Document MJoqwGgxX39OemvzzEdJe5xZk

fik Z 2 . 6 - 0 S 7 o BIODEGRADATION (BOD/COD) TEST SUBSTANCE_______________________________________________ Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-780B. (1Octanesulfonic acid) (CAS # 2795-39-3). Rem arks: The 3M production lot numbers were 1 and 501. The test sample is FC-780B. Current information indicates it is a mixture of 0.58% PFOS, 14% diethylene glycol monobutyl ether, 76.7% water, 5.5% urea, 1.17% Hydroxy foamer, 1.15% sodium octyl sulfate, 0.8% polyoxyethylene monooctylphenyl ether, 0.05% sodium lauryl sulfate, and 0.05% benzotriazole. The following is an abbreviated summary o f multiple biodegradation studies on FC-780B. These studies apply to a mixture with incompletely characterized concentrations o f impurities. Data does not accurately reflect degradation potential o f the fluorochemical component o f the test sample. METHOD:________________________________________________________ Method: Specific methods not noted. Type: Aerobic BOD and Dichromate reflux COD GLP: No Year completed: 1 9 7 8 -1 9 8 2 Contact time: 20 days Innoculum: Seed was from various sources. RESULTS________ ________________________________________________ Chemical Oxygen Demand (COD) range: 292,600 - 377,000 mg/kg Biochemical Oxygen Demand (BOD) range: 5-Day: 23,000 -1 6 5 ,0 0 0 mg/L 10-Day: 44,000 - 290,000 mg/L 15-Day: 192,000 - 380,000 mg/L 20-Day: 205,000 - 490,000 mg/L Rem arks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. C O N C L U S IO N S ___________________________________________________ No reliable conclusions can be derived from these studies. The indication is that the majority of the product components are readily biodegradable. 002498 Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY___________________________________________________ Reliability: Klimisch ranking = 3. The studies lack description and records of the method followed. The values for the study conducted under Lab Request number 7685 are from a summary sheet only - raw data not found. The inoculum was not properly characterized. The sample purity was not properly characterized and the study lacks analytical confirmation of the amount of fluorochemical proportion in the solution. REFERENCES________________________________ _ ______________ Testing was conducted by multiple laboratories at-the request of the 3M Company, Lab Request numbers 4 4 6 1 ,4 6 5 3 ,4 6 5 7 ,4 6 7 3 , 5598, and 7685. OTHER__________________________________________________________ Last changed: 6/28/00 002499 t' v , TABLE 1 COD AND BOD DATA FOR FC-780B -jA B r e q . # ,AB )ATE :o d 30D5 3d i o 3D i5 3OD20 BOD2 0 /COD 501 4673 SERCO 3/28/79 377,000 140,000 290,000 300,000 320,000 0.85 501 4673 Haller 3/28/79 293,000 165,000 190,000 192,000 205,000 0.70 501 4673 Babcock 3/28/79 345,000 27,000 44,000 220,000 230,000 0.67 LOT LAB REQ. # LAB DE COD bod5 b o d io b o d 15 B O D20 B O D 2 0 /COD COD BODg BODio boDi5 B O D20 b 2 0 /c o d 1 4461 3M ENV. 11/10/78 360,000 140,000 260,000 280,000 280,000 0.78 A yjel. 346,000 93,000 202,000 245,000 264,000 0.76 1 4657 3M ENV. 4/23/79 1 4653 3M ENV. 5/29/79 353,000 53,000 220,000 240.000 280.000 348,000 34,000 210,000 240,000 a 7 0 , 0 0 0 ;^ V > /V 0.79 0.78 9 5 % C. I. 326,000-376,000 28,000-158,000 113,000-292,000 204,000-287,000 221,000-307,000 Naval Research Lab Washington, DC 387,000 -- *69 - 0.83 0.96 002500 Form 10620-5-PW O cc: LAB REQUEST BOOK - 42-5W PRODUCT ECOLOGICAL ASSESSMENT REQUEST FOR LABORATORY WORK Ref: E N V IR . ASSESS. IN Q . #_ 7 9 0 3 7 ( 7 t 3 o * } j D IV IS IO N FV P R O D U C T : & o f S O/ LAB REQUEST NO. 3R3nrtioiVZOOP| 4073 REQUESTER Name: FTt il\J r~ Phon e N o. S 'O "7^ Reauest Date: / --3 / " 7 9 P ro ie c tN o .: 9 9 7 r t O / 1X7a 0 Prob. No. Code No.: Sample Date: / --2.C -- 7 ? Da te Ne eded: Description: Purpose of Tests: f U A /<*u h k . B>i o 1UW - c f J e l'oe / f - TLLa . p*UtcL~d' LABORATORY y.Date Received Sample Analyst: Date Completed Hours Spent: YB Y Z zST7^ ^S -Z S -T -j P Please Call Requester If Delays Are Encounter ed. P H YSIC A L & C H E M IC A L PROPERTIES Heatof Combustion Cal/G (BTU/Lb.) Density Ash Other 7? & U o -h S o ! 3 6 ^ $ . U\> W ATER PO LLU TIO N PH COD O B0D5 " f%SOr u/,~`Ge ^ 5 - * ^ / Oxygen Uptake Dehydrogenase A c tiv ity (TTC) Other X y x x m ooo / y o , eo ` __Z7o/ 3 . nex> 3Z, a 2 .r z 1(oO flrS 'jO O 0 n o , o oo / f Z . , O X a g '. O c>U?'*Z7>'Ci W t Oi ZZO . - 2 3 o ] i BIO ASSAY Specify Organism and Method: LEACH ATE FRO M LEA C H IN G TEST pH COD bod5 BOD, Uitimate TOC GC Bioassav Other OTHER Bioaccumulation Persistence Degradation Products - -- --- --------------------~ O t ) s ) 1 - NSW Y O U . H . Y. ,, PBOVIDEMCE. B. L BOSTON. MASS. NSW HAVEN. CONN. BOFFAtO. H. Y. THE HALLER TESTING LABORATORIES QtCOBPOBATED 336 Leletnd Avenue P la in fie ld , N . I. 07061 p. O. Bax 48 PLAINFIELD, N . I. TESTING INSPECTION CONSULTATION * This report is the confidential property of the Client, and information contained m ay not be published or reproduced without our written permission. Client Project Subject NmM Minnesota Mining & Mfg. Co., St. Paul, Minnesota Purchase Order No. 711707 - 400 Laboratory Testing for C.O.D. and B.O.D. Report No. P -7 9 -4 6 1 1 Lab. No. L-2954 Date March 15, 1979 The following are the test results of Sample No. 7901 delivered to our laboratory on February 5, 1979. TEST RESULTS C .O .D . 292,600 mg/1 B . O . D .5 165.000 mg/1 B.O.D.jq 190.000 mg/1 B .0 .D .-J 5 192.000 mg/1 B.O.D.20 205.000 mg/1 'THE HALLER TESTING LABORATORIES, INC. RWH:lg Reported to: Minnesota Mining & Mfg. Co. Bldg. 20, 881 Bush Ave., V. St. Paul, Minnesota 55106 Att: Mr. David Seely -3- 002502 PERU, ILLINOIS CLIENT: 3M Company 04TB COLLECTED: S A N ITA R Y E N G IN E E R IN G L A B O R A TO R IE S , INC. 2902 N. Cleveland Ave. Roseville, Mn. 55113 (612) 636-7173 | REPORT OF LABO RA TO RY ANALYSIS (M ethodologies EPA approved) REPORT NO. 205 02/21/79 PAQR 2 OF 2 . COLLECTED BY: CLIENT COD, Chemical. Oxygen Demand, ng/1 BOD, 5-day, ag/1 BOD, 10-day, ag/1 - BOD, 15-day, ag/1 ' BOD, 20-day, ag/1 377000 140000 290000 300000 320000 r 'mom w*m ummov 1 CMCAOO MNU TO 3 M Company Env. Lab 2 -3 K 935 Buah Avanua S t . Paul,MM 55106 btb i COPY AVAILABLE MIASUMO HO* EDWARD S. BABCOCK * SONS. r.aK 4H Inc .A Ho 7 9 0 2 0 5 -3 Submitted y M all . ; fW^' 2 / 5 / 7 9 uB-t-i^JMBB - '1w''.-/ ' Tima St 15 -/I- - 5 Day 10 Day 15 Day 20 Day t' 'Sr; Hi ' BOD * * /l COD H% 000 **^ *S S l *ty0o e> UK* i .},: jjte L *V* . C. . .A.'i... . * - 002504 tO N S .I e * , DEPT. CHARGE 0012 MONITOR 0 S 3 S PRODUCT ECOLOGICAL ASSESSMENT Hf 0222-=~ErftaFH REQUEST FOR LABORATORY WORK #Ref: E N V IR . ASSESS. IN CL Cj^M***t^c*J-*______ D IV IS IO N PRODUCT: S ^Z -C rud^. LAB REQUEST NO. REQUESTER Name: B r A A & jt t y s ' Request Date: / ~~2 ~7Sr* ______ Project N o .:. 9 4 7 0 0 / W OO Code N o .: ______________________________ Phone No. Prob. N o .. S o 7? LABORATORY Date Received Sample. A n a ly s t:______________ /- -7 U J/& Date Completed: T - 2 . 9 - 7 9 Hours Spent: 1Y3T / o A , 111 Sample D a te :______________________________Date N e e d e d :__________________ Y ____________ B _____________P _____________ Description: ) n't Purpose o f Tests:. Ti> a h i k 'S '& i O n ly <S/ts< OTt*.*--/ ^Please Call Requester If Delays A re Encounte d. I t fi'ts tirJ -. -- ,4 ^ TT'M** V * &P H Y S IC A L C H E M IC A L P R O P E R T IE S Heatof Combustion Cal/G (BTU/Lb.) Density Ash Other FUCt- 7SO0I /^n) 7>e a A t /v5~o A^-Zs) FC7* /$ . T S j/ FC Z4" cfJ/ _--5ZX_ (vJ=l^-yi') W ATER PO LLU TIO N CM Kc/.fo JO< i/'U Asi pH oreffLtJ" COD-- X <SS^.OOO sO >wN l4r SSLo d o BOD5 BOD, Ultimate TOC GC "2.oet^ ' 4/5 c c /J X l r m e e aaV5 t&&& M A X * -T J_ --- > < S 6 Ar~,-Az M& JTGS q W j& o D -.t - iE Oxygen Uptake Dehydrogenase A ctivity (TTC) s // tX* Xl/w f A / <4*A-C R O & f a* ^ ,3o>/0 r\AAL/TUb A tiU iprt '/ Other x VXi 2, ~ru ajl< IXCc--/. _z ? idftfi UbtAJt.JUAAd a -yP V ^ c R /)^f /io-- T~; BIOASSAY SfFpCeuctnilfldylCaOirgtapntiiszlm^aAnd<M./evth*odc: ,/i'-taj\.) OrVt. T V <?<f l^x'f^-s'j ' yu- * *r3L, 'S*# ft (hQi>/-5A" t.Bobtoj&o/ ys" 0U~cP^SOP y. LEA C H A TE FRO M LE A C H IN G TEST pH 4 'ST jFBE> iC ' h z y -T ? COD bod5 BOD, Ultimate TOC GC Bioassay Other -------- ----------- .K uvk5? U H4M L4 4 / 'DtTiDtAL /OB.K OAJ f-C----- *75?57T r -OT~ $-/ OTHER B io a c c u m u la tio n v. Persistence Degradation Products Recyclability Burnability Weathering BESTCC PV AVAILAB1 .h OC a s a s ____ f !~~C > y * 1 90SZO(> w o | v y j 3; Sc _i 31s * " a M i L Q -J 3! o ' fi Ul ul X i ^ tSdS * i fi A O wv ci * Voo> S5X r- rc4f 1N. Z2 g O a -*-++ , * a Si P o /-\ O *~ + .+ d 2 oo C" < *J UO- < U> C <1 t tu. + vu <a C\1 * <& .VU o OO <S u> K> * K yi h - A^ O <5 O <50 (S tu> ST a: <* vu X 0^0 ^ ri^ v  a .y .c A '^ - jo- rau T7L >i d d. i3 y 1 l ^ r y j X i V a -4 - X trJ i: atusas t ___ L $3 i f! 2 - fesj -- p ; r -- ^ -- ---- ---_ ~ LSka?dU(t 2d: ^ i td !:..53i M 2 l.3 -1-- r r r - T -4 - &* . -A---- .A & & d tk L 0#> i .-f*-*' i! f-;-]fr 'T~ a. S fc. ~r i '- f - - r y i -]-_ )._ |:_ l : :) ' - B^ST PYV. ' r : ; '; {J * ' 'l"r " 1 A o /)-:;.. ^j rrrf.' L *~1 t : i :: ! ^ r r ! ^ : t t : A* t BotttoNo. / r SampiSin -- -- -- R a p rN o . ~3 5 MVIRONMENTAL LABORATORY BOO WORK SHEET BEST COPY AVAILABLE Df:2 - iV - T i WJ. Dilution Wat: J 4 & _ K E ta tu s A M h u j Me. Awg._______________ Oaaoription 4>J+r%4LA) /pmA-L. D.O. (Os) %x 1 .1 A FpTo t t i/M uM Ity S iV r ? '* ? 8 ^3 STZ>. MGTH. s *&r*M in dACCtuAT** eoAm C M m *r* . / : 72 /O Z n 73 V / // V 3o ` ><0 f f . frfeA -fe-v \ T v )^ r r ~ -r ~ Jl 5 a**1 AsyCtk+^A* 4 i OT 8 /4 2 -z r ? .y r <<r ft-lffi& .L o T S ., ( u ^itu tO __ 1 . h0s 2,36-*ng/A ) -- -- ^ * t*yj j ^ 5 ^r 3 .7 0 ,< /o t~ -- -- 'v;/V';* .` ' JM -& ) ' '. .t '' 3^0, ooo 2 & o ,o 2 0 ,0 0 0 ro ,o o S L O /d o e / 9 0 ,0 9 0 *? # r /? - r /3 /n /* 1 2 .3 / ao 1 .1.3*/ \/3 3.o t.o /J& U U D & 3 ,0 (a0 1 .0 3 .0 (?.0 1.0 -- ** KS/7M /rc -1g o q t . * r . ' A e s u tT '. &C-1K&J L 0f~ / -- **4 0 0 hO&rJ--* /OPmS * r .tr 33o 3 2 0 , 0 CX? 2 So 000 JL&jQi oo M o 3 -3 0 . ooo /O t0t {.& #(> " 7 S 3 ----------- S* (O </.$< 3 3 0 .0 0 0 P o , ooo P-S, / o ^o c 1 .5 `S' 3- 0,000 /7 0 ^o o if / r 2>0>00O 3 / o, dc 3 / r .*/o y c o ato o j OOP 2 /0 ,0 0 0 110,000 S 4 ,0 Z r M tM tD Sr SJD /5&m * Au<c+ag - 4 7 . d iSd*n* .d/m&nui M aJP - fl*o , Jtvt&^x+JbUP o+*~r&M = 9>Z) H .Z o 3 /S P 2 -1 0 P -8 '0 80 o is O a Vo X?o ron* fa-* n o 5 ^ ( JF * mVIIMMMMTAL LABORATORY B E S W (8 W > W ffllA B LE aNo. i w - W - 7 f L /.4.S . Dilution Wr:f ! t 4 **Q3C*ffHt> 1&+* Botti*No. 46 xi 1 218 M SampUSiu ^0|wfBtion turnAL OJO. to,} rs S e e b * 2 S __ - wWwwfac/g jJ !4 S 3 ,o ><o 9 /0 1 .1 4 *1 H L -iZ & 'H trs/ Yrm*ijfjt) />t>on3'-*/<roo?J ( -- -- -- 5/2?Mmo saemcrh *$ * M uM /atl C A U U l&;f*!*V/ A-_ ... *0i* I1 r!*15 :' . C ^ y,gS--4,oNV>ti^ W " :"^ 6-3r 1A C V,00 0 0Q r0- itc^ooe .COMODO 2 1 0 ,0 *0 hotoef / yo*d VmA m Z>L i i S f r i 5 ,0 H XX bt 0 .o -- 4 <<vo 210, oo VyPyPO Vto,o iro.ooO - 3<iO Ii',000 /S9.0OC f t </.o BCO &r+iOAtJ> - S , oy 310 30. St 0 JdJu+Ai mJ/ mm V<>o Jn o X 2 ito ? 3.7r n 0 hd~ w ZS'o X3 A3 RP.QT.f ppV AVAII ARI F ,0ft!7.;05 A ' ' r.o+m' i tfiM ENVIRONMENTAL LABORATORY BOO WORK MEET BEST COPY AVAILABLE J B i* N o. 5 Dilution Wittr: ______ _ Bk. Af., (V iif P tL rffo P A JU jLD S ^C A M LM nM M M H M M M M il *J______ 2 ^ . (L y fa t L OD SmtiMXD wmmmmbmmmmmmmtmmmimmM ^ M a jw A 0 H M M jpjrfSdLo 3h*CSt ^00 3 ,s r 3-lcf o o o 3 )0 .0 0 0 n o 0 0 0 S <iS ~ 11 0.0 00 n .c o t> IfO jQ O C V 0 0 2 5 dO -- 9 *7 - 'Z Z ~L . ; ' ' ..T T Z ------------ * * Jb * *- -SJT7 J J o 'S . ( * '* = (N Y *'x*" -- '9 " -- /T**W" , V *Vk f * / O S s -- -Q **a M *$ o 'b * *ir^ W W T5 ^ .W . v-,- . * - * - '0 > -W > 1 - ? '/* |||,pppr * .. _ *- -X'<? > S'Q > FT~ -- 9% " T T -- E p P 'W T 0 '^ ~ m JPJ /*</* - / ,*< r/ / y * * y TJ -- S T - y j*-*i * * < * * !'/ O c7 > /J fi <?* It V" ^ ! '^ / X * ~JF5T~ _S*o> ify m r T ? . Dir~1RSBP9n - ' ~X -- j f x Xr X" .J '0 > _ '0 > y> -- A -- 0 ------ g-,---- A ^/ -- il 1 4c-- / W ^ y -- -------------r f /m i& g if -- i 7 T " ^ (J V fT *^ ) -- ItS J .o T V & L -'J 7 -- n- ? S?'g -^0 > T P S T S ' Q> ~ ~ S *r ~ d ia v i i /A V AdO O J S 3 a / iA f v w i i '& i ^ r r /i> "i^QCddrr i1 j r t r r jv q e fc f g y ^ '^ y S * ~ * V * C **!F *7 L* : /+ v s ti) ^ 'VMtmVWQ >nrvie r*etn9iP mm uam s HJ3H CUS S *'Z "Z 'A " J i' T? Qo'& X `i O V9W I -- r ^ r * O&O * * n v0u0irtf o% / W *fK J j*y *m * 7 p UOddfJOMQ AV*J|8 1 :P*e :m M HO f 'P fi U r -h -f" * i 3W xuoM aoe AuoivucM yn t v in 3w nohian3 S T S fy N ^ r ' J*y *^ 4 & ** ***1 hp y *ry *? *r 'Q '<J %2 Y * x<V -y ^ y y y ^ f^ O of- y y -c y r^ lt 0? y /-- /^ / Z */ .....7 7 " -- -- -- zts*(du*S J' oN^uoe FONM I H I M BEST COPY AVAILABLE m vm O N M M TM . LAaOAATOflY No. > o .Q .^ DmtkmWlr:/S~< F o rm 1Q6ZQ-5-PWO cc: LAB REQUEST BOOK - 42-5W PRODUCT ECOLOGICAL ASSESSMENT REQUEST FOR LABORATORY WORK R^f: ENVIR. ASSESS. INQ. # 7 < f ' 3 ^ 9 ^ ^ C DIVISION PRODUCT: f=C - <8 ~ L.Q+-1 LAB REQUEST NO. *c t1on-Z0aPi REQUESTER Name: zn<-> X 'e jn -fr '" Reauest Date: / --7 9 --7 9 Project No.: 9 9 7 O Oi 3 to O Code No.: Sample Date: Phone No. Prob No. Dite Needed: (T 0 7 Description: 2> s. U.tt~rrr\ Ac. 1 *Q _________________ Purpose of Tests: 71 S-- /a Jat~S o / LABORATORY / t f o Date Received Samp): Analyst: Date Completed Hours Spent: _L2. YB /-z jy -7 7 // s . P Please Call Requester If Delays Are Encountered. PHYSICAL & CHEMICAL PROPERTIES Heatof Combustion Cal/G (BTU/Lb.) Density Ash Other /r o> --/ UJ? r. _ WATER POLLUTION pH COD BODg -v-xva i J * BOD, Ultimate TOC 7* O n v * GC Oxygen Uptake Dehydrogenase A c tiv ity (TTC) Other 3 S --21 900 Sc 3 S 3 .O 0 O V . a ZZ m cJif Ajl,c x txir < 1/) BIOASSAY Specify Organism and Method: LEACHATE FROM LEACHING TEST pH COD bod5 BOD, Uitimate TOC GC Bioassay Other ' -- OTHER Bioaccumulation Persistence Degradation Products _____ n n o c ' 1 T . .. - UA*'* W hite - R eturn to Requester Canery - Environm ental Engrg. O ffice F ile 1 Pink - Environm ental Engrg. Lab Goldanrod - Return to Requester BEST COPY AVAILABLE MVIRONMfNTAL LABORATORY 0 0 WORK WEST H *No. S Dilution Watar: / f f BottiNo. SampiVa Daaoription Xau 4 A t* / mmg. * Bk. Am* De sta nemo S 2 B U eMMLArrw ;' /^VlTiltffn^' V ix " ir ro kj&HMAOE)J&4S j TfO PC-1W& corsoi -- -*2. -Jb ^ s*i..P ; L< O -- <o*y <>* : 9-0 <,r <*- .* v:;W J>0**U~*#*V*J (i ^JLPiA* \XuAjtlm -to Y M 3.0 1 Pt 1* ~s -- 3 ,/ < o ,r -- < o ,r ie- 7 to o miMfib . -- a< -*c ? / 5"/0 -- V llL 6/0 - <0#S~ * iK ic /. ____ AAOC * ^ ` 1 '- : 2.^ I 0 6 2>> 4 J* i V O (2m^ ENVIRONMENTALI 11 LI AA BR OD DRAATORY BOD WORK SHEET Blanks: lottle No. Sample Size Description F c -'tio B Lot o) D.O. Depletion - A . i .T> / , ^c>^3s Date: ...... Dilution Water; / M __ Seed: flu L y t y * - ( a u T Bk. Awn. ^ Day BOO Avg. '' isott f u ho / 4 ,6 '* fl.-Z O d .S o tO S ' Y ' f /<* 5", G O O 1 3 . o _________Da ^ ) 7 .0 / ^ > p __ / ' rs-o )c4 5fjfoo<0 ir ] V K 12&0 h tfi l `X * 2 . * > f 1# 2 o r f 7 .0 ^- 7l i . K . > . - 3 1.3 f ?7 ,/ UA4**0't>D a q a J L s * t\JLL+^A> -- r0 / ( ____ t L vi ^ aX l2s2 7Yb / l K u L M i y\ (J a& sl = < 7 .0 <. /< ? J^T? *L fY ^ \ N t / - Ai Lc ^o s '.o n/\.f>a ~ i^ $,<K ' 1 , >0 > /0-U 1 yj-z\. 2m n. 1L&U-*'*- \ /I J'T 'V nJ^* ? ) o 0 o *F -- t'booQ * V T j O o o * t 3 C ,o o o v t/ f t 1,000 1 3>; o o ^ _^ 3 ? ,eo P ^ 3 Odd i i m . oop iy R C C T C ( ^/ rD VT rAW\AMA IlIL An BD LI CC -------- 7 t . I K 3 v7 1---r----1--- 00?516 If " 2 ',/HM I a* 20 ", VH-i ENVIRONMENTAL LABORATORY BOO WORK SHEET Blanke - V&S3 5 Date: i - / * - / 9 Dilution Water: Bead l y * - d .U f' Bk. Avg. Bottle No. Sample Size Description FC .-190& i-o T SO) 0 .0 . Depletion fO - Day BOO 3 *0 JL^ ( Avg. Q'T&r+f 2STJ / 5 ho 7 3 >o ?/ _ * r 7 . a- Ti z, o r V r P ' / $ \ A i3 T ^ T c \tr > iv .-- ob o r* l/Q.nOd ^ o . o o e At znt>,oiO ***,ooo * Z l l o M J--.--2-------7---o---<---)-0----- 3 ^ 0 0 ,0 0 7 -^ m ______ / f f * ^ T / 2 a -g g o o c _______ ( H<v A j u o s t & V ) _________ r <9. < 2 0 , 0 0 0 ZiO,OC\ ---------- A 1 , ; ............... mm - -- *- K r V . (X-v . 'y ' V {) 1 -- 1 )0 2 5 1 7 17 --2. 70RM j"'.VO ENVIRONMENTAL LABORATORY BOO WORK SHEET 3 Blanks: _________, _________ . _________. _ ......... n...- 3 - / * - 7 9 Dilution Water: .f . S-- d:fu A tr1 ~ & U A Bk. Avfl. ____________ Bottla No. Sample Size Description F f-n to & l.o t r t O'TXyJ D.O. -t (4 ' /o Ao 1 3*o i r S '** ? *7 .0 - S ' r.s ' *3*7 /.-f < * 'J T fuJAs - L js r r f p y Daplation |5 " -O a y BOD Avg. _ /Wv ^ . V'f'V J 4 -lo ^ o o tM 3SD , OOOt x 1> -- ./ b . W< i*> .o o LO.OOt *4HCC>i ~ v " ............. "0 * - -- H K i} r 1A 1 , (Xv , \/ y* . i U 0V JS 1! T / ? - 2- roftht r-vto Blanks: 3^ ENVIRONMENTAL LABORATORY D .t.:^ V ilZ 2 _ BOO WORK SHEET Dilution Watar: 3 y*4(A. Saad: LAa^f*je - ________ Bk. A v g /__________ Bottla No. Sampla Siza Oaacription D.O. Daplation -- Day BOD Avi F ? -i*o B L.oT CO / O'T&yJ ^ 2 S T V ^ ) . /J ZF ^ 7 L S . U* * V 2 iO 1 If ---------- ho 3 . 9 .o ? ? ----------- 4 .8 2 .$ r o fio tlO p e o to ,0 0 0 _ 2 >.< 4 6 0 / 0 ^ ^ j o . o d o - * > ZioOfi 4 6 o\ c?'.4 - i o . o o Q ^ -7SLQ.G "V * T ta & 4 , too < ' z ftd ^ o o O ZlOjO* V7f - K *> i r' . A . (V ' . t S? "0 0 2 3 1 :* ii/" 2 't Joule No. 4 J2.S _ i. ..S I *>0 2? ENVIRONMENTAL.LA B O R A TO R Y BOD WORK SHEET Blanks: Sample Size Description 0 .0 ^ ^ p le tio n X&cXtXT' H ^O &Xa'Yi^x*4s 3 fa 4i %<4 WN> >^3 S Date: 1> ' /L- - ' / ^ _____ Dilution Water: i %~f __ Seed: ti.jjB - f t u Bk. Avg. Avg. 7 -o w r o rfo w o .s r o .H r Arv(s>~. s e e o eoum ton yv / H o l-T o l. = ________________________________ 3 . - ^ \ / L a^ a IP -7 .S V / V J T *4 f t ? 6 - S i L 2 - J O s 7>> - /fc a - v o -fie ' h? *3 V - l:~V.( # 2 .0 (Ury&UrCo, 5 f. o 4 . .*< > 1.0 8 3 0 < .0 ff.es- fajL^U : o .u > 0.2.0 <>` 10 O iiS l. o jF Z r A i */ J i wi 1 /ri / ] (?) 7 S ' 'lb '1 - - O O iS iii J < T -2 .2 OHM i f f i i j / ENVIRONMENTALL LABORATORY BOO WORK SHEET . -j S' Dm: 3 - / f a - 7 9 Dilution Water: 1%-P . i Bottla No. Sample Size Deteription H z -O > J * t^ h 4 S 0 0 <Q 1 N D $ W > n *V ^ r f ^ vs i.* r ? 9-------------^ Av. / /SUj -a * d .? / 2 73 V 4 ">0 f i C __ usQ____ _n -2 ^ S 0 e c U T K tL S _ ic W 7 7 /5 " V H x O {Lc -y3 X *~ & O s K r tn .u Z i . a M f i * j*v T O r& _______1 & ' - - n ib ; ______ `f i x P Al At r t ^ F / T M H M* n. * w> a - -J > rp 1& iKP R r /irjM fl 4,o *.o 4,? -7.4 />2 ? p .fA rV /j /.o \ '< ' J li \ \ \ v\ ______ i / I r ' _ R F R T P i 1 P V AX/AII A R I F -r'-i A x* y (J ) (a 1r / i ~u/ ^ * u , ifX / ^Vy. I L V " ,, . ^i 002521 u >>- V >c?M /WO Bottle No. Sample Size /2.S / Blanks: 'Z /t - jL ~ ENVIRONMENTAL LABORATORY BOO WORK SHEET . w J f e T 3 J5~ s D .t., 3 ~ / f e - 7 9 Dilution Water. 1%~P 3W #Sed: ye ~ ft Bk. Avg. Deecription 2>t * / > D03 l 1 j g " 3 i t; os AI v 1 w < r3 n r5 1 " Avg. C tw -~ d t , o r.-j V .V i'S .is - sn t - 1- Or1hr T l J ^ 2/ /2> V -- 5 ^ -- a </ --- g --- Up S f ie o e o u m o L -s <!P ............... V *A. 9 /t/n T H /i 11.^ " r t r m**i A if| %l j$ J L : ------------------------------ - t i l t r ___ ^ ....................... o > (Y l `' yyr S3 .. *}jO n lP urn 4 .0 &,*/<> > = 2. J - <L* .& & '.} A 1"P 1 W " U / UW / / , /TX / / * i 17 " A i r* 1 / i y *X bs ' ' l 1b G0252C /<-. 1 > rOM * ^*A*v'Oo ENVIRONMENTAL LABORA BOD WORK SHEET Blank*: RY 3 < Date: ...6 /* / Dilution Water. / )> i/ S fd :/^ a ~ ** Bk.A v .______ Bottle No. Sample Size Description D.O. * Depletion ^ Day BOO Avg. B o o /c o o <St> / sT - X , - / JLltLiPbo -1*? y ijfr 7 / /.o S m . 3^0 cf i 4C o "Z V -- Oc, C- Jf * / ' `loo 7.30 V H.cd (mtfO ] % ( S . 30 C^ 0 / / ^ - ^ 2 ------- I l f U /| * 3 ^ 5 T 7 W ii 2 . 60 3 .7 0 - ^ * 7 321 3 3 S' ---- -------------- 32^f ^ -V .7 5 - 3 X 5 " \i^ 2 - J^rL -- / f a * *U T iw a tm . ^#0 i r r z 7 'f - - 1 C t f i C^iajl^Zu v * a>1 a. ffi A ifo ttk w p - - 0 /^ r > \ VX J ltu X u y u 7 tv. V *\ (,o 2* o 3<o f.o S', 3 V .z r 37 0 2 -0 + 3% 0 ^XO V 3 f0 300 3 / 3 /0 jt ^ V 3 2 -0 300J 3 i0 J 3 io -' (A JL>^ 3 x o ^4 fVt 3/ b ^ i / t 0 3lO M \ BEST COPY AVAILARI f A .i IA a r V - 7 -- 00252' e'GRW'j *-w >4 Blanks: Q jj* ~ ENVIRONMENTAL LABORATORY BOO WORK SHEET 3 Date: Dilution Water: / Seed:/x^<a Bk. Awfl. / Bottle No. Sample Size Description D.O. B o o M o o <iT / i T JL ixU P b o ^ 't** </ iL/Depletion / 0 Day BOD Avg. *7l/ - 7 / /.o S> m 3 '0 - t f l if, 0 r,*r if 2 0 * 2 A _ . ^ o v 3 30 * ^ S 5 5 * 330 * ^20* 320 V 31-) >64* . ^% O M t f i . 3 2 . ,, ,, Z 3 / 0 ,, 1 J F F S T r.O P Y A V A IL A L E \ .... 1 _ '0 l ,,A \> ' u -- 002525 J> A_ t ronfA J-j v /* j2 u ^ ENVIRONM ENTAL LABORATORY 460 5 Data: *>- / < - ? v> .. BOO WORK SHEET ,, w*" ' ; M 5 ~ S /A SMd.A y , / . . . - Blank: ___________. ________________________ _ _ _________ Bk. A v Bottla No. 7/ Sampla Siza Daacrtptioo & Q & I& 0 D < in r i * T d ifito * ^ 1 . - Ao ti' _ m 3 ,o if. 0 .0 . Daplation Day BOO Avg. 'W / r ft I . (V * - " OtWb' A1/, C t_ 3 . A5? ... .. Y 4 * * 0 -v- +TO It . 3 2 .0 J e 330 ^ 3 VO 2 .T 0 i 3o<? ; ^ 2 ,0 U r t i or<7 Y n r t t f ii. , A 9o m -- * ..... ....y r 3 o 0 < *, l i . _ .. - ,0 -- i\ v 1 __ n n 9 C 9 V . 1 .... 1 * > - o*** 3ottle No. 1\ Sb. wt> yi Vs ENVIRONMENTAL LAkSORATORY BOO WORK SHEET Blanks: Date: 5- ' A ~ ''? V 1 D ilution W ater: l \ \ !? Sample Size Description D.O. Depletion o ` Day BOD Avg. /.o . * '0 3 *o & qoJ c *>o *xri> J *T .i \/y f l7 fj* " rf) l j/ Jy L -, Jy' / l^ 7 7 rrm rx * 4 i t e S ^ .... -- * 3 ,f o 6oo. 3 2 0 <*> 4 J T 2 .K S t* * - 3 3 -0 * 1 ,3 0 3 3 0 jb JS ' V ' w -------- j r 1- " - 3 T iO -^ 3 V0 * - 3 'L * > * tiA fS L ^ *irt 'JLHOs 7 ') fn l f 3 3 0 ~ .b r . P BE5" COPY AVAILABLE A '0 Cr 1) id b .'. i ... --- 002S 21 2 5 ~*2 . ' VT'-' ". ' Cn l oe ^ V P W O j T jU O f M QUEST BOOK - 42-BW t,; ^ ,.v, fv t ^^ r PRODUCT ECOLOGICAL ASSESSMENT REQUEST FOR LABORATORY WORK h: A S S E & fiW # 7 f ( ? 3 7 ^ 7 9 3 p f J . , LAB REQUEST NO.. CT j Z Z L L L o / SO vnam nni Vw -- REQUESTER Name: j ~ / t w J^JU V U tT Phone No. S'O ^9 Request Date: _ , / . T ^ 3 / r 7 ^ Project N d . u a g 7 i a a t g 7 . e t t Prob. N o., CCooddeeNNo0.:.y - - ~ -Tal ,__ ____ ____ SamplePri:. j & 7 f i \ a V Date Needed: Description: t~K*. PPnurrrpiMojAgoMf Tests! frifiT.*i' , a<fa J lg - r L __ i ~ T+*!4A!a 3 o* i LABORATORY Date Received Sample: Analyst: Date Completed: Hours Spent: YB Please Call Requester If Delays Are E. n` count\ered. # e !1 I1 | . . .. , R ^ t f e s T F O R LA B O R A TO R Y - WORK 'r : ^ 1 - ' k F I URL REPORT : -- R E Q U E S T O R -r / 'A M E t E R R : . PROJECT MO. 99 70 13 127 00 OESC FC 7 8 0 -B LOT - 301 ' C O D E ' TYPE DATE T IM E -y: f l o w rod . d^c : . ....______ ... TEST BOD BOD 1 0 BOD 1 5 B O D U L T C2.) COD 2900 0 300000 320000 377000 MG??L M G '-'L M G ^L M G ^L 1 9 .0 0 0 0 H G /'L C 1 9 2 0 0 0 M G /'L 2 0 3 0 0 0 M G >'L 9 2 6 0 0 MG^L ' 4 4 0 0 0 . M G ^ L .; r 20000 50000 343000 M G ^L M G7L MG>rL ; y .f - rf. r. ..;.\f. ' OTHER t.* --Ba--ioacc.u..m...u.l.a.tioni \ Pariistenca Degradation Product* W hite - Weturn to Hequeeter Canary - environm ental Engrg. O ffice 1 --*l-- .,*.).. - ---a. 'Lziizz i'Tv-* v, V; ' [?>'XJ oozsgy ~r Alati tsL* m ro r i) Q ld n ro d R i uraw am* ' frrn 1 0 620-B-PWO / - (E E & PC C o n ta ct) DEPT. CHARGE 0 0 1 2 - MONITOR 0222 -- ENGR. 0535 - PEA TO 6 ~?? & Lab Request No.. Water and Wastewater REQUEST FOR LABORATORY WORK TO: EN V IR! O N t M E N TA L ENGINEERING LABORATORY _____ _ - BUILDING 2-3 Requester Lab Personnel Name: _________________ Request Date: Project No.: Prob. No.:_____ Description:. ^ 1 ^ 3 a r r X V I A > T > Hold Sample For__ .Days Est. Date Needed:. Special Precautions. No. Sample Description 1 Total Hardness, mg/l as CaC03 37QS- "37 rw 'jc r r Data Rac'd. Samolej . iV -? o Analyst:______ G A U -7 Date Completed:______ <S - - 2 Q - i f r Hrs. Spent:____________ 2 <S> > m > y C o S r i ) 2 7 ^ - 2 Calcium Hardness, mg/l as CaCO, 3 " P" A lka lin ity, mg/l as CaC03 4 " M " A lka lin ity, mg/l as CaCO, 5 pH 6 Chloride, mg/l as Cl 7 Silica, mg/l as SiO 2 8 Total Fluoride, mg/l as F 9 Soluble Fluoride mg/l as F 10 Manganese, mg/l as Mn 11 Total Suspended Solids, mg/l < 12 Volatile Suspended Solids, ma/l 13 T u rb id ity, NTU 14 _[Otal-ShdS7Wr / f t p < - a JJL 15 ........ lhds, mg7l" 16 CondufiiuuiyjH HilikLio m JIL * 0^ 17 Sulfate, mg/l as SO, 'X V . fo '/ o .u p y ~ T W ~ L 2 Z S S iS 18 Sulfide, mg/l as S 19 Sulfite, mg/l as SO, 20 Ammonia Nitrogen, m g/l as N 21 Kjeldahl Nitrogen, mg/l as N 22 N itrite , mg/l as N 23 Nitrate, mg/l as N 24 O rtho Phosphate, mg/l as P 25 Total Phosphate, mg/l as P 26 . BOD, mgn 27 COD, mg/l (Short, Strong, Dilute) 28 Total Organic Carbon -- TOC mg/l as C If* * \/ ' 3 S2 .28 ? ** 29 Surfactant, mg/l as LAS 30 Phenol, mg/l 31 Tannin & Lignin, mg/l 32 Total Cyanide, mg/l as CN 33 Oil and Grease, mg/l 34 Standard Plate Count No./lOO ml 35 Total Coliform . No./lOO ml 36 Fecal Coliform , No./100 ml 37 Fecal Streptococcus, No./lOO ml nt _V -li>__ F 1 ns 1S Comments:. _ ST COPY AVAILABLE- - - - ------------------------------------------------------------------------------------------------------- 0 0 2 5 8 9 , cc: Internal Correspondence D. R. R i c x e r - 5 3 - 4 N D. L. B a c o n / R . L. B o h o n - 2 1 - 2 W - 0 5 Toe J . A . P I G N A T O - C O M M E R C I A L C H E M I C A L S L A B - 2 3 6 - 2 A - 0 1 From; E . A . R E I N E R - E N V I R O N M E N T A L L A B O R A T O R Y / E E & P C - 2 - 2 W - 5 MIL-SPEC AFFF BOD AND COD TESTING Date- M A Y 2 5 , 1 9 8 2 3M At ta ch ed is a summary of the BOD, c a r b o n a c e o u s BOD, and COD test results on FC-203C, FC-206C; and FC-780B. This testing was conducted at the 3M Environmental Laboratory and four outside laboratories. The results were more variable than I had anticipated. The Galbraith results on FC-206C were typical of their result from past testing, i.e., they had a very high B O D 20/ C O D ra t i o . T h i s o c c u r r e d d e s p i t e the f a c t t h a t some of this testing was done with a nitrification inhibitor (the C - BO D results) and some of the tests w e r e done using a seed unli ke ly to contain a large p o p u l a t i o n of nitrifying organisms (seed from the Knoxville waste treatment system). While I had previously thought that their results were due to nitrification, I must now say that I do not know why Galbraith gets such atypically high BOD results. I plan to use the average data from all of these tests in preparing-fcur Product Environmental Data Sheets and input for our Material Safety Data Sheets. If you have any questions lpncerning these data, please feel free to contact me on 778-5079. EAR/mk Attachment 002530 Lab 3M Pace Serco Capsule Galbraith S & W Seed Galbraith Knoxville B O D 20 (mg/kq) 580/000 800,000* 440,000 570,000 616,000 670,000 AND COD DATA ON MIL-SPEC AFFF PRODUCT C-BOD (mq/kq) COD (mq/kq) B O D 20 COD C-BOD?n COD FC-203C Lot 501 600,000 730,000* 440,000 620,000 671,000 730.000 740.000 810.000 730,000 737,000 950,000 776,450 .79 .60 .6 .79 .81 .60 .65 .86 641,000 776,450 0C0N V00O Average S. D. 575,000 85,000 594,000 90,000 782,000 80,000 .73 .12 .75 .12 * C a l c u l a t e d B O D 's f r o m d i f f e r e n t d i l u t i o n s w e r e v e r y inconsistent. Pace agreed to repeat this work but inadvertently lost their repeated test results as well. We did not request a third testing nor did we include these values in the averages. FC-206C Lot 502 3M Pace Serco Capsule Galbraith wS & Seed Galbraith Knoxville 290,000 290,000 350,000 240,000 260,000 416,500 370,000 260,000 320,000 411,000 395,500 374,000 ------* 5-------- - 380,000 360,000 450,000 370,000 410,000 407,250 407,250 0.78 0.78 0.65 0.63 1.02 .97 4-:- A v e r a g e S. d . 355,000 73,000 338,000 57,00 396,000 33,000 .81 .16 0.78 0.82 0.70 0.78 1.01 .92 .83 .11 3M Pace Serco Capsule 240,000 250,000 210,000 240,000 FC-780B Lot 501 230,000 250,000 220,000 230,000 320,000 330,000 350,000 287,000 360,000 .74 .71 .73 .67 .71 .71 .77 .64 D.APC ve . ra r\ g e 235,000 17,000 232,000 13,000 329,000 28,000 .71 .03 .71 .05 002531 Form 10620-5-PWO cc: LAB REQUEST BOOK - 42-5W Ref: ENVIR. ASSESS. INQ. JL _ C i CJSU PRODUCT ECOLOGICAL ASSESSMENT REQUEST FOR LABORATORY WORK LAB REQUEST NO. 3 m *ctlonr200l REQUESTER LABORATORY A&fo u f a l m Name: A -A/- J& d ' i f ReauestDate: ?/ 2 7 / 7r? Protect No.: 9 9 7 OO llfiOff Code No.: Sample Date: Phone No. vi*37 9 Prob No. D<ite Needed: ASAP Date Received Sampl Analyst:____ lilA S t: 1 Date Complte Hours Spent: `7 m W YB h e ___________________ - / O JLfTF . P' /7 Description: iftOD.fOO Purpose of Tests: <<i TdY ft/ L l_________________ Please Call Requester If Delays Are Encountered. . PHYSICAL & CHEMICAL PROPERTIES Heat o f Combustion Cal/G (BTU/Lb.) Density Ash Other <m> ~ ' -( j______________________________________________ - WATER POLLUTION Q j\ _____________________________________ : C BOD, Ultimate^ ( TOC S! GC Oxygen Uptake Dehydrogenase A ctivity (TTC) Other 1 3 S *< *iO o o * At TAc u U ooo A TA - H{ :T t 1 / o 3 tOoo - BIOASSAY Specify Organism and Method: * It LCj~q A<fuaJ'i\ J ok f&lveyi !( LEACHATE FROM LEACHING TEST pH COD BOD5 BOD, Ultimate TOC GC Bioassay Other /Ji 0 - ' s. n re o t z >T1 & fJ i W l\W T O R I F LJLC OTHER Bioaccumulation Persistence Degradation Products Whit - Return to flw u w tir Canary - Environmental Engra. O ffice FII m 2FR J iC 1o o / Pink Environmental Engrg. Lab Goldanrod Return to Requester 002.5 i b