Document MGRee5EjKvkXvq0JBK2JZR9dL

MATERIAL SAFETY DATA SHEET Cr S 7 26 DOW CHEMICAL U S.A. MIDLAND, MICHIGAN 48674 EMERGENCY (517) 636 4400 Product Code: 19633 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/3^/89 Date Printed: 08/27/90 Page: 1 MSDS:000660 1. INGREOIENTS: (% w/w, unless otherwise noted) Styrene monomer Vinyl ester resin CAS# 000100-42-5 35"5Q%* CAS# 036425-16-8 BAL. *for specific percentage of styrene monomer found in this product, see section 9- This document is prepared pursuant to the 0SHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: 294F, 14&C* VAP. PRESS: 7 mmHg @20C* VAP. DENSITY: 3-6* SOL. IN WATER: Insoluble. SP. GRAVITY: 1.025-1.075 APPEARANCE 6 ODOR: Straw yellow, viscous liquid - pungent ODOR: Pungent styrene odor. *Ba$ed on styrene 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: 70-80F METHOD USED: PMCC, ASTM 0-93 FLAMMABLE LIMITS LFL: 0.88%* UFL: 6.80% vol* SAL 000009586 (Continued On Page 2) (R) Indicates a Trademark of The Dow Chemical Company AN OPERATING UNIT OF THE DOW CHEMICAL COMPANY GS726 MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, Ml 48674 Emergency Phone: 517-636-4400 Product Code: 19&33 Page: 2 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/30/89 Date Printed: 08/27/90 MSDS:000660 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) *Based on styrene EXT INGUISHI MG MEDIA: Water fog, foam, alcohol foam, C02, dry chemicaI. FIRE & EXPLOSION HAZARDS: Upon exposure to heat or flame, an exothermic reaction can develop, followed by decomposition of product. Keep vapors away from possible ignition sources. FIRE-FIGHTING EQUIPMENT: Wear goggles and positive pressure, self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Avoid storage in direct sunlight and at temperatures above 120F, 1+9C. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Oxidizing materia 1 HAZARDOUS DECOMPOSITION PRODUCTS: Pyrolysis products such as CO. HAZARDOUS POLYMERIZATION: May occur. Avoid contact with metal salts such as ferric and aluminum chlorides, unintended contact with peroxides, and depletion of inhibitor levels. Avoid exposure to direct sunlight or temperatures above 120F (L9C). 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Treat as flammable liquid; keep heat, flame, or spark producing equipment away. Protect personnel from styrene vapors. Soak up spills in absorbent material such as sand and collect in suitable containers. (Continued On Page 3) (R) Indicates a Trademark of The Oow Chemical Company * An Operating Unit'of The Dow Chemical Company SAL 000009587 MATERIAL SAFETY DATA SHEET G S 7 26 Dow Chemical U.5.A.* Midland, Ml 48674 Emergency Phone: 517-636-4400 Product Code: 19&33 Page: 3 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/30/89 Date Printed: 08/27/90 MSDS:000660 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: (CONTINUED) Residual resin may be removed using steam or hot soapy water. Solvents are not recommended for cleanup unless the recommended exposure guidelines and safe handling practices for the specific solvent are followed. Consult appropriate solvent MSDS for handling information and exposure guidelines. For large spills, evacuate upwind of spills and contain with dike. DISPOSAL METHOD: Resin can be disposed of through burning in an adequate incinerator or burying in an approved landfill in accordance with federal, state and local regulations. 6. HEALTH HAZARD DATA: EYE: May cause moderate irritation with corneal injury. Vapors may irritate eyes. May cause lachrymation (tears). SKIN CONTACT: Prolonged exposure may cause skin irritation. Repeated exposure may cause skin burns. SKIN ABSORPTION: A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. The LD50 for skin absorption in rabbits is expected be >2000 mg/kg. to INGESTION: Single dose oral toxicity is believed to be low. The oral LD50 for rats is expected to be >4000 mg/kg. If aspirated (liquid enters the lung), may be rapidly absorbed through the lungs and result in injury to other body systems. INHALATION: Excessive vapor concentrations are attainable and could be hazardous on single exposure. Signs and symptoms of excessive exposure may be anesthetic or narcotic effects. Excessive exposure may cause irritation to upper respiratory tract. (Continued On Page 4) (R) Indicates a Trademark of The Oow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000009583 GS726 MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, Ml 48674 Emergency Phone: 517-636-4400 Product Code: 19&33 Page: 4 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/30/89 Date Printed: 08/27/90 MSDS:000660 6. HEALTH HAZARD DATA: (CONTINUED) SYSTEMIC & OTHER EFFECTS: Repeated excessive exposures to high amounts may cause central nervous system, liver, kidney effects and respiratory or eye irritation- Repeated excessive exposures to smaller amounts may cause central nervous system effects and respiratory or eye irritation. Styrene is reported to have caused hearing loss in laboratory animals upon exposure to high concentrations (sixteen times the TLV and higher); however, the relevance of this to humans is unknown. For hazard communica tion purposes under 0SHA Standard 29 CFR Part 1910.1200, this mixture contains a component (styrene) which is listed as a potential carcinogen by IARC (International Agency for Research on Cancer). Neither the data from various long-term animal studies nor from epidemiology of workers exposed to styrene provide an adequate basis to conclude that styrene is carcinogenic. In laboratory animals, styrene did not produce any effects on the fetus even at exposure concentrations having an adverse effect on the mother. In animal studies, styrene has been shown not to interfere with reproduction. Results of in vitro ("test tube") and animal mutagenicity tests on styrene have been inconclusive. 7. FIRST AID: EYES: Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel. SKIN: Wash off in flowing water or shower. INGESTION: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. INHALATION: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing is difficult, give (Continued On Page 5) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000009589 MATERIAL SAFETY DATA SHEET CS726 Dow Chemical U.S.A.* Midland, Ml 48674 Emergency Phone: 517-636-4400 Product Code: 19633 Page: 5 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Oate: 05/30/89 Date Printed: 08/27/90 M$DS:000660 7. FIRST AID: (CONTINUED) oxygen. Call a physician. NOTE TO PHYSICIAN: The decision of whether to induce vomiting or not should be made by the attending physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE (S): Styrene, monomer: ACGIH TLV and 0SHA PEL are 50 ppm TWA, 100 ppm STEL. VENTILATION: Provide general and/or local exhaust ventilation to control airborne concentrations below the recommended exposure guideline. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved airpurifying respirator. If vapor exposure causes eye discomfort, use a full-face respirator. SKIN PROTECTION: Use protective clothing Impervious to this material. Selection of specific items such as gloves, boots, apron, or full-body suit will depend on operation. EYE PROTECTION: Use chemical goggles. If vapor exposure causes eye irritation, use a full-face respirator. Eye wash fountain should be located in immediate work area. 9. ADDITIONAL INFORMATION: (Continued On Page 6) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000009590 GS7 26 MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, Ml 48674 Emergency Phone: 517-636-4400 Product Code: 19633 Page: 6 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/30/89 Date Printed: 08/27/90 MSDS:000660 9. ADDITIONAL INFORMATION: REGULATORY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: An immediate health hazard A delayed health hazard ( Afire hazard 1 A reactive hazard SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice good care and caution to avoid skin and eye contact and to avoid breathing vapors. For additional precautions, see Dow Bulletin, DERAKANE (R) Vinyl Ester Resins - Fabricating Tips. MSDS STATUS: Revised Section 8 & 9. The following products are represented by master #660. The specific composition of styrene monomer found within each product is indicated as follows: Derakane 411-35 VER 09690 ................................................................................................35% Derakane 411-35 Low Inhibitor VER (19774)..........................................................35% Derakane 411-45 VER (19633)................................................................................................35% Derakane 411-45 Low Inhibitor VER (19678).......................................................... 35% Intermediate Vinyl Ester Resin 145 (08808).......................................................... 35% XU 71822.00 (05202)....................................................................................................................35% Derakane 411-R (01646)............................................................................................................ 46% Derakane 411-50 (19630 ......................................................................................................... 50% Intermediate Vinyl Ester Resin 150 (08809)..........................................................50% (Continued on Page 7) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000009591 MATERIAL SAFETY DATA SHEET GS726 Dow Chemical USA* Midland, Ml 48674 Emergency Phone: 517-636*4400 Product Code: 19633 Page: 7 Product Name: DERAKANE (R) 411-45 VINYL ESTER RESIN Effective Date: 05/30/89 Date Printed: 08/27/90 MSDS:000660 REGULATORY INFORMATION: (Not meant to be all-inclusive--selected regulations represented.) NOTICE: The information herein is presented in good faith and believed to be accurate as the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one location to another; it is the buyer's responsibility to ensure that its activities comply with federal, state or provincial, and local laws. The following specific information is made for the purpose of complying with numberous federal, state or provincial, and local laws and regulations. See MSD Sheet for health and safety information. U S. REGULATIONS SARA 313 INFORMATION: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER CONCENTRATION STYRENE 000100-42-5 35 "50 % (R) indicates a Trademark of The Dow Chemical Company The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult The Dow Chemical Company For further Information. * An Operating Unit of The Dow Chemical Company sAl_