Document N2RR18oe7RQGM0eD8ov5VwN0R

Tenneco Chemicals A Tenneco Company Turner Place, P.O, Box 365 Piscataway. New Jersey 08854 (201 ) 981-5000 February 12, 1981 Mrs. Sonya Shashoua New Jersey Department of Environmental Protection Solid Waste Administration 32 East Hanover Street Trenton, NJ 08625 Dear Mrs. Shashoua: Per our recent conversation attached please find: 1. Copies of EPA Test Methods 106 and 107, for the determination of vinyl chloride monomer in air and residual monomer in slurry, wet cake and latco; samples, respectively. As I indicated, these methods are selectjvc to vii chloride, and were developed by EPA with regard to the NESHAPS Stand,aid on Vinyl Chloride. The copies were taken from the EIC publication, hut aio available in 40CFR 61, Subpart F and the October 21, 1976 issue of the Federal Register. 2. A listing of the major raw materials used in the resin plant which could reach the landfill. Included are the materials for which analyses arc inn as part of Dr. Marvan Sadat's sludge quality assurance program. Very truly yours, TENNECO CHEMICALS, INC. JPS:mm cc: Mr. F. W. Kanzler - Burlington Manager - Environmental Affairs COLORITE 017042 Hazardous Air Pollutants-VC July 1977 Rea 161 P-- Frodiu-tion of grade G, refin represented by the Pimple, in kg G,= Grade of resin, e.g., Gi, Gj, and G>. n " Total number of grades of resin produced during the 24-hour period, _ __ ____ ____ fvl) The owner or operator shall re tain at the source and make available aampllng personnel to vinyl chloride, a car cinogen. 1. Principle end Applicability- 1.1 An Integrated bag eample of atack gas containing vinyl chloride (chioroethene) Is subjected to chromatographic analysis, us ing s flame Ionization detector ~"i.2 The method ts applicable to the meas urement of vinyl chloride In stack gases from ethylene dlchlorlde, vinyl chloride and poly vinyl chloride manufacturing processes, ex 4 3-2 ChromctGraphic column Stainless steel. 2 mxif mm. containing 80/100 mesh Chromasorb 102 A aecondary column of GE SF-06, 20 percent on 60/80 mesh AW Chroma, sorb P. stainless steel. 2 mx3-2 mm or Torn, pak T, 80/100 mesh, stainless steel. 1 tux 3,2 mm le required If acetaldehyde Is presen', ij used, a secondary column la placed after tin chromasorb 302 column. The combined columns should then be operated st 120* c, 4 3 3 Flow meters 12)--Rolnmetcr tvpe. for Inspection by the Administrator for cept where the vinyl chloride is contained In 0 to 100 ml'nun capadtv. with flow ccmiot a minimum of 2 years records of all data oartlculate matter. valves needed to furnish the Information re quired by paragraph (c) (2) (v) of this section: The records are to contain the following information: (A) The vinyl chloride content found In all the samples required in paragraphs <c> (2) (i) and (c) (2) (il) of this section, identified by the resin type and grade and the time and date of the sample, and (B) The corresponding quantity of polyvinyl chloride resin processed by the stripperfs), identified by the resin type 2. Range and Sensitivity 4 3 4 Gas regulators--For required gas The lower limit of detection win vary ac cyllndei t cording to the chromatograph used Values 4 3 5 Thermometer--Accurate to one de reported Include 1 x 10-T mg and 4 X 10-` gree centigrade, to meosure temperature cl mg heated rumple loop at lime of sample Injec tion 3 /nfer/erences. Acetaldehyqp, which can 436 Bsromeicr--Accurate to 5 Tnm tp occur ID some vinyl chloride aourcee, will In- meMUre Atmospheric pressure around got chloride peek from Chr0matntiraph during temple analyst* the Chromasorb 102 1 column. Gee aectiona 43.7 pump--Leak-free, Minimum capae4.3.2 and 6,4 II resolution of the vinyl Jty J00 mimln chloride peak la still not satisfactory for a 44 Calibration particular sample, then chromatograph pa- 4,4,1 Tubing-*--Teflon. 6.4 mm outude rametera can be further altered with prior diameter, separate pieces marked for each and grade and the time and date it approval of the Administrator. If alteration ^pubrallon concentration represents. of the chromatograph parameters falls to 442 Tedlar bags--5ixteen*lnch square (3i The owner or operator shall In clude in the report a record of the emis sions from each reactor opening for which an emission limit is prescribed in I 61.64(a) (2). Emissions are to be deter mined in accordance with S 61.67(g) (5>, except that emissions for each reactor are to be determined. For a reactor that Is also used as a stripper, the determination resolve the vinyl chloride peak, then aup- sj24 ^cpaiaie bag marked for each cMibra* plemental confirmation of the vinyl chloride l|0n concentration peak through an absolute analytical tech- 443 syringe--0 5 ml. gas tight ntque, such sc dub spectroscopy, must he performed. 4 Apparatus 4.1 Sampling (Figure 106-1). 4 1.1 Probe--Stainless steel. Pyres glass, or Teflon tubing according to stack temper 4 4 4 Syringe--SOmI. gas tight 445 n.eicr--Rotameter trpe, 0 to Jfioo range accurate to tv mder ftitroi.cn in prep.u anon of stands-'d f rml u: < - <4C ttjitrh--Of it.own accuracy, to ature. each equipped ujth a glass uool plug li"ir p'>. flo-*- in preparation of standard gas may be made immediately following the to remove part irulatc matter ini\ nrc*> tripping operation. 4 1.2 Sample line--Teflon, 6 4 mm outride l U `5 ncce r^ry that all rea- diameter, of sufficient length to connect g-- * ? be of ehTomVsCgraphic grade. 8 61.71 Recordkeeping. (a) The owner or operator of any source to which this subpart applies shall probe to bnp A t\c*\ unused piece is employed *> 1 for ca**h srrle-i of bag samples flint constitutes b j ? li.i 'ira or nitrogen an tct____________________ ________ _ e`*rr. f'-r n n m.V.o.'rrnphic carrier gas 4X3 Male (2) and female (2) atalxUesa ft 1 2 r>rr*cr. g;jL---Zero (Trade retain the following information at the steel quick-connects, with ball checks (one * 1 T O'.vpeu g.v, nr Air. as required hy source and make it available for inspec pair without) located as shown In Figure ti'f' iifir (.t-- jr-ro grade tion by the Administrator for a mini 106-1, _____ ________________________ _______5__,2___C__a__li_b_r_a__t_io__n_.__U_s_e___o_n_e___o_f__t_h__e__following mum of two years: (1) A record of the leaks detected by the vinyl chloride monitoring system, as required by 5 61.65(b)(8). including the concentrations of vinyl chloride as measured, analyzed, and recorded b.v the vinyl chloride detector, the location of each measurement and the date and ap 4 l.f Tcdlnr haps. 11TO liter capacity--To options; either 6-2.1 and 6.2.2. or 6.2-3. contain sample. Teflon Ung^ are not accept. j y<7iyj chloride. MJ-j- percent- Pure able Aluminized Mj Jar tones may be used, vinyl chloride gas certified by the manuftc- pro\idcci that the rumple*, arc an.Vj.e:! turer to contain a minimum of 99,9 percent althlc 21 hours of collect ion. vinyl chloride for use in the preparation of 4 1 5 Rigid leakproof containers for 4 1 4. $t*ndard gas mixtures In Section 7.1. If the auh covering to pin'c'-t contents from mhi* gwn manufacturer maintains a bulk cylinder JlFhr supply of 99 94- percent vinyl chloride, the 4 1 G yeedle iaive-*To adjust sample flox\ certification analysis may have been per- proximate time of each measuiement. rft(- formed on this supply rather than on each (2) A record of the leaks detected dur ing routine monitoring with the portable hydrocarbon detector and the action taken {o repair the leaks, as required by i 61.65ib>(8>, including a brief state 4 17 rump--Lcnk'.'rce Minimum capac- gas cylinder prepared from this bulk suppiy. Jly 2 liters per immne The date of gas cylinder preparation and the 4 1 8 Charcoal tube--To pi event admi*- certified analysis must have been affixed <0 ion of >mvl chloride to atmosphere m wcln* ^ cyun<ier before ahlpment from the gas tty of samplers manufacturer to the buyer 4 1 9 Flow meter--For observing sample Nitrogen paj. Zero grade, for preps* ment explaining the location and cause flow rate, capable of measuring a flow range ration of standard gas mlx&uros of each leak detected with the portable hydrocarbon detector, the date and time of the leak, and any action taken to eliminate that leak. ____ ____ from 0 10 to l0 liter per minute 6-2-3 Cylinder standards (3)'. Oas mix- 4.i.30 Connecting tubtng Teflon, ture standards (60. 10. and 6 ppm vlnj] mm outside diameter, to assemble sample ehJorWe ^ nltmgen cylindete) for which the train (Figure 106->1). ,, composition baa been oerttiled toy the 4 1.11 Pitot luiic-"T\p* S or equivalent). manufacturer. The manufacturer must have (3) A record of emissions measured attached to the probe *0 that the sampling recommended a mtummn ahelf life lor each In accordance with I 61.68. (4) A dally operating record for each polyvinyl chloride reactor, lnclufiing pressures and temperatures. flow rate can be regulatrd proportional to cylinder ao that the concentration doe noi the stack gas velocity, change greater than percent from the 4.2 Sample recovery. Certified value. The date of gas cylinder prep* 4 2.1 Tubing--Teflon. 6 4 nun outside aration, certified vinyl chloride concentra- diameter. to connect bag to gas rhromato- tlon and recommended maximum shelf life 2. Appendix B Is amended by addir.g graph sample loop A new unused piece Is must have been affixed to the cylinder before Test Methods 106 and 107 as follows. employed for each series ol bag samples that ahlpment from the gas manufacturer to the Method 10S-DociHitjAtioN or Vintl Chloudc non Station..r Sormccs constitutes an emission test, and Isto be dls- buyer. These gas mixture etandarda may be carded upon conclusion ofanalysis ofthose directly used to prepare a t-rtfrp7i calibration curve as described in section 7.3, XWTlOOCCTtOH Performance of tills method should not oe attempted by persons unfamiliar with the operation of a gee chromatograph, nor bv 4 3 Analysis, 6.2 3.1 Cylinder standards ccrn/lcafion. 43 1 Ga eluoiintograph--With flame The concentration of vinyl chloride in nitro- lomzatlon delector, polentiometnc atrip gen In each cylinder must have been certified chart recorder and 1 6 to 5,0 nil heated sam- ^y the manufacturer by a direct analysis Of pllng loop Ui automatic Satinple valve. cylinder using ah analytical procedure those who are unfamiliar with source sam pling, as there are many details that are beyond the scope of this presentation. Care must be exercised to present exposure of that the manufacturer had calibrated on the 1 Mention of trade names on specific prod* day of cylinder analysis. The calibration of nets does not constitute endorsement by the the analytical procedure shall, a* a minimum. Environmental Protection Agency. have utilized a three-point calibration curve. Copyright T 1977 by Environment Information Center, Inc. COLORITE 017043 Air Reg 162 July 1977 Air Reflations It is recommended that the manufacturer m-1nte<n two calibration atandardt and use the standards in the following tray. (1) a high concentration standard (between 50 and tion 72 Measure the pe.ik area, A*. by use of H. .inti a di*c Inlfgrutor or a planimeter. Measure the pr.iit height H-. Record A - and the reifiitinn time, Repent the injection al vinyl chloride injected, the attenuator sel ling. chart speed, peak area, sample loop temperature, column temperature, csrrJe: gas flow rate, and retention time Record the 100 ppm) for preparation of a calibration least two times or until two consecutive vinyi laboratory pressure Calculate At, the pe^k curve by an appropriate dilution technique. chloride peaks do not vary* In area more than area multiplied bv the attenuator *ett':-g (2) a low concentration standard (between 5'i. The average value for these two areas Repeat until two injection area6 are with'r, 6 and 10 ppm)-for verification of the dilution technique used. v ill be u*-c*d to compute the brig concentra tion 6 percent, then plot these points v C> When the other concentrations have beer, plotuc, 62.3.2 gttablUhmont and verification 0/ Compare ihr ratio of H- to A* foi the vinyl draw a smooth curve through the points ecltbratum gtandard* The concentration of chloride Mnnl with tlie aame ratio for the Perform calibration dal!y,"or before and after each calibration standard must have been stindird perk which is closest in height As each set of bag samples, whichever Is more established by the manufacturer using a guideline if these ratios differ by more frequent. reliable procedure*. Additionally, each tii.in 10',, the vinyl chloride peak may hot calibration standard must have been veri fied by the manufacturer by one of the following procedures, and the agreement be pure OKJssIrjly acetaldehyde 1* present) ami the secondary column should bo em planed l*ee Section 4 3 2l, _ 7.4 Bag leak check*- White performance of this section is required subsequent u> bt use. It Is also edvleed that tt be performed between the initially determined concen tration value and the verification concen tration value must be within ^ 6 percent! (1) vemfieanon value determined by com parison with a calibrated vinyl chloride- permeation . tube, (2) verification value determined by comparison with a gas mix i, 5 Mrn^'ire the ambient temperature and b.iH'ine'n^ procure near the bag (Assume the relathc humidity to be 100 percent ) Hf'in a waici saturation vapor pressure table, determine the record and water vapor con tent of the bap. prior to beg use After each use. make sure a bag did not develop leaks as follow* To leak check, connect a water manometer and preecuriae the bag to 6-10 cm H,0 (3-4 In H,0) . Allow to stand for 10 minute* Any displace ment In the water manometer Indicates a leak. Also check the rigid container for lacks ture prepared In accordance with the pro In manner. cedure docribed In section 7.1 and using 7 Calibration and Standards, percent vinyle chloride, or (3) verifi cation value obtained by having the calibration standard analyzed by the Na tional Bureau Of standards All calibration standards must be renewed on a time Interval consistent with the shelf life of the cylinder standards sold. (Nora: An alternative leak check method 7.1 Preparation of vinyl chlonde stand t* to praasurtxe the bag to 6-10 cm H,G or ard pai mixture*. Evacuate a sixteen-inch 9-6 in, E*0 and allow to stand overnight square Tedlar bag that has passed s leak A deflated bag Indicates a teak.) For each check (described In Section 7.4) and meter ample bag In its rigid container, place a in 6 Utors of nitrogen While the bag la rotameter in-line between the bag and the filling, use the 0-5 ml syringe to inject pump Inlet. Evacuate the bag. Failure of the -20jJ of 99JI+ percent vinyl chloride rotameter to register wo flow when the bag (' Fj'-rdv!** through the wall of the bag Upon with appears to be empty indicetee a teak. drawing the syringe needle, Immediately 1` 1 SininlPip Alembic the sample tiain cover the resulting hole with a piece of 8. Calculations in Firure luC-1. Perform o b.ip leik check adhesive tape. The bag now contains a 8.1 Determine the sample peak area as ncrordir.p In Section 7 4 Ob.senc th.it all vinyl chloride concentration of 60 ppm. In follows: connedKn* between the bag and the piobe a like manner use the other syringe to are tight Pl.ire the end of the pmbe si the prepare gas mixtures having 10 and 6 ppm it#* AmAf erntrt.it: of the Mack and ft*rt the pump *Hh the nrftfie valve adjusted to yield a flow of 0 b 1pm After a period of time suffi cient lo puree the line seven.) limes has el.-.p'-ed. connect the vacuum line to the vinyl chloride .oonoentrationa. Place each bag on a smooth surface and alternately depress opposite sides of the bag 60 times to further mix the gases These gas mixture standards may be used for 10 days from the wberr A,-Tb KDpls peak area. A.-The weired peak am. Af-The aneoosfton looter, Equation 10&-1 bag ami rumsK the bag until the return- date of preparation, after which time prep eler inchrMer no flow. Then repetition the aration of new gas mixtures is required 62 Vinyl chloride concentration*, rrom sample and vacuum lines and begin the sc* (Caution--Contamination may be a prob the calibration curve deearlbad In Bedion tual 'imphnp- keepmc the rate piopoiuonal in Die f'nrk wlonlv Duect the pn<. exiting the roi.um ier an.ay from sampling personnel At the end of the wimple period shut oil the lem when a bag Is reused If the new gas mixture standard contains a lower con centration than the previous gas mixture standard did.) 72, above, select the value of O, that cor respond* to A,, the ample peak area. Cal culate Ct as follows: pump, d sconuect the sample line from the bag and disconnect tlie vacuum line fjom tlie container. Protect the bag container from sunlight 12 Determination of vinyl chloride re tention time This section can be performed r C.P.Tt ^~P<T.(l-Bwt) Eqns.Uoc 106-: ..jimthnncous-Jy with Section 7.3 Establish 6.2 Sample storage. Sample bags must be kept out of direct sunlight When at all possible analysis Is to be performed within 24 houn, but in no case in excess of 72 hours of sample collection, chromstoproph conditions identical with Where: those In Section 0 3, above. Set attenuator to x l pillion Plush the sampling loop i\iiji rcro helium or nitrogen and activate Dip sample valve Record the injection time, the sample loop temperature, the column B#t-Tbe water vapor oobieat ef tb lac soluble, m etxaiyied C-Tt eomotranoa of vinyl ebiortds la tbs be* --inpln La ppm. C.--Ttw eocceiUTOUoci ef vinyl chloric* indieeud by U* yas ehnraiMorTapb, la ppm temperatuie. the carrier gas flow rate, the Pr--Tb ^ injure, Uk laboratory petaon C 4 Analy.is Set the column temperature ch.iit speed and the attenuator setting rwafli rl danat eaUPragoa, tool Be. to PH)* C Die detector temperature to 150* Record penks and detector responses that C ni*d the :np)e loop temperature to 70* C ocmr in the absence of vinyl chloride Main T,-Tb* eamplt loop tamfMauxrv c tbe efcoofcrt* eoei* at Uw Um ol aaaiyu. *E. Fr-Tbe iohoratory pnman at Ubm of analytU, bus Whrn npunmm hydrogen and ovvpen flow tain conditions With the equipment plumb Bg late- hate been determined verify and main ing arranged identically to Section 6-3, flush tain tn"* now rates durinc all rhroniato- the sample loop ior 30 seconds at the rate of T,-*Tbe raferenec temperatare, th Ms}ph loop tamperatarv rvoorded durtof eabbratloa, *E graph <per.ittona. Using aero helium or 100 ml -nun with oue of the vinyl chloride ritrneen a* the carrier gas, establish a flow rai* in the range consistent with the manu facturer'* requirement* for witisfactnjy de tector opeiation. A flow- rate of npproMir.aif<)T 4Q ml mm nhould produce ndcnuivte 'VcpaiotmuF Observe the base Unc periodi cally and <l*"tfin*nc that tbc noise level has tr.rwJl/di snd that bste line drift has ceased. Turge the sample loop for thirty second* at the rate of 100 ml/mln, then activate the (ample tali* Record the injection time (the position of the pen on the chart at the time of sample injector)), the sample number, the sample loop temperature, the column tern* calibration mixtures and activate the sample valve Record the injection time, Select the peak that corr&^ponas to vinyl chloride. Measure the distance on the chart from the Injection tune to the time at which the peak maximum occurs This quantity, divided by the chart screed, Is defined as the retention time Rectos. , 9. Rsferanoee. I. Brown, D, toy, E W. and Stephen- eon. M. H. "Vinyl Chloride Monitoring Near the B. F. Goodrich Chemical Company In Loulrvlite, Kentucky.** Region IV, UB. Envi* mnmental protection Agency. Surveillance and Analysis Division* Athena. Georgia. June 34. 1074. 7.8 Preparation of chromatograph cali bration clime Make a gas chromatographic measurement of each gas mixture standard (described In section 62-2 or 7.1) using con 9. "Evaluation of A Collection end Analy tical Procedure for Vlnyj Chloride in Air,* by G. D. Clayton and Associates, Deoembcr 13, 1974. EPA Contract No. 66-03-1406. Task Order No. 9, EPA Report oN. 76-VCL~l. peraivre, carr-er pas flow rate, chart speed ditions Identical with those listed In sections and the attenuator setting. Record the lab 6.3 and 6.4. Flush the sampling loop for 30 oratory pressure. From the chart, select the seconds at the rate of 100 ml/mln with each peak having tlie retention time correspond- standard gas mixture and activate the sam 9. "Brandardixatlon of Stationary Source Emission Method for Vinyl Chloride," by Mid west Research Institute, 1976. KPA Contract tug to vinyl chloride, as determined in Sec ple valve. Record C<, the concentration of No. 66^03-1096, Task Order Mo. 7. environment Regulation Handbook COLORITE 017044 Hazardous Air Pollutants-VC July 1977 Air Recj 163 5 3 3 Thermometer--0 to 100* C. accurate to d0.1# C, Perkin-Emer No, 105-0100 a equivalent 6 3 4 Sample tray thermostat perkm-Elmer No 10&-0lQ3,or eqvivivkni 6 3 5 Septa--Sandwich type, for matlc dosing. 13 mm. Ferkln-1 >ih j No K>li 1008, or equivalent. 6 3 6 Integrator - recorder -- Hea'lc'.i Packard Model 3330A, or equivalent 6.3.7 Filter drier assembly ($)* roihinElmer No. 2230117. or equivalent. 63 8 So*ip Him flowmeter--Healed i'rukard No. 0101-0113. or equivalent 6 4 Callbratloo6,4.3 Regulator*--for required fa.*, cymders. 6. Reagents 0 1 Analysis. 6.1.1 Hydrogen gas--eero grade 6.1.2 Nitrogen gas--zero grade 6.1 A Air--'tero grade. _ _ ____ 6.2 Cslfbrafiort- rifn a i. ki| i^iin irtU, 6.2.1 Cylinder standard* (4). Om miuvu standards (60. 500.3.000. and 4.000 ).pt" \i">l chloride in nitrogen cylinder?) iot \,hiO> D>< gia composition has been certifies l>) Du manufacturer. Lower concentration stand ards should be obtained If lower concentrs- " tions of vinyl chloride samples are expected, Mmoo 1Q7--DnmoiAnoK ov Vdctl Cklo- of 3-M ppm, 4.16% for a sample with a mean as the intent Is to bracket the sample con mam Contxwt or Ittfiocsss WmtWim Of 1.66 ppm, and 5.29% for a sample with a centrations with standards The lu&nuft-o aits Vntn, Cm rums Ooirrurr or mean of 62.66 ppm, turer must have recommended r inaxiinu"? POLTTTJfTL CSLOKXOX BKW, &MJ1UT. W*T shelf life for each cylinder so tint Du cui> COKX, AMD LiTS &A1CPL2S WnOODUTTOW Performance of this method should not be 4. Safety. Do not release vinyl chloride to the labors* tory atmoephere during preparation of stand ards. Venting or purging with VCM/air mix centratlon does not obange grcsUr ilu n " percent from the certified value The date of gas cylinder preparation, certified vinyl chloride concentration and recommended Attempted by persons unfamiliar with the operation of a fee chromatograph. nor by those who are with impLing, m there axe many details that are beyond the tures must be held to a minimum. When they are required, the vapor must be routed to outaLda air. Vinyl chloride, even at low ppm levels, must never be vented inside the maximum shelf life must have been afHvod to the cylinder before sblpmmt fiou- Dk manufacturer to the buyer. 6.21.1 Cylinder standards oinifnviion. aoope of this presentation. Care must be laboratory. After vials have been analysed, exerci--d to prevent exposure of sampling the pressure within the vial must be vented personnel to vinyl chloride, a carcinogen. prior to removal from the Instrument turn L Principle and Applicability, 1.1 The basis for this method relates to the vapor equilibrium which Is established between RVCM. PVC, resin, water, and air In a closed system It has been demonstrated that the RVCM in a PVC rwin wlU equili table. Vials must be vented into an activated charcoal tube using a hypodermic needle to prevent release of vinyl chloride into the laboratory atmosphere. The charcoal must be replaced prior to vinyl chloride break through. The concentration of vinyl chloride m nitro gen in each cylinder must have. l*tee c<rti* fled by the manufacturer by a direct analysis of each cylinder using an analytic*.! pro:*dure that the manufacturer had on the day Of cylinder analysis 3 h< <*, libittlon of the analytical procedure shall, a* minimum, have utilized a three-poim cali bration curve. It is recommended that the brate In a dewed vessel quite rapidly, pro* 6. Apparatua. manufacturer maintain two calibration vlded that the temperature of the PVC resin 6.1 Sampling. standards and use these standards In the la maintained above the (lass transition 6.1.1 Bottles--60 ml (3 a), with waxed following way: (1) a high concentration temperature of that specific ream lined screw on tops, for PVC samples. standard (between 4.000 and 8.000 ppm) foi 6.1.3 Vials 60 ml Hypo-rial*.1 sealed with preparation of s calibration curve by an ap 113 This procedure Is suitable for deter Teflon faced Tuf-Bond discs for water sam propriate dilution technique: (2) i- low ion* mining the vinyl chorlde monomer <VCM) ples. centretlon standard (between 60 md content of toproceas wastewater samples, and 6J4 Electrical tape or equivalent, to ppm) for verification of the dilution tech the residual vinyl chloride monomer prevent loosening of bottle tope. nique used. (RVCM) content of polyvinyl chloride 6.3 Sample reoovery. 6 3.1.2 Establishment and verification of (PVC) resins, wet cake, slurry, and latex 5J.1 Vials--With seals and caps. Perfcln- calibration standards The concentration of samples. It cannot be used for polymer In fused forma, such *s sheet or cubes, If a resolution of the vlijyl chloride peak is not satisfactory for a particular sample, then chromatograph parameters may be altered provided that the precision and reproduci bility of the analysis of vinyl chloride cylin der standards are not Impaired. If there is reason to believe that tome other hydro carbon with an identical retention time is present in the sample, then supplemental confirmation of the vinyl chloride .peak through an absolute analytical technique, such as mass spectroscopy, should be per* formed. 3. Range and Se&eltmty. The lower limit of detection of vinyl chlo ride will vary according to the graph used. Values reported Include 1X10~* mg and a x 10"* mg. With proper calibration, the upper limit may be extended sa needed. 9. Precision and Reproducibility. &m*r Corporation No. 106-0116, or equiva aach calibration standard must have been lent. established by the manufacturer using reli 6JJ Analytical balance--Capable of able procedures. Additionally, each calibra weighing to ^0-001 gram. tion standard must have been verified by the 5J4. Syringe, 100 a* Precision Series manufacturer by one of the following proce "A" No. 010036. or eauivalent, dures, and the agreement between the h'- 62 4 Vlfil Sealor, Perkln-Elmer No. 106- tlolly determined concentration valut i*nti 0106 or equivalent. the verification concentration value mur-t be 6.3 Analysis. within 5 percent: (I) verification value de 6 3.1 Oos chromatograph--Pcrkln-Elmor termined by comparison with a gsc- mixture Corporation Model F^iO head-space ana standard generated In a slmllai luauni) to lyzer, No 104--0001, or equivalent, the procedure described In section 7.1 of 5.33 Chromatographic column Stainless steel, 2 m -X 3.2 mm, fcontatnlng 0 4 percent CArbowsJt 1500 on Carbcpak A. Pcrkln-lmer Corporation No 106-0133. or equivalent. Csrbopak C can be used In place of Carbcpak A. If methanol and/or acetaldehyde it pres ent in the sample, a pair of Poropak Q col umns In series (l m x 3.3 mm followed by Method 106 for preparing gas mixture stand ards using 96.9+ percent vinyl chkuicie. ot (2) verification value obtained by having th< calibration standard analyzed by the Nation al Bureau of Standards. All calibration stand ard* mu*t be renewed on a time litUiviJ consistent with the obeli life of the c>)Jj.hU, standards sold. 2 m x 33 mm) with provision for bsckfluah of the first column has been shown to pro vide adequate separation of vinyl chloride. 7. Procedure. 7.1 Sampling. 7.1.1 PVC sampling--Allow the it sin oi An Intarlaboratory comparison between slurry to flow from a tap on the tank or illo seven laboratories of three reeln. samples, 1 Mention of trade names on specific prod until the tap live has been well purged. Ex each split Into three parts, yielded a standard ucts does hot constitute endorsement by the tend a 60 ml sample bottle under the tap. fill, deviation of 3.63% for a sample with a mean Environmental Protection Agency, and Immediately tightly cap the bottle. Wrap Copyright 1977 by Environment Information Center, Ine. COLORITE 017045 Air Rea 164 July 1977 Air Regulations eJcctricnJ tnpr around th cnji and botti to anniyzi-r the analvsu, program according to the mcu- prevent tb top from lootonln- PJa^e an - 7.3 Analy:.!*-. factorcrs- jnxtrutUoua These instructions identifying label ou each bottle, and rocor-d 7.3 ) jTcpirsdon of ras chromatograph-- must be carefully followed when starting tbs date, time, and oample location both on InsiAll the chromatop-sphle cohjntr. and con nd stopping program to prevent damage to the botlle* and In a leg book dition overnight at 160*C Do not connect the the drying a*;*ombly 7 1-2 Water sampling--Prior to use, the 60 nil vials (without the discnj oiusi Uc Capped with aluminum foil and muffled at 400*C lor at least one hour to destroy or remove any organic matter that could in terfere with analysis At Uio onmpltnp loca tion fill the vials bubble-free, to overflowing *o that a convex meniscus forms at the top The ex coos Water Is displaced a$ the scaling dlxc Is carefully placed, Teflon side do-an, on the opening of the vLD, TiW? the aluminum cal o\er the disc and the neck of the vlM and crimp Into place. Affix an idoutifving label on the bottle, and record the dale. tun*, and sample location both on the vials aud In a log book. All samples must be kept re frigerated until analyzed. 75 Sample recovery Samples must be run within 24 hours. exit end of the column to the detector while 73 A Determination of total solldi (TS) conditioning For wet cake slurry. rc<ln solution, and 73 11 Flow rate adjustments--Adjust PVC latex sampler, determine TS fo: each flow tM-c* os foliov x sample by accurately weighing approxim a Nitrogen carrier gas--Set regulator on ately 3 to 4 grama of sample In an aluminum cylinder to read 60 pslg Set regulator on pan before and after placing in a draft chromatograph to 1.3 kg/em1 Normal flows oven (105 to 110* C) Samples oiusl be dried at thl* pTr* Mire rhould be 25 to 40 cc/tnlnuts. to constant weight. After first weighing re Cheek with bubble flow meter turn the pan to the oven for a short pe b. Burner air supply--Set regulator on cyl riod of time and then reweigh to verify com- inder to read 60 p?lg Set regulator Oh plel# diyne-is TS la then Calculated a? Die chromau>;:raph to supply air to burner at a final sample weight divided by initial aam- rate between 260 and 300 cc/minute. Check with bubble flowmeter. ple *c/plit 6 Calibration 3. Hydrogen supply--Set regulator on cyl Caimration If to be performed each eight- inder to read 30 pslf. Set regulator on hour period when the instrument i* used chromaU-graph w> supply approximately Each day, prior to running samples, the col 36-^5 cc/mlnute Optimize hydrogen Cow to umn should be conditioned by running two yi*`1d the most sensitive detector response Of the previous day* 2000 pp;n standard* without extinguishing the flame. Check flow 0 1 Preparation of Standards 7.3.1 Resin sampler--The weight of the with bubble meter and record this flos Calibration standards are prepared by fill rcstn URcd must be between 0 1 and 4 5 grnnn. 75 1.2 Temperature adjustments--Set ing the vlsl* with the tiny! ehlande/nltro- An exact weight must be obtained (-*-0^01 leniperaturcs as follows gen standards, rapidly seating the septum gram) Jot each sample In the case of sus a. Oven (chromatographic column), 60* and scaling with the aluminum cap Use a pension resins a volumetric cup can be pre pared which will hold the required amount C b Dosing line, 140* C atatnlros steel line from the cylinder to the vial Do not use rubber or tygos tubing The of sample The sample bottle is opened, and e. Injection block, 140* C. sample line from the cylinder must be the cup volume of rexiu la added to the tared ample viol (including arpium and alunil- purged (Into hood) for aeveraJ minutot prior d Sample chamber, water temperature. to filling vfais. After purging, reduce the flow Dum cap), The vial is immediately sralc<l 00* C* l o* c. rate to approdnately 600-1000 ec/mln, Fuoe and the exact ramplc weight Is then obtained 7.3.1.3 Ignition of flame ionization detec end of tubing into vial (near bottom) and Report this Value on the data sheet os It is tor-- JimiUo th* detector according to the after one minute ilowly remove tubing Place required for calculation of RVCM In the manufacturer's instructions septum in vial as soon as possible to mini Case of relatively dry resin samples (water content <0.3 weight T), 300 u\ of distilled water juuft be injected Into the Vial after rraljng and welching. a loo pi rynnge In the raxe of di^prrr.lon 'mslrts, the cup eminot be uaed. The sample Is instead weighed approximately in an aluminum dish, trmt'ferred to the tared viol and weighed accurately iu the vial The sample Is then pi need Is the Perk ln-Elmcf head space anaiy.-Z'r (Or equivalent) and conditioned lor one hour at CQ"C. NOtf- Some aluminum vjnl caps have e corner scctlou which must be removed prior to placing into sample tray tf sot removed, rertous damage to the Injection needle will Occur 7T..2 Suspension icr.ln slurry and wet coke samples--Slurry must be filtered using a 7.3 1 4 Amplifier balance--Balance the amplifier Recording to the manufacturer's instructions. 7 3 3 FrogramnilDg tb chromatogTaph-- Program the chromatograph as follows*, a I--Dosing ttme--The normal setting Is 2 seconds. b A--Analysis time--T7> normal setting Ls S minutes. Certain types of samples con tain hich bolhog materials which can cause intrriercuco wtlb the vinyl chloride peak on subsequent analyses Iji these coses the analysis limn must be adjusted to eliminate the Interference An automated backflush system can also be Used to solve this prob lem. c. B--Flushing--'Tho normal setting la 0 2 minutes, _ _______ mize mixing air with sample After the stand ard rials are sealed,'Inject 100^1 of distilled water. 8J Preparation of chromatograph calibra tion curve Prepare two 60 ppm, two 600 ppm. two 2000 ppm, and two 4000 ppm standard samples Runihe calibration samples In exactly the oame manner as regular aample Plot A*, the Integrator area count* for each standard aample vs the concentration of vtnyl chloride In each standard sample Draw a line of best fit through the points. ft. Calculation*. 9J Response factor. From the calibration curve described in Section 85. above, select the value ol c that corresponds to A, for each sample Ooin puts the response factor. Re. for each sample, vtuall Buchner funnel with vacuum to yield d W--Sfabffizcftcm time The normal act a* follow*: wit cake. The finding proccsr. must be con ing Is 0.2 mlnutea. tinued OTfl7 ax long as a steady stream or e X--Nvimber of analyses per sample--^"he Rf^^r Equation 107-1 water j exiting from the funnel Exccasivc OitrfiMnn time eouid result in some loss of VCM 17i wet cake sample (0.10 to 4.6 grams) normal retting la 1. 75 3 Preparation of sample turntable--Be fore placinc anv sample Into turntable, be D5 Residual vinyl chloride monomer con centration, or vipyi chloride monomer con is added to a tared vial (including septum and aluminum cap) and Immediately scaled. Sample weight is then determined to 3 deci mal pl:u-fs The sample is then placed In the certain that the center aection of the alu minum cap has been removed The numbered sample bottles should be placed is the cor responding numbered positions Lb tha turn centration, Calculate CV. a* follows: rcrkin-Elmer head apace analyzer (or equiva table. Insert cosies in the following order: lent) and conditioned for one hour at D0*C, Positions 1 4c 3--Old 2000 ppm atandardx A sample of wet cake is used to determine for conditioning. These are nedeaaary only TS (total solids). This is required for calcu after the analyzer boa not been used for 24 Equation 107-2 lating tho RVCM. 753 Dispersion resin slurry sample*; -- Thin material should not be filtered Sample must ho thoroughly mixed VMng a tared via) (including septum and aluminum cap) add approximately ft drops (0.25 to 0.36 grams) of slurry or latex using a medicine dropper. This should be douc Immediately after mixing. Seal the vial as soon as possible. Determine sample weight accurate to 0.001 grams. Total sample weight must not oxcecd hour* or longer Position 3--60 ppm standard, freshly pre pared. Position 4--600 ppm standard, freshly pre pared. Portion 6--2000 ppm standard, freshly prepared. Position 6--4000 ppm standard, freshly pre pared. Position 7--Sample No. 7 (This Is tbs first o.impto of the day, but Is given as 7 to be con* where: C,,, -- Concentration of vinyl chloride in the sample, in ppm. P.= Laboratory atmosphere plea sure, mm Hg. 7",= Room temperature, *K. Molecular height of VCM t',= Volume of vapor phase (vial volume lee* sample volume). Q.5Q grams Condition the vial for one hour sment with the turntable and the integrator m ,= Weight of sample, grams at Mi*C In the analyzer. Determine the TS on the sinrry sample (Section 73.5). 7.2-4 Inproceas wastewater samples-- Using tared vial (including septum aud a'uinUvmn cap) quickly add approximately 1 cc of water using a medicine dropper. Seal the vial a* soon u possible. Determine ample weight accurate to 0.001 gram Con dition the viol for two hours at D0"C In the printout ) After all samples have been positioned. In* tert the second set of 60, 600, 2000, and 4000 ppm standards. Samples, Including stand ards man be conditioned in the bath of DO' C for j hour (not to exceed 6 hours). 7.3 4 Start cliromatograpb program-- TO>en all sample*, including standards, have been conditioned at 20* C for 1 hour, start f?=C.a- constant 162.360 (cr-mmmnle-degree Kelt ini) K = Henrv'i Law constant. For VCM In PVC at 90' C. A.' = 6.52X10-s=/tV For VCM in I cc (approximate) wastewater sample at 90" C, A = 3.0X10-,= AV Environment Regulation Handbook COLORITE 017046 Hazardous Air Pollutants-VC July 1977 O'157'' ---- ) Equation 107-3 The following genera] equation can he u-vd for mr -ampic which contains VCM, PVC and water, c'--Sff*X[ifes7+A''tT5) r-A'-! 1 ~ 75' T>] Equation 107-4 where. TS=*Total *olids. Xort Km mu^t be determined for sample^ with a \apor volume to liquid \olume ratio other than 22.5 to 3, This ratio can he obtained by adjusting the sample weight through giwnir consideration to the total solid' and density of the PVC Results calculated using Equation 107-4 represent concentration based on the total sample To obtain result1* based on dr\ PVC eomnU, diwde by 73. Fur a i-cc wa-tewnter sample (that is, 22 ') to t vapor volume to liquid volume ratio) A v is 5 OX JO"1*. Thu-, Equation J07-4 can be simplified to the following- J~ A, p 5.9SS X 10'* .A , T [_------ iuT'------ r(2.065X 10 3) Equation 107-5 (Secs. 112 and 301(a) of the Clenn Air Act, 42 L'.S.C. 1657c-7 and 1857g(a).) T:= Equilibration temperature, K. If the following conditions are met, Equation 107-2 can be follows 1. Ti = 22c C ;295 K) 2. T.-90 C (363c K) 3 P* -- 750 mm Hg, simplified as 4 r,= vii^2Z'5~fi where .** Vial volume, cc (23.5). 5. Sample contains le?^ than 0.5 perceot water 10. Reference*. 1. lLm\&UAl Vinyl Chloride Monomer Con tent of Polyvlayt Chloride Resin* **<1 Wet Cake Semple*, B. p. Goodrich Chemical Co. Standard Twt Procedure No 1006-T. B. P. Goodrich Technical Center, Aron Lake. Ohio. January So, 1976. 2. Berea*, A. R,, JThe Solubility of Vinyl Chloride in Polyvinyl Chloride," ACS-Dlri* elon of Polymer Chemistry, Polymer Pre print* IS (3): 197, 1674. 3. Serena, A. R-. "The Dlffueton of Vinyl Chloride In Polynnyl Chloride," ACS-Dmelon of Polymer Chemistry, Polymer Pre prints XS (3): 303, 1974, 4. Berens, A, BH L. B, Crider. C. J. Tom*nek and J. U, Whitney, AnaJysl* for Vinyl Chloride in PVC Powders by Beed-Spoce Ou Chromatography," to b pubuahed, (FRDoc.77-1582 Piled 6-6-77. 45 am] Air Rea 165 Copyright I-1177 by Environment Information Center, Inc. COhORITE 017047 TENNECO CHEMICALS, INC. BURLINGTON, NEW JERSEY MAJOR RAW MATERIALS methanol tridecanol vinyl chloride vinyl acetate trichloroethylene ammonia food grade gelatin liquid caustic liquid chloride ferric sulfate 1 ime sulfuric acid MATERIALS REPORTED ON SLUDGE QUALITY REHCJ phenol toluene trichloroethylene mercury thiostop-N methylene chloride tetrachloroethylene di(2-ethylhexyl) phthalate COLOR!TE 017048 e plu vi-rC {iauwl lii /6 i ul It Leu aL^' tfWfJb /W 'A' Vu\li-(lut iVh'^ ' x t Ltpu. ,' i/yn? From the office of; J. P. SANDSTHDT i COLORITE 017049 B BIST OF TOXIC SUBSTANCES FROM APPENDICES B-l, B-2, B-3 0'. S jjt'1' S _ I. >4Ai;3.V: i . _____ J '. * 1T i 1 1 - / .7 - - i |4. 7`VV,V-jv 1 _ J/.y ^ * # lKT.il. .iJ j_Lj_'V; -1 " *! viV 1 1I1 1, 1 1ii \ ! 5. 56233 25Lbs/yr. A 6. 67663 25Lbs/yr. X 7. 7440473 c .5Lbs/yr. X 8. 7-440503 < .5Lbs/'yr. V 9. 57125 <: .5Lbs/yr. X-- 10. 75343 <.SLbs/yr. A 11. 75092 36T.bs./yr. y 12. 11781/ 2460 Lbs/yr. X 13. 85687 93Lbs/yr. X 14. 122394 < .5Lbs/yr. X 15. 7439921 <.5Lbs/yr. X 7439921 15Lbs/yr. X 16. 7439976 <.5Lbs/yr. X 17. 7440020 . 5Lbs/yr, X 7440020 1800Lbs/yr. X 18. 108952 < .5Bbs/yr. X 19. 7440224 20. 127184 127184 <.5Lbs/yr. 2067Lbs/yr. 18 gal/yr. X X X j.. : ^ ' ... ;_,S , t v !' 3. 1 1i11 1 i 1 X X X X A X X \Ar. X X X 4Vb X X X X X X X X X COLORXTE 017050 \ B LIST 01-' TOXIC SUBSTANCES FROM A'M-FNUICI'S K-1, R-2, R-" ' cts :ais 21. 1' 1 \ * ` i ,1 * 22, /i-'OO > ".DL'i.'./yr. 23. 79016 j * -J .--/ J - t 1 l2LWyr. ji 24. 7440666 ^ *bhbs/yr. 25. 7440473 ^.SLbs/yr. 7440473 500Lbs/yr. 26. 128041 l?.Lbs/yr. USA!) 1iAi.y 1 v, j i ...... i !' X/O.M-.L iri - i ! w * X X ii i X XX XX XX XX -2- COLORXTE 017051 c SELECTED LIST OF TOXIC SUBSTANCES AMD THE PROCEEDURES FOX TESTING CASINO 7-';-CUT-7A FA;-: I 'W.v-y (L-urF) l ns fix A 79016 12S041 Trichloroethylene Sodium. dimethyl dit hiocarbamoits .PU'Ki.iijUXI abs; n c.i.L I n - j-i>.i < j, "j#.. ` ",T 1f ' "j ' ] \-t 1 ^ ' ` r, , ^ t*ViAm? -- O J ^ J-nuvy '\'i ti and Tray t!si/ite a:id I'in-ie ioniza i:ii on detector. EPA Method 601- gas chromatograph with purge and trap device and Hall or Electron Capture Detector. No EPA method has been published for the analysis of this compound. Ne haVe requested informat! on on the specific procedures inquired but have not yet received it. *N0TK The above EPA Hotbeds fur GC analysis \viilfvl plae> i i_ ill rl'iO, Federal Register on December 3, 1979. (Vol. 44, No. 233V COLORITE 017052 - - -- S ,VlJ'~*~/sf (0? V D APPENDIX b-1 HEAVV METALS AND TOXIC opca:;ic conf o:;: ids i - - Coni ' :>"oc r '*, > f - ',t J Hon-/v A-I ' 1 .11 w, C: f'*'- ' ' j J. ' ; o; .1 u t\ |y - - -' ----- ` > - - ** * rXM Chrcm.J un (total) 890 Copper (total) 850 Lead (total) 500 .Mercury (total) 5 Nickel (total) 82 Zinc (total) . __ . 17740 Ci"! -.O ;.*Ci tJ L 1.11 jjTicirin Heptaciilor Heptachlor epoxide ; Lindane Methoxychlor P.p' - TDK (ODD) 0.1 0,10 0.10 0.10 0.10 0.10 . 0.25 0.25 Mi rex 0.25 ' P,P* - pdt 0.25 P,p' - DDK 0.25 Toxaphcnc 1.0 y t-3 wCi J"1-Jt 1 . V>* _1i_ w rv. ,i J1-U1 4v-- t.-.vUw-2 biphenyls (PCB's) 0.50 *dry-weight basis - * COLORITE 017053 E TESTING PROCElMiNES FOR UAN!>: O ATR d APi'l'?.A -4 Slonao iir.n yn'MJar.io'.'s using too ro ; i nw; n>; n t <_>c. aiti , COM- EFA Method 451. 3 i:i "Mi:-`I:ods for Chealeal Aral/sir. of , art or wastes" EPA, March lh/y. (attached) Oil & Grease- Standard Methods, 14 ed Method 502D (attn ched) pH- pH meter (electrode) Total Solids- Standard Methods, 14 ed. Method 0<1; do term Inat'jo'l o total residue in solid 4 s-rni solid sa:''> ies (attach od) COLOR!TE 017054 APPENDIX B-2 TOXIC POLLUTANTS CAS NO. IL-/ -*"^/w/ V ` " T3 32U acenauhthene 203968 acenaphthylene 107028 acrolein , -V --- -79061 \ acrvlamide - -- '--" " '/ ' pzrr. 107131 acrvlonitrile 3090 02 - - -alcrin ----- ~ -......... ................- ,......... ............. 1321115 aminobenzoic acid 61825 amitrole 71410 amyl alcohols 62533 aniline 142041 aniline hydrochloride 100663 anisole 4'/j. 120127 ~ 7440360 anthracene antimony (total) At-ouv.^-i'L: ;:;. --- - <'A -- 7440382 arsenic (total) A.C'VT rev2465272 atranine j 56553 1,2 - benzanthracene <1 -- 71432 92375 .benzene L benzidine 205992 3,4 - benzofluoranthcne 207089 11,12 ~ benzofluoranthene 191242 1,12 - benzoperylene 50328 3,4 - benzoovrene (bsnzo (a)oyrene) 98077 benzotrichloride 100469 benzylamine 7440417 beryllium (total) 319846 alpha BHC 319857 beta BHC 58899 qnmma BHC (Lindane) 319863 delta 3HC 111911 bis (2 - chloroethoxv) methane 111444 bis (2 - chlorocthv]) ether 39638329 bis (2 - chloroisooropyl) ether 75252 bromoform (tribromomethane) , ./ 101553 4 - bromoohenyl ohenvl ether -- 7440439 cadmium (total)S 56235 carbon tetrachloride (tetrachloromel 57749 chlordane (technical mixture and me! 95512 2 - chioroaniline 108429 3 - chioroaniline 106478 4 - chioroaniline -- 108907 chlorobenzene h 124431 chlorodibromomethane 110753 2 - chloroethyl vinyl ether (mixed) 55 - - 67663 chloroform (trichloromethane) i_ 91537 2 - chloronanhtha)ene iV * Chemical Abstracts Service Xumber COLORITE 01705$ APPENDIX B-2 (continued) CA.S No. -/ / "' 88733 2-chloronitrobenzenc 100005 4 - chloronitrobenzene 25167800 2 - chlorophenol 7005723 4 - chlorophenvl phenyl ether 126993 chloroprcne . . 7-4 4 0 4 7 3 . chromium (total) . -. --- --- '"'21 SOl'3"-' -Chrysene `` K 532821 chrvsolicine - -- 7440503 copper (total) 98328 cumene -- 57125 cyanide (total) 'u'r'-'v. 72548 D,p1 - DDD (p,p' - TDE) 72559 p,p' - DDE (D,p` - DDX) 50293 p,p' - DDT 53703 1,2: 5,6 - dibcnzanthracer.e 603275 2,3 - dichloroaniline 554007 2,4 - dichloroaniline 95829 2,5 - dichloroaniline 95761 3,4 - dichloroaniline 626437 3,5 - dichloroaniline 95501 1,2 - dichlorobenzene 541731 1,3 - dichlorobenzene 106467 1,4 - dichlorobenzene 91941 3,3' - dichlorobenziuine 75274 dichlorobrom.omethane C'Jn -75343 1,1 - dichloroethane --107062 1,2 - dichloroethane J5 </=? - 156592 -- 75092 1,2 - dichloroethylene (trans) 'dichloromethane (methylene chloride 120832 2,4 - dichloroohanol 78875 1,2 - dichloropropane -- 542756 1,3 - dichloropropenc 60571 dieldrin 84662 diethyl phthalate 14UO -- 117317 di (2 - ethvlhexyl) phthalate L <?5 -85637 131113 butyl benzyl phthalate dimethyl phthalate 84742 di - n - butyl phthalate 117840 di - n - octyl phthalate 119904 3,3* - dimethoxybenzidine 121697 dimethylaniline 119937 3,3* - dimethylbenzicine 57147 1,1 - dimethylhydrazine 105679 2,4 - dimethylphenol 534521 4,6 - dinitro - o - cresol 51235 2,4 - dinitrophcnol 121142 2,4 - dinitrotoluene COLOR!TE 01705$ AI'PCCHIX B-2 (cont i mice!) \hz//-r, CAS No. <?> ^A 606202 2,6 - dinitrololue.'ie 123911 1,4 - dioxane (1/4 - d ethvlene dioxide) -122394 diphenv] awn nc 122657 1,2 - dipheny]hydrazino 959908 endosulfan - I -;-332T3.53- IX 1 I ,-J. ,, -- _ _ 1031078" endosulran sulfate' 72208 endrin 7421934 endrin aldehyde 53494705 endrin ketone 100414 ethylbenzene 106934 ethylene dibromiae 151564 ethylene.ini nc (Aziridir.e) 206440 fluoranthsne 86737 fluorene 76443 heptachlor 1024573 heptachlor epoxide 118741 hexachlorobenzene 87683 hexachlorobutadier.e 77474 hexachlorocyclopentad i ene 6 7721 hexachloroethane 302012 hydrazine 193395 indeno (1,2,3-C,D) pyrene 78591 isophorone 7439921 lead (total) 7439976 mercury (total) 101144 4,4' - methylene bis (2-chJoranilinc) 101779 '4,4' - methylene dianiline 108101 methylloobu tyl ketone 91203 naphthalene 13 4 3 2 7 alpha naphthylamine 91598 beta naphthylamine 7440020 nickel (total) 98953 nitrobenzene 88755 2 - nitrophenol 100027 4 - nitrophenol 1321126 nitrotoluene 100618 >; - methvlani 1 ir.c 62759 N - nitros odine thylamine 621647 >J - nitrosoci - n - prepy me 86306 N - nitros ociohenvlaurn re 59507 parachloronetacresol PCB - 1016 (Aroclor 1016) PCB - 1221 (Aroclor 1221) 11097691 PCB - 1232 (Aroclor 1232) PCB - 1242 (Aroclor 1242) PCB - 1248 (Aroclor 1248) PCB - 1254 (Aroclor 1254) PCB - 1260 (.Aroclor 1250) //P; COLORITE 017057 APPENDIX B-2 (continued) V,,.l CAS No. S /865 H 3JW) 1 8 t -U.QS5_5> pcntachlorophencl p hcnanthrene phenol 9554 5 1,2 - phonylenediamine 108452 1,3 - phenylonodiami.ne 106503 1,4 - pnenylenediamine l;._ "1'2 9 0-0 Op; ._-_pvrare-: ~ ,,,c.: 7782492 t'1? --- 7440224 selenium: ftbtiTD " silver (total) 842079 sudan I (solvent yellow 14) 1746015 2, 3,7,8 - tetrachlorodibe.nzo 79345 1,1,2,2 - tetrachlorcethane 0 n ',-- 7 127184 vXtctrachloroethvlene L. 7440280 thallium (total) 62566_ thiourea -- ;i08 0 83' \toluene. -A' 104154 toluene sulfonic acids 26915128 toluidines 8001352 toxaphene 120821- 1,2,4 - trichlorcbenzer.e - 7155 6 1,1,1 - trichlorocthane v. d, m ---79005 -- ,7 9016- 88062 1,1,2 - tri chloroethane \trichloroethylene ----... .____ `2,4,6 - trichlorophenol 1300716 xylenols 1300738 xylidines <'4 -- 74406 6 6 zinc (total) (TCDD) <L- r>r /( ( ( COLORITE 017058 CAS No. APPENDIX B-3 pohut'v.xrs _rij,yr_ are jlwitljtory to ' Tu'Clog rcal "tkcat-MEnt " processes'"' INORGANIC POLLUTANTS ' "14213979 ' Borate' (Boron)" --7440473 Chromium 7439965 Manganese 7440622 Vanadium ORGANIC POLLUTANTS 107186 57067 141435 538283 4170303 97234 591355 138896 86565 593851 124094 148243 556616 867447 107197 ^3.141 -1_28 o 4 y> 137428 137260 97745 79196 A1lyl alcohol Allvl isothioevanate 2-Ami noethanol (mono ethanolamine) Benzyl thiuroniuin chloride Crotonaldehyde Dichlorophen 3,5 - dichlorophenol Dime thy lpara ni trosoani line* N , N-dimethy1-1-naphthvlamine Guanidine carbonate Hexamethylenediamine 8 - hydroxyquinol.ine Methyl iuothiocyana t. e Me:thyl thiuronium sulphate Pi'opargy 1 alcohol Shato.l e \Sodium dimethyl dithioenrbamate --li CiTT- O Sodium methyl dithi ocarbairnto Telramethyl thiuram disulphide Tetramethvl thiuram monosulphide Thiosemicarbazide I, 475358-475364:Y;A: COLORITE 017059 D APPENDTX I! - 2 TOXTc PObLUTAMTS C A." Ho. 8 37 2 j 2035 6 5 107023 75C >1 . 1071 -<1 a> nL ri -\ - --/ 17 VI ! J S 6 1 3 '* 7 62512 14 2 0 41 100563 120127 7440360 74403S2 2465272 56 5 5 3 71432 * 92875 205S92 20/089 191242 50328 9S077 100469 7 4 4 0 417 319846 319857 58899 315860 111911 111444 39638329 75252 101553 7440439 56235 57749 95512 108429 106478 108907 124481 110753 67663 91587 ^ SO ` tic ji iojso Loi cs'1-1 "H*: r*1 la , * "r - " ^' ` ' e.cT-yl o..: I..: lie ,1 j v . - , 7 ^ i"i M i 1.0' '*;: 1.0 "* , i.nitre! i i ,, l. . . '. j_ 1 3 '\-> .-nxl xi i? J iiyuxOCil-LOxlds an i.solc anthracans antimony (total) arsenic (total) auramine 1,2 - benzanthracene benzene benzidine 3,4 - benzofluoranthene 11,12 - benzofluoranthene 1,12- --benxoperylene 3,4 - benzopyrene (benzo (a)pyrene) benzotrichloride benzylaraine beryllium (total) alpha BHC beta BHC gamma BHC (Lindane) delta BHC bis (2 - chlorosthoxy) methane bis (2 - chloroethyl) ether bis (2 - chloroisopropyl) ether bromoform (tribromorr.e thane) 4 -- bromODhenvl phenyl ether cadmium (total) carbon tetrachloride (tetrachiorome.-ethane] chlorcar.e (technical mixture and me1 2 - chloroaniline _-- . 3 - chloroaniline 4 - chloroaniline chlorobenzene chlorodibrcmomethane 2 - chloroethyl vinyl ether 'mixed) chloroform (trichlor.on'.ethane) 2 - chloronaohthalene * Chemical Abstract.*; Service 1'umber COLORXTE 017060 / cess R "In tod /VO, CeIvatol 20WO Mothocel, IP cps 65 )ig Me timed, 50 cps 65 hg - Tri butyl Phosphate." -- Lauroyl Peroxide . Sodium Bicarbonate " lonol 40% DhW-SO - Avlrol P0L-1-S' Nino.i 12 SI Colloids 581-B AF--60 . Tri sod iin Phosphate Sodium Carbonate Tween 20 TricK'funol Vinyl Chloride 1 . Vinyl Acetate - Trichloroetlylene -- TATC Epoxol 9-5 ' - Sodium Bisulfite . Liq - rsol 223M Annonium Persulfate Anhydrous Ammonia Me thouel, 100 cps 90 hg IIoriTcl Gelatin r>lend Colloids 991 Sodium Acetate Aqueous Ammoniax rt-s Phenol (10% in MeOH)'- Sbeli Sol 71 - 7s~>> Operating Supplies Glycerine .. Nitrogen Hiiostop N , Air, breathing i i, RAW MATERIALS LIS! Boiler House - Effluent Plan! Phosphoric Acid 75% ' Aqueous Air.moiiia 28% : - Begreaser 701 {|6 fuel Oil 0.3% sulfur irnx.x i|4 ruel Oil e Muriatic Acid (128 lbs/13 gal) _ Caustic Liquid - Liquid Chlorine . j Ferric Sulfate - Calcium Hypochlorite, granular (65-70%) Hydrated Lime, low mg . Solar Salt (rock) Sink Floe AZ-6 ^ Sulfuric Acid 66 - Octafilm 2 Fuel Oil L Polyfloc 1120 7 ' ; i_ i yy Refoamer 300-66 x Liqni-Treat CL-2247 Betz Slimicidc C-30 % Betz Fuel-Solv TS-20 Betz Fuel-Solv rS-534 Pulverized Quick Lime Corrogen - 1. '/ y . ,,. Peri`o us Sulfate 6 1- Arco Chcm RW-S77 Miscellaneous Ethylene Glycol ^Methanol Acetone Solvesso 100 T11F Calcium Chloride,; Sand \\Perchloroethylene . R.A, Lop'ewski 4/12/79 \ \ COLOR!TE 017061