Document MGLkVOD0GBgDpB6qKdx9eayNM

DownloadRandom document
`E en p Precis ResReEarSEARCH - . -Y B Analytical Report AR2%-193 / 3M Company - Analysis of PFOA and PFOS In Wa0t4e-r0S9a0m8ples from Hastings Municipality Exygen Report No. L0004146 Revised " -_ Testing Laboratory - 30E5x8ygRoenseRaersceharDrcihve State College, PA 16801 Requester Manager,GaEErnHyvSiAr.OopHneomrheaentntisaoltnesOipnerations : Bu3ikMinCgo4m2p-a2n6y-27 St.Paul, MN 55106 - - - -- Rr HELiEnkT i]R,,on, usa - a - 1 Introduction " mHpInatkoseorhmivnoorsorncfhooasMorCgrtoermsrpeoa0(nuneyPt.FsaatOTroShea)etriropnoofcwpraoehltdaweafaosasraprtmnephovlia.esnAeesdsneaocyssUipvoccefaadlpuaetthuEeoxfryoqgeuocoents2atnecrnrsepqcoumaolasei(soFdttbOrRy)Cooarens)sd rovson. susvere nk coma TahnealBfosgqenupreacnfnoruttmhbeasaaamaspisodisg.nad 1 hesampesis LOOOH1AS. Tab | ks to target Table. TargetAnaes fo Quantitation - Barmeter sean Fomua Porfuorooctangicacd PrOA CF uCO0H - Perfiuorooctanesufionate PFOS CoFySOH 2 Sample Receipt ` pTAiwnreior1oqs2uino0asAsttanamocfpihlImeMsao,nawtledAlrsoarmyoioeisowdaarteaExnyagheznoidn.5A0c0ompLywohfiaelpllsasatmiconaorgowimomuetmhbmoetrs,r a sTahmapslaemspwleersowsteorreedreocfailgvradatonedf12o2m80m4o.TofhreseamcplteswaernoyshsiopedambientvaUPS, Tho S$ Methods - AnalayndtPriepacraatorly - 31 Water Sample Preparation - 1Fa00os0rdht%yopmmdiaoiwtstihoteahrnsaSlxot.LfatchcAiofpoaon(rl4Sio0Por%nEso)amwfmtaphhslaeuenwsecaekxsdc6tt0tao%wnpwsaralpstoaoWnrroaedantdtsohaw8.rGaTdtyheorSscPaaErcliagerefvvoaers.LuOTrhMessScIsSiaansnonanes.ys - using aacrosprayLNSNS. 1 aiocampievksndsop: a 32 SampleAnalbyyLCs/MiS/sMS - sifnraolHounghahrPy&rpoasisucarohLiaitshgeeccohClrhuromomnmaaattioogregarp1ha0ycp(otHlhoPuimLnkCc,)i.daBmnaosabelidiuoponhtaohsfee,axftftrhaecaisnofafieceteaedraeensrpaossmed - pacezors 5 CL L " - cahQrnadarasucgccuomrasaiteaecagmnnanaeimdainodtnu!easnetxftevooicdarftce,iadmetn.eda.sTytiFhoanonolgdlaodaiwroidvnn.isgdcoHhaPanLrgGaecsaeopfraoirracgtiaoofnn,stmchaomscpsoosmuppneoccusin.doHsm.aaterysperopviasedeeaalnoranpceiyd " 2Sa0mHpP1o100xstvofomrcaunaencrttaasosoan. 0anApiod Biosystems AP!4000wasusedtoanalyz the " 2Ias1namamoemrss.op5ar4amtocnokwiamsn.bTihneesduumsoinfg hogrSaocmonrtsakiornptohroaudgahsa&TShnogmovFiieopohraseearAnP,o5o0x - `Thefollowing gradient wasperformed: . MVooblbolPorPiahsao(s(Ao): 2MmorAanom! moAncaiinuWatmer a 12Ta00me w&&s 330 - 1810000 2a2 77s 180 EH " Thefolowing parametersweroused foraperatonof the massspectrometer: " TTP-- ooornmmeyentr-- ed ------ ENoegae------ TransitonsMontored 44115355937609 ((P"FCOPAF)OA4)95.60 (PFOS). a Gasjog Gas Temperature: 23500UmCin - " 4 Analysis 4.1 Calibration " 2P2A8FnmOdoA1S,6nPP00REcnOpaoStla.brnr(adootp"n)CccfuPoUrFrsevOeLdAGwdf.MaoSTssuIhaaMnomrSacpllaayeetznsie.adoTinn.htpio"aolCiasalsibnweedaanirtoohtnrposrruoaegsphmpaoocrunotsdteahvoraa.nsraBcloyhrtiacaa.alnc1sase0rqceauoseennscs5efwoor 20mn58d65p c. oaoforeoitf cdholie omnoitn.natUtasni(n1g)nwearreoelremsisneitinAnc1xaliicob,veoassotceapiieonoe2nn inthe rawdatainAtacrmonGt . Fortheresuts reported here, calbrationcriteria were met. `Thecalibrationcurvesareincluded 1 racers & of TT - ` a - - " [ " " ` " " u ~ -- 42 Surrogates s"WaIoCmrpPlFloeOccAotnittosauiansveeorldsubameseftorarisecutrhroIobngoaattwteofhsowtrhetarhseewaSamtaeptrt.osatmhplfeies.foCr saPmFpOiAnwg.aIsnatdhdee1d6Kt,o1tbhoeevmipotsy CPOArecoveriescanbofoundinAtachment 8. 4.3 Laboratory Control Spikes Laboratorycontospikos ntheanalyticalsotweroprepare byacing aknownconcentration oWaf1si5sP0eiF%sOosAhro,matehcetChdoo-adPtoaFpcOicsAii,rrraaeaajncneidcygte,PedTF.hOFoSollraobholroaabrtoeorarslyuocrsoynrrtoerpaooglresneptdiskh.eLesarbM,ourshaettlSoahrbooyrwcaotnfotorrcyoolcvsoeprniarksoelsbaesrtpewieeuessnew7da0rte.o 4.4 Field Matrix Spikes wsAaelmropolwiaandngd,dMehdaitg1htmhsapetirekiemxspsatpriyekusesawmeapdsltpo0racesopsnaairseasdnfmroesrtbehevofedorarycewcauhtreearcbysaiatnmtphlsoewimeanrltarhsxefe.inTethlde0,imCaootmipTsoopunkoderss swheoruodwisthiontwherecaocvcearpieisabboertawnogoo,n7x0c-e1p3t0a%.nFotoerdtheSercetsiuotnsreopfotrhtisedehpoarret, the marspies 45 SampleRelated Comments Allwater sampleswere collected in duplicate. thesampleresultsin AttachmenBt. Duplicate sampleresults arereportedalong with 5 Data Summary iPnlepaarstesspeoeAbtitlaoch(menngt)BffoorraPdeFtOaAilaenddliPsRtiOngSoft. he analytical resuts.The reas re ru epors ted. 6 StateofmAcecunracty Baeanpasilyootsid,coaalnnadrcfecusoruiascomyffaoltrabiPoFrsaOpthSokaroynscdsonhPtoFrwoOolAsdpfirokeuecslo,vsersil+eds3mW0at%ir.inxLtshpaekseosb,aancnogodensstr,uoolwgaiakhtetostsh,eopa(solsruo,uigytnhge exception: = ThePFOSrecoveryforsample H-W6-207643HighSpikewas 132%. Spacti sampl recoveries arogveninAtachmont8 Pacesors es set s see a - a .. 7 DSaa taai/mSooampcb lieas Rehternr tioaonSmeGs0 de Sopsofsfhrorrd lppo ott,,Sloasitase sdeaie rwEaosEsonn 1 8 Attachments ` 71 AttachmenAt:Analytical Results 72 AttachmenBt: SpikeRecoveryData PM 73 AtachmenCt:Chainof CustodyForms 76 Aarts Fawaracaoen a . 9 Signatures ' r 2d Ca M ato bite ogos a . fie % a " w J-- a Section A o E n a XY8!EARCH RRR - Sud Analytical " `Summaroyf PFOA and PFOS in Water `Samples E04-0909 ` ETghgi | TSaimpmoes reCmoeAscupmroAOnnRiast Fo_undrCiehgtsuiol)soenamtmPnRnOSe NG Wb Lts2 Hore Dup Na No a a L1lU4tiO1i4ec6Tsa5 wwaHHws-wiWss4g0o-7ro26s0r07se9ss9us3oup NNNNoooO Uitiots Hiwazoesss \ IN\NoD no " LLuiititisoeTts hiiwvarrso5oe0snss0astsuuspn N\Noo Liidozt _eonoomn Tip ak Ao \NNoo Ao a NNQD ==NNoottduifatbtlroc sNhoaver0a.2c5rncinni.sio sven 0.028 ni a Lt o Quantitation (LOG) whichis0.050 ng/mL El a " " a o E058ERy RDrBivoer, usa pfekz, /0 Section B ` E e RESn EARCH FrecPhreovReenseRaerschs.. - a Field Matrix Spike Recovery Summary for PFOA and PFOS In Water E04.0909 a _ DesScarmipptlieon ASgrpmintkoe)dt||[AImni{nSgFamiplned.CBRAeAGcmoGovPuenFrteOdAR_ ocovery|_A_IrncSsaFmospulunet.doRneAacmotovusenrtPedroRSecovery - T0E41240637,60413oLno3wpS)PE or | Na ogiisn) ms | gNmo) _ (onimm)e -- m3e) HAN[G.r20e76s43iHeigih nSpike S| on aes ow | wes rm " HWAeWrAt20e7.9093oLboswpSpnike or | No eos ow [ No ms rm a HAWAa-t2t0e7,95535H0iSgpheS)pike 5 Was es No se 1s o (HALW1S4-021017,60319pLpobSwiSkp)ike ox NO ooo os no oats 11s a HAN04S1-4281027.635H0igSh nSpike: 5 Wo am ow | Nas wm HWB1.42601653,0513pLoonSwpStp)ike 01 | No oom ow Wore mm HAWWA31.42001663,3530H0i0gShtaSypike 5 MW. ss te | Nes gr a HAVaTr-e50n9a0n513sLoonwstSpike o1 | wo Coos a CET - HW7e-r5i09n0,5o3 sHigshpSnpike 5 sa | oo se re - 04-0310496T2r2ip01Bl5an5ksLow Spk or | N00 10 | momo mo 04.05We0r8e0T2r3p,5Bolatnsk Hai)gh Spk 5 Mss 2 | wo as ow M NNQO ==NNQoouttanceiultaacnoiinad(baLlt0oG=rM)awebhaoisvcuher0e.d0c2o50n.nc05e0ngtPr.aotimon boon0.25 rt. andhaLin of o SEReseDarch RDoriveo, usa H00O29H13210 oomncom /R Co .`E - . - .a .LE] a - .- ; . a o rEcS,ne Surrogate Spike Recovery Summary for *C-PFOA in Water E04-0909 o--g_ re-- e,e -- FrEl___a "mlcPFeoA we _ iGnasL4146-1 gmaemsees,s H-WE-207643 i005 somm0.494 om99 GifwL4m1Ess4s64 mmaweemmmsomo8o0sx 'H-W6-207643 High Spk. 05 oE ao0.m5m8o2mdeo11w6 LfihE 141469 mmemeH-sW5mn-2e07s63,9, oio0wr5 oo0e.s5m4m7ww1o0m9 LGmu1Re46i-Rs14 mmHm-ewWm3-em2n06is33se3wDtu,p.s oaa0a5 s0ao6ms2moe1 gm om124 peann La146-17 unmHoe-W7mm-5ee09ns05s3,, sw0o5 omg05m71 114. SwaiuneE L4146-20 Tmeeromumeone,a H-W7-509053 High Spk oN0os5r Goo05Emm75 ow115 Xi = oanR,iani `eygencom /3 oo