Document N21MqRY39VxZRpp2Ve19RNbwD

7039 Chemical Abiirads 7040 ' Vol 05, 1900 33--ALIPHATIC COMPOUNDS Latmcncs L mitMN a* majlat u taxi C&lorscoxbo&s aod chJorohydrocirboas: chlorinated paraffias. ChJorocirboaa and chiorohydroearbons: oily! chloride. B. j| D, W. F. KartJtt. KirkdJtkmrr Emtytl. Cnrir.. Trrhnei., 2nd Ed. ( Ptlorx. K*rk-Oinmcr Encytl. Curm, Tccktud.. 2nd Ed. 5. ^O.Vjjl 5, Z3HO(19CiyEnc). A review on chlniut^ deriv*. of ' (19G-lXEig). A review on the phys. and cheni. fw->p.-TN-* Mtsrml or synthetic higher paraffins. without regard to whether ftyp*ol ddns. to the double bond, s mple replacements v/ Cl tht parent material a normally solid or liquid. including proper* formation of allyl esters and ul N CtMiipd*., and syntluwA ,j tin, annul., economic aspects, httulliut storage, and uses. 39 complex mol*.). manuf. (mechanism. reaction varkthlrs, chh. reference*. VNJZ practice. feed prepn.. rcjc|m system. And product recMw-rv) Antamatic preparatiea gtt chromatography apparatus. Ya. --- safety and handling (toxicity, precautionary measures. au.1 3d. Kucbcrov and A. J\ Lixorub. /.V?;rperrrwO#bta t AV/lr- remedial treatment). and usr*. 25 reference*. \*N J7. Jtkim., Abad. Sank Vkt. SER. Rtsf. .1ftzntrdvms*. 33. 1965, Chlorocorboaa' cod chlorohydrocarbooa; ethyl chloride l35-40(Russ). A 1:1.0.5 isooctanc-octanc-fv>ui*c mirt. was D. W. F. Hardic. Kirk-Otkmcr Encyel. Cnrm. Trtknal,. 2nd Fd. cpd. in a column of C m. length and 10 mm. dam.. N carrier u S. H0-7(19G4X Eng). A teview on the phys. mad chcro. protn-r- edodty 0-5 Wheatstone bridee current 170 nu., re* ties, manuf.. economic aspects, standards, handbag, toxicity carder sensitivity 50 mv. Samples (3.5 cc.) were injected at and uses. 39 references. * v.Njz ' 312*, and the components were collected and frozen ia cuss tubes CtJorocarboos cad chiorohydroearbons: dichloroethrlenes at 0*. The yield of the components **3* 55-00%. although by D. W. F. Hardie. Kiri^thmrr Encytl. CMcm. Tttnnei.. 2nd Ed condensation of the vapors, the yield enuid be increased to 60%; 5. 17$-63(19CdXEnc). A review on the phys. and ehem. prniw the puripr of the collected ccnipds. was W.9%. BXJR erties. manuf., and uses of 1,1* and 1,2-dichlQroctftyicnc. jy Reactions of active nitrogen with crraaic substrates. IV.__references. VXJZ Zaopxcna. Tenikiyo Jiana/usa and Norman ,\\ Lxhtin (Boston Unrv.. Boston. Maas.). Can. J. Cam. 44(10), 1230*2(4906) (Eng); cf. CA 55, l?G22r; 64. 11070J. The reaction oi iso___jrtza with active N at 60* 12 mm. was investinted. Products Tii- and percUoroclhylese. S. A. Miller. Frtxm n.*4`~7"(6m)', 26ft>75(19Cf'X--Enf). A review of processes for tlie manuf. of C;HCU and C*CU. The relative feasibilities depend on the availability of raw materials and the utilization of by trapped at -195* were HC.W MeCH.CH;. CU,:CHa. C*H,. products. 16 references. Paul A. Haas BC-CH, propync, EtMeC.CHj. (CH; CH)r. one propane. Chlorocarbooa and cbJorobydrocarooas: chloroacctvJcnes. Monomeric products trapped at -- 7Sa but vohtiig at 60*/0.01 D. \V. F. Hardie. /TtVf-</rAier Encytl. Ck~m. Ttxknal^, 2nd j. --mm. were d-tnthylpynole. pyrrole. XHj. l-o inoisoprene, and at 12 other unidentified conpds. The polymeric product was a complex mist, which probably contained CN and amino 3, 233-5(lP0-IXng). A review on the properties of mono- ami dichloroacctvlcne. 5 rcicrcnccs. VNJ2 Chlorocxfbofl* and ch/oroeydroearbona: chlorepreae. P, S. poops. C. M. Burns Bauchwitx (E. I. du Pent de Xeniours L Co., Inc.. Wiiminzton. Study of heterogeneous oxidation f n-butenes *o 1,3-buiadiene -- Del.). Ki*i-Oihmtr Er.cyci. Chcm. Tttkncl., 2nd Ed. 5. 215-31 ia the presence of steam. I. I. Yukci'san and 'a. A. Bomsixv- (196-tXEng). A review on the phys. and chem. properties tin- sJdi. Tr. Lah. Kkxm. Vyiokemoltcul. Soedin., I crtncinsic. Lniv. dudint reactions with 0. S. SO;. N*-0. halocens. H, halidn. and 1954(3), 6o-6(Russ). ine eject of steam conca. on oxidn. of n- 'h>*por.aious acids and esters, Diels-Aldcr addns. and dmerirabaieses over newly deveiwr*ed catalysts (oxides of group VIII tions, free-radical reactions, and polymerisation), prepn. trroro modified by elements of group IV) was studied. The raw mate- , C-H; via monovinylacctyleae, butadiene, butanes and tJLencs. m] was an industrial fraction of butenes with <hc cotr.pn. Hi a and 13-dichloTO-2-butcne), irdustrial manuf., health and safety 0J, CtH 0-3, CtH 0.6, 2.5. 32.C, 7-C,H C3.4. and factors, and isomers and bomoloes. 73 references. VNJ2 C*H 1.5 taole*%. Oxido. was eStrted tn a conLutuous tlowapp. Chiorocarboax osd ehlorobydrocarhoas: trichlcrocthvUre. at C5C* srd - 2:2.5 d:21. f the huteur witu air over 1 mi. cam- I/. V, . Hardie. K'irk-OikmcT sc*,x.*. Cacm. T<cfinal.. 2r.c F` lyst (particle size 2--3 rrm.) tn a quart: tube (dio^:. S mm.). S, 2$7--5i 1954 aEnc). A review on phys. aod chem. properties. With an increase in butrne-air-HtO mole ratio :>om 1:1.G to --nunuf., economic aspects, standards, haediing, toxicity, and 3:15B, the 1^-butadiene (1) content of the contact tasincrcascd uses. 53 references. VNJZ from 33.S to 20.6 roole-% ^basis dry gas). Cun ts were obtained Ch*lsrocarbc&s and chiorohydroc&rbosx: methrlcse chloride. ahowing the dependence of total butene conversion and 1 yield per amt. of passed and dcconpd. butene on the steam conen. in tlit zoixt. From Rtf. 2A., A'aim. 196C\4). Pi. II. Abstr. Xo.4X7. MVRK CbJoritudon reaction in the manufacture of hexschloroben- D. W. x. Hardie. A'tr^^tAirer Entytl. Cnrm. Ttchnol.. 2nd Ed. 5. 111-19{ 29G-KEng). A review on the phys. and chem. proper ties, manuf., economic aspects, standards and analysis, handling, toxicity, and uses. 40 references. VNJZ Chlorocarboss sod chlorobydrocarboas: chloroform. D. \V. acne. JeTay )awrrsk.i and Tadcusz Mazomki (Katedra Tech- y. Hardie. A'>-i/:AW4er Encytl. Chem. Tttkxud.. 2nd Ed. 5. aol. Chem. Org.. I'cliteeh. Slaska.'Pobnd). Przemytl Chem. 43 21&~27( 1904/Eng). A review on phys. and chem. properties, (2), 2~4(19C4XPoJ). Continuous chlorination ef a-diehloro- manuf.. economic aspects, standards, analysts, handling, toxic- bouetie in the gas phase (at 300--(CO*) and in the presence of *__ity, and uses. 25 references. VNJZ fixed bed catalyst was invcitscated. Tht catalyst used was in Chlorocarboss aad cfclorohydrocarbons: tetrachlorocthvlene. expensive activated C. Carbopol 2. in the fnrm of irregular fromiles, about 5 mm. m diam.. with a density of 230 g-/l. and a *p_ surface area of 157.7 m.*/g. A uniform temp, gradient was obtained when the upper part of the vertical pipe reactor was D. W. r. Hardie. Ktrk^Cthmtr Emycl. Cam. TecknaL. 2nd Ed. 5, 195-203( 1954XEng)- A review on the phys. and eftem. propenim, manuf.. economic aspects, standards, handlmg. toxicity, and uses. 45 references. VNJZ -filled with less active catalyst from a previous charge. The / Chlorocarboss and chlerobydrocarbons: other chloraethanes. pse of a partly deactivated eatalyst resulted tn a total absence of catalyst baking, even when its laid was increased by 40%. The reaction produet contained more than 9"jr,' of fiexachlorobcnxcnc, besides some peatochlorubctixene. A schematic diagram of the D.W. F. Hardie. Kiek-Otkmer Encxcl. Cktm. Ttchnol., 2nd J. 5. 14S-70C 19^*4)(Engi. A review on the phys. and chcm. prop erties, manuf., economic aspects, standards, handling, toxicity, and otw of l.l-`ar.d 1^-dichlorocthaoc, 1,1.1- and 1.1.2-trt- equipment used is shown. Edward A. Ackermann Chlorination of isobutylene tn methallyl chloride. E. M. Mebrii. Kh- 2. ICotovteh. and D. X. 3*oUpko. Kkim. Rmm., chiorocthanc. 1.1.1^2- and 1,1.2,2-tetracbloroclhane. pentachiorocthanc. and hexaehloroethane. 101 references. V.NJ2 Chlorosorboss aad chlorohydtocarboas: carbon tetrachloride. Jrjcrm. Xcui.-Tekkn. Zb. 1955(4). 7-b> Ukrain). A 99.5% D. V.'. F. Hr.rdtf. Kirk^Jiftmr* Eneyrl. Chcm. Tetanol.. 2nd EJ. pure isobutylene (I) was rrefni. by dehydration of /rrf-BuOli 5.12^--31H19G4X Eng). A review on the phy*. and chem. ptupet- a Al<Oi at 350* with the 2 l./hr. ratr ol I formation. The tics, m-inuf., cfonoCTtc aspects, standards and analysis. eatalyst was reeeneratcJ at 50k-20* /or 3 hrs. tn a stream of hot cirv. and u^rs. 7.1 refcTcne. VN.I2 sir. Mixing 1-2 moles 1 with 1 mole Cl at ViMW* gave a mi\t. g byaOesa of tridlkvlanuse-type extractioo agents by the Hof ol products, which on rectification at 7iV* rave methallyl mann reaction. B. N. Lavkoriu. D. I. Sknr<*v-jrv, ;iui \ . A. chloride (11). The (tactvm cisUetrrt at 72*."T c**ti^rtcl nl a 95:4 smtio of JX and dimcthyiviuyl chbirule whirh were dciicult to a__c_p. .A. lowe..r l-Ct (uolir ratio cau*v\l cSl-rfioation of tlc bemenov. Zk. /nil. 39,5). !l*4H-55'!9i4*,k Km.-?, lab.- and bench-scale ^--lUU kc.) method- were dc^cttlwU M prepn. td KN. where R is C--Cr. KRr sai prrjwJ. !> products and a hiditr ratio decreased the yield of 2i. At '<!*, -- heating a mitt, of K01I. IIBr c*r NaBr. and, H:SO. The *wc- *G2-72.G% ykld of XI vj* obtained. ChJorocarbons and chlerobydrocarbons: BMJW phay obtained, conic. 7,%-sn% RBr ami unrracted KOII. vjoyl chloride. treated with N-"3"4% NihOll at lU^IS>Vn`rtal atm. Tl*- D. W. F. Hardie. Rtrk<.*:*mer Eneyrl. Cnrm. Tttnntd.. 2nd Ld. yvlil of KiN increased with degreasing Nllf-KHr ratio lol'-'l i 5. ITI-KI^MEhr). A review on the fhrs. and chem. proper- and with increasing icinp. The yield was not aflvctwl hy NTM *\ l tia, manuf.. eennnmir aspects, standards, handling, toxicity, conen. or tier nr R. The yield of resin N*can to icn.*r .* ai.ri uses. 3X rc/crenerx VNJZ A ;1H'*; tltr yn-ld of (oJmI ftrmiuct. prob.*llv K.Vflr, oirr-j-,l Chloracarboes and ghlorohydroearbons: methyl chloride. with deeTriMii: tmtp. The starting condition* *d ;ioim**M4i-.i- \V. K. Ifarilte. Enevtl. Cnrwt. It, in>-L, 2nd Ed. Ngaine milder a* tin* ImicIi m/v* ineteaw-il, Ikcuu-*- the fi.o ir'i - S, 101-11( r*U'i hn.'l. A fvvn-w mi (lit pUy%. ju.l chilli. (*rnp- etottierniu* au! j Lrg- U.i!eh a Uir^w |h..)*k|*hi .a u erties. nuiuil., xeUM>nite a^|rct%, staml.ird^. aiMlyi\. hamlhng, nnm*il h.it H.oi U Miull h.itt'h umlir suiuUr owoln*..>. A tsiicity, and use*. 4J rdm'ims. VNJZ typcal iiiul (KvJutt d a Cr*C prepu. contained K*N 1*5*7n. M O l: a o o i