Document MGp6QoENXY4Oe5LgqDGwJrZ9

PLAINTIFF'S EXHIBIT nJ Ut lam 012209 )/V f/ (J RCDI HSDS I SUBSTANCE CHEMICA... SORTED BY USDS NUMBER SUPPLIER 2961 830032 2962 REQUESTED 3039 6050 3192 50040 3246 REQUESTED 3425 8860 3508 7750 3536 64410 3586 60220 3626 60710 3923 324860 LH5HT~NAPHTHA LIQUID C-5 AND LIGHTER MURIATIC ACID PROPANE RESIDUE SULFUR TOLUENE TURBO OIL 150 TURBO OIL 68 VALVATA OIL J-460 HRICO 7988 shell'""1 SHELL SHELL SHELL SHELL SHELL SHELL SHELL SHELL SHELL NRI6HT Page 2 BOOK NO. NO. COPI UNITVZONE 031 2~ DISTILLING 031 2 DISTILLING 031 2 031 2 DISTILLING DISTILLING 031 2 DISTILLING 031 2 DISTILLIN6 031 2 DISTILLING 031 2 DISTILLING 031 2 DISTILLING 031 2 DISTILLING 031 2 DISTILLING y[JLw ^ 3 303<2 Z. /ir/- 7 /?/'S/SO -A?//: Nr-n^/ P/,/7^ 3JY 2g LAM 012210 SM-32-mC (ACV 4-79J ^ Shell Oil Company Shell Chemical Company Interoffice Memorandum JANUARY 25, 1985 Qj 7<2*Ij FROM: INDUSTRIAL HYGIENE ASSISTANT TO: DISTILLING OPERATING PERSONNEL SUBJECT: THE IMPLEMENTATION OF THE WORK PERMIT ADDENDUM AT DISTILLING On November 25, 1983 the Occupational Safety and Health Administration (OSHA) published a standard on Hazard Communication (48 Federal Register 53280). The primary objective of the standard is to ensure that the physical and health hazards of all chemicals produced or imported are evaluated and communicated to the employees. The implementation of this standard at DPMC will involve many changes including the Material Safety Data Sheet Program, hazard warnings, labels and training. One current means of relaying hazard information to employees is via the Departmental or Safe Work Permit. A "Work Permit Addendum" was developed to supplement the permit with chemical hazard information (See Attachment 1). These permit addendums are specific to the streams in each process area. Attachment 1 provides a detailed explanation of each section of the Work Permit Addendum and Attachment 3 gives definitions and examples of the abbreviated hazard categories. For the purpose of getting feedback from operations and maintenance personnel on the practical use of the permit addendum. Distilling has agreed to use the addendums in the field on a trial basis. The Work Permit Addendums have been printed in quantity and will be stored in a central location in the control room. When the operator issues a Departmental Permit to a craftsmen he/she will attach the appropriate Work Permit Addendum associated with the stream name of the equipment's service. A reference book for all of the stream names and Work Permit Addendums will also be available in the control room. During this 1-2 week trial period or (until notice is given) we would appreciate any input or constructive comments on how the Work Permit Addendum can be improved or changed. The intent is to design an addendum which provides concise and practical information for maintenance personnel who may not be familiar with all of the hazardous properties of chemicals and mixed streams. LAM 012211 DPMC-13574 12 Your cooperation and input to this pilot program is appreciated. Comments or questions can be directed to Ken Grams, ext. 6717 or Industrial Hygiene, ext. 7375. cc: ECB Satellite JEB Chron LAM 012212 DPMC-13575 PAGE ATTACHMENT 1 SHELL HAZARDS SYSTEM .WORK PERMIT ADDENDUM STREAM DEBUT BOTTOMS 11/16/84 KEY HEALTH WARNINGS PHYSICAL FORM ANTICIPATED: X MIST/LIQUID VAPOR/GAS (2) STREAM #23 SOLID/DUST CHEMICAL MSDS (g) HT IR COR EF LTND OT DERM TE CAN REP SEN BENZENE 7600 XX X ODOR DETECTED AT 2PPM; LEUKEMIA AND C6' S X XX XX X OTHER BLOOD EFFECTS ARE POSSIBLE X C7s + .: XX LIGHT ENDS X PEL=600PF'M. REPEATED EXPOSURE WELL IMMEDIATE HEALTH HAZARDS SUMMARY XX ABOVE THIS MAY INJURY NERVOUS SYST CHRONIC DELAYED HAZARDS X HIGHLY TOXIC X CANCER AGENT X IRRITANT X REPRODUCTIVE AGENT CORROSIVE SENSITIZER/ALLERGEN X EMBRYO FETUS X LOU TOXICITY/NUISANCE DUST X EFFECTS SUCH AS HEADACHE, NAUSEA, DIZZINESS POSSIBLE X DERMITITIS/ WITH REPEATED CONTACT ROUTE OF EXPOSURE TO PROTECT AGAINST INGESTION X INHALATION SKIN CONTACT Q KEY PHYSICAL HAZARDS X SKIN ABSORPTION TEMPERATURE OF MATERIAL X FLAMMABLE/COMBUSTIBLE UNDER HIGH PRESSURE REACTIVE/PYROPHORIC LAM 012213 DPMC-13576 ATTACHMENT 2 1) Stream $ All of the streams have been identified by their common stream name and assigned a number (presently there are 30 streams identified at . Distilling). 2) Physical Form Three categories are given. Usually one of the three will be designated. 3) Chemical This section lists the primary chemicals in the stream. 4) MSDS References the Material Safety Data Sheet number for the chemical. More information can be obtained from the MSDS sheet. HT, IR.......... Hazard categories of the specific chemicals. These are defined on Attachment 3. Also may find additional comments written in this section. 5) Summary Summarizes all of the hazards for the stream as a whole (a combin ation of the individual chemical hazards above). 6) Route Of Exposure One or more of these categories may apply. This should help in determining the type of protective clothing needed ie. respiratory, slicker suit, coveralls, gloves. 7) Key Physical Hazards Most frequently used category will be flammable/combustible, however, information on temperatures and pressures can be inputted in the future. LAM 012214 DPMC-13577 ATTACHMENT 3 i DEFINITIONS OF HAZARD CATEGORIES FOR WORK PERMIT ADDENDUM Abbrev. Category HT Highly Toxic IR Irritant COR Corrosive EF Embryo Fetus LTND Low Toxicity/Nuisance Dust OT Other Effects DERM Dermatitis/With Repeated Contact : Definition Examples Can seriously effect body systems from short term exposure Galvanized fume, H2S, chlorine, tetraethyl lead, aniline, phenol. Can irritate respira tory system, eyes, nose or skin from inhalation or skin contact. Chlorine, epichlorohydrin, methyl ethyl ketone, BPA'dust, most solvents and oil like hydrocar bons, welding fume. Can cause burns and other serious destruction of tissue Phenol, caustic and chromate solutions, most acids. Substances presently classified as having a potential toxic effect to the embryo or fetus. Benzene, hydrazine and methyl oxitol. Chemicals with no known serious body organ effect or requiring high exposure conditions to cause such an effect. Butane, propane, alcohol, kerosene, BPA dust, catalyst dusts, iron oxide fume. Typically materials which can produce a "narcosis" with headaches, nausea, etc. MEK, H2S, mixed light hydrocarbons, ethylene dichloride. Contact may result in a skin condition characterized by reddening, itching, scaling, peeling, drying, etc. Hydrocarbon solvents epichlorohydrin, BPA dust. LAM 012215 DPMC-13578 V. \t ' . \ 2 Abbrev. Category T Ocher Toxic Effects To Body Organs CAN Carcinogen REP Reproductive Definition Examples Repeated, excessive exposure may result in medical problems with respiratory system, liver, kidney, etc. N-Hexane, (neurotoxic) benzene (blood cell abnormalities), Reported to have produced cancer in at least test animals. Vinyl chloride, benzene, asbestos, PCA's. Toxic to reproductive organs of male or female. - LAM 012216 DPMC-13579 t Distilling (ref): Heavy Flush Distillate Toluene Butane Gasolines & Naphthas Turbine Fuel Heavy Gas Oil Extra Heavy Gas Oil Residues Pitch Wrico Cooling Water Additive Kontol 424 Additive Kontol 430 W Additive Shell Parts Loosener (Aerosol) Isopropyl Alcohol (IPA) In Laboratory: Doctor Solution Phenophthalein Silver Nitrate Acetic Acid Methyl Orange Indicator Potassium Chromate 13 DPMC-13580 LAM 012217