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AR 226 -- 0402 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (DAPHNIA MAGNA) TEST SUBSTANCE Identity: rAefmeirxrteudretocaonstaPiFnOiSng, pFeCr-f9i5uo,roorocatsanaescuolmfponoanteen,twhoficFhC-m3a0y41a.lso(1b-e Octanesulfonic acid) (CAS # 2795-39-3). 3R0e4m1ar(kcsc :809-1T).he C3uMrrpernotdiuncftoiromnatloitonnuimndbiecratweassit2is30a0m.iTxthueretoesft6s%amPplFeOSis,F3C6-% doicteytlhyslulefnaeteg,ly0c.ol55b%utyslodetihuemr,la3u6r.yl0s6u%ifwaattee,ra,n1d20%.4S%ulttoolynletrfioaazomleer., 9% sodium cThhaerfaocltleorwiiznegdscounmcmeantrryataipoplniseosftiompaurmiitxiteusr.e Dwaittha imnacyomnpoltetaeclcyurately reflect the toxicofitthye fluorochemical component of the test sample. METHOD: Method: Not given GTyLpPe:: NSotatic acute Year completed: 1981 . SSpupepcliieesr:: DRaapnhdniMacNmeaigllnya Analytical monitoring: Temperature, pH, and dissolved oxygen. TEexsptosourrgeanpiesrmioadg:e:48-<h2o4urhsours old Statistical methods: LCso values calculated using the moving average angle Tmeetshtocdo.nditions: Dilution water: Carbon-fitered well water, St. Paul, MN DilutioHnawradtneerssc:hemistr2y5:3 mg/L as CaCO; Alkalinity: ~~ 221 mg/L as CaCO SLitgohctkinagn:dNtoetstgsivoelnu.tion preparation: A 5000 mg/L primary stock solution was Aplrieqpuaortesdwbeyreditluhteinngad5d00edmdgiorefcttelysttosduiblsuttiaonncweaitner10in0tmhLeotfestdivleustsioenlsw.ater. Exposure vessels: 250 mL beakers containing 200 mL exposure solution and a sNoulumtbieonrdoefptrhepolif6cactems.: 2 - NNuummbbeerr ooff dcaonpchennitdrsatpieornsr:eplfiicvaetpel:us2a0 blank control Water cphHemriasntgrey(d0u4r8inhgoutrhse):study: 88..00-88..11((1c0on0t0roml ge/xLpoesxuproes)ure) 002902 TDeimspsoelrvaetduroexyrgaennger(a0n-g4e8 (h0o-u4r8s)h:our1s8)-:20 C 74..90--99..33 mmggl/LL ((c1o0n0t0romlge/xLpoesxuproes)ure) RESULTS Nominal concentrations: Blank control, 65, 100, 155, 240, and 370 mg/L. Element values: 48-hour LCso = 269 (242 ~ 276) mg/l. Element values based on nominal concentrations. Remarks: Substance TReestmianrgkwsafsielcdo. nTduhcetveadlouensarmeipxotrutreed as described apply to that in the Test mixture and not the fluorochemical proportion alone. - CONCLUSIONS Tcohnefitedsetnscuebisnttearnvcael 48-hour LCs of 242 to 276 was determined mg/L. to be 259 mg/L. with a 95% Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY RHeolwieabvielrit,yt:heKisitmuidsychlarcaknskiinnfgo=rm2a.tiTohnisonstpuudryitmyeoefttshtehteesctristuerbisatfaonrcqeuaalnidty testing. analytical confirmationofthe amountoffluorochemical proportion in solution. REFERENCES "This study Paul, MN, was Lab Rceoqnudeuscttendumbybetrhe6350M8SC,om1p9a8n1.y, Environmental Laboratory, St. OTHER Last changed: 6/26/00. 002903 EETFw EeEA 2 dm Tyre TeAbs stSos ne Ye, rerialTeed ELEY itL500 Tost Orgegn apet reiRm AN0m MOMa EALRIt Me( cd 2.vo. 58. Age: First-Inster young (0.3-1.50m) `No. Crgsmises yor tro2sO tamt 5 Test Ties Chamber: 250ul glass beaker statad__NIZOPBKet,e Test Solution Vol.: Started2/1/81 200ml pete Test Solution th: Gem. Completed 2Ebi 4. bilution Meter, 8. stigator 1 wel} wyter ter. LB_.po LEpy Uses \2- 4 ie 7 Co ogNo 254 wldCSE TH ko USED -MAUNCGAVERIGE ANGLE METNOD _ Bplea [2 1 0lad7al o lgdad! NTT TM mall -- 0 Bard 0kdaql XT 711 Al es Lizel ledalll [ Bozgdl TH IL" 11 Baloo zo I + ledzdl | Iselpdl TTX T1 Ass Tal T= kdzdl 3 kal TF IN 11 Ro laa 2 BALL 2Bas3l FT HN 1] ALZADO IL74120 Rael 20 a1 ZITTN CrJ erm || rh #7 || 1 TZTFT zoo 1 1 NN siesome TP82/2 1 222/i3A1] ' Effects other than Mortality By eal] Tonk [ Total No, Affected No. Symptoms or Reactions 24-Hr, 48 Hr, 7: L rrr 1 1 rf] | Ff rm ESEWATERALSADIRKAMBERSAMYLQUL Sas JAR) LTE (TAI EATEau STEMVERY SEST COPY AVAILABL. 002904, ENVIRONMENTAL. LABORTORY AQUATIC TOXICITY DATA SVEET 1X GHSOE. To: 15Ee [ern Tre RNTested R300 Age: First-Instar young (0.5-1.50m) Ne. Crgemises ror tres20t0 ment BE To far al eal mae Test Chamber: 250ul glass beaker Test Solution Vol.: 200ml Test Solution Depth: ca. Time started_A/050gBpet(e started duke com 2/i (3/n B) & Bliution Wter_Carhen-tiltevedwel}wter wvescigeor ZEEE 1c, i (053 Cf0ida.mc0e .L2in3kype< . i y ou sip ZZ omE. KLCso ZS al BE "CS TTA 2% ANE Mednn lemon! =H 0 ladzall hrolsolN TT [I 1] Lined! -- 11 0 gaged] oo Roledl IT II P] IRL es T= TT legzdll 2 Bozo IY II 71] palloo IT201 0 Ted | [xdidl TNL" 11 Fel sell = Ts dell = dedl TTANT] BRI Zo I VBI Z tedudl X Bdsdl TP IT S11 Cr sI=70 71710S ZoI ROAT AT1N YJ mer te, [| 2220 [| 20% I 1 me | CS afl wa Il z| Comment: patio)SAA SOMO+S00 K00mELERYlot[SG om on ae rm n| ' Effects other them Mortality yy EE ---------- ---- ol | ospticn T wena] I TTTT rf ff rrr rr L fF mtTT We dS AAR ley SIeaAUIISAL NTE AY AMBEST Seebl STERPERPEi: BEST COPY AVAILABLE 00290 TABLE 2 ENVIRONMBELDNGT.AL2L-3AEBORATORY ST. PAUL, MINNESOTA WELL WATERFIRSSUTPPQLUYARFTOERRLAYQUARETPIOCRTT,OXI1C9I8T1Y TESTING PARAMETER AVERAGE JAN. 28 FEB. .26 MAR. 25 (+S) TOTAL HARDNESS* - 256 252 252 253 + 2 as mg/l CaC03 -- a TOTAL "M" ALRALINITY* 232 220 210 221 + 11 as mg/l CaC03 a ELECTRICAL SPECIFIC 360 305 320 328 + 28 CcOn?NDUaCtTA2N5C9EC* as umhos per JR" TOTAL SOLIDS* 267 299 a 202 + 23 as ng/1 JE..." pHA* 7.7 7.7 7.7 7.740 ce STANDARD PLATE COUNT*** 19 6 n 1247 per 1.0 ml ee -- CRITERIA OF CONSTANT QUALITY * Maovnetrahgleys.rang(eAsSTMshoSutladndaberdleEs7s29-t1h9a8n0.1)0% of their respective *+ Monthly range of pH should be less than 0.4 unit. 729-1980.) (ASTM Stan=dard #44 opetralml.bact(eUrSiEaPlA-d6e0n0s/i8t-i7e8s-01s7h,oulpd. not be 101.) greater than 500 organisms 002906