Document MJog90L2GmoLdb1x203Dx2gyV

Environmental Protection Department South Charleston Plant AUG 2 4 1976 PLAINTIFF'S EXHIBIT .August 23, 1976 To: Mr. J. H. Murray Building 307-2 cc: Mr. H. H. Frazier Mr. J. L. Worstell/Mr. W. C- Young SHARE Committee - 514 From: Mr. B, L. Murray Subject: Potential of Asbestos Exposure From Storeroom Materials Plant Stores, Building 307-1 & North Charleston Storage Building 8-505 South Charleston Plant Project No. 514-H-307-8-505-76_________________________________________ Jim, as you requested, we have made an initial determina tion of the potential of asbestos exposure at the two storeroom locations in the South Charleston Plant including North Charleston Storage, Building 8-505. In surveying these areas with Mr. Arlie Lynch and Mr. Ray Harris, the storage areas were found clean and orderly with minimal deposits of dust from asbestos material. However, as Mr. H. H. Frazier from the Institute Plant pointed out in his report (attached) of an asbestos dust exposure study, it is recommended to isolate the materials containing asbestos fibers. This could be accomplished by storing all materials in plastic containers including the asbestos cloth on rolls. In this way the employee dispensing the material would be freeing the bulk of the asbestos dust inside of the plastic container. According to Arlie the majority of the asbestos containing material is dispensed as stored and eliminate the untangling and preparation of small quantities of the material. Based upon these observations, compliance with the program of isolating the asbestos containing material, and the air sampling results from Mr. Frazier, we feel that the potential for exposures of the stores employees' to asbestos dust exceeding 2 fiber/cc greater than 5 fd in length will not be exceeded. An Environmental Health Data Sheet is attached for Asbestos. /Pi Attachment UCC 011655 UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS DIVISION ENVIRONMENTAL HEALTH DATA SHEET SOUTH CHARLESTON PLANT SECTION I HEALTH HAZARD NIOSH Manufacturer's Narne^ Chemical Asbestos (Chrysotile) Serpentine Chemical Family______________________________ Trade Name Formula 3MgO. ZSi 0? -2H;>0 Magnesium Silicate Good heat resistance High tensile strength and SECTION II - Physical Properties flexibility Boiling Point (<'F) Specific Gravity Z . 5 Vapor Pressure (mmltg)_ Vapor Density (Air=l)_ %Volatile by volume Solubility in water_________ Odor-Characteristic (TO) Decomposition Products__ Flash Point (F)NA Molecular Weight_ **5f/ml>5^u long TLV(PPM) Melting Point ("C) ower Explosive Limit (LEL)A^citNionpLpe-r- Explosive Limit (UEL)_ Evaporation Rate (Butyl Acetate = 1) Color - White SECTION III - Health Hazard Data Ingestion - LDjq - If accidentally swallowed, report to the Medical Department. Skin Penetration Wear protective clothing. If contacted, wash affected skin areas with watei. Vacuum protective clothing befoie removal. Skin Irritation Breathing Eyes - Wear protective clothing. If contacted, wash affected skin areas with water. Maintain and laundry protective clothing. Store, transpoit and dispose of clothing in sealed non-reusable containers marked "Asbestos - Contaminated Clothing". Prolonged inhalation of the asbestos particle may cause delayed lung injury. Wear respiratory protection and use. with adequate ventilation. If exposed, wash eyes with water. Report to the Medical Department. Spills - Clean up - wet the material before handling where possible. If loose material must be cleaned up dry, use vacuum cleaning or sweeping compount to keep . dust under control. Waste Disposal - Collect in plastic bags - Landfill. -Air Sampling and Analysis -- Collect on membrane filter and analyze by phase contrast illumination. ** - 8 hour time-weighted average 2 f/ml>5/u effective July 1, 1976 OSHA is proposing 0.5 f/ml 5 fi - ceiling limit 5 0 m>b u. * 0,5. DCM(!rr of H four 14, fpwoi.co, nr/**-*-* UCC 011656 ---------------- . IEMICALS Ann rt A" ncs (N*m) Mr. P. H. Day Pf to Mr. J. E. McDermott, Jr. Dr. R. J. Sexton Mr. F. Williams July '), I''/(> ER - Industrial Hygiene hmpjcivec Exposure to Asbestos -- Plant S to res l'.u i I <1 i hr, l HI In response to question:; by Plant Stores Employees, yon have asked for nshostos exposure levels to be determined at certain locations within Building 3J0. Evaluation of Storage conditions and dispensing methods 1ms been made together with appropriate area and personal sample collection. The conditions of .sang*ting and results arc reported as follows: SAMPLE DATE TYPE SAMPLE SPECIFIC LOCATION AND/OK CONDITIONS ASBESTOS FIBERS/ML AIR COUNT TLV 6-7-76 6-16-76 6-16-76 6-16-76 6-16-76 6-16-76 6-16-76 Area Asbestos rope storage and dispensing. Personal* employee untangled and prepared ID// of 3/6" Asbestos Rope for dispensing. Personal* ,, Employee replaced rope in bin and swept aisle of fallen libers - five mi miles Area T above, rope storage Bin - during, two five-minute Rampling, periods . -------- -------- ------------........... .. . Personal* A)\\rlnj' fivo-mfnuio !;;tmp 1 i oj* p'rio<l, / Kmp l (tyro S 1 mu 1 a t *<1 filling j'.auki't / otaW-JS from How A $, ,uul M Uius. Area \tt~~feet TT77m'-r?oW'/i3 gasket bins darifij' pcruooa i avim(* 1 i nj', ;ihnv('. Area O'* al>ov(* floor (liiriii)' aliovu aampl i * f-- inr hulri t liroc. 1 In otip.li aislu .md l wo flips on l,i ;iti:;[ioi i rr. 0.13 0. 76 0.0 0. 3r 1 .0 ) 0.0 0.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 *A11 personal, sample's were roller led on I lie person of and with l ho coupe ra I I nil of Mr. It 0._llanna. A IM resp i in l o r was _umn liyjlr. Hanna, at. our ronnost _______ The potential ffir excessive oiuployee exposure in asbestos fibers In appari'nt ul the different storage bln local Ions and especially al l lie asheslm: rope dispensing bin. Each time rope or gaskets are removed from l lie storage bin, .inhesion fibers are released and are plainly visible. liberated fibers are deposited and/or are accumu lated on the floor with the potential of becoming, airborne due to sweeping or generated air currents. Although the potential for excessive exposure appears to he serious, the results obtained during our sampling evaluation arc weLl within Lhe limits of the new ThV of two fibers greater than five micrometers per milliliter of air. One reasonable explana tion for the lower than expected values is that fibers being, liberated are large and of sufficient density that they do not easily become airborne. Asbestos must, nevertheless be controlled wherever possible. UCC 011658 f dc;i I 1 y , <>:: o< m 1 a i it i nli./t 1 t - r i .t i '; w< .1 I 1<1 !<i' '. I I I H ,f i til 11 I !' |l.|l I ( l' 1 Oollt , hav i ltg proper Von t i I a I i oil , a t I Iir.l I i m 1:; s;i, h . e , i' i .11d Mules. I liie.tsiii emeut s , however, 1 Jr; lint, tnilit.tif- i' sposui e ieyci.s <if .1 m.u;n I n*:e 'n jn'.l ify isolated storage a.S a requ i rernen t. Wo do o II or re e 1 itiimi'nd a I 1 mi:'. Ini your Iinr. idi'rnl imi, a:; I n H ows : l-'I H ST: Itoloeale t lio sl.or-u *.e a 10.1 of d/A'* a:.la si n:: rope In a morn remote area of I lie lit! I l (it ng where there is 11 older f i I I i n > a* I 1 v i I y . M <<v i de a p. 1 r I i a I I V i'IK1 li'Si'il spool typo <1 i sponsor to ;1 void work witli all on I nop, I m I mass nl malorial, wliii'ti appears to bo. cncoun t o rod each limo an order i s rilled. Another npl inn wonlil bo In have employees wear JM Respirators and prepare pi o-wo i /.Imd 01 lengths of rope in plastic bags for ready order filling. SKCONI): Consideration lie given to individual and/or nmni uiiuiPers ol mol a I rolnforoed gaskets being stored and dispensed in plant i< bag.;:. i i 1 i . practice would avoid possible exposure of employees oilier tliuii Stores personnel to ashes I os liberated from the gaskets through handling until final application. THIRD: Make 3M Respirators readily available to all Mores personnel for use during asbestos and other Job tasks where need for a rospit at or is apparent. Please inform Mr. Hoffman and Mr. Carey of (lie retail ts of the above listed samplings and should there bo further questions, please eaI 1 me. IlUF/kj s It. II. I l.iaiei. UCC 01 1659