Document MJooOX6ZVoyNn9NzmkkXyLZaj

UNIROYAL CHEMICAL *'*** 'JfS'JII". -;;"!'1^! E Material Safety Data Sheet Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS Nn C267016 IDENTIFICATION -------- Trade Name: NAUGARD76 Date Issued: ^5/^5 Date Revised 11/16/87 CAS Number: 2082-79-3 R-2 Chemical Name: Octadecyl 3, 5,-di-tert-butyl 4-hydroxyhydrocinnamate Chemical Family: Hindered Phenolic SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 2082-79-3 ND ----------------------------- OSHA (1910.1200) EEC* Not hazardous Not hazardous Hazard assessment based on available data. Transportation: PHYSICAL DATA Appearance and Odor: White crystalline flake, granular or powder; odorless Solubility: ^n0iu,ble in water Soluble in most organic solvents Melting Point:122-131eF (50-55C) Boiling PoinNt A Other Data: Specific Gravity (H20 = 1): 1-02 Vapor Pressure @ 20C.ND Vapor Density (Air = 1):ND Volatility @ 70 F;Low FIRE AND EXPLOSION HAZARD DATA -------- Flash Point:^ Autoignition Temp:ND Extinguishing Media: sPraV' dry chemical Flammable Limits;ND Special Fire Fighting Procedures:Protect against inhalation of combustion products. Unusual Hazards:form explosive dust-air mixtures. REACTIVITY DATA ---------------------------------------------- StabilityStable at ambient temperatures and pressures. lncompatibility:Stron9 oxidizing agents. - ,. . . .u , .. Decomposition Products.xides of carbon under burning conditions. DO 086710 CONFTDENTTA! NA = Not Applicable ND = Not Determined 'European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this date provided, true and accurate to the best of Uniroyal s knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ---------------------- Engineering Controls: Sufficient ventilation to minimize dust exposure. Protect closed handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator. STORAGE, SPILLS AND DISPOSAL INFORMATION ------ Storage: Store away from sources of direct heat in a dry area. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal: In accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information: Environmental effects have not been determined. HEALTH RELATED DATA ------------------------------------------- Specific Hazard(s): Contact with skin may cause irritation. No chronic health effects have been identified, There are no known medical conditions that are aggravated by exposure to this material. Primary Route(s) of Entry: Powder - inhalation, skin absorption. First Aid Procedures: Ey contact: Flush with water for 15 minutes. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information: Oral toxicity: LD50 (rats) - > 10 g/kg Dermal toxicity: LD50 (rabbits) - > 2 g/kg Irritation: eye (rabbits) - negative skin (rabbits) - slight Sensitization: skin (guinea pigs) - negative. Carcinogenic per NTP_______ IARC________ OSHA_______ None NAUGARD 76 DO 086711. CONFIDENTIAL UNIROYAL CHEMICAL fi'L'lfrl Material Safety Data Sheet Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS No. IDENTIFICATION Trade Name:NAUGARD XL-1 Date Issued: 9/12/85 CAS N u m ber:70331 -94-1 Chemical Name:2,2'-oxalyldiamidobis[ethyl 3-(3,5-di-t-Chemical Family:Phenolic butyl-4-hydroxyphenyl) propionate] R-1 SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 70331-94-1 ND ---------------------------- OSHA (1910.1200) EEC* Not hazardous Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA Appearance and Odor: White powder, negligible odor Solubility: Insoluble in water, moderately Soluble in acetone & chloroform. Melting Point:347-356F (175-180C) Boiling Point: NA Other Data: NA Specific Gravity (H2O = 1):ND Vapor Pressure @ 20C.NA Vapor Density (Air = 1):NA Volatility @70 F: Low FIRE AND EXPLOSION HAZARD DATA ------------------- Flash Point:500F (260C) TOC Autoignition Temp:525F (273C) Fire point Extinguishing Media: Water spray, dry chemical Flammable Limits:ND Special Fire Fighting Procedures: Protect against inhalation of combustion products. Unusual Hazards: May form explosive dust-air mixtures. REACTIVITY DATA --------------------------------------------------- Stability: Stable at ambient temperatures and pressures. Incompatibility:Strong oxidizing agents, acids and bases. 086712 Decomposition Products: Oxides of carbon, nitrogen and sulfur under burning conditions. NA - Not Applicable ND = Not Determined 'European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this date provided, true and accurate to the best of Uniroyal s knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ----------------------- Engineering Controls: Sufficient ventilation to minimize dust exposure. Protect closed handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator. STORAGE, SPILLS AND DISPOSAL INFORMATION ------- Storage: store away from sources of direct heat in a dry area. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal: |n accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information: Environmental effects have not been determined. HEALTH RELATED DATA ----- Specific Hazard(s): Contact with eyes can cause irritation. Primary Route(s) of Entry: inhalation, skin absorption. First Aid Procedures: Eye contact: Flush with water for 15 minutes. Get medical attention. ` Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information: Oral toxicity: LD50 (rats) - > 10 g/kg Irritation: eye (rabbits) - slight skin (rabbits) - negative Sensitization: skin (guinea pigs) - negative Mutagenicity: Ames Salmonella - negative Subchronic: The feeding to rats and dogs of up to 2% did not produce significant adverse effects. DO 086713 CONFIDENTIAL UNIROYAL CHEM'iCAL COMPANY, INC. World Headquarters Middlebury, Connecticut 06749 Technical Service: j-WO-322-3243 Corner Service 1-800243-3024 Naugard445 a non-discoloring amino antioxidant UNIROYAL CHEMICAL NAUGARD* 445 Non-Discoloring Amine Antioxidant for Polymers and Lubricants NAUGARD 445 is a new amine antioxidant which is relatively non-discoloring. Both by itself and in combination with other stabilizers NAUGARD 445 protects hot melt adhesives, polyacetals, nylon 6, polypropylene, polyethylene, ethylene-propylene co polymers and tcrpolymers, ABS, synthetic lubricants, polyether polyols and other oxidation susceptible products from degradation caused by high temperatures, oxygen and shearing action during fabrication of products. Initial test results also suggest NAUGARD 445 as a stabilizer for polyesters, polyacrylates, industrial lubricants and monomers such as the methacrylates. Because of its unusual structure NAUGARD 445 shows a reduced tendency to discolor during heat aging. The combination of high amine-antioxidant activity and good color makes NAUGARD 445 an ideal antioxidant and heat stabilizer for many materials. HOT MELT ADHESIVES NAUGARD 445 is an excellent antioxidant for poly amide hot melt adhesive formulations. It inhibits skin formation at elevated temperatures and prevents breakdown of the polymer. The data below compares NAUGARD 445 with another antioxidant used for this purpose. STABILITY OF POLYAMIDE RESIN Formulation Hours to Skinning @ 400 F. (204 C.) Polyamide resin (unstabilized)..................... Polyamide + 1.0% NAUGARD445 ............. Polyamide + 1.0% Antioxidant A(U............. 0-1 4-5 1.5-2.5 POLYACETAL RESINS NAUGARD 445 is an excellent heat stabilizer for polyacetals. Discoloration and decomposition, as evidenced by weight loss due to "unzipping" of polymer to volatile components, is inhibited by the use of small amounts of NAUGARD 445. The following table illustrates the advantages of NAUGARD 445 over commercial phenolic antioxidants in preventing discoloration and decomposition. THERMAL STABILITY OF POLYACETAL Test: Five grams of powdered resin placed in open aluminum cup and exposed in 446 F. (230C.) oven for 45 minutes. Ave. Total Wt. % Wt. Loss Color Formulation Loss, % per min. After Exposure Polyacetal resin (unstabilized)....................... Polyacetal + 0.2% NAUGARD445 ................ Polyacetal+ 0.5% NAUGARD 445 ............... Polyaceta! + 0.5% Antioxidant B'2*............... Polyacetal + 0.5% Antioxidant C(3)............... Stabilized commercial resin........................... 31.9 .709 buff-yellow (crumbled) 0.70 .015 white 0.81 .018 off-white 1.97 .044 buff 2,10 .047 buff 1.72 .039 light buff (l)2,4-bis(octylthio)-6-(3,5-di-tert-butyl-4-hydroxyphenylamino)-l,3,5-triazine <2)4,4'-butylidenebis(3-methyl-6-tert-butylphenol) <3)2,2'-methylenebis(4-methyl-6-tert-butylphenol) DO 086715 CONFIDENTIAL -3- NYLON 6 NAUGARD445 reduces discoloration and prevents loss in physical properties of Nylon 6 upon thermal aging. NAUGARD 445 docs not interfere with polymerization and may be added before, during or after polymerization. Thermal Stability of Nylon 6 Formulations: A -- unstabilized B -- unstabilized + 0.5% NAUGARD 445 C -- unstabilized + 0.5% Aminox<41 Formulation: Aged @ 250 F. (121 C.), 11 days.... Aged @ 320 F. (160 C.), 48 hrs......... Aged @ 320 F. (160 C.), 72 hrs......... Tensile Strength ABC 44 94 92 42 99 97 23 69 65 Percent Retained Tensile Impact ABC 1.5 79 76 -- -- -- -- -- -- A Tan Lt. Bra. Brown Color B Buff Buff Tan C Brown Brown Dk. Bra. POLYPROPYLENE NAUGARD 445 is an efficient heat stabilizer for polypropylene when used in combination with thiodipropionate esters. NAUGARD 445-NAUGARD DLTDP (dilauryl thiodipropionate) combinations are synergistic and comparable in performance to several commercial phenolic-thiodipropionate formulations. Thermal Stability of Polypropylene Formulation Blank ...................................................... ............ 0.4% NAUGARD DLTDP................... ............ 0.3% NAUGARD DLTDP + 0.2% NAUGARD445................... ............ 0.2% NAUGARD DLTDP + 0.1% NAUGARD445................... ............ 0.4% NAUGARD DLTDP + 0.1% NAUGARD445................... 0.4% NAUGARD DLTDP + 0.2% NAUGARD445................... ............ 0.4% NAUGARD DLTDP + 0.3% NAUGARD445................... 0.4% NAUGARD DLTDP + 0.1% Antioxidant B<2)................... ............ 0.4% NAUGARD DLTDP + 0.1% Antioxidant D*^'................... ............ 0.4% NAUGARD DLTDP + 0.1% Antioxidant E(6)................... ............ Initial Color White White White White White White White White Days to Break* 300 F. (148 C.) 320 F. (160 C.) 11 13 6 42 33 41 30 41 -- 61 -- 42 -- 47 -- 45 33 Color @ Break off-white It. buff white white off-white off-white off-white off-white off-white off-white (,)Two out of three 90 mil disks craze or crumble (4>UNIROYAL (5,Stearyl ester of beta-(4-hydroxy-3,5-di-t-butyIphenyl) propionic acid *6lTris(3-methyl-6-t-butylphenol) butane 0 0867.7 a CHFlorNTjAl -4- POLYETHYLENE NAUGARD 445 inhibits resinification of polyethylene cross-linking and embrittlement of polyethylene as exposed to air at high temperatures. Also, weather-o- measured by change in brittle point after 300 and 500 meter studies indicate that NAUGARD 445 prevents hours exposure in the weather-o-mcter. Blank........................................ 0.1% NAUGARD 445................ STABILITY OF LDPE BRITTLE POINT, F. (C.) Initial -45 (-43) -60 (-51) Weather-o-Meter Exposure 300 hrs. 500 hrs. -30 (-34.5) -60 (51) -30 -65 Min. to Resinilication @ 375 F. (190-5 C.) 120 300 ACRYLONITRILE-STYRENE-BUTADIENE RESINS (ABS) t NAUGARD 445 is an excellent heat stabilizer for ABS NAUGARD 445-thiodipropionate combinations arc resins when used in combination with thiodipropionate most effective with dark colored resins such as those used esters. These combinations are synergistic and prevent for pipe compounds because some discoloration may be heat induced oxidation of the resin. encountered in light colored resins exposed to ultraviolet radiation. ! tr Formulation Thermal Stability of ABS Resins Oxidative Life<8)@ 400 F. (204.5 C.), Minutes ABS(7>+commercial phenolic system.................................... ABS + 0.5%NAUGARD445 + 0.5%NAUGARD DLTDP .. ABS + 0.7%NAUGARD445 + 0.7%NAUGARDDLTDP .. 75 135 190 Oxidative Life vs. Temperature Temp., F. (C.) f7)Resin containing approximately 20% rubber. DO 086717 <8)Oxidative life is measured as the time that a sharp increase in the optical density at 5.85 (cai CONFTDFNTT AL ed. -5- 4. ETHYLENE-PROPYLENE-DIENE TERPOLYMER<'> NAUGARD 445 inhibits degenerate cross-linking and gelation of ethylene-propylene copolymers, terpolymers of ethylene, propylene and dienes, and other similar olefin heteropolymers exposed to heat and mechanical shearing in the presence of air. The amount of NAUC ARD 445 required for polymers containing unsaturat ed carbon groups is generally higher than that required for the essentially saturated homopolymers and co polymers. Results below illustrate the effectiveness of NAUGARD 445 as a processing stabilizer and anti-gel additive for an ethylene-propylene-diene terpolymer. Formulation Thermal Stability of Ethylene-Propylene-Diene Terpolymer Mooney Viscosity vs. Time on 148s C. Mill 0" 15" 30" 45" 60" Blank ........................................ 0.19c NAUGARD445............... 57 74 90 97 52 51 51 50 50.5 Hrs. to Initial Gelation Oven Exposure @ 300 F. (148 C.) 24 Hours 72 Hours SYNTHETIC LUBRICANTS NAUGARD 445 retards oxidation, viscosity increase, acid number increase and metal corrosion in synthetic lubricants used for high temperature applications. The effectiveness of NAUGARD 445 in di-(2-ethylhexyl) sebacate is illustrated below. Formulation Unstabilized Di{2-ethylhexyl) sebacate 2% Phenyl-alpha-naphthylamine........ 29r NAUGARD445 ............................. Test: Fluid samples containing copper and iron catalyst were placed in glass cells and exposed to 400 F. (204.5 C.) temperature for 72 hours with 12.5 liters of air per hour blown through the samples continuously. S.U.S. Viscosity Increase @ 210 F. (99 C.), % 32 8 5 Acid No. Increase 29 18 16 Sludge Formation Trace Moderate Moderate POLYETHER POLYOLS NAUGARD 445 both alone and in combination with phenolic compounds will effectively stabilize polyether polyols at concentrations of 500-1000 ppm. Increasing the stability of the polyol helps to reduce discoloration and scorch in flexible polyurethane foams during preparation. The table below shows the results obtained using NAUGARD 445 by itselfand in combination with NAUGARD BHT. DSCs in an oxygen atmosphere, a technique developed by Olin Corporation, was used to determine the effect of the stabilizers. The higher the Transition Temperature, the temperature at which oxidative decomposition begins, the more stable the polyol formulation. Polyol - 3000 MW. propoxylated glycerine-based triol, DS C. Perkin-Elmer Model IB DO 086718 CONFTDENTTA1 Stabilizer Concentration (ppm) Blank............................................................................................... NAUGARD BHT........................................................................... NAUGARD445 ............................................................................. BHT 445 ....................................................................................... -- 1000 500 1000/500 Transition Temperature, C. 155 162 176 187 ,9,Terpolymer of ethylene, propylene and a small amount of non-conjugated diene. -6- TYPICAL PROPERTIES OF NAUGARD 445 Chemical Composition: Substituted diphenylamine Color and Appearance: White to off-white powder Melt Range: Solubility, RT 205-210F. (96-99C.) gms / 100ml solvent Hexane 0.68 Heptane 0.74 Cyclohexane 3.5 Benzene 35.2 Toluene 32.8 Acetone 40.8 Methyl ethyl ketone 41.2 Methanol 0.66 Storage Stability: Excellent, store in a cool dry place. HANDLING PRECAUTIONS Normal handling precautions should be exercised. Avoid ingestion, eye contact, prolonged contact with skin and prolonged inhalation of dust. TOXICOLOGY NAUGARD 445 has an oral LD50 for rats greater than 10 gm/ kg. body weight. It is not a primary skin irritant as these terms are defined in the Regulations of the Federal Hazardous Substances Labeling Act (Federal Register Aug. 12, 1961). These conclusions are based on studies performed on laboratory animals. NAUGARD 445 is FDA approved for use in adhesives under 121.2520 of the Food Additives Regulations. The recommendations for the use of our products are based on tests believed to be reliable. However, we do not guarantee the results to be obtained b> others underdifferent conditions Nothing tn this brochure is intended asa recommendation to use our products so as to infringe on an) patent. -7- DO 08671.9 CONFIDENTIAL UNIROYAL CHEMICAL wmm Material Safety Data Sheet Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS Mn C266001 IDENTIFICATION --------- Trade Name: NAUGARD 445 Date Issued:. 8/5/85 Date Revised 8/25/87 CAS Number: 10081-67-1 R-1 Chemical Name: 4,4' Di(o,cr- dimethylbenzyl) diphenylamine Chemical Family: Aromatic Amine SPECIAL REGULATORY HAZARDS Ingredient CAS No, Exposure Limit Product 10081-67-1 ND ---------------------------- OSHA (1910.1200) EEC* Not hazardous Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA Appearance and Odor: White to off-white powder; characteristic odor Solubility: Insoluble in water Soluble in most organic compounds Melting Point: 203F (95C) Boiling Point: NA Other Data: NA Specific Gravity (H2O = 1): 1-14 Vapor Pressure @ 20 C. ND Vapor Density (Air = 1): ND Volatility @70 F: Low FIRE AND EXPLOSION HAZARD DATA -------------------- FlashPoint: 531F (276.7C) TCC Autoignition Temp: 569F (298C) Fire point Extinguishing Media: Water spray, dry chemical Flammable Limits: ND Special Fire Fighting Procedures: Protect against inhalation of combustion products. Unusual Hazards: MaY,orm explosive dust-air mixtures. REACTIVITY DATA Stability: Stable at ambient temperatures and pressures. Incompatibility: Strong oxidizing agents. DO 086720 CONFIDENTIAL Decomposition Products: Oxides of carbon and nitrogen under burning conditions. NA = Not Applicable ND = Not Determined 'European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this I date provided, true and accurate to the best of Uniroyal s knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ----------------------- Engineering Controls: Sufficient ventilation to minimize dust exposure. Protect closed handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator. STORAGE, SPILLS AND DISPOSAL INFORMATION -- Storage: Store away from sources of direct heat in a dry area. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal; In accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information: Environmental effects have not been determined. HEALTH RELATED DATA ------------------------------------------- Specific Hazard(s): No acute or chronic health hazards have been identified. There are no known medical conditions aggravated by exposure to this material. Primary Route(s) of Entry: Inhalation, skin absorption. First Aid Procedures: Eye contact: Flush with water for 15 minutes. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information; Oral toxicity: LD50 (rats) - > 10 g/kg Irritation: eye (rabbits) - negative skin (rabbits) - negative Mutagenicity: Ames Salmonella - negative No significant adverse effects have been noted with long-term production and use of this material. Carcinogenic per NTP_______ IARC________ OSHA NAUGARD 445 None X 0 086721 CNFTDFNTTA(.. UNIROYAL CHEMICAL Material Safety Data Sheet Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS No P.P7Qnm___ Date Issued: __aZ5ZSS IDENTIFICATION ---------------------------------- Trade Name: NAUGARD512 CAS Number: 26523-78-4 Chemical Name: Tris (mono-nonylphenyl) phosphite Chemical Family: Organophosphite SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 26523-78-4 ND OSHA (1910.1200) Not hazardous EEC* Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA Appearance and Odor: Clear viscous liquid; phenolic odor Solubility Insoluble in water Specific Gravity (H20 = 1): 0.978 @ 25/15.5C Miscible with most organic solvents Melting Point: NA Boiling Point: ND Other Data: Pour Point: 20 F; - Color (Gardner): 2 Vapor Pressure @ 20C. ND; @ 437F: 5mmHg Vapor Density (Air =1): ND Volatility @ 70 F: Low Viscosity @ 77 F - 5,200 cps @ 120F - 500 cps FIRE AND EXPLOSION HAZARD DATA -------------------- Flash Point: 430F (221C) TOC Autoignition Temp: 455F (235C) Fire point Extinguishing Media: Water spray, dry chemical Flammable Limits: ND Special Fire Fighting Procedures: Protect against inhalation of combustion products. Unusual Hazards: None identified. REACTIVITY DATA --------------- Stability; Stable at ambient temperatures and pressures. Incompatibility: Moisture and strong oxidizing agents. D 086722 confident tai Decomposition Products: Upon hydrolysis, phosphorous acid and phenols. Under burning conditions, oxides of carbon, phosphorous. NA = Not Applicable ND - Not Determined `European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this date provided, true and accurate to the best of Uniroyal s knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein.___________ SPECIAL PROTECTION INFORMATION ----------------------- Engineering Controls: Sufficient ventilation to minimize vapor exposure. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified respiratory protection for organic vapors. STORAGE, SPILLS AND DISPOSAL INFORMATION ------- Storage: store away from sources of direct heat in a dry area. Keep containers closed when not in use. Avoid any moisture contamination. Spills: Absorb on inert material. Shovel into secure containers for proper disposal. Use personal protective equipment as outlined above. Disposal |n accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information. Environmental effects have not been determined. HEALTH RELATED DATA ------- Specific Hazard(s) No health hazards have been identified. Primary Route(s) of Entry: Inhalation First Aid Procter..'--? Eye contact: Flush with water for 15 minutes. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information The following data are for a mixture of tris (mono and dinonylphenyl) phosphite. Oral toxicity: LD50 (rats) - 19.5 g/kg Irritation: eye (rabbits) - negative Sensitization: skin (guinea pigs) - negative Chronic: The feeding of up to 3300 ppm to dogs and rats for two years did not produce significant adverse health effects. DO 086723 CONFIDENTIAL