Document Mqq5qkwvg5D3q1gZyz5w6Vyj
www.axysanalytical.com
AXYS
Axys Analytical Services Ltd
2045 Mills Road West SID N EY, BRITISH COLUMBIA, CANADA V8L 5X2
T E L 250-655-5800 FAX250-655-5811
www .axysanalytical.com
AXYS Client No.: Client Address:
4673
Cardno ENTRIX 4295 Okemos Road, Suite 101 Okemos, MI, US, 48864
The AXYS contact for these data is Kalai Pillay.
Page 1 of 49
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BATCH SUMMARY
Batch ID:
WG39768
Analysis Type: Perfluorinated Organic
Contract: Samples:
L17838-1 L17838-2 L17838-3 L17838-4
BATCH MAKEUP
4673
Reference Tiss. TCR11-0039 MSF05D 120403 MSF11D 120403 MSF24D 120405
Date: 27-Apr-2012 Matrix Type:
Tissue
Blank: WG39768-101
Reference or Spike: WG39768-102 WG39768-104 WG39768-105
Duplicate: WG39768-103
Comments: 1. Data are not blank corrected.
FQA-006 Rev. 2. 18-Jul-1994
Copyright AXYS Analytical Services Ltd February 1993
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AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. Reference Tiss. TCR11-0039 Sample Collection: N/A
3M - ALABAMA
L17838-1
Matrix:
TISSUE
Sample Size:
2.00 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 00:32:37
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 24
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
7.16
1.00 (L)
8:17
(1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFC_FC_LC_PFOA_L17838-1_Form1A_FC2G_157S24_SJ1453688.html; Workgroup: WG39768; Design ID: 1722 ]
Page 3 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. Reference Tiss. TCR11-0039 Sample Collection: N/A
3M - ALABAMA
L17838-1
Matrix:
TISSUE
Sample Size:
2.00 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 00:32:37
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 24
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0
31.5
87.6
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
10.6
88.5
7:04
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-1_Form2_FC2G_157S24_SJ1453688.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-1_Form2_FC2G_157S24_SJ1453688.html)
Page 4 of 49
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AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 Sample Collection: 03-Apr-2012
3M - ALABAMA
L17838-2 (A)
Matrix:
TISSUE
Sample Size:
2.11 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 0 1 :39:33
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 28
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
656 0.948(L)
8:17
(1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFC_FC_LC_PFOA_L17838-2_Form1A_FC2G_157S28_SJ1453692.html; Workgroup: WG39768; Design ID: 1722 ]
Page 5 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 Sample Collection: 03-Apr-2012
3M - ALABAMA
L17838-2 (A)
Matrix:
TISSUE
Sample Size:
2.11 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 0 1 :39:33
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 28
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0
28.4
79.0
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
9.77
81.5
7:06
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-2_Form2_FC2G_157S28_SJ1453692.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_L17838-2_Form2_FC2G_157S28_SJ1453692.html)
Page 6 of 49
www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF11D 120403 Sample Collection: 03-Apr-2012
3M - ALABAMA
L17838-3 N (A)
Matrix:
TISSUE
Sample Size:
2.15 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 16:11:38
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_158 S: 8
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
5
Cal. Ver. Data Filename:
FC2G 158 S: 4
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
D
3720
4.65 (L)
8:21
(1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-3_Form1A_FC2G_158S8_SJ1453777.html; Workgroup: WG39768; Design ID: 1722 ]
Page 7 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF11D 120403 Sample Collection: 03-Apr-2012
3M - ALABAMA
L17838-3 N (A)
Matrix:
TISSUE
Sample Size:
2.15 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 16:11:38
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_158 S: 8
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
5
Cal. Ver. Data Filename:
FC2G 158 S: 4
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
D
36.0
20.4
56.5
8:21
CLEANUP STANDARD
13C8-PFOA
D
12.0
8.90
74.2
7:06
(1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-3_Form2_FC2G_158S8_SJ1453777.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-3_Form2_FC2G_158S8_SJ1453777.html)
Page 8 of 49
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AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF24D 120405 Sample Collection: 05-Apr-2012
3M - ALABAMA
L17838-4
Matrix:
TISSUE
Sample Size:
2.05 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 0 1 :22:47
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 27
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
537 0.976 (L)
8:17
(1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L 17838-4_Form1 A_FC2G_157S27_SJ1453691.html; Workgroup: W G39768;DesignID: 1722 ]
Page 9 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF24D 120405 Sample Collection: 05-Apr-2012
3M - ALABAMA
L17838-4
Matrix:
TISSUE
Sample Size:
2.05 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 0 1 :22:47
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 27
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0
27.3
75.9
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
10.8
90.3
7:06
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-4_Form2_FC2G_157S27_SJ1453691.html; Workgroup: WG39768; Design ID: 1722 ]
Page 10 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. Lab Blank Sample Collection: N/A
N/A
WG39768-101
Matrix:
TISSUE
Sample Size:
2.00 g
Sample Receipt Date:
N/A
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012 Time: 23:59:06
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 22
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G _157 S: 15
Concentration Units:
ng/g
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
U
1.00 (L)
(1) W here applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-101_Form1A_FC2G_157S22_SJ1453684.html; Workgroup: WG39768; Design ID: 1722 ]
Page 11 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. Lab Blank Sample Collection: N/A
N/A
WG39768-101
Matrix:
TISSUE
Sample Size:
2.00 g
Sample Receipt Date:
N/A
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012 Time: 23:59:06
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 22
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0
33.2
92.3
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
11.2
93.7
7:04
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-101_Form2_FC2G_157S22_SJ1453684.html; Workgroup: WG39768; Design ID: 1722 ]
Page 12 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 8A
PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR)
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Lab Sample I.D.:
W G 39768-102
Matrix:
TISSUE
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012 Time: 22:51:55
Column ID:
C18MS
Extract Volume (uL):
4000
OPR Data Filename:
FC2G_157 S: 18
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS IN EXTRACT, BASED O N A 1 m L EXTRACT VOLUME.
COMPOUND
LAB FLAG 1
SPIKE CONC. (ng/mL)
CONC. FOUND (ng/mL)
% RECOVERY
RETENTION TIME
PFOS
80.0
87.1
109
8:17
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested.
For Axys Internal Use Only [ XSL Template: FC-Form8A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-102_Form8A_SJ1453676.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS METHOD MLA-043 Rev 8
Form 8B
PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR)
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Lab Sample I.D.:
W G 39768-102
Matrix:
TISSUE
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012 Time: 22:51:55
Column ID:
C18MS
Extract Volume (uL):
4000
OPR Data Filename:
FC2G_157 S: 18
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G 157 S: 15
ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS IN EXTRACT, BASED O N A 1 m L EXTRACT VOLUME.
LABELED COMPOUND
LAB FLAG 1
SPIKE CONC. (ng/mL)
CONC. FOUND (ng/mL)
% RECOVERY
RETENTION TIME
13C4-PFOS
36.0
29.0
80.5
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
11.2
93.3
7:04
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested.
For Axys Internal Use Only [ XSL Template: FC-Form8B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-102_Form8B_SJ1453676.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_WG39768-102_Form8B_SJ1453676.html)
Page 14 of 49
www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF11D 120403 (Duplicate) Sample Collection: 03-Apr-2012
3M - ALABAMA
WG39768-103 N (DUP L17838-3)
Matrix:
TISSUE
Sample Size:
2.07 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 16:28:24
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_158 S: 9
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
5
Cal. Ver. Data Filename:
FC2G _158 S: 4
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
D
3510
4.83 (L)
8:21
(1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-103_Form1A_FC2G_158S9_SJ1453778.html; Workgroup: WG39768; Design ID: 1722 ]
Page 15 of 49
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AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF11D 120403 (Duplicate) Sample Collection: 03-Apr-2012
3M - ALABAMA
WG39768-103 N (DUP L17838-3)
Matrix:
TISSUE
Sample Size:
2.07 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 16:28:24
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_158 S: 9
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
5
Cal. Ver. Data Filename:
FC2G _158 S: 4
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
D
36.0
25.9
72.0
8:21
CLEANUP STANDARD
13C8-PFOA
D
12.0
10.7
89.2
7:06
(1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-103_Form2_FC2G_158S9_SJ1453778.html; Workgroup: WG39768; Design ID: 1722 ]
Page 16 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012
3M - ALABAMA
W G39768-104 (MS)
Matrix:
TISSUE
Sample Size:
2.01 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 01:56:19
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 29
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G _157 S: 15
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
670 0.995 (L)
8:17
(1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-104_Form1A_FC2G_157S29_SJ1453693.html; Workgroup: WG39768; Design ID: 1722 ]
Page 17 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012
3M - ALABAMA
W G39768-104 (MS)
Matrix:
TISSUE
Sample Size:
2.01 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 01:56:19
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 29
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G _157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0
35.4
98.2
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
11.0
91.3
7:06
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-104_Form2_FC2G_157S29_SJ1453693.html; Workgroup: WG39768; Design ID: 1722 ]
Page 18 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012
3M - ALABAMA
WG39768-105 (MSD)
Matrix:
TISSUE
Sample Size:
2.11 g (wet)
Sample Receipt Date:
19 -A p r- 2 0 1 2
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 02:13:05
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 30
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G _157 S: 15
Concentration Units:
ng/g (wet weight basis)
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
COMPOUND
LAB FLAG 1
CONC. FOUND
REPORTING LIMIT (RL)2
RETENTION TIME
PFOS
653 0.948 (L)
8:17
(1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-105_Form1A_FC2G_157S30_SJ1453694.html; Workgroup: WG39768; Design ID: 1722 ]
Page 19 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8
Form 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Project No. Lab Sample I.D.:
CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012
3M - ALABAMA
WG39768-105 (MSD)
Matrix:
TISSUE
Sample Size:
2.11 g (wet)
Sample Receipt Date:
19-Apr-2012
Initial Calibration Date:
24-Apr-2012
Extraction Date:
23-Apr-2012
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012 Time: 02:13:05
Column ID:
C18MS
Extract Volume (uL):
4000
Sample Data Filename:
FC2G_157 S: 30
Injection Volume (uL):
15
Blank Data Filename:
FC2G _157 S: 22
Dilution Factor:
N/A
Cal. Ver. Data Filename:
FC2G _157 S: 15
Concentration Units:
ng absolute
This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested.
LABELED COMPOUND
LAB FLAG1
SPIKE CONC.
CONC. FOUND
R(%) 2
RETENTION TIME
13C4-PFOS
36.0 37.1 103
8:17
CLEANUP STANDARD
13C8-PFOA
12.0
10.9
91.1
7:04
(1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-105_Form2_FC2G_157S30_SJ1453694.html; Workgroup: WG39768; Design ID: 1722 ]
Page 20 of 49
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8 Form 3A
PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
CS0 Data Filename: CS1 Data Filename:
FC2G _157 S: 4 FC2G _157 S: 5
Instrument ID:
LC MS/MS
CS2 Data Filename:
FC2G _157 S: 6
LC Column ID:
C18MS
CS3 Data Filename:
FC2G _157 S: 7
CS4 Data Filename:
FC2G _157 S: 8
CS5 Data Filename:
FC2G _157 S: 9
CS6 Data Filename:
FC2G _157 S: 10
CS7 Data Filename:
FC2G _157 S: 11
CS8 Data Filename:
N/A
COMPOUND PFOS
LAB FLAG1
CS0 104
CS1 91.9
CS2 86.4
PERCENT RECOVERY (%) CS3 CS4 CS5
105 99.5 112
CS6 101
CS7 99.7
CS8
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Kristina Coleman______
For Axys Internal Use Only [ XSL Template: FC-Form3A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3A_GS45507.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3A_GS45507.html)
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8 Form 3B
PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
CS0 Data Filename: CS1 Data Filename:
FC2G _157 S: 4 FC2G _157 S: 5
Instrument ID:
LC MS/MS
CS2 Data Filename:
FC2G _157 S: 6
LC Column ID:
C18MS
CS3 Data Filename:
FC2G _157 S: 7
CS4 Data Filename:
FC2G _157 S: 8
CS5 Data Filename:
FC2G _157 S: 9
CS6 Data Filename:
FC2G _157 S: 10
CS7 Data Filename:
FC2G _157 S: 11
CS8 Data Filename:
N/A
LABELED COMPOUND
13C4-PFOS CLEAN-UP STANDARD 13C8-PFOA
LAB FLAG1
CS0 103
101
CS1 82.4 99.6
PERCENT RECOVERIES (%) CS2 CS3 CS4 CS5 CS6
92.7
86.9
104
103
111
94.3
98.3
101
98.9
103
CS7 117 104
CS8
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Kristina Coleman______
For Axys Internal Use Only [ XSL Template: FC-Form3B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3B_GS45507.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3B_GS45507.html)
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8 Form 3C
PERFLUORINATED ORGANICS INITIAL CALIBRATION RETENTION TIMES
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
CS0 Data Filename: CS1 Data Filename:
FC2G _157 S: 4 FC2G _157 S: 5
Instrument ID:
LC MS/MS
CS2 Data Filename:
FC2G _157 S: 6
LC Column ID:
C18MS
CS3 Data Filename:
FC2G _157 S: 7
CS4 Data Filename:
FC2G _157 S: 8
CS5 Data Filename:
FC2G _157 S: 9
CS6 Data Filename:
FC2G _157 S: 10
CS7 Data Filename:
FC2G _157 S: 11
CS8 Data Filename:
N/A
COMPOUND PFOS
LAB FLAG1
CS0 8:17
CS1 8:17
CS2 8:17
RETENTION TIMES
CS3
CS4
CS5
8:17
8:17
8:17
CS6 8:17
CS7 8:17
CS8 MEAN RT
8:17
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Kristina Coleman______
For Axys Internal Use Only [ XSL Template: FC-Form3C.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3C_GS45507.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3C_GS45507.html)
Page 23 of 49
www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8 Form 3D
PERFLUORINATED ORGANICS INITIAL CALIBRATION RETENTION TIMES
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
CS0 Data Filename: CS1 Data Filename:
FC2G _157 S: 4 FC2G _157 S: 5
Instrument ID:
LC MS/MS
CS2 Data Filename:
FC2G _157 S: 6
LC Column ID:
C18MS
CS3 Data Filename:
FC2G _157 S: 7
CS4 Data Filename:
FC2G _157 S: 8
CS5 Data Filename:
FC2G _157 S: 9
CS6 Data Filename:
FC2G _157 S: 10
CS7 Data Filename:
FC2G _157 S: 11
CS8 Data Filename:
N/A
LABELED COMPOUND
13C4-PFOS CLEAN-UP STANDARD 13C8-PFOA
LAB FLAG1
RETENTION TIMES CS0 CS1 CS2 CS3 CS4 CS5 CS6 CS7
8:17
8:17
8:17
8:17
8:21
8:17
8:17
8:17
CS8
MEAN RT
8:18
7:04
7:04
7:04
7:04
7:04
7:04
7:04
7:04
7:04
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Kristina Coleman______
For Axys Internal Use Only [ XSL Template: FC-Form3D.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3D_GS45507.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3D_GS45507.html)
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www.axysanalytical.com
AXYS METHOD MLA-043 Rev 8 Form 4A
PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
VER Data Filename:
FC2G _157 S: 15
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012
LC Column ID:
C18MS
Analysis Time:
2 2 :0 1 :37
COMPOUND PFOS
LAB FLAG1
RETENTION TIME 8:17
EXPECTED CONC. (ng)
80.0
CONC. FOUND (ng)
86.8
RECOVERY (%) 108
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA _FC_LC_FC2GJ57S15_Form4A_SJ1453671.html; Workgroup: WG39768; Design ID: 1722 ]
Page 1 of 1 (WG39768 -PFOA_FC_LC_FC2G_157S15__Form4A_SJ1453671.html)
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AXYS METHOD MLA-043 Rev 8 Form 4B
PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
VER Data Filename:
FC2G _157 S: 15
Instrument ID:
LC MS/MS
Analysis Date:
24-Apr-2012
LC Column ID:
C18MS
Analysis Time:
2 2 :0 1 :37
LABELED COMPOUND
13C4-PFOS CLEANUP STANDARD 13C8-PFOA
LAB FLAG 1
RETENTION TIME 8:17
EXPECTED CONC. (ng)
36.0
CONC.FOUND (ng)
36.0
R E C O V E R Y (%) 100
7:06
12.0
12.1
101
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA _FC_LC_FC2GJ57S15_Form4B_SJ1453671.html; Workgroup: WG39768; DesignID: 1722 ]
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AXYS METHOD MLA-043 Rev 8 Form 4A
PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
VER Data Filename:
FC2G _158 S: 4
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012
LC Column ID:
C18MS
Analysis Time:
15:04:34
COMPOUND PFOS
LAB FLAG1
RETENTION TIME 8:17
EXPECTED CONC. (ng)
80.0
CONC. FOUND (ng)
81.1
RECOVERY (%) 101
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFOA_FC_LC_FC2G_158S4__Form4A_SJ1453773.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS METHOD MLA-043 Rev 8 Form 4B
PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Initial Calibration Date:
24-Apr-2012
VER Data Filename:
FC2G _158 S: 4
Instrument ID:
LC MS/MS
Analysis Date:
25-Apr-2012
LC Column ID:
C18MS
Analysis Time:
15:04:34
LABELED COMPOUND
13C4-PFOS CLEANUP STANDARD 13C8-PFOA
LAB FLAG 1
RETENTION TIME 8:21
EXPECTED CONC. (ng)
36.0
CONC.FOUND (ng)
28.3
RECOVERY (%) 78.6
7:06
12.0
11.8
98.3
(1) Where applicable, custom lab flags have been used on this report.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_FC2G_158S4__Form4B_SJ1453773.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS METHOD MLA-043 Rev 8
PERFLUORINATED ORGANICS ANALYSIS REPORT RELATIVE PERCENT DIFFERENCE
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Project No.
Contract No.:
4673
Client ID:
MSF11D 120403
Concentration Units:
3M - ALABAMA ng/g (wet weight basis)
COMPOUND PFOS
L17838-3 (A)_______
LAB FLAG1
CONC. FOUND
D 3720
WG39768-103
LAB FLAG 1
CONC. FOUND
D 3510
MEAN 3620
RELATIVE PERCENT DIFFERENCE
5.77
(1) Where applicable, custom lab flags have been used on this report; D = dilution data.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
These pages are part o f a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested.
For Axys Internal Use Only [ XSL Template: RPD.xsl; Created: 27-Apr-2012 15:00:24; Application: XMLTransformer-1.12.13; ReportFilename: RPD_FC_LC_PFOA-RPD_WG39768-103_L17838-3_.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS METHOD MLA-043 Rev 8
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4673
Form 8C PERFLUORINATED ORGANICS MATRIX SPIKE (MS)
ANALYSIS REPORT
Project No.
Lab Sample I.D.:
Matrix:
TISSUE
Sample Size:
Extraction Date:
23-Apr-2012
Initial Calibration Date:
Analysis Date:
25-Apr-2012 Time: 01:56:19
Instrument ID:
Extract Volume (uL):
4000
Column ID:
Injection Volume (uL):
15
MS Data Filename:
Dilution Factor:
N/A
Blank Data Filename:
Cal. Ver. Data Filename:
CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012
3M - ALABAMA W G39768-104 (MS) 2.01 g (wet) 24-Apr-2012 LC MS/MS C18MS FC2G_157 S: 29 FC2G _157 S: 22 FC2G 157 S: 15
ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS ON SAMPLE SIZE BASIS
COMPOUND PFOS
LAB FLAG1
ION ABUND.
RATIO
N/A
SPIKE CONC (ng/g)
39.8
SAMPLE LAB
FLAG 1
SAMPLE CONC (ng/g)
656
CONC. FOUND (ng/g)
670
MS R% 2
36.4
REL %
DIFF
(1) Where applicable, custom lab flags have been used on this report. (2) R% = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested.
For Axys Internal Use Only [ XSL Template: MS.xsl; Created: 27-Apr-2012 15:00:16; Application: XMLTransformer-1.12.13; Report Filename: MS_FC_LC_PFOA-MS-MSD_WG39768-104_L17838-2_Form8C.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS METHOD MLA-043 Rev 8
Form 8E PERFLUORINATED ORGANICS MATRIX SPIKE DUPLICATE (MSD)
ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811
Project No.
Contract No.:
4673
Lab Sample I.D.:
Matrix:
TISSUE
Sample Size:
Extraction Date:
23-Apr-2012
Initial Calibration Date:
Analysis Date:
25-Apr-2012 Time: 02:13:05
Instrument ID:
Extract Volume (uL):
4000
Column ID:
Injection Volume (uL):
15
MSD Data Filename:
Dilution Factor:
N/A
Blank Data Filename:
Cal. Ver. Data Filename:
CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012
3M - ALABAMA W G39768-105 (MSD) 2.11 g (wet) 24-Apr-2012 LC MS/MS C18MS FC2G_157 S: 30 FC2G _157 S: 22 FC2G 157 S: 15
ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS ON SAMPLE SIZE BASIS
COMPOUND PFOS
LAB FLAG1
ION ABUND. RATIO
N/A
SPIKE CONC (ng/g)
37.9
SAMPLE LAB
FLAG 1
SAMPLE CONC (ng/g)
656
CONC. FOUND (ng/g)
653
MSD R% 2
REL %
DIFF
(1) Where applicable, custom lab flags have been used on this report. (2) R% = percent recovery.
These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes.
Signed:____________ Bryan Alonzo______
These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested.
For Axys Internal Use Only [ XSL Template: MS.xsl; Created: 27-Apr-2012 15:00:16; Application: XMLTransformer-1.12.13; Report Filename: MS_FC_LC_PFOA-MS-MSD_WG39768-105_L17838-2_Form8E.html; Workgroup: WG39768; Design ID: 1722 ]
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AXYS Analytical Services Ltd.
Table 1a NELAP Accreditation Held by AXYS Analytical Services Ltd. for Chlorinated Dioxins/Furans, Chlorinated Pesticides, PCBs and PAHs
Matrix Codes for Table 1a
NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue
Accreditation Method Codes and Explanation for Table 1
Code Accreditation Certificate Applicable AXYS Method and Description No. Method Reference
1 EPA 1613B
MLA-017, performance based implementation of EPA1613B (GC/HRMS)
2 EPA 8290
MLA-017, performance based implementation of EPA 8290 (Gc /HRMS)
3 AXYS MLA-017
MLA-017, performance based implementation of EPA 1613B, 8290 (GC/HRMS)
4 EPA 608
MLA-007, performance based implementation of EPA 608 (GC/ECD)
5
EPA 8270C or 8270D
MLA-007, performance based modification of 8270C/D (GC/LRMS)
6
EPA8081Aor8081B
MLA-007, performance based implementation of EPA 8081A/B (GC/ECD)
7 EPA 1668A
MLA-010, performance based implementation of EPA 1668A (GC/HRMS)
8 SM 6630B
MLA-007, performance based implementation of SM 18-20 6630B (GC/ECD)
9 EPA 1625B
MLA-021, performance based modification of EPA 1625B (GC/LRMS)
11 EPA 625
MLA-007, performance based modification of EPA 625 (g C/LRMS)
20
EPA 8270C or 8270D
MLA-021, performance based modification of EPA 8270C/D (GC/LRMS)
TABLE 1
PCDD/F - Polychlorinated Dioxins and Furans Dioxins Dioxins and Dibenzofurans 1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDD
ACC-101 Rev 06, 29-Jun-2011
New York State
D epartm ent of Health
Lab ID 11674 NELAP Primary
NP W
S
California D epartm ent
of Public Health
Lab ID 01138CA
NELAP Secondary
NP W
S
1 2
12 12 12 12 12 12
State of Florida D ep artm en t
of Health
Lab ID E871007 NELAP Primary
Dr. NP WW
S
T
1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
State of New Jersey Department of E n viro n m en tal Protection
Lab ID CANA005 NELAP Secondary
Dr. NP WW
S
T
12 2 12 2 12 2 12 2 12 2 12 2
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TABLE 1
1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDD 1,2,3,7,8,9-HxCDF 1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDF 2,3,4,6,7,8-HxCDF 2,3,4,7,8-PeCDF 2,3,7,8-TCDD 2,3,7,8-TCDF OCDD OCDF Total TCDD Total TCDF Total PeCDD Total PeCDF Total HxCDD Total HxCDF Total HpCDD Total HpCDF
PCBs - Polychlorinated biphenyls
PCB 1
2-Chlorobiphenyl
PCB 3
4-Chlorobiphenyl
PCB 4
2,2'-Dichlorobiphenyl
PCB 5
2,3-Dichlorobiphenyl
PCB 15
4,4'-Dichlorobiphenyl
PCB 18
2,2',5-Trichlorobiphenyl
PCB 19
2,2',6-Trichlorobiphenyl
PCB 31
2,4',5-Trichlorobiphenyl
PCB 37
3,4,4'-Trichlorobiphenyl
PCB 44
2,2',3,5'-Tetrachlorobiphenyl
PCB 52
2,2',5,5'-Tetrachlorobiphenyl
PCB 54
2,2',6,6'-Tetrachlorobiphenyl
PCB 66
2,3',4,4'-Tetrachlorobiphenyl
PCB 77
3,3',4,4'-Tetrachlorobiphenyl
PCB 81
3,4,4',5-Tetrachlorobiphenyl
PCB 87
2,2',3,4,5'-Pentachlorobiphenyl
ACC-101 Rev 06, 29-Jun-2011
AXYS Analytical Services Ltd.
New York State
D epartm ent of Health
Lab ID 11674 NELAP Primary
NP W
S
1
California D epartm ent
of Public Health
Lab ID 01138CA
NELAP Secondary
NP W
S
12 12 12 12 12 12 12 12 12 12 12 1 1 1 1 1 1 1 1
State of Florida D epartm ent
of Health
Lab ID E871007 NELAP Primary
Dr. NP WW
S
T
1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2 , 3 1, 2, 3 1, 2, 3 1, 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3
State of New Jersey Department of E n viro n m en tal Protection
Lab ID CANA005 NELAP Secondary
Dr. NP
WW
1 1 1 1 1 1 1 1 1 1 1
S
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
T
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77
Page 2 of 18
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AXYS Analytical Services Ltd.
TABLE 1
PCB 101 PCB 104 PCB 105 PCB 109 PCB 114 PCB 118 PCB 123 PCB 124 PCB 126 PCB 138 PCB 141 PCB 151 PCB 153 PCB 155 PCB 156 PCB 157 PCB 167 PCB 169 PCB 170 PCB 180 PCB 183 PCB 187 PCB 188 PCB 189 PCB 202 PCB 205 PCB 206 PCB 208 PCB 209 Aroclor 1260 Aroclor 1254 Aroclor 1221 Aroclor 1232 Aroclor 1248 Aroclor 1016 Aroclor 1242
2,2',4,5,5'-Pentachlorobiphenyl 2,2',4,6,6'-Pentachlorobiphenyl 2,3,3',4,4'-Pentachlorobiphenyl 2,3,3',4,6-Pentachlorobiphenyl 2,3,4,4',5-Pentachlorobiphenyl 2,3',4,4',5-Pentachlorobiphenyl 2,3',4,4',5'-Pentachlorobiphenyl 2,3',4',5,5'-Pentachlorobiphenyl 3,3',4,4',5-Pentachlorobiphenyl 2,2',3,4,4',5'-Hexachlorobiphenyl 2,2',3,4,5,5'-Hexachlorobiphenyl 2,2',3,5,5',6-Hexachlorobiphenyl 2,2',4,4',5,5'-Hexachlorobiphenyl 2,2',4,4',6,6'-Hexachlorobiphenyl 2,3,3',4,4',5-Hexachlorobiphenyl 2,3,3',4,4',5'-Hexachlorobiphenyl 2,3',4,4',5,5'-Hexachlorobiphenyl 3,3',4,4',5,5'-Hexachlorobiphenyl 2,2',3,3',4,4',5-Heptachlorobiphenyl 2,2',3,4,4',5,5'-Heptachlorobiphenyl 2,2',3,4,4',5',6-Heptachlorobiphenyl 2,2',3,4',5,5',6-Heptachlorobiphenyl 2,2',3,4',5,6,6'-Heptachlorobiphenyl 2,3,3',4,4',5,5'-Heptachlorobiphenyl 2,2',3,3',5,5',6,6'-Octachlorobiphenyl 2,3,3',4,4',5,5',6-Octachlorobiphenyl 2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl Decachlorobiphenyl
New York State
D epartm ent of Health
Lab ID 11674 NELAP Primary
NP W
S
77 77 77 77 77 77 77
California D epartm ent
of Public Health
Lab ID 01138CA
NELAP Secondary
NP W
S
7 7 7 7 7 7
7 7 7 7 7 7 7 7 7 7 7 7 7 7 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11
7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7
5, 7 5, 7 5, 7 5, 7 5, 7 5, 7 5, 7
11 11 11 11 11 11 11
5 5 5 5 5 5 5
State of Florida D epartm ent
of Health
Lab ID E871007 NELAP Primary
Dr. NP WW
S
T
ACC-101 Rev 06, 29-Jun-2011
State of New Jersey Department of E n viro n m en tal Protection
Lab ID CANA005 NELAP Secondary
Dr. NP
WW
7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7
S
7 7 7 7 7 7 7 7 7 7 7 7 7 7
7 7 7 7 7 7 7 7 7 7
7 7 7
T
Page 3 of 18
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TABLE 1
Pesticides 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) Chlordane, technical Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde trans-Chlordane (gamma-Chlordane) Gamma-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Methoxychlor Mi rex
PAH Anthracene Pyrene Benzo[ghilperylene Indeno[1,2,3-cdlpyrene Benzo[blfluoranthene Fluoranthene Benzo[klfluoranthene Acenaphthylene Chrysene Benzo[a]pyrene Dibenz[ahlanthracene Benz[alanthracene
ACC-101 Rev 06, 29-Jun-2011
AXYS Analytical Services Ltd.
New York State
D epartm ent of Health
Lab ID 11674 NELAP Primary
NP W
S
California D epartm ent
of Public Health
Lab ID 01138CA
NELAP Secondary
NP W
S
State of Florida D epartm ent
of Health
Lab ID E871007 NELAP Primary
Dr. NP WW
S
T
11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 55 5, 11 5 11 5 11 5 11 5 4646 4646 4646 4646 4646 4646 55 11 5 11 5 11 5 11 5 4646 9595 4,8 6 8 6 5
State of New Jersey Department of E n viro n m en tal Protection
Lab ID CANA005 NELAP Secondary
Dr. NP WW
S
T
9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20
9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20
Page 4 of 18
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TABLE 1
Acenaphthene Phenanthrene Fluorene Naphthalene
AXYS Analytical Services Ltd.
New York State
D epartm ent of Health
Lab ID 11674 NELAP P rim a ry
NP W
S
9 20 9 20 9 20 9 20
California D epartm ent
of Public Health
Lab ID 01138CA
NELAP Secondary
NP W
S
9 20 9 20 9 20 9 20
State of Florida D epartm ent
of Health
Lab ID E871007 NELAP Primary
Dr. NP WW
S
T
State of New Jersey Department of E n viro n m en tal Protection
Lab ID C AN A005 NELAP Secondary
Dr. NP WW
S
T
ACC-101 Rev 06, 29-Jun-2011
Page 5 of 18
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AXYS Analytical Services Ltd.
Matrix Codes for Table 1b
NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue
Table 1b NELAP Accreditation Held by AXYS Analytical Services Ltd.
for Perfluorinated Organic Compounds
Accreditation Method Codes and Explanation for Table 1b
Code Accreditation Certificate Applicable AXYS Method and Description No. Method Reference
12 AXYS MLA-041 13 AXYS MLA-043 14 AXYS MLA-060
MLA-041, laboratory performance based method (LC/MS-MS) MLA-043, laboratory performance based method (LC/MS-MS) MLA-060, laboratory performance based method (LC/MS-MS)
TABLE 1
State of Florida D epartm ent
of Health
Lab ID E871007
NELAP Primary
Dr. NP WW
S
T
Minnesota Department of Health
Lab ID 232-999-430
NELAP Primary!
Dr. NP WW
S
T
State of New Jersey Department of E n viro n m en tal Protection
Lab ID CANA005
NELAP Secondary
Dr. NP WW
S
T
PFC - Perfluorinated Organic Compounds
Perfluorobutanoate (PFBA) Note Perfluoropentanoate (PFPeA) Note
Perfluorohexanoate (PFHxA) Note
Perfluoroheptanoate (PFHpA) Note
Perfluorooctanoate (PFOA) Nte
Perfluorononanoate (PFNA) Note
Perfluorodecanoate (PFDA) Note
Perfluoroundecanoate (PFUnA)
N ote N
Perfluorododecanoate (PFDoA)
N ote N
Perfluorobutanesulfonate (PFBS)
Perfluorohexanesulfonate (PFHxS)
Perfluorooctanesulfonate (PFOS)
Perfluorooctane sulfonamide (PFOSA)
14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13
Note: Accreditations by Minnesota Department of Health and New Jersey Department of Environmental Protection are against the corresponding acid form of the anion shown.
ACC-101 Rev 06, 29-Jun-2011
Page 6 o f 18
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AXYS Analytical Services Ltd.
Table 2: Canadian and US State Specific Accreditation Held by AXYS Analytical Services Ltd.
Matrix Codes for Table 2
NP W = Non-Potable Water Dr. W = Drinking Water W = Aqueous S = Solid T = Tissue
Accreditation Method Codes and Explanation for Table 2
Code Accreditation Certificate No. Method Reference
Applicable AXYS Method and Description
1 EPA 1613 3 AXYS MLA-017 7 EPA 1668A 10 AXYS MLA-007
12 AXYS MLA-041 13 AXYS MLA-043 14 AXYS MLA-060 15 AXYS MLA-010 16 AXYS MLA-028 17 AXYS MLA-033 18 AXYS MLA-021 19 AXYS MLA-075
MLA-017 Performance based implementation of EPA 1613B (GC/HRMS) MLA-017 Performance based implementation of EPA 1613B (g C/HRMs ) MLA-010 Performance based implementation of EPA 1668A (GC/HRMs ) MLA-007, Performance based modification of EPA 8270C/D, 8081A/B (GC/LRMS and GC/ECD) MLA-041 Laboratory performance based method (LC/MS-MS) MLA-043 Laboratory performance based method (LC/MS-MS) MLA-060 Laboratory performance based method (LC/MS-MS) MLA-010 Performance based implementation of EPA 1668A (GC/HRMS) MLA-028 Laboratory performance based method (GC/HRMS) MLA-033 Performance based implementation of EPA 1614 (Gc /HRMS) MLA-021 Performance based modification of EPA 8270C/D (GC/LRMS) MLA-075 Performance based implementation of EPA 1694 (LC/MS-MS)
TABLE 2
PCDD/F - Polychlorinated Dioxins and Furans 1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDD 1,2,3,7,8,9-HxCDF 1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDF 2,3,4,6,7,8-HxCDF 2,3,4,7,8-PeCDF 2,3,7,8-TCDD 2,3,7,8-TCDF OCDD OCDF Total TCDD Total TCDF Total PeCDD Total PeCDF Total HxCDD
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W
11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11
Page 7 of 18 Page 38 of 49
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AXYS Analytical Services Ltd.
TABLE 2
Total HxCDF Total HpCDD Total HpCDF Total PCDD Total PCDF Total PCDD + PCDF
PCBs - Polychlorinated biphenyls
PCB 1
2-Chlorobiphenyl
PCB 2
3-Chlorobiphenyl
PCB 3
4-Chlorobiphenyl
PCB 4
2,2'-Dichlorobiphenyl
PCB 5
2,3-Dichlorobiphenyl
PCB 6
2,3'-Dichlorobiphenyl
PCB 7
2,4-Dichlorobiphenyl
PCB 8
2,4'-Dichlorobiphenyl
PCB 8/5
PCB 9
2,5-Dichlorobiphenyl
PCB 10
2,6-Dichlorobiphenyl
PCB 11
3,3'-Dichlorobiphenyl
PCB 12
3,4-Dichlorobiphenyl
PCB 13
3,4'-Dichlorobiphenyl
PCB 14
3,5-Dichlorobiphenyl
PCB 15
4,4'-Dichlorobiphenyl
PCB 16
2,2',3-T richlorobiphenyl
PCB 16/32
PCB 17
2,2',4-T richlorobiphenyl
PCB 18
2,2',5-Trichlorobiphenyl
PCB 19
2,2',6-T richlorobiphenyl
PCB 20
2,3,3'-T richlorobiphenyl
PCB 21
2,3,4-T richlorobiphenyl
PCB 22
2,3,4'-T richlorobiphenyl
PCB 23
2,3,5-T richlorobiphenyl
PCB 24
2,3,6-T richlorobiphenyl
PCB 24/27
PCB 25
2,3',4-T richlorobiphenyl
PCB 26
2,3',5-Trichlorobiphenyl
PCB 27
2,3',6-T richlorobiphenyl
PCB 28
2,4,4'-T richlorobiphenyl
PCB 29
2,4,5-T richlorobiphenyl
PCB 30
2,4,6-T richlorobiphenyl
PCB 31
2,4',5-Trichlorobiphenyl
PCB 32
2,4',6-T richlorobiphenyl
PCB 33
2,3',4'-T richlorobiphenyl
PCB 33/20/21
PCB 34
2,3',5'-T richlorobiphenyl
PCB 35
3,3',4-T richlorobiphenyl
PCB 36
3,3',5-T richlorobiphenyl
PCB 37
3,4,4'-T richlorobiphenyl
PCB 38
3,4,5-T richlorobiphenyl
PCB 39
3,4',5-T richlorobiphenyl
PCB 40
2,2',3,3'-Tetrachlorobiphenyl
PCB 41
2,2',3,4-Tetrachlorobiphenyl
PCB 41/71/64/68
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 11 11 11 11 11 11
15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 18 15 15 15 15 15 15 10, 15 15 10
15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10
15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10
77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77
Page 8 of 18 Page 39 of 49
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AXYS Analytical Services Ltd.
TABLE 2
PCB 42 PCB 42/59 PCB 43 PCB 44 PCB 45 PCB 46 PCB 47 PCB 47/48/75 PCB 48 PCB 49 PCB 49/43 PCB 50 PCB 51 PCB 52 PCB 52/73 PCB 53 PCB 54 PCB 55 PCB 56 PCB 56/60 PCB 57 PCB 58 PCB 59 PCB 60 PCB 61 PCB 62 PCB 63 PCB 64 PCB 65 PCB 66 PCB 66/80 PCB 67 PCB 68 PCB 69 PCB 70 PCB 70/76 PCB 71 PCB 72 PCB 73 PCB 74 PCB 74/61 PCB 75 PCB 76 PCB 77 PCB 78 PCB 79 PCB 80 PCB 81 PCB 82 PCB 83 PCB 83/108 PCB 84 PCB 85 PCB 85/120
2,2',3,4'-Tetrachlorobiphenyl
2,2',3,5-Tetrachlorobiphenyl 2,2',3,5'-Tetrachlorobiphenyl 2,2',3,6-Tetrachlorobiphenyl 2,2',3,6'-Tetrachlorobiphenyl 2,2',4,4'-Tetrachlorobiphenyl
2,2',4,5-Tetrachlorobiphenyl 2,2',4,5'-Tetrachlorobiphenyl
2,2',4,6-Tetrachlorobiphenyl 2,2',4,6'-Tetrachlorobiphenyl 2,2',5,5'-Tetrachlorobiphenyl
2,2',5,6'-Tetrachlorobiphenyl 2,2',6,6'-Tetrachlorobiphenyl 2,3,3',4-Tetrachlorobiphenyl 2,3,3',4'-Tetrachlorobiphenyl
2,3,3',5-Tetrachlorobiphenyl 2,3,3',5'-Tetrachlorobiphenyl 2,3,3',6-Tetrachlorobiphenyl 2,3,4,4'-Tetrachlorobiphenyl 2,3,4,5-Tetrachlorobiphenyl 2,3,4,6-Tetrachlorobiphenyl 2,3,4',5-Tetrachlorobiphenyl 2,3,4',6-Tetrachlorobiphenyl 2,3,5,6-Tetrachlorobiphenyl 2,3',4,4'-Tetrachlorobiphenyl
2,3',4,5-Tetrachlorobiphenyl 2,3',4,5'-Tetrachlorobiphenyl 2,3',4,6-Tetrachlorobiphenyl 2,3',4',5-Tetrachlorobiphenyl
2,3',4',6-Tetrachlorobiphenyl 2,3',5,5'-Tetrachlorobiphenyl 2,3',5',6-Tetrachlorobiphenyl 2,4,4',5-Tetrachlorobiphenyl
2,4,4',6-Tetrachlorobiphenyl 2,3',4',5'-Tetrachlorobiphenyl 3,3',4,4'-Tetrachlorobiphenyl 3,3',4,5-Tetrachlorobiphenyl 3,3',4,5'-Tetrachlorobiphenyl 3,3',5,5'-Tetrachlorobiphenyl 3,4,4',5-Tetrachlorobiphenyl 2,2',3,3',4-Pentachlorobiphenyl 2,2',3,3',5-Pentachlorobiphenyl
2,2',3,3',6-Pentachlorobiphenyl 2,2',3,4,4'-Pentachlorobiphenyl
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W
15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10
S
15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10
Pulp
T
15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 77
77 77 77 77 77
77 77
77 77 77
77 77 77 77
77 77 77 77 77 77 77 77 77 77
77 77 77 77
77 77 77 77
77 77 77 77 77 77 77 77 77
77 77
Page 9 of 18 Page 40 of 49
www.axysanalytical.com
AXYS Analytical Services Ltd.
TABLE 2
PCB 86
2,2',3,4,5-Pentachlorobiphenyl
PCB 87
2,2',3,4,5'-Pentachlorobiphenyl
PCB 87/115/116
PCB 88
2,2',3,4,6-Pentachlorobiphenyl
PCB 89
2,2',3,4,6'-Pentachlorobiphenyl
PCB 90
2,2',3,4',5-Pentachlorobiphenyl
PCB 91
2,2',3,4',6-Pentachlorobiphenyl
PCB 92
2,2',3,5,5'-Pentachlorobiphenyl
PCB 93
2,2',3,5,6-Pentachlorobiphenyl
PCB 94
2,2',3,5,6'-Pentachlorobiphenyl
PCB 95
2,2',3,5',6-Pentachlorobiphenyl
PCB 95/93
PCB 96
2,2',3,6,6'-Pentachlorobiphenyl
PCB 97
2,2',3,4',5'-Pentachlorobiphenyl
PCB 97/86
PCB 98
2,2',3,4',6'-Pentachlorobiphenyl
PCB 99
2,2',4,4',5-Pentachlorobiphenyl
PCB 100
2,2',4,4',6-Pentachlorobiphenyl
PCB 101
2,2',4,5,5'-Pentachlorobiphenyl
PCB 101/90/89
PCB 102
2,2',4,5,6'-Pentachlorobiphenyl
PCB 103
2,2',4,5',6-Pentachlorobiphenyl
PCB 104
2,2',4,6,6'-Pentachlorobiphenyl
PCB 105
2,3,3',4,4'-Pentachlorobiphenyl
PCB 105/127
PCB 106
2,3,3',4,5-Pentachlorobiphenyl
PCB 107
2,3,3',4',5-Pentachlorobiphenyl
PCB 107/109
PCB 108
2,3,3',4,5'-Pentachlorobiphenyl
PCB 109
2,3,3',4,6-Pentachlorobiphenyl
PCB 110
2,3,3',4',6-Pentachlorobiphenyl
PCB 111
2,3,3',5,5'-Pentachlorobiphenyl
PCB 112
2,3,3',5,6-Pentachlorobiphenyl
PCB 113
2,3,3',5',6-Pentachlorobiphenyl
PCB 114
2,3,4,4',5-Pentachlorobiphenyl
PCB 115
2,3,4,4',6-Pentachlorobiphenyl
PCB 116
2,3,4,5,6-Pentachlorobiphenyl
PCB 117
2,3,4',5,6-Pentachlorobiphenyl
PCB 118
2,3',4,4',5-Pentachlorobiphenyl
PCB 118/116
PCB 119
2,3',4,4',6-Pentachlorobiphenyl
PCB 120
2,3',4,5,5'-Pentachlorobiphenyl
PCB 121
2,3',4,5',6-Pentachlorobiphenyl
PCB 122
2,3,3',4',5'-Pentachlorobiphenyl
PCB 123
2,3',4,4',5'-Pentachlorobiphenyl
PCB 124
2,3',4',5,5'-Pentachlorobiphenyl
PCB 125
2,3',4',5',6-Pentachlorobiphenyl
PCB 126
3,3',4,4',5-Pentachlorobiphenyl
PCB 127
3,3',4,5,5'-Pentachlorobiphenyl
PCB 128
2,2',3,3',4,4'-Hexachlorobiphenyl
PCB 129
2,2',3,3',4,5-Hexachlorobiphenyl
PCB 130
2,2',3,3',4,5'-Hexachlorobiphenyl
PCB 131
2,2',3,3',4,6-Hexachlorobiphenyl
PCB 131/142
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W
15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10
S
15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10
Pulp
T
15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 77 77
77 77 77 77 77 77 77 77
77 77
77 77 77 77
77 77 77 77
77 77
77 77 77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77 77 77 77 77
Page 10 of 18 Page 41 of 49
www.axysanalytical.com
AXYS Analytical Services Ltd.
TABLE 2
PCB 132
2,2',3,3',4,6'-Hexachlorobiphenyl
PCB 133
2,2',3,3',5,5'-Hexachlorobiphenyl
PCB 134
2,2',3,3',5,6-Hexachlorobiphenyl
PCB 134/143
PCB 135
2,2',3,3',5,6'-Hexachlorobiphenyl
PCB 136
2,2',3,3',6,6'-Hexachlorobiphenyl
PCB 137
2,2',3,4,4',5-Hexachlorobiphenyl
PCB 138
2,2',3,4,4',5'-Hexachlorobiphenyl
PCB 138/163/164
PCB 139
2,2',3,4,4',6-Hexachlorobiphenyl
PCB 140
2,2',3,4,4',6'-Hexachlorobiphenyl
PCB 141
2,2',3,4,5,5'-Hexachlorobiphenyl
PCB 142
2,2',3,4,5,6-Hexachlorobiphenyl
PCB 143
2,2',3,4,5,6'-Hexachlorobiphenyl
PCB 144
2,2',3,4,5',6-Hexachlorobiphenyl
PCB 144/135
PCB 145
2,2',3,4,6,6'-Hexachlorobiphenyl
PCB 146
2,2',3,4',5,5'-Hexachlorobiphenyl
PCB 147
2,2',3,4',5,6-Hexachlorobiphenyl
PCB 148
2,2',3,4',5,6'-Hexachlorobiphenyl
PCB 149
2,2',3,4',5',6-Hexachlorobiphenyl
PCB 149/139
PCB 150
2,2',3,4',6,6'-Hexachlorobiphenyl
PCB 151
2,2',3,5,5',6-Hexachlorobiphenyl
PCB 152
2,2',3,5,6,6'-Hexachlorobiphenyl
PCB 153
2,2',4,4',5,5'-Hexachlorobiphenyl
PCB 154
2,2',4,4',5,6'-Hexachlorobiphenyl
PCB 155
2,2',4,4',6,6'-Hexachlorobiphenyl
PCB 156
2,3,3',4,4',5-Hexachlorobiphenyl
PCB 157
2,3,3',4,4',5'-Hexachlorobiphenyl
PCB 158
2,3,3',4,4',6-Hexachlorobiphenyl
PCB 158/160
PCB 159
2,3,3',4,5,5'-Hexachlorobiphenyl
PCB 160
2,3,3',4,5,6-Hexachlorobiphenyl
PCB 161
2,3,3',4,5',6-Hexachlorobiphenyl
PCB 162
2,3,3',4',5,5'-Hexachlorobiphenyl
PCB 163
2,3,3',4',5,6-Hexachlorobiphenyl
PCB 164
2,3,3',4',5',6-Hexachlorobiphenyl
PCB 165
2,3,3',5,5',6-Hexachlorobiphenyl
PCB 166
2,3,4,4',5,6-Hexachlorobiphenyl
PCB 167
2,3',4,4',5,5'-Hexachlorobiphenyl
PCB 168
2,3',4,4',5',6-Hexachlorobiphenyl
PCB 169
3,3',4,4',5,5'-Hexachlorobiphenyl
PCB 170
2,2',3,3',4,4',5-Heptachlorobiphenyl
PCB 170/190
PCB 171
2,2',3,3',4,4',6-Heptachlorobiphenyl
PCB 172
2,2',3,3',4,5,5'-Heptachlorobiphenyl
PCB 172/192
PCB 173
2,2',3,3',4,5,6-Heptachlorobiphenyl
PCB 174
2,2',3,3',4,5,6'-Heptachlorobiphenyl
PCB 174/181
PCB 175
2,2',3,3',4,5',6-Heptachlorobiphenyl
PCB 176
2,2',3,3',4,6,6'-Heptachlorobiphenyl
PCB 177
2,2',3,3',4,5',6'-Heptachlorobiphenyl
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W
15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15
S
15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15
Pulp
T
15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 77 77 77
77 77 77 77
77 77 77 77 77 77
77 77 77 77 77
77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77 77 77 77
77 77
77 77
77 77 77
Page 11 of 18 Page 42 of 49
www.axysanalytical.com
AXYS Analytical Services Ltd.
TABLE 2
PCB 178
2,2',3,3',5,5',6-Heptachlorobiphenyl
PCB 179
2,2',3,3',5,6,6'-Heptachlorobiphenyl
PCB 180
2,2',3,4,4',5,5'-Heptachlorobiphenyl
PCB 181
2,2',3,4,4',5,6-Heptachlorobiphenyl
PCB 182
2,2',3,4,4',5,6'-Heptachlorobiphenyl
PCB 183
2,2',3,4,4',5',6-Heptachlorobiphenyl
PCB 184
2,2',3,4,4',6,6'-Heptachlorobiphenyl
PCB 185
2,2',3,4,5,5',6-Heptachlorobiphenyl
PCB 186
2,2',3,4,5,6,6'-Heptachlorobiphenyl
PCB 187
2,2',3,4',5,5',6-Heptachlorobiphenyl
PCB 187/182
PCB 188
2,2',3,4',5,6,6'-Heptachlorobiphenyl
PCB 189
2,3,3',4,4',5,5'-Heptachlorobiphenyl
PCB 190
2,3,3',4,4',5,6-Heptachlorobiphenyl
PCB 191
2,3,3',4,4',5',6-Heptachlorobiphenyl
PCB 192
2,3,3',4,5,5',6-Heptachlorobiphenyl
PCB 193
2,3,3',4',5,5',6-Heptachlorobiphenyl
PCB 194
2,2',3,3',4,4',5,5'-Octachlorobiphenyl
PCB 195
2,2',3,3',4,4',5,6-Octachlorobiphenyl
PCB 196
2,2',3,3',4,4',5,6'-Octachlorobiphenyl
PCB 196/203
PCB 197
2,2',3,3',4,4',6,6'-Octachlorobiphenyl
PCB 198
2,2',3,3',4,5,5',6-Octachlorobiphenyl
PCB 199
2,2',3,3',4,5,5',6'-Octachlorobiphenyl
PCB 200
2,2',3,3',4,5,6,6'-Octachlorobiphenyl
PCB 201
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
PCB 202
2,2',3,3',5,5',6,6'-Octachlorobiphenyl
PCB 203
2,2',3,4,4',5,5',6-Octachlorobiphenyl
PCB 204
2,2',3,4,4',5,6,6'-Octachlorobiphenyl
PCB 205
2,3,3',4,4',5,5',6-Octachlorobiphenyl
PCB 206
2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl
PCB 207
2,2',3,3',4,4',5,6,6'-Nonachlorobiphenyl
PCB 208
2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl
PCB 209
Decachlorobiphenyl
Total Monochlorobiphenyls
Total Dichlorobiphenyls
Total Trichlorobiphenyls
Total Tetrachlorobiphenyls
Total Pentachlorobiphenyls
Total Hexachlorobiphenyls
Total Heptachlorobiphenyls
Total Octachlorobiphenyls
Total Nonachlorobiphenyls
Total Decachlorobiphenyls
Total Polychlorinated biphenyls
Aroclors Aroclor 1260 Aroclor 1254 Aroclor 1268 Aroclor 1221 Aroclor 1232 Aroclor 1248 Aroclor 1016
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W
10, 15 10, 15 10, 15
15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10
S
10, 15 10, 15 10, 15
15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10
Pulp
T
10, 15 10, 15 10, 15
15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 77 77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77
77 77 77 77 77 77 77 77 77 77 77 77 77
7
10 10 10 10 10 10 10 10 10 10 10 10
10 7 10 7 10 10 7 10 7 10 7
7
7 7
7 7 7 7
Page 12 of 18 Page 43 of 49
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AXYS Analytical Services Ltd.
TABLE 2
Aroclor 1242 Aroclor 1242/1016
Pesticides 2,4'-DDD 2,4'-DDE 2,4'-DDT 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) cis-Nonachlor Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde Endrin ketone Gamma-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorobutadiene Methoxychlor Mirex Oxychlordane Toxaphene trans-Chlordane (gamma-Chlordane) trans-Nonachlor
BDE - Brominated Diphenylethers
BDE 7
2,4-dibromodiphenylether
BDE 8
2,4'-dibromodiphenylether
BDE 10
2,6-dibromodiphenylether
BDE 11
3,3'-dibromodiphenylether
BDE 12
3,4-dibromodiphenylether
BDE 13
3,4'-dibromodiphenylether
BDE 15
4,4'-dibromodiphenylether
BDE 17
2,2',4-tribromodiphenylether
BDE 25
2,3',4-tribromodiphenylether
BDE 28
2,4,4'-tribromodiphenylether
BDE 30
2,4,6-tribromodiphenylether
BDE-33
2',3,4-tribromodiphenylether
BDE 35
3,3',4-tribromodiphenylether
BDE 37
3,4,4'-tribromodiphenylether
BDE 47
2,2',4,4'-tetrabromodiphenylether
BDE 49
2,2',4,5'-tetrabromodiphenylether
BDE 66
2,3',4,4'-tetrabromodiphenylether
BDE 75
2,4,4',6-tetrabromodiphenylether
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
10 10
10
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W 77
10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16
10, 16 10, 16 10, 16
10 10, 16
16
10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16
16 10, 16 10, 16 10, 16
10 10, 16 10, 16
10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16
16 10, 16 10, 16 10, 16 10, 16 10, 16
16 10, 16 10, 16 10, 16
10 10, 16 10, 16
16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16
16 16 16
16 16
17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17
17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17
Page 13 of 18 Page 44 of 49
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AXYS Analytical Services Ltd.
TABLE 2
BDE 77 BDE 85 BDE 99 BDE 100 BDE 105 BDE 116 BDE 119 BDE 126 BDE 140 BDE 153 BDE 154 BDE 155 BDE 166 BDE 181 BDE-183 BDE 190 BDE 206 BDE 207 BDE 208 BDE 209
3,3',4,4'-tetrabromodiphenylether 2,2',3,4,4'-pentabromodiphenylether 2,2',4,4',5-pentabromodiphenylether 2,2',4,4',6-pentabromodiphenylether 2,3,3',4,4'-pentabromodiphenylether 2,3,4,5,6-pentabromodiphenylether 2,3',4,4',6-pentabromodiphenylether 3,3',4,4',5-pentabromodiphenylether 2,2',3,4,4',6'-hexabromodiphenylether 2,2',4,4',5,5'-hexabromodiphenylether 2,2',4,4',5',6-hexabromodiphenylether 2,2',4,4',6,6'-hexabromodiphenylether 2,3,4,4',5,6-hexabromodiphenylether 2,2',3,4,4',5,6-heptabromodiphenylether 2,2',3,4,4',5',6-heptabromodiphenylether 2,3,3',4,4',5,6-heptabromodiphenylether 2,2',3,3',4,4',5,5',6-nonabromodiphenylether 2,2',3,3',4,4',5,6,6'-nonabromodiphenylether 2,2',3,3',4,5,5',6,6'-nonabromodiphenylether Decabromodiphenylether
PFC - Perfluorinated Organic Compounds Perfluorobutanoate (PFBA) Perfluoropentanoate (PFPeA) Perfluorohexanoate (PFHxA) Perfluoroheptanoate (PFHpA) Perfluorooctanoate (PFOA) Perfluorononanoate (PFNA) Perfluorodecanoate (PFDA) Perfluoroundecanoate (PFUnA) Perfluorododecanoate (PFDoA) Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA)
PAH Anthracene Pyrene Benzo[ghi]perylene Benzo[e]pyrene Indeno[1,2,3-cd]pyrene Perylene Benzo[b]fluoranthene Fluoranthene Benzo[k]fluoranthene Acenaphthylene Chrysene Benzo[a]pyrene Dibenz[ah]anthracene Benz[a]anthracene Acenaphthene Phenanthrene Fluorene
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17
17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W
14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12
13 13 13 13 13 13 13 13 13 13 13 13 13
18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18
18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18
Page 14 of 18 Page 45 of 49
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AXYS Analytical Services Ltd.
TABLE 2
Naphthalene
PPCP (Pharmaceutical and Personal Care Products) Acetaminophen Azithromycin Caffeine Carbadox Carbamazepine Cefotaxime Ciprofloxacin Clarithromycin Clinafloxacin Cloxacillin Dehydronifedipine Digoxigenin Digoxin Diltiazem 1,7-Dimethylxanthine Diphenhydramine Enrofloxacin Erythromycin Flumequine Fluoxetine Lincomycin Lomefloxacin Miconazole Norfloxacin Norgestimate Ofloxacin Ormetoprim Oxacillin Oxolinic acid Penicillin G Penicillin V Roxithromycin Sarafloxacin Sulfachloropyridazine Sulfadiazine Sulfadimethoxine Sulfamerazine Sulfamethazine Sulfamethizole Sulfamethoxazole Sulfanilamide Sulfathiazole Thiabendazole Trimethoprim Tylosin Virginiamycin
Anhydrochlortetracycline (ACTC) Anhydrotetracycline (ATC) Chlortetracycline (CTC) Demeclocycline
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
18 18
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
19 19 19 19 19 19 19 19
Page 15 of 18 Page 46 of 49
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AXYS Analytical Services Ltd.
TABLE 2
Doxycycline 4-Epianhydrochlortetracycline (EACTC) 4-Epianhydrotetracycline (EATC) 4-Epichlortetracycline (ECTC) 4-Epioxytetracycline (EOTC) 4-Epitetracycline (ETC) Isochlortetracycline (ICTC) Minocycline Oxytetracycline (OTC) Tetracycline (TC)
Bisphenol A Furosemide Gemfibrozil Glipizide Glyburide Hydrochlorothiazide 2-hydroxy-ibuprofen Ibuprofen Naproxen Triclocarban Triclosan Warfarin
Albuterol Amphetamine Atenolol Atorvastatin Cimetidine Clonidine Codeine Cotinine Enalapril Hydrocodone Metformin Oxycodone Ranitidine Triamterene
Alprazolam Amitriptyline Amlodipine Benzoylecgonine Benztropine Betamethasone Cocaine DEET (N,N-diethyl-m-toluamide) Desmethyldiltiazem Diazepam Fluocinonide Fluticasone propionate Hydrocortisone 10-hydroxy-amitriptyline Meprobamate
ACC-101 Rev 06, 29-Jun-2011
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
Page 16 of 18 Page 47 of 49
www.axysanalytical.com
TABLE 2
Methylprednisolone Metoprolol Norfluoxetine Norverapamil Paroxetine Prednisolone Prednisone Promethazine Propoxyphene Propranolol Sertraline Simvastatin Theophylline Trenbolone Trenbolone acetate Valsaran Verapamil
AXYS Analytical Services Ltd.
Canadian Association for Laboratory Accreditation
(CALA)
Accreditation No.: A 2637
W S Pulp T
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
W ashington State
D epartm ent of Ecology
Lab. ID: C404
NP S
W
Table 1 and Table 2 - Explanation of Terms Used:
NELAP = National Environmental Laboratory Accreditation Program Non-potable water = water not fit for consumption without treatment as it may contain
pollutants, contaminants, minerals or infective agents. Surface water, ground water, rainwater, effluents as well as any other non-drinking water sources are included in this category. Solid = environmental solid sample. Soil, sediment, biosolids, hazardous waste, mixed phase samples with significant solids content are included in this category. Performance based implementation = methodology follows that of the method reference but modifications deemed by AXYS as minor 1may apply, results meet method reference data quality standard. Performance based modification = modifications deemed by AXYS as significant2 have been made to method reference protocol, results meet method reference accuracy standard. The suitability of the methodology for any method prescriptive applications should be assessed based on the modifications made and the specific work requirements. Performance based method = an in-house AXYS method, published method reference not applicable. GC/LRMS = gas chromatography, low resolution mass spectrometry detection. GC/HRMS = gas chromatography, high resolution mass spectrometry detection. GC/ECD = gas chromatography, electron capture detection. LC/MS-MS = liquid chromatography, mass spectrometry-mass spectrometry detection.
ACC-101 Rev 06, 29-Jun-2011
Page 17 of 18 Page 48 of 49
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AXYS Analytical Services Ltd.
Note 1:
Performance Based Implementation - Examples of Minor Modifications
- use of additional isotopically labeled references - adjustment of calibration range - adjustment of clean-up technique - use of a different extraction of same general type (example soxhlet vs soxhlet Dean Stark) - addition of matrix type using same principles (example addition of tissue matrix using same
detection principle and similar extraction type)
Note 2:
Performance Based Modification - Examples of Significant Modifications
- different acquisition conditions using same detection principle (example MS SIM vs. full scan) - different internal control limits while meeting method reference accuracy standard
ACC-101 Rev 06, 29-Jun-2011
Page 18 of 18 Page 49 of 49
