Document MJ53j2nz4ma7qrqVNRZGwggJ9

AR.a<_ / 32> FOURTH QUARTER 2002 C-8 SURFACE WATER AND GROUNDWATER MONITORING REPORT FOR WASHINGTON WORKS FACILITY AND LOCAL, LETART AND DRY RUN LANDFILLS WASHINGTON, WV Date: December 2002 Project No.: D6WW7423.01 18983635.40000 18983627.00001 18983630.00001 18983636.00001 113? A CORPORATE REMEDIATION GROUP An Alliance between DuPont and (JRS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 CD v> CONTAIN N O c p i 000003 WVDEP 17200 Surface W ater and Groundwater Monitoring Report Table of Contents TABLE OF CONTENTS 1.0 Introduction..................................................................................................................1 2.0 C-8 Analytical Reporting............................................................................................. 3 3.0 Washington Works Facility.........................................................................................5 4.0 Local Landfill............................................................................................................... 7 5.0 Letart Landfill.............................................................................................................. 8 6.0 Dry Run Landfill........................................................................................................ 10 7.0 References.................................................................................................................. 11 Table 1.0 Table LIA Table 1.1B Table 2.0 Table 2.1A Table 2.IB Table 3.0 Table 3.1A Table 3.IB Table 4.0 Table 4.1A Table 4.1B TABLES Monitoring Well Construction and Groundwater Elevation Data Washington Works Facility C-8 in Surface Water - Washington Works Facility C-8 in Groundwater - Washington Works Facility Monitoring Well Construction and Groundwater Elevation Data - Local Landfill C-8 in Surface Water - Local Landfill C-8 in Groundwater - Local Landfill Monitoring Well Construction and Groundwater Elevation Data - Letart Landfill C-8 in Surface Water - Letart Landfill C-8 in Groundwater - Letart Landfill Monitoring Well Construction and Groundwater Elevation Data - Dry Run Landfill C-8 in Surface Water - Dry Run Landfill C-8 in Groundwater - Dry Run Landfill Figure 1.0 Figure 1.1 FIGURES Site Location Map - Washington Works Facility Monitoring Well and Surface Water Sample Location Map - Washington Works Facility 4th Q trG M R .do c Dec. 11, 02 Wilmington, DE 000004 I Surface W a ter and Groundwater Monitoring Report Table of Contents Figure 1.2 C-8 Concentration Map 4Q02 - Washington Works Facility Surface Water and Groundwater Figure 2.0 Site Location Map - Local Landfill Figure 2.1 Monitoring Well and Surface Water Sample Location Map - Local Landfill Figure 2.2A Groundwater Elevation Map 2Q02 - Local Landfill Figure 2.2B Groundwater Elevation Map 3Q02 - Local Landfill Figure 2.2C Groundwater Elevation Map 4Q02 - Local Landfill Figure 2.3 C-8 Concentration Map 4Q02 - Local Landfill Outfalls and Monitoring Wells Figure 3.0 Site Location Map - Letart Landfill Figure 3.1A Monitoring Well and Surface Water Sample Location Map - Letart Landfill Figure 3.IB Rt. 33 Stream and Blinker's Run Surface Water Sampling Locations Letart Landfill Figure 3.2A F-Zone Groundwater Elevation Map 2Q02 - Letart Landfill Figure 3.2B F-Zone Groundwater Elevation Map 3Q02 - Letart Landfill Figure 3.2C F-Zone Groundwater Elevation Map 4Q02 - Letart Landfill Figure 3.3A C-8 Concentration Map 4Q02 - Letart Landfill Outfalls and Monitoring Wells Figure 3.3B C-8 Concentration Map 4Q02 - Letart Landfill Zone F Figure 4.0 Site Location Map - Dry Run Figure 4.1 Monitoring Well and Surface Water Sample Location Map - Dry Run Landfill Figure 4.2A Groundwater Elevation Map 2Q02 - Dry Run Landfill Figure 4.2B Groundwater Elevation Map 3Q02 - Dry Run Landfill Figure 4.2C Groundwater Elevation Map 4Q02 - Dry Run Landfill Figure 4.3 C-8 Concentration Map 4Q02 - Dry Run Surface Water Figure 4.4 C-8 Concentration in Groundwater 4Q02 - Dry Run Bedrock Monitoring Wells APPENDICES Appendix A Laboratory Analytical Data Reports - Washington Works Facility Appendix B Chain-of-Custody Records - Washington Works Facility Appendix C Laboratory Analytical Data Reports - Local Landfill Appendix D Chain-of-Custody Records - Local Landfill 4th Qtr GMR.doc Dec. 1 1 ,0 2 Wilmington, DE ii 0 0 0 0 OS Surface W a ter and Groundwater Monitoring Report Table of Contents Appendix E Laboratory Analytical Data Reports - Letart Landfill Appendix F Chain-of-Custody Records - Letart Landfill Appendix G Laboratory Analytical Data Reports - Dry Run Landfill Appendix H Chain-of-Custody Records - Dry Run Landfill 4th Q trG M R .doc Dec. 11, 02 Wilmington, DE 000006 ili Surface W a ter and Groundwater Monitoring Report Introduction 1.0 INTRODUCTION A multi-media consent order (Order No. GWR-2001-019) was entered into between the West Virginia Department of Environmental Protection (WVDEP), the West Virginia Department of Health and Human Resources - Bureau for Public Health (WVDHHRBPH) and DuPont on November 15, 2001 (Consent Order). The Consent Order identified a series of requirements and tasks to be performed by the parties to determine whether there has been an impact on human health and the environment as a result of releases of ammonium perfluorooctanoate (C-8), CAS Number 3825-26-1, to the environment from DuPont operations at the Washington Works facility and the associated landfills (Local, Letart and Dry Run). The Consent Order established the C-8 Groundwater Investigation Steering Team (GIST) to oversee investigations and activities that will be conducted to assess the presence and extent of C-8 in drinking water, groundwater, and surface water at and around the Washington Works facility and the Local, Letart and Dry Run Landfills. An additional component of the Consent Order relates to the West Virginia National Pollutant Discharge Elimination System (WV NPDES) permit sampling requirements. In this portion o f the Consent Order, specific outfalls and outlets (outfalls) are to be sampled monthly for C-8 by DuPont. Pursuant to Attachment A of the Consent Order, three tasks will be performed by DuPont and evaluated by the GIST, Tasks A, B, and C. Task A: Groundwater Use and Well Survey/Groundwater Monitoring has been completed (DuPont, 2002a; 2002b). Task B: Assessment of Existing Groundwater and Surface Water Monitoring Data includes the compilation of historical C-8 data, monitoring all wells at the landfills and the development of a Groundwater Monitoring Plan (GMP) for the Washington Works facility. The first part of the task, the historical C-8 data compilation report has been submitted to the GIST for evaluation (DuPont, 2002c). The second part of this task, monitoring C-8 in groundwater at the landfills, began in December 2001 and was performed monthly for four months and quarterly thereafter. The third part of the task, the proposed GMP for the Washington Works facility, was submitted to the GIST (DuPont, 2002d) and groundwater sampling at the Washington Works facility began in January 2002. Groundwater sampling at the Washington Works facility was conducted monthly for four months and continues quarterly. Task C: Plume Identification/Groundwater Assessment is ongoing. This report presents the results of the monthly (October 2002) C-8 surface water and the 4th^Quarter 2002 (4Q02) C-8 groundwater sampling. The results for additional surface water sampling, that was performed in October 2002, are also included. This additional sampling is not required by the Consent Order or the WV NPDES permit. The 4Q02 C-8 groundwater-sampling event included sampling new wells installed as part of Task C: Plume Identification/Groundwater Assessment. Three new monitoring wells were installed at the Washington Works facility, five at the Local Landfill, five at the Letart Landfill, and seven at the Dry Run Landfill. These 20 new monitoring wells will be included in future quarterly C-8 sampling events as additional monitoring well sampling 4th Qtr GMR.doc Dec. 11, 02 Wilmington, DE 1 000007 Surface W a ter and Groundwater Monitoring Report Introduction points. Further, an additional surface water location at the Letart Landfill was sampled. This new location, called Brinker's Run, will also be included in future quarterly C-8 sampling events. 4th QtrGM R.doc Dec. 11, 02 Wilmington, DE 2 000008 Surface W ater and Groundwater Monitoring Report C-8 Analytical Reporting 2.0 C-8 ANALYTICAL REPORTING The analytical method, method detection limit, and laboratory utilized for C-8 analysis has changed over time. Prior to 1991, DuPont performed C-8 analysis at the DuPont Experimental Station in Wilmington, Delaware. In 1991, when the RCRA Verification Investigation was conducted, the analysis was contracted to the CE^MHill Laboratory in Montgomery, Alabama. Both labs used a Gas Chromatography/Electron Capture Detector (GC-ECD) based analytical method with detection limits for C-8 that ranged from 0.1 to 1.0 ug/1. CH2MHill conducted C-8 analysis for DuPont into the fall of 1998 when the laboratory ceased operation. At that time, DuPont had completed one round of analysis for the RCRA Facility Investigation (RFI). The analytical work was transferred to Lancaster Laboratories, Lancaster, PA, for the RFI second round analysis in March 1999. Lancaster Laboratories continued to conduct C-8 analysis using GC-ECD for DuPont until October 2001, when development and testing was completed on a new analytical method developed by Exygen Research, Inc. (Exygen; located in State College, PA) that utilizes Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS). DuPont adopted the regular use of LC/MS/MS for C-8 analysis in water in November 2001 and Exygen was contracted to perform the analyses for DuPont. Exygen reports C-8 results for the laboratory replicate of each field sample. These results are evaluated for precision by comparing the field sample result to the corresponding laboratory replicate result. If both results are less than the practical quantitation limit (PQL), the replicate sample for that analyte is considered to have passed the precision criteria. If one or both results are between one and five times the PQL, the replicate is considered to have met the precision criteria if the two results differ by less than the PQL. If one result is less than the PQL and the other is not, and if the two results differed by a value less than the PQL, the replicate is said to have met the acceptance criteria. If both results are at least five times the PQL, the replicate is considered to have met the criteria if the relative percent difference (RPD) between the two results is less than or equal to 20%. The RPD is the absolute value of the difference of two measurements divided by their average. When the precision criteria outlined above are met, Exygen reports the average of the field sample and lab replicate results reported by the laboratory. If criteria for precision are exceeded, Exygen reports the higher of the sample and lab replicate results. Finally, when one result (from the sample/lab replicate pair) is above the PQL and one below, the result that is above the PQLs is reported. C-8 results are recorded in the Corporate Environmental Database (CED) and are reported as FC-143 for consistency with historical results. 4th Qtr GMR.doc Dec. 11, 02 Wilmington, DE 3 000009 Surface W a ter and Groundwater Monitoring Report C-8 Analytical Reporting An aliquot of each field sample is also analyzed as a matrix spike (MS). Results of the MS analysis are used to assess accuracy. The MS recovery value must fall between 70 to 130%, unless the sample concentration is at least four times the amount spiked. The maximum amount used to spike field samples is 500 ug/L. All data packages generated by Exygen are reviewed in-house for compliance with the laboratory Standard Operating Procedures (SOP) and data usability, using the checklist provided in the QAPP. Results of the in-house review indicate that data reported by Exygen have been generated in compliance with the laboratory SOP, with few exceptions as noted in the individual review summaries. All data reported by Exygen have been judged usable for the purposes of the project. 4th Qtr GMR.doc Dec. 1 1 ,0 2 Wilmington, DE OOOOIO 4 Surface W a te r and Groundwater Monitoring Report Washington Works Facility 3.0 WASHINGTON WORKS FACILITY Figure 1.0 shows the location of the Washington Works facility. On October 18, 2002, six outfalls were sampled for C-8 (001, 002, 003, 005, 007, and 105). All of these outfalls collect process water and stormwater runoff. Sampling of these outfalls is required by the Consent Order and WV NPDES permit No. WV0001279. The locations of these outfalls are shown in Figure 1.1. Groundwater sampling was attempted at 12 monitoring wells on October 16, 2002, including the three new monitoring wells installed as part of the C-8 Plume Identification/Groundwater Assessment activities (AJ06-MW02, N04-MW03, and Y14MW02). Monitoring well N13-MW01 was not sampled during this sampling event because the well was dry. No other changes to routine sampling protocols or other observations were recorded in the field notes during this sampling event. In addition, groundwater from six production wells was sampled on October 22 or 25, 2002. Sampling of these wells was done according to routine sampling protocols. A combined groundwater sample representative of all the wells in the DuPont-Lubeck Well Field, labeled West Wellfield 1, was also collected, and analyzed for C-8. Sampling this well field was not identified in the Groundwater Monitoring Plan for the Washington Works facility nor was it recommended by the GIST for C-8 sampling. However, it was being sampled quarterly and analyzed for C-8 as required by the permit. Sampling of this well field on a monthly basis began in December 2001 and continued through April 2002, and is now sampled quarterly. The locations of the monitoring and production wells sampled are shown on Figure 1.1. This figure also shows the position of the DuPontLubeck Well Field that was sampled. Table 1.0 summarizes the well construction data and 4Q02 groundwater elevations measured for the monitoring wells. The surface elevations were incorrectly used to calculate the groundwater elevations for 2Q02 and 3Q02. In addition, for the C-8 plume delineation work, the spreadsheet of well construction information for all Local Landfill wells was updated. In this process, it was concluded that six of the measuring point elevations used in calculating groundwater elevations were incorrect. Therefore, all the groundwater elevations presented in Table 1.0 have been recalculated using corrected measuring point elevations. A row for measuring point elevation data was added, and the row for surface elevations was deleted in Table 1.0 for completeness of data presentation. A groundwater elevation map for 4Q02 was not generated because of the limited data set. The groundwater elevation map for February 2002, usually included in the monitoring reports, is not included in this 4Q02. This map is undergoing revision based on the corrected groundwater elevations, the geological information gained during the installation of the new wells, and on observation made during the groundwater modeling effort. The revised groundwater elevation map for February 2002 will be provided in the C-8 Plume Identification/Groundwater Assessment Activities report that will be submitted to the GIST in early January 2003. Tables 1.1A and 1.IB provide the C-8 analytical results for surface water and groundwater, respectively. For each sampling point listed in these tables, historical data 4th Q trG M R .do c Dec. 11, 02 Wilmington, DE 5 OOOOil Surface W a ter and Groundwater Monitoring Report Washington Works Facility are summarized with the most recent results listed first. Figure 1.2 presents the C-8 concentration map for the wells and outfalls sampled during the 4Q02 sampling event. Laboratory analytical data reports and the Chain-of-Custody records are included in Appendix A and B, respectively. (Note that C-8 results from Outfall 005 on October 16 and 17, 2002 are included on one of the laboratory analytical data reports and on one of the Chain-of-Custody records. However, these samples were collected for the Ohio River water investigation and, therefore, were documented in the Ohio River Water Sampling Results report (DuPont, 2002e). 4th Qtr GMR.doc Dec. 11, 02 Wilmington, DE 0000X2 e Surface W ater and Groundwater Monitoring Report Local Landfill 4.0 LOCAL LANDFILL Figure 2.0 shows the location of the Local Landfill. Sampling of five outfalls is required by the Consent Order and the WV NPDES permit No. WV0076538. These five outfalls collect stormwater runoff. On October 31, 2002, Outfall 101 was sampled for C-8. Outfalls 004(Old), 004(New), and 005(Old)/SSl, and 005(New) were not sampled due to no-flow conditions. The locations of these five outfalls are shown in Figure 2.1. Between October 8 and 15, 2002, nine monitoring wells, including the five new monitoring wells installed as part of the C-8 Plume Identification/Groundwater Assessment activities, were sampled following routine sampling protocols. Figure 2.1 shows the location of the monitoring wells sampled. Table 2.0 summarizes the well construction and groundwater elevation data for the monitoring wells. The surface elevations were incorrectly used to calculate the groundwater elevations for 2Q02 and 3Q02. Therefore, all the groundwater elevations presented in Table 2 have been recalculated using corrected measuring point elevations. A row for measuring point elevation data was added, and the row for surface elevations was deleted in Table 2.0 for completeness of data presentation. Groundwater elevation maps for 2Q02 and 3Q02 have been reconstructed using the corrected data and are presented in Figures 2.2A and 2.2B, respectively. Figure 2.2C presents the groundwater elevation map for 4Q02. The groundwater elevation data from the five new monitoring wells are not included in this figure because site conceptual model refinement based on these new wells is ongoing. Tables 2.1A and 2.IB present the C-8 analytical results for the 4Q02 surface water and groundwater samples, respectively. These tables include the historic data available for each location sampled. The data are presented with the most recent data first. Figure 2.3 provides the C-8 concentration map for the outfalls and monitoring wells for the 4Q02 sampling event. Laboratory analytical data reports and Chain-of-Custody records are provided in Appendices C and D, respectively. 4th Qtr GMR.doc Dec. 11, 02 Wilmington, DE 000013 7 Surface W a ter and Groundwater Monitoring Report Letart Landfill 5.0 LETART LANDFILL Figure 3.0 presents the Letart Landfill location map. Sampling of Outfalls 002 and 003 (both containing stormwater runoff) is required by the Consent Order and WV NPDES permit No. WV0076066. Sampling of the Cap Runoff and Rt. 33 stream surface water locations is not required by the Consent Order nor the WV NPDES permit. On October 31, 2002, sampling was conducted at Outfall 002, Cap Runoff, and the Rt. 33 stream. Sampling was attempted at Outfall 003 but no-flow conditions were observed. An additional surface water sampling location, Brinker's Run, was also sampled on October 14, 2002 as part of the 4Q02 event. The location of Outfall 002, Outfall 003, and the Cap Runoff samples are shown in Figure 3.1A. The locations of the Rt. 33 stream sample and the Brinker's Run are near the property boundary to the west and are shown in Figure 3.IB. Sampling was attempted at eighteen monitoring wells at Letart Landfill between October 10 and 17, 2002, including the five new monitoring wells installed for the C-8 Plume Identification/Groundwater Assessment activities. Figure 3.1A shows the locations of the monitoring wells. Changes to routine sampling protocols were recorded in the field notes and are summarized below. Monitoring well LMW-12 went dry during low-flow purging and could not be sampled. Monitoring well LMW-10 could not be sampled due to instrumentation problems. Pump problems were encountered in this monitoring well during the 3Q02 sampling event and the pump had been replaced prior to the 4Q02 sampling event. However, even with the new pump, it was not possible to collect a sample, indicating that the problem is not the pump. A thorough evaluation of the instrumentation will be conducted prior to the next sampling event to ensure that sample collection will be possible. Monitoring well LMW-3, LMW-3A, and LMW-5A went dry very rapidly and did not recharge well after a week. Due to the very limited volume of water in these wells, C-8 samples were collected immediately after starting to pump the wells. Only one round of parameters were measured before the wells went dry. Monitoring well construction and groundwater elevation data for the 18 monitoring wells are presented in Table 3.0. The surface elevations were incorrectly used to calculate the groundwater elevations for 2Q02 and 3Q02. In addition, for the C-8 plume delineation work, the spreadsheet of well construction information for all Letart Landfill wells was updated. In this process, it was concluded that the seven of the measuring point elevations used in calculating groundwater elevations were incorrect. Therefore, all the groundwater elevations presented in Table 3.0 have been recalculated using corrected measuring point elevations. A row for measuring point elevation data was added, and the row for surface elevations was deleted in Table 3.0 for completeness of data presentation. Groundwater elevation maps of the F-zone aquifer for 2Q02 and 3Q02 have been reconstructed using the corrected data and are presented in Figures 3.2A and 3.2B, respectively. Figure 3.2C presents the 4Q02 groundwater elevation map for the F-Zone aquifer. The groundwater elevation data from the new monitoring wells are not included in this figure because site conceptual model refinement based on these new wells is ongoing. 4th Qtr GM R.doc Dec. 11, 02 Wilmington. DE 8 000GJ.4 Surface W a te r and Groundwater Monitoring Report Letart Landfill The C-8 results for the 4Q02 surface water and groundwater samples are presented in Tables 3.1A and 3.IB, respectively. For each sampling point listed in these tables, historical data is summarized with the most recent results listed first. Figure 3.3A presents a C-8 concentration map for monitoring wells and outfalls for the 4Q02 event. Figure 3.3B provides a C-8 concentration contour map for the F-zone, the underlying significant aquifer. Appendices E and F present the laboratory analytical data reports and the Chain-of-Custody records, respectively. 4th QtrGMR.doc Dec. 11, 02 Wilmington, DE 000013 9 Surface W a te r and Groundwater Monitoring Report Dry Run Landfill 6.0 DRY RUN LANDFILL Figure 4.0 shows the location of the Dry Run Landfill. On October 30, 2002, Outfall 001 was sampled. Outfalls 003 and 004 were not sampled due to no-flow conditions. (Outfall 002 is a required outfall sampling location as stated in WV NPDES permit No. WV0076244. However, it was a temporary relocation of Outfall 001 and no longer exists). Outfall 001 collects stormwater and leachate. Outfalls 003 and 004 collect stormwater only. In addition, there are five additional locations that are sampled quarterly for C-8 that are not required to be sampled by the Consent Order. These include Stream Samples #1 and #2, DR Leachate, Pond Underdrain, and Property Boundary. These five locations were sampled on October 30, 2002. The locations of the surface water sampling points are shown in Figure 4.1. The Property Boundary sample location is on the western property boundary and is not shown in this figure. Between October 7 and 15, 2002, 15 monitoring wells were sampled, including the seven monitoring wells newly installed for the C-8 Plume Identification/Groundwater Assessment activities. No changes from routine sampling protocols were identified in the field notes. The locations of the monitoring wells can be found in Figure 4.1. Table 4.0 summarizes the monitoring well construction and groundwater elevation data for the monitoring wells. The surface elevations were incorrectly used to calculate the groundwater elevations for 2Q02 and 3Q02. In addition, for the C-8 plume delineation work, the spreadsheet of well construction information for all Dry Run Landfill wells was updated. In this process, it was concluded that the all of the measuring point elevations used in calculating ground water elevations were incorrect. Therefore, all the groundwater elevations presented in Table 4 have been recalculated using corrected measuring point elevations. A row for measuring point elevation data was added, and the row for surface elevations was deleted in Table 4.0 for completeness of data presentation. Groundwater elevation maps of the site aquifer for 2Q02 and 3Q02 have been reconstructed using the corrected data and are presented in Figures 4.2A and 4.2B, respectively. Figure 4.2C presents the 4Q02 groundwater elevation map for the bedrock aquifer. The groundwater elevation data from the new monitoring wells are not included in this figure because site conceptual model refinement based on these new wells is ongoing. Tables 4.1A and 4. IB present the C-8 analytical results for the 4Q02 surface water samples and groundwater samples, respectively. The data in these tables include historical data available for each location sampled. Figure 4.3 and 4.4 presents the C-8 concentration map for surface water and groundwater for the 4Q02 event. Laboratory analytical data reports and Chain-of-Custody records are provided in Appendices G and H, respectively. 4th Qtr G M R.doc Dec. 1 1 ,0 2 Wilmington, DE 000016 10 Surface W a te r and Groundwater Monitoring Report References 7.0 REFERENCES DuPont. 2002a. One-Mile Radius Survey and C-8 Sampling Report and Ohio River Public Water Supply Sampling, DuPont Washington Works (December 2001February 2002) January 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002b. Two-Mile Radius Survey and C-8 Sampling, DuPont Washington Works Facility/Local Landfill, West Virginia (March-May 2002) August 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002c. Compilation o fHistorical C-8 Data, DuPont Washington Works Main Plant and Landfills January 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002d. Proposed Groundwater Monitoring Plan for Washington Works Facility Plant and Landfills January 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002e. Ohio River Water Sampling Results, Washington Works Facility and the Letart Landfill November 2002. DuPont Corporate Remediation Group and URS Diamond. 4th Qtr GM R.doc Dec. 11, 02 Wilmington, DE 11 OOO017 TABLES 00001S Table 1.0 Monitoring Well Construction and Groundwater Elevation Data DuPont Washington Works Facility Washington, WV Monitoring Wells New Well ID Old Well ID Measuring Point Elevation (ft) AE11-MW01 AJ06-MW02 AM07-PW01 AO08-PW01 AX13-PW01 D08-MW01 E13-MW01 TW-74 336 331 335 TW-M5 TW-76 628.94 635.55 634.26 632.91 630.69 600.67 625.47 K16-PW01 L4(354) 623.24 L04-PW01 GALLERY 589.75 Total Depth (ft) 72 128 96 95 90 74 Well Diameter (inches) 2 2 18 18 18 4 2 18 Slot Size (inches) 10 10 10 Screen Length (ft) Elevation of Screen Interval (ft) 10 567.51 557.51 15 507.55 522.55 20 20 13 555.00 535.00 558.70 538.70 556.00 543.00 Groundwater Elevation (feet) 10 559.50 549.50 NA January-02 567.02 ** 562.73 561.29 * February-02 566.02 * * * 562.69 561.12 * March-02 564.77 * * * 562.09 560.07 * April-02 565.93 * * * 562.51 560.59 * May-02 566.54 * * * 562.71 560.76 * August-02 567.61 * * * 564.55 562.23 * October-02 568.52 569.55 * * * 564.24 561.23 * * * * * * * * 'Groundwater elevations not measured. "W e ll was dry. 12/4/2002 1 Of 2 000019 Table I.O.xIs Table 1.0 Monitoring Well Construction and Groundwater Elevation Data DuPont Washington Works Facility Washington, WV New Well ID Old Well ID Measuring Point Elevation (ft) Total Depth (ft) Well Diameter (inches) Slot Size (inches) Monitoring Wells N04-MW03 N13-MW01 P04-MW02 P08-MW01 Q04-MW02 R04-MW02 V05-PW01 Y14-MW01 Y14-MW02 Ron's MW-5 TW-83 Ron's MW-4 Ron's MW-1 TW-85 RANNEY TW-90 595.44 88.5 2 10 625.87 70 2 592.39 28 2 10 629.29 71 2 598.76 71 2 594.92 28 2 10 632.00 92 NA 642.25 90 2 10 643.12 131.59 2 10 Screen Length (ft) Elevation of Screen Interval (ft) 15 520.44 505.44 5 560.00 555.00 10 572.60 562.60 5 10 10 567.00 557.00 566.00 556.00 575.20 565.20 Groundwater Elevation 1 542.00 541.00 10 549.93 539.93 15 520.12505.12 January-02 February-02 March-02 April-02 May-02 August-02 October-02 572.35 560.88 576.61 * 562.78 559.92 571.91 560.10 560.05 576.39 * 562.15 ** 571.56 * 559.45 575.64 * 559.24 ** 573.13 ** 560.40 576.97 * 561,34 ** 574.32 ** 559.77 577.10 it 561.67 ** 572.69 ** 563.77 575.28 * 563.05 567.82 ** 572.69 562.09 563.06 574.98 * 562.89 561.75 'Groundwater elevations not measured. "W e ll was dry. 12/4/2002 2 of 2 000020 Table L0.xls Table 1.1 A Summary of Analytical Results: C-8 in Surface Water DuPont Washington Works Facility Washington, WV Sample OUTLET 001 OUTFALL 002 OUTLET 003 Date 10/18/02 9/24/02 8/27/02 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 10/18/02 9/24/02 8/27/02 8/27/02 (dup) 7/23/02 6/25/02 6/25/02 (dup) 5/20/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 11/26/Or 10/25/01 9/19/01 7/11/01 6/14/01 5/31/01 4/11/01 3/21/01 2/14/01 10/18/02 9/24/02 8/27/02 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 3/19/02 (dup) 2/5/02 1/17/02 1/17/02 (dup) 12/20/01 .................. C-8 (ug/l) 10.5 2.15 2.94 8.63 17.9 22.4 19.7 21.4 9.43 10.9 3.720 3.49 2.14 2.56 2.51 2.29 3.86 3.81 4.13 2.45 5.85 4.66 4.23 1.980 4.84 2.8 0.118 0.558 0.594 0.436 1.5 8.54 1.74 0.870 0.317 0.268 0.291 0.175 0.503 2.76 2.91 2.81 1.33 0.956 3.99 0.713 j j 12/04/02 1 of2 Table 1.1A.doc 000021 Table 1.1A Summary of Analytical Results: C-8 in Surface Water DuPont Washington Works Facility Washington, WV Sample OUTFALL 005 OUTLET 007 OUTLET 105 Date 10/18/02 9/24/02 9/24/02 (dup) 8/27/02 7/23/02 6/25/02 5/20/02 5/17/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 12/20/01 (dup) 11/26/01 10/25/01 9/19/01 8/30/01 7/11/01 6/14/01 5/31/01 4/11/01 3/21/01 2/14/01 10/18/02 10/18/02 (dup) 9/24/02 8/27/02 7/23/02 7/23/02 (dup) 6/25/02 5/20/02 4/16/02 3/19/02 2/5/02 2/5/02(dup) 1/17/02 12/20/01 10/18/02 9/24/02 8/27/02 7/23/02 6/25/02 5/20/02 5/20/02 (dup) 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 I C-8 (ug/l) 12.1 4.64 5.02 12.4 19.2 17.9 98.6 65.7 3.8 9.26 141.0 137.0 31.40 35.20 915 65.7 2.86 2.16 120 7.4 1.43 4.31 199 153 0.251 0.209 NQ (<0.05) 0.207 0.597 0.544 0.284 0.490 0.567 0.483 0.320 0.339 0.871 1.99 54.6 3.69 6.73 34.7 3.86 6.27 5.16 15.9 13.2 14.6 7.53 9.78 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). 12/04/02 2 of 2 Table 1.1A.doc 000022 Table 1.1B Summary of Analytical Results: C-8 in Groundwater DuPont Washington Works Facility Washington, WV I Sample AE11-MW01 AJ06-MW02 AM07-PW01 j AO08-PW01 AX13-PW01 D8-MW01 Date 10/16/02 9/04/02 5/23/02 4/29/02 3/26/02 2/22/02 1/28/02 2/2/99 11/10/98 10/16/02 10/22/02 8/26/02 5/17/02 4/16/02 3/21/02 2/14/02 1/22/02 11/20/00 8/16/00 5/12/99 2/3/99 11/18/98 6/19/98 6/2/97 4/2/96 10/22/02 8/26/02 5/17/02 4/16/02 3/21/02 2/14/02 1/22/02 11/20/00 11/20/00 (dup) 8/15/00 5/12/99 6/19/98 6/2/97 4/2/96 10/22/02 8/26/02 5/17/02 4/16/02 3/21/02 2/14/02 10/16/02 9/04/02 5/23/02 4/29/02 3/26/02 2/22/02 1/28/02 C-8 (ug/l) 1.74 1.92 1.25 1.22 2.82 1.45 1.2 0.69 L 0.41 0.133 0.269 0.335 0.247 0.159 0.171 0.129 0.131 0.24 0.071 J 0.578 0.082 B 1.9 L 0.4 0.79 0.48 0.415 0.420 0.499 0.497 0.568 0.439 0.355 0.4 0.26 0.167 0.307 1 0.55 0.52 0.721 0.834 0.911 1.42 1.22 1.03 0.126 0.117 0.551 0.424 0.262 1.27 0.582 J I I 12/04/02 1 of 3 000023 Table 1.1 B.doc Table 1.1B Summary of Analytical Results: C-8 in Groundwater DuPont Washington Works Facility Washington, WV Sample E13-MW01 ' I K16-PW01 L04-PW01 I I j I I N04-MW01 N04-MW03 N13-MW01 P04-MW02 Date 10/16/02 9/04/02 5/23/02 4/29/02 3/28/02 2/22/02 1/28/02 5/12/99 2/2/99 11/11/98 10/22/02 8/26/02 5/17/02 4/16/02 3/21/02 2/14/02 1/22/02 11/20/00 2/9/99 11/18/98 10/25/02 8/13/02 5/21/02 4/18/02 3/21/02 2/7/02 1/15/02 7/11/01 4/11/01 11/20/00 2/7/99 11/18/98 11/18/98 (dup) 1/28/02 10/16/02 10/16/02 9/04/02 5/23/02 4/29/02 3/28/02 2/25/02 2/2/99 11/11/98 10/16/02 10/16/02 (dup) 9/04/02 5/23/02 4/29/02 3/26/02 2/25/02 1/28/02 1/25/01 2/6/99 11/12/98 C-8 (ug/l) 3.43 2.39 2.47 2.44 1.62 2.32 2.11 0.882 0.59 L 2 16.2 971 12.4 13.2 17.2 12.00 10.5 7.5 16.2 0.46 L 14.3 3.06 15.1 16.1 40.9 23.5 30.9 0.202 3.99 13.8 5.89 7.9 J 3.9 J 689 21.2 Dry-no sample Dry-no sample Dry-no sample Dry-no sample Dry-no sample 57.8 29.6L <0.1 46600 48300 34400 42400 36500 32300 26800 23600 12600 13600 8300 I | 12/04/02 2 of 3 000024 Table 1.1B.doc Table 1.1 B Summary of Analytical Results: C-8 in Groundwater DuPont Washington Works Facility Washington, WV Sample Date C-8 lug/l) P08-MW01 10/16/02 120 9/04/02 Dry-no sample 5/23/02 Dry-no sample 4/29/02 Dry-no sample 3/28/02 Pump problems-no sample 2/25/02 20.7 2/4/99 43.4 11/13/98 36 Q04-MW02 10/16/02 9/04/02 7720 32.2 5/23/02 1480 4/29/02 1210 3/26/02 i 2/25/02 2070 1590 1/28/02 1480 2/4/99 994 11/13/98 660 R04-MW02 10/16/02 84100 9/04/02 5/23/02 66500 68100 4/29/02 56300 3/26/02 54400 2/25/02 43600 1/28/02 1/25/01 47500 13800 2/6/99 9420 11/12/98 1300 V05-PW01 10/25/02 51.2 8/13/02 34.8 5/21/02 35.8 4/18/02 37.6 3/21/02 2/7/02 40.9 25.10 1/15/02 29.0 7/11/01 4/11/01 11.4 5.48 11/20/00 13.7 2/7/99 12.4 2/7/99 (dup) 3.95 11/18/98 0.66 L Y14-MW01 10/16/02 9/04/02 18.2 18.4 5/23/02 4/29/02 15.3 13.9 3/28/02 15.5 2/22/02 10.9 1/28/02 12.7 2/2/99 4.95 L 11/10/98 12 Y14-MW02 10/16/02 NQ (< 0.05) West Well Field (1) 10/25/02 10.3 8/13/02 6.41 5/21/02 7.09 4/16/02 6.69 3/21/02 2/7/02 7.72 5.77 1/15/02 6.52 7/11/01 2.31 4/11/01 1.58 J = estimated value (below laboratory quantification limit) L = possible low bias result (relative to QA/QC) B= compound detected in QC blank Note: Analytical method changed as of November 2001 (see Section 2.0 for details). n r ir tr io r - 5V / u v U a . 12/04/02 3 of 3 Table 1.1B.doc I t! ;i Ii Table 2.0 Monitoring Well Construction and Groundwater Elevation Data Local Landfill Washington, WV Parameters Measuring Point Elevation (feet) LLMW-4 847.55 Total Depth (feet) Well Diameter (inches) Slot Size (inches) 155 4 0.02 Screen Length (feet) Screen Interval (feet) 20 717.20697.20 December-01 January-02 February-02 March-02 May-02 August-02 October-02 692.55 715.39 715.28 715.31 714.93 715.52 715.53 LLMW-6 796.27 90 4 0.020 20 723.20 703.20 719.69 720.41 719.76 722.00 721.52 719.77 719.56 Monitoring Wells LLMW-9 LLMW-10 LLMW-11A LLMW-11B LLMW-12B LLMW-13B LLMW-14B 788.54 805.04 663.83 80 87 42 442 0.020 0.020 0.01 20 728.54 708.54 20 738.94 718.94 20 641.83621.83 Groundwater Elevation (feet) 727.78 728.06 728.01 728.12 728.48 728.24 728.10 720.67 720.51 720.73 720.90 721.84 722.97 723.01 640.42 665.12 116 2 0.01 20 569.12549.12 764.28 750.80 672.04 95.5 140.5 57 222 0.01 0.01 0.010 20 688.78 668.78 15 625.30 610.30 15 630.04 615.04 563.60 681.93 648.29 627.74 12/4/2002 1 Of 1 C00026 Table 2.0.xls Table 2.1A Summary of Analytical Results: C-8 in Surface Water Local Landfill Washington, WV I Sample I OUTFALL 004 (New) OUTFALL 004 (Old) OUTFALL 005 (New) OUTFALL 005 (Old)/SS1 Date 10/31/02 9/30/02 8/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 10/31/02 9/30/02 8/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 2/20/02 1/24/02 12/13/01 9/27/2000 12/10/1999 6/3/1999 6/2/1998 5/29/1997 4/2/1996 2/16/1994 10/31/02 9/30/02 8/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 10/31/02 9/30/02 8/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 2/20/02 1/11/02 12/13/01 9/27/2000 12/10/1999 6/3/1999 6/2/1998 5/29/1997 4/2/1996 2/16/1994 C-S(ugfl) No-flow conditions No-flow conditions No-flow conditions 11.2 9.29 No-flow conditions 14.5 14.6 No-flow conditions No-flow conditions No-flow conditions 11.6 10.0 No-flow conditions 15 1.54 10.9 11.4 No-flow conditions 4.73 7.1 3.06 12 13 13 11 No-flow conditions No-flow conditions No-flow conditions No-flow conditions No-flow conditions No-flow conditions 34.3 16.0 No-flow conditions No-flow conditions No-flow conditions 32.1 27.3 No-flow conditions 40.9 39.0 46.0 51.4 No-flow conditions 13.3 34 6.8 39 41 39 35 12/04/02 1 of 2 Table 2.1A.doc 000027 Table 2.1A Summary of Analytical Results: C-8 in Surface Water Local Landfill Washington, WV Sample OUTLET 101 Date 10/31/02 9/30/02 8/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/25/02 2/20/02 1/23/02 12/13/01 9/14/2000 6/3/1999 6/2/1998 C-8 (ug/I) 78.6 115.0 70.3 63.0 38.0 40.0 48.2 36.4 63.10 81.4 82.40 12 15 54 Note: Analytical method changed as o f November 2001 (see Section 2.0 for details). 12/04/02 2 of 2 Table 2.1A.doc 000028 Table 2.1B Summary of Analytical Results: C-8 in Groundwater Local Landfill Washington, WV J= estimated value (below laboratory quantitation limit) ND= Not Detected at or above the limit o f detection (LOD) NQ= Not Quantifiable. Detected at a concentration above the LOD and below the limit o f quantification (LOQ). Note: Analytical method changed as of November 2001 (see Section 2.0 for details). 12/04/02 1 of 1 Table2.1B.doc 000029 f si i Table 3.0 Monitoring Well Construction and Groundwater Elevation Data Letart Landfill Parameters Measuring Point Elevation (feet) Total Depth (feet) Well Diameter (inches) Slot Size (inches) LMW-1 768.93 33 2 LMW-7 --------------------------- -- ' ' ' ' Monitoring Weils LMW-8 LMW-3 LMW-3A LMW-4 LMW-5A LMW-2A 770.24 35 4 777.06 38.5 4 676.47 30 2 674.79 60.1 4 0.010 651.58 28 2 647.22 28 4 0.010 780.87 180.8 4 0.010 Screen Length (feet) Elevation of Screen Interval (feet) 5 738.53 733.53 December-01 January-02 February-02 March-02 May-02 August-02 October-02 752.62 752.82 752.65 752.10 750.27 751.98 751.02 10 745.24 735.24 749.73 752.25 751.87 751.56 751.16 751.49 751.75 955 748.06 739.06 650.10645.10 619.61 614.61 Groundwater Elevation (feet) 745.04 746.76 745.05 746.24 745.41 744.95 745.43 646.82 648.19 648.07 648.47 646.74 646.53 646.77 617.4 616.76 615.37 614.80 615.27 615.54 615.84 5 626.17621.17 628.08 642.79 639.99 643.30 643.08 636.02 632.47 10 627.23 621.23 619.22 618.76 618.10 617.61 617.50 617.36 617.23 30 628.53 598.53 NA 622.19 622.23 622.44 622.28 622.44 622.38 LMW-5B 646.22 72 4 0.01 20 594.39 574.39 596.31 596.64 596.34 596.86 596.66 596.25 596.86 12/4/2002 1 of 2 V00030 Table 3.0.xls Parameters Measuring Point Elevation (feet) Total Depth (feet) Well Diameter (inches) Slot Size (inches) Table 3.0 Monitoring Well Construction and Groundwater Elevation Data Letart Landfill Letart, WV - Monitoring Weils LMW-6 LMW-9 LMW-10 LMW-11 LMW-12 LMW-13A LMW-13B LMW-14A LMW-14B 755.99 183 4 0.010 777.85 225 4 0.010 734.37 189.85 4 0.010 776.21 161.5 4 0.010 742.62 105 4 0.01 766.25 150 4 0.01 765.86 190 4 0.01 742.62 156 4 0.01 767.10 200 4 0.01 Screen Length (feet) Elevation of Screen Interval (feet) 30 606.22 576.22 December-01 January-02 February-02 March-02 May-02 August-02 October-02 NA 582.26 581.97 581.82 581.97 582.34 582.05 20 20 572.85552.85 562.52 542.52 NA 552.12 551.96 551.79 551.24 552.51 551.73 NA 543.37 543.36 543.39 543.39 543.26 543.35 25 20 20 637.84 612.84 637.62 617.62 616.25596.25 Groundwater Elevation (feet) NA 619.58 620.70 620.99 621.28 621.52 621.10 635.47 621.07 20 575.86 555.86 582.86 20 586.62 566.62 602.75 20 567.70 547.10 569.31 ! 12/4/2002 2 of 2 o o a i Table 3.0.xls Table 3.1A Summary of Analytical Results: C-8 in Surface Water Letart Landfill Letart, WV Sample 002(LEACHATE BASIN) 003 STORMWATER RUNOFF RT 33 STREAM BRINKER RUN CAP RUNOFF Date 10/31/02 9/27/02 8/30/02 7/30/02 6/28/02 5/30/02 4/30/02 3/28/02 2/19/02 1/25/02 12/14/01 11/27/2001 7/20/01 7/25/2000 4/3/2000 1/14/2000 10/21/1999 10/31/02 9/27/02 8/30/02 7/30/02 6/28/02 5/30/02 4/30/02 3/28/02 2/19/02 1/25/02 12/14/01 9/27/02 10/31/02 9/27/02 8/30/02 5/30/02 4/30/02 3/28/02 2/19/02 1/25/02 7/20/2001 7/31/2000 7/20/1999 7/23/1997 4/17/1996 10/14/02 10/31/02 8/30/02 6/28/02 5/30/02 4/30/02 3/28/02 2/19/02 1/25/02 I C-8 (UB/1) 645 4.52 2050 1410 Not Analyzed* 1630 443 131 355 50.1 36.1 53.2 159 1350 1900 920 3240 No-Flow Conditions 0.170 No-Flow Conditions No-Flow Conditions Not Analyzed* 0.282 0.0653 0.198 No-Flow Conditions 0.148 0.390 50.9 2.83 2.24 No-Flow Conditions 1.570 0.845 1.26 3.92 1.9 2.01 0.573 2.23 2 1.8 0.0612 102 No-Flow Conditions Not Analyzed* 371 279 Not Sampled No-Flow Conditions 119 i Note: Analytical method changed as o f November 2001 (see Section 2.0 for details). * Samples were taken at the respective surface water locations. However, due to an error by the courier, the samples arrived at the lab warm and were not analyzed. 12/04/02 1 of 1 Table 3.1A.doc 000032 Table 3.1 B Summary of Analytical Results: C-8 in Groundwater Letart Landfill, Letali, WV Sample LMW-2A ! LMW-5B F-Z one W ells Date 10/14/02 8/27/02 5/24/02 3/29/02 2/24/02 1/26/02 12/11/01 7/19/2001 1/30/2001 10/5/2000 7/25/2000 4/3/2000 1/14/2000 10/21/1999 7/20/1999 5/28/1998 7/23/1997 4/17/1996 9/20/1994 3/15/1994 11/22/1991 3/22/1991 10/11/02 10/11/02 (dup) 8/27/02 8/27/02 (dup) * 5/21/02 5/21/02 (dup) * 3/27/02 3/27/02 (dup) 2/23/02 2/23/02(dup) 1/26/02 1/26/02 (dup) 12/11/01 7/20/2001 7/20/01 (dup) 1/31/2001 10/5/2000 10/5/00 (dup) 7/25/2000 4/3/2000 4/3/00 (dup) 1/14/2000 10/21/1999 10/21/99 (dup) 7/20/1999 7/23/1997 9/20/1994 3/15/1994 11/22/1991 3/22/1991 C-8 (ug/1) 931 676 922 717 714 740.0 830 242 423 248 275 306 453 370 350 990 460 460 270 260 63 50 2230 2280 1480 1340 1720 1630 1810 1850 1460 1490 1780 1890 1880 483 592 615 1190. J 780 900. J 1100 1020 1030 1750 1700 445 480 530 1200 380 340 12/04/02 1 of 4 Table3.1B.doc 0000o Table 3.1 B Summary of Analytical Results: C-8 in Groundwater Letart Landfill, Letart, WV Sample LMW-6 LMW-9 LMW-10 LMW-11 LMW-12 LMW-13B LMW-14B Sample LMW-3A F -Z one W eils Date 10/14/02 8/27/02 5/24/02 3/29/02 2/24/02 1/26/02 12/11/01 1/13/2000 5/28/1998 11/22/1991 3/22/1991 10/17/02 8/29/02 5/24/02 3/27/02 2/23/02 1/26/02 12/10/01 10/7/1992 10/17/02 8/29/02 5/21/02 3/27/02 2/23/02 1/26/02 12/13/01 10/14/02 8/27/02 5/21/02 3/29/02 2/24/02 1/26/02 12/11/01 10/10/02 10/10/02 10/10/02 D /E -Z one W ells Date 10/11/02 8/26/02 5/24/02 3/27/02 2/23/02 1/26/02 12/11/01 7/19/1999 11/22/1991 3/22/1991 C-8 (ug/1) 15.1 10.5 20.7 14.8 14.9 18.1 15.8 9.4 30 24 25 0.907 0.479 0.715 0.631 0.617 0.875 0.845 0.2 Instrumentation problems-Not sampled Pump problems-Not sampled 0.298 0.136 0.126 0.133 0.134 0.121 0.058 0.069 0.119 0.112 0.159 0.128 Dry-no sample 0.0956 105 C-8 (ue/1) 204 Dry-no sample 134 132 101 98.6 100 60.3 350 380 12/04/02 2 of 4 Table 3.1B.doc 000034 Table 3.1 B Summary of Analytical Results: C-8 in Groundwater Letart Landfill, Letart, WV f I Sample I LMW-4 LMW-5A LMW-13A I LMW-14A Sample LMW-3 Sample LMW-1 D /E -Z one W ells Date 10/11/02 8/27/02 5/21/02 3/27/02 2/23/02 1/26/02 12/13/01 4/3/2000 1/14/2000 11/22/1991 3/28/1991 10/11/02 8/26/02 5/21/02 3/27/02 2/23/02 1/26/02 12/11/01 11/22/1991 3/22/1991 10/10/02 10/10/02 C -Z one W ells Date 10/11/02 8/26/02 5/24/02 3/27/02 2/24/02 1/29/02 12/13/01 11/22/1991 3/22/1991 A -Z one W ells Date 10/14/02 8/29/02 5/24/02 3/29/02 2/24/02 1/26/02 12/10/01 7/19/2001 1/31/2001 10/4/2000 7/24/2000 4/3/2000 1/13/2000 10/21/1999 7/20/1999 5/28/1998 7/23/1997 4/17/1996 11/22/1991 3/22/1991 C-8 (ug/1) 2840 1410 1690 2620 2250 3060 1580 272 172 830 690 112 Dry no sample 87.6 93.6 82.2 99.3 94.4 0.8 1.6 510 974 C-8 (ug/1) NQ (<0.05) Dry no sample 2270 1760 1920 1700 1520 1000 390 C-8 (ug/1) 25900 23000 30500 20600 18400 29400 24600 6100 9190 10600 8990 13600 17400 12600 6920 24000 5100 1700 68 60 12/04/02 3 of 4 Table 3.1B.doc 000035 Table 3.1 B Summary of Analytical Results: C-8 in Groundwater Letart Landfill, Letart, WV J = estimated value (below laboratory quantitation limit). Note: Analytical method changed as of November 2001 (see Section 2.0 for details). * Analytical duplicates' values were previously inadvertently omitted from the tables. 12/04/02 4 of 4 Table 3.1B.doc 000036 Table 4.0 Monitoring Well Construction and Groundwater Elevation Data Dry Run Landfill Lubeck, WV Param eters M easuring Point Elevation (feet) Total Depth (feet) W ell Diam eter (inches) S lo t Size (inches) Screen Length (feet) Screen Interval (feet) D e cem b er-01 January-02 February-02 M arch -02 M ay-02 A u g u s t-02 O cto b er-02 Monitoring W ells DRMW -6A DRM W -12 DRMW -12A DRM W -12B DRMW-13 DRMW -13A DRM W -14 744.46 12.2 2 0.01 737.81 738.29 738.26 738.75 738.25 735.25 736.92 733.1 35 4 0.01 15 710.50695.50 724.40 725.25 725.40 725.74 725.99 723.65 723.54 732.41 17 732.85 15 722.68 35 444 0.01 0.01 0.01 5 718.30713.30 10 725.50 715.50 15 700.60 685.60 Groundwater Elevation (feet) 727.30 728.50 727.99 728.89 728.97 725.51 725.91 728.11 729.14 728.70 729.58 729.67 726.24 726.64 711.81 712.17 711.46 712.21 712.54 710.65 711.65 722.57 11 4 0.01 5 714.30709.30 714.35 716.97 714.16 716.68 716.70 713.62 713.97 938.08 260 10 NA NA NA 754.09 757.99 754.87 755.45 755.12 755.31 755.13 DRMW -15 734.28 45 2 0.01 20 705.87 685.87 716.10 716.50 716.33 717.02 716.88 715.82 716.02 Param eters M easuring Point Elevation (feet) M onitoring W ells DRMW -16B DRM W -17B DRMW -18B DR M W -19BI DRM W -20B DRMW -21A DRM W -21B 789.97 850.27 924.15 880.27 867.07 705.55 705.60 Total Depth (feet) W ell Diam eter (inches) S lo t Size (inches) Screen Length (feet) Screen Interval (feet) 63 4 0.01 20 750.97 730.97 125 198 150 444 0.010 0.010 0.010 20 745.27 725.27 20 746.15726.15 20 750.27 730.27 G roundw ater Elevation (feet) 134 4 0.010 20 753.07 - 73.07 17 2 0.010 10 698.55 688.55 175 4 0.010 20 550.60 530.60 O cto b e r-0 2 730.48 733.90 755.75 749.22 751.23 700.93 610.94 12/4/2002 1 of 1 Table 4.0.xls 000037 Table 4.1A Summary of Analytical Results: C-8 in Surface Water Dry Run Landfill Lubeck, WV | Sample OUTLET 001 OUTLET 003 OUTLET 004 PROPERTY BOUNDARY Date 10/30/02 9/30/02 8/30/02 7/31/02 7/1/02 6/28/02 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 5/19/1998 4/9/1996 10/30/02 9/30/02 8/30/02 7/1/02 6/28/02 5/28/02 4/29/02 3/26/02 2/25/02 1/28/02 12/12/01 10/30/02 9/30/02 8/30/02 7/1/02 6/28/02 5/28/02 4/27/02 3/26/02 2/25/02 1/28/02 12/12/01 10/30/02 8/30/02 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 7/14/1998 4/9/1996 ..................... C-8 tug/ : 81.7 No-flow conditions No-flow conditions No-flow conditions No-flow conditions No-flow conditions 30.9 41 71.6 43.9 41.6 No-flow conditions 31.5 66 17 86 No-flow conditions No-flow conditions No-flow conditions 25.3 No-flow conditions No-flow conditions 20.1 6.77 No-flow conditions No-flow conditions No-flow conditions No-flow conditions No-flow conditions No-flow conditions 0.70 No-flow conditions No-flow conditions No-flow conditions 158 No-flow conditions No-flow conditions No-flow conditions 3.80 No-flow conditions 9.41 6.69 22.8 3.81 11.1 3.99 10.3 39 0.88 I 9.9 l 12/04/02 1 of 2 Table 4.1A.doc 000038 Table 4.1A Summary of Analytical Results: C-8 in Surface Water Dry Run Landfill Lubeck, WV I Sample Date c-8 (ue/i) STREAM SAMPLING POINT#1 10/30/02 8/30/02 5/28/02 4/24/02 3/25/02 2/25/02 1.63 No-flow conditions 1.63 0.932 1.06 0.850 1/28/02 0.893 12/12/01 1.19 10/3/2000 12/29/1999 0.758 0.54 5/19/1998 1 STREAM SAMPLING POINT#2 10/30/02 29.2 8/20/02 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 No-flow conditions 51.0 28.9 66.6 24.3 42.4 20.5 10/3/2000 27.6 12/29/1999 87 5/19/1998 4.6 DRLEACHATE 10/30/02 704 5/28/02 4/24/02 3/25/02 2/25/02 150 237 334 256 1/28/02 398 12/12/01 109 10/3/2000 12/29/1999 27.4 34 5/19/1998 7/22/1997 56 62 POND UNDERDRAIN 10/30/02 5/28/02 38.8 67.4 4/24/02 33.4 3/25/02 2/25/02 1/28/02 12/12/01 66.7 37.1 29.3 35.4 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). I 12/04/02 2 of 2 Table 4.1A.doc 000033 | 12/04/02 Sample DRMW-6A DRMW-12 DRMW-12A DRMW-12B DRMW-13 Table 4.1 B Summary of Analytical Results: C-8 in Groundwater Dry Run Landfill, Lubeck, WV Date 10/9/02 8/28/02 5/22/02 3/30/02 2/20/02 1/27/02 12/12/01 7/20/2000 7/21/1999 5/26/1998 7/22/1997 4/10/1996 10/9/02 8/28/02 5/22/02 3/30/02 2/20/02 1/25/02 12/12/01 7/19/2000 7/21/1999 5/26/1998 7/22/1997 4/10/1996 10/9/02 8/28/02 5/22/02 3/30/02 2/20/02 1/25/02 12/12/01 7/19/2000 7/21/1999 5/26/1998 7/22/1997 4/10/1996 10/9/02 10/9/02 (dup) 8/28/02 5/22/02 3/30/02 3/30/02 (dup) 2/20/02 1/25/02 1/25/02 (dup) 12/12/01 7/20/2000 7/21/1999 6/16/1998 10/9/02 8/28/02 8/28/02 (dup) * 5/22/02 3/30/02 2/20/02 1/25/02 12/12/01 7/20/2000 7/21/1999 5/26/1998 7/22/1997 C-8 (ug/l) 1.13 0.785 1.24 0.843 0.822 0.824 1.04 0.212 0.096 0.27 0.36 0.19 0.109 0.0626 0.0817 0.0929 0.11 0.116 0.086 0.16 0.134 <0.10 <0.1 <0.1 0.181 0.0880 0.0832 0.0785 0.125 0.168 0.158 0.128 0.081 J <0.10 <0.1 <0.1 0.258 0.242 NQ NQ NQ NQ NQ 0.073 0.085 0.215 ND (0.029) 5.4 <0.1 20.9 13.1 14.6 16.9 12.6 11.5 16.5 9.86 9.8 3.6 9.2 7 I I 1 of 2 Table 4.1B.doc 000040 Table 4.1B Summary of Analytical Results: C-8 in Groundwater Dry Run Landfill, Lubeck, WV Sample DRMW-13A DRMW-14 DRMW-15 DRMW-16B DRMW-17B DRMW-18B DRMW-19B DRMW-20B DRMW-21A DRMW-21B Date 10/9/02 8/28/02 5/22/02 3/30/02 2/20/02 1/25/02 12/12/01 7/20/2000 7/21/1999 5/26/1998 7/22/1997 4/10/1996 4/10/1996 (dup) 10/15/02 8/28/02 5/22/02 3/30/02 2/20/02 1/27/02 12/12/01 7/20/2000 7/21/1999 6/16/1998 7/21/1997 4/10/1996 10/15/02 8/28/02 5/22/02 5/22/02 (dup) * 3/30/02 2/20/02 1/27/02 12/12/01 7/20/2000 7/21/1999 10/8/02 10/8/02 10/7/02 10/7/02 10/8/02 10/9/02 10/9/02 C-8 (ug/1) 6.66 5.14 2.31 4.0 3.73 5.97 6.4 9.9 0.070 J 8.7 15 8.2 11 NQ (0 .0 5 ) NQ NQ NQ NQ NQ NQ 0.115 2.5 0 .1 0 .1 0 .1 4.92 3.99 5.0 4.66 4.91 3.65 4.35 4.94 0.763 0.263 NQ (0 .0 5 ) 0.155 ND (0 .0 1 ) NQ (0 .0 5 ) NQ (0 .0 5 ) 0.270 NQ (0 .0 5 ) ND = Not Detected at or above the limit of detection (LOD). The listed LOD is approximate and varies by instrument and over time. NQ = Not Quantifiable. Detected at a concentration above the LOD and below the limit of quantification (LOQ). J = estimated value (below laboratory quantitation limit). Note: Analytical method changed as o f November 2001 (see Section 2.0 for details). * Analytical duplicates' values were previously inadvertently omitted from the tables. j 12/04/02 2 Of 2 Table 4.1B.doc 000041 FIGURES 00004: LEGEND D08-MW01 J17-PW01 OUTLET 0 0 5 MONITORING WELL PRODUCTION WELL OUTFALL SAMPLING POINT OOOOH-H- LEGEND D08-MW01 J17-PW01 <* OUTLET 0 05 54.6 1 0 .3 MONITORING WELL PRODUCTION WELL OUTFALL SAMPLING POINT CONCENTRATION OF C - 8 (u q /L ) IN SURFACE WATER CONCENTRATION OF C - 8 (u g /L ) IN GROUNDWATER 000045 FJW'X- it). h-,J SCALE 700 700' DESIGNED SJO DRAWN INfTlALS DEL CHECKED t TDt -. APPROVED(DCStON) ASH APPROVHKCONaTWUCTION) <mm y Corporate Remediation Group An Alliance between DvPont and URS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 C--8 IN SURFACE WATER AND GROUNDWATER - 4Q02 D u P o nt W ashington W orks Facility W ashington, W est Virginia scali Aa show n re 6 /2 4 /0 2 m um . 74238006 noue 1 .2 10*38' poH800' DCSKM CD DRAW N DEL CHECKED TD L APPROVBXDBXM ) W nU LS WS A V * Xpfpprate Remediation A n Alliance between Group DuPont and URS Diamond A P R R 0 V E D (C O M S T R U C I1 O N ) Barley Mill Plaza, Building 27 __________ Wilmington, Delaware 19805 LOCAL LANDFILL MONITORING WELL AND SURFACE WATER SAMPLE LOCATION MAP Local Landfill W ashington, W est Virginia me Am hew n 0*51 0*0 m mo, 7421B 014 mm 2 .1 - 1 0 '38 LEGEND --------OVERBURDEN MONITORING WELL A --------BEDROCK MONITORING WELL ( 7 2 7 . 9 2 ) --------MONITOR WELL WATER LEVEL ELEVATION ------------ --------APPROXIMATE BEDROCK GROUND WATER FLOW DIRECTION 7 2 0 ----------------------GROUND WATER CONTOUR WITH ELEVATION 000048 400 SCA L o  O O ta 800' DESIGNED INITIALS DRAWN Da CHECKED TDL APPMM3D(DESIQN) x-' w p fto v n x c o N s m u c n o N ) Corporate Remediation Group An Alliance between - i 4 * DuPont and URS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 GROUNDWATER ELEVATION CONTOUR MAP - 2Q 02 Local Landfill W ashington, W est Virginia DOE 1 1 /2 7 /0 2 CUD HLE NO, 74219017 nouns 2.2A 10*38' '.j ! 1 3;i LEGEND 5 --------OVERBURDEN MONITORING WELL i Aj --------BEDROCK MONITORING WELL ( 7 2 7 . 9 2 ) --------MONITOR WELL WATER LEVEL ELEVATION --------APPROXIMATE BEDROCK GROUND WATER FLOW DIRECTION i 7 2 0 -- -------------- GROUND WATER CONTOUR WITH ELEVATION 000049 400 SCALE 04 LEGEND 4 --------OVERBURDEN MONITORING WELL A --------BEDROCK MONITORING WELL ( 7 2 7 . 9 2 ) --------MONITOR WELL WATER LEVEL ELEVATION ----------- -------- APPROXIMATE BEDROCK GROUND WATER FLOW DIRECTION 7 2 0 --------------------- GROUND WATER CONTOUR WITH ELEVATION 000050 400 SCAL 0 r n * i4 i 000053 LEGEND: LMW-8 A ZONE MONITOR WELL ^ LMW-3 LMW-4 ^.LM W -2A C ZONE MONITOR WELL D /E ZONE MONITOR WELL F ZONE MONITOR WELL SURFACE WATER SAMPLE LOCATION 4 Corporate Remedtatkxi Group An Alliance between DuPont and URS Diamond Borley Mill Plaza, Building 27 Wilmington, Delaware 19805 i MONITORING WELL AND SURFACE j WATER LOCATION SAMPLE MAP Letart Landifll Site Letart, West Virginia " J, ih<-(| I" " " h/^ h I""*. 74BM014 """i l * kP gjO Q Q C S ROAD Ri. 33 Stream LEGEND: ^ SURFACE WATER SAMPLE LOCATION SCALE 650 0 SOURCE: MAP TAKEN FROM THE USGS NEW HAVEN, WV 7 650* Corporate Remediation Group A n A llia n c e betw e en DuPont a n d UHS Diamond Barley Mill Pla20, Building 27 Wilmington, Delaware 19805 RT. 3 3 STREAM AND BRINKER'S RUN SURFACE WATER SAMPUNG LOCATIONS L e ta rt Landfill Site L etart, W est Virginia jcjtr As shown cure 11/25/02 OCStCNCD CKCKCO MWN OEL APWWCVtO TDL c a o n u wo. 7420A019 neuer 3 . IB ipyjooO O r 3SO O Q 0 r [ i; i: LEGEND; A-LMW-2A F ZONE MONITOR WELL ^ 541.39 GROUNDWATER ELEVATION MEASUREMENT GROUNDWATER CONTOUR UNE GENERAUZED GROUNDWATER FLOW DIRECTION < lt> A Corporate Rem edation Group An Alliance between DuPont and URS Diamond B o rle y Mill P laza. B u ild in g 27 W ilm ington, Delaware 19805 F ZONE GROUNDWATER ELEVATION CONTOUR MAP - 4Q02 Letart Landifll Site Letart, West Virginia MC As them K. DIMS 11/Z7/QI a n wsm OB. CMSM74C2M00i015 "" *3.2c b lsS O Q C X ) 000058 1 & 2S000Q 000059 !1 f( / 'VMt X'-, /r / - 7 -, - l.i r ii k?BSOCQ0 \ LMW-10 , NOT SAMPLER / / / / ./ r ._ y I Tf f \I t J; \ \ \ \ \ \ \\\ 1 \ ; \ \\ \ \ * \ ' \\\\ /' ... \ \ \ . \ \ j \\w \ ' ! /, ' i \\\ y //\ ^ / /\ \ 1/ / ,' ; ) ' / 200 LEGEND: -^-LMW-2A ^ F ZONE MONITOR WELL C -8 CONCENTRATION (ug/L) ESTIMATED LINE OF ISOCONCENTRATION (C -8 ) Corporate Rem erflatlon Group An Alliance between DuPont and URS Diamond Borley Mill Plozo. Building 27 W ilm ington, Oelowore 19805 Ml Ml Letart Landifll Site Letali, West Virginia am m mm PU M l OK M U M 74000012 " " S JB G0Q060 Source: MAP TAKEN FROM THE LUBECK. WV USGS QUADRANGLE 1200 0 1200' 2400' MMN0 K.0AVIS DRAWN DEL CHttXtD MTMS APHW rtW DH) AppMUKcoNsmucnoM) Corporate Rem ediation Group An iance b tlu ie e n DuPont and URS D iam ond Barley Mill Plaza, Building 27 ________ Wilmington, Delaware 19805 SITE LOCATION MAP Dry Run Landfill Lubeck, West Virginia nu Ae heen m 1 1/1 /0 1 W H T B S -------- m um 74221006 4.0 LEGEND: OVER BURDEN MONITOR WELL BEDROCK MONITOR WELL Q SURFACE WATER LOCATIONS 000061 SCALE LEGEND:__________ + OVER BURDEN MONITOR WELL A BEDROCK MONITOR WELL (7 3 8 .3 0 ) MONITOR WELL WATER LEVEL ELEVATION 750----------------GROUNDWATER CONTOUR WITH ELEVATION -------------- APPROXIMATE DIRECTION OF GROUNDWATER FLOW 000062 SCALE 250 0 O O O O i Q 250' 5E5KTO-------------------- TDL DRAWN DEL CHECKED K. DAVIS A P P R 0 V E D (D C 9 G N ) - A P P R O V E D (O O N S m u C T l0 N ) Corporate Rem ediation Group An AUAanoo between DuPont and URS Diamond Barley Mill Plaza, Building 27 Wllmlnaton. Delaware 19BO5 GROUNDWATER ELEVATION CONTOUR MAP - 2002 Dry Run Landfli Wood Couity, Wool VfrgHa MA 1* - 2 9 0 ' Nf B /24/02 Id F it m. I 7422B035 InouK 4 .2 A if LEGEND: + OVER BURDEN MONITOR WELL A BEDROCK MONITOR WELL (7 3 8 .3 0 ) MONITOR WELL WATER LEVEL ELEVATION 750 ----------------GROUNDWATER CONTOUR WITH ELEVATION -------------- APPROXIMATE DIRECTION OF GROUNDWATER FLOW 000063 SCAL 250 0 000063 a 250' SOSOS---------------- WlUli TDL DRAWN DEL CHECKED ! -b K. DAVIS APPROVEZKOCSIGN) c flB ) A Corporate R em edatlon Group An A U ia n e * between uPont and UBS Diamond A Pfm vED CcoN sniucnoN ) Barley Mill Plaza. Building 27 WTIminaton. Delaware 19805 GROUTOW ATER ELEVATION CONTOUR MAP - 3 0 0 2 Dry Run U n d fl Wood Couity, WMt VfrgHa BMC mi odmem. Inaunc 1* - 290* 1 2 /2 /0 2 74220036 4 .2 8 * LEGEND:__________ + OVER BURDEN MONITOR WELL A BEDROCK MONITOR WELL (7 3 8 .3 0 ) MONITOR WELL WATER LEVEL ELEVATION 750----------------GROUNDWATER CONTOUR WITH ELEVATION -- -------------- APPROXIMATE DIRECTION OF GROUNDWATER FLOW 000064 SCALE 250 0 OQOC&H'Cl 250' BBaSHT----------------- i i n r TOL DRAWN DEL CHECKED K. DAVIS APPR0VE2XDES0N) uvnmnUooNsmicnon) <JH S E > A Corporate Rem edkitkm Group An AUiane* between D uP ont and URS Diamond Barley Mill Plaza, Building 27 Wllmlnaton. Delaware 19805 GROUNDWATER ELEVATION CONTOUR MAP - 4 0 0 2 Dry Run LamMI Wood Couity, Wort V t * * i 1* - 2 5 0 ' 1 2 /2 /0 2 pu m Iroue 74229097 4.2C \ I i I ! >i 1J >f I I ) * 1 E 1.378.800 LEGEND SURFACE WATER SAMPLE LOCATION 20.5 CONCENTRATION C - 8 ( u g /l) JANUARY, 2 0 0 2 400 SCALE 0 snap A C o rp o ra te R e m e d ta tio n 4 n A llia n c e b e tw e e n D u P o n t a n d U R S D ia m o n d G roup Bortey Mill Plozo, Building 27 Wilmington. Odowore 19805 C - 8 IN S U R FA C E WATER FORTH QUARTER 2 0 0 2 Dry Run Landfill DuPont W ashington Works Lbeck, West Virginia toMX |N M * thorn 1 in w 1 0G. ic e n t m . 1 7422*01 " l W 0 i 1' `tol 1------- 1" 4 . 3 1i i I \ i i i -i i i APPENDICES 00006V APPENDIX A LABORATORY ANALYTICAL DATA REPORTS WASHINGTON WORKS FACILITY 000068 Proven Results. Analytical Results Washington Works C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) W W K -Z-O utfall-001 W W K-Z-Outfall-002 W W K-Z-Outfall-003 W W K-Z-Outfall-005 (10/18/02) W W K-Z-Outfall-007 W W K-Z-Outfall-105 W W K-Z-Outfall-007-2 W W K -K -E Q B LK -1 W W K-Z-Outfall-005 (10/16/02) W W K-Z-Outfall-005 (10/17/02) 10500 3490 870 12100 251 54600 209 ND 141000 18000 Limit of D etection (LOD) fo r the procedure is appoxim ately 10 ng/L Limit of Q uantitation (LO Q ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 007 000069 .3058 Research Drive kState College, PA 1 6 8 0 1 , USA T : 814.272.1039 kF: 814.231.1580 exygen.com .Precise Research. Proven Results. Analytical Results Washington Works C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) W WK-G-QO4-MW02 W W K -G -R O 4-M W 02 W W K -G -P O 4-M W 02 W W K-G-PO4-MW02-2 W W K-G-P08-M W 01 W W K -G -D O 8-M W 01 W W K -G -E 13-M W 01 W W K-G -Y14-M W 01 W W K -G -A E 11-MW01 W W K-K-EQBLK-2 7720000 84100000 46600000 48300000 120000 126 3430 18200 1740 ND Lim it of Detection (LOD) fo r the procedure is appoxim ately 10 ng/L Limit of Q uantitation (LOQ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 000070 00 ,3058 ResearchDrive ^StateCollege, PA16801, USA T: 814.272.1039 F: 814.231.1580 exygen.com Precise Research. Proven Results. Analytical Results Washington Works C8 Sampling 10/02 DuPont Sample identification APFO (ng/L) W WK-G-AJO6-MW02 W W K -G -N O 4-M W 03 W W K -G -Y 14-M W 02 W W K -K -E Q B LK -3 133 21200 NQ ND Limit of Detection (LOD) for the procedure is appoximately 10 ng/L Limit of Q uantitation (LOQ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 000071 ,3S0t5a8teRCeosleleagrceh, PDAriv1e6801, USA T: 8 1 4 .2 7 2 .1 0 3 9 TM Proven Results. RC H Analytical Results Washington Works C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) W W K -G -W ell 331 W W K-G-W el! 336 W W K-G-W est Wellfield 4 W W K -G -A X 13-P W 01 W W K -K -FB LK -2 415 269 16200 721 ND Lim it of Detection (LOD) fo r the procedure is appoxim ately 10 ng/L Lim it of Q uantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result Is not quantifiable. ND<LOD<NQ<LOQ Results are calculated according to the following criteria Ifthesample andlaboratoryduplicateare greater than250 ng/L, andthe relative percent difference (RPD) islessthan20, theaveragevalue isreported. If the RPDisgreater than20, the higher value isreported. Ifthe sample andlaboratoryduplicateare lesstha250 ng/L, andthe absolute differenceislessthan 50, theaveragevalue isreported. Ifthe absolute difference isgreater than50, the higher value is reported. 0 007 000072 ,3058 ResearchDrive ..StateCollege, PA16801, USA --.T: 814.272.1039 SL,F: 814.231.1580 pexvyagpenn.cmomm Proven Resulte. Analytical Results Washington Works C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) W W K-G-Gallery W W K-G -R anney W W K-G-W est Wellfieid 1 W W K-K-FBLK1 14300 51200 10300 ND Limit of Detection (LOD) for the procedure is appoxim ately 10 ng/L Limit of Q uantitation (LOQ) for the procedure is 50 ng/L ND - C om pound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0.07 000073 3058 Research Drive State College, PA 16801, USA |;>T: 8 1 4 .2 7 2 .1 0 3 9 ffeF: 814.231.1580 exvsen.com APPENDIX B CHAIN-OF-CUSTODY RECORDS WASHINGTON WORKS FACILITY 000074 | CHAIN OF CUSTODY/ANALYSIS REQUEST FORM p C 11 Exygen Research Sample Receiving 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): ------q u o i n . . ' 1 ' /in /> J y /.. *LS S * A f / 1.''" - /**. *-y7^- ' / y te ? r Phone: / .leu. S9j / 9 s Fax: ^ _ . V. S a m p le r4 ^ c o ^ x x c U ^ Project Manager (Name & E-mail Address): 7,/P< S*'-<<r.. A r s 1 * r / - / - s f i. , e <' <> Project Name: ___________C jP RO. #: L VjV'/ d/,.,, Quotation # : ^ _______ 'XefJ Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIMS# Client Sample Identification Collection Collection Date Time L fs w -i L JJr/9-L L L cS JW -f k s ts K y tV S // - f / /~<r// - V' A X 0* //!//- v 3 l^s ^H ' ^ --00~ iO zM i VOAJi:o? 1 H P 1340 C f i r s t 6 U - W f - 7- - / / - /s , -T iQ-t^-oj. V2>\S i - l i m j L U^t-</*' ~<?-tj~T/S // \- -1 \ 0 \&-o> A3 4 0 1l / r / f g - >r f d l / s - / \(H$-v4 \ 3 SS L A Ii U S I ONLY Specify Matrix ^ /-I Comments 'I s* L ^ ft io / {, S / 79 C / s/C'fS' L / /, ! 6ir>r.xf iit,t u!/1r i----v-r-'-J-t-*y*-f-7-j *-- - r jtz V s j 1 Cooler ID # Cooler Temp. (C) ^9 s K * M * DC 4 / 7; llll LL 11 11 L l L L L L l IL L LL L L 90 PROJECT REQUIREMENTS Results Deadline: U9 OTHER INFORM ATION 00007S Laboratory Report Options: I | Sample results only I I Add case narrative I I Add quality control summary F I Add calibration summary CD Add raw data CDOther CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving ` 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 - F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m Page . / of / > PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): /l,t) fQi,7 S'i'-%<r --c'. Project Manager (Name & E-mail Address): .?i" X., .4'* rfhj Phone: Fax: Sampler: J ') 7 t,, . AssT SV'j-o r 7'.,. j y - . v,- / L. cT"T . VA, ( V aA cU ajcU / S'),*/,*. /. 1 Project Name: RO. # : Q u o ta tio n # : &J-r.ss/. ,-vi a a a-atm* Please fill out this form completely to ensure correct analysis and proper handling of your samples. G rab Com posite Number of C o n ta in e rs SAMPLE ANAL.YS1S ExyLIMS# Client Sample Identification am i L.tivM. Ci Collection Collection Date Time Voi \V>kV j'ikVl /( X Specify Matrix Comments t v f h i /-'A j. > \ . N .V \ V X A /V \ s- ^7 1 I A V USE ONLY N M N Ol v,? O D iI Relinquished by Date Time lA ~ \ {A ( 'A /v , v ' l (Jc|'br\,'v_ !r > j \ \ a C$> 1$ , ^ D i >l il li iWFuUMlON VA', Cooler ID # < X W / o / / ,) Received, )& l/HL---- v *r Cooler Temp. (C) -1 Date Time j fn (tn - fa 20 LAB USE O f lLY * - y. 3 > i * 00007fi PROJECT REQUIREMENTS Results Deadline- t, \ r A H ^ v Q3 X t (aaA >^ Laboratory Report Options: j | Sample results only 0 Add case narrative [ I ] Add quality control summary 1 I Add calibration summary I I Add raw data Other Ili) I I 1I i I i } CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m j / . P a g e ____ of ' PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): A A .*? . - A w ... X * /> '}/? ZZ/.~/; - ) *;<*-r.- Z Z / * Z li ' r / ,, / / - . . ,, ,, X L . y y j'o s - Phone: '' v > - s- s' a a / / Fax: Sampler: L - r f T I 'V o v -^ , 0 ) C , i I A ljo C X l Project Manager (Name & E-mail Address): '-'` i - A X / . . , , . . ^ h / <.Z?si-i f * Z>. -A- <c, Project Name: A X ] ./?, j , Z c\. , s L "V P.O. # : L Q uotation#: 5 i L . a -~ Please fill out this form completely to ensure correct analysis and proper handling of your samples. G rab Com posite Number of C o n ta in e rs SAMPLE ANALYSIS ExyUMS# Client Sample Identification / , , % / j d - 6 - A 'j V - fH ts i) i~ Collection Collection Date Time \ o \ l ik i . \ o `A / Xf N Specify Matrix ci- - i ^ / 7 Comments L A .U y 'V A n x & v H \ 1 ^ /v, Xj i Jxr X. ______________________ . ________ -i ' \ .\.v L fX A, L \ i LO ( A G .*i o o 1 I AB USE ONLY Relinquished by \^/ ia/ 'aw^V'.- A l ^ iv i n \i Date . Time \T) li/il-J t li> 'Ti ! H Cooler ID # Received / f t --------------------------- 7^ 1 Cooler Temp. (C) -7 Date Time ItJ ii t.AUU'l: wHt.Y i i l i l i IN FO R M A I lo ft , _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ (~C Ve q 3 v- ^ la c . A .-,V-y \ x @ A 0 0 77 PROJECT REQUIREMENTS Results Deadline: , \ N \ Q /k \\ atI :! Laboratory Report Options: I I Sample results only I I Add case narrative I I Add quality control summary Add calibration summary f~l Add raw data LD Other 1I PROJECT INFORMATION Client (name & address): CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 ex yg en research.com Pa g e ^ , f ______ ANALYSES REQUESTED 1 Project Manager (Name & E-mail Address): - > / ' / < - / (' ksbW .-i+A .x . /?p* r Phone: " s tn - Fax: ;'T7Sampler: 1 . Vtc v\, ^ B . Q a Q c iu *M zh u. / -r Vi /. A. X - . iy S -f . i s / - c-y... .Project Name: x M---. /* /* * P.O. # : /' & *s* - v.s^ <t: g y p ir x Quotation # : f. = vv-. Please fill out this form completely to ensure correct analysis and proper handling of your samples. - V Y 'MX\r'' u j, 4tks1. `j x\ "i X \j X\ G rab C om posite Number of C o n ta in e rs B, 1i Ui yififjeEP I1,Al:;. ,f t i Vi # vLu 9 4.1 ExyLIMS# / Client Sample Identification tc -<$- P # t / - 'hi-U-JL Collection Collection Date Time Xio/llpjc ,a |l W 1' 1 Specify Matrix Comments X- 0 >i\ (iv //,, -/ i' )u ) -i" X T. T .1 A ii use o M i.v _____ _____ _____ Reli pquished by Date Time t 1 \ \ ex k x k f i Y V r i \d - vav'-. \ v l\ 1 \ a\h x U p nO I/ {7 Cooler ID # Cj6**0 I S Cooler Temp. (C) 0 -7 Received b/ Date Time ~ ------------ / i l l **-- /c2fl G i'HUi INFORMATION .AB 11i r , cc W ixw...c . | x) x O 3 i j , Q0 0 Q ?n PROJECT REQUIREMENTS Results Deadline: e;t V c ^ S l r u x ^ cLaboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary EH Add calibration summary ED Add raw data Other RESEARCH PROJECT INFORMATION Client (name & address): CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3117 Research D riv e State C ollege, PA 16801, USA T: 814.231.8032 F: 814.231.1580 * exygenresearch.com yi Page / of (& ANALYSES REQUESTED Project Manager (Name & E-mail Address): . ,a . ..... r Project Name: Phone: <r,f / > /U Fax: P.O. # : .g_&, ^ Sampler: L.. r 1T , vV^aa. v S CV^ciuKlS > Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. Com posite Number of C o n ta in e rs S V A P L iir A N A L Y S I S ExyLIMS# Client Sample Identification J ? * * * - - } ' L , - 6 f in(- MWvQ" Collection Collection Date Time I'd At? 0, K W / -Q nwJ o Specify Matrix Comments X W r i u / `/ r i / t )- tv, \ ) 'i i.vi k 4 s it ' y,, U "i t >1, Ik . fk ! AH USE O N Li 60079 PROJECT REQUIREMENTS Results Deadline: , V V\ ITt Laboratory Report Options: Q Sample results only I I Add case narrative CD Add quality control summary I I Add calibration summary f~~l Add raw data Other ______ I iS l CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m Page ^ of l& CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m / Page ( q i of I * PROJECT INFORMATION Client (name & address): ///V y -v , - A, ./ A ,, * '/r/t .)'> . J & // s i ' / y e s / J -,, ..... K. .. , Ci.Ji ' \KPJ Phone: Fax: - ' A .> > . 7 i Sampler: 1 . , ` \ C '(ft, O n l i W i L A i . Project Manager (Name & E-mail Address): --; /ri',' ... /'! /Cl-.-.-.--/. '--X -- (P*--fXr* Project Name: RO. # : i- i: (t- -v i Quotation #: f >> Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. ANALYSES REQUESTED s, 'ft \ v H v `S. v * >AA4PU: ANALYSIS ExyLIMS# Client Sample Identification 3E0Z-& L, -2 w - Wjw I Collection Collection Date Time [Mi>1 X +0- tnn> X0--1.0p=} Ec Z3 UO Specify Matrix i - . / . ... Comments -f" xl o\ 'Zc. 2 001 i AB USE O NIV OTHER INrGRMXTIOU Cooler ID # jliim lly Received by / ---------- ------------------- Cooler Temp. (C) -1 Date . Time 6/ina-- /MLO LABUSEOi ilV ^ f :Ay v v c X - > v i-'Vxi f A,Ci. V i le , ^ Q O O f i l PROJECT REQUIREMENTS Results Deadline; pAfcdrVyjjjfl o^xwcWcrc Laboratory Report Options: j | Sample results only I I Add case narrative d ] Add quality control summary I I Add calibration summary I I Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 *exygenresearch.com Page of O C! O o c -r CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3117 Research Drive * State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 exygenresearch.com --. Page ft of '___ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): - 3 ,.. /4iVt if /?/!/.. J > 1 , cW . Phone: ' 3 * ss- i r Fax: Sampler: L r T Y ' V W v f 3 ) , A ? / / </ / Project Manager (Name & E-mail Address): M /. A - Project Name: A ',.? P.O. # : # 5*4 Q u o ta tio n #: ,vi., ,, i t . , k j**.*< . e -V '-i Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. G rab Com posite Num ber of C o n ta in e rs 4.- a i i f t i J i r : M M a i y c f C L L j n i hI / ^ L j l i ExyLIMS# Client Sample Identification 3 X 0 Z - & "YW ~ i Collection Collection Date Time \ 1\V, 0 : L l f T \ 3 1' Specify Matrix .X Comments i V s i < ? / o v y / .. 'Y~'Ti k y tV H. -V" JA c i. vi; 1 A') YY . l 7 f IAaPr>u1i:rrr oAAniliy> O I i iivi* IN l'O R M Ai'luN i . ____ Cooler ID # Receive by A ------------------- ---- Cooler Temp. (C) Q.~f Date Time / ln h *- IO?c LAB US- ONLY v -iu A ' j ^ i U r l r 000083 PROJECT REQUIREMENTS Results Deadline:.-, . s i . VytouA \(j Laboratory Report Options: I | Sample results only I I Add case narrative O Add quality control summary f~ i Add calibration summary O Add raw data Other CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e * T o f j f ____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): lb w / 'S' A -..-, /H., y AC -X\ .. x-V A V y 7'/ ''-.V'T _ , s t r..,,, ,/ ' Phone: 3.SJ- - - SC Fax: Sampler: l . ' - n wtA/v T - l . CairVu.A' .P'l Project Manager (Name & E-mail Address): A 4-, A -Crh ( , . s i ,, .Y`Va* /' c Project Name: J' // P.O. # : / , Av , f-'i- Ai- ` /s* s-'x&sx Quotation #: S. V Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIMS# Client Sample Identification 3 }*>*-* ksj.'ic <A- Collection Collection Date Time i ul/i-Jn O2 o Q. .<nu.b3 E Ec o 3o u Z U Specify Matrix j A-'-* / - ' Comments 0 Lri ii 'j / t y *ri r CM O O k un I AH UhT ONLY A/ I N oi- .HAI ODY Re inquished by po Date Time k 1 \ .1(A A '/>).(' v i ' 1( li ^ ^ " V ID /lk (U i i Y V , // 1 1 Cooler ID # CMP ll* f Received, ^ ------ / - Cooler Temp. (C) 0 . 7 Date --- / Time lo w (.NULA IMH>l<MAHOH lAti U.-.t / I- C Jry y VhAA- YU' 000084 PROJECT REQUIREMENTS Results Deadline:, [f/1 (-Af\si(t YYamAv ., I Laboratory Report Options: | | Sample results only I I Add case narrative I I Add quality control summary I I Add calibration summary Add raw data P I O ther_________________ i I CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 ,2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m l* PROJECT INFORMATION Client (name & address): 1 AtS -A--,>., - J , -// v'ltf/h A S /'A. J "> a .... As S ri / Phone: Fax: Sampler: L ;T0 tWa 0 ,Cd:3c^uXJ.il Project Manager (Name & E-mail Address): A)/-./h , /, A -1,.: * i> t Project Name: A>a /.>/<- #:RO. -A- & v-m A ,A ,. S #:Quotation Please fill out this form completely to ensure correct analysis and proper handling of your samples. G ra b Com posite Number of C o n ta in e rs SAMPLE ANALYSIS E x y U M S # C lien t S am ple Id e n tific a tio n V w Z~M >//'QSIjc- jl Collection Collection Date Time / X Specify Matrix C o m m e n t s - CU' *'<>H/(s'/j,?/y ANALYSES REQUESTED 1 X v! vXI`l\`'V4VJ>.4.v* 4" X \X-:i X -{ Xh\ tO*- Y\v >o -S-1f" CM O o >.ntl;~r -- __ -- Cooler ID # A Received \)j ft-- ~ jl f Cooler Temo. (0 L Date Time J o /j-ilu - /a A * ol !FS? INFORMATION LAB (JSf: Ol ii Y , ^ _________________________________________O -l e o 000085 L.j, A\ o L or-.j U (' PROJECT REQUIREMENTS Results Deadline: f, Y Y \ 0:H'\ All J Laboratory Report Options: 0 Sample results only 0 Add case narrative 1 I Add quality control summary I 1Add calibration summary I I Add raw data i I Other ti i CHAIN OF CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sam ple Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F; 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m Page____ o f _______ PROJECT INFORMATION Client (name & address): A A - 'L,*.-., / A'h.A A',-'.-'/, 'i AJA' s? /- A Y / .4-- / / A , r,,. Phone: r Fax: Sampler: ( . r T T i i 't n A . ^ > C x i3 d u ^ li Project Manager (Name & E-mail Address): At. <-&*; b. A. Project Name: <L$ so RO. # : L a'Xn - ytoc Q u o ta tio n # : , ,vC -v At* Aa--.fa Please fill out this form completely to ensure correct analysis and proper handling of your samples. ANALYSES REQUESTED 1 A ) Y T, J V YY ' i 's; 1 G ra b Com posite Number of C o n ta in e rs / \ i \ / | I *I P A (VI i \ I y % i ExyLIMS# Client Sample Identification Collection Collection Date Time "FWtWoi 5c 11 3 Specify Matrix Comments --- :)T7/ F" X . N O _^cxv>A,f\t -- \ aA.. <Xa A. , 1 / I AB I.JSF ON I Y 8jf IN OF CUSTODY Relinquished by ^ W("a..A Af 1u ' T i ) . /( D 1 ^ Date Time k j h l N HfXV> Cooler ID # _________ Received by Cooler Temp. (C) Date Time O l i l i ii INI O H M i l O t t 000086 LAB USE ONLY ^ Ve \ \ q X n (Li n I - i r PROJECT REQUIREMENTS Results Deadline: (^ Laboratory Report Options: Q Sample results only Q3 Add case narrative I I Add quality control summary f~~i Add calibration summary CD Add raw data IH Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 - exygenresearch.co m Page____ o f _____ PROJECT INFORMATION Client (name & address): Project Manager (Name & E-mail Address): , <f y a/ y # /./, j > -<. f*M,-<L.rX., / y,.r Phone: v, > j ;)j - Str-r Fax: Sampler: f k l ) / f ) 1- Ixalu *//- yA iiY ____-/t-7 - X . , , ''A -...,,, p A f . l & . & L . f J c - . t f , Project Name: -c--_--e---s--- / --------- .y RO. # : S'-Ai- - &Si>L ,Y*. Quotation #: Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. >AMPLE ANALYSIS ExyLIMS# Client Sample Identification Collection Collection Date Time L JlK Q l d - (A y E Jh O \ .3 3 X ll 3O Z U Specify Matrix >7- Comments y fi- 11`Y i j ANALYSES REQUESTED i \ \NT k \ iM -K X I 111 H CO CNI CD Q I AB USE OHI V C H A IN ir S rk v-KII. Relinquished by -~) , Date Time ^./}U--\ i Ck\ -- a j; t T V ). )( . L X 1-''----------------------------- Y oJiW ui l 1 [Lo?>0 Cooler ID # C" Received by i -- ..................... ' ------- fCooler Temp. (C) / Date . Time /t b lk * - 02< OTHER INFORMATION nAAAO**J c A C ,t\ X\ 'i H PROJECT REQUIREMENTS Results Deadline,: ,h f S W:;H \ W v itu X 3 3 Laboratory Report Options: I | Sample results only Q Add case narrative Add quality control summary I I Add calibration summary Add raw data Other CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 exygenresearch.com Page of PROJECT INFORMATION ANALYSES REQUESTED I Client (name & address): $C> h / / A / * - . - * - Vi /Ai A '/e/j. 7 - ,, c . S S / & / / * / a . , /',.. / ! /V / w a Phone: / / ?r Fax: Sampler: ('S>Y.) nr> I?. IV yW riuM Project Manager (Name & E-mail Address): A ,. A;,,./,-,./.- b. V '.,.,. /I Project Name: RO. # : L ''1 - - / r ' 0 0 , . Q uotation#: S a 'o s *- Please fill out this form completely to ensure correct analysis and proper handling of your samples. 4.' 4 s, \ Vi 0 - i ,,N'1 V % si V 0* X. G rab Com posite Number of C o n ta in e rs /' 0 0 (T S A M P L E ANALYSIS ExyLIMS# Client Sample Identification - C) AJeV - Aiu-'aA Collection Collection Date Time V'- /* o;: 1H i X '1 Specify Matrix Comments -L. L(\c> \ a / vTs t-f il Hf I AB USE OMI Y 0 -1A IN I.ISTODY Relinquished by HJ ACi A A m 'y l ~ ~V?------------------------------------ --------- Date Time 1 /ta ffi? 1 o ( OTHER INFORMATION 000088 < \' 0 ( , \ \ v ' -I..Ak. `i X \ .i (\ PROJECT REQUIREMENTS Results Deadline^ Laboratory Report Options: 0 Sample results only 1 1Add case narrative 0 Add quality control summary 1 i Add calibration summary 0 Add raw data 0 Other J f# v I > I f l I Il1 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 J __________________1 Client (name & address): ///)(% I1-> ii',' *./ ~ i) T i?.<*?A A )J.. ' eL.-.,-,. /iff ./O '/ a , Jht~ Phone: pju - Fax: n Sampler: 0 , Y> /. M <jU_i .. L v"T l t f a w , Project Manager (Name & E-mail Address): A, , 4'* / V /") - : . >. A1--:t ,. {ffis.iSP- . / c Project Name: V s... RO. # : l j . u y e t i ' tf.f,*,. *x o?i Q u o ta tio n # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. G ra b Com posite Number of C o n ta in e rs S A M P L E A N A L Y S IS ExyLIMS# Client Sample Identification l\.sU/.i'' <4 I/'/1/ -S*tHsa-L- Collection Collection Date Time l i i d 1 bL Specify Matrix C o m m e n t s A '; VA ?</ L 'I F /j T .4V rn. \t , , vV\r1 'i \ jY H X' V V VK X r-i f j ____________________ / * I AH USE O lli V Ai B 8I rlillSilV`Sl O F f JSJ O D Y Relinquished by ---x ; Date Time li-fM Iq1llmullC ( o 4 0 ~T7------------------------------------------------ l i II,it INFORMATION 000089 Cooler ID # //c&azi /S' Receive/yby /f. Cooler Temp. (C) /*/_ Date Time /7 A>//7/e ^ fo lt I An use Oi-Jiv V i \\! C.A* a t-.lv PROJECT REQUIREMENTS Results Deadline: CM\ <0 -lTlx\/< T s 1- a r4 Laboratory Report Options: f~1 Sample results only I I Add case narrative I I Add quality control summary 0 Add calibration summary 0 Add raw data Other s \ CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3117 Research Drive * State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): / / /.. a } * ! /A-; S a..-', Phone: Fax: "" JT r ,, - 0 ? Z / P S ,- V/ . / .' i i /?;,> Sampler: * \k -$ vvJaX l L CXT \ \ v \ Project Manager (Name & E-mail Address): 1. S s s& i-c t... .-*-1 / A . ... ; w . A /. c , . ^ Project Name: F ' a. .. /, t., //: - PO- $ - & S ' Y \ Ci ; Quotation #: //V' Please fill out this form completely to ensure correct analysis and proper handling of your samples. A n \PLE ANALYSIS ExyLIMS# Client Sample Identification Collection Collection Date Time fa'- ? ! Q. Eo U z3 uO Specify Matrix aA 4m Comments b-fsrcu \ \ `Vi H 1; 'vi A V. tN ilM to o t.AI; USC ONLY CHAIN OF CUSTODY " 1 1--....... Relinquished by -- * Dal e x Time " A ,, f, f) I -\o [ i t Cooler ID # //Lw & l^ Received hV --------------- Cooler Temp. (C) l~( Date Time /i/tlfc x - /0 O OTHER INFORMATION 000090 l-Ab USL O NiV ; l ( ;c 4 y u A /w ^ V V & . \ & A a io l A PROJECT REQUIREMENTS Results Deadline: , Laboratory Report Options: | | Sample results only I I Add case narrative CD Add quality control summary F I Add calibration summary f ~ 1 Add raw data Other CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive * State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): d in /i A S'/r/L .J ) a.-, >' / Phone: //, ^ Fax: Sampler: f\ AXa sA.A / " ' V / Project Manager (Name & yn,'/c? A) . f. A , A i . , . . Project Name: eg RO. # : L -A r Q uotation#: E-mail Address): su- Please fill out this form completely to ensure correct analysis and proper handling of your samples. c h | y | p t T /% Y S 'i^ f c ExyLIMS# Client Sample Identification n siv i ^ /1 ,/d - ;a / .3*')' * m - < . 4 - e r X Jtyt i ( ir ?7 . ? A /4 A a . / A - c Z / X ;/ / / X n i >- y ksitSJt- Xi sfX i '] / - J , S" /sf.J A -X Collection Collection - CO Date Time O \ tS s 2 A l U k i 3 _ IU K j X l ^ U h U - X ^ oo H > r Specify Matrix .X ,.Jr, _ .. I JJ iJ1 K..:'*,.*'' Comments 6 `i s c j < f ' ( A' V )i fi, Y r o h/ / bA .'-/'ni*. ' JN r>i YX k; \ 'V \\ k \' L \? X" i 4K J/ < J X. C om posite Number of C ontainers / a*' ^ 1 %.C `l e 1 ii V. t 2JL / r i.sr ,v. y t AB USE ONLY A'% I V. i!|1v h \>S DYfr i." J Cooler ID # Receivfed by <?! i Ibi? INFORMATION LAB HSL O iil.Y 000091 Cooler Temp. (C) & * ^ Date Time UY^XiX \\c s n Jljllwvt. /6 ?c` J PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data 0 Other v p > r *- * CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3117 Research Drive * State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 * exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): Project Manager (Name & E-mail Address): r f / . s -- / /--/A -.4 /hS /?/ fh A r . . .. . , :W ss>sa? Project Name: Phone: .u u - ,??.> - / $s- S > /*/#* Fax: . _ v, P.O. # : XW / S j a m p l e r : ^ K ^ 3 x ) i S > \ Q u o t a t i o n #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. __________________________________________ ____________________ ______ _________________________________________________________ _ _ xYV'j] % tv^ 1'W \ i "k nS "Y 'r S' T y \s\`.Hv. Com posite Number o f C o n ta in e rs S A M P L E A N A L Y S IS ExyLIMS# Client Sample Identification / JSM- ! LkSit*''ft " 1 r m y - j b-S{S - ' ?.-i,>*.<ff L ?jW - ? H C \ . i*lSji7~,S fr/ / /. /./Z- X*- /' S'L./ci' f Collection Collection Date Time -oOu I-Xs-^ ig V A'JJSaV \ 'X X .\^ Specify Matrix /- y"rt 77^ .) ! y. / X- Comments >i{<>~Xo / ' i 'C fiv/ ; v 1 ;-) / i ft> 7 0 L- -t >i -Yrc/O C vy jy -r r y A' .\/ y4 # s' rP yr 4h IA USE O M lv Cooler ID # C Received b y *> / Cooler Temp. (C) Date \C i y is u t. //J > / > < - Time 'y ! La li n a -.'SMi V OTHER INFORMATION *> /*' * --- ------------------------- 000093 PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative 0 Add quality control summary 0 Add calibration summary 1 I Add raw data 0 Other APPENDIX C LABORATORY ANALYTICAL DATA REPORTS LOCAL LANDFILL 000093 L en 4 RESEARCH Precise Research. Proven Results. Analytical Results Local Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LC L-Z-O utlet 101 78600 Lim it of D etection (LOD) for the procedure is appoxim ately 10 ng/L Limit of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000094 I3058 Research Drive kState College, PA 16801, USA T: 814.272.1039 kF: 814.231.1580 exygen.com j RESEARCH Precise Research. Proven Results. Analytical Results Local Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LC L-G -M W -4 LC L-G -M W -6 LC L-G -M W -9 LC L-G -M W -10 LC L-G -M W -6-2 LCL-K-EQBLK-2 79600 19900 56.9 395 17000 NQ Lim it of Detection (LOD) for the procedure Is appoxim ately 10 ng/L Lim it of Q uantitation (LOQ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result Is not quantifiable. ND<LOD<NQ<LOQ Results are calculated according to the following criteria If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. nj 007 000095 0 0 5 8 Research Drive | xState College, PA 16801, USA I'.T: 814.272.1039 LF: 814.231.1580 exygen.com Proven Results. Analytical Results Local Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LC L-G -M W -14B LCL-K-EQBLK-3 488 ND Lim it of D etection (LOD) fo r the procedure is appoxim ately 10 ng/L Lim it of Q uantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher vaiue is reported. 000:9 000097 College, PA16801, USA exygen.com APPENDIX D CHAIN-OF-CUSTODY RECORDS LOCAL LANDFILL 000098 tY I R C II CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 G rab Com posite Num ber of C o n ta in e rs /? / / Client (name & address): -C - c, X - /J . ^ ./* * fs * // Phone: Fax: Sampler: /j h /9 fe r s>>- / ^ t k ^ _______ Project Manager (Name & E-mail Address): Al - j t A i.s s */. A /- r . Project Name: RO. # : L Quotation # : Cf c -tre t V ,/... ^ *,,0 Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIMS# Client Sample Identification } S G C -( L- C c - /o t Collection Collection Date Time mm X Specify Matrix A - ^ 4 7^^ Comments H /6 7 i / / l Y V \ T. \ <\ 4 Ni -kr J c - -i % 'S * Id 6000 LAti USE ONLY OTHER INFORMATION Cooler ID # " * * * 1 Received by Ll'L /?/+ Cooler Temp. ( C )^ 7 Date Time \(h 3 ite . / w LAti USE ONLY PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 0 Add case narrative PI Add quality control summary 0 Add calibration summary 0 Add raw data 0 Other i CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research S am ple Receiving 3117 Research D riv e S tate C ollege, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P a g e ______ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): Y flk * - .z x . , r f r -1 ^ ____________________ / k , e. i . . . . ________________________________________________ ( i h / ' t i ' / l -1 > / .......... . e . / , . . . . . y^.,. j/- " 7 f y j i' Phone: f/' i - y J - / / 9f s < // y.'/ ' Project Name: ____________ C <? -Ki ,, /.,, ,,/ cs*,-. U/*JL______ Fax: P.O. # : ~'>-/v - y' w- /?, L. .. /!/, Sampler: u r T t V w n T& - Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIMS# Client Sample Identification L.33 m \ / C L - C- A hs 1 / L -- a> C - eg- L / / .U M L m -r. Cl / . s' -- G *^4- ^ L a . - g - ni ^ /- - JC- ere ~ ftR L-C -i-& w sV i L 3 /7 9 - g [ n d h r - fe - LAB USE ONLY \^> Collection Collection ate Time mm \Ljf) s mr |C '"k W lQ 5 $ A I o ji le \ U b > A 1u .E11 -g-S ca oc Z U Specify Matrix j . .I Comments______________ --------------------- /yC----i.-.--v---r--7---9_/_ >V/ `>jps/ y / / ^ y /-?9o/ c / f ^ 9 y 1 y -/ 7 A a f n i ! ovr/KZ XIG 0 r f si Fr CHAIN OF CUSTODY Rdipquished by Date . Time "^-4 . Ca y ^ r i f l T V V l . r i L OiorL- NT/1 5 /0 9 IT -0 1D Cooler ID # _ i$0 06.7 Coo,er Temp. (*Q & 7 R e c e iv e d jw y il - . / D a t t 7 :" : -- _ 7 ; ' T'.rj OTHER INFORMATION ___________ oooioo : i# :':' V,-.'i LAB USE ONLY . .ii/r*11-<' . '`.i f.'.*V; v"-*. T \J U V A r CLMf -X <5? x> $ s V N k % Si \ 4 ** k A ~Z A 1 9 9a h t L JA L l 9 .i7.? h l JG PROJECT REQUIREMENTS Results Deadline: ^ . Laboratory Report Options: Q Sample results only [ [ ] Add case narrative I" ! Add quality control summary O Add calibration summary d Add raw data D Other______________ - L 100 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3117 Research Drive c State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 * exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): J/h /> /J , AY ----- ----------------j . z*?' / Y / .A- V Phone: .?*>*- x Fax: Sampler: N>` - if f l O f . jl Project Manager (Name & E-mail Address): _________ /'? /*? /, /AL2^gV_ /?- Project Name: RO. # : S ' s -7"--7---- < p j. Z-, * c J Quotation # : 'i Please fill out this form completely to ensure correct analysis and proper handling of your samples. \ A M P I F AWAITS! t ExyLIMS# Client Sample Identification L u > i - t L ( i & -/`i/- r//7 Collection Collection Date Time E v . O O -a i.r jo nt Cc 3O ZU Specify Matrix Comments Ay.a> u / t f -jL , i \ / i k Ni V' A' <c. x CnJ S-H I d o o LAB iJSr ONLY CHAIN OF CUSTODY Relinquished by Date Time .Ul ,c, ^irm?n^>y>v . vk zk 1\oD K Cooler ID # Received by iOTHER INFORMATION. LAB USL O N i.r ---------------------------------------------------------------9 & 0 1 0 1 j i Cooler Temp. (C) K f Date Time f lo PROJECT REQUIREMENTS Results Deadline:*I Laboratory Report Options: Sample results only I I Add case narrative I I Add quality control summary CDAdd calibration summary EDAdd raw data EDOther ! S' ' ! CHAIN OF CUSTODY/ANALYSIS REQUEST FORM PROJECT INFORMATION Exygen Research Sample Receiving 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ ANALYSES REQUESTED 1 Client (name & address): S r /'' _iV ;./ " / /*>)S0 . i V , / : J Y 3-, >5^/ ? / * /< S Y A-.3I 73 Phone: ' V3- -'sA- Fax: Sampler: 3 npn p i Project Manager (Name & E-mail Address): /'. A t'f .M .cit-H i t\ . -i Project Name: P.O. #: .f' -C--,,.3. a:/3.. 3 Quotation #: /. Cf.-. Please fill out this form completely to ensure correct analysis and proper handling of your samples. > 'vj -1 'M\ < ,`0 41 V.'. k-A:" XAA,' ,\s\` G ra b Com posite Number of C o n ta in e rs :>AMPLE a n a l y s is ExyLIMS# Client Sample Identification 3- (:, / `a, - / V A ' Collection Collection Date Time UVoi, 1iJ. YA Specify Matrix -. i ^ . ^ 4 Comments ? j jp J l A*z ( / i f x 3 i- K) O h i 9-i 3 !isn uacr\ .I*yt ;?IAIN OF CUSTODY Relinquished by Date Time \ a jkJXc4rFIAT ncCHtuv- i o h x L >U# D . -- - ______ . Cooler ID Received by LAB USE ONL\ OTHER INFORMAI ION ------------------------- OQOlOg gegg H Cooler Temp. (C) (< ( Date Time />J PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary I I Add calibration summary l~~l Add raw data o th e r ____ } PROJECT INFORMATION Client (name & address): ./fa* - i 1i\ CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 ` exygenresearch.com P a g e ______ o f _______ ANALYSES REQUESTED Project Manager (Name & E-mail Address): / ' SO/'* Co =i, 1 L - / / - . , j?j?- / %/&.)- Phone: j?<.i yjyjr Fax. Sampler: " 5 . 0 p n f? , ^L/AAri/l.U Project Name: RO. $ . Q uotation#: u /* J'C'i.,6. Please fill out this form completely to ensure correct analysis and proper handling of your samples. G rab Com posite Number of C o n ta in e rs SAMPLE ANALYSIS ExyLIMS# Client Sample Identification L- L t'-jU' - fX-g Collection Collection Date Time k'hCl nn> Specify Matrix Comments Y Y Y T ", y 'V A- r r{ 1 '+A -,L V1 U, V'\i o o 1 n n u x -3 ! AO USE OM.Y IN r iA.T| C3 18 Relinquished by Date j b L , v c * c ^ / y i : ? ( H -> -- ----yi----- Time , , i WF1/ Cooler ID # Received by o 'i'H L P iN l-O ltM A T H M- I..AK H .i .1il . 000103 % Cooler Temp. (C) ( t / Pate Time fi?/l/j&Sl. Ibi _. PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample results only f l Add case narrative i I Add quality control summary I i Add calibration summary P I Add raw data Other }1 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive * State College, PA 16801, USA T: 814.231.8032 >F: 814.231.1580 ` exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): / } h 6l. ` ` l Z ? /1* X - C- / - a"/1; ,1 5 w 'f A V '/ /H -A c / l j / t , 4ii f 4 ., e.*V*> . ,, ,, r i '., , j ) Project Name: Phone: ' 7 *-j '*<)>- / 9 - r Fax: P.O. # : A Tr V ; r x c - f '* Sampler: S , Csn o (y - i* ) Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. Number of C ontainers C om posite --- Grab S A M P L E A N A L Y S IS ExyLIMS# Client Sample Identification 1/ L- ' A 'hit,/- f. H Collection Collection Date Time lb-i-t'2. 11^7 * 1 Specify M atrix Comments ....... C `- z 1 C- / X. - - S9 \ A V -I. \Y X Y >< y 4 J* X 'V\fi ' yN' % V. ' 8V tn 0 0 I AB USf- ONI.Y Relinquished by /v2t Ljvc- v*r ^ l r ~ M ? T K Date Time 1(lorhiA i (dW s * Cooler ID # Received by LAB USL OML' * H-U INFORMATION ________________________________ 0 0 0 1 0 4 ? 6 Cooler Temp. (C) ^ Date Time fel* PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: I | Sample results only F I Add case narrative l~~l Add quality control summary [~1 Add calibration summary D Add raw data O ther_________________ I ! CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED I Client (name & address): .....----------//--X--T----v--r>'.,--" -7*--<4-h /j <*/./, J > A.-...,, Y. ),L,.... C., , A" / Phone: ' C v ' / w . /).r- Fax: Sampler: 9; Project Manager (Name & E-mail Address): -- -- ----- -----*--" -------------- --- ---- --------- -- /, Ji. a/*,. S.-'S'-t Project Name: P.O. # : Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. v* V Vv- % . tT 4 S. - l-U T- ,Y V, N. G rab C om posite Number of C o n ta in e rs SAMPLE ANALYSIS ExyUMS# Client Sample Identification Collection Collection Date Time -i- - & '><*.* /Y?$ to h i o* 11 L_________________________ ______________________ ______________ it I X- Specify M atrix A Comments i/ &''( x s } -A ~ K o\ i-7 Hr o o ; t AB t K t O lii .' Am ain o f custo dy Relinquished by \ K S u J ^ A (t~ \N 1 . 'j > > Date Time <V " W - IV |o? . |^ 7 o OTHER INFORMATION f\ J Q ) \p : 000105 ^ \ 'P i' -Wyrv/l il( j Cooler ID # fjf JC a V R e c e iv e d ^ / x /K ( ^ -- -- - Cooler Temp. (C) Date Time LAB USE ONI V -Vrw~. UooJL ? / V A ~T ______________________ PROJECT REQUIREMENTS Results Deadline^ iV \ K^cl ci Laboratory Report Options: I j Sample results only 0 Add case narrative 0 Add quality control summary f~ l Add calibration summary 0 Add raw data 0 Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving - 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 * F: 814.231.1580 * exygenresearch.com Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): hh&i*! /Y '.i /> . -s ^ / 'i / // -1''//'(.* "A--,.. &- / fV * ^ *ei Project Name: c,-.- -= Phone: > /j r Fax: RO. # : Sampler: l >HTTV\v h 5 TS Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. S.. V. W\ U .VVi %AMPLE ANALYSIS ExyLIMS# Client Sample Identification C 3 777-6 - X - /}/< > ..{ L j - ? Collection Collection Date Time \&!ivh'f I ) b 'hi o 0J.5 a . . flj uo E3 c Z U Specify Matrix [/ Comments (Hilft K & 1-2 0020 1AO USE OMt.'i IN OF Relinquished by U Date, U 4 C, < ' )' Time V3-3r> Vll 1ER INFORMATION C i A C A)vOl-ive 000106 PROJECT REQUIREMENTS Results Deadline: ,, t Laboratory Report Options: Q Sample results only 0 Add case narrative 1 I Add quality control summary r~l Add calibration summary CH Add raw data Other APPENDIX E LABORATORY ANALYTICAL DATA REPORTS LETART LANDFILL 000107 TM Proven Results. RC H Analytical Results LeTart Landfill C8 Testing 10/02 DuPont Sample Identification APFO (ng/L) LTL-Z-Outlet 002 LTL-W -Rt33 Stream Sample LTL-Z-Cap Runoff LTL-K-EQBLK-1 645000 2830 102000 ND Limit o f Detection (LOD) for the procedure is appoxim ately 10 ng/L Limit o f Q uantitation (LOQ) for the procedure is 50 ng/L ND - Com pound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND<LOD<NQ<LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sa m p le and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 to g fe\3058 Research Drive l|S ta te College, PA 16801, USA i\T : 814.272.1039 I f : 814.231.1580 exygen.com RESEARCH Analytical Results LeTart Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LTL-G-LMW -9 LTL-K-EQBLK-5 907 ND Lim it of Detection (LOD) for the procedure is appoxim ately 10 ng/L Limit of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria if the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. It the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 000109 ,3058 Research Drive LState College, PA 16801, USA F:e8xy1g4e.2n3.c1c.m1580 RES EA R Precise Research. Proven Results. Analytical Results Letart Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LTL-G -LM W -13A LTL-G -LM W -13B LT L-G -LM W -14A LTL-G -LM W -14B LTL-G -LM W -3 LTL-G -LM W -3A LTL-G -LM W -4 LTL-G -LM W -5A LTL-G -LM W -5B LT L-G -LM W -5B -2 LTL-K-EQBLK-2 510000 95.6 974000 105000 NQ 204000 2840000 112000 2230000 2280000 ND Lim it of Detection (LOD) for the procedure is appoxim ately 10 ng/L Lim it of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 hg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 O O O llO >,3058 Research Drive Slate College, PA 16801, USA exygen.com RESEARCH Precise Research. Proven Results. Analytical R suits Letart Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) LTL-G -LM W -1 LT L-G -LM W -2A LTL-K-EQBLK-3 LTL-S-Brinker Run LTL-G -LM W -6 LTL-G -LM W -7 LTL-G -LM W -8 LTL-G-LMW -11 25900000 931000 ND 61.2 15100 300000 3480000 121 Limit of Detection (LOD) fo r the procedure is appoximately 10 ng/L Lim it of Q uantitation (LOQ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. .0007 O O O lll. .3058 Research Drive State College, PA 16801, USA H.T: 814.272.1039 1 ; F : 814.231.1580 exygen.com APPENDIX F CHAIN-OF-CUSTODY RECORDS LETART LANDFILL 000112 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m Page____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): A O i l ' l l / X S-'L-'i'-i-L , - ^-`,30.1f ih f` 44 j. > / /?/ s y / .I.* S -il / / . . /Avo. .- A .-Aa - T /- " r / -X.ti+f y^ t 4 y ty Project Name: Phone: '' ru- /*%? Cs s ^L v Fax: . v P.O. # : '- U /lx ##/ Sampler: A SJ Quotation #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. \ i. 'I W yM M t 4 \ >' 4 > - > E xyL lM S # L C lie n t Sam ple Id e n tific a tio n 4-72- - 7 Collection Collection Date Time \\5 * 2 In - v c n * c r - i L 7 L / O ^ j I / - - > * X f * / rr X t i i ` t ' / im s 3S UTTj-QA \3.AC> liklbi o Cl JuL.=n) uEo 3 CO Z U Specify Matrix 4 X- .* l,- C om m ents / 6 ^'-cry 4= >> b / / - Lt'l-/P l;<V / &*h7VcP>? _u yz J- ?i / c/J- ><-/< ON o o LL o u. u Id I t 14- I All USE ONLY .f' I i S! ( - C l R elinquished by `^ :XJ \ ^ X v x OTHER INFORMATION ODV D ate T im e \ 3 \* jL \H 3 ? 7 C o o ler ID # yXoootfg z f R eceived by JSEs. C o o ler Tem p. (C) < 3 .7 D ate T im e \S O O LAfi USE OHS', 000113 PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: I | Sample results only I I Add case narrative I I Add quality control summary CD Add calibration summary Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 - F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): A'h /i'S-i 'A - h; .f sh -It hU-,s ' 4 /J ., v- 1 Z u , , j& 'i///..,,* ,. :-ii / <) Phone: ,> - s z 'ir Fax: .<W vV Cyi'i / . S ? Project Name: *- A S RO. # : vzb A./' / ^/ /!/-. . ( f r-VU j AxA Sampler: ;- r 7 tnt a w .r ^f t5-.---(-v--t--l-d- m---t->--L---(--- Quotation #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. A i / i i. > C it i V C I <' ExyLIMS# Client Sample Identification L r / - CU-A.... 9 Collection Collection Date Time ocu J<2P.ani) E EC uo 3 O Z U Specify Matrix c. Comments J , r/ T i; r tv Y)viUArvu' hax t\ L\! reOs. t A"i M Q A" m li V 0\ o CD uO . Z I/llI J0T.Lr -.-fcQJL&-5 K>JlmUA&3p * v- X li) 3 I AB USE ONLY mu% fi- U,>rIvU^Lr J \ Relinquished by Date . <4 L \k LAM f) rHlA 0 1 ) ' 0M- Time 151)0 1( / ' Cooler ID # f l 0*4.3/&7 Cooler Temp. (C) ~ Received ty / J /-- M P z. Date -- Time /d?3 1tifi i-; iNl-oltM AKJN -- & oo4-- LAB USB Ol ii Y V" 19 cX sA ^A aC, C\j) t k, nAP.ar e d i) }<L- PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: I | Sample results only 0 Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data 1 I Other I i 1 I CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sample Receiving * 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.com Page_____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): A V )r'V in dA>7> /J 4 ./ > / - ,b ~ y. .-. 7 . / if x iV /V a .- Phone: Fax: j A <iT y < y j'* r j> 0 ? .? Sampler: ----/,,-----A----T,--?--tH-,o--,.------- j---------A-----k=-d----A-----u- ---l-l--L--- A /< ' Project Name: (I RO. # : Quotation # : ^ 'f ^ >r f 1/ ; /C * / ) Ji. s ~ 3 t. j f . / .r u y y .. s a ' gj? / Please fill out this form completely to ensure correct analysis and proper handling of your samples. '.7 & SAMPLE ALssAI <r"1ip o o.E Q. x i m ExyLIMS# Client Sample Identification Collection Collection Date Time uE o E3 cO Z U Specify Matrix -rrr-, 5 k A Comments )\ -fAuu Vt, A ________.____ J- yL A:hA^ [LciM e.. -k> h x -W s x j l A 'Y T ') o o i B USE OHI.V /v"'A.k Jpi?i i-!|f*^*'A S-'.J'"Li L.U J I Q lJY Relinquished by --% ' ilS ^ V TA A X f l T JiU W L 'J ./ ! Date ro lftc x / Time ifin > i >YI ICR INFOliMTIOM 000115 Cooler ID # Received jiy / ........ I.AB USE ONI V Cooler Temp. (C) -1 Date toj i t h t- Time H i* PROJECT REQUIREMENTS Results Deadline: _ C A e1i-'h cv l VsTtlbwl >ft> Laboratory Report Options: I | Sample results only [~| Add case narrative HU Add quality control summary I I Add calibration summary d j Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 .* exyg en research.com P a g e ______ o f _______ PROJECT INFORMATION Client (name & address): Project Manager (Name & E-mail Address): A t S t '.'t.- r--i - ->/ /*? A t A /? t f r, j \ V .a -'/ ' v v ' f i sC h '1 .. / , / S ^ ..^.1.-, 7e, (- c- , 1., U'- // * > .* * Tm, /'k f'S .T Project Name: Phone: - j j ~ / kr c" .v- .J .: /> /, Fax: RO. # : /-es;-- t y te Sampler: < T s' ,0 Quotation # : ' Co Please fill out this form completely to ensure correct analysis and proper handling of your samples. AMPLE ANALYSIS ExyLIMS# Client Sample Identification L 3 ? 777-1 - 7?-- A I Mi*' / i A Collection Collection Date Time Itj te)**: X oQ. E uo Specify Matrix Comments ANALYSES REQUESTED \ ky * 'I V 13 n uO v-- CD 'A B USE OI'UV S' IAIN OF CUSTODY Relinquished by Date Time X>\ /\ rlcD^YA T )/UipT"a./ Y o|\l 0 x r 'V b '* 11 Cooler ID # Cooler Temp. (C) Received b y / / , Date Time M J a -- - -- - -- /o /rt/o----- to fjr H l l t U INFORMATION ________ 000116 A B USE ONLY Y-l n h w . C T X i \ t f . x a H z . PROJECT REQUIREMENTS Results Deadline: ,, . . A r< yJiV vtdo.-Y > v\ Laboratory Report Options: 0 Sample results only 0 Add case narrative I~1 Add quality control summary n Add calibration summary I~1 Add raw data f~l Other ___ ___ "T * I ;v. f ii1 CHAIN OF CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sample Receiving 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * f: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): ///.Fv.-v - ,, - j ) is* s /J.-r > * J'v'V V'.,/ L , T' / v'rv^ Phone: Fax: Sampler: U n ' P V ' W v ?S Project Manager (Name & E-mail Address): i a ,,/. T ., /h _ / - /) Project Name: P.O. # : .< 22, - v r ^ Q u o ta tio n # : / 0 . / aJ pj T /P ,. ^ * # / Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. G rab Com posite Number of C o n ta in e rs Nv A M P L I : A i \ 1A S I S ExyLIMS# Client Sample Identification 3 *7 7 7 * - <1> C-' v A " / t i l Collection Collection Date Time ^isq /o. 11 X Specify Matrix A Comments A y / 7 >".i / L Y' A O ' - AX 'll V\i k ,A X -E V 'X -i I f ' TV '/ ' T ` V, fof) t . U'.i o u t v R elinquished by S f A u r A.A, /P i/ irP T W D d P D ate |e j i( '.\ 1 Tim e O li ICI; INFORMAI ION 000X17 I AH i I ..f (Al ii A O tt Tat t PROJECT REQUIREMENTS Results Deadline: . PAbK\fc>c> <.\XqjJ& c c Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary 0 Add calibration summary 1 I Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m Page____ o f_____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): 'j , `*~y.,', t . - ~ ^ / Phone: Fax: Sampler: . y . />. f 9fits' S`<>- - i 'j - / 'if vp AJ.(?____ Project Manager (Name & E-mail Address): ______ '"`i / /h. ,-7<? {S t? C, Project Name: ex /' ; RO. # : -yxi-' /?I A A .'.y j-'( Quotation # : Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. AMI A ii rAt iI :'t** E x y L IM S # C lie n t Sam ple Id e n tific a tio n Collection Collection Date Time 3 jm -S L - f 'f- -- C : - / t `-i i v ' j t / d VO O o 0).= o. S i flJ E uo 2E3UcO Specify Matrix C om m ents 1- / / '?r > / <ff 1 Y ? Jr A\ A H mv .v x\ Vi v%t 0 017 iAt'i USF O M IY U iA iM OF CUSTODY R elinquished by ~ {/ KC^ O l Y^ D a te . T im e (V b 1 y o litJ ^ v . Y V S D j/ A C ooler ID # R e c e iv e d ^ / C o o le r T em p . (C ) 7-^T ---------------------- D ate A r /y A T im e < Ti UM INI O>a.a/wM vIiII'O-MN'i 0o l l 8 I.AB USE o m y f%'*\ PlecJ^v^c^\ / PROJECT REQUIREMENTS Results Deadline: . ~ fY \ Q -jfasodtyla% Laboratory Report Options: n Sample results only I 1Add case narrative I I Add quality control summary I I Add calibration summary CDAdd raw data CDOther RESEARCH PROJECT INFORMATION Client (name & address): 5 .. /iJS > f CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m Page____ o f_____ ANALYSES REQUESTED Project Manager (Name & E-mail Address): ^T, yit y??*> Phone: Fax: Sampler: A-,, :\ --> > - f l > / L -~ r-; r - t ^ s .q w Project Name: RO. # : Quotation # : -C---\-<---?--- ---Z---A ---- A---. --, --, -.- y. --------'--- --A--'----- - . -A..<- /'i .-,PI Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. A M P I ANALYSIS ExyUAAS# Client Sample Identification c i--?/ - / nu-? /V t Collection Collection Date Time Voj\cj* V o a _-4oJc.m= Uo E3 Oc Z U Specify Matrix Comments r& t/s / i- '//7,c/ V k XJ M X'v X% v\ &\ 9 - i 9. 0018 Ims nsf nwr, <NAIN t il" CU5TODV Relinquished by * Dato ; Time va r a yOccIciTVA 7~)A'h>-, IO h i k a /1 * >i ! h it iN lT iR M A T lO i'j 000139 p j PctyeiAc. Cooler ID # tw co1/# Cooler Temp. (C) Q .j* PROJECT REQUIREMENTS Results Deadline: ( Y ) - e l i u A 6 - W Ui Laboratory Report Options: f~ l Sample results only P I Add case narrative [~1 Add quality control summary I i Add calibration summary I I Add raw data Other I I ) I I 1' ' CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORAMTION ANALYSES REQUESTED Client (name & address): / / is L-XV!.. cCi__2T-. r- >'>A W /4 K- Z - D'> ./ i Phone: z&Jt* zD jt- i / ( Vp sw Fax: Sampler: j . $?> I r l u ; u l _____ Project Manager (Name & E-mail Address): A A. Project Name: L JPX- RO. # : -/A - Quotation # : -------------------------------- y i-------------- ^ -yl/,.-, /.A- Please fill out this form completely to ensure correct analysis and proper handling of your samples. t, V\s- SAMPLE ANALYSIS ExyLlMS# Client Sample Identification L 3 S i - n ~ i / n - ci y Collection Collection Date Time ss ? o^ a>>~ 3.E -n m Ec 3o Z U Specify Matrix ir' lAV\ A Comments <>` / * - V r *P- / */ C " V'' I X >i rsi -Z D ZD I A H U S E O M tY Relinquished by --- Date Time - ^ v j u - A ^ d ^ f V U / U W |o \ i h x f t BS . 1 Cooler ID # Received W T, / M -- -------------- Cooler Temp. (C) / ( Date Time /o //y /L - lo t? o lH B l INFOUMATiOfu x u S t M - _____0 0 0 1 2 0 LAB USE OH IY a b K 4e> A.-f rrwiL, b>tf( A VlXj\ j y ^ u J o \ ^ ______________________ PROJECT REQUIREMENTS Results Deadline: nJ Laboratory Report OjDtions: Q Sample results only I | Add case narrative I I Add quality control summary I I Add calibration summary EJ Add raw data CD Other CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive 1 State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): /);' -C - LA,,r, / &/h J s /.*>.. / f . d / 'Kro~ Phone: ' Fax: Sampler: 0 v'T'Y > 0 , 0 0W iJcM Project Manager (Name & E-mail Address): S*t e4' s/i-, ----- /) , , r . Project Name: /'/- > RO. # : /x **/ Q uotation#: Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. G rab C om posite Number of C ontainers .i-i f %\hn i* ,SLL . r - y1\^1ff \ I Sf 0,,Jl1JC>' ExyLIMS# Client Sample Identification ' L n - . -Lrhi-'- Collection Collection Date Time \c 0 M # i _x Specify Matrix Comments J. K' 1 ->y/ c v v j v f > . N-, 1 K i , v'SV X vv ;i: V\ t i f -/ f iAHusr OHIY 0 1 A r J V ( i l l VA C o oler ID # C o o ler Tem p. (C) f s f PROJECT REQUIREMENTS Results Deadline: A A <?4rW xl Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary I I Add calibration summary 0 Add raw data 0 Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): /)& > l> l A / ? S * * .'* ' .< , ~ t s>, / . , v . . , J> A y.A,,,i 4 s . /?A F / y / w / 9y&.-i ' A * / . > Project Name: </. /T Phone: Fax: Sampler: " J W - jva 9 * C vT T /V n vi . 7 P> C~ f i i r J----l-A----l-i-i-_--_--_---_ *-- JP' '7i- P.O. # : Quotation # : ?Hf-f C?j ' M... y M <>./ Please fill out this form completely to ensure correct analysis and proper handling of your samples. rv' H H fitVi Iti s LI f:t Yi l 'lIlMi V.ji ExyLIMS# C lie n t S a m p le Id e n tific a tio n L JS/777-) oa 4-Jc.E X i n) Collection Collection O o 3 ODate Time E EC U z u Specify Matrix iojukn 7 J- C om m ents Cv r rwy/ y ( rx > 1 v u X rY v 7,7 0023 I .AR USE n u a HAIN OF O J $ O D v R elinquished by M i. vu ca ^ a<&c y v i . M i O ' k n D ate 1 0 / If / 0 ,1 f' T im e 1*33 0 HI-U INFORMATION 000122 C o o ler ID # / /.a t a o O T C o oler Tem p. (C) h j R eceived by D ate T im e -------------------------------------- ---- I I m - ' h iT LAB USE ONI V PROJECT REQUIREMENTS Results Deadline: , (f f \ Laboratory Report Options: 0 Sample results only 1 I Add case narrative f~ l Add quality control summary I I Add calibration summary f~ l Add raw data Other Is I1 I CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 - F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m Page____ o f _______ PROJECT INFORMATION ANALYSES REQUESTED I Client (name & address): /$/)/&tyi j/t/' < - /\. : '/' tfhrtP i?/'/. Lsf.pvr Phone: Fax: Sampler: [ CA. On Project Manager (Name & E-mail Address); /^i<(iff //sC.-.'t h. -Ai,... _ r-.c w, Project Name: M/os RO. #: i-X Q u o ta tio n # : Please fill out this form completelyto ensure correct analysis and proper handling of your samples. .Crab C om posite Number of C o n ta in e rs - S M P L E A N A L Y S IS ExyLIMS# Client Sample Identification 5 /7 7 7 - S?-/ - & c-shA.-. s/9 Collection Collection Date Time !i'V' /ilAi)H1 i s X Specify Matrix Comments ~r~?/.A?J_'/ /, t//y / f v 's i 'JV. '"A s** '\V i%\S)i A; \ V-I, Ay'* AVvA'.V., k .Vr -1st' CM O O -- -------------------------------------------- !-- - I A l i i ist' ONIV PROJECT REQUIREMENTS Results Deadline: ^ \A u)JA aav\ a\ Laboratory Report Options: | 1Sample results only Q Add case narrative 0 Add quality control summary 1 i Add calibration summary Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g ______ f _______ PROJECT INFORMATION Client (name & address): / t t ) ( \ / t /? -- 1) $ /h .J .>".1 A? , cs/ //-V A .,. Phone: ' .? *> - Fax: >P sa w / t? Sampler: / . "TV Y W .. , OolM iaiIUIX Project Manager (Name & E-mail Address): P .'/ic S p t, ^ A ,, / . h. /A , p a s s / , -/, ...... / Project Name: ' r J , /,J. / s > / ^ 9.0. - ` r o c **< { Q u o ta tio n # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. ANALYSES REQUESTED ZS'- \ \, `H , i M " . R L l -s G rab C om posite Number of C o n ta in e rs Pj C h i \ h p i f. , i \ I \ f 11 L 1 . li ft 1 % i "% L . 1 ,Jf I ExyUAAS# Client Sample Identification C it r r T ii L 7 - (Z n i, . ' - i s( Collection Collection Date Time H i\ u j /` Specify Matrix Comments S 0 *l < 1 ' ' / i < , 7 C V k k. f 7 -r U r i M; use ONLY CHAIN Oi': CUSTODY Re, inquished by ^ \ _ Date . Time -\k P AP c IrtYl 1 ) Ucav lO //i/o . '( 1 V-T'.TO u OTI li t' INFORMATION 000124 V_\ C o o ler ID # / ' f o o c o f, T C o o ler Tem p. (C) / f R eceived b y / / ....... M -------------------------------------------- D ate /a T im e t< * /r LAB use ONLY \ H lXm HUYxjoltl PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative f~1 Add quality control summary 1 I Add calibration summary I ! Add raw data CDOther ___ CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ Grab Com posite Number of C o n ta in e rs - / A -/ 1 PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): / j b l ' t - l / A " i C .'-tS -1* . J - l f / > m S M , .!> A * , A t / e j t - / y v .u * , 7 >-,,. 7 ^ .. J- ax- Phone: ' .fr.;- s t ir Fax: Sampler: ' U C T ~ \ ~ V w . Ey - Ca A A o_>(LM Project Manager (Name & E-mail Address): A C . C -.-.A A > . V.i ( . i- / . A Project Name: A a a . st S R O .# : - / A `s s d Q uotation#: d / . . . . . A '., Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIAAS# Client Sample Identification 1 ? 7 7 7 -1 1 / 7 2 ' ('> / yi-r 4t A " S 4?' ` ^ Collection Collection Date Time iO iiloT Specify Matrix Comments A i '( p t / & vy i t > 1 i,' tV k * Ni X ''S, x. N.. H Y* V Vi \Y Et t AV 74 i.AH USE O lii V OVi 1ER INFORMATION 000125 C o o ler ID # f t - V c oe C f R eceived Jk& C o o le r Tem p. (C) / . { D ate Tim e /O /J l-A fi U S E O N L Y \\ H\y^A PROJECT REQUIREMENTS Results Deadline: ,, . p f l i 4 'W rl A Y mA Laboratory Report Options: I | Sample results only | | Add case narrative Add quality control summary ED Add calibration summary I I Add raw data O ther_________________ 1I ! I I 11' CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 " exygenresearch.co m P a g e ______ o f ------------ PROJECT INFORMATION ANALYSES REQUESTED | G rab C om posite Number of C ontainers A 'A y d Client (name &address): iO h iilH Phone: Fax: Sampler: /}/* ^ /.m, 7%*. Ar S t s e r jv->- a/a S (/ / ^ (0j , d i A i f U Project Manager (Name &E-mail Address): <-rA l ' t A r `. Ai L \ A*..!.:....:. ., .At/,.. .<C Project Name: RO. #: C g `S . / . - V & Q uotation#: /#/& ?- aaa/ Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS ExyLIAAS# Client Sample Identification /77/-/5 ' A-L t itS L '# - J Collection Collection Date Time lfTe5 l Specify Matrix Comments r 9 / ` /" n f ' .l tC\.l 'V .AV-) \ A. N'1j $ -r" '*V 'ft' A\Axj 04 O J L S i 1Mr1ICCOMiv' i IH N 4 OF CUSTODY Relinquished by (J i Date Time ic la v x , W h Iv a l'KVt 1i T- - -- Cooler ID # / / Receive^j5y _____ f U r ----------------- -- OTHERINFORMA!ON Q0Q 1Z l A B U $ O i' ii.Y ' T ' A t e jfo rq /\A aL V h i I Cooler Temp. (C) I f Date Time / //S~ PROJECT REQUIREMENTS Results Deadline: - f A ^ Vo m I 2 l a Laboratory Report Options: I | Sample results only I I Add case narrative P I Add quality control summary I I Add calibration summary 0 Add raw data 0 Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION 1ANALYSES REQUESTED &Client (name address): &Project Manager (Name E-mail Address): ,.>.1r/f/J., JS /..... . z9/ /S^VV/ L,.,, ty,. &: y'ft'.r Sh ^ ..A.. /: A /:< Project Name: . .. , >'Si Phone: Fax: ' /6 RO. #: , c-.,. xx /s .ro f/ V% v ,vi Sampler: 1^ ,< 1 V W iPS-.(ViirturfM Q uotation#: 1, `ft: * t Please fill out this form completely to ensure correct analysis and proper handling of your samples. 1 4 V\ 4 S A M P LE ANALYSIS E xyL IM S # C lien t S am ple Id e n tific a tio n Collection Collection Date Time Si Ortf S S 7 *z -l L n - c--, / /L.y / Ic/HIo 1 "y Specify Matrix C o m m e n t s ri.2 it- : >y/a'i '>/ Li /a>,r- / -k'" X U 7-7 --4L C om posite Number of C ontainers 0010 I AB USE OMI Y CHAIN C I J S T i l i W R elinquished by 4VK<';Xa.rm 'ViAX t 8 / D ate T im e \o)\'l-X '1 OTHER INFORMATION 000127 C o o le r ID # ^ jL -w * * * S ' ! C o o le r Tem p. (C) j R e c e iv e d /^ //fa / ifW ______________ _ _ D afe (A T im e /O la LAB USE Or i f . C ' \ i i / i !r \ ' \ A A A. i -a b it PROJECT REQUIREMENTS Results Deadline: }AAH ko j. ?: ^ aA oI Laboratory Report Options: I | Sample results only I I Add case narrative I I Add quality control summary I I Add calibration summary I I Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sample Receiving * 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA f: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 ` exyg en research.com Page. of PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Hr, 7 ,C' /v C;., . /it' ArV -'-// /_ . . / A * /O .,, gCpg r Phone: i - - / ' y,/ Fax: Sampler: Bi "<T 7 / - b w v Project Manager (Name & E-mail Address): __________ '`-i . - 7/ -,_______________ f h A h A-'t.g.,.... rA 9*wr. Project Name: ________v a ... -v /. ____________ RO. # : jL g jj -j YXot, 7*/<*,, Quotation #: '-Ta ,:;.*! Please fill out this form completely to ensure correct analysis and proper handling of your samples. 1; h p / y t s j A l ~ ' i si, 9 s ExyLIMS# Client Sample Identification S J 7 f c ' 3 L 71 O /- / r7-t-' - 3 - / ? L 3 n ri -z- Collection Collection Date Time o .O CL otC uII. o r4>.vE -Q nj E3 cO Z U Specify Matrix JL A- </j. Comments i ^ / n -7- / 7 y / i r i V NK \ 1 V k 'Vi 'L tc 1 CD J-7 H O h(* I AB USE O N I Y CHAIN OF CUSTODY Relinquished by Date jH {? Time \?j\kr. ?; oivs OTHER INFORMATION 00012K Cooler ID # / c c a o / 1 Cooler Temp. (C) ) Received \gi / / Date ----------- Time ! ':.B 11Si: Gii!.:, S aC -rercl PROJECT REQUIREMENTS Results Deadline: f.A/l Laboratory Report Options: 0 Sample results only 0 Add case narrative 1 I Add quality control summary I I Add calibration summary I I Add raw data 0 Other j i j i | I ! 1I * * CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving ` 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION Client (name & address): U f)tJ A -C - . / /! /- /., .2 S / y/ .V.Za Phone: /O Fax: /'in - r / -U * Sampler: U - r O N v h M . , C rx k c X u X J -A Project Manager (Name & E-mail Address): A /Z A j , / . t>. A A ' .-.-, A / . f A . Project Name: ' RO. # : . . T ~ / r r * t .a Q uotation#: .< ? //> j ANALYSES REQUESTED V V v SL \J & N. P le a s e f i l l o u t t h is f o r m com pletely t o e n s u r e c o r r e c t a n a ly s is a n d p r o p e r h a n d l i n g o f y o u r s a m p le s . Com posite Number of C o n ta in e rs si r AT iMV l iP 1I L Lt . hr \ Sf \ SW " * l -i Y KA f !f %t E x y L IM S # C lie n t Sam ple Id e n tific a tio n 3 3 7 H -5 31 m 9 / T ~ k ' L -T L ' X J a j j - J Collection Collection Date Time ) O ff J fl Pr V a ' t> 1 Specify Matrix Ix S -f* 9~ io h A o v C om m ents ' r y / A / i v r r / / 9 -a .S 03 %j R X i -i - l 1- Z A' ^3 % H -\V K Ni N . ts 'M X) V. y ?< A y *34 J 1 .t W & T fA / / - A T - k / .jl 0 012 IMS USE ONIV Av i/gviil&fvt tS' O/ "''i rf : L/ ' `A'I JJt I O i Jt'Vi1' R elinquished by Da te j Z l Z , ! r i r k J c :1 :V \ . I l i ) V v " \ o U* '' T im e C o oler ID # C o o ler Tem p. (C) R eceived b / / . y jjf __________ /* W/ a * - D ate, __________________ ______________ , T im e A- ( UNIT; i! li;i fl;lviA ii >1 O O XZS- i AB USE Oiif.V L-A\ eA. C(. , V .~X2.ll.A>yO O i c PROJECT REQUIREMENTS Results Deadline: ysfci& kfld Js W a Laboratory Report Options: I j Sample results only I I Add case narrative CH Add quality control summary I I Add calibration summary I I Add raw data Other CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research D rive 4 State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 4 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m Page____ o f _____ RESEARCH PROJECT INFORMATION Client (name & address): C h X iN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ ANALYSES REQUESTED Project Manager (Name & E-mail Address): /- if/c/-, A ?< Ai.s-* P h>, M - , Z,:-/.rX' Av,a ..,/. v - / p.p&r Project Name: Phone: ^ /s > //Z r C .P ) yly/aJ- Fax: RO. # : /f-f/i,,,, Oc <5-P/ Sampler: C e t " i b , cl3u1 >J Quotation # : ) Please fill out this form completely to ensure correct analysis and proper handling of your samples. r\l\flS" M A IV C K E xyL IM S # C lie n t Sam ple Id e n tific a tio n Z 'T i - < V- /* Collection Collection Date Time \r; H|c; iU 2 i X oa .oSO.S*<n-) uEo Ec z u3 O Specify Matrix C om m ents Of Ni SO -f- * * O o I AB USE OHiV R elinquished by .r z W L ' l i D ate I T im e o'i'f 1ER INFORMATION 000131 C o o le r ID # S 'j fe O g A 1 C o o le r T em p. (C) R eceivod^y M S *-- w D a te/ T im e ____________ /O f f T it - I Ali II:.'.: OrUY tl. PROJECT REQUIREMENTS Results Deadline: nA giW d r> V v Laboratory Report Options: | | Sample results only CH Add case narrative Q Add quality control summary CH Add calibration summary I I Add raw data [~~1 O th e r RESEARCH PROJECT INFORMATION Client (name & address): CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive 6 State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m Pa e of ANALYSES REQUESTED Project Manager (Name & E-mail Address): /A )A A" Phone: Fax: Sampler: /?/nA i -, .* ,.. ,<?/ s v / 7M h/-~ J9XPS J-i.i - - / -jj- A \ )W - __ , Q a M V2- Project Name: RO. # : I,, gf.jZc; ir-ir:c Quotation # : _____________ izJcot Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE AN LYi: E xyL IM S # C lie n t Sam ple Id e n tific a tio n L J/ 7 K -1 . T C - < -S Collection Date d fd Collection Time M L -iQd A oQ. E uo Specify Matrix C om m ents 6 MM >t / i f y / 3 .7 f -A \I A <Y 4 * ic $A V. \V' >A."\v 0015 I !! iJSf ONLY CHAIM OF CUSTODY R elinquished by \J } L 1 D ate .T im e vdHfeA r -------- C o o ler ID # ^ / c c o j'1 R e c e iv e d ___ ------------------------------- C o o ler Tem p. (C) 0 ~ 9 D ate T im e /C 2 o 0.1HERihH-ORMAllN ------0 0 0 1 3 2 __ y 1 c.y yvvH ( ' * O UYUr fv>V-r PROJECT REQUIREMENTS Results Deadline: f\A SaV Laboratory Report Options: Q Sample results only I I Add case narrative [ 1 Add quality control summary F I Add calibration summary CD Add raw data !~1 Other i r i s 1 * CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving " 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): /lO tiri - A ...W I r './.s.. 7? / ... / '? ,,> / v- / --------------------~ ....... ........ -- Phone: s* &r ' Fax: ~ Sampler: L - T ; i W . iES .(InJ/lu H !JA F`roject Manager (Name & E-mail Address): sh >A ../7.. . / i . i , , y. s>7 .. ., j'f_i.sj F'roject Name: 3.0 . I - /?y'i - & Sisi' &/**.,-. /'a Oc ^.ti <Quotation #: Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. t(ji "i N4' M i f \" i A, '`V\ I Crab Com posite Number of C o n ta in e rs 9100 ,>/ \ l \ / l " L 1: A W L S I ExyLIMS# Client Sample Identification t r m - t TZ US- '{ Collection Collection Date Time \ \ )\ WH HLvA\() X __ Specify Matrix j /... Comments V ' ~;y y / / -V/ '.V i -f- * S- I AR ! ) j f ONLY Relinquished by ' j - . U t'A A A i l ( f W l . ~7p V* Date t L W ' - 10 1 4 : 7 Time Cooler ID # Received by / /' / ---------- t i l i i IER INFORMATION 000133 i.AB USF w i'JY <1__ - O a , r W l a a ' C cl; Cooler Temp. (C) } Date / Time / / / / / A - /e tc PROJECT REQUIREMENTS Results Deadline:^ fH \ Q1 \ \ SXctAA^JT Laboratory Report Options: | j Sample results only I I Add case narrative E H Add quality control summary I I Add calibration summary I i Add raw data Other C ra b C om posite Number of C o n ta in e rs ,,r * ./s#*,-* 0 017 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f ---------- PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): - i c u / - tf/k S / .... s & ' i - b/f. / 9 t*s Phone: w - jvj. Fax: Sampler: t S Opr% i /// Project Manager (Name & E-mail Address): A ./.- .. Project Name: ^^ RO. # : V iS t V . /u. i e X r t i Quotation #: Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. K.i \ 'Sw %v-u V'?. SAMPLE ANALYSS Collection Collection ExyLIMS# Client Sample Identification Date Time ---- ~yS /'7>jZ7 " /* r -- --------- ---- -- 1Specify Matrix `iS'iC Comments M - IM c> ^ rXv-vvfi \t?, -- ^e.xx (Z A A i : .-.ti u -.r o u t v Relinquished by Date Time A VKCA,OvrrY\\71 ( Cdkr-x NlwlQ-k 1 t *! I H U IN O R M A i l O I J 000134 Cooler ID # ________ Received by Cooler Temp. (C) Date Time tA UKt' O i ls I PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative f~ l Add quality control summary 0 Add calibration summary 1 I Add raw data 0 Other APPENDIX G LABORATORY ANALYTICAL DATA REPORTS DRY RUN LANDFILL 000135 Analytical Results Dry Run Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) DRL-W -Stream Sampling Point #2 D R L-W -S tream Sam pling Point #1 DRL-Z-Property Boundary D R L-Z-DRLeachate Upper Pond Inlet DRL-Z-Pond Underdrain DRL-K-EQBLK-2 D R L-W -O utlet 001 29200 1630 3800 704000 38800 NQ 81700 Lim it of Detection (LOD) fo r the procedure is appoxim ately 10 ng/L Lim it of Q uantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Com pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000136 3058 Research Drive .State College, PA 16801, USA L i : 814.272.1039 ILF:ex8y1g4e.2n3.c1o.m1580 Proven Results. RC H Analytical Results Dry Run Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) D R L-G -D R M W 21B D R L-G -D R M W 21A D R L-G -D R M W 6A D R L-G -D R M W 12 D R L-G -D R M W 12A D R L-G -D R M W 12B D R L-G -D R M W 13 D R L-G -D R M W 13A D R L-G _D R M W 12B -2 DRL-K-EQBLK-3 NQ 270 1130 109 181 258 20900 6660 242 ND Lim it of Detection (LOD) for the procedure is appoxim ately 10 ng/L Lim it of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LCD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000137 ,3058 Research Drive |State College, PA 16801, USA | T: 814.272.1039 & .F : 814.231.1580 TM se Research. Proven Results. RC H Analytical Results Dry Run Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) D R L-G -D R M W 14 D R L-G -D R M W 15 NQ 4920 Limit o f Detection (LOD) fo r the procedure is appoxim ately 10 ng/L Limit o f Q uantitation (LOQ) fo r the procedure is 50 ng/L ND - Compound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0009 000138 3058 Research Drive ^.State College, PA 16801, USA T. 814.272.T039 F: 814.231.1580 exygen.com Precise Research. Proven Results. RCH Analytical Results Dry Run Landfill C8 Sampling 10/02 DuPont Sample Identification APFO (ng/L) D R L-G -D R M W 16B D R L-G -D R M W 17B D R L-G -D R M W 18B D R L-G -D R M W 19B D R L-G -D R M W 20B DRL-K-EQBLK-4 DRL-K-EQBLK-5 NQ 155 ND NQ NQ NQ NQ Limit of Detection (LOD) fo r the procedure is appoxim ately 10 ng/L Limit o f Q uantitation (LOQ) for the procedure is 50 ng/L ND - Com pound not detected NQ - C om pound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sam ple and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less tnan 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sam ple and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0Q7 000139 3058 Research Drive LSfcate College, PA 16801, USA T : 814.272.1039 ' f: 814.231.1580 exygen.com APPENDIX H CHAIN-OF-CUSTODY RECORDS DRY RUN LANDFILL 000140 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive 4 State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.com P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): _______ P >cx y l -\ ____ As ' Phone: Fax: .A iC X /X - v t / , & ~~ & f St X M / 9 09_______ Sampler: ^ c X t c v i Ou (-Vv\V ;V! nv--> Project Manager (Name & E-mail Address): ______________f o t t (C f f o v g * . _________________________ _______ fa (r t-u*-ef . >, Project Name: ___________S B RO. S Quotation #: 4 S - tjS ' /< o i y a / c l ~ _____________ /tHiy t-A---- yd'."-. ! . ,, ? i Please fill out this form com pletely to ensure correct analysts and proper handling of your samples. S ' x? . K . E x y L IM S # C lie n t Sam ple Id e n tific a tio n Collection Collection Date Time L j j r s t - i P / l - lAJ - *P- y .3 o s L9 D / L ~ <a j - / AOQ.-i U \ 0 5 ? L 3 ? r5C S 0/1 - ^ -/W v /i h tA J s o f6sU U HO a f i r s t -1 9/CC~e~pU *iJ^the--uUj/&^o*s i o ap f,. B 5 |frgo-f ,K . L 3 J "> & X r j / L - g-- P csif n / - e r jlr * t * n D /L - K - z. iO>30-tVj i3 X X I A li IJCt" Of il V (n\X)or H js X jua.Em Ec =O z u Specify Matrix *2_ <?> C om m ents HSX/9, V S S Z i C,HSSz i CeHf/fa 6?HSnCo . *- e* H S r i $ , c ~ H ? r i i &LI 5 n S H S i i i r H ? / g ! f /, y y V- t s X^>Hl9f XVbHZo >t N 0 si t' ' M% X N. 4 V Vy yK 2L Xl y y Ai OA o o >o Q ;r r S ? (sp C C o oler ID # C o o ler Tem p. (C) # 7 PROJECT REQUIREMENTS Results Deadline: 000141 Laboratory Report Options: I | Sample results only I I Add case narrative [H Add quality control summary I I Add calibration summary I I Add raw data 0 O t h e r ___________  I f '1 ' I CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RCH Exygen Research Sample Receiving 8 3 1 1 7 Research Drive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 8 exygenresearch.co m P a g e ______ o f PROJECT INFORMATION Client (name &address): Project Manager (Name & E-mail Address): If bi *1 *4?, . . . , -A-..-.-.!/ f/.k- h /J , Z-,-.,.- //? /VvV- A'* - . h~ e....*, 'I--'/--I.,... To: A / /'>rV.," Project Name: Phone: ... y j - / 'h r Cy y ,/, u y ,, Fax: RO. f t : ' (>/ /,/.,, ^t'/: ~k'c>'v? Sampler: L..rr'YWw. 9-, ( a IriuX-U \ Quotation #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. ANALYSES REQUESTED v * % \ k i a h t 1 :L .s... .h i A .b E x y U M S # C lie n t Sam ple Id e n tific a tio n Lam i Collection Collection Date Time \ 6 0J, o o_ E uo X Specify Matrix C o m m e n t s 'r a jL CD C, *.J I -U i I r . i i H n V Relinquished by S V v ^ f a k - d c t v v , j J i . --f ~ j x * * ----- *"-------- cMi sn< inFORMATION D ate T im e W 'JtJ-f/ J I` \ r c A'vvr-n. C o oler ID # R eceived by / / $ C o o ler Tem p. (C) a * D ate T im e te a } i.A I> U D F >-! \ $ YeAtNflWcuQ\<-' 000142 PROJECT REQUIREMENTS Results Deadline: AA -y K-'Via?c! f; <k rv f Laboratory Report Options: Q Sample results only I j Add case narrative CD Add quality control summary I I Add calibration summary I I Add raw data CDOther PROJECT INFORMATION CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ ANALYSES REQUESTED 0-4 O o Relinquished by Date '?K' < U' oicxYVl H \(bih~ t * Time \<?CrG Cooler ID # C Received by * Hiir.H INFORMATION ,_____________________________ t e V y ^ v A ^ c , LAB USE ONIY ^ 3 Cooler Temp. (C) Q- Date Time o->- / j. 9 000143 PROJECT REQUIREMENTS Results Deadline: /W ^V tocN Laboratory Report Options: Q 3 Sam ple results only I I A dd case narrative I I Add- quality control sum m ary I 1A d d calibration sum m ary I I Add raw data O ther CHAIN O F CUSTODY/ANALYSIS REQUEST FORM RESEARCH Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive " State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m Page____ o f_____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): A 0 L i' <"> M s /i/J, \s /'A/--'*. " // > , . , * . . . .4 s s ,?f / v / /' , Z1) A; S * .'#-* . -, /h . A l-, Q x s # , Project Name: A .... Phone: 'gv> - j - f j - / U r Fax: Sampler: L * T ~ : Ytws. ' h , C o .\A \aA L A ! R O .# : -t'J ytW Quotation #: A4 >>v >? Please fill out this form completely to ensure correct analysis and proper handling of your samples. s /'iiVtCLi; w - , !5i ExyLIMS# Client Sample Identification L U K s . h JL <T', LS 'H H r ':L t u A 'h~.' A i Lz h * s~ hSi- ( b%ih-v i A /) L u ^ t s 6 hSL- > ig s m r 7 & ' - t S L itH f' S bs i Q /yU y t A / J S'^;l-, /--! Sjt r '~ ( L - b * M Collection Collection Date Time l\;|<7?|o % i l 4 > A-. \2>3k A % ms i 2 0).h -Q tC Z3 UO Specify Matrix Comments W f^ i / &c<' * - f t ' S ) S" v'Cs a>/ vs -/ / `/X-s-$>.>. YSrpr/ vr& i L, --/ r r i>V / - r M V r / .A-^y ' ' `y r /*>y - fkWA VS V "U. 4 _L V I 't -i 'k Y; *5\j \VC sV 's . ro N-O y.s i s 2d 7J 2Y ?*r y .i h- 2a o a OF; CUSTODY Relinquished by rh \A T ,/ - nv.fc>H. Date Time lo jSoWlu-.i OTHfc'tt INFiTivMATION \a RtVV'-i> - | ` | Cooler ID # #*'& >// Received by Cooler Temp. (C) g>.. Date Time LAU SUA . ( i~. U ,.sVL S t \t O ^ 4 v.A- CU-h 000144 PROJECT REQUIREMENTS Results Deadline: HA stW . ^ Laboratory Report Options: [~~1 Sample results only I I Add case narrative CH Add quality control summary I I Add calibration summary I I Add raw data Other r CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): A b & f t /9 ,--7 ^ --i // t/ xsTM, J s / -- .'- j f i j / X f ' W Lt Phone: Fax: tS., . f y j ' Sampler: U . T H W a P* (ViJbAmjCJUl Project Manager (Name & E-mail Address): / I , /&:- A i /./ft. Project Name: 'g RO. # : L - e 'e # . / / v s * Q u o ta tio n # : / X - Please fill out this form c o m p l e t e l y to ensure correct analysis and proper handling of your samples. G rab C om posite Number of C o n ta in e rs SAMPLE ANALYSIS Collection Collection ExyLIMS# Client Sample Identification Date Time U 2>& 9 - I - 4 M i a i'3 & o X L ' U te> Ai?L -~ -V l o- jt a 1if i H b ' O X Specify Matrix / ii. /t --1 Comments .L V j c, /i> / y j ^ r / tKi V\ ' { >. :k i rX ,xy K VT: K;4 H s \ v- 'X ~n X 2 .r x r So i I.AR USE OMIY Relinquished by Date V "Nu riA A fi/irV V l T l cOYo-v-v-,, Time i<?ro Cooler ID # Received by OTHER INFORMa HOH I All IK;. O iil V' it 3 Cooler Temp. (C) Q.U Date Time / H.-A 000145 PROJECT REQUIREMENTS Results Deadline: \/s\e fcwcA cf. Laboratory Report Options: I | Sample results only F I Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data 0 Other_________________ I II' CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 ` exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): ___ n w g a 1 /7 r r-i A th!/4 j > t / 1 J/S .e/1 /< -// Phone: sVM' v 9j ' A1 9.f Fax: Sampler: U C 'T S\ - W n . On rL u t> k Project Manager (Name & E-mail Address): _______ A t. t _________________ A i, e./ j / 0 Project Name: c .j - , - . - A s > / 0___________________ < y RO. # : _ - r i'e A /&. Quotation #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. C AMPLE ANALYSIS ExyLIMS# Client Sample Identification L jim tL C L - 6 - / `i `s e t - G '7 Kr' ' L 7191 cc to LI 7U9H L JJtStzSL C I2 H L d u m .-i /.A rh h r L e e a 'H . _k. L C- - /C- <rr(DALA- 2 D R L - ( \~ A ^ v\o \4- d 1AB USE OM1.Y Collection Collection late; Time 5pt LM E E s srva A * 3 L U?ip o m.E a . jq E Ec uo z3 uO Specify M atrix Comments V / 7A ) / tsf-/ 9/ h'/ >:fP / /7 ,-v -} / Cvr y j '.r v / ~>s.y / I `'t "j 9J~ 0 -// ? >y yy J 6 it'/ 7 / / -e r '7 A jH n i f vxc\ktAi SIG o i T j s o W c DF CI.fSTODY Relinquished by D^te . Time <"' U KCa A.rli'A0/t /l . n 1Oieru >rd i5 /o a 1T O O 1/ Cooler ID # k t ! (WOOL7 Received,\d // ........................... / --------------------- Cooler Temp. (C) <3. 7 Date /a / / Time OTHER INFORMATION !.AB USE ONLY 000146 $ x. X If N l {% I- X kk K< XX Au J * CD /9 O i.jf LL [C . L i 9 ,i~ ->tr 7 .9 t PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary 0 Add calibration summary 0 Add raw data 0 O ther_________________ t` W . RESEARCH CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving * 3 1 1 7 Research D rive 4 State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.com P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): Project Manager (Name & E-mail Address): M u .-, # / * % / ' 6i.J, ? ') / s /-5c r f / ,/V Y H, ,t`v i , r - * d i ( A --(Sfr. . c . t .'-, u tut / w e r Project Name: Phone: .> lj - u i.v ( -Y C . , 0 , ' / T ) . ; Fax: Sampler: L < C<xk\ 1 RO. # : / T v - - w \'et Quotation # : ^ ',Kz>y\> Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. \s, m \ SAMPLE ANALYSIS E x y U M S # C lien t S am ple Id e n tific a tio n U ^ l )u^i cS hi'/b-'/ /? Collection Collection Date Time O T O o CL ..EId E Ec uo 3 o H U Specify Matrix C om m ents &VJTn / L// Vi~>}, \\ r-o \-- T, o C.._) L A O Ii:"i O r l i I rf IM-sirasbiri,In,^,,i (Jf rUST R elinquished by D ate . \a Cx a x W M n i Q '-k r ^ . i/ t T im e l\ & f> OTHER INFORMATION ~oA t C o oler ID R eceived by C o o le r Tem p. (C) & D ate T im e 1.ABUSECh'-ILV \ ^ jL^ -O A t'o k if v 000147 PROJECT REQUIREMENTS Results Deadline:. Laboratory Report Options: | | Sample results only 0 Add case narrative 1 I Add quality control summary I I Add calibration summary Cl Add raw data I I Other m\ 3-0'; CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 3 1 1 7 Research D rive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): 'V / i n / /i?/,;/,, AS -j f- /W rz ., / w . - Phone: i , - s 9 a- / t U Fax: , Sampler: L :T*" V W (T ^ Project Manager (Name & E-mail Address): /*?-/*. / i / C J . U , A 4,;,;:., P ^ Project Name: * m <&*" ?/l*~ C ? s (S* ) & / o t RO. # : C iiT J l cT aa? Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. * * \ 1, -7 -V T` V.I \ C ra b C om posite Number of C o n ta in e rs / V ' -V' ^ ? SAMPLE ANALYSiS ExyLIMS# Client Sample Identification h ru ix Collection Collection Date Time C/[,V)c5 {1 MiO S Specify M atrix X Comments 1 "\1 r "V O O LA US ONI.Y CHAIN O CUSTODY R elinquished by D it d i= T \. D ate \$ fa I1 T im e Ift3> 0 C o o le r ID # C - # j m t f o R eceived by C o o ler Tem p. (C) D ate T im e S //j^ L / LA USti ONLY 000148 PROJECT REQUIREMENTS Results Deadline: rv\ i>.Mngxl -J Laboratory Report Options: l~ l Sample results only I I Add case narrative I I Add quality control summary I I Add calibration summary CD Add raw data I I Other 1I I CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving * 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f PROJECT INFORMATION Client (name & address): Project Manager (Name &E-mail Address): "/Ssy ^ ,Af - A-&:. /?/.a/ / >. /A, c., a . >/M ' /^.r Project Name: Phone: ' J o * s t A - ' /sir C $ / o / aa Fax: RO. #: .< r fo - c v^ *e.L... (v ,, Sampler: it; 1W- V> .(filrLwid } Q u o ta tio n # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. G rab C om posite Number of C ontainers SAMPLE ANALYSIS Collection Collection ExyLIMS# Client Sample Identification Date Time U iu ii h f? ( M b tf/h K '/M - io j-.j il.-. I' ` Specify Matrix Comments J. />vr r ? / t v r /& i ANALYSES REQUESTED t. A 1 &f \ N $ v "i -V \ k ' N -Y V ^ 'V i lx r-' Jo. i AB USE ONLY te- Re inq uish ed by \ i f , , r A r iT V in J - t k u / \7 D ate , T im e it o x / o a DINER INFORMATION C o oler ID # R eceived by C t # tw & g C o o le r T em p. (C) 0 , 6 D ate T im e LAB ONLY 000149 PROJECT REQUIREMENTS Results Deadline: . , Laboratory Report Options: Q Sample results only F I Add case narrative I I Add quality control summary I I Add calibration summary I ! Add raw data HD Other____________ CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sam ple Receiving 8 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 8 exygenresearch.co m Page______ o f _______ 000150 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): n h 'O i'lf t.-j- - r 'H >" d /J * U'? 6 . . , . 676 A ' r A "/ C , /); / O'-- > Phone: ' . ?*> /, Fax: Sampler: U ' J, FYoject Manager (Name & E-mail Address): *i, u , 4 A \ ts.it .,</ , A i F3roject Name: <-</* .. r 1 t o . # : t CS <Quotation # : ., /&/>:* .7,/ . A Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. G rab C om posite _________________________ Number of C ontainers SAMPLE ANALYSIS ExyLIMS# Client Sample Identification L n c -r i i /VX;^ ^ A A'*Af'6 - ' j't Collection Collection Date Time *1 1 K Specify Matrix Comments JL. O r i,/ a / 6 r&/(T X f 1, `4 'T. 1 V V -s, T; '1 A y .`- V.VN \ Xi >* ! A B U C O NLY CHAIN OF CUSTODY Relinquished by \ Date Time M >( aa O r b il i t ky^W TTY u.j okjo:. 1m o C o o ler ID # / '/ e i i 'o // > Received by C o oler Tem p. (C) 0 , 6 Date Time de>/<)A#^ OTHER INFORMATION I A l . w - .l Gt-Ji-V t. c_. \ c W u a ' c \ c eoo is i PROJECT REQUIREMENTS Results Deadline: tV \ yJAnsCfl Laboratory Report Options: n Sample results only I I Add case narrative I I Add quality control summary Q Add calibration summary I I Add raw data I I Other_______ ___ Telephone/ Com m unications Log Company Nam e and Address: Protocol Number: U . /k /f M ______ L'--J` . t>-- / 9 ------ _________________ J 2 - r z - f o r t Name o f Person: , Ab A C CO / Q Originator: a Exygen Sponsor Exygen Study Number: L J f7 '7 ~ J Date: _______ / o f i j f c ^ Time: ________ L C L ~ t C \ a J C K - 3 u - u t i L c L -K - c d ttf-H b *c + h /-e j A sf -M -e e '/ > *~ i`4+-*s&f <=-~ A * r4 C ~r~A ^ . s4 t /t^ i k k& 5~*ttJ 4* -'T-e tcle-fP * P & r-* tn*,- /* * i t f - l r ._______________________________________ Signature: Date: ~ /tr 6 * 0028 xSmistai3058 Research Drive State College, PA 1 6 80 1, USA V T: 8002813219 F: 8 1 4 .2 7 2 .1 0 1 9 exygenresearch.com 000152 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3 1 1 7 Research D rive * State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 F: 8 1 4 .2 3 1 .1 5 8 0 exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): t \ M YCCfft'.--'. t-j - Us Phone: .Y/-.4 ,>-i / . . , c:. ^ / ? / / / / f v if y %-j . y j j - / y Fax: Sampler: Project Manager (Name & E-mail Address): A sAc Project Name: /y P.O. # : '-/Xft Quotation # : 5 (r ' -J / ( t X A,/<..< M * Please fill out this form completely to ensure correct analysis and proper handling of your samples. 'V % *Y X' Y: Y ,nMPI..E ANALYSIS E xyL IM S # C lien t Sam ple Id e n tific a tio n Collection Collection Date Time UiXl- )> ? L - k - rZ VH a ii o - -(0 EC z3 uO Specify Matrix C om m ents M"2 2 . Nj X. Y CO 4 --- V p,/ O ) I ftB U S E O N l.V { SA i f CUSTODY R elinquished b y / i < . D ate , T im e x o j m 3 ) Vj l S O C o o ler ID # -A ffevv i / o R eceived by C o o ler Tem p. (C) D ate T im e OTHER INFORMATION I.AB USE OHLV Y . 1f c t i r O ^ L . t\ \ ^ Y i.L tv re .-o x k i t . . _______o o o i - s a PROJECT REQUIREMENTS Results Deadline: A/\ o-jtUgdi i Laboratory Report Options: | | Sample results only I I Add case narrative 0 Add quality control summary n Add calibration summary 1 IAdd raw data 0 Other 1 CHAIN O F CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving ` 3 1 1 7 Research Drive State College, PA 1 6 8 0 1 , USA T: 8 1 4 .2 3 1 .8 0 3 2 * F: 8 1 4 .2 3 1 .1 5 8 0 * exygenresearch.co m P a g e ______ o f _______ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): il / ,, Phone: Fax: Sampler: 6!.L. j'y Y,.-.,.... /Ar je SV* ....... . (> /Y/-0 V _W -cf-yj /; y,F L ' T \ \'\stva_ 1^, . i. ci L(\l iY'Di Project Manager (Name & E-mail Address): *"i./(,,___ l>. Project Name: ____________ C > 5 RO. # : 'Vv Quotation # : p-U Stf n if, /<- / f j - _____ >c> Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. Y. V T; Y SANIP! Y8 i ExyUMS# Client Sample Identification L21 711-7 h n 'L- Collection Collection Date Time Oa _n nj E E o 3O u Z U Specify M atrix xfojoT) I M t'V'C) Comments Hrp-ar-fec. ^4 4 M T Z * `. . A V*""* o O' l.A U S E O N L Y CHAIN OF CUSTODY Relinquished by Date Time X YL O u C d O V i n 1 ' u c /o H in t ( tv * Cooler ID # /e'<.u^ r/o Received by Cooler Temp. (C) _f^_ Date Time X v/ j&u. OTHER INFORMATION I. A U U S E O N I V C <* c A f e W . v u l 000154 PROJECT REQUIREMENTS Results Deadline: , Laboratory Report Options: | 1Sample results only I I Add case narrative I I Add quality control summary EH Add calibration summary EHAdd raw data n Other