In KjO . O.S Calibration Motor Cat Voluae V ft3 ('U*.mo MMk Motor Ion Hour Pat Voluae ft3 41. ILL . i\ .ifc-i Temperature Calibration Motor i Meter lot 9 oUr Inlet Outlet Average Inlet Outlet Average ,tdf1 *W <*dt> <`dl> ltd,* v *F *F F F F *F *1*L M ' OL iL tir Inti /al At q*4 all i. /. TTTB" qrin 'K IS *n 11 it w Hi. <i** loC tn 4t. 107 * l.i w n 74 S4 Ilf TOOL 111 w i iff io IL? '*! .ML -JCMB *11 7Lm 115 lo> 116. .Oft! 1 T -- n "L llo IAL i/L Tine (0) atn. 10 io IA 10 Motor Ion Motor Coefficient u UHt) 'O.TIT3W 1vi-y- TFT.V -- 6,oi "T^ST emei i.li IO HV iaH V krii -kAfl \o WT?K*7+ r^i3B r*i- L i________ 15 A.QvtlA IO i.W I.CB r1 B.1M "B3BC 75 OArt IJmT 'll n iLVl *IO ion in ! 1 "STBS" o-iliM o to <J7 1.0 ^.o o.oi4" L' P tit uarHn ' 4V ri 7L 14. I3C 1M 41 "1X3! MO Mi to o-ino 0.01 A.0151 5.01 (ji 1 l*oAifo *r*-.*i ** F:60 ah# . * Pb(ttf * 4601 d|(Td*> * , .t !ii. JSLi22-----------d Itd, * 4601 ,,b , *M#) UHCRE: *M0 Orifice Protiure Differential that give! 0.7$ da of air at 70*F and 29.92* of aorcury, In HgO. foloranco *0.1$ Hater let Identification *5^3 Calibrated by: fo.X^rv^S Oate:_ 1-a.vw Dedicated DCM S Point Splroaeter Calibrated by: ftwtx<toia Calibration Hater Identification Barone trie fretture (Pfcl: Data; tdi OS In H| -a- O.OnfQH %ltd 60) f^lTdt) * ltd *601 Ud( 0) AH t <Pb * n.i' MKttt AH# Orifice Preswre Differential that jive* 0.75 cfm of air at 70*f and 19.91* of nercury, In HjO. Tolerance *0.15 F:62 iompany Name: TPa. N. PITOT TUBE INSPECTION DATA SHEET Pre-sa*>le . Oate H hl /8-t Post Sample Oate t-3-& YS NO NO * r r o' / _ O' /* 0.815 o. **0 o. *t .37* 0 level? obstructions? damaged? -10* < a < +10* -10* < oj < +10* -5* < Bi < +5* -5* < B* < +5* T*S bo o,, 3 o' o' . I* Y 8 of A 0-fi>u 1.05 Ot < Pa < 1*5 Ot 1.0S Dt < ?b < 1.5 Dt 3/16" *4 Ot '< 3/8" 0*4^ 0.4-1* o.vrs A tan y < 0.125" o A tan 8 < 0.03125* O Pa - Pb t 0.063" Counts: * SLIGHT MtAe* ^7>nc of fUgf FlLf> 76 SMOQ*H*tCSS pitot tube/probe number / meets or exceeds all specifications criteria and/or applicable design features* and is hereby assigned a pitot tube calibration factor of 0.84. ** Signature Date _ n/n/H u. <s cm u. m. *o. *** i. Kk MtlMt *r IM tktn(Ml< M ** If* gratia* kiUN* * k'ut tx6 Mt tt tilt u* %m * tkii m*. 'Vfc+L*- SL 025757 *