Document MoKEGXZg7y5xQJ81LXpwaNkQx
DRUGS, OILS AND PAINTS , / f ('> ^ e / ? ? )
en temperature. The technologist has ride use of this characteristic in conwith his work on cellulose nitrate, and ubtless be able to apply much of that ition to similar products employing e acetate. However, a warning note e sounded in regard to this practice, it exhibits many of the properties of rate, cellulose acetate possesses a group
inctive characteristics which are not jle to the treatment acorded cellulose
or cellulose benzoate. For example,
se nitrate is readily soluble in methyl , whereas the acetate is quite insoluble liquid. Any solvent formula, whether inning, coating, spraying, brushing or
g, which contains methyl alcohol, may sidered in the case of cellulose nitrate
g a formula containing a solvent; whereands. Representatives of this class are ie, 1, 4 dioxen and tetrahydro furfuryl
en cellulose acetate is substituted the 1 alcohol becomes a diluent with respect
cellulose ester. liquids which will dissolve cellulose aceetween 36% and 42% acetyl are not only
as regards classes of compounds, but
er properties as well. Among the very loiling liquids may be mentioned aniline,
84.5 C., and acetophenone, B. P. 198 C.,
irmer an amine and the later a ketone, g the esters which are solvents for cellucetate may be mentioned methyl formate, ri salicylate, methyl lactate and glycol ate. Some of the halogenated hydro-
ns are also solvents, for example, tetrasthane, trichlorethane, and hot ethylene de. These are, however, all more or less
ble and somewhat toxic, both of which them less desirable than other materials,
lose acetate is also soluble in heterocyclic ol. Nitrobenzol is also a solvent, repreig another class of organic substances, itro-compounds. Heat is required to bring ose acetate into solution in the majority
e nitro bodies. Of the alcohols, mention jeen made previously. However, cellulose te is readily soluble in diacetone alcohol,
e ether-alcohols are also solvents, in the of the mono methyl or ethyl ether of
>1, or trimenthylene glycol. The above rill suggest the wide variety of the solvents
hich cellulose acetate is soluble. But this 5 only a part of the story, for as in the of cellulose nitrate, there are mixed sol-
s for cellulose acetate in which neither ionent is a solvent. The action of these id solvents has offered a most perplexing lem to the scientific worker, not only in field of cellulose esters, but in other fields ganic chemistry where this same phenomehas been observed. Again, the technologist
found such mixed solvents to be valuable, he case of cellulose nitrate the example
immediately comes to mind is the use of U volumes of ether and alcohol, neither
vhich will dissolve the ester when used e. A parallel to the above in the case of llose acetate is the use of mixtures of roform and alcohol. Other halogenated rocarbons with alcohols also may be used, the acetyl content of cellulose is reduced w the acetone soluble range, say to 30% yl, it becomes soluble in a still greater ety of solvents, such as hot 75% aqueous hoi. . However, the products so obtained e not been found useful by the technologist, rom the above it is seen that for technical poses the range of solvents for cellulose -ate is sufficiently broad to permit of great |tjf f i^ n c h o i c e s o th atth e optimum solvent
LEAD is a lasting m e ta l.. LEAD in paints gives lasting satisfaction. Is there enough LEAD in your paints?
EAGLE-PICHER
134 N o. La Salle St., Chicago
W hite Lead, C arbonate Sublim ed Blue Lead R ed Lead Super Sublim ed W hite Lead Sublim ed W hite Lead Litharge O range M ineral Sublim ed Litharge Lithopone Zinc Oxide
.. u.a.
I' . t o e .
the ratio of solvent to solute. This procedure
is subject to grave limitations and usually is governed by the requirements imposed by the apparatus in which the solution is to be used or by the character of the coating which it is desired to obtain. The solutions of cellulose acetate for brush lacquers should, of course,
be higher in viscosity than those to be used in spraying. It is obviously impractical to at tempt to use the spraying solution for brush
ing both because of the difference in volatility of the solvent mixture and the viscosity of the solution which would produce brush marks. On the other hand, in a spraying lacquer it is not desirable to reduce the viscosity by ad dition of solvent because of the fact that a thin
in the not very distant future, it will take l place among the new coating materials whic have become such important factors in th problem of the protection of all manner 0 surfaces against the forces of nature, or tha of the beautification of the home and its fui nishings. For some purposes it is believe that cellulose acetate lacquers will be muc more suitable than cellulose nitrate. Example will be given later.
(To be concluded)
NEWS AND COMMENTS
Increased Production of Carbon Black
D R U GS, OILS AND PA IN TS , VJ~ ( To> c S / f r 9 )
ft
At the top of the tabulating card is an -oice form, simplified somewhat but contain-
g the major items of information needed in
icing a company's business activity. If this e sale represented the entire year's business
this fictitious company, the bill would prode the managers with all the information
ey would need in planning the next year's
rations. They would know that they had Id a certain quantity of a certain quality of
lint to a certain company in a certain place,
id they could fairly easily determine the cost ; handling that commodity and could, without
reat difficulty, figure their net profit from the
ansaction.
It happens, however, that this bill is but ne of many hundred that will be made out in
oe company's offices during the course of the
ear. Sales will be made in the territory of ve salesmen, to nine types of customers
ocated in sixty-three cities, and these sales vill represent orders for an amazing variety
if items, sold in widely varying quantities and
it widely varying discounts. Somewhere in
.he maze, this order of ten gallons of red paint s lost. It is never seen again unless the
Smith Hardware Co. of New York writes in
md says that there was a mistake in the total
charge or that they had ordered blue paint
instead of red. If that happens, and the job ber isn't busy, he may. reflect that he made
such and such a profit on that sale, but he still
has no way of knowing how much red paint he sold for the year, in what quantities, and at
what price.
It is plain, then, that the first task involved
in reconstructing last year's business is the recording of the information contained on the
sales slip in such a fashion that it may be
readily classified and integrated.
To accomplish this, we first convert all the
information on the record into numbers. Salesman Charles Adams becomes salesman
No. 1, and the territory served by him takes the same number. The Smith Hardware Co. becomes customer No. 213, located in county
No. 41 and city No. 4. All of the items car ried by the store are carefully coded after the
manner of this order so that the description
column will bear, in this instance, the number 6174, the first digit indicating that the article
is paint, the second that it is of a particular
manufacture, the third that it is used for a particular purpose, and the fourth that it is
sold in a particular size container. Three
additional digits are then added to show color; discount, value, etc., are similarly treated and
the bill is then given to an operator who punches holes in the card under the proper
headings. When the punching work is com
pleted, the card represents exactly the informa
tion that is contained on the charge slip, but that information is now in such a form that
it may readily be associated with all similar information. The data, now, instead of being
written, is expressed by a hole punched in the
card, and by use of a sorting machine all cards bearing similar information may readily be
brought together. If the invoice lists several items, a card is punched for each item and
another is punched to show the total of the
order. We might now begin at the left of the card
and discuss the significance of the information
that may be derived from each section as we cross the sheet. The first three columns are used purely for identification and as an aid in checking back on possible errors. The more direct interest in the card begins with the two columns under the heading of date.
A Detailed Record
It is from this column that the logical time
and quantity of purchases may most readily
ve . determined. .We will start by sorting out
-- -U-J
4.i*_
" Q,,j
is the enduring metal (and the paint public knows it)
R*e.U. 3. P a t. Off.
T h e more lead there ' // is in your paints the
more enduring w ill be your customersatisfaction.
EAGLE-PICHER
134 N O R T H LA SALLE ST R E ET C H IC A G O W hite Lead, C arbonate Sublim ed W hite Lead * Sublim ed Litharge Sublim ed Blue Lead O range M ineral Super Sublim ed W h ite Lead
Litharge * R ed Lead Zinc O xide - Lithopone
merely secured the total sales for the entire
business by months. It would be safe to rely on such figures if
the house sold only one item, but where many items are sold it becomes necessary to know not only how much is sold in a particular month, but what it is out of the entire stock that goes most strongly to make up that total. To discover this, we take the cards for each month and break them down by items. When the tabulation comes off this time, each item speaks for itself. Any faults in buying that may have crept in stand out and ask for cor rection. For instance, the vendor's invoices may show a purchase of $10,000 worth of red paint in the month of January. The tabula tion would show the monthly distribution of sales to be 5 per cent, for January, 4 per cent, for February, 20 per cent for June, etc. With
" rures in hand, the merchant can see
able and how many are costing you money The first thing to determine is, of course, amount of his total annual purchase for customer. But while this figure may give|uj a rough outline of our fortune or laclM" fortune with reference to customers, it haSy
starts to tell the story, for just as im port11; as the total amount ordered is the method use' in ordering. It would be quite possible A"
sell one customer $1000 worth of goods during the year at a loss and another $500 worth a: a profit. This fact can readily be appreciate' if we consider the $1000 worth of business a representing 500 two-dollar orders, and" th $500 as representing five $100 orders.
Customer Analysis I have here the record of sales made to il'L companies during the months of J a n u a r February, May and June, 1928, which w demonstrate the pertinence of such custom