Document MJ3JqZnMg03XZB2KBkvJz90Za

Engineers Ptonners Economists Scientists AR226-2428 April t2, 19&3 LM635216.XX Mr. Roger Zipfal Dupont ParkfiKaburg Dupont Road (Highway 892) Washington, West Virginia 26181 KSt analytical Data for JMQ Laboratory Reference No. 24340 Dear Mr. zipteli On March 29, 1983, the CH2M HIM. Montgomery Laboratoty (WB) teeeived fifteen Baoplsa witb a request for analysis of selected organic parameteta. AS you ara awarer saaple 24340012 arrivad broken. The ftny aunnuasluyatilcaaliffriecsuullttisoaandsnacosusnotceiBaatedd dquurianlgitythecoanntarolylSdiBataotayreouernacalotaspeldes. ara diBOus86d in the case narrative. Under CB2M HXXA policy, have your sainplee not given us will b6 Btored for prior instructions up to 30 days for disposal, after we will If reporting. if contact you you any Baift&lea require disposal aa naaardoue wast. If if CyoHU2MK HaInISa>lyIitaitcoaolranteoerdiess aagpapine.eciatfeyyoouuxs- hbouuflldinehaaaveanadnyloqoukesftoiorwnsardcotnocesrenrinvgingthe data, or you need additional information, please call- Sincerely, UlouJi^ o?. OA^ wanda !. Hall Data package gupervieor Bneleaures W2MHILL Quality Anatyt'WllLaboratories S567FairlaneOrive. P.O.Box 23051S. Montgomery. Alabam9361 IB 205.271.^44 EID941040 'EBBUS OF covrsssrss rjr?M HXEI. Ixtboratory Kef. Bo. 24727 Page Ko., I.is-b of Organl.c Data Qualifiers ......................................... a. List of Sample ID Qualifiers ........................................... ii Client Sample Cross--Reference ......................................... iii. PC-143 DATA 1 case Narrative .................................................... 3 Sample Results .................................................... 13 Blank Results .................................................... 16 HS/MSD KesultB ................................................... 18 Copy of COC Documentation .............................................. CH2MHIUL OuaSUy Analytical Laboratories 25G7Fairlane Drive. P.O. Bw230S48. Montgomery.Atabama361 IS 205371.W4 EID939358 ORGANIC DSia. COM-IKCEBS n -- indicates the compound was analyzed for but not detected. The number adjacent to the "0" qualifier indicates the reporting limit for that compound. The reporting limit can vary from sample to sample depending on dilution factors or percent moisture adjustment when indicated. It j -- Indicates an estimated value. is used when the data indicates -the presence of a compound below the stated reporting limit. C -- This flag applies to GC pesticide results only. The "C" flag indicates the presence of this compound-has been confirmed by GC/MS analysis. (This definition is still being reviewed and discussed) . B -- This flag is used when the analyte is found in the associated blank as well as the sample. This notation indicates possible blank contamination and suggests the data user evaluate these compounds and their amounts carefully. E -- This qualifier indicates that the value reported exceeds the linear calibration range for that compound. Therefore, the sample should, be reanalyzed at an appropriate dilution. The "E" qualified amount is an estimated concentration, and the results of the dilution will be reported on a separate Form I. D -- This qualifier indicates compounds which have been identified during a diluted reanalysis. "D" qualifiers are used for samples that have been analyzed initially at a lesser dilution than required for accurate quantitation. -- This qualifier indicates that the response for the compound exceeded the linear range of the instrument. Therefore, this is an estimated concentration. "P -- This qualifier is used for a pesticide/Aroclor target analyte when there is greater than 25t difference for detected concentrations between the two GC columns. The lower of the two values is reported on Form I and flagged with a "P". M -- This qualifier indicates presumptive evidence of a compound. This flag is only used for tentatively identified compounds, where the identification is based on a mass spectral library search. Xt is applied to all TIC results. For generic characterization of a, TIC, such as chlorinated hydrocarbon, the "M" qualifier is not ttsed. A -- This qualifier indicates that a TIC is a suspected aldol-condenaation product. CH2MHIU, Quality Analytical Laboratories 2S67FairlaneOrive.P.O. Box230548, Montgomery. Alabama 36116 205.27t.M44 EID939359 DRGBHTC TAB SKtSPVE ID QnKLIPTERS The qualifiers that nay be appended to the I>ab Sample ID for organic analyses axe defined below; DI. -- R -- BS -- MS -- USD -- Dilution Run. Indicates the sample contained compounds exceeding the calibration range. The sample was diluted, and reanalyzed- Both results are reported. Rerun. The sample was reanalyzed. sample was also re-extracted. The "E." is not used if the Re-extraction Analysis. reanalyzed. The sample was re-extracted and Matrix Spike (may be followed by a digit to indicate multiple matrix spikea within a sample set) Matrix Spike Duplicate {may be followed by a digit to indicate multiple matrix spike duplicates within a sample set) CH2MHIUL OuaSty Analytical Laboratories ii 2567FairtaneDnve, P.O. Box230543, Montgomery. Alabama 36116 205.271.1444 EID939360 CLIENT SMELE CHOSS-BEPKBBHCK rargM prr.T. laboratory Ref. Bo. 24727 LHG Sample ID 24727001 24727002 24727003 24727004 : 24727005 Client Sample ID CENTB&I. STREAM I^&CH&TE' WEST STREAM HBtL 11 T.W. 25 CH2MH;U. QuaSty Analytical Laboiatoiies iii SS67FairtaneDrive.P.O.Bw23054B. Montgomery. AtabamaSS116 205.271.1444 EID939361 CftSE NARRATIVE GC fC-143 SAMPI.ES IABORATORX : CH2M HIIA LABORATORIES CSSE NO. i IAB REP- NO.s H/A 24727 CLIENT; DOPOHT COMTRACT NO.: N/A SDG HO.s N/A I. RECEIPT A. Date; May 20, 1993 B. Sample Information IAB SAMPLE ID CLIENT SAMPLE ID SBMPLE T-MLTABiT-KPOJ-TAY 24727001 24727001BE 24727002 24727002KE 24727003 24727003BE 24727004 24727004RE 24727005 24727005BE W05243B1 W05243B2 W)6013B1 CEHTKLSTBEaM CEl.n'RI.STKBaM RE laACHATE ISACHATE BE TOiST STKE&M WEST. STREAM BE flEI.L.fl. WEI.L1 KB T.W-25 T.W.25 BE QC BIAHK 1 QC BIAHK 2 QC BrAHK 3 WATER 'WATER WATER HATER WATER WATER WATER WATER WATER WATER WATER WATER WATER DATE SAHPI.ED EXTRACTIOH DATE 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 N/A K/A H/A 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 05/24/93 06/01/93 AMALYSIS DATE 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 05/28/93 06/03/93 C. Docume'atatei.on Exceptions : Mo exceptions were encountered. II. EXTRACTION A. Holding tineas Holding tiroes'were met for all original extractions. However, re-extracfcionB wece performed beyond the 7- day holding time. CHSMHILI- Ouality Analytical Laboratories ZSGTFairianeDrive.P.O. Box23Q54a Montgomery. Wabama361 IS 000001 20S.271.1444 EID939362 fC-143 TAB KEF- 130. 24727 PAGE 2 B. Extraction Exceptions All field samples were re-extracted to Investigate low spike recoveries in the original extractions. Smaller aliguota were used. for the re-extractions to provide more insurance that surrogates would not be diluted out. II J. ANALYSIS Mo other exceptions were encountered. A. . Holding times; All holding tines were met. B. Analytical Exceptions Several samples were diluted to prevent 'EC-3.43 from exceeding the calibration range. Both the original and the re-extractions are reported since the re work was performed beyond the extraction holding time . No other exceptions were encountered. IV. ODKLItY CONTROI. A. Hethod Blank : PC-143 was not present in any of the laboratory blanks. B. Surrogate Recoveries s All samples were re-extracted and reanalyzed as a corrective action for poor spike recoveries observed in the original work.. C. Matrix Spiks Results All re-extracted samples met acceptable.QC limits. Matrix spike results have been reported with this contract along with the laboratory control sample (blank spike) results. The analytical system was not in control for original extractions performed on 05/24/93. Spike recoveries were back. to normal for the re-extractions performed on 06/01/93. V. X certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data packa9e has been au-thorized by -the I,aboratory Manager or Mf desginee, as verified by the following signature. - CH2MHIU. ^oewell Smiley GC Supervisor 0^/>^-S Date OuaSty AnalyScalLaboratories 2567Fa5rtanBDme.P.O.Box230548. Montgomery. Alat>ama36116 000002 205^71.1444 EID939363 ORQMUCS AMM.YSIS DATA SHEET ^aboratory Name; CH2M HIIJ./MSM lab Sample ID: 24727001 Client Sample XD: CSRTRI STREBM Concentration: Sample Matrix: Percent Moisture: PC-143 LOW WMCER ____ Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution Factor: -20 3825-26-1 FC-143 26 Perfluorononanoic acid - SS Perfluorodecanoic acid - SS HH-Eicosafluoroundecanoic acid - SS HD I MD t " KD H - Analyzed- for- but not detected. J - Present," concentration estimated. B - Detected in QC blank. SS - Surrogate ^.Standard reported as percent recovery. Cotnrnents; Surrogates were not determined due to the Xarge dilution required for analysis. Form X ;--?-a-... -: CH2MHWJL duality Analytical Laboratories 2567FalrtaneDrive.P.O.BoxZ3054S. Montgomery. Alabama 36116 000003 2053:71.1444 EID939364 ORGMtTCS AKAT.YSIS DATA SHEET xiaboratory Haae: CH2M HHJ./MGM Iiato Sample ID; 24727001BE Client Sample ID: CEHTKL STREAM Concentration: IiOT Sample laatrix: 'WM Percent MoiBture: PC-143 Date Extracted: 06/01/93 Date Analyzed; 06/03/93 Dilution Factor: 5.0 CAS Minriber 382P-''C-i PC-143 . . . . . Perfluorononanoic acid - S3 Perfluorodecanoic acid - SS llH-Eicoeafluoroundecanoic acid - nci/Ii. 37 70 t 50 t SS 42 If U - .Analyzed for but not detected- ff - Present/ concentration estimated. B - Detected in QC blank. SS - Surrogate Standard' reported as. percent recovery. Comments; This is a re-extraction of sample 24727001 to investigate low surrogate recovery from the original extraction. Only 50 mL were extracted rather than the usual 1000 tfL due to the esqpected high concentration of PC-143. Form X CHZMHILL Quality Analytical Laboratories 25S7FairtaneDme. P.O. Box230548. Mont<jomery,AIabama3G116 I o\-> 00 -- 000004 205.277.1444 EID939365 ORGXHICS AHMiYSIS DATA SHEET -jaboratory Mane: CH2M HIU./MGM Lab Sample XD: 24727002 Client San^le ID: LgftCHATE Concentration: Sample Matrix; Percent Moist-are: PC-143 " LOW WATER ____ Date Extracted: 05/24/93 Date Analyzed.: 05/28/93 Dilution Factor: 20 CflS Humber, 3825-26-1 PC-143 Perfluorononanoic acid - SS Perrluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - ucr/L 17 HD 1r ND t BS ND t U - Analyzed for but not detected. >T - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standaxd reported as percent recovery,. Comments; Surrogates were not determined due to the large dilution required for analysis. Form T CH2MH1H. Otiality Analytical Laboratories 2567Farfane Drive. P.O. Box 230548, Montgomery. Alabama36116 EID939366 ORGMIICS AHM.YSTS DATA SHKBT ^aboratory Haane; CH2M HIU./MGM lab Sample ID: 24727002RB Client Sample ID: IBACHftTB Concentration: LOW Sample Matrix: WATER Percent Moisture: FC-143 Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor; 5.0 CAS number ucr/l. ......... 3825-26-1 FC-143 Perfluorononanoic acid - SS Perfluorodecanoic acid - SS - HH-Bicosafluoroundecanoic acid - SS 3B 63 78 t 60 % U - Analyzed tor but not detected. 3 - Present," concentration estimated. B - Detected in QC blank, SS - Surrogate Standard reported as percent recovery. Comments; This is a re-extraction of sample 24727002 to investigate low surrogate recovery from the original extraction. Only 50 tHI were extracted rather than the usual 1000 inli due to the expected high concentration'of PC-143. Pom I CH2MHIU. duality Analytical Laboratories 25S7Fairtane Drive. P.O. Box230548. Montgomery. Alabama 36116 000006 Z05.Z71.1444 EID939367 ORGANXeS ASM.YSZS DATA SHEET laboratory Name: Lab Sample IDi CH2M HIIJ./MGM 24727003 Client Sample ID: WEST STREAM Concentration: Sanqple Matriac: Percent Moisture: PC-143 V3VI 'HKTBI ___ Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution Factor; ___5.0 CRS number uq/I 3825-26-1 PC-143 3.2 Perfluorononanoic acid - SS 'Perfluorodecarioic acid - SS llH-Eicosailuoroundecanoic acid - SS 25 IT 27 ^ ' 27 I V - Analyzed for but not detected. J - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. Comments; Form I CHZMHIiL Quality Anatyfical Laboratories 2SB7FairianeDrive. P.O. Box23054B. Montgomery. Alabama36f 16 EID939368 ORG&HICS AHH.YSIS DATA SHEET Laboratory Name; CH2M HIU./MGM Lab Sample ID: 24727003RB Client Sample XT); WEST STREKM Concentration: .lOW Sample Matrix: WRTER Percent Moisture: ____ PC-143 Date Extracted: 06/01/93 Date Analyzed.: 06/03/93 Dilution Factor; 5.0 CM Number 3825-26-1 PC-143 Perfluorononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicosafluorotinctecanoic acid - uq/I 11 102 66 I SS 62 0 - Analyzed for but not detected- T - Present,, concentration estimated. B - Detected in QC blank. S3 - Surrogate Standard reported aa percent recovery. Comments: This is a re-extraction of sample 24727003 to investigate low surro9ate recovery from the original extraction. Only 200 n>I were extracted rather than the usual 1000 IBLL due to the expected high concentration of FC-143. Form I CH2MHILL OtiaSty Analytical Laboratories o -A oo\ V> 2S67FairtaneDriveJ'.0. Box23054a. Montgomery, ftlabama36116 000008 205.271.1444 EID939369 ORQAHICS AHM.YSIS DATA SHEET .jaboratoxy Name: . CH2M HILI./MGM Lab Sample XD: 24727004_____ Client Sample ID; WEISMI. ____ Concentration: Sample Matrix; Percent Moisture: PC-143 IiQW WATER _____ Date Extracted: 05/24/93 Date Analyzed; 05/28/93 Dilution Factor: ____1.0 CRS Uumber _______________.__________tiq/Ii ......... 3825-26-1 PC-143 Eerfluorononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicbeafluoroundecanoic acid - 0.6 8 t 11 I SS 8 U - Analyzed for but not detected. J - Present," concentration estimated. B - ^Detected in QC blank. SS - Surrogate Standard-reported as percent recovery. Comments: Porm I CH2MHILL duality AnafyticaSl.abotatories 2567Fairtane>DHve.P.O.Bw23054S. Montgomery. Alabama36116 000009 20S.27f.t444 EID939370 GOEXSiCS AHALYSIS DATA SHEET jratory name: CH2M HILL/MSM ..ab Sample ID: 24727004RE client Sample ID: TO3IJ. #1 Concentration: Sample 'Matrix: Percent Moisture: PC-143 I<OW VKTER. ____ Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Yactor: ____I'.O !ftS iHoniber uq/I> 1825-26-1 PC-143 Perfluox-ononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - 2-1 67 74 % SS 61 \ n - Analyzed for but not detected. J - Present,' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. lonaments: This is a re-extraction of sample 24727004 to investigate low surrogate recovery from -Ae original extraction. Only 200 ml. were extracted rather than the usual 1000 nil. due to the .imitation of raw sample available. . Form I CH2MHIU. duality Analytical Laboratories 2567FairianeDme. P.O. Box23054S. Montgcimeiy. Alabama 36116 000010 205S71.1444 EID939371 ORGAHICS AHAMSIS DATA SHBET Laboratory Kama: CH2M HIU./MGM Lab Sangale ID: 24727005_____ Client Sample ID: T.'W.ft25_____ Concentration: Sample Matrix: Percent Moisture: EC-143 LOW WATBR _____ Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution 'Factor: 5.0 CRS Humber_______:___________________w/ti ......... 3825-26-1 PC-143 Pertluorononanoic.. acid - SB Perfluorodecanoic acid - SS llH-EicoBaflttoroundecanoic acid - 4.3 11 t 8 SS 7 % TJ - Analyzed^ for but not detected. J - Present,"' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. Comments: Form I W2MHIU. Quality Analytical Laboratories 25B7FairtanBDrive.P.O.Bat230548. Montgomery, /Uatama36116 000011 205371.1444 EID939372 ORGMITCS AHAI.YSXS DATA SHEET Laboratory Name: CH2M HIIJ./MGM Lab Sample XD; 24727005RB Client Sample ID: T.W.t25 Concentration: Sample Matrix: Percent Moisture: PC-143 MW WOTER ____ Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor; 5.0 gas Mumber 3825-26-1 PC-143 Perfluorononanoic acid - SS Perfluorodecanoic add - SS llH-Eicosafluoroundecanoic acid - ucr/I. 9.9 88 81 t SS 77 U - Analyzed for but not'detected. J - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported BB percent recovery. CcanmentB: This is a re-extraction of sample the original extraction. Only 200 rtL -were 24727005 to investigate low surrogate extracted rather than the usual 1000 recovery from mL due to the expected high concentration of FC-143. - Fonn X CH2MHIU. Qualify Analytical Laboratories 5 o >--A O-t to ^0 <-> 2567 Fairlane drive. P.O. Bw230S4S. Montgomery. Alabama 3611B 000012 205.271.t444 EID939373 OBGMICB AK&LYS1S DATA SHEET Laboratory Bane: CH2M HIU./MSM Lab Sample ID: WD5243B1_____ Client Sample ID: OC BLRHK 1 Concentration: Sample Matrix: Percent Moisture: FC-143 LOW WBTER _____ Date Extracted: Date Analyzed: Dilution factor; 05/24/93 05/28/93 1.0 3825-26-1 FC-143 Perfluorononanoic'acid - SS Perfluoroaecanoic acid - SS llH-Eicosafluoroundecanoic acid - 0.1 V 2.3 t 5 k SS 7 t TJ - Analyzed for but nofc' detected. J - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. Comments; Form I CH2MHILL OuaSitf AnatyticalLaboralortes 2567FairtaneDwe, P.O. 8ox230549. Montgomery. Mabama36^ 16 000013 2J5.27f.f444 EID939374 ORSAHICS AHM.YSIS DATA SHSBT laboratory name; CH2M HXLI./MSM I>ab Sample ID: W05243B2 Client Sample ID: OC BIAUK 2 Concentration: Sample Matrix; Percent Moisture: PC-143 low 'BKTBR _____ Date Extracted: Date Analyzed: Dilution Factor: 05/24/93 05/28/93 1.0 CAS Huniber . . . . . 3825-26-1 PC-143 Eerfluorononanoic acid - SS Eerfluorodecanoic acid - SS HH-Bicoeafluoroundecarioic acid - Tier/I. 0.1 TT 19 20 SS 17 tJ - Analyzed for but not detected. J - Present, concentration, estimated. B - Detected in QC blank.. SS - Surrogate Standard reported as percent recovery. Comments: Form I ^ :.^. CHZMHIU. duality Analytical Laboratories SSB/FairtaneDrive.P.O. Box230548. Montgomery. A/abama36116 000014 205.27T.f444 EID939375 ORGKHICS ASM.YSIS DATA SHEET Laboratory Name: .CH2M HIIJ./MGM X>ab Sample ID; W06Q13B1_____ Client Sample XD; QC BIiRHK 3 Concentration: lOW Sample Matrix; WATER Percent Moisture: _____' PC-143 Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: ' 1.0 CflS Mumper_____________________________uq/Ii .......... 3825-26-1 PC-143 Perfl-uorononanoic acid - SS 0.1 U 100 ^ PerjEluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - SS 92 77 % XT - Analyzed for- but not detected. il - Present, concentration eBtiaatedB - Detected in QC blank. BS - Surrogate Standard reported-'as percent recovery- Comments: Form I CH2MHILL Quality Analytical Laboratories 2567FairtaneDriv9,P.O.Bw<230548. hfontgomeyy. Alabama 36116 000015 205^71.1444 EID939376 FC-143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS Moratory Name: CH2MHILL/MGM Case No: 24727 Extraction (SEPF/CONT/SONC): SEPF Matrix: Water Native Sample Lab ID: Laboratory Method Blank: Compound FC-143 24727004 W05243B1 and W05243B2 Spike Added (ug/L) Sample Cone. (ug/L) 2 0.57 MS Laboratory ID: 24727M04 MSD Laboratory ID: 24727D04 MS Cone. (ug/L) 0.75 MS % Recov 9 MSD Cone. (ug/L) 0.87 MSD % .Recov 15 RPD 15 C9 - Surrogate C10 -- Surrogate 011 -- Surrogate 2 ---- 2 ------ 2 ------ 0.13 0.13 0.11,. 7 0.25 12 62 7 0.30 15 78 6 0.20 10 56 Associated Blank Spike Laboratory ID: BW052431. Compound FC-143 Spike Added (ug/L) 1 BS Cone. (ug/L) 0.21 BS % Recov 21 C9 -- Surrogate do--Surrogate C11 -- Surrogate 1 0.12 12 1 0.11 11 1 0.13 13 Comments: Only 0.5 L was extracted for the MS and for the MSD due to a limitation of raw sample available. File ID: F24727F3.WK1 Form 3 000016 EID939377 PC-143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS Laboratory Name: CH2M HILL/MGM Extraction (SERF / CONT / SONG): SEPF Case No: 24727 Matrix: Water Native Sample Lab ID: 24727001 RE Laboratory Method Blank: W06013B1 MS Laboratory ID: 24727M01 MSD Laboratory ID: 24727DOT Compound FC-143 Spike Added (ug/L) 20 Sample Cone. (ug/L) 36.6 MS Cone. (ug/L) 52.5 MS % Recov 80 MSD Cone. (ug/L) 55.7 MSD % Recov 96 RPD 6 C9 - Surrogate C10 -- Surrogate C11 -- Surrogate 20 -- 14.0 70 21.80 109 44 20 ------ 12.4 62 21.40 107 53 20 ------ 12.9 65 17.80 89 32 Associated Blank Spike Laboratory ID: BW060131 Compound FG-143 Spike Added (ug/L) 1 BS Cone. (ug/L) 0.64 BS % Recov 64 C9 - Surrogate C10 -- Surrogate C11 -- Surrogate 1 0.83 83 1 0.91 91 1 0.86 86 Comments: Only a 0.05--liter aliquot was extracted for the MS, the MSD, and 2472701 RE due to a limitation of raw sample available. File ID: F24727F3.WK1 Form 3 000017 EID939378 w WS-Hllf"- QUALITY ANALYTICAL LABORATORIES CHSMHIH.Projtct* Purchtse Order* rti-rlK. CHAIN OF CUSTODY RbGORD AND AGREEMENT TO PERFOR LAB TEST CODES l-)lJUl-H-Jl-)l-)t).LJU'l-)t-l Prcl.clH.m. OuAbHT Lt<.^-L i.frW-1 Ft 1 I ("^^IY c.-^ # Company Hinr/CHZM HILL Olllci 1 0 F projaet Manager & Phona ( Ruport copy to: WZ3. "/(.7 ^i1,1 . Dr.d Rquil<j Complellon Oqf: (y<BM Simpling Riqulnnrni* LUoyTbtoTt-^ ,C 0 N Sample Disposal: SCWA NPDES RCRA OTHER Dlipor Return A D Da a a 1 N TVpt Matrix E Sampling c 0 Ws CLIENT SAMPLE ID R 0 RA0 (9 CHARACTERS) S M Dal Till'* P B E I, n ^ S-R'TS ' / 4 5-IW ,og S'.H.l3 l/ LA, C e)y T^ M ^ \Vi ft- 1-\ I L-L L E<t eh 'I- r & 1 un a; <.l T & TR. V-ff -\ I Wi 1^ \0^ 5-RiB L.L, u c- LL 3t. 1 I/ Li T u? Tt 1 s \ ' ANALYSES REQUESTED ^^ -1\^3 ^ ? ; N c G W C f T ^ 5 s rn^y^k ^^m <^(^ SsmplEl By & TUI (HMM ilm tiri |W i>tm> RtCflVtdBy 1 (H--(jnil|liiHiil 1 i i i 1 i t DalefflW? 0-' ^'.[hasI 'y^- Dlle nima Rylljiqulshed By ^ (l<ilBnn<pilnlnnn) ^r^ ^^^A-)< <-l-b^J? HelltTquishBed7^ (PliimltnMidiilnliuiiw) Dal/Tlm < S'W ^ ; Dale/Tim HiCllVKJBy lM.l(aii<pllB>n) DilB/Tlmi RlUnqullhed By (t'limiiBnmiKiiiiimiMi- Dale/Tim a "%%^ ^J^s^" ^ Worli Aulftorl*d By ('> I(B ws nw m") / Oilta/Tlma /^.? /^/j5 Remiftui ShippedVie UPS BU3 //Tf^tdd--eExx )J Handa ""--^ oOilnheet--.. .-- ^ .,,,,..,,.,,., Shipping Instructions and Agreement Provisions on Reverse Side nisiwnicw TKSVT.'R OF COHTBHTS ca2M BEta* laboratory Kef. Ho. 24727 Page Ho.. Z.xB-fc of Organic Data Qualifiers ......................................... i. I,lBt of Sample ID Qualifiers ........................................... ii Client Saaple Cross-Reference ......................................... iii FC-143 DATA 1 Case narrative .................................................... 3 Saaple Results .................................................... 13 Blank Results .................................................... 16 MS/MSD :ResultB ................................................... 18 Copy of COC Documentation .............................................. CHZMHIUL Quality Analytical Laboratories 25e7FairlaneDrive.P.O.Boi<Z3054B, Montgomery,Alatfatna361 IS 205.27t.M44 EID939358 OBSBHIC naia. COM.IFIEBS U -- Indicates the compound was analyzed for but not detected. The number adjacent to the "0" qualifier- indicates the reporting limit for that compound. The reporting limit can vary from sample to sample depending on dilution factors or percent moisture adjustment when indicated. It J -- Indicates an estimated value. is used when the data indicates the presence of a compound below the stated reporting limit. C -- This flag applies to GC pesticide results only. The "C" flag indicates the presence of this compound-has been confirmed by GC/MS analysis. (This definition is still being reviewed and discussed). B -- This flag is used when the analyfce is found in the associated blank as , well as the sample. This notation indicates possible blank contamination and suggests the data user evaluate these compounds and their amounts carefully. B -- This qualifier indicates that the value reported exceeds the linear calibration range for'that compound. Therefore, the sample should be reanalyzed at an appropriate dilution. The "E" qualified amount is an estimated concentration, and the results of the dilution will be reported on a separate Form I- D -- This qualifier indicates compounds which have been identified during a diluted reanalysis. "D" qualifiers are used for samples that have been analyzed initially at a lesser dilution than required for accurate quantitation. * -- This qualifier indicates that the response for the compound exceeded the linear range of the instrument. Therefore, this is an estimated concentration. P -- This qualifier is used for a pesticide/Aroclor target analyte when there is greater than 25% difference for detected concentrations between the two GC columns. The lower of the two values is reported on Form I and flagged with a "P". M -- This qualifier indicates presumptive evidence of a compound. This flag is only used for tentatively identified compounds, where the identification is based on a mass spectral library search. Xt is applied to all TIC results. For generic characterization of a TIC, such ag chlorinated hydrocarbon, the "M" qualifier is not used. & -- This qualifier indicates that a TTC is a suspected aldol-condensation product - Illllll CH2MHILL duality . Analytical Laboratories i 2567FairtaneOrive.P.O.Box23054a, MontgomBry,Alabama36116 20S.271.1444 EID939359 OKGKHIC IAB SaMBtK ID QOai.IFIKRS The qualifiers that nay be appended to the I>ab Sample ID for organic analyses axe defined below; DI. -- K -- KB -- MS -- HSD -- Di.luti.on Run. Indicates the sample contained compounds exceeding the calibration range. The sample was diluted and reanalyzed. Both results are reported. Kerun. The sample was reanalyzed. sample was also re-extracted. The "R" is not uaed if the Re-extraction analysis. The sample was re-extracted and reanalyzed. Matrix Spike (nay be followed by a digit to indicate multiple matrix spikea within a sample set) Matrix Spike Duplicate (may be followed by a digit to indicate multiple matrix spike duplicates within a sample set) CH2MHIU. OuaSty Analytical Laboratories il Z5G7FwrtaneDriv(i,P.O.Bo)t230548. Montgomery. Alabama 3611S 205.271.1444 EID939360 CLIENT SSMFIK CROSS--BKPEHKHCS CB2M Trn-.t. laboratory Ref. Ho- 24727 LMG Sample ID 24727001 24727002 24727003 24727004 24727005 Client Sample IP CStlTKM. STREAM I.ES.CH&TE' WEST STREAM HBLL 1 T.W. 25 CHSMWUL. OuaSty AnatylicaHjaboratories 111. 2567Fairtane Drive. P.O. Bm23054S. Montgomery. Alabama361 T6 205.271.1444 EID939361 CASE NARRATIVE GC FC-143 SAMPLES IABOBATOBX ; CH2M HIM. "LABORATORIES CASE HO. ; H/A IAB KEF. NO.i 24727 CLIENT; DTOOHT CONTRACT IIO.s N/A SDG KO.; H/A I. RECEIPT A. Date; Hay 20, 1993 B. Sample Information IAB SAHPLE ID CLIENT SftMPI.E ID SAHPEE HB.TRIX 24727001 2472700 IRE 24727002 24727002KE 24727003 24727003BE 24727004 24727004RE 24727005 24727005BE W05243B1 W05243B2 W06013B1 CEMTBI.STBEftM CgMTKLSTBEaM BE LEACHATE LEACHA'EE BE WEST STREAM HEST. STREAM RE HEEL#1 HEIJ.1 RE T.W.25 T.W.25 KB QC BIAMK 1 QC BIAHK 2 QC BLMIK 3 WATER HATER WATER HATER HATER HATER HATER HATER HATER WATER WATER WATER WATER BATS SAMPLED EXTRACTION DATE AHAI.YSIS DATE 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 N/A N/A N/A 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 05/24/93 06/01/93 05/28/93 -06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 05/28/93 06/03/93 C. Coc'uinentatJLbn Exceptions ; Ho exceptions were encountered. II. EXTRACTION A. Holding times: HoldJuag tines were met for all original extractions. However re-extractions were performed beyond the 7day holding time. CH2MHILL duality Analytical Laboratories 2567 Fairlane Drive. P.O. BoxZ3054S. Montgomery, Atabama3611S 0 0 0 0 0 1 205.271.1444 EID939362 rc-143 IAB REP. HO. 24727 PAGE 2 B. Extraction Exceptions All .field samples were re-extracted to investigate low spike recoveries in the original extractions." Smaller alicpiots were used. for the re-extractions to provide more insurance that surrogates would not be diluted out. Ill. ANALYSIS A. ; Holding tixness Ho other exceptions were encountered. All holding times were met. B. Analytical Exceptions Several samples were diluted to prevent FC--143 from exceeding -the calibration range. Both -the original and the re--extractions are reported Bince the re work was performed beyond the extraction holding time. Mo other exceptions were encountered, iv. QUM.rrr COHTKOI. A. Hetbod Blank : PC-143 was not present in any of the laboratory blanks, B. Surrogate Recoveries : All samples were re-extracted and reanalyzed as a. corrective action for poor spike recoveries observed in the original work. c. Matrix Spike Results All re--extracted samples net acceptable .QC limits. Matrix spike results have been reported with this contract along with the laboratory control sample <bl"ank spike) results. The analytical system was not in control for original extractions performed on 05/24/93. Spike recoveries -were back to normal for the re-extractions performed on 06/01/93. V. I certify tha-t this data package ia in compliance with the terms and conditions .of the contract, both technically and for completeness, for other than -the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the laboratory Manager or hia desginee, as verified by the following signature. ^oewell Smiley GC Supervisor CX^W/^-5 Date CH2MHII.L OuaSty Analytical Laboratories ZSeHFairtaneDme. P.O. Bm230548. Montgomery. Alabama36116 000002 20SJ371.1444 EID939363 ORQAHICS ANALYSIS DATA SHEET Laboratory Name: CH2M HILI./Mtai I>ab Sample ID: 24727001 Client San^le ID: CBHTRI. STREBM Concentration: Sample Matrix: Percent Moisture: FC-143 liQW WRTBR ____ Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution Factor: 20 CAS Number 3825-26-1 FC-143 Perfluorononanoic acid - SB Perfluorodecanoic acid - SS llH-Eicosarluoroundecanoic acid - Wf/ti 25 HD t KD I SS ' HD t TT -'Analyzed, for but no.t detected. 3 - Present," concentration estimatedB - Detected in QC blank. SS - Surrogate ^Standard reported as percent recovery. Comments: Surrogates were not determined due to the large dilution required ror analysis. Form I CH2MHIU. OuaSty Analytical Laboratories Z567FaiilaneDrive, P.O. Bw230548. Montgomery. Alabama 3G116 000003 205371.1444 EID939364 ORGKSXCS AHM.YSXS DATA SHEET Laboratory Name: CH2M HIIJ./MGM Iiab Sample XD; 24727001BB Client Sample ID: CBHTBI. STREAM Concentration: Sample Matrix: Percent Moisture: PC-143 Date Extracted: 06/01/93 Date .Analyzed; 06/03/93 Dilution Factor: 5.0 CRS number 3825-2S-1 FC-143 Perfluorononanoic acid - SS Perfluorodecanoic acid - SS llH-EicoBafluoroundecanoic acid - Tier/I. 37 70 t 50 t . SS 42 U - Analyzed for but not detected. J - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard' reported as. percent recovery. Comments: This is a re-extraction the original extraction. Only 50 of sample 24727001 mL were extracted to investigate low surrogate rather than the usual 1000 recovery from ml. due to the expected high concentration of PC-143 . Pom I .Sir,'y' CHZMHtU. Quality AnalyticalLatmratories S567Fgt[taneDrive, P.O. Box23054B. Montgomeiy.AtabamaSG116 a I --A OS to 00 ~-1 000004 205.27T.t444 EID939365 ORGMIICS AHSI.YSIS DATA SHSET Laboratory Name: CH2M HTLI./MGM Lab Sample ID: 24727002 Client Sample ID: IiSACHftTS Concentration : Sample Matrix: Percent Moisture: PC-143 ' Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution Factor: 20 CAS TTuniber 3825-26-1 FC-143 Perfluorononanoic acid - SS Eerfluorodecanoic acid - SS llH-eicosafluorotindecanoic acid - uq/I 17 MD ND % SS MD t TJ - Analyaed for but not detected. 3 - Present/ concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.. Comments: Surrogates were not determined due to the large dilution required for analysis. Form X CH2MHIUL Quality . Analytical Laboratories 2567FlttrtaneDrive.P.O.Bw230548. Montgomery. Alabama36116 EID939366 ORGAH1CS AMM.YSTS DATA SHEET Iiaboratory Maine; CH2M HIU./MGM lab Sample ID: 24727002EB Client Sample ID: LERCHRTB Concentration: Sample Matrix: Percent Moisture; PC-143 Date Extracted: 06/01/93 Date Analyzed: 06/03/&3 Dilution Factor: 5.0 CAS Humber 382'S-26-1 PC-143 . . . . , Perfluorononanoic acid - SS Pertluorodecanoic acid - SS llH-Eicosafluoroundecarloic acid - ucr/I 38 63 78 t SS 60 t U - Analyzed for but not detected. 3 - Present," concentration estimated. B - Detected in QC blank. ' . . SS - Surrogate Standard reported as percent recovery. Comments: This ie a re-extraction of sample 24727002 to investigate low surrogate recovery from the original extraction. Only 50 ml -were extracted rather than the usual 1000 inl. due to the esqpected high concentration'of FC-143. Form 1 CH2MH1U- OuaSty Analytical Laboratories 25S7FalrtaneDrive. P.O. Box23054B. Montgomery. Alabama 36116 OOOOOG 20SS71.1444 EID93&367 ORGMUCS AHM.YSIS DATA SHEET? Iiaboratory Name: CH2M HIU./MGM Lab Sample ID; 24727003 Client Sample ID: WBST STREAM Concentration: 1C Sample Matrix: S? Percent Moisture: _ PC-143 Date Extracted; 05/24/93 Date Analyzed: 05/28/93 Dilution Factor: 5.0 CAS Hmnber UCT/I. 3825--26-1 PC-143 . . . . . 3 .2 Perfluorononanoxc acid - SS Perfluorodecarioic acid - SS llH-EicoBaxluoromidecaQioic acid - SS 25 k 27 27 t U - Analysed for but not detected. J - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery- ConanentB: Form I CHZMHIU. QuaKty Analytical Laboratories 2S67Fairtane Drive. P.O. Bw230543. Montgomery. Alabama 36116 EID939368 ORGAKICS AHMiYSIS DATA SHSBT Laboratory Name; CH2M HIItL/KEM Lab Sample ID: 24727003Rg Client Sanyle Xt: WEST STREAM Concentration; Sample Matrix: Percent Moisture: PC-143 Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: ____5.0 CM Number UCT/I. 3825-26-1 PC-143 11 Perfl-itorononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid. - SS 102 66 t 62 t U - Analyzed for but not detected- >T - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery- ConnnentB: This is a re-extraction of sample 24727003 to investigate low surrogate recovery from the original extraction. Only 200 mIi were extracted rather than the usual 1000 inL due to the expected high concentration of PC-143. Form I CH2MHH.L Quality Analytical Laboratories I >--^ OS to VO 2567FairlaneDrwe,P.O. Box230545, Montgcnery,Alatiafna36n6 000008 205371.1444 EID939369 ORG&HICS AHH.YSIS DATA SHEET Laboratory Name: . CH2M HIIJ./MGM Lab Sample ID; 24727004 Client Sample XD: WBLLftI Concentrat ion: lOW Sample Matrix: Percent Moisture; PC-143 Date Extracted; 05/24/93 Date Analyzed; 05/28/93 Dilution Factor: ____1,0 CRS Huniber 3825-26-1 FC-143 Perfluorononanoic acid - BS Perfluorodecanoic acid. - SS llH-Eicosarl-uoroundecanoic acid - uq/I. 0.6 8 <f 11 1; SS 8 \ U - Analyzed for but not detected. 3 - Present," concentration estimated. B - ^Detected in QC blank. SS - Surrogate Standard, reported as percent recovery. Comments: Form I CH2MHHL Ouaffly AnalyticatLatioratories 2567Fairtan<'Dme. P.O. Box23054B. Montgomery. Alabama36116 000009 205371.1444 EID939370 OHJE&HXCS ASAI.YSrS DATA SHEET ..dOoratory frame: CH2M HIIiL/MBH :,ab Sample ID: 24727004KB :lient Sample ID: 'WEU. #1 Concentration: Sample Matrix; LOW 'HKTER ' Percent Moisture: PC-143 Date Extracted; 06/01/93 Date Analyzed; 06/03/93 Dilution Factor: JL^ as Nuiriber 1825-26--1 FC-143 . . . . . Perfluorononanoic acid - SS Perfluorodecanoic acid - SS XlH-Eicosafluoroundecano:Lc acid - m/l, 2.1 67 74 SS 61 t n - Analyzed for but not detected. J - Present,' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. :omroents: This is a re-extraction of sample 24727004 to investigate low surrogate recovery from ;he original extraction- Only 200 inl were extracted rather than the usual 1000 s0i due to the .imitation of raw sample available. ?om I CH2MHIUL Quality Analytical Laboratories ZSBTKairtane Drive, P.O. Box23054B. Montgomery.Alabama36116 000010 205.27f.M44 EID939371 ^laboratory Name: Lab Sample ID; 2472'7005 Client Sanple ID: T.W.#2S ORGaarrcs ANALYSIS DATA SHBET Concentration : IOW Sample Matrix: Percent Moisture: PC-143 Date Extracted: 05/24/93 Date .analyzed: 05/28/93 Dilution Factor: CRS Number 3825-26-1 PC-143 Perfluorononanoic. acid - SS Perfluorodecanoic acid - SS llH-EicoeaEluoroundecanoic acid - iiq/I, 4-3 11 t 8 t SS 7 tr U - Analyzed for but not detected. 3 - Present/ concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. Comments; Form I CH2MHIU. duality Analytical Laboratories S5B7FsttrtmeDme. P.O. Bcnt230548. Montgomery,Alatiama361'l6 000011 205.27t.M44 EID939372 ORGASXCS AH&I.YSIS DATA SHEET Laboratory Name: CH2M HIM./MSM Lab Sample XD: 24727005'RS Client Sample TD; T.W.25 Concentration: Sample Matrix: Percent Moisture: PC-143 KM TOyrSR _____ Date Extracted: 06/01/53 Date Analyzed; 06/03/93 Dilution Factor; 5.0 CAS number 3825-26-1 FC-143 Perfltiorononanoic acid - SS Perfluorodecanoic acid - SS ' llH-Eicosafluoroundecanoic acid - uq/Ii 9.9 88 % . 81 % SS 77 % TJ - Analyzed for- but not detected, J - Present, concentration estimated. B - Detected in -QC blank. SS - Surrogate Standard reported as percent recovery. ' Comments: This is a re-extraction of sample 24727005 to investigate low surrogate recovery from the original extraction. Only 200 inL -were extracted rather than the usual 1000 BtL due to the expected high concentration of FC-143. .- . Form X CHSMHILL Quality Analytical Laboratories 5 o >--* 0K>\ VO u 2567Falrtane Drive. P.O. Box230548. Montgomery. Alabama 36116 000012 205.271.1444 EID939373 ORGMIICS Alil&I.YSIS DATA SHEET Laboratory Name: CH2M HIU./MGM lab Sample ID; W05243B1 Client Sample ID: OC BIAHK 1 Concentration: Saniple Matrix: . Percent Moisture: FC-143 IiQW WRTBR ____ Date Extracted: 05/24/93 Date Analyzed: 05/28/93 Dilution factor; 1.0 CftS 'Suastoer 3825-26-1 PC-143 Perfluorononanoic'acid - SS Perfluorodecanoic acid - SS HH-Eicosafluoroundecanoic acid - ug/I., 0.1 n 13 t 5 % SS 71 U - Analyzed for but not, "detected. 3 - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. Comments: Form I CHZMHIUL Quality Analytical Laboratories 25B7FaSTtaneDrive, P.O. Bw23054Q. Montgomery. Atabama36116 000013 205.271.1444 EID939374 ORGANXCS ANXt.YSIS DATA SHEET Iaboratory Name: CH2M HXIJ./MGM lab Sample ID; W05243B2 Client Sample TD: OC BUaTK 2 Concentration; Sample Matrix; Percent Moisture; FC-143 Date Extracted: 05/24/93 Date Analyzed; 05/28/93 Dilution Factor: 1.0 CAS Humber 3825-26-1 FC-143 . Perfluoroncaaanoic acid - SS Eerfluorodecanoic acid - SS HH-Eicosafluoroundecanoic acid - ucr/I. 0.1 n 19 1; 20 SS 17 t U - 3'malyzed tor but not detected- 3 - Present,' concentration,estimated. B - Detected in QC blank;. SS - Surrogate Standard reported as percent recovery. Connaents : Form I CHSMHIU. QuaTity Analytical Laboratories Z5B7Fairtane Drive, P.O. Box230548. Montgomery, Alabama36116 000014 2D5.27t.t444 EID9393-75 ORGaancs xsavisis DATA SHEET laboratory Name; .CH2M HIMi/MSM: I>ab Sample mi H06013B1_____ Client Sample ID; PC BIAHK 3 Concentration: Sample Matrix: Percent Moisture: PC-143 WVf WATER _____ Date Extracted; 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: i.q CflS Mumber_______________________mr/Ii .......... 3825-26-1 PC-143 Perfluorononanoic acid - SS 0.1 Xf 100 <r Perfluorodecanoic acid ~ SS llH-Eicosafluoroundecanoic acid - SS 92 \ 77 % O - Analyzed for but not detected- T - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery. ConanentB: Form 1 CH2MHIU- Quality Analytical Laboratories Z567FairtanBDrive, P.O. Box 330548. Montgomery, Alabama 361 IS 000015 205371.1444 EID939376 FC-143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS aboratory Name:" CH2MHILL/MGM Case No: 24727 Extraction (SEPF/CONT/SONC): SEPF Matrix: Water Native Sample Lab ID: Laboratory Method Blank: Compound FC-143 24727004 W05243B1 and W05243B2 Spike Sample Added (ug/L( Cone. (ug/L) 2 0.57 MS Laboratory ID: 24727M04 MSD Laboratory ID: 24727D04 MS Cone. (ug/L) 0.75 MS % Recov 9 MSD Cone. (ug/L) 0.87 MSD % Recov 15 RPD 15 C9 -- Surrogate ClO--Surrogate C11 -- Surrogate 2 ---- 2 ---- 2 ------ 0.13 0.13 0.11, 7 0.25 12 62 7 0.30 15 78 6 0.20 10 56 Associated Blank Spike Laboratory ID: BW052431 Compound FC-143 Spike Added Cug/L) 1 BS Cone. (ug/L) 0.21 BS % Recov 21 C9 -- Surrogate C10-- Surrogate G11 -- Surrogate 1 0.12 12 1 0.11 11 1 0.13 13 Comments: Only 0.5 L was extracted for the MS and for the MSD due to a limitation of raw sample available. File ID: F24727F3.WK1 Form 3 000016 EID939377 FG-143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS Laboratory Name: CH2MHILL/MGM Extraction (SEPF / CONT / SONG): SEPF Case No: 24727 Matrix: Water Native Sample Lab ID: 24727001RE Laboratory Method Blank: W06013B1 MS Laboratory ID: 24727M01 MSD Laboratory ID: 24727D01 Compound FC-143 Spike Added (ug/L) 20 Sample Cone. (ug/L) 36.6 MS Cone. (ug/L) 52.5 MS % Recov 80 MSD Cone. (ug/L) 55.7 MSD % Recov 96 RPD 6 C9 - Surrogate C10 - Surrogate C11 --Surrogate 20 ---- 14.0 70 21.80 109 44 20 ------ 12.4 62 21.40 107 53 20 ------ 12.9 65 17.80 89 32 Associated Blank Spike Laboratory ID: BW060131 Compound FG-143 Spike Added (ug/L) 1 BS Cone. (ug/L) 0.64 BS % Recov 64 C9 -- Surrogate C10 ~ Surrogate C11 - Surrogate 1 0.83 83 1 0.91 91 1 0.86 86 Comments: Only a 0.05-liter aliquot was extracted for the MS, the MSD, and 2472701 RE due to a limitation of raw sample available. File ID: F24727F3.WK1 Form 3 000017 EID939378 ny ws-Hnf^'- QU^L/ry ANaLmML LABORATOHIES (tfUr. CHAIN OF CUSTODY RbCORD AND AGREEMENT TO PERFORM WM Hilt Proltct Purctwe order * LAB TEST CODES . tl L-) l--l U LJ I--I l-J 1--1 I--I U LJ 1--1 PfOlclNm Ou,tbh>T Loe.n-L Lk-^-i P* \ G^^t-lY C.-^ # Company Nam;CH2M HILL Olllcs * 0 La ^ ' Quo F Pr<i)BctMtnijBr i. Phono < Report Copy to: ?^"jZ3,"/<.7 Mr,11 Dri? ' RC)Ut*d Completion Dql: LuayTbl^t\ &OM.< Sampling Rqulramenl .C 0 N Sample Disposal: T SOWA HPDES RCRA OTHER Dlspo Ralurn A a aa D D 1 . ANALYSES REQUESTED ] Pro ^No. N Typa Matrix E Simpling C GWS CLIENT SAMPLE ID R 0 H A0 (9 CHARACTERS) 8 k A Dal 71m P e E I. R CO ?^/ D-- ^ 5-n>i3 ' , 4 s-n-?? '/ 5'-W.13 10% \/ y-RfB p^<&;, ^ <, Qftf rn, M. ^ r^e 1^ ^ L'i. L E^ ^ ^ r 1 LI, U) ^l r S r^. ^ft P\ 1 Ll., U B- LL 3, 1 [ ^^ -^.^3 U? 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