Document MpR5m8ynm2mBzZZxK0oNz4Xj

A (L & & G - 0 7 / / ACUTE AQUATIC TOXICITY TEST SUBSTANCE________________________________________________ Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203. (1Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot numbers were 4 and 6. The test sample is FC-203. Current information indicates it is a mixture of 1.34% PFOS, 35% diethylene glycol butyl ether, 37.85% water, 20% ethylene glycol, 2.66 % Sultone foamer, 3% sodium octyl sulfate, 0.1% sodium lauryl sulfate, and 0.05% tolyltriazole. The following summary applies to a mixture with incompletely characterized concentrations o f impurities. Data may not accurately reflect toxicity of the fluorochemical component of the test sample. METHOD:_________________________________________________________ Method: Not given. Type: Various static and Continuous flow screening GLP: No Year completed: 1973 - 1974 (5 studies conducted) Species: Not given. Supplier: Not given. Analytical monitoring: Temperature, and DO Exposure period: 96-hours, 10 days, and 18 days Statistical methods: TL50/LC50 values calculated using graphic interpolation. Test organism age: Not given. Pretreatment: Not given. Test conditions: Various. Lighting: Not given Concentrations dosing rate: Various Stability of the test chemical solutions: Not noted Exposure vessels: Not given Number of replicates: 1 Number of organisms per replicate: Not given. Number of concentrations: five plus a blank control Water chemistry during the study: Various RESULTS_____________________________________________ Nominal concentrations: Bk control and various concentrations Element values: Study 1 (wX3% concentrate Lot 4): 000520 96-hour LC50 = 0.75 mL Study 2 (w/3% concentrate Lot 6): 96-hour LC50 = 0.075% cone. Study 3 (Lot 4): 96-hour LC50 = >1000 mg/L Study 4 (Lot 4): 96-hour LC50 = 0.061% Study 5 (Lot 4): 96-hour LC5o = 0.1875% Study 6 (Lot 4): 4-7 day LC50 = 1875 mg/L 8 day LC50 = 1525 mg/L 9-10 day LC50 = 1250 mg/L Study 7 (Lot 4): 96-hour TL50 = 0.0438 (no units, assume % concentrate) Element values based on nominal concentrations Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. C O N C L U S IO N S ___________________________________________________ The test sample LC50 varied among the studies depending on the test type and duration. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY ________________________________________________ Reliability: Klimisch ranking = 3. Testing lacks record of methodology used. Sample purity was not properly characterized and the study lacks analytical confirmation of the amount of fluorochemical proportion in the solution. R E F E R E N C E S --------------------------------------------------------------------------------------- This study was conducted by the 3M Company, Environmental Laboratory, St. Paul, MN, Lab Request number 2002 and 2009,1973-1974. O T H E R ___________________________________________________________ Last changed: 6/27/00 000521 -fr Tr*?**" m m . ) o f eD l n ^ rr BB.1T f'o 1- * ,, o -< cvS N . ON --) 2 o <X=> N 3 Qm $ ^ -' *** ^ o o &s I o^ <r> O' I r% e r " 3 <s/ er Banrvrt's r i ^i*--> r1 m00 or .H O 0 -0 *< 1 I- mr - -CT-55- `^ e r e r <s c o. vi aO O F O R M 10620-PW O Sc: LAB REQUEST BOOK - 42-5W File:. Water and Wastewater IQ |/|i" REQUEST FOR LABORATORY WORK Lab Ret^uest No-------- ' ------ TO: ENVIRONMENTAL ENGINEERING LABORATORY - BUILDING 53-6N Requestor Lab Personnel Name: Request D ate_____ Project No___________Prob. No_______ Code #_ Description: _ JU i- Sample Date: .Date Needed: Hold Sample F o r. .Days Est. Tim e:. . Hrs. Date Rec'd. Sample: :_ Analyst: ___ y T3 TS" Date Completed:. f2 -~[3 Hrs. Spent: ____ D -X l Sample Description Total Hardness, mg/l as CaC03 Calcium Hardness, mg/l as CaC03 03"P" Alkalinity, mg/l as CaC 03"M " Alkalinity, mg/l as CaC pH 4Sulfate, mg/l as SO 3Nitrate, mg/l as NO Chloride, mg/l as Cl Silica, mg/l as Si02 Fluoride, mg/l as F Ortho Phosphate, mg/l as P Total Phosphate, mg/l as P Total Chromium, mg/l as Cr Hex. Chromium, mg/l as Cr Total Cyanide, mg/l as CN Ferrocyanide, mg/l as CN Iron, mg/l as Fe Manganese, mg/l as Mn Surfactant, mg/l as LAS Phenol, mg/l BOD, mg/l COD, mg/l (Short, Long, Dilute) Total Suspended Solids, mg/l Volatile Suspended Solids, mg/l Turbidity, mg/l Silica Total Solids, mg/l Total Volatile Solids, mg/l Conductivity, mhos Total Bacteria, No./100 ml Total Coliform, No./100 ml Fecal Coliform, No./100 ml Fecal Streptococcus, No./100 ml Ammonia Nitrogen, mg/l as N Kjedldahl Nitrogen, mg/l as N Oil and Grease, mg/l t.\o a s s a v \ <u> . *\ ) ^ / <1, o .o ib Comments: -3n t o f h ? ) ^ *2_ *3 ^5 ipy APIB E S I ( X AV/U l C _ 1f O -V f* 3. 5 -* B u -iy/ Q jltkH nh00523 1 tr * /C J ^ y -' I K A L - 3 a f (3 6 6 ~ 7 o ; > 5 ^ * | - Vi ; f >W h ite -- E n v iro n m e n ta l Engrg. La b C anary -- E n v iro n m e n ta l Engrg. Lab P in k -- E n v iro n m e n ta l Enorg. La b G o ld e n ro d -- R e a u a ita rt CoDV . .. .. - . . I --+i i l - = E mi_:::if :4---3- h#i-i V\t>*V. U S a - 3 .5 /C "~ ,t: ! :;^7rt *"T - f Bist L-or AVAlLAblu. .... " ~ 3WnWWAdOO i53a t. : ; r y p n a w/ *; fva c y 9/v ; , : w 0\ <? f c r - ` '' T : ilv V r ;" T r ^ ^ ; M ...: - ` P & q < w " - p m } ^ | ; r f V * ^ ' . $ . ? : fte w 07 00052 4$ c&v Str V*|> ^ T - T ? r T ;- ^ *f- :>*- , .. . i --..j V 'V A * -'-> ~,--- c< Jfi .. `WLKTid*' tHii' j r>-: ."f fe--- <7*r ;r /~ V.-i-,: T * i A/T7 .V *'!:.' ! ' tr'ri< ~T'-i +* '**i. u^ J y \ i- Ai*-,'. ';. ; /i- -.r`4T'r*4-----r. " i --vt ::p ; fu Iii* d a i~il I ' '*P* ,,IJHMlH. w -*f - *4 /"v - t ' '? r>. < "t I^vj t `A " \<i -.T' ' .? - *3 1 % -v . i. i .. - i. .i,..iii i' 'i .' .<i ii i' i T^V**' * i;-A . | W !; r.t: L >.T1.."/^u :r.. . r-';*' , : jr- *''1UIXiv\' . 1^'Ml.lj l.< " " ^ <- 1K 'If. ' 1 - 11-Hg --i' - I- ;:' **K- ` ^p>k > . :...1 ' . w . -'t> - t- ' * ' ' * ' | c '-*^*'* ^ i r~r*- - - - . : * V * .S g i^ - :T < 7 f V '9 o f jV A lA 4 0 < 5 VO^J ~F't" 1 :* V 4' i. :[..: 1 .iv':'* -' 'l- ' u * ^ . ^t ^*. ti - r - -T tA tm i^ t s : 9 i > V 'S Tl NI 30VW OH N 1 0 7 X 3 i a 3 N 3 3 H 3 H 3NI d J d SNOISIAIQ Q l X 3*13X3 3IWH1I v a o i iwas . H3HVd HdVMQ N 3Q ZX 3IO O l l - O ^ C 000528 F O R M t 0620-PW O cc: LAB REQUEST BOOK - 42-5W Water and Wastewater File:. REQUEST FOR LABORATORY WORK Lab Rec'uest No- TO: ENVIRONMENTAL ENGINEERING LABORATORY - BUILDING 53-6N ^oo Requestor Name: ^ (A c Project No. Description: \>(Xa Y \ Request Date Prob. No. Code # trff ^ SamDle Date: Date Needed: Hold Sample For Davs Est. Time: Hrs. Lab Personnel Date Rec'd. Samle: Analvst: fitIE Y Id B TEST ? Date Completed: Hrs. Spent: ____ _______ S' Sample Description X Total Hardness, mg/l as CaC03 Calcium Hardness, mg/l asCaCOs "P" Alkalinity, mg/l as CaC03 "M " Alkalinity, mg/l as CaC03 pH 4Sulfate, mg/l as SO 3Nitrate, mg/l as NO Chloride, mg/l as Cl 1 2Silica, mg/l as S O Fluoride, mg/l as F Ortho Phosphate, mg/l as P Total Phosphate, mg/l as P Total Chromium, mg/l as Cr LU Hex. Chromium, mg/l as Cr --I Total Cyanide, mg/l as CN CO Ferrocyanide, mg/l as CN 5 Iron, mg/l as Fe Manganese, mg/l as Mn Surfactant, mg/l as LAS I Phenol, mg/l BOD, mg/l > CL COD, Total mg/l (Short, Long, Dilute) Suspended Solids, mg/l O O Volatile Suspended Solids, mg/l Turbidity, mg/l Silica I-- CO LU Total Total Solids, mg/l Volatile Solids, mg/l GQ Conductivity, mhos Total Bacteria, No./lOO ml Total Coliform, No./100 ml Fecal Coliform, No./100 ml Fecal Streptococcus, No./100 ml Ammonia Nitrogen, mg/l as N Kjedldahl Nitrogen, mg/l as N Oil and Grease, mg/l 0, LcjsoI 4_____________ ^ T - v ________v____ . ..--4 O.iXfS 0, 06,/- * * V sV _ --------------------------------------------------------------------------------------------------- -- ------0 0 0 S 2 9 " f ' W hite -- E nvironm ental Engrg. Lab Canary -- E nviron m en tal Engrg. Lab P ink * E nviron m en tal Engrg. Lab G oldenrod -- Requester C opy . : : /`h ttir F - 2 o3 5 gal pai 1. L o t * ^ i _. J ...;...L :,.' .. 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V ^ C V C L r x 10 DIVISIONS PER INCH iia v iiv A V A d o o is a a p ....... --wU *' " ' %' " ' i, *", T-11 !;v# Z- * JS^ter-' -1. "sci'V ..'. '.''........ '. . i ... i . : -. . ^''`-. t*-*-1*'-"I C-;-r^l-iiv'v i.-i,.;. i f j ` jr- I f e i j......... 000538 HAI-' uL,um . BESTi.'ii ) ui. COPY AVAILABLE MAU6 N U. s. 'A j> u> di d> tp - 0 til. f U K M X0 6 20* PW O cc: LAB REQUEST BOOK - 42-5W File: Water and Wastewater REQUEST FOR LABORATORY WORK Lab Request No. I t 5- I TO: ENVIRONMENTAL ENGINEERING LABORATORY - BUILDING 53-6N Requestor Lab Personnel Name: D ,, Project No. Description: SamDle Date: Hold Sample For Request Date Prob. N o . , Code # M Date Needed: Days Est. Time: Hrs. Date Rec'd. Sam Die: Analyst: M tz Y 1H B} P 1 Date Completed: -- 1-- \---------------------------- Hrs. SDent: v ^ ________ fll J CQ ^ SI ^5 H* W/ TvJ Sample Description 03Total Hardness, mg/l as CaC Calcium Hardness, mg/l as CaC03 03"P" Alkalinity, mg/l as CaC 03"M " Alkalinity, mg/l as CaC pH 4Sulfate, mg/l as SO 3Nitrate, mg/l as NO Chloride, mg/l as Cl Silica, mg/l as Si02 Fluoride, mg/l as F Ortho Phosphate, mg/l as P Total Phosphate, mg/l as P Total Chromium, mg/l as Cr Hex. Chromium, mg/l as Cr Total Cyanide, mg/l as CN Ferrocyanide, mg/l as CN Iron, mg/l as Fe Manganese, mg/l as Mn Surfactant, mg/l as LAS Phenol, mg/l BOD, mg/l COD, mg/l (Short, Long, Dilute) Total Suspended Solids, mg/l Volatile Suspended Solids, mg/l Turbidity, mg/l Silica Total Solids, mg/l Total Volatile Solids, mg/l Conductivity, mhos Total Bacteria, No./100 ml Total Coliform, No./100 ml Fecal Coliform, No./100 ml Fecal Streptococcus, No./100 ml Ammonia Nitrogen, mg/l as N Kjedldahl Nitrogen, mg/l as N Oil and Grease, mg/l \2A oc^<\y . 7W I Comments: v - 7 Up x day - Qt - fp day jy & ~ 7 5 /2 S _ 000541 m W hite -- E nvironm ental Engrg. Lab Canary -- E nvironm ental Engrg. Lab Pink -- E nviron m en tal Engrg. Lab G oldenrod -- Requesters C opy C irbo nlui P BEST QP V V L A B L B L'UGENf DIETZOFN t. M A 1 1f N vi h A. BEST COPY AVAILABLE ; Jfaif cr i o y . - ? 4 000544 0 BEST COPY AVAILABLE y 'n n i * a v * t soo Naazj.ua iN ien a h o n i 3d SNOistAm at x sansAa z a V a a "M W 3B d 3 d * d MdVQ N 3 0 Z JJIQ O iZ n * a ^ E ON