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H AR126- O73 FM-1) ou H MULTI-CITY STUDY H FIELD REPORT FOR CLEVELAND TENNESSEE AND DECATUR ALABAMA - BATTELLE DUXBURY ACTIVITIES H for un Project Number n N1100672-01 un `submitted to on Confidential un July 9,1999 un Prepared by un mn Scott C. Macomber ite " Baatttteelllle un 397 Washington Street un |_| 20390 on |] nl iat n TABLE OF CONTENTS nN 1 INTRODUCTION coovmsmsssssssssmeseesmesssnesssssmssssssanssnmssssssssss 1 1.1 SURVEY SPECIFIC APPROVAL w.cvcorererssssssisssssrsssssssssssssssssssssssssssssssssssssssssssssisss srviimniinie 4.1 SAMPLEMATRIX AVAILABILITY ccvcrreersessessussesssmssspsresesessessessoessessersessers essere sesssseess 3 on LIST OF TABLES nN TA3BRONLOLoEGY OR BVENTS ONMAY 25, 1999 "TABLE | MUNICIPALITIES SAMANP D AL PPRE OVAD LS GRANTED DURING SURVEY ...ocvverssrsonsssssssns | "T2A CHRB ONL OLOE GY OF EVEONNT MASY 24, 1999 .c.cosrssnivsenrssrmssarssssnssssssssss sissies 2 `TSA CHRB ONL OLOE GY OFEVENTS ON MAY 27,1999 .cccvcrirssrsssssssssssssssssssssssssssssmssssssmsssssssnnes & nN "T6A CHB RONL OLOE GY OF EVEONNT MAS Y 28, 1999 ..ccoocconmsmmsrsrsmmsnrrssmsnsssssssssssssssssss ---- mn "TABL9E SAMPLING SITE POSITIONSINCLEVELTANND ...ooccvvee onvsapmsnmommnemeansss 11 "TABLE 10 SAMPLING SITE POSITIONS IN DECATURAL w.cocvsnnssssssssssssnsssssnsrmssssssssssssssssssssonss 11 00391 a --R e--o--O EeeEeET m==e= eeeemmentBeamtrlrlte " a - me nN | nN [ nN nN | |_| nN n n n n n " nN n mx 1. INTRODUCTION "The objectiveofthe sampling task in this study is to collect representative samples for trace- level analysis of specific FC residuals, to assess sources, dispersion in the environment, and `cohnusmiadneerxepdo`ssutruedyt'horrou`gchontthreoflocoidtecsh.ai`nS.tuTdhy'ecciittiieessarseeleccotnesdidfoerresdamtpholseecaorlclaesctwiiotnhwiFlCl be. production facilities or large industrial FC-consumers. `Control cites do not contain FC p`porpoudluacttiioonn soirzec,onasndudmrpitnikoinngfawcialtietiressaounrdcea.re matched to study cities based on general location, `During the initial phase of the study phone calls were made to municipal agencies requesting `permission to collect various matrices of interest. Based upon the level of cooperation received from the municipal agencies, appropriate sampling strategies were developed. The Quality Assurance Project Plan (QAPP) and the Survey Plan contain the detailed information concerning the matrices for collection and methods to be utilized for this process. `The full project sampling scope is accomplished using two field teams: 1) Battelle's Duxbury Personnel collect drinking water, POTW, landfill and urbanair samples, and 2) Battelle's Marine Sciences Laboratory (MSL) personnel collect surface water microlayer, bulk water and finfish `samples. This report summarizes the Duxbury team effort. A separate report summarizes the MSL activities. 1.1 Survey Specific Approval Approval was granted in Cleveland Tennessee from the Publicly Owned Treatment Works (POTW), municipal drinking water plant, and Cleveland Fire Department (for atmospheric sampling). szmple was Permission was not granted in Decatur granted for sampling at Alabama for the POTW the municipal (including air landfill. Permission to sampling), municipal drinking property water plant, and for atmospheric municipal sampling. landfill. Table 1 The Decatur highlights the Fire D cities epartment denied visited during this access survey to their and the approvals granted by municipal departments. Table 1. Municipalities Sampled and Approvals GrantedDuring Survey SCotnutrdayl_o|r| F(AiirreSaDmepplaritnmge)nt DrWiantekriPnlgant| `LMaunndifciilpal [Deca AL Swdy TNA | Ir [1 | (CoNvA=NoTANppJrovoalmReacei[ve1d [CJ [8] + Air sample collected Final Field Rpt Cleveland TN Decatur AL 000392 :Baateteltletnt ] tToetes 5 2. METHODS ny The collection of environmental samples is conducted according to Standard Operation Procedures (SOP's). The SOP's used in the Multi-City Study were written by Battelle and are used to train personal prior to conducting field activities and also serve as a reference documents nN while in the field. These documents, along with the QAPP, serve as the guidance documents for the collectionoffield samples. The methods used for collection are summarized below. n The collection of position data (latitude and longitude) was completed at each sampling location using a Garmin 12XL GPS unit according to Battelle SOP 3-164-01. Instrument accuracy was validated by comparing an acquired position versus a position of known location. The collection n of air samples was completed using a General Metals Model PS-1 atmospheric sampler. The sampling was conducted accordintog Battelle SOP M3-MC-F-1.1. The use of this system allows the separate collection of particulate and vapor phase compounds using a glass fiber filter n for particulate matter and a polyurethane foam PUF for the vapor phase. Water samples from drinking water supplies, POTW's, and landfills were collected according to SOP M3-F-2.0. `Surface water samples were collected via direct submersion, tap water and drinking water n supplied by the municipal plant were collected via a valve system, and effluent was collected using either a bucket or small sampling beaker. Sediment samples were collected using Battelle m SOP M3-F-7.0. Both sludge and sediment were collected using a stainless steel spoon. 3. CHRONOLOGY nN `Tables 2 through 6 provide a detailed chronology of the events that occurred each day of the survey. The times recorded for the collection of each sample matrix has been transcribed from un the sample collection log, all other times have beer estimated based on the eventsofthe day. All times have been recorded in Eastern Standard Time. BW eschromonyeotnEyv2e41n59s9 un; [[30[9000Am|vAve einAitlantna.GACandhmeetawithmKima Andrn ews,oogeTh.|| n materials praendasccoeuntned for. [300 |DepartChattanoogaandproceedto ClovelandTN. | Arrive in Cleveland and check into hotel. Proceed to have kickoffmeeting over lunch. n s`Daumrpilnegr.the meeting it is discovered that more sampling materials are required for air n [1500 | Armiveatfire tationandplaceaisampling ontbehind buldingforsamplecollection.| [e A R| Hamevparlo,vides maps, directions, and informs the managersofthe plants of our scheduled n shipment toChattanoog a 000393 a Final Field Rpt Cleveland TN Decatur AL. Baa ties lleaik I Carapneoarty n re wat ati. nN Table 3. Chronology of Events on May 25, 1999 70 "Arrive af the fire station, ar sampler did mo stop at end of 12h period. Sampling event n Table ContinuecCdoonmcollue3dr5etdBilaptamn0ek7ns4t5r.emCalienaendedinssaammpplleerrafnodrp3l0acesdectohnedPs,UFthayndwefirletetrhbelnanpklsaicnetdonthsetorage aw `muive at Cleveland Utilities Wastewater Treatment Plant (WWTP). Discuss sampling nN E075 Collect pos cngsug.Usdines see spon for collection ~~~] with Mr. Mike Ward who wasthe supervisor for the shift, no significant issues raised. Soeployee Compe calesai10o55n. Flingcollcion of aleKim nN Andrews departedthetetaorretumrn to Columbus. `Benchmark discovered at the WWTP, inquired about the coordinates from the plant nN eCmpolooyeme.aHfeorctohntbacetnecdhmaamrek.mbTehreofctohoredciimttyeesngainreeeNri3ng51de8p3a5rt0m"enWt w8h5o4p7r5o4v.i0d"e.d the "Amive at Hiwasses drinking water plant, Spoke with Chris Wiles who is the manager of the plant water quality lab. Collect raw untreated river water and post filtration n i520 |J collect surface water and sediment samples. Collet fue atesadsediment samplesSie2] eT Tr -- W n [ET r CiomlerlecSiionofaRpowavteer foanmdTa 7e5.nsesITaessC neo y eoe] n `Table 4. Chronology of Events on May 26, 1999 W FITTS RveanidesrCvo uoswpiahRnosoanCnarBiuofaCothtCyhasSarnoco.ge s Alper | " [BI DA poiwsarbteeautpipnhes (ersL . PUT. ad ld spike samp] le. 1430 Receive phone call from Marcia Nishioka. The client and Decatur Utlitics manager TM Glen Cart nin ee n KPeOmTCararnaghreeddrtoobaicnonwfaitdeenrtipaalitt.y agreement that would allow us to sample from the ou calibration of instrument. om Fo Fold Rot Civeend TY Dosa AL 000394 B#aBtatiteellllee wy ny L wy my li wn nN | J nN nN |_| mn || |:| i. Ped [1600|Amive at hotel and begin preparing waier-samplingBotefor the following Gay. `Table 5. Chronologyof Events on May 27,1999 Table 5. Continued +at Dry Creek WWTP. Collect air sample, air sampler stopped automatically auc 12 hours. Clean unit and collect QCsamples including anextra field spike sample. `Collect effluent sample using S00ml-sample collector that the facility provided. The. ample was colic from the spllvay that ld to he dischire pipe. The ient 1s discharged ~50 feet inttho river wherethe channel exits. "Jim Meares collected liquid sludge from a collection tank using aplastic jar. No GPS location recorded; the collection tank was ~500yds from the air sampling location. 1045 "Arrive at Decatur Water Plant. Collect raw and `teScahmnpilceisacnoollnedcuttyed idnurtihnegwaotuerrcoqlulaelcittiyonl.abofthe final processed drinking water. facility; Richard Blackwood was the. 15 Collect quit water body sample from the Northwest corner of Flint Creek. The area `SwEa.s lbyoca2t0ed0-a3cr0o0ss froyarmds. the Decatur Country Club. It was north of Country Club Lane. SE TTT cCoolmlpelcetxtalpocwaatteedrofnrtohmSeiTteenn2eTsosceaeteRdivaettr.he DecatBouart Harbor(within Riverwalk complex) "Arrive at Morgan County Landfill. Present site manager Richard Terry, with a request lewteterptrhoacteewdaeds troetquhiereldeparchiaotretopondouurncsoulpleecrtviionseodf saanmdplceosl.letFollelaocwhaitneg a tesrasmpele.discussion DCoelclaetcutr,Ste 3 tap water froma Texacogas siation/convenience store on Route 67 1 1635 `FCioellldecstpeidkSeiseam1ptlaeps wwaetreerpfrroocmesrsoeodm, s2a0m7polefsthseegHraegmapttedo,naInndn.cooler packaged for shipping Table 6. Chronologyof Events on May 28, 1999 [| `fAorrtsihveipimneCnhta.ttanooga, paperwork completed or sample Spent, coolers packaged 100 "dAersttiivneaatioFnesderal Express and ship all samples and equipment (here respective 4. RESULTS `The initial survey of the Multi-City Study resulted in the collection of the majority of the. s3atmhprloeusghde5scorfitbheed QinATPaPblweesr3e tsharmopulgehs5foorftthhee cQlAiePnPt .andAlasothciordllleacbtoerdabtourtynospteicnicflieuddebdyitnhTeables client. The collectionof these samples tripled the number of water and sediment samples taken. T"Thhee sfoalmlpolweisnwgesreectcioolnlsedcetsedcrainbde tphreocreessusletdsionftthheessaammeplmeacnonlelrecatsiotnheofsfeoritnttheantdeodccfuorrrBeadttdeulrlei.ng 000395 FoldRpCovadTNDeerAL s3eMBraatettenlleee oot 0 Kriegtess N this survey. Tables 7 and 8 provide alistofthe samples collected including sampling locations and sample ID's. Tables 7 and 8 do not contain the Quality Assurance samples collected along nN with authentic samples. n 4.1 Sample Matrix Availability Per client instructions no food items were collected during survey. Du to scheduling and permit nN icsosluleesctneod aftinefiitshherweCrleevceollalencdtodrurDiencgattuhirsdsuuervteoy.heaTlhteh ccoolnlceecmtiso.noBfotPhOPTOWTiWnfilnufelnutewntasstnroetams available for sampling contained biological hazards. In both cities, the staff at the facilites wn indicated that the chlorination process occurs following secondary treatment Neither landfill leachate nor an altemative sample was collected for the municipality of mn Cleveland, TN. The reasoning that an altemative sample was not sought after is based on the following information. A discussion with the managerofthe landfill in February resulted in the denial of permission to collecta sample. During this discussion it was revealed that the leachate mw from the landfill is pumped to the POTW for treatment. During subsequent discussions with . tChleevleelacahnadtUeatiiltitiiess panumofpfeedr winasfrmoamdtehetolarnedfmiollv.e H2omwaenvheorl,ebceocvaeursetwhaet whoaudlndotalbleoewnusgraacncteesds to mn permission it was decided that we would not collect the leachate sample. With the sample: unattainable and the leachate pumped from the landiil it reasoned that the leachate would not be migrating from the landfill and entering a nearby water source. Therefore, no altemative site nm was collected. Also to be collected, but not included in the QAPP, was a sampleof quiet/undisturbed surface nN | cwoatnedru.ctTehdi.s IsnamCplelveeilsainndtwenedewdefroeruunsaeblientaocloonlgl-ettertmhitsrasnasmppolret sbteucdayustehaatcicsecsusrrweanstluynabveaiinlgable 10 the pond selected as a sampling sit as it was located on private property. A sample was mn collected at Flint Creek in Decatur. om 42 Onsite Observations Cleveland, TN: The drinking water plant withdrawal location is approximately 2 miles mn= eeansdot/fnoEratdheeassotorfEtahdesprloaandt.inOtnhee HspiewlalsisngeewaRisvoerb.seTrvheedlooncaatliooncoafl stthreeestursfiagnceawnadttehresoitteheirs at the displayed on a local map. The sit is a smal state access area located at the tp of the peninsula. Nn The area appeared highly utilized by the local population for recreational activities. Decatur, AL: The Riverwalk Marina complex where surface water and sediments were oN= Dcoelclaetcutre.d Tishiloscaarteead iasdjaahciegnhtltyoatchteivHeimgahrwianya c72ombprildeg,estehvatertarlavpeerospelsetwheerTeenonbessesreveedRifvieshriinngtforom the banks. Several dead catfish were observed along the shore. A semi-sofishelled turtle of | wuanskncoolwlnecstpeedcifersomwaasroebcesnetrlvyecdoantstSriutcet2e.d AcotlltehcetMioonrgpoannd.CoTuhnitsypLraenvdiioiulslltyhsealmepalcheadtpeosnadmple: m 000396 m. Final Field Rpt Cleveland TN Decarar AL ABaatteelyleook B FReastts nN (December 1998) was surrounded by vegetation and access would have been extremely difficult. The pond sampled during this survey contained avarietyofwildlife living in and or around it. nN Several turtles, multitudes of insects and larvae, and various birds were observed feeding at the pond. nN `Table 7.CollectedSamplesfromClevelandTN mn Matrix Sample ID Vo`lAupmperoCxoilmlaetceteTdo(tLa)l or Location Collected BY [Deeebr [MCDB [ *SedimeI ntMass (gv77e bTinTsVr a Fim | DDtiinkiinngg WWtiFFooesss |MMEC12138348TT1T FFiivveess DDrriinnkkiinngg WWaatteerrllaat|] nm [DDDririinnnikkiinnngggWWWaaitieerFPProrooscsesessseeddTM |MMMCCE--1I12D22T5KKB T|[1T1 | FHHiaiwwatsasaseeeDDDrriininkkiinnnggWWWaaattteeerrPPlllaaanntt_|_|| [DrinkingWaterProcessed |MC-123K [1 | HiwasseeDrinkingWaterPlant_| nN [Drinking WaterProcessed |MC-124K [1 | HiwasseeDrinkingWaterPlant_| [Drinking WaterProcessed [MC-125K [1 | HiwasseeDrinkingWaterPlant_| BE [[DDrrDiinnkVkiinneggWWaartteemrPPrreoocceeesssseredd |NMMCC--C10241EHH T[[1T1 | HuiwwausssseseiDDrukinnkikiinnggWWWaatteeerrPPllaann|tt_| BW CDre ingWal te Proe cessed bMCi -128H [1 [wuessDrp inkingWe at Pe lan _| IDrinking Water Unpioceed |MC-IT7B--|I HowseDiningWat Pan Bl |Doki Vote Uprocesed [MCli9 1 ivaseDining Wr la | [DrinkingWaterUnprocessed |MC-[16K [1 HiwasseeDrinkingWaierPlant_| [DrinkingWaterUnprocessed|MC-119K [1 | HiwasseeDrinkingWaterPlant_| [DrinkingWaterUnprocessed |MC-1isH [1 | HiwasseeDrinkingWaterPlant| " |_| |J [[[DDDrruiiknnkkiiinnngggWWWaaattteeerUUUnnnppprrrooocsecesssseeeddd |||MMMCCC--H11I19S7HHH --oS-- [[|T 11 -- | HiHiviwawasssiseceeeeDDDrrr| iiinnnkkkiiinnngggWWWaaatteerrrPPPlllaaannntt|__|| ---------- TY-- Er ST -- om [TapWaierSiedl [Mci2oB [1 . [[TTaappWWaatteerrSSetsel [|MMCC-i12360KB [[11 [BoymomtHowl | ||BBeayymmoomnHHooww || =m [TopWaterSite# __ [MC128K [1 te [Top WaterSite#1 [MC-129K [1 [Tap WaterSite#1 [MC-30K [1 m [Top WaterSite #1 [MC-26H [1 a TapwaeSie#1 Thc 11 - [Top WaterSite #1 [MC-z7H [1 |BaymomtHow | [BaymomHoel | |BaymomHoel | |BaymomHoel | Tpumontloel000397 |BaymomHoel | um1 Final Field Rpt Cleveland TN Decatur AL. 3BBaattlteelilele o n on n By WM nN |:| |1 IN BlNesr BM nN BM; Wm ~ I = * om | rroou Sample TD "Approximate Total Tocation Collected `VoSleudmiemCeonltleMctaesds(L())or Tapbrie?iChoanievned [TapWaterSite2 _ [TapWaterSite#2 hiM ciats G TeoB GufsoSur--o ------ |MCU31IK |MCiU3tH [1 [1 [AmocoGasSution | |AmocoGasSution | [aB pWaterSie#3 e TMH i TT c TTTeemmeo seecnhamclkeCoatre | [SurfaceWaterSite#1 [MCIOIB_____[1 |iwasseeRiver | FSeoitrivsweaei Sss tepehhhoicimo03mp1 T[ T haTe u[aimsar mRfiere or]] [SurfaceWaterSite #1 [SurfaceWater Site #1 |MC105B 1 |MC-10IK [1 [HiwasseeRiver | |HiwssseeRiver | FSotiscwwai SaaoshTheeosK Tan [Hi eh ] ] [SurfaceWaterSie $1 [SufaceWaterSite#1 [SurfaceWater Sie#1___ [SufficeWater Site #1 [SufficeWater Sie#1 [Suffice Water Site #1 [Suffice WaterSite #1 [Sufice WaterSite #2 [Suffice Water Site #2 [T MeIo THuaT seeRiou] [MCIOSK [1 [MC-IOIH [1 |MC-l02H [1 |MC-103H [1 |MC-104H [1 |MC-10SH [1 |MC-1068 [1 |MC-106K [1 | HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | |HiwasseeRiver | SS[ eitteih vWwaaerrsSsihe##73 e hhhTTiihMecCeGTliBooenIDwe TDTTTahehimnaeeet eserrekRtiieeeeer || [SedimentSie#1 [SedimentSite#l___ [SedimentSie#z [SedimentSite#2 [SedimentSite#2 [SedimentSite #3 TMCHOK T2000 |MC-lIOH___[200* |MCi11B [2000 |MCIIIK [2000 [MCE [2000 |MC-1i2B [2000 CShPiemoiernsSeiees3i hhToh vihiwcicteeiiimeA--D [o 1e oro a eCe sith p n ireo] r]|| [POTWEMuem _ FOr Etat T1 MC 68 TCinuludMu1 naiparporw | [POTWEffluent [MCa4iB [McK Fe -- To [[PFOOTTWWEEfMfuieenmt__ [MMCCI148IKK [POTWESfuem --[MCI3H [POTWESuent _ [MC1aIH [POTWEMuent -- [MClazH [1 [1 T[1I JI [1 [1 | HaseeRes | [HiwasseeRiver | |HiwsssecRiver | |HiwasseeRiver | | HiwasseeRiver | | WiwasseeRiver | |ClevelandMunicipalPOTW | Civelani MuncspurPOTW__| ||CClievnecllanndiMMunuicinpagl PpOoTrWv__|| | ClevelandMunicipalPOTW | | Cleveland MunicipalPOTW | | ClevelandMunicip POTW | 000398 Final Field Rpt Cleveland TN Decatur AL e sBatelle By u om ny uN 0 nN BN BK om |] Rests JES] [POTWShdge [POTWSlidge ee SampleTD|VolApupmreoCxoilmlaetceteTdo(tLa)lor Tocation Collected [MC-aB [MC-l4dK [200+ [200+ [ClevelandMunicipalPOTW | [ClevelandMunicipalPOTW | Mus [UrbanAir(Vapo)_____|MC-l46 | 1Fier [ClevelandFireDepartment | [UrbanAir (Particulate) |McC-147___[IPUF | ClevelandFireDepartment | "Table 8. Collected Samples from Decatur AL SampleTD | ACpolplreocstiemda(t1e) Toort*alSeVdoilmuemnte| Location Collected [Drinking WaterProcessed__|MC2218 [1 [DrinkingWaterProcessed |MC2228 [1 [DrinkingWaterProcessed [MC2238 [1 [DrinkingWaterProcessed [MC-2248 [1 [Drinking WaterProcessed_[MC225B [1 [DrinkingWater Processed __[MC221K [1 [DrinkingWater Processed __[MC222K [1 [DrinkingWater Processed __[MC223K [1 [DrinkingWaterProcessed |MC224K____[1 [DrinkingWaterProcessed [MC225K [1 [DrinkingWaterProcessed [MC221H [1 [DrinkingWaterProcessed [MC2238 [1 [DrinkingWaterProcessed [MC-224H [1 [Drinking WaterProcessed [MC-225H [1 [DrinkingWaterUnprocessed _[MC215B____[1 [Drinking WaterUnprocessed [MC-216B____[1 [DrinkingWaterUnprocessed_[MC2178 [1 [DrinkingWaterUnprocessed |MC2188 [1 [DrinkingWaterUnprocessed[MC2198 [1 [DrinkingWaterUnprocessed |MC21SK [1 [Decatur WaterPlat | | DecatwWaterPlamt | | DecaturWaterPlamt | [DecatwWaterPlamt____| [DecatwWaterPlam | | DecawWatrPlamt____| |DecatwWaterPlamt____| | DecatwWaterPlant___| | DecatwrWaterPlant_____| | DecaturWaterPlant | | Decatur WaterPlant_____| [DecaturWaterPlamt | | DecatwWaterPlamt | [DecatwWaterPlamt | [Deca WaterPlant _____| | DecatwWaterPlant ____| | DecaturWeer Plamt____| | DecaturWaterPlant ____| | DecatwWaterPlant____| | DecatwWaterPlamt_| apWrSeat eae m [DrinkingWaterUnprocessed |MC2I7H [1 . [DrinkingWaterUnprocessed |MC218H [1 [DrinkingWaterUnprocessed |MC219H [1 ou [TopWaterSite#l _ mc2oie1 | DecatwrWaterPlant____| | DecatwWaterPlant_____| T|aDemcaptuorWoattenrPlat____|| [Wamplonlm | TaeStele[TTHamportn Final Field Rpt Cleveland TN Decatur AL unJ 000399 a3Barelie 0 nes es Bn =" Bn n = | oN |1 BR mm |] mo mn : nm n : nm : m m3 "Approximate Total Volume Collected (L) or *Sediment Location Collected Mag (Tovaoswes -- [TapWaerSiedl [wegn [Mcp [1 [1 THemoamn | [Hemponbm | ly `TTaabpleW8a.teCronSttien#u2ed [Megson TvMeeaasstiek [[[ 11 DeawwB [Haompu onlb m wbr|| [| 1 DecwrBoubwbr| [Tap WaterSie#y [TapWaerSie#s [Mega [1 [MCB [1 | DecanrBoubarbor | [TescoGmsSuion | [TopWaerSie#s -- [TapWaerSie#s -- [MComk [mMeasan [1 [1 |ToucoGuSmion | |TocoGuSaion | [Surface WaterSke #1 [SurfaceWaterSed] [MC20lB [1 [MCB [1 |TomeseeRiver | | TemessceRiver | [SurfaceWerSie#1 [SurfaceWaterSe #1 [MC2008 [MC20ap [1 [1 [|TTeommeeswsseeRRiiveerr | | [SurfaceWaterSteal [SurfaceWaterSite #1 [Mego [1 [MC20IK [1 | TomesccRiver | | TeomeseeRiver | [Surface WaterSiepl [SufaceWaterStep [MCatek [1 [Mego [1 TemesesRiver | |TemesesRier | [SurfaceWaterSted Surface WaerSted [MCR [1 MC20SK [1 [TomesecRiver |TememeeRiver | | [[SSuurrffaacceeWWaatteerrSStiee##11 [MCOOIH__[1 [Mego [1 |TemesecRiver | |TemeseeRiver | [[SSuurrffaacceeWWaatteerrSSttee#dl [Mea [MC20aH [[|11TemesmeeRTiemeemereR_ive_r ___|| [SurfaceWaterSe#1 [Surface WaterSte#2 [Mcgos [1 [Moos [1 | TemesecRiver | |TemescoRiver | [Surface WaterSto #2 [SufaceWaterSue#2 [MCaoek [Cao [1 [1 |TemesceRver | TemeseeRiver | [`Sutacs WinterSiews SurfaceWaterStew [Mcgors [1 [Meek [1 |TemesssRier [TomemeeRiver | | [Surface WaterSte#3 [SedimemSted [McCoo [1 |Mcalop [or |TomemeeRiver | |TememeeRiver | [SedimentSie#1 [SedimentSte $1 [MCol0K __[200[Maton [aor |TomeseoRiver TemesesRiver | | SedimentSiew [SedimentSie#2 [MC [2000 [MCaNK [2000 [TomesccRier | TemesceRiver | | [SedimenSte #2 [SedimenSted [Mca --_[Mcais __[200F [aor | TemeseeRiver | |TemesesRiver | [SedimentSie#3 [SedimentSess [MCoizk [MC [00+ [oor || TToommeemseceeRRiivveerr _____|| [POTWEMMeem [Meow 11 oT [DnCeekWwp | 1 3. -- [POTWEmuen [PoTWEMuen -- [Mee [1 [Meaam [1 [bnCeswwir [bnCeswwp | [POTWEmuen weak [1 [POTWEMen --Mcak [1 [bnCeawwr | [bnCekwwr | [[PPOOTTWWEEMMvueenm-- --[[MMcc2peeKk [1 [1 IbnCeswwr | [boCekWwip | S Fa Fd Rt Cleveland TN Deca AL S 3= B Batteel0l0e e0400 [[PPOOTTWWEEMMMwweenm--[Me[aMaemn [[|11DoCeskwwIbroCrek_wW_w___]| = mn mn' |] m | |] : |} =' mn ' . i a || m - = " wm . riag.es [IES Fath Ee] e Collected (L)or*Sediment [Porwemwn [PoTwsidge-- |Mczan1 [Mcoan [200+ |DnCekwwre | |DyCeekWwip | Table8.Continued jet Surtace Water [MGs 200 [MCosap [1 [bnCreawwrr | [EimCesk | e QauinEetiSra lurfFacres Waterh--a |c Mct osake-- [[11 ----[S -- M[e ||FMiom2 CreneCkos S unyL5 a-- nd8i}1] [Landfil Leachate [andlLeachate [MC23sK [1 [MC23sH [I | MorganCounyLandfill | Morgan CounyLandfil | [ObSaamnplAeisra(rPearntoitcpuairmteoyf he Mu|li-MCcitoyaSt7ud_y__[UPUF | DoyCreskWwre | 43 Instrumentation Results MAi3r-MsaCm-pFlLe.s1wetrhee aciorllseacmtpeldeurscianlgibaraGteinoenraislaMcecteaptlasbMloe difelitiPS-wi1thaiirn s1am0p%leorf.thAececxopredcitnegdtroesSuOltPs. To determine the acceptable results a calibration was conducted in Duxbury prior to the initiation coufrtvheessgteundye.raTtehdeiinniCtliaelvecallainbdraatnidonDceucravteurrehsaudltRed?ivnalauneRs"ofva0l.u9e97oafn0d.909.7.996Threescpaelcitbirvaetliyo.n The `fpoerrCcelnetvdeilfafnedreanncde 0in%retcoo6r.d5ed6%vafloureDsefcartoumr,threesinpietcitailvceallyi.bration ranged from -1.92% to 3.70% TDprhueexsbelunotrceaydtibioynncTooafbmelpaeacsrhi9nsaganmadplb1ie0nn.gcThshimteaerwakacasctudBearttateoecrlfmylietnvheeedrGussPuisSntguhneaimtGeawarasmsuirvneerd1i2flioXecdLatpiGroiPnoSrd,etottehdreempriaenrstueludtrsbeyafrtrehoem Fionsltlrouwmienngt.shTihpemednitffteoreTnecnentehsesetreutehaenidnsmterausmuernetdwcaosorrdeiinniattaelsizweads. 0T.h0i1skwialosmectoenrdsu.cted at the ``mBaapysmoanntdHlootcealtioonnsMoafyth2e4l%o.caWliatrheai,n wsheviecrhalinmdiincuatteeds tohfatthiet wpreoscewsosr,ktihnegupnriotpwearlsy.disTphleayriensgults of the verifications for each sampling day are presented in Table 11. T"threuer"esaunltdomfetahseurveerdifciocoartdiionnaftoers.ClAelvtehloaungdhwtahseavedriifffiecraetnicoen oisfb0e.y11onKdiltohmeetaecrcsepbteatnwceeecnritthereia, the pwoassitrieocnediavtiangodrattah,etdheayDewpilalrtbemecnotnosfidDeerfeednvsaelimdibgehctauhsaeveitaadpjpuestaerdedthtehastatwehlliiltee tsheleecitnisvter.ument pavoasiiltaiboinliatpy.peTarheeditnostcrhaamnegnet did in a not record a constant position regulated step manner. overa five-minute period and the T"threuer"esaunltdomfetahseurveerdifciocoartdiionnatinesD.ecTahteurrerfeesruelntceed pinoiandtitfhfaetrewnacse uosfe1d.f6o8rktihleomveetriefriscabteitowneweanstthheat roefftehreendciescphoasrigteiofnorwathsetphlaatnto,f tDhuer?ipnlgantthoeutvfelriofwiclaotciaotnedthoenspiltaen.t mBaansaegdeornstuhsepescubtsetdantth0iaatl0th0e 401 nn 4 sas GGL ses Final Field Rpt Cleveland TN Decatur AL #5BMatiteelsloe ork = - regent =H By 0 nN difference in positions further investigation was conducted. Subsequently it has been discovered that the position is the termination point of the discharge pipe located in the river. Based on this information verification was not possible for that day. According Feet apart. the QAPP the minimum distance The following results have been between sediment sampling calculated using the Garmin sites GPS. positions is 500 The distance fro m Cleveland from Site Site 1 to Site 2 is 229.6", the distance from Site 1 to Site 3 is 360.8". Sampling at Cleveland did 2 to Sit3e is not meet the 196.8" QAPP and the distance requirements. The. distance from Decatur Site 1 to Site 2 is 951.2", thedistance from Site 2 to Site 3 is 754.4' and the distance from Site 1 to Site 3 is 1,148". n mn |1 = TM om wm mn || `Table 9. Sampling Site Positions in Cleveland TN [v[ ase_ sDriS nkinge Weterm Plantp||l 316Li 0at1i5tn "ude g||L WoaLao osn3g1ic 9tu"des||t 11aVai AldledyrRo eosasd n|| [AmocoGasSun [|TeinvnaesssseeeeRJiavcekrsSCiael#17 [NsIIaAlT |[3N355721013386"2 |Weasr205" ||WW8BAe'SsI3128024"" |RowesGOand75 | ||REaodsubsluf0faRnodn7d5 || [ ivassesRiver Sie#3 [N35720908" |WBeSIT5.1" |FadsBluffRoad __| "T= Transcribed daa in log `Table 10. Sampling Site Positions in Decatur AL [__Semp | lLati itudn e g | L Lono gituc de a |t __Ai ddreo ss n| [D[[TTeeecsmasetesuosrGeBeeosRSwivFiebroSontre#_ 1 _[ [|NN33#40N 33572036093 7" # |||WWWEa83 ro60s8U86s006 8"52TM__5 _[||RRRiio7 vvweerrewwaall7 kk_MMaa_rrii_nn7 aa__||| [[TDernymCerseeeeRWivWeTrSPt(eE#fu3eatSame) |NN33##33T703015."" [DryCrock WWTP(hrSample) |N3457204" _[|W8W6a'e5s6o2s1s5T |Wsos3sTM [|tiRgivhewrwaayl2kM0arina || |Highway20 | MorganCounty Landi |N345719" |WEr0602 |Highway20 | mu `Table 11. GPS Position Verification Results [CalibrationLocations |___ClevelandTN |____DecaturAlL_____| mu [[DGiPfSrDeenrcievedPostion |0N.31S11KlIo8m3e5l"e/rWsbeeawri7ngSE5Z ||1N638#3Ki7lo3m1et4e"rsWbeaBri6n5g9457ST || on = TT TT ese `Final Field Rpt Cleveland TN Decatur AL 000402 ------ 3Bm atti elleTo wrk q reptstemFugse u 4.4 Communications oy `wDeurreinngottehde.coTmhpelseeticoonmmoufntihceaftiielodnssuwrveerye,csoenvderuacltecdonbveetrwsaeteinonBsatrteelglaerdsitanfgftahnedsvaamrpiloiunsg effort mn `municipal employees or the public. n IHnosCplietvaellawnodu,lTdNb,eCsheinetfdGiareycltolyrforfotmheCoClFuDmbwuassiinntfhoerimrendamthea.t aWdeonmautsitonetnosutrhee tSth.atJtuhdies'esffort is completed. Paul Pits the Assistant Manager of Cleveland Utilities Water Division provided `maps to the facilities and reiterated his offer o allow us to sample the landfill leachate as itis 0 `pumped to the POTW. OnMay21, 1999 a call was received from Kem CaofDrecartur Utilities indicatingthathe 0 `i`wnaowfuaorlredmoenfodttohafeltlshioetwucatlthiieeonnts..amFTpnollirlenosgwptioonngsoectcthouetrchaoetnvtsehiretsuPaattOiiooTnnW,itMowararDscridiaencNkiiidsnehgdiWobakytaetwrhaePscllacinoetnnittfaachntede dwaasndnmota Battelle de that a 0 cCCloainrefrni.td'esAnticidaoelnnivttieytrysaawgtraiesoenrmeebvneettawlreeeedvenianMliscno.gnNftiihdseehniidcoeekn,atiaatnnyddoifMnrtrh.eetCcaulrmirewnrteerwseuoluatlleddloibwneeaddnrtaaofgtcreoedlleaemcnetdnstoafimfnperwleehdsiacttohtMthrhe..e nN POTW and the drinking water plant. The agreement was completed on Wednesday May 26, uN sM1a9am9c9po.lmLibangteertreioanmdnilcMeaaatdeyedr,2th6MaTMrt.dheuCarwriornuaiglnddcioicnnavfteoerrdsmathttaihtoenhperboewjtaewcnetteemndaMntora.gsepCreaarokrf tatohnedthsSeictcoultaitteinMotna.dciorOemncbtelMyr.a,yMthr2e..7 Mr. Carr directly contacted the manager of the local manufacturing plant for further information. 0 Mdru.riCnagroeu'rs veimspitlotoyetehse faatcitlhietyP.ODTurWinignqtuhierecdalsiebvreartailontoifmetsheabaiorutsawmhpalterweMiwcehraeelloDoekcikn,gafnor 0 atshseisftacainltitsyupheardvidsiosrchaatrtgheeepxlcanetedaesnkceedsiifnwtehewererceenstamppalstindguefotroMloolcaylbdinednuustmr.y iHneputr.evealed that oN Tfahceirlietiweesrtehantoweotrheesrapmeprlteidne.ntDcuornivnegrstahteicoonusrssuerorfoucnodlilnecgttihneg csoulrlfeaccteiwonatoefrssaammpplleessaitnthbeotvharious n DeeaccahtcuarseanadgCelneevraellaannds,wmeermwbaesrsofoffertehde agnednearlallipntuebrleiscteidnqpuairrtieedsawbeorute the sampling satisfied. effort. In un 5. PROBLEMS EXPERIENCED AND RECOMMENDATIONS During the collection of samples from Cleveland TN and Decatur AL the following QAPP nu deviations were encountered The QAPP Section 12.2 states that "samples will be shipped at the end of each collection day 0 fsohripnpeexdt-odnaythdeelsiavemrey"d.ayInthbaottthheciytiweesrleogciosltlieccatlepd.roCblleevmeslparnedvseanmtpedletshewesraempcloelslefcrtoedm obneing Hn `Tuesday May 25% and shionpWepdneesdd ay May 26". Decatur samples were colle0c-- t0ed0or4, 03 = Final Field Rpt Cleveland TN Decatur AL yB1aMataiTeolmioegr H Problems expec od recommenFduatgieontss H Thursday May 27 that samples can be and shipped on chilled (on ice) Friday May 28". Battelle project leaders overnight and shipped the following day have when indicated adequate N time is available, and that this change to protocol will be addressed in an addendum to the QAPP. N Th`mearkseadmpfloresa cSoaltluercdtaedy idnelDievcerayt,urrewseulrteinsghiinppaed4-odnayFrpiedraiyodMianytr2an8s"ita.nSdawmeprleesnowtesrpeecifically delivered Tuesday June 1%. Prior to the next survey logistical preparations will be in place. H for Saturday delivery to recipient laboratories. uN `dBuartitenlglet'hseSseamspulrivenygsTaansdkhQausalpirteypaArsesduraannicnetOefmfailcerre,poRrotstaoninmaprBuohvle,fcieolndduopcetreadtiaofniseladnaduednitsure on full compliance with will redesign several tfiheelQd AloPgPfoarnmdsStOoPhse.lpIfnacrielsitpaotnesteitmoelByatatneldlae'cscuirnatteemdaaltaaudrietc,ortdhienfgi.eld crew mn | _`Final Field Rpt Cleveland TN Decatur AL 000404 2UE BraattTeolvleeTok ul Field Report Addendum -- Cleveland, TN aud Decatur, AL ec Sampling Details The following detaialrs included her complete the field record with M respect to sampler positioning. Cleveland, TN: The sir sampler at this site was positioned approximately 4 feet from the fire department ug headquarters located at 555 S. Ocoee Street. Ng DWeecsatteurw,aiAeL:reTahtmeeanitr pslaamntp.ler in Decatur was positioned approximately 3 to 4 feet from the Dry Creek Surface Water Sampling. The following det sr included ere to complete the field record with respect un tosit characteristics. Cleveland, TN: The surface water collcted at each of 3 within 2m of shore in ca. 0.5 m depth. Re- n `suspended bottom sediments were avoided in each case. Dmecataur, fAL: sThhoeresuirnfcaac.e0w.a5tmerdceopltlhe.cteRdef-rsoumstpheendelodcbalotitvom sseydsitmeemntwsaswecroellaevctoeiddaedeiacehaocfhtchaes3e sites n sediments were avoided. u Additionally, a single "quiescent" water site was sampled `within Flint Creek accessed from Country Club Road. The sample was also collected within 2 mofshore in ca. 0.5 mdepth. Re-suspended bottom n Kelly Jizan, Bale Duxbury Operations JDaotelly A 000205