Document MMvon2Qdmg4kdbQ6xOx3yKzLM
PPG Industries, Inc. Chemicals P.O. Box 1000 Lake Charles, Louisiana 70602
June 12, 1991
Ms. Diana Gamble U.S. Environmental Protection Agency Water Management Division Enforcement Branch (6WE) 1445 Ross Avenue Dallas, TX 75202-2733 RE: May DMR - LA0000761 .Dear Ms. Gamble: Enclosed is the DMR for May, 1991. The daily average limitation for total nickel at Outfall 201 was exceeded for the month. An explanation is attached. If you have any questions concerning this report, please contact Mark W. Wood at (318)491-4450. Res " ''
wil
Manager, Laboratory Services/ Environmental Control
wjp/mm
025015
ATTACHMENT I EXPLANATION OF EXCURSIONS
DATE
OUTFALL
PARAMETER
LIMIT
EXCURSION
May 1991 201
Total Nickel, 24 hr. Comp.
10.2 lb/day +5.0 lb/day
EXPLANATION
Nickel measurements at this outfall increased markedly about the first of May and remained above the daily average limitation throughout the month. A nickel investigation team comprised of technical and operational personnel from all areas discharging to Outfall 201 was formed to locate and control the nickel source. Findings thus far are as follows:
1. The system treating OCPSF wastewater is effectively controlling Cu and Ni.
2. Chlor-alkali and Silicas operations are normal and potential nickel source points within these units (contributing wastewater streams) indicate no consistant, significant contributions of nickel to Outfall 201.
3. Samples of the treated influent water (Sabine River) at several points in the plant system were found to have significant nickel concentrations on an inconsistent basis. This water (utilized for process wash water, scrubbers, cooling tower make up, and once-through cooling) is a major source of Outfall 201 discharge. The normal nickel concentration is below the MDL of 15 ig/L.
4. Nickel discharges dropped to well below daily average limitation the first of June.
Although the nickel investigation team is continuing extra outfall and source streams monitoring on a daily composite basis, the only variable found to correlate with elevated nickel discharge is flood conditions in the Sabine watershed. The record rainfall during May has necessitated increased chlorination of incoming water. As is typical of high run off periods, the natural pH buffering capacity of this influent is diminished.
We conclude higher residual chlorine and lowered pH within the water distribution system could have been corroding various nickel alloys throughout the Complex. Such corrosion is suspected to be the source of the elevated May discharges of nickel at this outfall.
SRMITTEE NAME/ADDRESS {include
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AME______
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NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDF.S)
DISCHARGE MCj^SpRING REPORT (MIR)
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expires 12-31-F7
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QUALITY OR CONCENTRATION
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NUMBER
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(REPLACES EPA FORM T-40 WHICH MAY NOT BE USED.)
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PAGE
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PAGE
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12-31-87
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NUMBER
DATE
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orm 3320*1 (Rev. 10-791 previous edition to be used
' 'until supply is exhausted
tREPLACES CPA FORM T-4 WHICH MAY NOT BE USED. I
PAGE
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ERMtTTEE NAME/AD ESS {include
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ANO AM FAMILIAR WITH THE INFORMATION SUBMITTED HEREIN AND BASED
ON MY INQUIRY OF THOSE INDIVIDUALS IMMEDIATELY responsible FOR
OBTAINING THE INFORMATION I BELIEVE THE SUBMITTED INFORMATION
lb TRUE ACCURATE AND COMPLETE I AM AWARE THAT THERE ARC SlG
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PAGE
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ERMITTEE NAMC/AODRUf (Include HilK) Name/Location ^^/fierent)
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ON MY INQUIRY OF THOSE INDIVIDUALS FMMECNATELY RESPONSIBLE FOR
OBTAINING The INFORMATION I BELIEVE THE SUBMITTED INFORMATION IS TRUE ACCURATE AND COMPLETE I AM AWARE THAT THERE ARE SlG NiFlCANT PENALTIES FOR SUBMITTING FALSE INFORMATION INCLUDING T HI POSSIBILITY OF FINE ANO IMPRISONMENT SEE IB USC I 1001 ANO
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NUMBER
DATE
YEAR
MO
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-orm 3320-1 (Rev. 10-79) previous edition to be used
' - iimtii cnct>tvtepvu.*ic'rro
(REPLACES EPA FORM T-AO WHICH MAY NOT BE USED.)
PAGE
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